KR100900026B1 - Method of making the coated cloth that develops anion and far infrared ray and controls the proliferation of a house dust mite and is coated with composition of antistaticfunction - Google Patents

Method of making the coated cloth that develops anion and far infrared ray and controls the proliferation of a house dust mite and is coated with composition of antistaticfunction Download PDF

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KR100900026B1
KR100900026B1 KR1020080108934A KR20080108934A KR100900026B1 KR 100900026 B1 KR100900026 B1 KR 100900026B1 KR 1020080108934 A KR1020080108934 A KR 1020080108934A KR 20080108934 A KR20080108934 A KR 20080108934A KR 100900026 B1 KR100900026 B1 KR 100900026B1
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oxide
weight
fabric
coated
antistatic
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김성환
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김성환
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/16—Physical properties antistatic; conductive
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D10B2503/04—Floor or wall coverings; Carpets
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D10B2503/06—Bed linen
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00—Industrial
    • D10B2505/10—Packaging, e.g. bags

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

본 발명은 음이온과 원적외선 방사, 집먼지진드기 증식억제 및 대전방지 기능을 하는 코팅 원단에 있어서, 토르마린 2.00 중량%, 게르마늄 5.00 중량%, 대전방지제 5.00 중량%, 이산화티타늄 5.94 중량%, 산화란탄(La2O3) 1.20 중량%, 산화사마륨(Sm2O3) 0.6 중량%, 산화프라세오디뮴(Pr2O3) 1.5 중량%, 산화세륨(CeO2) 2.4 중량%, 산화지르코늄(ZrO2) 12.00 중량%, 산화철(Fe2O3) 0.06 중량%, 산화알루미늄(Al2O3) 0.30 중량%, 산화규소(SiO2) 3.00 중량%, PVC수지 55 중량%, 고령토 6 중량%가 포함된 혼합물이 베이스지의 표면에 코팅되는 것을 특징으로 하며, 실내 건축용 섬유류가 포함된 침구류, 매트, 시트커버, 장판, 각종 의류나 가방 등에 사용하여 대전방지효과와 실내공간에 증식하기 쉬운 집먼지진드기의 증식억제효과를 나타낼 수 있도록 한 것이다.The present invention is a coating fabric having an anion and far-infrared radiation, house dust mite growth inhibition and antistatic function, 2.00% by weight tourmaline, 5.00% by weight germanium, 5.00% by weight antistatic agent, 5.94% by weight titanium dioxide, lanthanum oxide (La 2 O 3 ) 1.20 wt%, samarium oxide (Sm 2 O 3 ) 0.6 wt%, praseodymium oxide (Pr 2 O 3 ) 1.5 wt%, cerium oxide (CeO 2 ) 2.4 wt%, zirconium oxide (ZrO 2 ) 12.00 wt% Base is a mixture containing 0.06% by weight of iron oxide (Fe 2 O 3 ), 0.30% by weight of aluminum oxide (Al 2 O 3 ), 3.00% by weight of silicon oxide (SiO 2 ), 55% by weight of PVC resin, 6% by weight of kaolin It is coated on the surface of the paper, and used for bedding, mats, seat covers, floor coverings, various clothes, bags, etc., which contain fibers for indoor construction, to prevent the antistatic effect and the growth inhibitory effect of house dust mites that are easy to proliferate in the indoor space. It is to be shown.

원적외선, 음이온, 대전방지, 원단, 집먼지진드기 Far infrared rays, negative ion, antistatic, fabric, house dust mite

Description

음이온과 원적외선 방사, 집먼지진드기 증식억제 및 대전방지 기능을 하는 코팅 원단의 제조방법{Method of making the coated cloth that develops anion and far infrared ray and controls the proliferation of a house dust mite and is coated with composition of antistaticfunction}Method of making the coated cloth that develops anion and far infrared ray and controls the proliferation of a house dust mite and is coated with composition of antistaticfunction }

본 발명은 음이온과 원적외선 방사, 집먼지진드기 증식억제 및 대전방지 기능을 하는 코팅 원단의 제조방법에 관한 것으로서, 토르마린 2.00 중량%, 게르마늄 5.00 중량%, 대전방지제 5.00 중량%, 이산화티타늄 5.94 중량%, 산화란탄(La2O3) 1.20 중량%, 산화사마륨(Sm2O3) 0.6 중량%, 산화프라세오디뮴(Pr2O3) 1.5 중량%, 산화세륨(CeO2) 2.4 중량%, 산화지르코늄(ZrO2) 12.00 중량%, 산화철(Fe2O3) 0.06 중량%, 산화알루미늄(Al2O3) 0.30 중량%, 산화규소(SiO2) 3.00 중량%, PVC수지 55 중량%, 고령토 6 중량%를 주재료로 하여 원적외선과 음이온을 동시에 방사하는 원단을 구성함으로써 인체에 착용하는 의류나 실내건축용 섬유류가 포함된 침구류 등으로부터 인체에 이로운 원적외선 및 음이온을 지속적으로 장시간 방사할 수 있도록 하고, 이산화티타늄을 포함하여 멸균효과를 가지는 동시에 대전방지효과를 제공하는 것이다.The present invention relates to a method for producing a coating fabric having an anion and far-infrared radiation, house dust mite growth inhibitory and antistatic function, tourmaline 2.00% by weight, germanium 5.00% by weight, antistatic agent 5.00% by weight, titanium dioxide 5.94% by weight, oxidation Lanthanum (La 2 O 3 ) 1.20 wt%, Samarium oxide (Sm 2 O 3 ) 0.6 wt%, Praseodymium oxide (Pr 2 O 3 ) 1.5 wt%, Cerium (CeO 2 ) 2.4 wt%, Zirconium oxide (ZrO 2 ) 12.00 wt%, iron oxide (Fe 2 O 3 ) 0.06 wt%, aluminum oxide (Al 2 O 3 ) 0.30 wt%, silicon oxide (SiO 2 ) 3.00 wt%, PVC resin 55 wt%, kaolin 6 wt% By constructing a fabric that emits far infrared rays and negative ions at the same time, it is possible to continuously radiate far infrared rays and negative ions, which are beneficial to the human body, for a long time from clothing worn on the human body or bedclothes containing fiber for indoor construction, and includes titanium dioxide. Sterilization effect The same time has to provide an antistatic effect.

음이온은 양이온을 경화 침전시켜 여러 가지 오염물질들을 제거하므로 공기 를 깨끗하게 하고 신선하게 유지시켜 준다. 숲속이나 폭포, 온천 등에서 인체에 상쾌함을 전달시켜 주는 것은 바로 음이온이다.Negative ions harden and precipitate cations to remove various contaminants, keeping the air clean and fresh. It is the anion that delivers freshness to the human body in forests, waterfalls, and hot springs.

원적외선은 적외선의 파장영역중에 4 ~ 1000 ㎛의 파장범위의 것을 지칭한다. 물질은 고유의 진동수로 끊임없이 운동하며, 입력되는 에너지의 진동수가 물질분자의 진동수와 일치하면 전자파를 흡수하고, 그 에너지에 의해 진동이 활성화되어 물질의 온도를 올리게 되는 것이다. 원적외선이 인체에 쪼였을 경우에 원적외선의 진동수가 물분자의 진동수와 매우 근접하기 때문에, 인체의 70%에 이르는 물 분자를 활성화시켜서 건강에 도움을 주는 것이다.Far infrared rays refer to those in the wavelength range of 4 to 1000 µm in the infrared wavelength range. The material constantly moves at its own frequency, and when the frequency of the input energy coincides with the frequency of the material molecule, the material absorbs electromagnetic waves, and the vibration is activated by the energy to raise the temperature of the material. When the far infrared rays hit the human body, the frequency of the far infrared rays is very close to the frequency of the water molecules, activating water molecules up to 70% of the human body to help health.

사람의 일상생활을 하고 있는 주변 환경에는 다양한 세균이 서식하고 있으며, 특히 의류나 침구로 사용되는 섬유의 경우에는 인체에서 분비되는 땀, 노폐물 등으로 인해서 세균 등의 서식이 유리한 환경을 제공하게 되고, 이에 따라 증식된 미생물은 천식이나 알레르기, 피부질환 등과 같은 인체에 치명적인 질병을 유발하기도 한다.A variety of bacteria inhabit the surrounding environment where people live daily life, and especially textiles used as clothing or bedding provide a favorable environment for the growth of bacteria due to sweat and waste products secreted by the human body. As a result, the multiplied microorganisms may cause fatal diseases such as asthma, allergies, and skin diseases.

특히, 집먼지진드기는 거미강, 진드기목에 속하는 절지동물의 한 종류로서 사람이 장시간 수면을 취하는 침대매트리스와 이불, 베개 등에 서식하며, 천식, 각종 알레르기 유발의 원인이 된다. 이러한 미생물, 집먼지진드기를 퇴치하기 위하여 원적외선을 방사하여 산업적으로 이용하려는 여러가지 시도가 행해지고 있다.In particular, the house dust mite is a kind of arthropod belonging to the arachnid, aphid, and inhabits bed mattresses, duvets, pillows, etc., which people sleep for a long time, and causes asthma and various allergens. In order to combat such microorganisms and house dust mites, various attempts have been made to radiate far infrared rays and use them industrially.

또한, 섬유류가 포함된 침구류, 매트 등에 사용에 있어서 마찰에 의해 정전기가 발생하는 데, 이를 방지하기 위한 다양한 방법이 논의되고 있다.In addition, electrostatics are generated by friction in use in bedding, mats, etc., including fibers, and various methods for preventing the same have been discussed.

본 발명은 인체에 착용하는 의류나 수면시 사용하는 침구류 등으로부터 음이온 및 원적외선이 방사되어 인체에 해로운 각종 미생물과 집먼지진드기 등의 증식을 억제하는 원단을 제공하는 것을 그 목적으로 한다.An object of the present invention is to provide a fabric that suppresses the growth of various microorganisms and dust mites harmful to the human body by the radiation of negative ions and far-infrared rays from the clothes worn on the human body or bedding used for sleep.

또한, 섬유류가 포함된 침구류, 매트 등에 사용에 있어서 마찰에 의해 발생하는 정전기 방지의 기능을 갖춘 원단을 제공하는 것을 목적으로 한다.It is also an object of the present invention to provide a fabric having an antistatic function caused by friction in use in beddings, mats, and the like in which fibers are contained.

한편, 광촉매인 이산화티타늄을 혼합하여 자외선을 쪼였을 경우 다양한 종류의 박테리아 등을 억제, 살균하는 원단을 제공하는 것을 목적으로 한다.On the other hand, it is an object of the present invention to provide a fabric that suppresses and sterilizes various kinds of bacteria when the ultraviolet light is mixed by mixing titanium dioxide which is a photocatalyst.

또한 은을 코팅시켜 은나노의 효과를 이용한 살균, 항균, 탈취의 기능을 갖춘 원단을 제공하는 것을 그 목적으로 하며, 촘촘한 망사직물 구조로 되어 있는 망사원단을 부착시켜 통풍으로 인한 항균, 탈취의 기능을 제공하는 것을 그 목적으로 한다.In addition, it aims to provide a fabric with functions of sterilization, antibacterial and deodorization by coating silver, and attaches a mesh fabric with a dense mesh fabric structure to prevent the function of antibacterial and deodorization due to ventilation. Its purpose is to provide.

토르마린 2.00 중량%, 게르마늄 5.00 중량%, 대전방지제 5.00 중량%, 이산화티타늄 5.94 중량%, 산화란탄(La2O3) 1.20 중량%, 산화사마륨(Sm2O3) 0.6 중량%, 산화프라세오디뮴(Pr2O3) 1.5 중량%, 산화세륨(CeO2) 2.4 중량%, 산화지르코늄(ZrO2) 12.00 중량%, 산화철(Fe2O3) 0.06 중량%, 산화알루미늄(Al2O3) 0.30 중량%, 산화규소(SiO2) 3.00 중량%, PVC수지 55 중량%, 고령토 6 중량%가 포함된 혼합물이 베이스지의 표면에 코팅된 원단을 특징으로 한다.Tourmaline 2.00 wt%, Germanium 5.00 wt%, Antistatic agent 5.00 wt%, Titanium dioxide 5.94 wt%, Lanthanum oxide (La 2 O 3 ) 1.20 wt%, Samarium oxide (Sm 2 O 3 ) 0.6 wt%, Praseodymium oxide (Pr 2 O 3 ) 1.5 wt%, cerium oxide (CeO 2 ) 2.4 wt%, zirconium oxide (ZrO 2 ) 12.00 wt%, iron oxide (Fe 2 O 3 ) 0.06 wt%, aluminum oxide (Al 2 O 3 ) 0.30 wt% , 3.00 wt% of silicon oxide (SiO 2 ), 55 wt% of PVC resin, and 6 wt% of kaolin is characterized by a fabric coated on the surface of the base paper.

또한, 상기 베이스지 하면에는 0.2 ~ 0.5cm 두께의 망사원단이 부착되고, 상기 혼합물이 코팅된 상면에는 입도 1 ~ 20nm인 은을 코팅시킨 것을 특징으로 한다.In addition, the bottom surface of the base is attached to a 0.2 ~ 0.5cm thick mesh fabric, characterized in that the upper surface coated with the mixture is coated with a silver particle size of 1 ~ 20nm.

또한, 토르마린 2.00 중량%, 게르마늄 5.00 중량%, 대전방지제 5.00 중량%, 이산화티타늄 5.94 중량%, 산화란탄(La2O3) 1.20 중량%, 산화사마륨(Sm2O3) 0.6 중량%, 산화프라세오디뮴(Pr2O3) 1.5 중량%, 산화세륨(CeO2) 2.4 중량%, 산화지르코늄(ZrO2) 12.00 중량%, 산화철(Fe2O3) 0.06 중량%, 산화알루미늄(Al2O3) 0.30 중량%, 산화규소(SiO2) 3.00 중량%, PVC수지 55 중량%, 고령토 6 중량%가 포함된 혼합물이 혼합되는 혼합공정과 상기 혼합된 조성물을 12,000 ∼ 20,000메쉬로 분쇄하는 분쇄공정과 상기 분쇄 혼합물에 상기 분쇄 혼합물 100중량부 대비 증점제 4 중량부를 투입하여 겔상태로 형성하는 겔형성공정과 상기 겔상태 혼합물을 롤러를 통해 베이스지에 전사하는 전사공정과 상기 혼합물이 전사된 상면에 입도 1 ~ 20nm인 은을 침투시키는 침투공정과 상기 은이 침투된 원단을 100 ~ 130℃의 온도로 약 10분간 건조하는 건조공정과 상기 베이스지 하면에 0.2 ~ 0.5cm 두께의 망사원단이 부착되는 공정으로 이루어짐을 특징으로 한다.In addition, tourmaline 2.00%, germanium 5.00%, antistatic agent 5.00%, titanium dioxide 5.94% by weight, lanthanum oxide (La 2 O 3 ) 1.20% by weight, samarium oxide (Sm 2 O 3 ) 0.6% by weight, praseodymium (Pr 2 O 3 ) 1.5 wt%, cerium oxide (CeO 2 ) 2.4 wt%, zirconium oxide (ZrO 2 ) 12.00 wt%, iron oxide (Fe 2 O 3 ) 0.06 wt%, aluminum oxide (Al 2 O 3 ) 0.30 A blending process comprising a mixture containing a weight%, silicon oxide (SiO 2 ) 3.00% by weight, 55% by weight of PVC resin, 6% by weight of kaolin and a grinding step of grinding the mixed composition to 12,000 ~ 20,000 mesh and the grinding 4 parts by weight of a thickener based on 100 parts by weight of the pulverized mixture is added to the mixture to form a gel, a transfer process of transferring the gel mixture to a base paper through a roller, and a particle size of 1 to 20 nm on the upper surface of the mixture. Penetration process for penetrating phosphorus silver and the fabric penetrating the silver If not at a temperature of 100 ~ 130 ℃ drying process and the base to dry for approximately 10 minutes characterized by constituted by any process which is attached a mesh fabric of 0.2 ~ 0.5cm thick.

본 발명은 인체에 착용하는 의류나 수면시 사용하는 침구류 등으로부터 음이온 및 원적외선이 방사되어 인체에 해로운 각종 미생물과 집먼지진드기 등의 증식을 억제하는 원단을 제공하는 장점이 있다.The present invention has the advantage of providing a fabric that suppresses the growth of various microorganisms and dust mites harmful to the human body by the radiation of negative ions and far infrared rays from clothing worn on the human body or bedding used during sleep.

또한, 섬유류가 포함된 침구류, 매트 등에 사용에 있어서 마찰에 의해 발생하는 정전기 방지의 기능을 갖춘 원단을 제공하는 장점이 있다.In addition, there is an advantage to provide a fabric having an antistatic function caused by friction in use in bedding, mats, and the like containing fibers.

한편, 광촉매인 이산화티타늄을 혼합하여 자외선을 쪼였을 경우 다양한 종류의 박테리아 등을 억제, 살균하는 원단을 제공하는 장점이 있다. On the other hand, there is an advantage in providing a fabric that suppresses and sterilizes various kinds of bacteria when the ultraviolet ray is mixed by mixing titanium dioxide as a photocatalyst.

또한 본 발명은 은을 코팅시켜 은나노의 효과를 이용한 살균, 항균, 탈취의 기능을 갖춘 원단을 제공하는 장점이 있으며, 촘촘한 망사직물 구조로 되어 있는 망사원단을 부착시켜 통풍으로 인한 항균, 탈취의 기능을 제공하는 장점이 있다.In addition, the present invention has the advantage of providing a fabric having a function of sterilization, antibacterial, deodorization by using the effect of silver nano coating, the function of antibacterial, deodorization due to the ventilation by attaching a mesh fabric of a dense mesh fabric structure There is an advantage in providing.

이하, 본 발명을 조성하는 각 성분에 대해 상세히 설명한다.Hereinafter, each component which comprises this invention is demonstrated in detail.

토르마린(Tourmaline)은 6각 주상형의 결정을 갖는 붕규산염으로 토르마린의 결정은 미약 전류를 계속 발생시키므로, 이 토르마린 결정은 공기 중에 포함된 수분(H2O)에도 작용하여 물분자를 전기분해시키고 물분자(H2O)를 수소이온(H+)과 수산이온(OH-)로 분리시켜 음이온을 만든다.Tourmaline is a borosilicate that has hexagonal columnar crystals, and the tourmaline crystals continue to generate a weak current.The tourmaline crystals also act on the water (H 2 O) contained in the air to electrolyze the water molecules. Water molecules (H 2 O) are separated into hydrogen ions (H +) and hydroxyl ions (OH −) to form anions.

게르마늄은 반도체로 전기적 광학적 성질을 갖고 있으며, 방사하는 원적외선의 온열효과와 자율신경계의 균형유지 및 혈액순환과 신진대사를 촉진시키고 전자파의 차단과 정전기방지효과를 가진다.Germanium is a semiconductor with electrical and optical properties. It has the effect of radiating far-infrared rays, balancing the autonomic nervous system, promoting blood circulation and metabolism, and blocking electromagnetic waves and preventing static electricity.

대전방지제는 아데카 코리아의 DW A-시리즈를 사용하였다. 이 제품은 고무, 수지 등에 적용가능한 다목적 대전방지제로서 DMLA(Dimethyl Laurylamine), Ammonium salt 및 GMS(Glycerine Monostearate) 등의 도전성폴리머 또는 금속염이 하나 이상 포함되어 구성된 무색의 액체이다. 상기와 같은 대전방지제 5 중량%를 첨가하여 원단에 뛰어난 대전방지성, 내구성, 열 안정성의 효과를 부여하는 것이 바람직하다. 5 중량%미만을 첨가하면 내구성과 지속성이 떨어지는 단점이 있고, 5 중량%이상을 사용하면 대전방지 효과가 더 이상 향상되지 않는 단점이 있다. The antistatic agent used was Adeka Korea's DW A-Series. This product is a multi-purpose antistatic agent applicable to rubber, resin, etc. It is a colorless liquid composed of one or more conductive polymers or metal salts such as DMLA (Dimethyl Laurylamine), Ammonium salt and Glycerine Monostearate (GMS). By adding 5% by weight of the antistatic agent as described above, it is preferable to give the fabric an effect of excellent antistatic property, durability, and thermal stability. If the addition of less than 5% by weight has the disadvantage of poor durability and durability, the use of more than 5% by weight has the disadvantage that the antistatic effect is no longer improved.

이산화티타늄은 화학적인 반응성이 거의 없어 인체에 무해하므로 화장품이나 그림물감, 완구의 도료, 식품의 포장용기, 도자기의 유약, 비누 또는 인쇄잉크의 원료, 수정액 등의 주원료로 널리 이용되고 있으며, 특히 공기정화, 오염물 제거 등에 있어서 탁월한 효과를 나타내는 광촉매로 각광받고 있다. 이러한 이산화티타늄에 자외선을 쪼이면 다양한 종류의 박테리아와 유해균을 살균하는 효과를 가진다. Since titanium dioxide has little chemical reactivity and is harmless to the human body, it is widely used as a main raw material for cosmetics, paints, paints for toys, food containers, ceramic glazes, soap or printing ink raw materials, and correction liquids. It has been spotlighted as a photocatalyst which exhibits an excellent effect in purification, removal of contaminants, and the like. When ultraviolet rays are irradiated on the titanium dioxide, it has the effect of sterilizing various kinds of bacteria and harmful bacteria.

산화란탄(La2O3), 산화사마륨(Sm2O3), 산화프라세오디뮴(Pr2O3), 산화세륨(CeO2)은 희토류 금속산화물로서 그들의 원자구조 특이성으로 인해서 광학적, 자기적 성질을 가진다.Lanthanum oxide (La 2 O 3 ), samarium oxide (Sm 2 O 3 ), praseodymium oxide (Pr 2 O 3 ), and cerium oxide (CeO 2 ) are rare earth metal oxides, which have optical and magnetic properties due to their atomic structure specificities. Have

희토류 금속은 주기율표 제3A족인 스칸듐, 이트륨 및 원자번호 57에서 71인 란탄계열의 15원소를 합친 17원소의 총칭을 말한다. 란탄계열 원소 중 란탄늄을 제외한 세륨 이하의 14원소는 란탄족으로 총칭된다. 또 란탄늄에서 사마륨까지의 6원소를 세륨족 원소, 유로퓸에서 루테튬까지 원소, 이트륨, 및 스칸듐을 합친 11원소를 이트륨족 원소라고 한다. 이러한 원소는 모두 희유원소에 속하며, 프로메튬은 방사성원소(放射性元素)로 안정 동위원소(同位元素)는 존재하지 않는다. 원자번호가 홀수인 것은 짝수인 것에 비해 존재량이 적으며,일반적으로 은백색 또는 회색 금속이다. 또한, 공기 중에서 서서히 산화하며, 산 및 뜨거운 물에는 녹지만 알칼리에는 녹지 않고, 화학적 성질은 아주 비슷하며, 보통 모두 ＋3가의 화합물을 만드는데, 세륨, 테르븀, 프라세오디뮴에서는 ＋4가, 이테르븀, 유로퓸, 사마륨에서는 ＋2가도 있다. 알칼리금속과 알칼리토금속에 이어 양성(陽性)이 현저하고, 수산화물은 염기이다.Rare earth metal is a generic term for 17 elements in which scandium, yttrium of Group 3A of the periodic table and 15 elements of the lanthanide series of atomic numbers 57 to 71 are combined. Of the lanthanide-based elements, 14 elements of cerium or less except for lanthanum are collectively referred to as lanthanides. Moreover, the 11 element which combined six elements from lanthanum to samarium, the element from cerium group, the element from europium to lutetium, yttrium, and scandium is called yttrium group element. All of these elements belong to rare elements, and promethium is a radioactive element, and there is no stable isotope. Odd atomic numbers are less present than even and are usually silver white or gray metal. It also oxidizes slowly in the air, soluble in acids and hot water but insoluble in alkalis, and having very similar chemical properties, usually all of which produce + trivalent compounds. There is also +2. Following alkali metals and alkaline earth metals, the positiveness is remarkable, and the hydroxide is a base.

지르코늄(Zr)은 주기율표 상에서 티탄족에 속하는 제5주기의 전이금속으로 산과 알칼리에 극히 높은 내식성을 갖는 원소이다. 이러한 Zr의 산화물이 '산화지르코늄(ZrO2)'이며 단사정(monoclinic), 정방형(teragonal), 입방형(cubic) 등 3가지의 동질다형체(同質多形體)로 존재한다.Zirconium (Zr) is a transition metal of the fifth cycle belonging to the titanium group on the periodic table and is an element having extremely high corrosion resistance to acids and alkalis. The oxide of Zr is 'zirconium oxide (ZrO2)' and exists in three homogeneous polymorphs such as monoclinic, tetragonal and cubic.

산화철(Fe2O3)은 삼산화이철 또는 삼이산화철이라고도 한다. 천연으로는 적철석(赤鐵石)으로서 널리 산출된다. 적갈색 분말로, 비중 4.5 ∼ 5.2, 녹는점 1,550℃이고, 햇빛·공기·수분·열 등에 대하여 상당히 안정하며, 한번 가열한 것은 잘 녹지 않는다. Iron oxide (Fe 2 O 3 ) is also called ferric trioxide or iron trioxide. In nature, it is widely calculated as hematite. Reddish brown powder with specific gravity of 4.5 to 5.2 and melting point of 1,550 ° C. It is fairly stable against sunlight, air, moisture, heat, etc., and it is difficult to melt once heated.

산화알루미늄(Al2O3)은 공업적으로는 알루미나라고도 하며 여러 가지 형태를 가진 것이 알려져 있는데, 가장 안정된 형태의 α-산화알루미늄이 주로 알루미늄의 제조원료입니다. 일반적으로 융해하여 석출시킨 결정은 굳기가 단단하고(모스굳기 9), 굴절률 1.76 ∼ 1.77이며, 인조보석·연마제로서도 사용되며 결정이 발달하면 산이나 알칼리에 잘 녹지 않게 되므로, 소결하여 알루미나 자기(磁器)를 만듭니다.Aluminum oxide (Al 2 O 3 ) is known industrially as alumina and is known to have various forms. The most stable form of α-aluminum oxide is mainly a raw material of aluminum. In general, the melted and precipitated crystals have a hard solidity (Moss firmness 9), have a refractive index of 1.76 to 1.77, and are also used as artificial gemstones and abrasives. As crystals develop, they hardly dissolve in acids or alkalis. ).

산화규소(SiO2)는 규산무수물이라고도 한다. 일반적으로 실리카라고 하는데, 이것은 천연으로 존재하는 각종 규산염 속의 성분으로서의 이산화규산을 말한다. Silicon oxide (SiO 2 ) is also called silicic anhydride. Generally referred to as silica, it refers to silicic acid dioxide as a component in various naturally occurring silicates.

PVC수지는 열가소성 플라스틱의 하나로 '폴리염화비닐', '염화비닐수지'라고도 하며, 염화비닐을 주성분으로 하는 플라스틱으로 필름, 시트, 성형품, 캡 등 광범위한 제품으로 가공된다. 플라스틱의 대표적인 PVC는 원래 딱딱한 물질로 프탈산계(phthalates, DEHP, DINP, DBP 등) 가소제나 아디핀산계(adipates, DHEA 등) 가소제를 사용해 유연성과 탄력성을 높인 뒤 제품화된다.PVC resin is one of the thermoplastic plastics and is also called 'polyvinyl chloride' and 'vinyl chloride resin'. It is a plastic mainly composed of vinyl chloride and processed into a wide range of products such as films, sheets, molded products, and caps. Plastics, which are representative of PVC, are originally hard and are manufactured after increasing flexibility and elasticity by using phthalates (plastics, DEHP, DINP, DBP, etc.) or adipic acids (adipates, DHEA, etc.).

고령토는 백도토라고도 하는데, 경남 하동(河東) 지방에 질이 좋은 백토가 많이 생산되고, 원적외선이 다량으로 방사된다.Kaolin, also known as white clay, produces a lot of good white clay in Hadong, Gyeongnam, and emits a large amount of far-infrared rays.

상기 베이스지는 PVC 나 PU(polyurethane) 등의 합성수지를 주재료로 하여 베이스지에 음이온 및 원적외선 방사원석 혼합물을 전사하여 합성수지가 닳지 않는 한 지속적으로 사용가능하므로 경제성을 높일 수 있다.The base paper is made of synthetic resin such as PVC or PU (polyurethane) as a main material and transfers the anion and far-infrared radiation gemstone mixture to the base paper can be used continuously as long as the synthetic resin is not worn, thereby improving economic efficiency.

상기 원단에는 0.2 ~ 0.5cm 두께의 망사원단을 부착시켜고 있어 통풍으로 인한 항균, 탈취의 기능을 제공하는 특징으로 한다. 특히 망사원단은 촘촘한 망사직물 구조로 되어 있고, 다수의 통풍구멍이 형성되어 있어서 뛰어난 통풍성을 갖게 한다.The fabric is attached to the 0.2 ~ 0.5cm thick mesh fabric is characterized by providing the function of antibacterial, deodorization due to ventilation. In particular, the mesh fabric has a dense mesh fabric structure, and a plurality of ventilation holes are formed to provide excellent ventilation.

상기 증점제는 천연증점제, 화학증점제, EVA계수지, SBR(Styrene Butadiene Rubber) 중 하나 이상을 혼합사용하는 것을 특징으로 한다.The thickener is characterized by using one or more of a natural thickener, a chemical thickener, EVA resin, SBR (Styrene Butadiene Rubber).

토르마린 2.00 중량%, 게르마늄 5.00 중량%, 대전방지제 5.00 중량%, 이산화티타늄 5.94 중량%, 산화란탄(La2O3) 1.20 중량%, 산화사마륨(Sm2O3) 0.6 중량%, 산화프라세오디뮴(Pr2O3) 1.5 중량%, 산화세륨(CeO2) 2.4 중량%, 산화지르코늄(ZrO2) 12.00 중량%, 산화철(Fe2O3) 0.06 중량%, 산화알루미늄(Al2O3) 0.30 중량%, 산화규소(SiO2) 3.00 중량%를 넣었을 때 원단의 음이온농도와 원적외선 방사율을 측정하고 그 결과를 하기 표 1, 표 2에 나타내었다.Tourmaline 2.00 wt%, Germanium 5.00 wt%, Antistatic agent 5.00 wt%, Titanium dioxide 5.94 wt%, Lanthanum oxide (La 2 O 3 ) 1.20 wt%, Samarium oxide (Sm 2 O 3 ) 0.6 wt%, Praseodymium oxide (Pr 2 O 3 ) 1.5 wt%, cerium oxide (CeO 2 ) 2.4 wt%, zirconium oxide (ZrO 2 ) 12.00 wt%, iron oxide (Fe 2 O 3 ) 0.06 wt%, aluminum oxide (Al 2 O 3 ) 0.30 wt% , When the silicon oxide (SiO 2 ) 3.00% by weight was measured anion concentration and far-infrared emissivity of the fabric and the results are shown in Table 1 and Table 2.

구분         division 실시예1 Example 1 비교예2 Comparative Example 2 비교예3Comparative Example 3 토르마린(중량%) Tourmaline (% by weight) 2.002.00 00 1.001.00 게르마늄(중량%) Germanium (% by weight) 5.005.00 00 2.502.50 대전방지제(중량%) Antistatic Agent (wt%) 5.005.00 5.005.00 5.005.00 이산화티타늄(중량%) Titanium Dioxide (% by weight) 5.945.94 5.945.94 5.945.94 산화란탄(중량%) Lanthanum oxide (wt%) 1.201.20 2.002.00 1.201.20 산화사마륨(중량%) Samarium oxide (% by weight) 0.60.6 1.001.00 1.001.00 산화프라세오디뮴(중량%) Praseodymium Oxide (wt%) 1.5 1.5 1.921.92 2.002.00 산화세륨(중량%) Cerium Oxide (wt%) 2.42.4 2.852.85 2.502.50 산화지르코늄(중량%) Zirconium Oxide (wt%) 12.0012.00 15.8315.83 15.9015.90 산화철(중량%) Iron oxide (wt%) 0.060.06 0.080.08 0.060.06 산화알루미늄(중량%) Aluminum oxide (% by weight) 0.300.30 0.480.48 0.300.30 산화규소(중량%) Silicon Oxide (wt%) 3.003.00 3.903.90 1.601.60 PVC수지(중량%) PVC resin (wt%) 5555 5555 5555 고령토(중량%) Kaolin (% by weight) 66 66 66

실시예1      Example 1 비교예2Comparative Example 2 비교예3Comparative Example 3 음이온농도(ION/cc) Anion concentration (ION / cc) 826826 647647 754754 원적외선 방사율(5∼20㎛) Far Infrared Emissivity (5 ~ 20㎛) 0.932 0.932 0.8720.872 0.8980.898

음이온 방사특성의 시험방법은 한국건자재시험연구원에 의뢰하여 KICMFIR-1042법에 의거하여 실시하였다. 원적외선 방사특성의 시험방법은 상기 한국건자재시험연구원에 의뢰하여 실시하였다. 40℃에서 5 ∼ 20㎛의 파장에서 스캐닝하면서 FT-IR분광계를 이용하여 방사율(emissivity)을 측정하였다.The test method of anion emission characteristics was performed in accordance with KICMFIR-1042 method by the Korea Institute of Construction Materials. Far infrared radiation characteristics test method was performed by the Korea Institute of Construction Materials. Emissivity was measured using an FT-IR spectrometer while scanning at a wavelength of 5 to 20 ㎛ at 40 ℃.

상기 표 1, 표 2에 의하면 본 발명의 방법에 의해 제조된 원단은 음이온과 원적외선이 다량 방사되는 것을 알 수 있다.According to Table 1, Table 2 it can be seen that the fabric produced by the method of the present invention is a large amount of anion and far infrared radiation.

상기 은의 침투공정은 입도 1 ~ 20nm인 은을 침투시키는 경우에는 골고루 분사될 수 있고 은이 침투된 원단을 100 ~ 130℃의 온도로 약 10분간 건조하는 경우 더욱 안정화된 원단을 생성할 수 있다.The infiltration process of silver may be evenly sprayed when infiltrating silver having a particle size of 1 to 20 nm, and may further produce a more stabilized fabric when the fabric infiltrated with silver is dried at a temperature of 100 to 130 ° C. for about 10 minutes.

특히, 상기에서 첨가되는 은은 입도 1 ~ 20nm의 나노은을 사용함이 바람직하며, 원단의 항균율과 탈취율을 측정하고 그 결과를 하기 표 3에 나타내었다.In particular, the silver added in the above is preferred to use the nano-silver of particle size 1 ~ 20nm, the antimicrobial and deodorization rate of the fabric is measured and the results are shown in Table 3 below.

구분            division 항균율(%)        Antibacterial rate (%) 120분후 암모니아 탈취율(%) Ammonia deodorization rate (%) after 120 minutes 은이 첨가된 경우     If silver is added 99          99 63            63 은이 첨가되지 않은 경우   If silver is not added 24          24 27             27

항균율은 ATCC 6538법에 따라 측정하였으며, 탈취율은 KICM-FIR-1004에 따라 측정한 결과이다. 상기 표 3에 의하면 본 발명의 방법에 의해 제조된 섬유는 항균, 탈취효과가 모두 양호한 원단임을 알 수 있다.Antibacterial rate was measured according to the ATCC 6538 method, deodorization rate was measured according to KICM-FIR-1004. According to Table 3, it can be seen that the fiber produced by the method of the present invention is a fabric having both good antibacterial and deodorizing effects.

또한, 상기 제조된 원단에 대한 진드기 기피성 시험에 따르면, 한국 원사시험 연구원에서 진드기 기피성 시험결과, 공시충 큰다리 먼지진드기(Dematophagoides Farinae) 및 세로무늬 먼지 진드기(Dematophagoides Pteronyssinus)에 대해 기피성능이 있는 것으로 평가되었으며, 이 같은 진드기 기피성 시험결과에 따르면, 큰다리 먼지 진드기(Dematophagoides Farinae)와 세로무늬 먼지 진드기(Dematophagoides Pteronyssinus)에 대해 각각 89.4 ~ 94.1% 와 90.3 ~ 97.2%의 기피율이 나타났다.In addition, according to the mite repellency test for the fabric prepared above, the repellent performance of the mite repellency test, Dematophagoides Farinae and Dematophagoides Pteronyssinus in the test yarn of the Korea Yarn Testing Institute The results of this mite repellency test showed 89.4-94.1% and 90.3-97.2% rejection rates for the large leg mites (Dematophagoides Farinae) and the dematophagoides Pteronyssinus, respectively.

앞의 상세한 설명에서 최적의 실시예들이 개시되었다. 여기서 특정하게 사용된 용어들은 단지 본 발명을 설명하기 위한 목적에서 사용되는 것이지 의미 한정이나 특허등록청구범위에 기재된 본 발명의 범위를 제한하기 위하여 사용된 것은 아니다. 그러므로 본 기술 분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시예가 가능하다는 점을 이해할 것이다. In the foregoing detailed description, optimal embodiments have been disclosed. The terminology specifically used herein is for the purpose of describing the invention only and is not intended to be limiting of meaning or scope of the invention as described in the claims. Therefore, those skilled in the art will understand that various modifications and equivalent other embodiments are possible from this.

Claims (3)

토르마린 2.00 중량%, 게르마늄 5.00 중량%, 대전방지제 5.00 중량%, 이산화티타늄 5.94 중량%, 산화란탄(La2O3) 1.20 중량%, 산화사마륨(Sm2O3) 0.6 중량%, 산화프라세오디뮴(Pr2O3) 1.5 중량%, 산화세륨(CeO2) 2.4 중량%, 산화지르코늄(ZrO2) 12.00 중량%, 산화철(Fe2O3) 0.06 중량%, 산화알루미늄(Al2O3) 0.30 중량%, 산화규소(SiO2) 3.00 중량%, PVC수지 55 중량%, 고령토 6 중량%가 포함된 혼합물이 베이스지의 표면에 코팅되는 것을 특징으로 하는 음이온과 원적외선 방사, 집먼지진드기 증식억제 및 대전방지 기능을 하는 코팅 원단.Tourmaline 2.00 wt%, Germanium 5.00 wt%, Antistatic agent 5.00 wt%, Titanium dioxide 5.94 wt%, Lanthanum oxide (La 2 O 3 ) 1.20 wt%, Samarium oxide (Sm 2 O 3 ) 0.6 wt%, Praseodymium oxide (Pr 2 O 3 ) 1.5 wt%, cerium oxide (CeO 2 ) 2.4 wt%, zirconium oxide (ZrO 2 ) 12.00 wt%, iron oxide (Fe 2 O 3 ) 0.06 wt%, aluminum oxide (Al 2 O 3 ) 0.30 wt% , 3.00% by weight of silicon oxide (SiO 2 ), 55% by weight of PVC resin, 6% by weight of kaolin is coated on the surface of the base anion and far-infrared radiation, house dust mite growth inhibitory and antistatic Coated fabric. 제1항에 있어서, 상기 베이스지 하면에는 0.2 ~ 0.5cm 두께의 망사원단이 부착되고 상기 혼합물이 코팅된 상면에는 입도 1 ~ 20nm인 은을 코팅시킨 것을 특징으로 하는 음이온과 원적외선 방사, 집먼지진드기 증식억제 및 대전방지 기능을 하는 코팅 원단.According to claim 1, wherein the base fabric is attached to the network fabric of 0.2 ~ 0.5cm thick, and the mixture is coated on the upper surface of the anion and far infrared radiation, dust mite growth, characterized in that the coating of silver 1 ~ 20nm Coated fabric with restraint and antistatic function. 토르마린 2.00 중량%, 게르마늄 5.00 중량%, 대전방지제 5.00 중량%, 이산화티타늄 5.94 중량%, 산화란탄(La2O3) 1.20 중량%, 산화사마륨(Sm2O3) 0.6 중량%, 산화프라세오디뮴(Pr2O3) 1.5 중량%, 산화세륨(CeO2) 2.4 중량%, 산화지르코늄(ZrO2) 12.00 중량%, 산화철(Fe2O3) 0.06 중량%, 산화알루미늄(Al2O3) 0.30 중량%, 산화규소(SiO2) 3.00 중량%, PVC수지 55 중량%, 고령토 6 중량%를 혼합하는 혼합공정;과 상기 혼합된 조성물을 12,000∼20,000메쉬로 분쇄하는 분쇄공정;과 상기 분쇄 혼합물에 상기 분쇄 혼합물 100중량부 대비 증점제 4 중량부를 투입하여 겔상태로 형성하는 겔형성공정;과 상기 겔상태 혼합물을 롤러를 통해 베이스지에 전사하는 전사공정;과 상기 혼합물이 전사된 상면에 입도 1 ~ 20nm인 은을 침투시키는 침투공정;과 상기 은이 침투된 원단을 100 ~ 130℃의 온도로 약 10분간 건조하는 건조공정;과 상기 베이스지 하면에 0.2 ~ 0.5cm 두께의 망사원단이 부착되는 공정으로 이루어짐을 특징으로 하는 음이온과 원적외선 방사, 집먼지진드기 증식억제 및 대전방지 기능을 하는 코팅 원단의 제조방법.Tourmaline 2.00 wt%, Germanium 5.00 wt%, Antistatic agent 5.00 wt%, Titanium dioxide 5.94 wt%, Lanthanum oxide (La 2 O 3 ) 1.20 wt%, Samarium oxide (Sm 2 O 3 ) 0.6 wt%, Praseodymium oxide (Pr 2 O 3 ) 1.5 wt%, cerium oxide (CeO 2 ) 2.4 wt%, zirconium oxide (ZrO 2 ) 12.00 wt%, iron oxide (Fe 2 O 3 ) 0.06 wt%, aluminum oxide (Al 2 O 3 ) 0.30 wt% , 3.00 wt% of silicon oxide (SiO 2 ), 55 wt% of PVC resin, 6 wt% of kaolin; and a grinding step of grinding the mixed composition into 12,000 to 20,000 mesh; and the grinding mixture into the grinding mixture. A gel-forming step of forming a gel state by adding 4 parts by weight of a thickener to 100 parts by weight of the mixture; and a transfer step of transferring the gel-like mixture to a base paper through a roller; and a silver having a particle size of 1 to 20 nm on the upper surface of the mixture. Penetration process to penetrate; and the fabric in which the silver is penetrated to a temperature of 100 ~ 130 ℃ Drying step of drying for about 10 minutes; And the negative electrode and far-infrared radiation, house dust mite growth inhibition and antistatic function of the coating fabric, characterized in that consisting of a step of attaching a mesh fabric of 0.2 ~ 0.5cm thickness on the lower surface of the base Manufacturing method.
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KR20040077197A (en) * 2003-02-28 2004-09-04 박우식 Textile with coating film radiating anion and far-infrared
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ITRN20090028A1 (en) * 2009-06-23 2010-12-24 N C T New Chemical Technology Srl USE OF SILVER IONS IN COMBINATION WITH THYMALINE AS A PRESERVATIVE OF PRODUCTS IN ALL KNOWN PHYSICAL FORM AND AS AN ACTIVE BACTERICIDAL AND HYGIENIZING PRINCIPLE IN THEIR USE AND IN THE TREATMENT OF WATER AND LIQUIDS IN GENERAL.
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CN108505320A (en) * 2018-04-25 2018-09-07 东南大学 Composite oxide coating and its preparation method and application
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