KR101004657B1 - Coating for use on natural stone material to create solid beauty design and its manufacturing method - Google Patents
Coating for use on natural stone material to create solid beauty design and its manufacturing method Download PDFInfo
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- KR101004657B1 KR101004657B1 KR1020100061379A KR20100061379A KR101004657B1 KR 101004657 B1 KR101004657 B1 KR 101004657B1 KR 1020100061379 A KR1020100061379 A KR 1020100061379A KR 20100061379 A KR20100061379 A KR 20100061379A KR 101004657 B1 KR101004657 B1 KR 101004657B1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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Abstract
Description
본 발명은 천연석재 입체 질감 무늬형성 도료 및 그 제조방법에 관한 것으로, 더 상세하게는 일반 건축물의 사용 할 경우 소지면 부착력 증대와 강도를 부여하고, 휘발성 유기용제가 포함하지 않은 친환경 제품으로 도장 후, 화강석 무늬 또는 대리석과 같은 천연 석재의 무늬와 동시에 입체 질감을 부여 할 수 있도록 발명된 것이다.
The present invention relates to a natural stone three-dimensional texture pattern forming paint and a method for manufacturing the same, and more specifically, when using a general building gives increased surface adhesion and strength, and after painting with an environmentally friendly product that does not contain a volatile organic solvent, It is invented to give a three-dimensional texture at the same time as the pattern of natural stone, such as granite pattern or marble.
일반적으로, 아파트 저층부 특화부위, 빌라, 상가, 오피스텔 등 건축물의 내, 외면에 사용하는 주요자재는 의장성을 높여 고급스러운 느낌을 부여하는 천연석재, 인조대리석, 천연석과 유사한 색상 및 재질을 갖는 석재 뿜칠재, 수중유적형 또는 수중수적형 및 에멀젼 수적형 다채 무늬도료로 마감처리하고 있다.In general, the main materials used in the interior and exterior of the building, such as the specialized floor, apartments, villas, malls, officetels, etc., have natural colors, materials similar to those of natural stone, artificial marble, and natural stone that enhance the design. It is finished with spraying material, oil-in-water type or water-in-water type and emulsion-in-water colorful paint.
그러나, 천연석재 및 인조대리석은 시공비가 매우 많이 소요될 뿐만 아니라, 석재 뿜칠재의 경우 규사를 이용하여 재질감을 창출하는데 거친 표면으로 인체에 손상을 줄수 있다.However, natural stone and artificial marble not only takes a lot of construction cost, but in the case of stone fuming material, it can damage the human body with a rough surface to create a texture using silica sand.
게다가, 오염물질(황사, 먼지, 자동차배기)이 침착되어 내오염성이 취약하며, 수중유적형 다채 무늬도료는 유기용제 함량이 높아 냄새가 심하고, 외부에 사용 시 내후성이 떨어져 색상 변색(탈색)이 심하며, 접착력이 나쁘다는 단점이 있다.In addition, pollutants (yellow dust, dust, automobile exhaust) are deposited and are vulnerable to fouling resistance.The oil-in-water multicolored paint has a high organic solvent content and has a bad smell. It is severe and has the disadvantage of poor adhesion.
또, 수중수적형 및 에멀젼 수적형 다채 무늬도료는 유기용제 함량이 적어 냄새가 없으며, 친환경적인 장점은 있으나, 대리석 또는 화강석 질감 표현에 있어 근거리에서 시각적으로 볼 때 외관적인 무늬 형성은 유사하나, 입체 질감의 표현이 떨어지며 원거리서 외관은 단색 톤의 단조로움을 느끼는 단점이 있다.In addition, the water-in-water type and emulsion-in-water multicolored pattern paints are low in odor due to their low organic solvent content, and they have eco-friendly advantages. There is a drawback of feeling the monotony of monochromatic tone with the appearance of texture and the distance from the far.
그리고, 무늬형성을 위하여 두껍게 1회 스프레이 도장 시 접착력이 떨어지는 문제점도 있었다.In addition, there was a problem in that the adhesive strength is lowered when spraying once thick to form a pattern.
이러한 건축 내장재용 도료에 관련하여 국내 공개 특허공보 2007-0012273호에서는 천연 화강석 또는 대리석 무늬를 쉽고 자연스럽게 제조 및 도포할 수 있는 수용성 천연 화강석 또는 대리석 무늬 도료 조성물 도장 방법을 제안한 바 있었다.
Regarding such a paint for building interior materials, Korean Unexamined Patent Publication No. 2007-0012273 has proposed a water-soluble natural granite or marble pattern coating composition coating method that can easily and naturally produce and apply natural granite or marble pattern.
그러나, 국내 공개 특허공보 2007-0012273호에 알려진 도료는 시각적은 무늬 연출만 가능하며, 엠보싱 효과에 의한 입체 질감을 표현에는 한계가 있었다.However, the paint known in Korean Unexamined Patent Publication No. 2007-0012273 has only a visual appearance, and has a limitation in expressing three-dimensional texture by embossing effect.
또한 국내 공개특허공보 2007-0027155호에서도 에멀젼 수적형 다채무늬 도료로서 정형화된 5mm 이상의 입자 크기일 경우, 화강석 무늬 연출이 가능하다고 기술하고 있다.In addition, Korean Unexamined Patent Publication No. 2007-0027155 describes that it is possible to produce granite pattern when the particle size of 5mm or more that has been formulated as an emulsion droplet type colorful pattern paint.
그러나, 수성 졸에 색상제를 혼합 교반하면 색상제가 분산되면서 소정의 직경을 갖는 입자가 형성되기는 하나, 정형화된 즉 일정한 크기의 입자를 형성하기는 어렵다.However, mixing and stirring a colorant in an aqueous sol forms a particle having a predetermined diameter while the colorant is dispersed, but it is difficult to form a particle of regularized size.
또, 크고 작은 입자들이 혼합된 상태로 형성되며, 입자가 5-10mm 크기의 화강성 무늬를 형성하는 도료 또한 무늬 연출은 가능하지만, 엠보싱 효과에 의한 입체 질감을 표현에는 한계가 있었던 것이다. In addition, the large and small particles are formed in a mixed state, the particles to form a 5-10mm granular pattern is also possible to produce a pattern, but the three-dimensional texture by the embossing effect was limited.
본 발명은 상기와 같은 문제점을 해소하여 엠보싱 효과에 의한 입체 질감부여을 부여할 수 있도록 한 천연석재 입체 질감 무늬형성 도료을 제공하는데 있다.The present invention is to provide a natural stone three-dimensional texture pattern forming paint to solve the problems described above to impart a three-dimensional texture by the embossing effect.
본 발명의 다른 목적은 건축 자재의 소지면 부착력과 강도를 증대시키고, 중도 뿜칠자재 및 뿜칠자재 상도로 천연석재 무늬를 형성할 수 있도록 한 입체 질감 무늬형성 도료를 제공하는데 있다.Another object of the present invention is to provide a three-dimensional textured patterning paint to increase the surface adhesion and strength of the building material, and to form a natural stone pattern to the upper and middle materials.
본 발명의 또 다른 목적은 자연석의 색채와 질감 특성이 잘 나타나는 고품격의 마감 창출이 가능하며 또한 천연대리석 대비 원가 절감이 가능하고 내오염성, 내후성이 우수한 천연석재 입체 질감 무늬형성 도료을 제공하는데 있다.Still another object of the present invention is to provide a high-quality finish that exhibits the color and texture characteristics of natural stone, and also to reduce the cost of natural marble, and to provide a natural stone three-dimensional textured pattern forming paint having excellent pollution resistance and weather resistance.
본 발명의 또 다른 목적은 휘발성 유기용제가 포함하지 않은 친환경 제품으로 도장 후, 도장 그 두께가 1-3mm의 비교적 얇은 두께로 입체 질감을 부여 할 수 있는 입체 질감 무늬형성 도료를 제공하는데 있다.
Still another object of the present invention is to provide a three-dimensional textured patterning paint that can give a three-dimensional texture with a relatively thin thickness of 1-3mm after coating with an eco-friendly product that does not contain a volatile organic solvent.
이러한 본 발명의 목적을 달성하기 위한 도료 조성물은, 변성 아크릴 에멀젼 20 내지 40 중량부와, 물 10 내지 20 중량부, 규조토 5 내지 10 중량부, 셀룰로오스계 증점제 0.1 내지 5.0 중량부, 아크릴계 증점제 0.1 내지 5.0 중량부, 클레이 증점제 0.1 내지 5중량부, 분산제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 방균제 0.1 내지 2.0 중량부, 동결안정제 0.5 내지 5.0 중량부, 착색안료 0.5 내지 5 중량부 및 탄산칼슘 35 내지 40 중량부, 실리카 15 내지 20 중량부를 혼합하여 엠보 중도재와;The coating composition for achieving the object of the present invention, the modified acrylic emulsion 20 to 40 parts by weight, water 10 to 20 parts by weight, diatomaceous earth 5 to 10 parts by weight, cellulose thickener 0.1 to 5.0 parts by weight, acrylic thickener 0.1 to 5.0 parts by weight, clay thickener 0.1 to 5 parts by weight, dispersant 0.1 to 2.0 parts by weight, defoamer 0.1 to 2.0 parts by weight, preservative 0.1 to 2.0 parts by weight, antibacterial 0.1 to 2.0 parts by weight, freeze stabilizer 0.5 to 5.0 parts by weight, coloring 0.5 to 5 parts by weight of the pigment, 35 to 40 parts by weight of calcium carbonate and 15 to 20 parts by weight of silica are mixed with the embossed intermediate;
물 30 내지 40 중량부, 합성실리카계 증점제 0.1 내지 5.0 중량부, 변성 아크릴 에멀젼 40 내지 5 0 중량부, 분산 제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방균제 0.1 내지 2.0 중량부, 벤토 나이트계 증점제 0.1 내지 5.0 중량부, 셀룰로오스계 증점제 0.1 내지 5.0 중량부, 동결안정제 0.5 내지 5.0 중량부, 착색안료 0.5 내지 10 중량부(유기안료 및 무기안료) 및 체질안료(탄산칼슘) 5 내지 10 중량부를 포함하여 이루어지는 안료가 분산된 수용성 입자용 색상 페이스트와; 물 85 내지 95 중량부와 셀룰로오스계 증점제 0.1 내지 3.0 중량부와, 우레탄계 증점제 0.1 내지 3.0 중량부, 합성실리카계 증점제 1 내지 5.0 중량부, 피로인산소다 0.1 내지 1.0 중량부, 동결 안정제 0.5 내지 10.0 중량부, 방부제 0.1 내지 3.0 중량부, 방균제 0.1 내지 5.0 중량부 및 소포제 0.1 내지 3.0 중량부를 혼합하여 된 수용액에 안료가 분산된 수용성 입자용 페이스트를 균일하고 일정한 크기로 컷팅하여 된 상도부재로 이루어진다.30 to 40 parts by weight of water, 0.1 to 5.0 parts by weight of synthetic silica thickener, 40 to 50 parts by weight of modified acrylic emulsion, 0.1 to 2.0 parts by weight of dispersant, 0.1 to 2.0 parts by weight of preservative, 0.1 to 2.0 parts by weight of antifoam, room 0.1 to 2.0 parts by weight of fungicides, 0.1 to 5.0 parts by weight of bentonite thickeners, 0.1 to 5.0 parts by weight of cellulose thickeners, 0.5 to 5.0 parts by weight of freeze stabilizers, 0.5 to 10 parts by weight of pigmented pigments (organic pigments and inorganic pigments) and sieving A color paste for water-soluble particles in which a pigment comprising 5 to 10 parts by weight of a pigment (calcium carbonate) is dispersed; 85 to 95 parts by weight of water, 0.1 to 3.0 parts by weight of cellulose thickener, 0.1 to 3.0 parts by weight of urethane thickener, 1 to 5.0 parts by weight of synthetic silica thickener, 0.1 to 1.0 part by weight of sodium pyrophosphate, and 0.5 to 10.0 weight of freeze stabilizer It consists of a top coat member which is cut into a uniform and uniform size of a water-soluble particle paste in which a pigment is dispersed in an aqueous solution obtained by mixing parts, 0.1 to 3.0 parts by weight of an antiseptic agent, 0.1 to 5.0 parts by weight of an antiseptic agent, and 0.1 to 3.0 parts by weight of an antifoaming agent.
또, 천연석재 입체 질감 무늬형성 도료의 그 제조방법은, 변성 아크릴 에멀젼 20 내지 40 중량부와, 물 10 내지 20 중량부, 규조토 5 내지 10 중량부, 셀룰로오스계 증점제 0.1 내지 5.0 중량부, 아크릴계 증점제 0.1 내지 5.0 중량부, 클레이 증점제 0.1 내지 5중량부, 분산제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 방균제 0.1 내지 2.0 중량부, 동결안정제 0.5 내지 5.0 중량부, 착색안료 0.5 내지 5 중량부 및 탄산칼슘 35 내지 40 중량부, 실리카 15 내지 20 중량부를 혼합하여 엠보 중도재의 조성물을 제조하는 단계와;Moreover, the manufacturing method of the natural stone three-dimensional texture pattern forming paint, 20-40 weight part of modified acrylic emulsion, 10-20 weight part of water, 5-10 weight part of diatomaceous earth, 0.1-5.0 weight part of cellulose thickeners, acrylic thickener 0.1 to 5.0 parts by weight, clay thickener 0.1 to 5 parts by weight, dispersant 0.1 to 2.0 parts by weight, antifoaming agent 0.1 to 2.0 parts by weight, preservative 0.1 to 2.0 parts by weight, antibacterial 0.1 to 2.0 parts by weight, freeze stabilizer 0.5 to 5.0 parts by weight Preparing a composition of an embossed intermediate by mixing 0.5 to 5 parts by weight of colored pigment, 35 to 40 parts by weight of calcium carbonate, and 15 to 20 parts by weight of silica;
물 30 내지 40 중량부, 합성실리카계 증점제 0.1 내지 5.0 중량부, 변성 아크릴 에멀젼 40 내지 5 0 중량부, 분산 제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방균제 0.1 내지 2.0 중량부, 벤토 나이트계 증점제 0.1 내지 5.0 중량부, 셀룰로오스계 증점제 0.1 내지 5.0 중량부, 동결안정제 0.5 내지 5.0 중량부, 착색안료 0.5 내지 10 중량부(유기안료 및 무기안료) 및 체질안료(탄산칼슘) 5 내지 10 중량부를 포함하여 이루어지는 안료가 분산된 수용성 입자용 색상 페이스트 조성물의 제조하는 단계와;30 to 40 parts by weight of water, 0.1 to 5.0 parts by weight of synthetic silica thickener, 40 to 50 parts by weight of modified acrylic emulsion, 0.1 to 2.0 parts by weight of dispersant, 0.1 to 2.0 parts by weight of preservative, 0.1 to 2.0 parts by weight of antifoam, room 0.1 to 2.0 parts by weight of fungicides, 0.1 to 5.0 parts by weight of bentonite thickeners, 0.1 to 5.0 parts by weight of cellulose thickeners, 0.5 to 5.0 parts by weight of freeze stabilizers, 0.5 to 10 parts by weight of pigmented pigments (organic pigments and inorganic pigments) and sieving Preparing a color paste composition for water-soluble particles in which a pigment comprising 5 to 10 parts by weight of a pigment (calcium carbonate) is dispersed;
물 85 내지 95 중량부와 셀룰로오스계 증점제 0.1 내지 3.0 중량부와, 우레탄계 증점제 0.1 내지 3.0 중량부, 합성실리카계 증점제 1 내지 5.0 중량부, 피로인산소다 0.1 내지 1.0 중량부, 동결 안정제 0.5 내지 10.0 중량부, 방부제 0.1 내지 3.0 중량부, 방균제 0.1 내지 5.0 중량부 및 소포제 0.1 내지 3.0 중량부를 혼합하여 수용액을 제조하는 단계와;85 to 95 parts by weight of water, 0.1 to 3.0 parts by weight of cellulose thickener, 0.1 to 3.0 parts by weight of urethane thickener, 1 to 5.0 parts by weight of synthetic silica thickener, 0.1 to 1.0 part by weight of sodium pyrophosphate, and 0.5 to 10.0 weight of freeze stabilizer Preparing an aqueous solution by mixing 0.1 to 3.0 parts by weight of preservative, 0.1 to 5.0 parts by weight of antiseptic and 0.1 to 3.0 parts by weight of antifoaming agent;
상기 언급 된 수용액에 안료가 분산된 수용성 입자용 페이스트를 균일하고 일정한 크기로 컷팅하여 단계:Step by cutting the paste for water-soluble particles in which the pigment is dispersed in the above-mentioned aqueous solution to a uniform and uniform size:
상기 단계가 순차적으로 이루어지는 것에 의해 달성된다.
This step is accomplished by sequential steps.
이러한 본 발명에 의하면, 예로서 대리석 또는 화강석 등의 천연 석재와 같은 입체 질감 무늬를 형성하는 도료를 이용하여 도장 두께 1-3mm 엠보 형성에 따라서 입체 질감을 부여하여 자연석의 색채와 질감 특성이 잘 나타나는 고품격의 마감 창출이 가능하게 된다.According to the present invention, by using a paint forming a three-dimensional textured pattern, such as natural stone, such as marble or granite, for example, by applying a three-dimensional texture according to the coating thickness 1-3mm embossing, the color and texture characteristics of natural stone appear well High quality finishes can be created.
또한, 도료 작업에 의해 천연대리석 대비석과 같은 시각적 미감과 질감을 갖도록 하므로써 시공비 절감이 가능하고 천연석 채취로 인한 환경파괴를 줄이는 효과가 있다.
In addition, it is possible to reduce the construction cost by having a visual aesthetic and texture, such as natural marble contrast stone by the paint work and has the effect of reducing the environmental damage caused by natural stone collection.
도 1은 본 발명에 따른 엠보 중도재에 따른 도장 표면 상태의 사진.
도 2는 본 발명의 컷팅기를 보인 사진.
도 3은 크기 1-2mm의 비교적 작은 무늬가 형성된 표면 상태의 사진
도 4는 크기 3mm 이상의 비교적 큰 석재 무늬가 형성된 표면 상태의 사진.1 is a photograph of the coating surface state of the embossed middle material according to the present invention.
Figure 2 is a photograph showing a cutting machine of the present invention.
Figure 3 is a photograph of the surface state formed with a relatively small pattern of size 1-2mm
Figure 4 is a photograph of the surface state formed with a relatively large stone pattern of size 3mm or more.
이하, 본 발명의 바람직한 실시 예를 첨부된 도면에 의거하여 상세히 설명하면 다음과 같다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
본 발명은 천연석재의 엠보싱 효과에 의한 입체 질감을 부여하는 것으로 중도 뿜칠자재 도료 조성물(이하 엠보중도재)은 무늬형성 도료의 엠보 중도재로서 스프레이노즐 1-2 mm, 분사구경(팁) 4-8 mm 사용하여 분사압력 3-5gf/cm2으로 1회스프레이(내압식/본타일건) 도장하면 엠보싱이 있는 도막두께 1-3mm 형성 시키며 하지면과의 접착력이 우수하고, 천연석재의 강도를 부여하며, 상도 화강석 무늬 형성 도료와 층간 부착력도 증대시키게 된다.The present invention is to impart a three-dimensional texture by the embossing effect of the natural stone material to be sprayed material (hereinafter embossed material) is the embossed middle material of the pattern-forming paint spray nozzle 1-2 mm, spray nozzle (tip) 4- When using 8 mm spraying with spray pressure 3-5gf / cm 2 (pressure-resistant / bone tile gun), it forms 1-3mm of coating thickness with embossing. It also increases the adhesion between top coat and granite pattern forming paint.
그리고, 이에 본 발명에서는 변성 아크릴 에멀젼 20 내지 40 중량부와, 물 10 내지 20 중량부, 규조토 5 내지 10 중량부, 셀룰로오스계 증점제 0.1 내지 5.0 중량부, 아크릴계 증점제 0.1 내지 5.0 중량부, 클레이 증점제 0.1 내지 5중량부, 분산제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 방균제 0.1 내지 2.0 중량부, 동결안정제 0.5 내지 5.0 중량부, 착색안료 0.5 내지 5중량부 및 탄산칼슘 35 내지 40 중량부, 실리카 15 내지 20 중량부를 혼합하여 엠보중도재의 조성물을 제조하는 단계를 수행하게 된다. In the present invention, the modified acrylic emulsion 20 to 40 parts by weight, water 10 to 20 parts by weight, diatomaceous earth 5 to 10 parts by weight, cellulose thickener 0.1 to 5.0 parts by weight, acrylic thickener 0.1 to 5.0 parts by weight, clay thickener 0.1 To 5 parts by weight, 0.1 to 2.0 parts by weight of dispersant, 0.1 to 2.0 parts by weight of antifoaming agent, 0.1 to 2.0 parts by weight of preservative, 0.1 to 2.0 parts by weight of antiseptic agent, 0.5 to 5.0 parts by weight of freeze stabilizer, 0.5 to 5 parts by weight of pigmented pigment and 35 to 40 parts by weight of calcium carbonate and 15 to 20 parts by weight of silica are mixed to prepare a composition of the embossing material.
상기 변성 아크릴 에멀젼은 실리콘을 부가 중합시킨 수성 바인다로서 20 내지 25 중량부를 첨가하는 것이 소재와 부착성 증진, 내수성, 내후성이 우수하고, 충진제와 결합하여 강도를 증진 시키는 역할을 가장 바람직하게 수행하게 된다.The modified acrylic emulsion is an aqueous binder obtained by addition polymerization of silicone, and the addition of 20 to 25 parts by weight of the modified acrylic emulsion is excellent in improving adhesion to the material, water resistance, and weather resistance, and in combination with a filler to enhance strength. .
규조토(diatomite)는 낮은 밀도와 높은 공극률로 여과제, 흡수제, 도료첨가제, 연마제, 단열재(insulator) 등으로 여러 산업 분야에서 사용되는데, 특히 도료 첨가물로서 화학적으로 안정하기 때문에 색소들의 역할을 방해하지 않으며, 광택과 번쩍거림을 죽여주는 억제제로 사용된다. Diatomite is used in many industries as a filter, absorbent, paint additive, abrasive, insulator, etc. with low density and high porosity, especially because it is chemically stable as a paint additive and does not interfere with the role of pigments. It is used as an inhibitor to kill gloss and glare.
규조토의 공극률과 입자들의 큰 표면적은 도료가 건조 시, 표면을 조정하여 크랙(crack)방지하며, 규조토의 미묘한 구조가 도료 층간 접착력을 높이는 역할을 하는 것으로 5 내지 8중량부를 첨가하는 것이 바람직하다. The porosity of the diatomaceous earth and the large surface area of the particles control the surface when the paint is dried to prevent cracking, and it is preferable to add 5 to 8 parts by weight as the delicate structure of the diatomaceous earth serves to increase the adhesion between the paint layers.
셀룰로오스 증점제, 아크릴 증점제 및 클레이계 증점제는 일정한 입자크기의 엠보싱 형성에 중요한 역할을 하는 것으로써, 각각 그 첨가량이 0.1 중량부 미만일 경우에는 도료 조성물의 안정성이 떨어지고, 도장 시 흐름에 의해 도막의 품질이 떨어지는 문제점이 있으며, 그 첨가량이 1.0 중량부를 초과할 경우 도료 조성물의 점도가 너무 높아져 도장 시 작업성이 떨어지는 문제점이 있으므로 각각 0.1 내기 1.0 중량부를 첨가하는 것이 바람직하다.Cellulose thickeners, acrylic thickeners and clay thickeners play an important role in the embossing formation of a certain particle size. When the addition amount is less than 0.1 part by weight, the stability of the coating composition is deteriorated, and the quality of the coating film is improved by flow during coating. There is a problem that falls, if the addition amount exceeds 1.0 parts by weight, the viscosity of the coating composition is too high, there is a problem in the workability during coating, it is preferable to add 0.1 to 1.0 parts by weight, respectively.
석재 질감의 모양을 나태내기 위한 엠보싱 입체 질감의 형성을 좌우하는 충진제로서 역할을 하는 탄산칼슘은 그 첨가량이 30 중량부 미만일 경우에는 도료 조성물의 충진제로서 엠보 형성이 떨어지고, 40 중량부를 초과 할 경우 도막의 강도가 떨어지고, 스프레이 작업 시 작업성이 떨어져 균일한 엠보싱 형성이 어려우므로 35 내지 40 중량부를 첨가하는 것이 바람직하다.Calcium carbonate, which serves as a filler that influences the formation of the embossed three-dimensional texture to represent the shape of the stone texture, is less than 30 parts by weight of the embossing agent as a filler of the coating composition, and the coating film when the amount exceeds 40 parts by weight. It is preferable to add 35 to 40 parts by weight because the strength of the, and the workability during spraying is difficult to form a uniform embossing.
또한, 실리카는 도료에서 도막의 강도를 높여주고, 급격한 환경변화에 영향을 받지 않아 도료가 경화 후 긁힘과 충격에대한 저항을 강하게 만들어 내구성을 증가시키는 역할을 하는 것으로서 15 내지 20 중량부를 첨가 하는 것이 바람직하다. In addition, silica increases the strength of the coating film in the coating, and is not affected by a sudden environmental change, so that the coating increases the durability by increasing the resistance to scratches and impact after curing, and thus adding 15 to 20 parts by weight. desirable.
제조된 도료 조성물을 동절기 운송 및 보관 장소의 온도가 낮아지면 도료 조성물 내의 응집에 의한 침강 등이 발생하여 저장성이 낮아지게 되는데, 이를 방지하기 위하여 동결안정제가 첨가된다. When the temperature of the prepared coating composition is lowered during the winter transportation and storage place, sedimentation due to aggregation in the coating composition occurs and the storage property is lowered. In order to prevent this, a freeze stabilizer is added.
동결안정제는 주지된 에틸렌 글리콜을 사용할 수 있으며, 그 첨가량이 0.5중량부 미만일 경우 저온 보관성이 떨어지는 문제가 있으며, 그 첨가량이 5.0 중량부를 초과할 경우 건조시간이 길어지고 더 이상 증진 된 효과를 볼 수 없어 동결안정제는 0.5 내지 5.0 중량부 첨가하는 것이 바람직하다.The freeze-stabilizer can be used well-known ethylene glycol, when the addition amount is less than 0.5 parts by weight, there is a problem of low temperature storage properties, when the addition amount exceeds 5.0 parts by weight, the drying time is longer and further improved effect Since the freeze stabilizer can not be added 0.5 to 5.0 parts by weight is preferred.
엠보 중도재 제조 시 상기한 성분들 이외에 첨가되는 분산제, 착색안료, 방부제, 방균제 및 소포제는 당해분야에서 일반적으로 첨가되는 것으로서, 그 첨가량은 당해분야에서 사용되는 범위내로 첨가할 수 있으며, 본 발명에서는 분산제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 방균제 0.1 내지 2.0 중량부, 착색안료 0.5 내지 5.0 중량부를 사용하였다.Dispersing agents, coloring pigments, preservatives, antiseptics and antifoaming agents added in addition to the above components in the production of embossed intermediates are generally added in the art, the amount of the addition may be added within the range used in the art, the present invention In the dispersing agent 0.1 to 2.0 parts by weight, antifoaming agent 0.1 to 2.0 parts by weight, preservative 0.1 to 2.0 parts by weight, antibacterial 0.1 to 2.0 parts by weight, coloring pigments 0.5 to 5.0 parts by weight.
상기와 같이 제조된 엠보 중도재 조성물은 점도가 125 내지 140KU이며, 스프레이 노즐 1-2mm, 분사구경(팁) 4-8mm 사용하여 분사압력 3-5gf/cm2으로 1회 스프레이(내압식/본타일건)도장하면 엠보 질감이 있는 도막두께 1-3mm의 입체 질감 무늬형성도료를 얻을 수 있다. The embossed intermediate composition prepared as described above has a viscosity of 125 to 140 KU, sprayed once at a spray pressure of 3-5 gf / cm 2 using a spray nozzle 1-2 mm and a 4-8 mm spray nozzle (tip). Tile gun) can be used to obtain a three-dimensional textured pattern forming paint with an embossed coating thickness of 1-3mm.
만약 점도가 125KU 미만 일 경우, 도장 작업 시 수직면에 엠보싱을 형성 할 수 없고 3mm 도막 형성 시 흘러내리는 문제점이 있으며, 점도가 140KU 이상일 경우, 작업성이 떨어지는 문제가 있으므로 상기 범위의 점도를 갖도록 제조한다.If the viscosity is less than 125 KU, embossing can not be formed on the vertical surface during painting work, there is a problem that flows down when forming the 3mm coating film, if the viscosity is more than 140 KU, the workability is inferior problem is manufactured to have a viscosity in the above range. .
도 1은 본 발명의 엠보 중도재에 따른 도장 표면 상태의 사진을 보이고 있다.Figure 1 shows a photograph of the coating surface state according to the embossed middle material of the present invention.
한편, 중도wi 도장 후 화강석 또는 대리석 무늬를 형성하는 상도용 도료 조성물은 물 30 내지 40 중량부, 합성실리카계 증점제 0.1 내지 5.0 중량부, 변성 아크릴 에멀젼 40 내지 50 중량부, 분산제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방균제 0.1 내지2.0 중량부, 벤토나이트계 증점제 0.1 내지 5.0 중량부, 셀룰로오스계 증점제 0.1 내지 5.0 중량부, 동결안정제 0.5 내지 5.0 중량부, 착색안료 0.5 내지 10 중량부 및 체질안료(탄산칼슘) 5 내지 10 중량부를 포함하여 이루어지는 안료가 분산된 수용성 입자용 색상 페이스트 조성물의 제조하는 단계와;On the other hand, the coating composition for the top coat to form granite or marble pattern after the coating wi is 30 to 40 parts by weight of water, 0.1 to 5.0 parts by weight of synthetic silica thickener, 40 to 50 parts by weight of modified acrylic emulsion, 0.1 to 2.0 parts by weight of dispersant , 0.1 to 2.0 parts by weight of antiseptic, 0.1 to 2.0 parts by weight of antifoam, 0.1 to 2.0 parts by weight of antibacterial agent, 0.1 to 5.0 parts by weight of bentonite thickener, 0.1 to 5.0 parts by weight of cellulose thickener, 0.5 to 5.0 parts by weight of freeze stabilizer, coloring Preparing a color paste composition for water-soluble particles in which a pigment comprising 0.5 to 10 parts by weight of pigment and 5 to 10 parts by weight of extender pigment (calcium carbonate) is dispersed;
물 85 내지 95중량부와 셀룰로오스계 증점제 0.1 내지 3.0 중량부와, 우레탄계 증점제 0.1 내지 3.0 중량부, 합성실리카계 증점제 1 내지 5.0 중량부, 피로인산소다 0.1 내지 1.0 중량부, 동결 안정제 0.5 내지 10.0 중량부, 방부제 0.1 내지 3.0 중량부, 방균제 0.1 내지 5.0 중량부 및 소포제 0.1 내지 3.0 중량부를 혼합하여 수용액을 제조하는 단계와;85 to 95 parts by weight of water, 0.1 to 3.0 parts by weight of cellulose thickener, 0.1 to 3.0 parts by weight of urethane thickener, 1 to 5.0 parts by weight of synthetic silica thickener, 0.1 to 1.0 part by weight of sodium pyrophosphate, 0.5 to 10.0 weight of freeze stabilizer Preparing an aqueous solution by mixing 0.1 to 3.0 parts by weight of preservative, 0.1 to 5.0 parts by weight of antiseptic and 0.1 to 3.0 parts by weight of antifoaming agent;
상기 언급 된 수용액에 안료가 분산된 수용성 입자용 페이스트를 균일하고 일정한 크기로 커팅하여 제조하는 단계를 더 거치게 된다. It is further subjected to the step of preparing by cutting the paste for water-soluble particles in which the pigment is dispersed in the above-mentioned aqueous solution to a uniform and constant size.
여기서 상기 엠보 중도재 상도로 화강석 무늬 또는 대리석 무늬를 형성하는 도료 조성물은 수용액에 안료가 분산된 수용성 입자용 페이스트를 균일하고 일정한 크기로 컷팅하는 제조 단계가 중요하다.Here, the coating composition for forming a granite pattern or a marble pattern with the embossed intermediate material is an important manufacturing step of cutting the water-soluble particle paste in which the pigment is dispersed in an aqueous solution to a uniform and constant size.
수용성 입자용 색상 페이스트 제조 시 사용하는 변성 아크릴 에멀젼은 실리콘을 부가 중합시킨 수성바인다로서 부착력, 내후성, 내수성이 우수하며, 도막형성 조용제인 텍사놀(Texanol)을 사용하지 않아도 상온에서 도막이 형성되는 역할을 하는 것으로서, 40 내지 50 중량부를 첨가하는 것이 바람직하다.The modified acrylic emulsion used in the manufacture of color paste for water-soluble particles is an aqueous binder obtained by addition polymerization of silicone, and has excellent adhesion, weather resistance, and water resistance, and has a role of forming a coating film at room temperature without using Texanol, a coating film forming agent. It is preferable to add 40-50 weight part as it is.
수용성 입자용 색상 페이스트 제조 시 첨가되는 증점제로 본 발명에서는 합성실리카계 증점제 0.1 내지 5.0 중량부, 벤토나이트계 증점제 0.1 내지 5.0 중량부, 셀룰로오스계 증점제 0.1 내지 5.0 중량부를 사용하였다.In the present invention, 0.1 to 5.0 parts by weight of the synthetic silica thickener, 0.1 to 5.0 parts by weight of the bentonite thickener, and 0.1 to 5.0 parts by weight of the cellulose thickener were used as the thickener to be added when preparing the color paste for water-soluble particles.
이 증점제는 색상 페이스트의 점도 조절에 따라서 입자 형성 및 안정성에 중요한 역할을 하는 것으로서 각 증점제들의 첨가량이 상기 범위를 벗어 날 경우 수용액에 컷팅 시 입자 형성이 어렵고, 저장 중 안정성이 떨어져 입자가 수용액상에 풀리거나, 딱딱해져 스프레이 도장 시 문제가 발생되는 단점이 있어 상기 범위내에서 첨가하는 것이 바람직하다.This thickener plays an important role in the formation and stability of particles by controlling the viscosity of the color paste. If the amount of each thickener is out of the above range, it is difficult to form the particles when cutting into the aqueous solution, and the particles are difficult to form during storage. It is preferable to add it within the above range because there is a disadvantage that loosening or hardening causes problems during spray coating.
또한, 색상을 내기 위한 착색안료와 체질안료가 첨가된다. 여기서 착색안료나 체질안료는 당해분야에서 일반적으로 사용되는 것이며, 본 발명에서는 착색안료는 유기 및 무기안료를 둘다 포함하게 되는데 0.5 내지 10 중량부, 체질안료로 탄산칼슘 5.0 중량부 내지 10.0 중량부를 사용하였다. In addition, coloring pigments and extender pigments for coloring. Here, pigmented pigments or extender pigments are generally used in the art, and in the present invention, colored pigments include both organic and inorganic pigments, and 0.5 to 10 parts by weight and 5.0 to 10.0 parts by weight of calcium carbonate are used as extender pigments. It was.
필요에 따라서는 운모(Mica), 합성 펄, 알루미늄 페이스트 등 특수한 색감을 위하여 사용될 수 있으며, 이러한 것들은 1 내지 10 중량부 범위내에서 사용할 수 있다. If necessary, it may be used for a special color such as mica (Mica), synthetic pearl, aluminum paste, these can be used within the range of 1 to 10 parts by weight.
이외에 분산제, 소포제, 방부제, 방균제가 추가로 첨가되는데, 이러한 성분들은 당해 분야에서 일반적으로 사용되는 것이며, 당해분야의 통상의 첨가 범위 내에서 첨가하면 된다. In addition, dispersants, antifoams, preservatives, antibacterial agents are further added, these components are generally used in the art, and may be added within the usual range of addition in the art.
본 발명에서는 분산제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 방균제 0.1 내지 2.0 중량부를 사용하였다.In the present invention, 0.1 to 2.0 parts by weight of a dispersant, 0.1 to 2.0 parts by weight of antifoaming agent, 0.1 to 2.0 parts by weight of preservative, and 0.1 to 2.0 parts by weight of disinfectant were used.
상기와 같은 성분들을 물에 순차적으로 투입, 교반, 고속 분산의 과정을 거처 수용성 입자용 색상 페이스트가 제조된다.The color paste for water-soluble particles is prepared by sequentially adding such components to water, stirring, and high speed dispersion.
상기 언급된 수용성 입자용 색상 페이스트 제조와 별도로 본 발명에서는 물 85 내지 95중량부, 셀룰로오스계 증점제 0.1 내지 3.0 중량부와, 우레탄계 증점제 0.1 내지 3.0 중량부, 합성실리카계 증점제 1 내지 5.0 중량부, 피로인산소다 0.1 내지 1.0 중량부, 동결 안정제 0.5 내지 10.0 중량부, 방부제 0.1 내지 3.0 중량부, 방균제 0.1 내지 5.0 중량부 및 소포제 0.1 내지 3.0 중량부를 혼합하여 수용액을 제조하는 단계를 거치게 된다.Apart from the aforementioned color paste preparation for water-soluble particles, the present invention includes 85 to 95 parts by weight of water, 0.1 to 3.0 parts by weight of cellulose thickener, 0.1 to 3.0 parts by weight of urethane thickener, and 1 to 5.0 parts by weight of synthetic silica thickener, and fatigue. 0.1 to 1.0 parts by weight of sodium phosphate, 0.5 to 10.0 parts by weight of a freeze stabilizer, 0.1 to 3.0 parts by weight of preservative, 0.1 to 5.0 parts by weight of antiseptic and 0.1 to 3.0 parts by weight of antifoaming agent to prepare an aqueous solution.
수용액에 첨가되는 증점제는 입자용 색상 페이스트와 혼합 컷팅하는 과정에서 대리석, 화강성 무늬 형성 입자의 구형화 된 일정한 입자를 얻는데 중요한 역할을 하는 것으로서 셀룰로오스계 증점제 0.1 내지 3.0 중량부, 우레탄계 증점제 0.1 내지 3.0 중량부, 합성실리카계 증점제 1 내지 5.0 중량부를 사용하였다. The thickener added to the aqueous solution plays an important role in obtaining spherical and uniform particles of marble and granulated pattern forming particles in the process of mixing and cutting with the color paste for particles. Cellulose thickener 0.1 to 3.0 parts by weight, urethane thickener 0.1 to 3.0 By weight, 1 to 5.0 parts by weight of the synthetic silica thickener was used.
수용액 점도의 점도가 낮으면 색상 페이스트 컷팅 시 균일한 입자 형성이 어려우며, 입자가 서로 뭉쳐 안정성이 떨어지는 문제가 발생 되며, 수용액의 점도가 높을 경우에는 컷팅 시 1mm-2mm의 잘게 부서지는 입자가 많이 생겨 도장 시, 대리석 및 화강암과 같은 천연석의 무늬 표현에 문제가 발생되는 단점이 있어 상기 범위 내에서 첨가하는 것이 바람직하다.When the viscosity of the aqueous solution is low, it is difficult to form uniform particles when cutting the color paste, and the particles are agglomerated with each other, resulting in poor stability. When the viscosity of the aqueous solution is high, many finely broken particles of 1mm-2mm are generated when cutting. When painting, there is a disadvantage that a problem occurs in the representation of the natural stone, such as marble and granite, it is preferable to add within the above range.
본 발명에서는 수용액의 점도를 일정하게 유지 할 수 있도록 피로인산소다 0.1 내지 1.0 중량부를 사용하였다.In the present invention, 0.1 to 1.0 parts by weight of sodium pyrophosphate was used to maintain a constant viscosity of the aqueous solution.
피로인산소다는 수중에 가수분해 되어 제2피로인산나트륨으로 되며 합성실리카계 증점제의 양이온과 착염을 형성하여 수용액의 겔(gel)을 지연하는 역할을 하는 것으로서 상기 범위 내에서 첨가하는 것이 바람직하다.Sodium pyrophosphate is hydrolyzed in water to form a second sodium pyrophosphate, which forms a complex salt with a cation of a synthetic silica thickener to delay the gel of the aqueous solution and is preferably added within the above range.
수용액 제조 시 상기한 성분들 이외에 첨가되는 방부제, 방균제 및 소포제는 당해분야에서 일반적으로 첨가되는 것으로서, 그 첨가량은 당해분야에서 사용되는 범위내로 첨가할 수 있으며, 본발명에서는 동결 안정제 0.5 내지 10.0 중량부, 방부제 0.1 내지 3.0 중량부, 방균제 0.1 내지5.0 중량부 및 소포제 0.1 내지 3.0 중량부를 사용하였다.Preservatives, fungicides and antifoaming agents added in addition to the above components in the preparation of the aqueous solution is generally added in the art, the amount may be added within the range used in the art, in the present invention 0.5 to 10.0 wt. Part, 0.1 to 3.0 parts by weight of preservative, 0.1 to 5.0 parts by weight of antiseptic and 0.1 to 3.0 parts by weight of antifoaming agent were used.
상기와 같은 성분들을 물에 투입 혼합한 후 1시간-2시간 고속 교반(800rpm)하면 수용액이 제조된다.After mixing and mixing the above components in
전술한 단계에서 제조된 수용액 100 중량부에 수용성 입자용 색상 페이스트를 80 내지 130 중량부 투입하고 컷팅기(1)의 채(2)를 이용하여 컷팅하면 원형의 균일한 크기의 입자를 갖는 점도 70 내지 100KU의 화강석질감무늬도료를 제조 할 수 있다.80 to 130 parts by weight of the color paste for water-soluble particles is added to 100 parts by weight of the aqueous solution prepared in the above-described steps, and when the cutting is performed using the cutting machine 1 (2), the viscosity has a particle having a circular uniform size of 70 to Can produce 100KU granite textured paint.
수용액 100 중량부에 색상 페이스트가 80 중량부 미만인 경우에는 무늬 입자의 개수가 적고, 점도가 낮아 전체 도장 시 작업성이 불량하며, 130 중량부 이상 이면 입자 컷팅 시 무늬 입자는 형성하나 저장성 떨어져 수용액과 색상 페이스트의 비율은 상기 범위 내에서 제조함이 바람직하다.If the color paste is less than 80 parts by weight in 100 parts by weight of the aqueous solution, the number of pattern particles is small, and the viscosity is low, so workability is poor during the whole coating. The proportion of the color paste is preferably prepared within the above range.
컷팅기(1)는 도 2에서와 같이 적정한 입도를 갖는 채(2)가 용기내에 상하 구동 가능하게 설치되어, 수용액과 입자용 색상 페이스트가 용기(3)내에서 혼합된 상태에서 컷팅용 채(2)를 상하, 좌우로 다수회 수동 또는 동력에 의해 왕복시키는 것에 의해 컷팅되는 것이다.As shown in Fig. 2, the cutting
또한, 화강석 또는 대리석 무늬를 형성하는 도료 도장 방법으로는 도료 스프레이 장비를 사용하게 되는데 스프레이 노즐 1-2mm, 분사구경(팁) 2.5-3mm 사용하여 분사압력 3-4 gf/cm2으로 1-2회 압송식으로 스프레이 도장하는 것이 바람직하다.In addition, paint spraying equipment is used as a coating method for forming granite or marble pattern, using spray nozzle 1-2mm and spraying diameter (tip) 2.5-3mm to spray pressure 3-4 gf / cm 2 1-2 It is preferable to spray-coating by a pressure-feed type.
<엠보 중도재 조성물의 실시예 1><Example 1 of the embo intermediate material composition>
상기 제조 된 실시예 1 내지 4 와 비교예 1 내지 2 을 스프레이 노즐 1-2 mm, 분사구경(팁) 4-8 mm 사용하여 분사압력 3-5 gf/cm2 으로 1,200g/m2 되도록이 1회 스프레이(내압식/본타일건) 도장 시 입체 질감의 엠보싱이 형성되는 작업성 및 물성에 대하여 표 1에 나타내었다.Using the prepared Examples 1 to 4 and Comparative Examples 1 to 2, the spray nozzle 1-2 mm, the spray bore (tip) 4-8 mm using a spray pressure of 3-5 gf / cm 2 to 1,200 g / m 2 Table 1 shows the workability and physical properties in which the three-dimensional embossing is formed when spraying a single spray (pressure-resistant / bone tile gun).
상기 <표 1>에서와 같이 본 발명의 특징이 엠보 질감에 의한 입체감을 부여하여 석재와 같은 표면 질감을 나타내기 위하여 제조한 실시예의 경우 비교예에 비하여 엠보 형성이 양호하며, 표면상태가 부드러워 무늬형성 도료를 도장 시 화강석 및 대리석 질감 연출이 우수하다. As shown in <Table 1>, the embodiment of the present invention provides a three-dimensional effect by embossing texture to exhibit a surface texture such as stone, so that embossing is better than the comparative example, and the surface state is smooth. When painting the forming paints, the granite and marble textures are excellent.
그러나 실시예 1, 실시예 3, 실시예 4의 경우 본 발명의 범위를 벗어난 경우 표면강도가 약하고, 엠보형성이 불량하며, 도장 작업성이 떨어지는 것을 확인 할 수 있다.However, in the case of Examples 1, 3, and 4, it can be confirmed that the surface strength is weak, the embossing is poor, and the painting workability is poor when it is outside the scope of the present invention.
따라서, 본 발명의 천연석재(대리석/화강석) 입체 질감 무늬형성 도료 조성물 중 엠보 중도재 조성물은 <실시예 2>를 사용하였다. Therefore, <Example 2> was used for the embossed middle material composition of the natural stone (marble / granite) three-dimensional texture pattern forming coating composition of the present invention.
< 수용성 입자용 색상 페이스트 실시예 2><Color paste Example 2 for water-soluble particles>
상기 수용성 입자용 색상 페이스트의 색상 별 실시예 1 내지 4는 본 발명의 범위 내에서 수차례 실험에 의한 조성물이다. Examples 1 to 4 for each color of the color paste for water-soluble particles are compositions by several experiments within the scope of the present invention.
석재 색상 구현을 위한 조색은 실시예 1 내지 4 의 각 색상들의 혼합으로 다양한 색상의 페이스트를 제조 하였다.Toning for the color of the stone was prepared in a paste of various colors by mixing each of the colors of Examples 1 to 4.
< 수용액 실시예 ><Aqueous Solution Example>
상기 수용액 100 중량부에 소무늬(1-2mm)의 석재 무늬인 경우 색상 페이스트를 100중량부를 넣고 컷팅채로 컷팅하였으며, 큰무늬(3mm이상)인 경우에는 120중량부를 넣고 컷팅 하였다.100 parts by weight of a small pattern (1-2 mm) in the case of a stone pattern was cut into 100 parts by weight of the color paste, and cut in a cutting state, and in the case of a large pattern (3 mm or more), 120 parts by weight were cut.
그리고, 스프레이 장비를 사용하여 스프레이 노즐 1-2mm, 분사구경(팁) 2.5-3mm 사용하여 분사압력 3-4 gf/cm2으로 1-2회 스프레이(압송식)도장 하였다.Then, the spray equipment was sprayed 1-2 times at a spray pressure of 3-4 gf / cm 2 using a spray nozzle 1-2 mm and a spray diameter of 2.5-3 mm.
이러한 방법으로 도 3의 사진에서와 같이 1-2mm의 비교적 무늬가 작은 석재 무늬의 표면 상태로 가공할 수 있다.In this manner, as shown in the photograph of FIG. 3, the surface of the stone pattern having a relatively small pattern of 1-2 mm may be processed.
또, 도 4의 사진에서와 같이 3mm이상의 비교적 무늬가 큰 석재 무늬의 표면 상태로 가공할 수 있다.In addition, as shown in the photograph of FIG. 4, it can be processed to the surface state of the relatively large stone pattern of 3 mm or more.
따라서, 사진에서와 같이 표면에 엠보가 형성되어 마감재에 마치 실제 석재와 같은 입체 질감을 부여하여 자연석의 색채와 질감 특성이 잘 나타나는 고품격의 마감 창출이 가능하게 된다.Therefore, emboss is formed on the surface as shown in the photo to give the finishing material a three-dimensional texture as if it is a real stone, it is possible to create a high-quality finish that shows the color and texture characteristics of natural stone well.
또한, 천연대리석에 비하여 크게 원가를 절감시킬 수 있고, 천연석 채취로 인한 환경파괴를 줄이는 효과가 있는 것이다.
In addition, it is possible to greatly reduce the cost compared to natural marble, it is effective to reduce the environmental damage caused by natural stone harvesting.
1 - 컷팅기 2 - 채
3 - 용기1-cutter 2-pole
3-container
Claims (3)
물 30 내지 40 중량부, 합성실리카계 증점제 0.1 내지 5.0 중량부, 변성 아크릴 에멀젼 40 내지 5 0 중량부, 분산 제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방균제 0.1 내지 2.0 중량부, 벤토 나이트계 증점제 0.1 내지 5.0 중량부, 셀룰로오스계 증점제 0.1 내지 5.0 중량부, 동결안정제 0.5 내지 5.0 중량부, 착색안료 0.5 내지 10 중량부 및 체질안료 5 내지 10 중량부를 포함하여 이루어지는 안료가 분산된 수용성 입자용 색상 페이스트와; 물 85 내지 95 중량부와 셀룰로오스계 증점제 0.1 내지 3.0 중량부와, 우레탄계 증점제 0.1 내지 3.0 중량부, 합성실리카계 증점제 1 내지 5.0 중량부, 피로인산소다 0.1 내지 1.0 중량부, 동결 안정제 0.5 내지 10.0 중량부, 방부제 0.1 내지 3.0 중량부, 방균제 0.1 내지 5.0 중량부 및 소포제 0.1 내지 3.0 중량부를 혼합하여 된 수용액에 안료가 분산된 수용성 입자용 페이스트를 균일하고 일정한 크기로 컷팅하여 된 상도부재로 이루어 지는 것을 특징으로 하는 천연석재 입체 질감 무늬형성 도료.
20 to 40 parts by weight of modified acrylic emulsion, 10 to 20 parts by weight of water, 5 to 10 parts by weight of diatomaceous earth, 0.1 to 5.0 parts by weight of cellulose thickener, 0.1 to 5.0 parts by weight of acrylic thickener, 0.1 to 5 parts by weight of clay thickener, dispersant 0.1 to 2.0 parts by weight, antifoam 0.1 to 2.0 parts by weight, preservative 0.1 to 2.0 parts by weight, antibacterial 0.1 to 2.0 parts by weight, freeze stabilizer 0.5 to 5.0 parts by weight, coloring pigments 0.5 to 5 parts by weight and calcium carbonate 35 to 40 parts by weight Part, mixing 15 to 20 parts by weight of silica with the embossed middle material;
30 to 40 parts by weight of water, 0.1 to 5.0 parts by weight of synthetic silica thickener, 40 to 50 parts by weight of modified acrylic emulsion, 0.1 to 2.0 parts by weight of dispersant, 0.1 to 2.0 parts by weight of preservative, 0.1 to 2.0 parts by weight of antifoam, room 0.1 to 2.0 parts by weight of fungicides, 0.1 to 5.0 parts by weight of bentonite thickeners, 0.1 to 5.0 parts by weight of cellulose thickeners, 0.5 to 5.0 parts by weight of freeze stabilizers, 0.5 to 10 parts by weight of pigmented pigments and 5 to 10 parts by weight of extender pigments A color paste for water-soluble particles in which a pigment formed by the dispersion is dispersed; 85 to 95 parts by weight of water, 0.1 to 3.0 parts by weight of cellulose thickener, 0.1 to 3.0 parts by weight of urethane thickener, 1 to 5.0 parts by weight of synthetic silica thickener, 0.1 to 1.0 part by weight of sodium pyrophosphate, and 0.5 to 10.0 weight of freeze stabilizer It is made of a top member made by cutting a paste for dispersing water-soluble particles in a uniform and constant size in an aqueous solution obtained by mixing parts, 0.1 to 3.0 parts by weight, 0.1 to 5.0 parts by weight of antiseptic, and 0.1 to 3.0 parts by weight of antifoaming agent. Natural stone three-dimensional texture pattern forming paint, characterized in that.
물 30 내지 40 중량부, 합성실리카계 증점제 0.1 내지 5.0 중량부, 변성 아크릴 에멀젼 40 내지 5 0 중량부, 분산 제 0.1 내지 2.0 중량부, 방부제 0.1 내지 2.0 중량부, 소포제 0.1 내지 2.0 중량부, 방균제 0.1 내지 2.0 중량부, 벤토 나이트계 증점제 0.1 내지 5.0 중량부, 셀룰로오스계 증점제 0.1 내지 5.0 중량부, 동결안정제 0.5 내지 5.0 중량부, 착색안료 0.5 내지 10 중량부(유기안료 및 무기안료) 및 체질안료(탄산칼슘) 5 내지 10 중량부를 포함하여 이루어지는 안료가 분산된 수용성 입자용 색상 페이스트 조성물의 제조하는 단계와;
물 85 내지 95 중량부와 셀룰로오스계 증점제 0.1 내지 3.0 중량부와, 우레탄계 증점제 0.1 내지 3.0 중량부, 합성실리카계 증점제 1 내지 5.0 중량부, 피로인산소다 0.1 내지 1.0 중량부, 동결 안정제 0.5 내지 10.0 중량부, 방부제 0.1 내지 3.0 중량부, 방균제 0.1 내지 5.0 중량부 및 소포제 0.1 내지 3.0 중량부를 혼합하여 수용액을 제조하는 단계와;
상기 언급 된 수용액에 안료가 분산된 수용성 입자용 페이스트를 균일하고 일정한 크기로 컷팅하여 단계:
상기 단계가 순차적으로 이루어지는 것을 특징으로 하는 천연석재 입체 질감 무늬형성 도료 제조방법.
20 to 40 parts by weight of modified acrylic emulsion, 10 to 20 parts by weight of water, 5 to 10 parts by weight of diatomaceous earth, 0.1 to 5.0 parts by weight of cellulose thickener, 0.1 to 5.0 parts by weight of acrylic thickener, 0.1 to 5 parts by weight of clay thickener, dispersant 0.1 to 2.0 parts by weight, antifoam 0.1 to 2.0 parts by weight, preservative 0.1 to 2.0 parts by weight, antibacterial 0.1 to 2.0 parts by weight, freeze stabilizer 0.5 to 5.0 parts by weight, coloring pigments 0.5 to 5 parts by weight and calcium carbonate 35 to 40 parts by weight Part, mixing 15 to 20 parts by weight of silica to prepare a composition of the embossed middle material;
30 to 40 parts by weight of water, 0.1 to 5.0 parts by weight of synthetic silica thickener, 40 to 50 parts by weight of modified acrylic emulsion, 0.1 to 2.0 parts by weight of dispersant, 0.1 to 2.0 parts by weight of preservative, 0.1 to 2.0 parts by weight of antifoam, room 0.1 to 2.0 parts by weight of fungicides, 0.1 to 5.0 parts by weight of bentonite thickeners, 0.1 to 5.0 parts by weight of cellulose thickeners, 0.5 to 5.0 parts by weight of freeze stabilizers, 0.5 to 10 parts by weight of pigmented pigments (organic pigments and inorganic pigments) and sieving Preparing a color paste composition for water-soluble particles in which a pigment comprising 5 to 10 parts by weight of a pigment (calcium carbonate) is dispersed;
85 to 95 parts by weight of water, 0.1 to 3.0 parts by weight of cellulose thickener, 0.1 to 3.0 parts by weight of urethane thickener, 1 to 5.0 parts by weight of synthetic silica thickener, 0.1 to 1.0 part by weight of sodium pyrophosphate, and 0.5 to 10.0 weight of freeze stabilizer Preparing an aqueous solution by mixing 0.1 to 3.0 parts by weight of preservative, 0.1 to 5.0 parts by weight of antiseptic and 0.1 to 3.0 parts by weight of antifoaming agent;
Step by cutting the paste for water-soluble particles in which the pigment is dispersed in the above-mentioned aqueous solution to a uniform and uniform size:
Natural stone three-dimensional texture pattern forming paint manufacturing method characterized in that the step is made sequentially.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101089051B1 (en) | 2011-07-27 | 2011-12-02 | 미래피앤씨(주) | Composition for granite or marble multicolor paint with hectorite, it's manufacturing |
| KR101519404B1 (en) * | 2014-11-03 | 2015-05-13 | 유지씨 주식회사 | Building coating method using the composition and the composition born tile paint to prevent flow down |
| KR101645501B1 (en) | 2015-03-24 | 2016-08-04 | 충남대학교산학협력단 | Mortars Binder Composition Using Recycling Non-firing Binder |
| KR101700640B1 (en) | 2016-09-23 | 2017-01-31 | 미래피앤씨(주) | Manufacturing Method for Multi-Color Aqueous Paint Composition, Multi-Color Aqueous Paint Composition thereof and Coating Method Using the Same |
| KR102027084B1 (en) | 2019-03-08 | 2019-09-30 | 조원행 | Building wall surface finishing paint composition for forming multi-colored design of natural stone solid texture and method for preparing the same |
| KR102061446B1 (en) | 2019-03-08 | 2019-12-31 | 조원행 | Method for coating stone pattern paint using spray coating process |
| WO2020130694A1 (en) * | 2018-12-19 | 2020-06-25 | 주식회사 포스코 | Finishing materials for construction having stone patterned coating layer and manufacturing method for same |
| CN115725208A (en) * | 2021-08-30 | 2023-03-03 | 福建波普画材科技有限公司 | Pigment for art painting and preparation method thereof |
| KR102525587B1 (en) | 2023-01-25 | 2023-04-26 | 주식회사 위드디앤아이 | Coating composition for stone patternt and manufacturing method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20050024076A (en) * | 2003-09-04 | 2005-03-10 | 박성수 | Composition of multi-coloring paint having type of water in emulsion |
| KR100848812B1 (en) | 2008-03-04 | 2008-07-28 | (주)삼우종합건축사사무소 | Embossing paint composition of epoxy type without solvent and the constructing method thereof |
| KR100854445B1 (en) | 2007-03-20 | 2008-08-27 | (주)피티케이 | Method of multi-coloring paint composition of water in emulsion type for granite pattern and multi-coloring paint composition of water in emulsion type by the method |
-
2010
- 2010-06-28 KR KR1020100061379A patent/KR101004657B1/en not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20050024076A (en) * | 2003-09-04 | 2005-03-10 | 박성수 | Composition of multi-coloring paint having type of water in emulsion |
| KR100854445B1 (en) | 2007-03-20 | 2008-08-27 | (주)피티케이 | Method of multi-coloring paint composition of water in emulsion type for granite pattern and multi-coloring paint composition of water in emulsion type by the method |
| KR100848812B1 (en) | 2008-03-04 | 2008-07-28 | (주)삼우종합건축사사무소 | Embossing paint composition of epoxy type without solvent and the constructing method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101089051B1 (en) | 2011-07-27 | 2011-12-02 | 미래피앤씨(주) | Composition for granite or marble multicolor paint with hectorite, it's manufacturing |
| KR101519404B1 (en) * | 2014-11-03 | 2015-05-13 | 유지씨 주식회사 | Building coating method using the composition and the composition born tile paint to prevent flow down |
| KR101645501B1 (en) | 2015-03-24 | 2016-08-04 | 충남대학교산학협력단 | Mortars Binder Composition Using Recycling Non-firing Binder |
| KR101700640B1 (en) | 2016-09-23 | 2017-01-31 | 미래피앤씨(주) | Manufacturing Method for Multi-Color Aqueous Paint Composition, Multi-Color Aqueous Paint Composition thereof and Coating Method Using the Same |
| WO2020130694A1 (en) * | 2018-12-19 | 2020-06-25 | 주식회사 포스코 | Finishing materials for construction having stone patterned coating layer and manufacturing method for same |
| KR102027084B1 (en) | 2019-03-08 | 2019-09-30 | 조원행 | Building wall surface finishing paint composition for forming multi-colored design of natural stone solid texture and method for preparing the same |
| KR102061446B1 (en) | 2019-03-08 | 2019-12-31 | 조원행 | Method for coating stone pattern paint using spray coating process |
| CN115725208A (en) * | 2021-08-30 | 2023-03-03 | 福建波普画材科技有限公司 | Pigment for art painting and preparation method thereof |
| KR102525587B1 (en) | 2023-01-25 | 2023-04-26 | 주식회사 위드디앤아이 | Coating composition for stone patternt and manufacturing method thereof |
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