KR101218264B1 - Transcribing film with finger mark-resisting and method of manufacturing the same - Google Patents

Transcribing film with finger mark-resisting and method of manufacturing the same Download PDF

Info

Publication number
KR101218264B1
KR101218264B1 KR1020080049096A KR20080049096A KR101218264B1 KR 101218264 B1 KR101218264 B1 KR 101218264B1 KR 1020080049096 A KR1020080049096 A KR 1020080049096A KR 20080049096 A KR20080049096 A KR 20080049096A KR 101218264 B1 KR101218264 B1 KR 101218264B1
Authority
KR
South Korea
Prior art keywords
layer
transfer film
weight
transfer
composition
Prior art date
Application number
KR1020080049096A
Other languages
Korean (ko)
Other versions
KR20090123156A (en
Inventor
김철호
이강엽
진원섭
Original Assignee
(주)엘지하우시스
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by (주)엘지하우시스 filed Critical (주)엘지하우시스
Priority to KR1020080049096A priority Critical patent/KR101218264B1/en
Publication of KR20090123156A publication Critical patent/KR20090123156A/en
Application granted granted Critical
Publication of KR101218264B1 publication Critical patent/KR101218264B1/en

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42—Intermediate, backcoat, or covering layers
    • B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
    • B41M5/443—Silicon-containing polymers, e.g. silicones, siloxanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Laminated Bodies (AREA)

Abstract

본 발명은 내오염성이 우수한 전사필름에 관한 것으로, 전사원단에 특수표면처리층, 보호처리층, 무늬인쇄층, 프라이머층, 접착제층이 순차적으로 적층되어 있는 전사필름으로서, 상기 특수표면처리층이 우레탄아크릴 모노머를 주제용액으로 하여 실리카 10~20중량% 및 멜라민 수지 3-5중량%를 포함하는 조성물로부터 형성되는 것을 특징으로 하는 전사필름에 관한 것이다. The present invention relates to a transfer film having excellent stain resistance, and is a transfer film in which a special surface treatment layer, a protective treatment layer, a pattern printing layer, a primer layer, and an adhesive layer are sequentially laminated on a transfer fabric. It relates to a transfer film characterized in that the urethane acrylic monomer is formed from a composition containing 10 to 20% by weight of silica and 3-5% by weight of melamine resin as the main solution.

전사지, 내지문성, 우레탄, 실리카, 멜라민 Transfer paper, anti-fingerprint, urethane, silica, melamine

Description

내지문성이 우수한 전사필름 및 그 제조방법{Transcribing film with finger mark-resisting and method of manufacturing the same}Transcribing film with finger mark-resisting and method of manufacturing the same

본 발명은 휴대용 전자기기, 가전제품 등의 외장재의 형성에 사용되는 전사필름에 대한 것이다. The present invention relates to a transfer film used in the formation of exterior materials such as portable electronic devices, home appliances.

전사필름은 합성수지 성형물(창호재, 판넬, 몰딩재, 천정재 등), 금속 성형물(철판, 알미늄샷시 등), 합성목재 성형물(PB, MDF 등), 석고보드 가공물 표면의 전사 인쇄에 이용되는 것으로 가공물 표면에 색상 및 장식무늬 부여는 물론 내마모성, 내스크레치성, 내용제성, 내약품성, 내후성, 내열성, 내굴곡성 등 여러가지 성능을 부여한다. The transfer film is used for the transfer printing of synthetic resin moldings (window materials, panels, molding materials, ceiling materials, etc.), metal moldings (steel plates, aluminum chassis, etc.), synthetic wood moldings (PB, MDF, etc.) and gypsum board workpieces. It not only gives color and decorative pattern to the surface of the workpiece but also gives various performances such as wear resistance, scratch resistance, solvent resistance, chemical resistance, weather resistance, heat resistance, and flex resistance.

상기 전사필름은 일반적으로 종이나 합성수지 필름으로 된 전사원단에 무늬인쇄층 및 접착제층 또는, 필요에 따라, 인쇄 보호를 위한 보호처리층 또는 프라이머층을 추가로 적층하여 제조된다. 상기 전사필름은 성형가공물의 표면에 대접하여 가열압착하므로써 접착제층이 가공물 표면에 융착되도록 한 다음 전사원지를 분리 제거시키는 방법으로 전사 인쇄에 이용된다.The transfer film is generally manufactured by further laminating a pattern printing layer and an adhesive layer or a protective layer or primer layer for printing protection on a transfer fabric made of paper or synthetic resin film. The transfer film is used for transfer printing in such a way that the adhesive layer is fused to the surface of the workpiece by heat-compression bonding to the surface of the molded workpiece and then separating and removing the transfer paper.

그러나, 상기의 전사필름에 의한 코팅 후 가공물 표면에 있어서는 인쇄 후 내지문성이 매우 취약하며 특히 필름의 인쇄층이 짙은 계열의 색깔일 경우 지문에 대한 오염이 심각한 문제점이 있다.However, on the surface of the workpiece after coating with the transfer film, the fingerprinting property is very weak after printing. In particular, when the printing layer of the film is a dark color, there is a serious problem of fingerprint contamination.

상기 문제를 해결하기 위하여 본 발명은 전사 인쇄에 의해 성형 가공물의 외장 코팅재의 형성에 사용되는 전사필름에 있어, 전사필름의 내지문성을 향상시킴으로써 짙은 계열의 색상 및 무늬 인쇄 후에도 성형가공물 외장의 지문에 대한 오염을 방지하는 것을 목적으로 한다. In order to solve the above problems, the present invention provides a transfer film used to form an exterior coating material of a molded product by transfer printing, and improves the fingerprinting property of the transfer film so that the fingerprint of the exterior of the molded product can be printed even after dark color and pattern printing. The purpose is to prevent pollution.

즉, 본 발명의 전사필름은 다양한 색깔 구현시에도 지문에 대한 오염성이 방지되어 사용 중 깨끗한 상태로 유지되는 외장 코팅재 형성을 가능하게 하는 것을 목적으로 한다.In other words, the transfer film of the present invention is intended to enable the formation of an exterior coating material that is kept clean during use because it is prevented from contaminating fingerprints even when implementing various colors.

본 발명은 전사 인쇄에 의해 성형 가공물의 외장 코팅재로 사용되는 전사필름에 있어서 (a) 전사원단; (b) 우레탄아크릴 모노머 72-86중량%, 실리카 10~20중량%, 멜라민 수지 3-5중량% 및 개시제 1~3중량%를 포함하는 조성물로부터 형성되는 특수표면처리층; 및 (c) 하드코팅층을 포함하는 것을 특징으로 하는 전사필름을 제공한다.The present invention provides a transfer film used as an exterior coating material for a molded product by transfer printing (a) transfer fabric; (b) a special surface treatment layer formed from a composition comprising 72-86% by weight of a urethane acrylic monomer, 10-20% by weight of silica, 3-5% by weight of melamine resin and 1-3% by weight of an initiator; And (c) provides a transfer film comprising a hard coating layer.

상기 하드코팅층은 무늬인쇄층 및 접착제층을 포함할 수 있다.The hard coating layer may include a pattern printing layer and an adhesive layer.

상기 하드코팅층은 보호처리층 또는 프라이머층을 포함할 수 있다.The hard coating layer may include a protective layer or a primer layer.

또한, 본 발명은 전사원단에 우레탄아크릴 모노머 72-86중량%, 실리카 10~20중량%, 멜라민 수지 3-5중량% 및 개시제 1~3중량%를 포함하는 조성물로부터 증착 또는 스퍼터링 공법으로 특수표면처리층을 형성하고; 닙 코터(Nip Coater), 바 코터(Bar Coater) 또는 그라비아(Gravure) 코팅의 방법으로 하드코팅층을 형성함으로써 제조되는 것을 특징으로 하는 전사필름의 제조방법을 제공한다.In addition, the present invention is a special surface by a deposition or sputtering method from a composition comprising 72-86% by weight of the urethane acrylic monomer, 10-20% by weight of silica, 3-5% by weight of melamine resin and 1-3% by weight of the initiator in the transfer fabric Forming a treatment layer; It provides a method for producing a transfer film, characterized in that it is produced by forming a hard coat layer by a nip coater (Nip Coater), Bar Coater (Bar Coater) or gravure (Gravure) coating method.

본 발명에 의하면 전사 인쇄에 의해 성형 가공물의 외장 코팅재의 형성에 사용되는 전사필름에 있어, 인쇄 후 내지문성이 매우 취약하며 특히 필름의 인쇄층이 짙은 계열의 색깔일 경우 지문에 대한 오염이 심각한 문제를 해결할 수 있다. 즉, 본 발명의 전사필름은 다양한 색깔 구현시에도 지문에 대한 오염성이 방지되어 사용 중 깨끗한 상태로 유지되는 외장 코팅재 형성을 가능하게 한다.According to the present invention, in the transfer film used for the formation of the exterior coating material of the molded product by transfer printing, the fingerprinting property is very weak after printing, and in particular, when the print layer of the film is a dark series of color, contamination of fingerprints is a serious problem. Can be solved. That is, the transfer film of the present invention enables the formation of an exterior coating material that is kept clean during use since contamination of fingerprints is prevented even when various colors are implemented.

이하 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

도 1은 본 발명의 전사필름의 일실시예의 단면을 나타낸 것이다. 상기 도1에 의하면, 본 발명의 전사필름은 전사원단(1) 위에 특수표면처리층(2), 보호처리층(3), 무늬인쇄층(4), 프라이머층(5) 및 접착제층(6)을 적층한 구조이다.Figure 1 shows a cross section of an embodiment of the transfer film of the present invention. Referring to FIG. 1, the transfer film of the present invention has a special surface treatment layer 2, a protective treatment layer 3, a pattern printing layer 4, a primer layer 5, and an adhesive layer 6 on a transfer fabric 1. ) Is laminated structure.

상기 전사원단(1)은 내열성 합성수지 필름으로써, 폴리에스테르 필름 또는 필요에 따라 폴리염화비닐 또는 기타의 합성수지 필름을 사용할 수 있다. The transfer fabric 1 is a heat-resistant synthetic resin film, it may be a polyester film or, if necessary, polyvinyl chloride or other synthetic resin film.

상기 특수표면처리층(2)은 전사원단이 제거된 후 성형 가공물의 표면에 나타나는 표면층을 이루는 것이다. 상기 성형 가공물 표면층의 내지문성을 강화하기 위 해 특수표면처리층의 형성에 사용되는 조성물은, 우레탄아크릴 모노머를 주제용액으로 하여 실리카 10~20중량%, 멜라민 수지 3-5중량% 및 개시제를 1~3중량% 함유하는 조성물인 것을 특징으로 한다.The special surface treatment layer 2 forms a surface layer appearing on the surface of the molded product after the transfer fabric is removed. The composition used in the formation of the special surface treatment layer to strengthen the fingerprint properties of the molded article surface layer, 10 to 20% by weight of silica, 3-5% by weight of melamine resin and the initiator using a urethane acrylic monomer as the main solution It is a composition containing-3 weight%.

상기 조성물로부터 전사원단(1) 상에 특수표면처리층(2)을 형성하기 위해 증착 또는 스퍼터링 공법을 사용한다. A deposition or sputtering method is used to form the special surface treatment layer 2 on the transfer fabric 1 from the composition.

상기 증착은 진공 증착법을 이용하여 증착하는데, 10-2 내지 10-6 토르의 진공 및　300 내지 800℃의 온도에서 진공증착을 실시하여 50 내지 500Å 두께의 증착막을 형성한다.The deposition is carried out using a vacuum deposition method, a vacuum of 10 -2 to 10 -6 Torr and vacuum deposition at a temperature of 300 to 800 ℃ to form a deposition film of 50 to 500 kPa thick.

상기 스퍼터링은 진공증착법을 이용하는 공정과 비슷하지만 진공도가 10-4 내지 10-8 토르의 진공하에, 고온에 의한 열증착법이 아닌 금속물질을 이온화 시켜서 증착하고자 하는 면에 물리적 충격을 가함으로써 증착시킨다.The sputtering is similar to the process using a vacuum deposition method, but under a vacuum of 10 -4 to 10 -8 Torr vacuum, the sputtering is deposited by applying a physical impact on the surface to be deposited by ionizing the metal material, not the thermal deposition by high temperature.

한편, 상기 보호처리층(3), 무늬인쇄층(4), 프라이머층(5) 및 접착제층(6)은 하드코팅층이라하여 전사 인쇄 시 필요에 따라 선택하여 적층될 수 있다. Meanwhile, the protective layer 3, the pattern printing layer 4, the primer layer 5, and the adhesive layer 6 are called hard coating layers, and may be selected and stacked as necessary during transfer printing.

보호처리층(3)은 무늬인쇄층과 특수표면처리층과의 결합력을 강화시키고 무늬인쇄층의 강도를 증가시키는 것이다. 또한, 인쇄시 무늬인쇄층의 비틀림 및 흔들림을 방지시키는 역할을 한다. 이러한 보호처리층의 형성에 사용되는 조성물은 아크릴 레진과 셀룰로오스 계열의 화합물을 혼합한 조성물이다.The protective layer 3 is to enhance the bonding force between the pattern printing layer and the special surface treatment layer and to increase the strength of the pattern printing layer. In addition, it serves to prevent twisting and shaking of the pattern printing layer during printing. The composition used to form such a protective layer is a composition in which acrylic resin and a cellulose-based compound are mixed.

바람직하게 상기 보호처리층 형성에 사용되는 조성물은 아크릴 레진 15~25중량%와 셀룰로오스 5~10중량%을 포함하며, 그라비아 공법으로 1～5㎛ 의 두께로 형 성된다.Preferably the composition used to form the protective layer comprises 15 to 25% by weight of acrylic resin and 5 to 10% by weight of cellulose, and is formed to a thickness of 1 to 5㎛ by the gravure method.

무늬인쇄층(4)은 아크릴 레진과 염화비닐코폴리머를 혼합한 조성물로부터 형성되며, 무늬에 따라 안정제, 브로킹방지제 및 소광제를 첨가함으로써 인쇄 효과를 향상시킬 수 있다. The pattern printing layer 4 is formed from a composition in which acrylic resin and vinyl chloride copolymer are mixed, and the printing effect can be improved by adding a stabilizer, an anti-broking agent and a matting agent depending on the pattern.

바람직하게 상기 무늬인쇄층 형성에 사용되는 조성물은 아크릴 레진 20~30중량% 및 염화비닐코폴리머 10~20중량%을 포함하며, 그라비아 공법으로 1～5㎛의 두께로 형성된다.Preferably, the composition used to form the printed layer includes 20 to 30% by weight of acrylic resin and 10 to 20% by weight of vinyl chloride copolymer, and is formed to have a thickness of 1 to 5 μm by a gravure method.

프라이머층(5)은 무늬인쇄층과 접착제층과의 결합력을 증대시키는 기능을 하는 것으로서, MEK(Methyl Ethyl Ketone) 및 톨루엔으로부터 합성되는 수지 또는 폴리우레탄 계열의 수지를 사용할 수 있다. The primer layer 5 serves to increase the bonding force between the pattern printing layer and the adhesive layer, and may be a resin synthesized from MEK (Methyl Ethyl Ketone) and toluene or a polyurethane-based resin.

상기 프라이머 층은 그라비아 공법으로 1～5㎛의 두께로 형성될 수 있다.The primer layer may be formed to a thickness of 1 ~ 5㎛ by the gravure method.

접착제층(6)은 전사 인쇄 공정에서 성형가공물 표면에 전사필름을 가열압착할 때 가공물의 표면에 융착된다. 접착제층으로는 폴리염화비닐과 아크릴 레진을 혼합하여 유기용매에 희석한 것을 사용한다. The adhesive layer 6 is fused to the surface of the workpiece when the transfer film is hot pressed to the surface of the molded workpiece in the transfer printing process. As the adhesive layer, a mixture of polyvinyl chloride and acrylic resin, diluted in an organic solvent, is used.

실시예Example

폴리에스테르 필름에 우레탄아크릴 모노머를 포함하는 코팅액(SSCP 삼성화학 / HD 100A-1)을 10-4 토르의 진공 및　400℃의 온도에서 진공증착의 방법으로 코팅하였다. 다음으로, 아크릴 레진 15wt%와 셀룰로오스 5wt%을 포함하는 코팅액(청우화학 K-1), 아크릴 레진 25wt% 및 염화비닐코폴리머 10wt%을 포함하는 코팅액(SK chemical / up056), MEK(Methyl Ethyl Ketone) 함유 코팅액(삼영잉크 / PVB)을 순차적으로 그라비아 공법으로 코팅하여 보호처리층, 무늬인쇄층 및 프라이머층을 형성하였다. 그런 후, 접착제를 도포하여 접착제층을 형성함으로써 전사필름을 제조하였다. The coating solution (SSCP Samsung Chemicals / HD 100A-1) containing a urethane acryl monomer was coated on a polyester film by vacuum deposition at a temperature of 10 −4 Torr and a temperature of 400 ° C. Next, a coating liquid containing 15 wt% of acrylic resin and 5 wt% of cellulose (Cheongwoo Chemical K-1), a coating liquid containing 25 wt% of acrylic resin and 10 wt% of vinyl chloride copolymer (SK chemical / up056), MEK (Methyl Ethyl Ketone) ) The coating solution (Samyoung Ink / PVB) was sequentially coated by a gravure method to form a protective layer, a pattern printing layer, and a primer layer. Then, a transfer film was prepared by applying an adhesive to form an adhesive layer.

비교예Comparative example

상기 실시예에서 우레탄아크릴 모노머를 포함하는 코팅액을 진공증착하는 것을 제외하고, 실시예와 동일한 방법으로 전사필름을 제조하였다. A transfer film was prepared in the same manner as in Example, except that vacuum coating of the coating solution including the urethane acrylic monomer was performed.

실험예Experimental Example

상기 비교예 및 실시예에서 제조된 전사필름의 내지문성을 평가하기 위하여 손가락으로 필름을 가압하여 필름 표면에 지문의 흔적상태를 육안으로 관찰하였다. In order to evaluate the fingerprints of the transfer films prepared in Comparative Examples and Examples, the film was pressed with a finger to visually observe the traces of fingerprints on the film surface.

평가 결과 실시예의 전사필름에서는 지문을 전혀 관찰할 수 없었으나, 비교예에서는 지문 자국이 뚜렷이 나타났다.As a result of the evaluation, fingerprints could not be observed at all in the transfer film of Examples, but fingerprint marks were clearly seen in the comparative examples.

도1은 본 발명 전사필름의 단층 구조를 도시한 것이다.Figure 1 shows a single layer structure of the transfer film of the present invention.

<도면 부호에 대한 설명><Description of Drawing>

1- 전사 원단1- Warrior Fabric

2- 특수표면처리층2- special surface treatment layer

3- 보호처리층3- protective layer

4- 무늬인쇄층4-pattern printing layer

5- 프라이머층5- primer layer

6- 접착제층6- adhesive layer

Claims (11)

전사 인쇄에 의해 성형 가공물의 외장 코팅재의 형성에 사용되는 전사필름에 있어서 In the transfer film used for forming the exterior coating material of the molded product by transfer printing (a) 전사원단; (a) a transcriptional fabric; (b) 우레탄아크릴 모노머 72-86중량%, 실리카 10~20중량%, 멜라민 수지 3-5중량% 및 개시제 1~3중량%를 포함하는 조성물로부터 형성되는 특수표면처리층; 및(b) a special surface treatment layer formed from a composition comprising 72-86% by weight of a urethane acrylic monomer, 10-20% by weight of silica, 3-5% by weight of melamine resin and 1-3% by weight of an initiator; And (c) 아크릴 레진 20~30중량% 및 염화비닐코폴리머 10~20중량%을 포함하는 조성물로부터 형성되는 무늬인쇄층 및 접착제층을 포함하는 하드코팅층(c) a hard coating layer comprising a pattern printing layer and an adhesive layer formed from a composition comprising 20 to 30% by weight of acrylic resin and 10 to 20% by weight of vinyl chloride copolymer. 을 포함하는 것을 특징으로 하는 전사필름.Transfer film comprising a. 삭제delete 제 1 항에 있어서, 상기 하드코팅층은 보호처리층 및 프라이머층 중 선택되는 적어도 하나의 층을 포함하는 것을 특징으로 하는 전사필름.The transfer film of claim 1, wherein the hard coating layer comprises at least one layer selected from a protective layer and a primer layer. 제 1 항에 있어서, 상기 특수표면처리층은 50 내지 500Å의 두께인 것을 특 징으로 하는 전사필름.The transfer film of claim 1, wherein the special surface treatment layer has a thickness of 50 to 500 mm 3. 제 3 항에 있어서, 상기 보호처리층은 아크릴 레진 15~25중량%와 셀룰로오스 5~10중량%을 포함하는 조성물로부터 형성되며, 1～5㎛ 의 두께인 것을 특징으로 하는 전사필름.The transfer film of claim 3, wherein the protective layer is formed from a composition comprising 15 to 25 wt% of acrylic resin and 5 to 10 wt% of cellulose, and has a thickness of 1 to 5 μm. 제 3 항에 있어서, 상기 무늬인쇄층은 1~5㎛ 의 두께인 것을 특징으로 하는 전사필름.The transfer film of claim 3, wherein the pattern printing layer has a thickness of about 1 μm to about 5 μm. 제 3 항에 있어서, 상기 프라이머층은 MEK(Methyl Ethyl Ketone) 및 톨루엔으로부터 합성되는 수지 또는 폴리우레탄 계열의 수지로부터 형성되는 것을 특징으로 하는 전사필름.The transfer film of claim 3, wherein the primer layer is formed from a resin synthesized from MEK (Methyl Ethyl Ketone) and toluene or a resin of polyurethane series. 제 3 항에 있어서, 상기 접착제층으로 폴리염화비닐 및 아크릴레진을 유기용매에 희석킨 것을 사용하는 것을 특징으로 하는 전사필름.4. The transfer film according to claim 3, wherein polyvinyl chloride and acrylic resin are diluted in an organic solvent as the adhesive layer. 전사원단에 우레탄아크릴 모노머 72-86중량%, 실리카 10~20중량%, 멜라민 수지 3-5중량% 및 개시제 1~3중량%를 포함하는 조성물을 증착 또는 스퍼터링에 의해 특수표면처리층을 형성하고; A special surface treatment layer was formed by depositing or sputtering a composition comprising 72-86 wt% of urethane acrylic monomer, 10-20 wt% of silica, 3-5 wt% of melamine resin, and 1-3 wt% of initiator in the transfer fabric. ; 닙 코터(Nip Coater), 바 코터(Bar Coater) 또는 그라비아(Gravure) 코팅의 방법으로 아크릴 레진 20~30중량% 및 염화비닐코폴리머 10~20중량%을 포함하는 조성물로부터 형성되는 무늬인쇄층 및 접착제층을 포함하는 하드코팅층을 형성하여 제조되는 것을 특징으로 하는 전사필름의 제조방법.Patterned printing layer formed from a composition comprising 20-30% by weight of acrylic resin and 10-20% by weight of vinyl chloride copolymer by a method of nip coater, bar coater or gravure coating, and Method for producing a transfer film, characterized in that it is produced by forming a hard coat layer comprising an adhesive layer. 제 9항에 있어서, 상기 증착은 10-2 내지 10-6 토르의 진공 및　300 내지 800℃의 온도에서 진공증착시키는 것을 특징으로 하는 전사필름의 제조방법.10. The method of claim 9, wherein the deposition is carried out by vacuum deposition at a temperature of 10 -2 to 10 -6 Torr and a temperature of 300 to 800 ℃. 제 9항에 있어서, 상기 스퍼터링은 10-4 내지 10-8 토르의 진공하에 증착물을 이온화시켜 물리적 충격을 가하는 것을 특징으로 하는 전사필름의 제조방법.The method of claim 9, wherein the sputtering ionizes the deposit under a vacuum of 10 −4 to 10 −8 Torr to apply a physical impact.
KR1020080049096A 2008-05-27 2008-05-27 Transcribing film with finger mark-resisting and method of manufacturing the same KR101218264B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020080049096A KR101218264B1 (en) 2008-05-27 2008-05-27 Transcribing film with finger mark-resisting and method of manufacturing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020080049096A KR101218264B1 (en) 2008-05-27 2008-05-27 Transcribing film with finger mark-resisting and method of manufacturing the same

Publications (2)

Publication Number Publication Date
KR20090123156A KR20090123156A (en) 2009-12-02
KR101218264B1 true KR101218264B1 (en) 2013-01-03

Family

ID=41685435

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020080049096A KR101218264B1 (en) 2008-05-27 2008-05-27 Transcribing film with finger mark-resisting and method of manufacturing the same

Country Status (1)

Country Link
KR (1) KR101218264B1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101281833B1 (en) * 2010-11-30 2013-07-03 (주)엘지하우시스 Insert mold transcription film with lusterless hair-line pattern and method for fabricating the same
KR101733600B1 (en) 2014-07-07 2017-05-08 인스콘테크(주) Transferring films and the methods of making thereof
KR102119232B1 (en) * 2019-03-28 2020-06-05 이상규 Clothes having patterns printed with temperature activated color changing thermochromic paint, and printing methoed thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100486657B1 (en) * 2002-02-04 2005-05-03 서울화학(주) Heat transfer film directly transfered to low pressure melamine and high pressure melamine, and Manufacturing process thereof
KR20060089838A (en) * 2005-02-04 2006-08-09 삼성에스디아이 주식회사 Donor film for thin film transfer
JP2006306087A (en) * 2005-03-31 2006-11-09 Dainippon Printing Co Ltd Protective layer transfer sheet and printed matter

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100486657B1 (en) * 2002-02-04 2005-05-03 서울화학(주) Heat transfer film directly transfered to low pressure melamine and high pressure melamine, and Manufacturing process thereof
KR20060089838A (en) * 2005-02-04 2006-08-09 삼성에스디아이 주식회사 Donor film for thin film transfer
JP2006306087A (en) * 2005-03-31 2006-11-09 Dainippon Printing Co Ltd Protective layer transfer sheet and printed matter

Also Published As

Publication number Publication date
KR20090123156A (en) 2009-12-02

Similar Documents

Publication Publication Date Title
CN103303048B (en) Decoration transfer film and products formed
WO2008002042A1 (en) Transferring films, multilayered sheets and manufacturing methods thereof
KR101218264B1 (en) Transcribing film with finger mark-resisting and method of manufacturing the same
BRPI1007347B1 (en) ELEMENT IN FORM OF STONE PLATE OR REINFORCED NATURAL CONGLOMERATE AND PROTECTIVE COATING OF MULTIPLE LAYERS OF THE SAME, AND RESPECTIVE METHOD OF OBTAINING
KR200325627Y1 (en) Decorative transparent panel
KR200435526Y1 (en) Transparent decoration panels
KR101213258B1 (en) Plastic film for lamination having three-dimensional emboss effect and method for manufacturing the same
JP2012521476A (en) Hard coating composition, multilayer sheet using the same, and method for producing the same
KR100864572B1 (en) Scratch-resistant decoration sheet and method for manufacturing the same
KR102100028B1 (en) Uv-curable matt paint composition and coating film using the same
KR200211973Y1 (en) Transfer paper
KR100877184B1 (en) Manufacturing method of frinting film for insert molding
KR100968698B1 (en) Superior Scratchproof and Pollutionproof Surface Treatment and PVC Decoration Sheet Coated with Thereof
JP6260408B2 (en) Chimi design decorative veneer
JP2004299384A (en) Decorative sheet with protecting sheet and method for manufacturing decorative molding
JP2001001453A (en) Decorative material
JP4430555B2 (en) Nameplate working sheet body and method for producing the same
TW201231266A (en) Manufacturing method of functional thin film
KR102384870B1 (en) Eco-friendly surface materials with enhanced wear resistance by ceramic coating and their manufacturing method
JPH0232156B2 (en)
JP2009291961A (en) Decorative sheet
JP2014208431A (en) Transfer sheet and covering member prepared using the same
JP2001287324A (en) Decorative sheet
JP2002086658A (en) Decorative material
KR20100108043A (en) Protecting film for scattering, decorative glass panel comprising the same and preparing method thereof

Legal Events

Date Code Title Description
N231 Notification of change of applicant
A201 Request for examination
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20150923

Year of fee payment: 4

FPAY Annual fee payment

Payment date: 20170828

Year of fee payment: 6