KR101154562B1 - The solder, the semiconductor package and the method for manufacturing the same - Google Patents
The solder, the semiconductor package and the method for manufacturing the same Download PDFInfo
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- KR101154562B1 KR101154562B1 KR1020100084592A KR20100084592A KR101154562B1 KR 101154562 B1 KR101154562 B1 KR 101154562B1 KR 1020100084592 A KR1020100084592 A KR 1020100084592A KR 20100084592 A KR20100084592 A KR 20100084592A KR 101154562 B1 KR101154562 B1 KR 101154562B1
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- alloy layer
- layer
- solder
- lead
- copper
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/10—Bump connectors; Manufacturing methods related thereto
- H01L2224/12—Structure, shape, material or disposition of the bump connectors prior to the connecting process
- H01L2224/13—Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
Abstract
The present invention discloses a lead-free solder consisting of an alloy having a composition comprising up to 3.0 weight percent silver, 0.5 to 1 weight percent copper, and excess tin. Therefore, for the surface treatment of forming an electroless nickel alloy layer, a palladium alloy layer, and a gold alloy layer on a copper pad, the thickness of the metal bonding layer can be reduced by changing the composition of the solder, and cracks are formed in the solder rather than in the metal bonding layer. In order to prevent separation of the solder and the substrate.
Description
The present invention relates to a solder, a semiconductor package comprising the same, and a manufacturing method thereof.
The circuit board includes a circuit pattern on an electrically insulating substrate, and is a substrate for mounting electronic components or the like.
1 is a cross-sectional view of a conventional printed circuit board.
Referring to FIG. 1, a
The
The
Meanwhile, various surface treatment methods have been proposed to prevent oxidation and corrosion of the
The embodiment proposes a solder of a new semiconductor package.
The embodiment provides a semiconductor package and a method for manufacturing the same, including a solder having a strong adhesion with a new surface treatment layer.
The example proposes a lead-free solder consisting of an alloy having a composition comprising up to 3.0 wt% silver, 0.5 to 1 wt% copper, and excess tin.
On the other hand, the semiconductor package according to the embodiment is a printed circuit board including a pad and a circuit pattern, a metal layer including at least one layer on the pad, is attached on the metal layer, silver 3.0 wt% or less, copper 0.5 to 1 wt% or less And a lead-free solder made of an alloy having a composition including excess tin, and at least one semiconductor device mounted on the printed circuit board through the lead-free solder.
Meanwhile, the method of manufacturing a semiconductor package according to the embodiment may include preparing an insulating plate on which a circuit pattern and a pad are formed, and non-plating an alloy containing nickel on the circuit pattern or the pad to form the first metal layer. Step, non-plating an alloy containing palladium on the first metal layer to form a second metal layer, Non-plating an alloy containing gold on the second metal layer to form a third metal layer, Forming a lead-free solder comprising 3.0 wt% or less of silver, 0.5 to 1 wt% of copper, and excess tin on the metal layer, and reflowing and bonding the lead-free solder to the semiconductor device.
According to the present invention, with respect to the surface treatment of forming the electroless nickel alloy layer-palladium alloy layer-gold alloy layer on a copper pad, the thickness of the metal bonding layer can be reduced by changing the composition of the solder, and the cracks are formed in the metal bonding layer. It can occur in the solder and prevent separation of the solder and the substrate.
1 is a cross-sectional view of a conventional printed circuit board.
2 is a cross-sectional view of a semiconductor package according to an embodiment of the present invention.
3 through 10 are cross-sectional views illustrating a method for manufacturing the semiconductor package of FIG. 2.
FIG. 11 is a cross-sectional view illustrating the metal bonding layer formed in FIG. 10.
12a and 12b are cross-sectional views showing a metal bonding layer of the control group for the present invention.
FIG. 13 is a graph illustrating drop characteristics according to the composition of solder in the printed circuit board of FIG. 2.
14 is a photograph of a metal bonding layer according to each composition of FIG. 13.
DETAILED DESCRIPTION Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those skilled in the art may easily implement the present invention. The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.
Throughout the specification, when a part is said to "include" a certain component, it means that it can further include other components, without excluding other components unless specifically stated otherwise.
In order to clearly illustrate the present invention in the drawings, thicknesses are enlarged in order to clearly illustrate various layers and regions, and parts not related to the description are omitted, and like parts are denoted by similar reference numerals throughout the specification .
Whenever a portion of a layer, film, region, plate, or the like is referred to as being "on" another portion, it includes not only the case where it is "directly on" another portion, but also the case where there is another portion in between. On the contrary, when a part is "just above" another part, there is no other part in the middle.
The present invention provides a composition of a solder having excellent adhesion to a surface treatment for forming a non-electrolytic nickel alloy layer-palladium alloy layer-gold alloy layer on a copper base layer with respect to a circuit pattern.
Hereinafter, a semiconductor package according to an exemplary embodiment of the present invention will be described with reference to FIGS. 2 to 10.
2 is a cross-sectional view of a semiconductor package according to an embodiment of the present invention.
Referring to FIG. 2, the semiconductor package according to the embodiment of the present invention may include an
The
When the
The
A plurality of
The
The
The
The
A
The solder resist 140 protects the surface of the
The
The
The
In this case, the
As such, the semiconductor package which performs the surface treatment (ENEPIG: elctroless Ni, elctroless Pd, inversion Au) in which the nickel alloy layer-palladium alloy layer-gold alloy layer is stacked on the
Silver (Ag) constituting the lead-
Copper (Cu) constituting the lead-
Preferably, the
The lead-
Lead-
Hereinafter, a method of manufacturing the semiconductor package of FIG. 2 will be described with reference to FIGS. 3 to 10.
First, as shown in FIG. 3, the insulating
The conductive layer is etched to form the
Next, non-plating is performed on the patterned
The first plating layer 135 may be formed of an alloy of nickel (Ni) and phosphorus (P), and the first plating layer 135 may include 3 to 10 w% of phosphorus (P).
Next, as shown in FIG. 5, the first plating layer 135 is etched to cover the
Next, as shown in FIG. 7, a
The
In this case, the width of the window 185 may be larger than the width of the
The
In this case, before forming the
The
Next, as shown in FIG. 8, the
In this case, before forming the
The
Next, a lead-
The lead-
Finally, the
In the above description, the
A
Hereinafter, the formation of the metal bonding layer by reflow of the present invention and the control will be described with reference to FIGS. 11 to 12B.
FIG. 11 is a cross-sectional view illustrating the metal bonding layer generated in FIG. 10, and FIGS. 12A and 12B are cross-sectional views illustrating the metal bonding layer of the control group of the present invention.
As shown in FIG. 11, when a nickel alloy layer-palladium alloy layer-gold alloy layer is formed on the
Therefore, the
At this time, the
This metal junction forms a Cu 6 Sn 5 layer or a Cu 3 Sn 4 layer.
FIG. 12A illustrates a control (ENIG: ellectroless Ni, immersion Au) of the present invention, in which an electroless nickel alloy layer-gold alloy layer is formed on a
In this case, the
FIG. 12B is another control (OSP: organic solderability preservative) of the present invention, which is OSP-treated on a
Hereinafter, the drop impact test conducted on the semiconductor package of FIG. 11 will be described with reference to FIGS. 13 and 14.
Experimental Example 1
A flexible solder (Sn-Pb) containing tin and lead is applied to a substrate including a copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer, and the nickel alloy layer has a thickness of 3 μm and a palladium thickness of 0.03 μm, A semiconductor package in which the thickness of the gold alloy layer was 0.03 μm was prepared.
Experimental Example 2
A flexible solder (Sn-Pb) containing tin and lead is applied to a substrate including a copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer, and the nickel alloy layer has a thickness of 6 μm and a palladium thickness of 0.1 μm. A semiconductor package was prepared when the thickness of the alloy layer was 0.1 μm.
Experimental Example 3
A flexible solder (Sn-Pb) containing tin and lead is applied to a substrate including a copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer, and the nickel alloy layer has a thickness of 7 μm and a palladium thickness of 0.03 μm, A semiconductor package in which the thickness of the gold alloy layer was 0.03 μm was prepared.
Experimental Example 4
The thickness of the nickel alloy layer was applied to a substrate including a copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer by a lead-free solder (SAC305) containing 3% by weight of silver, 0.5% by weight of copper, and excess tin. The semiconductor package was produced when 3 micrometers, a palladium thickness is 0.03 micrometer, and a gold alloy layer thickness is 0.03 micrometer.
Experimental Example 5
The thickness of the nickel alloy layer was applied to a substrate including a copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer by a lead-free solder (SAC305) containing 3% by weight of silver, 0.5% by weight of copper, and excess tin. 6 micrometers, the palladium thickness is 0.1 micrometer, and the gold alloy layer thickness is 0.1 micrometer, The semiconductor package was produced.
Experimental Example 6
The thickness of the nickel alloy layer was applied to a substrate including a copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer by a lead-free solder (SAC305) containing 3% by weight of silver, 0.5% by weight of copper, and excess tin. The semiconductor package was produced when the thickness was 7 μm, the palladium thickness was 0.03 μm, and the gold alloy layer thickness was 0.03 μm.
Experimental Example 7
The thickness of the nickel alloy layer is applied to a substrate including a copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer by a lead-free solder (SAC302) containing 3% by weight of silver, 0.2% by weight of copper, and excess tin. The semiconductor package was produced when 3 micrometers, a palladium thickness is 0.03 micrometer, and a gold alloy layer thickness is 0.03 micrometer.
Experimental Example 8
The thickness of the nickel alloy layer is applied to a substrate including a copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer by a lead-free solder (SAC302) containing 3% by weight of silver, 0.2% by weight of copper, and excess tin. 6 micrometers, the palladium thickness is 0.1 micrometer, and the gold alloy layer thickness is 0.1 micrometer, The semiconductor package was produced.
Experimental Example 9
The thickness of the nickel alloy layer is applied to a substrate including a copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer by a lead-free solder (SAC302) containing 3% by weight of silver, 0.2% by weight of copper, and excess tin. The semiconductor package was produced when the thickness was 7 μm, the palladium thickness was 0.03 μm, and the gold alloy layer thickness was 0.03 μm.
Experimental Example 10
The lead-free solder (SAC1205) containing 1.2% by weight of silver, 0.5% by weight of copper, and extra tin was applied to the substrate including the copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer, and the thickness of the nickel alloy layer The semiconductor package was produced when 3 micrometers, a palladium thickness is 0.03 micrometer, and a gold alloy layer thickness is 0.03 micrometer.
Experimental Example 11
The lead-free solder (SAC1205) containing 1.2% by weight of silver, 0.5% by weight of copper, and extra tin was applied to the substrate including the copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer, and the thickness of the
Experimental Example 12
The lead-free solder (SAC1205) containing 1.2% by weight of silver, 0.5% by weight of copper, and extra tin was applied to the substrate including the copper base pad-nickel alloy layer-palladium alloy layer-gold alloy layer, and the thickness of the nickel alloy layer The semiconductor package was produced when the thickness was 7 μm, the palladium thickness was 0.03 μm, and the gold alloy layer thickness was 0.03 μm.
Experiment result
FIG. 13 is a graph showing drop impact characteristics according to solder composition in the printed circuit board of FIG. 2, and FIG. 14 is a photograph of metal bonding layers according to experimental examples.
The drop impact test was repeatedly performed to determine whether the semiconductor packages of Experimental Examples 1 to 12 were defective due to the impact generated by dropping the semiconductor packages toward the ground, specifically, cracks in the solder or metal bonding layer. The number of drops to be determined is shown in FIG.
As described above, the nickel alloy layer-palladium alloy layer-gold alloy layer formed on the copper base pad has a solder composition of SAC305, that is, 3 wt% silver, 0.5 wt% copper and extra tin regardless of the thickness of each layer. The eggplants were found to have the highest resistance to impact.
These values were observed higher than when the flexible solders of Experimental Examples 1 to 3 were formed, and as shown in FIGS. 12A and 12B, they showed higher suitability than nickel-gold plating or OSP treatment.
Referring to FIG. 14, in the surface treatment of the nickel alloy layer-palladium alloy layer-gold alloy layer, it can be seen that cracks are observed in the solder together with the case where the solder composition is SAC305.
Therefore, when cracks are generated in the metal bonding layer, such as SAC302, it is very vulnerable to dropping impact and the solder and the pad are separated. In the case of SAC1205, cracks are irregularly formed according to the thickness of the surface treatment layer, so that the reliability is high. It can be seen that it is not secured.
In the above experiments, when the surface treatment of the nickel alloy layer-palladium alloy layer-gold alloy layer is formed on the copper base pad as in the embodiment of the present invention, the solder is less than 3% by weight of silver, 0.5% by weight of copper and extra tin. In the case of the composition, it can be seen that the rigidity is the most excellent.
Although the embodiments of the present invention have been described in detail above, the scope of the present invention is not limited thereto, and various modifications and improvements of those skilled in the art using the basic concepts of the present invention defined in the following claims are also provided. It belongs to the scope of rights.
Printed
Claims (11)
Nickel alloy layer containing nickel on the pad,
A solder resist exposing the nickel alloy layer on an upper surface of the pad;
A palladium alloy layer formed on the exposed nickel alloy layer and extending to an upper surface of the solder resist;
A gold alloy layer formed on the palladium alloy layer and including gold,
A lead-free solder adhered to the gold alloy layer, the lead-free solder consisting of an alloy having a composition including not more than 3.0 wt% silver, 0.5-1 wt% copper, and excess tin, and
At least one semiconductor device mounted on the printed circuit board through the lead-free solder
Semiconductor package comprising a.
The nickel alloy layer is 1 to 10 μm,
The palladium alloy layer is 0.03 to 0.15μm, and
The gold alloy layer has a thickness that satisfies 0.03 to 0.15μm.
The nickel alloy layer, the palladium alloy layer and the gold alloy layer is formed by a non-plating semiconductor package.
The lead-free solder comprises 3.0 wt% silver, 0.5 wt% copper and extra tin.
Non-plating an alloy containing nickel on the circuit pattern or pad to form a first metal layer,
Forming a solder resist exposing the top surface of the first metal layer,
Non-plating an alloy including palladium on the exposed first metal layer and on the solder resist to form a second metal layer,
Non-plating an alloy containing gold on the second metal layer to form a third metal layer,
Forming a lead-free solder comprising less than or equal to 3.0 wt% silver, 0.5 to 1 wt% copper and excess tin on the third metal layer, and
Reflowing the lead-free solder to bond the semiconductor device
Method of manufacturing a semiconductor package comprising a.
The first to third metal layers are formed of an alloy with P (phosphorus), B (boron), W (tungsten) or Co (cobalt).
Wherein the lead-free solder comprises 3.0 weight percent silver, 0.5 weight percent copper and excess tin.
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