KR101019867B1 - The manufacturing method of a rubber chip with laminated color - Google Patents
The manufacturing method of a rubber chip with laminated color Download PDFInfo
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- KR101019867B1 KR101019867B1 KR1020100126115A KR20100126115A KR101019867B1 KR 101019867 B1 KR101019867 B1 KR 101019867B1 KR 1020100126115 A KR1020100126115 A KR 1020100126115A KR 20100126115 A KR20100126115 A KR 20100126115A KR 101019867 B1 KR101019867 B1 KR 101019867B1
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- rubber
- chip
- color
- manufacturing
- weight
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/04—Making preforms by assembling preformed material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/04—Making granules by dividing preformed material in the form of plates or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/02—Layered products comprising a layer of natural or synthetic rubber with fibres or particles being present as additives in the layer
Abstract
Description
The present invention is composed of a multi-layered rubber layer of various colors on one chip, according to the frequency and number of layers, the size of the chip shape, natural marble, oyster shell, rib shell, cloud, It is possible to produce a variety of patterns ranging from a parallel or flow-like pattern like a wood result, and because one type of color is formed separately on an existing chip, the color of the chip pattern rubber tile is different from the monotonous one. By forming several colors on the chip in multiple layers, it is possible to give the product a variety of colors and luxurious splendor, thereby enhancing the competitiveness in the domestic and overseas market, and based on various types of laminated color rubber chips based on rubber (synthetic rubber) Multi-layered rubber chips that can be applied to rubber tiles by coating or vulcanizing and kneading them with raw rubber A description of the production method.
In the conventional single-layered rubber tile, since the pattern is formed in one color on one chip, each chip has a sharp angle. The rubber tile has a rubber chip having a diameter of 1 mm or more. The shape is a polyhedron with sharp edges, and the rubber chips are monochromatic and coated with various colors of chips.
In addition, other conventional rubber tiles are sprayed with one or two colors of simple colored chips, the chips having a diameter of 1 mm or more, the shape of which is generally a polyhedron with sharp edges, and a little compared to general rubber tiles. It is gorgeous, but there is a limit in the variety of products, and compared to other flooring (PVC-based) is monotonous, there is a limit in the marketability of rubber tiles.
In addition, the appearance of the conventional rubber tile is a single color of the rubber, there is a spot pattern on the rubber, or sprayed by separating one or two kinds of chips of a simple color on a single color sheet or on the tile surface layer thereof. It was so simple that it could not increase its value.
Conventional rubber tiles are not provided with the functionality that can merely serve as a flooring material is a reality, and the surface of the rubber tile surface is often blurred or erased due to long friction.
In addition, Figure 1a is a view showing the color configuration of the conventional rubber chip, Figures 1b and 1c is a photograph showing that the rubber chip is formed on the surface of the conventional rubber tile, in the case of the conventional one type of color on one chip Since they are formed separately, there is a problem that the color of the chip pattern rubber tile is monotonous and the marketability is lowered.
Therefore, the rubber layer of various colors in one chip is composed of multiple layers according to the frequency, the number of layers, and the size of the chip, along with the field advertisement, such as natural marble, oyster shell, rib shell, cloud, wood grain Various patterns can be produced, ranging from parallel or flow-sensitive patterns. Since several colors are formed in multiple layers on one chip, it is possible to give a variety of colors and classy splendor to a product. Development of a method for manufacturing laminated color rubber chips that can be applied to rubber tiles by applying various types of laminated color rubber chips to base rubber (synthetic rubber) or kneading vulcanized chips with raw rubber There is a great demand.
The present invention has been conceived to solve the above problems, the rubber layer of various colors on one chip is composed of multiple layers according to the frequency and the number of layers and the size of the chip, with the natural color, natural natural three-dimensional The purpose is to provide a method of manufacturing laminated color rubber chips that can produce a variety of patterns, such as marble, oyster shell, rib shell, cloud, and wood-like patterns.
Another object of the present invention is that since one type of color is separately formed on an existing chip, the color of the chip pattern rubber tile is monotonous, so that several colors are formed in multiple layers on a single chip, thereby providing a color It is to provide a manufacturing method of laminated color rubber chips that can give diversity and classy splendor to enhance competitiveness in domestic and overseas markets.
Another object of the present invention is a method of manufacturing a laminated color rubber chip which can be applied to a rubber tile by applying various types of laminated color rubber chips to a base rubber (synthetic rubber) or kneading the vulcanized chip with raw rubber. To provide.
In the manufacturing method of the laminated color rubber chip according to a preferred embodiment of the present invention for achieving the above object, 3 to 5 parts by weight of zinc oxide, 1 to 3 parts by weight of anti-aging agent in 100 parts by weight of synthetic rubber (Synthetic rubber) , Kneader 100-300 parts by weight, 2-4 parts by weight of sulfur, 4-6 parts by weight of vulcanizing agent and vulcanizing aid, 2-4 parts by weight of plasticizer and softening agent, 1-10 parts by weight of color pigment, kneader mixer, short hair Blending and branding synthetic rubber to produce raw rubber by using any one of a mixer and a mixing roller; A sheet manufacturing step of manufacturing the branded raw rubber formed in each color into a sheet having a sheet shape of 1 to 10 mm using a roller or a calendar; Designing and manufacturing a multi-layered structure in which the sheets are stacked in two to fifteen kinds of colors according to the color order, and pressed into any one of a mixing roll, a calendar, an extruder, and a hydraulic press to produce a multilayer sheet; A pulverizing step using a pulverizer for crushing the multilayer sheet into a size of 1 mm to 15 mm to produce various patterns of a product using a pulverizer; Characterized in that it comprises a.
In the present invention, the synthetic rubber (Synthetic rubber) is styrene butadiene rubber (styrene butadiene rubber), nitrile-butadiene rubber (nitrile-butadiene rubber), ethylene propylene rubber (Ethylene Propylene Terpolymers), polybutadiene rubber (Polybutadiene rubber) ), Chloroprene rubber (Chloroplene rubber) is characterized in that any one or five kinds of mixed branding.
In the present invention, the pressure applied to the skin surface of the unvulcanized chip in the hydraulic press is 50 to 100 kg / ㎡, in the case of vulcanized chip is 100 to 200 kg / ㎡, in the case of vulcanized chip vulcanized press or continuous vulcanizer It is characterized by vulcanizing at 3 to 10 minutes at 100 to 200 ℃.
In the present invention, the appearance of the laminated color rubber chip is in the shape of tetrahedron to polyhedron, the laminated color is characterized in that the harmony of 2 to 15 kinds of colors.
The manufacturing method of the laminated color rubber chip according to the present invention has the following effects.
First, the present invention is composed of a multi-layered rubber layer of various colors on a single chip according to the frequency and number of layers, the size of the chip shape, natural marble, oyster shell, rib shell, A variety of patterns can be produced, ranging from parallel or flow-like patterns such as clouds and trees.
Second, since the present invention is formed by separately separating one type of color on a single chip, the color of the chip pattern rubber tile is monotonous. It can give a luxurious splendor and enhance competitiveness in domestic and overseas market.
Third, the present invention can be applied to rubber tiles by applying various types of laminated color rubber chips to a base rubber (synthetic rubber) or kneading the vulcanized chips with raw rubber.
Figure 1a is a view showing the color configuration of a conventional rubber chip.
Figure 1b and Figure 1c is a photograph showing that the rubber chip is formed on the surface of the conventional rubber tile, respectively.
2 is a flowchart illustrating a process of manufacturing a laminated color rubber chip according to an embodiment of the present invention.
3 is a view showing the color configuration of a laminated color rubber chip according to an embodiment of the present invention.
4 is a photograph showing a state in which a laminated color rubber sheet forming a laminated color rubber chip according to an embodiment of the present invention is placed on a roller;
FIG. 5 is a photograph showing a laminated color rubber chip sheet forming a laminated color rubber chip according to an embodiment of the present invention separated through a roller; FIG.
FIG. 6 is a photograph showing a state in which a laminated color rubber sheet forming a laminated color rubber chip according to an embodiment of the present invention is placed on a support frame to be pressed by a hydraulic press; FIG.
7a to 7c is a photograph showing that the laminated color rubber chip is formed on the surface of the rubber tile according to an embodiment of the present invention.
Looking at the preferred embodiment of the present invention together with the accompanying drawings as follows, when it is determined that the detailed description of the known art or configuration related to the present invention may unnecessarily obscure the subject matter of the present invention The description will be omitted, and the terms to be described below are terms defined in consideration of functions in the present invention, which may vary according to intentions or customs of users or operators, and the definitions describe the manufacturing method of the laminated color rubber chip according to the present invention. It should be made based on the contents throughout the specification.
Hereinafter, a method of manufacturing a laminated color rubber chip according to a preferred embodiment of the present invention will be described.
2 is a flowchart illustrating a process of manufacturing a laminated color rubber chip according to an embodiment of the present invention.
As shown in Fig. 2, the manufacturing method of the laminated color rubber chip is as follows.
The first step is blending and branding, 3 to 5 parts by weight of zinc oxide, 1 to 3 parts by weight of antioxidant, 100 to 300 parts by weight of filler, 2 to 4 parts by weight of sulfur, in 100 parts by weight of synthetic rubber 4 to 6 parts by weight of a vulcanizing agent and a vulcanizing agent, 2 to 4 parts by weight of a plasticizer and a softener, and 1 to 10 parts by weight of color pigments, and then branding the synthetic rubber with any one of a kneader mixer, a bandari mixer, and a mixing roller. To make.
Here, the raw rubber is pressed by a kneader mixer, a half-barrier mixer,
The Kneader mixer is a mixing machine similar to a short-barrier mixer. Like the rubber two-stage mixer, the machine is small and it depends on the specifications. The screw type and the cooling device are used up to 150 ℃. The rubber mixing is completed by mixing at high temperature and putting down the accelerator in the low temperature two-stage roller machine.
In addition, the Bnbary mixer is a mixing machine that mixes rubber dough compound, polyethylene, vinyl, EVA, resin, etc., by processing up to 180 ℃, the accelerator is mixed and processed in the Barbary mixer. Put the accelerator back on the 2nd roller and lower the work by adding accelerator at low temperature. The roller is screw type, and the cooling device and the thermometer are attached. Unlike the two-stage roller mixer, the roller is opened and opened at high temperature and mixed, so that there is no branch in the factory and the production process is large.
In addition, the rubber mixer two-stage mixing roller is a mixing down processing machine that passes through the primary gate in rubber production. The rotating ratio is 1: 125, and the rubber is rolled down and the compound is processed according to the slow rotation and the rear roll. It is an indispensable primary rubber processing machine in the rubber industry. For rubber down machining, 60 ° C is most suitable for the temperature of the roller.
The second step is a sheet manufacturing step, in which the branded raw rubber, which is formed in each color, is made into a sheet having a sheet shape of 1 to 10 mm using a
The third step is to design and manufacture in a multi-layered structure, each of the sheets are laminated in 2 to 15 kinds of colors according to the color sorting order by pressing any one of the mixing roll, calender, extruder, hydraulic press (50) It is made of a
The vulcanization (vulcanization) is a hardening operation by sulfur compounding of raw rubber, in which chain rubber molecules are entangled with each other to give rubber elasticity, thereby forming a three-dimensional network structure so that plastic deformation does not occur. In addition, the vulcanized rubber has a higher tensile strength, resists swelling and abrasion, and has a wider temperature range for maintaining elasticity. The simplest form of vulcanization is to heat the rubber with sulfur and accelerators.
The press vulcanization is achieved by supplying heat and pressure into the press. Press vulcanization consists of two or more plates that are pressed and detached by hydraulic pressure, and the hot plate is usually heated by steam or electricity. Rubber products are vulcanized in various types of molds between press plates. In its simplest form, the mold consists of two metal plates with a cavity that matches the appearance of the final product. Molded rubber products are removed from the mold and cooled to room temperature to shrink to a smaller size than the cavity. This mold shrinkage is due to the thermal contraction rate of the rubber, which is much larger than the metal shrinkage rate. The coefficient of thermal expansion of rubber is about 10 times that of metal. The coefficient of thermal expansion of the rubber compound is deeply related to the type and amount of fillers put into the raw material rubber, but the number of thermal expansion decreases as the amount of the filler is increased. In order to produce products with accurate dimensions, molds are made larger than actual products. Since most rubber compounds cause similar mold shrinkage, rubber products made from the same mold have almost similar dimensions.
In the continuous vulcanization method, the molding and vulcanization of the rubber compound are performed continuously in one process. Continuous vulcanization is typically used to produce extruded products, insulated wires, conveyor belts, flooring, and the like. There are several methods of continuous vulcanization, but the principle is largely the same. That is, the unvulcanized product moves along the vulcanized medium. Vulcanizing media include liquids, heated air, steam, microwaves, infrared rays, radiation, and the like. Continuous vulcanization with a liquid bath is called the Liquid Curing Method (LCM), where the extrudate passes through a liquid bath at a suitable temperature as soon as it exits the extruder. The temperature of the liquid bath is maintained at about 200 to 300 ℃, the heating medium is a salt mixture, polyglycol, silicone oil, metal alloy and the like. When vulcanizing a thin product, it is possible to pass it through a hot air tunnel or use a fluidized bed of small glass grains suspended in hot fluid air. The latter heat transfer effect is much greater. Flat products such as conveyor belts and flooring are continuously vulcanized in a rotaque method, which is pressed against a large heating drum that slowly rotates the material with a wide sheet of steel.
The fourth step is a pulverization step using a pulverizer, wherein the multilayer sheet is pulverized to a size of 1 mm to 15 mm to produce various patterns of the product by using a pulverizer. Here, the outer shape of the multi-layered multi-colored
3 is a view showing the color configuration of a laminated color rubber chip according to an embodiment of the present invention.
As shown in FIG. 3, the color configuration of the laminated
4 is a photograph showing a state in which a laminated color rubber sheet forming a laminated color rubber chip according to an embodiment of the present invention is placed on a roller, and FIG. 5 is a laminated color rubber chip according to an embodiment of the present invention. It is a photograph figure which shows the state which laminated | stacked color rubber sheet to form fell apart through a roller.
4 and 5, in order to form the laminated
FIG. 6 is a photograph showing a state in which a laminated color rubber sheet forming a laminated color rubber according to an embodiment of the present invention is placed on a support frame to be pressed by a hydraulic press. FIG.
As shown in FIG. 6, the laminated
7a to 7c is a photograph showing that the laminated color rubber chip is formed on the surface of the rubber tile according to an embodiment of the present invention.
As shown in Figure 7a to 7c, the laminated
The laminated color rubber chips are very diverse and can be applied to rubber tiles which are flooring materials in airports, terminals, subway platforms and aisles, railway stations, schools, hospitals, department stores, libraries, conference rooms, auditoriums, and churches. It is also useful for airport travel, hospital travel, flooring in department stores and shopping centers, and rubber tiles, flooring in auditoriums and churches, living rooms in apartments and verandas.
As described above, various substitutions, modifications, and changes can be made by those skilled in the art without departing from the technical spirit of the present invention, and thus, the embodiments and the accompanying drawings are limited. It doesn't happen.
10: laminated color rubber chip 20: rubber tile
30: laminated color rubber sheet 40: roller
50: hydraulic press 60: support frame
Claims (4)
3 to 5 parts by weight of zinc oxide, 1 to 3 parts by weight of antioxidant, 100 to 300 parts by weight of filler, 2 to 4 parts by weight of sulfur, vulcanizing agent and 4 to 6 parts by weight of synthetic rubber Blending 2 to 4 parts by weight of a plasticizer and a softener, and 1 to 10 parts by weight of color pigments, and then blending and branding the synthetic rubber with any one of a kneader mixer, a half-barrier mixer, and a mixing roller to make raw rubber;
A sheet manufacturing step of manufacturing the branded raw rubber formed in each color into a sheet having a sheet shape of 1 to 10 mm using a roller or a calendar;
Designing and manufacturing a multi-layered structure in which the sheets are stacked in two to fifteen kinds of colors according to the color order, and pressed into any one of a mixing roll, a calendar, an extruder, and a hydraulic press to produce a multilayer sheet;
A pulverizing step using a pulverizer for crushing the multilayer sheet to a size of 1 to 15 mm to produce various patterns of a product using a pulverizer; Method of manufacturing a laminated color rubber chip comprising a.
Synthetic rubber is a styrene butadiene rubber, nitrile-butadiene rubber, ethylene propylene rubber (Ethylene propylene terpolymers), polybutadiene rubber (polybutadiene rubber), chloroprene rubber ( Chloroplene rubber) any one or five types of mixed branding, characterized in that the manufacturing method of the laminated color rubber chip.
The pressure applied to the skin surface of the unvulcanized chip in the hydraulic press is 50 to 100 kg / ㎡, in the case of vulcanized chip is 100 to 200 kg / ㎡, in the case of vulcanized chip using a vulcanized press or continuous vulcanizer Method for producing a laminated color rubber chip, characterized in that the vulcanization at 3 ℃ to 10 minutes.
The outer shape of the laminated color rubber chip is tetrahedral to polyhedral, and the laminated color is a manufacturing method of the laminated color rubber chip, characterized in that the harmony of 2 to 15 kinds of colors.
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Citations (1)
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KR20050097667A (en) * | 2004-04-02 | 2005-10-10 | 주식회사 화승알앤에이 | A method for preparing rubber tile with various patterns using not-crosslinked rubber chips |
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KR20050097667A (en) * | 2004-04-02 | 2005-10-10 | 주식회사 화승알앤에이 | A method for preparing rubber tile with various patterns using not-crosslinked rubber chips |
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