KR100824632B1 - Method of Manufacturing Semiconductor Device by 90nm Design Rule - Google Patents
Method of Manufacturing Semiconductor Device by 90nm Design Rule Download PDFInfo
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- KR100824632B1 KR100824632B1 KR1020060083440A KR20060083440A KR100824632B1 KR 100824632 B1 KR100824632 B1 KR 100824632B1 KR 1020060083440 A KR1020060083440 A KR 1020060083440A KR 20060083440 A KR20060083440 A KR 20060083440A KR 100824632 B1 KR100824632 B1 KR 100824632B1
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract description 54
- 239000000758 substrate Substances 0.000 claims abstract description 25
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 23
- 239000010703 silicon Substances 0.000 claims abstract description 23
- 229920002120 photoresistant polymer Polymers 0.000 claims abstract description 22
- 230000001788 irregular Effects 0.000 claims abstract description 20
- 238000005530 etching Methods 0.000 claims abstract description 17
- 239000007789 gas Substances 0.000 claims description 21
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 12
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 12
- 238000001020 plasma etching Methods 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims 1
- 238000010030 laminating Methods 0.000 claims 1
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
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- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
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- H01L21/3083—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
- H01L21/3086—Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment
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- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
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- H01L21/311—Etching the insulating layers by chemical or physical means
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Abstract
본 발명은 90nm 디자인 룰에 따른 반도체 소자 형성방법에 있어서, 특히 절연막 내측벽에 형성된 불규칙적인 러프네스를 효과적으로 제거하는 반도체 소자 형성방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for forming a semiconductor device in accordance with 90 nm design rules, and in particular, to a method for forming a semiconductor device for effectively removing irregular roughness formed on an inner wall of an insulating film.
본 발명에 따른 반도체 소자 형성방법은, 실리콘 기판상에 절연막 및 포토레지스트 패턴을 순차적으로 형성하는 단계, 상기 포토레지스트 패턴을 식각 마스크로 상기 실리콘 기판이 노출될 때까지 상기 절연막을 식각하는 단계, 상기 식각된 절연막 내측벽에 불규칙한 러프네스가 형성되면, 상기 절연막에 대해 러프네스 제거공정을 수행하여 상기 러프네스를 제거하는 단계 및 상기 러프네스를 제거한 후, 상기 실리콘 기판에 STI 공정을 수행하여 STI를 형성하는 단계를 포함하여 이루어지는 것이다. In the semiconductor device forming method according to the invention, the step of sequentially forming an insulating film and a photoresist pattern on a silicon substrate, etching the insulating film until the silicon substrate is exposed using the photoresist pattern as an etching mask, the When irregular roughness is formed on the inner wall of the etched insulating layer, a roughness removing process is performed on the insulating layer to remove the roughness, and after the roughness is removed, an STI process is performed on the silicon substrate. It comprises the step of forming.
LER, 누설전류, STI LER, Leakage Current, STI
Description
도 1은 종래 기술에서 ArF용 포토레지스트 패턴을 이용하여 실리콘 기판에 STI를 형성한 후 실리콘 기판의 상면을 SEM을 통해 촬영한 이미지.FIG. 1 is an image of an upper surface of a silicon substrate taken through an SEM after forming an STI on a silicon substrate using an ArF photoresist pattern according to the related art.
도 2a 내지 도 2e는 본 발명에 따른 반도체 소자 형성방법을 설명하기 위한 단면도.2A to 2E are cross-sectional views illustrating a method of forming a semiconductor device in accordance with the present invention.
*** 도면의 주요 부분에 대한 부호의 설명 ****** Explanation of symbols for the main parts of the drawing ***
200 : 실리콘 기판 201 : 절연막200
202 : 제 1 실리콘 질화막 204 : 실리콘 산화막202: first silicon nitride film 204: silicon oxide film
206 : 제 2 실리콘 질화막206: second silicon nitride film
본 발명은 90nm 디자인 룰에 따른 반도체 소자 형성방법에 있어서, 절연막 내측벽에 형성된 불규칙적인 러프네스를 효과적으로 제거하는 반도체 소자 형성방법에 관한 것이다.The present invention relates to a method of forming a semiconductor device for effectively removing irregular roughness formed on an inner wall of an insulating film in a method of forming a semiconductor device according to a 90 nm design rule.
도 1은 종래 기술에서 ArF용 포토레지스트 패턴을 이용하여 실리콘 기판에 STI를 형성한 후 실리콘 기판의 상면을 SEM(Scanning Electron Microscop)을 통해 촬영한 이미지이다.FIG. 1 is an image obtained by scanning electron microscop (SEM) of an upper surface of a silicon substrate after forming an STI on a silicon substrate using an ArF photoresist pattern in the prior art.
도 1에서 보는 바와 같이, 실리콘 기판 상부에 절연막(ONO:Oxide-Nitride-Oxide))을 형성하고, 상기 절연막(ONO:Oxide-Nitride-Oxide) 상부에 ArF용 포토레지스트를 형성한다. 그리고, 상기 절역만 상부에 형성된 ArF용 포토레지스트를 패터닝한 후, 상기 패터닝된 ArF용 포토레지스트를 식각 마스크로 상기 절연막을 선택적으로 식각한다. 그런 다음, STI 공정을 수행하여 상기 실리콘 기판에 STI를 형성한다.As shown in FIG. 1, an insulating film (ONO: Oxide-Nitride-Oxide) is formed on the silicon substrate, and an ArF photoresist is formed on the insulating film (ONO: Oxide-Nitride-Oxide). After the patterning of the ArF photoresist formed only on the region, the insulating layer is selectively etched using the patterned ArF photoresist as an etching mask. Then, an STI process is performed to form an STI on the silicon substrate.
그러나 이러한 반도체 소자 형성공정에서 ArF용 포토레지스트를 패터닝하는 경우에 ArF용 포토레지스트에 불규칙적인 러프네스(roughness)가 형성되고, 상기 불규칙한 러프네스가 형성된 포토레지스트를 식각 마스크로 식각공정을 수행하면, 식각 대상물인 상기 절연막 내측에도 불규칙적인 러프네스가 형성된다. 따라서, 상기 실리콘 기판의 활성화 영역을 형성하는 경우, 누설전류가 증가하는 문제점이 발생한다.However, when the ArF photoresist is patterned in the semiconductor device forming process, irregular roughness is formed on the ArF photoresist, and the etching process is performed using the photoresist on which the irregular roughness is formed using an etching mask. Irregular roughness is also formed inside the insulating film, which is an etching target. Therefore, when the active region of the silicon substrate is formed, a problem of increasing leakage current occurs.
본 발명은 상술한 바와 같은 종래 기술의 문제점을 해결하기 위하여 제안된 것으로, 러프네스(roughness) 제거공정을 추가로 수행하여 상기 절연막 내측에 형성된 불규칙적인 러프네스를 제거하는 반도체 소자 형성방법을 제공하는 데 목적이 있다.The present invention has been proposed to solve the problems of the prior art as described above, and further provides a method of forming a semiconductor device for removing the irregular roughness formed inside the insulating film by further performing a roughness (roughness) removing process. There is a purpose.
상기한 목적을 달성하기 위한 본 발명의 일실시 예에 따른 반도체 소자 형성방법의 일 특징은, 실리콘 기판상에 절연막 및 포토레지스트 패턴을 순차적으로 형성하는 단계, 상기 포토레지스트 패턴을 식각 마스크로 상기 실리콘 기판이 노출될 때까지 상기 절연막을 식각하는 단계, 상기 식각된 절연막 내측벽에 불규칙한 러프네스가 형성되면, 상기 절연막에 대해 러프네스 제거공정을 수행하여 상기 러프네스를 제거하는 단계 및 상기 러프네스를 제거한 후, 상기 실리콘 기판에 STI 공정을 수행하여 STI를 형성하는 단계를 포함하여 이루어지는 것이다.
보다 바람직하게, 상기 절연막은, 상기 실리콘 기판 상부에 제1 실리콘 질화막, 실리콘 산화막 및 제2 실리콘 질화막을 순차적으로 적층하여 형성한다.
보다 바람직하게, 상기 러프네스 제거 공정은, 5~30mTorr의 분위기 압력을 갖는 챔버 내에 300~800W의 소스 파워 및 10~80W의 바이어스 파워를 인가한 상태에서 CF계의 공정가스를 이용하여 5~20sec 동안 반응성 이온식각(Reactive Ion Etching) 공정을 수행한다.
보다 바람직하게, 상기 공정챔버 내에 상기 CF계의 공정 가스를 20~80sccm 유량으로 유입하되, 상기 CF계의 공정가스는 1~10sccm 유량의 수소가 첨가된 CF계 가스 및 1~5sccm 유량의 Cl계 가스를 포함한다. One feature of the method for forming a semiconductor device according to an embodiment of the present invention for achieving the above object is the step of sequentially forming an insulating film and a photoresist pattern on a silicon substrate, the photoresist pattern as an etching mask Etching the insulating film until the substrate is exposed; if irregular roughness is formed on the inner side of the etched insulating film, performing a roughness removing process on the insulating film to remove the roughness; After removal, the step of forming an STI by performing an STI process on the silicon substrate.
More preferably, the insulating film is formed by sequentially stacking a first silicon nitride film, a silicon oxide film, and a second silicon nitride film on the silicon substrate.
More preferably, the roughness removing process is performed using a CF-based process gas in a state in which a source power of 300 to 800 W and a bias power of 10 to 80 W are applied to a chamber having an atmospheric pressure of 5 to 30 mTorr. Reactive Ion Etching process is performed.
More preferably, the CF-based process gas is introduced into the process chamber at a flow rate of 20 to 80 sccm, but the CF-based process gas is a CF-based gas to which hydrogen is added at a flow rate of 1 to 10 sccm and a Cl system at a flow rate of 1 to 5 sccm. Contains gas.
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이하에서는 첨부된 도면을 참조하여 본 발명에 따른 90nm 디자인 룰에 따른 STI 형성방법을 포함한 반도체 소자 형성방법에 대해서 상세히 설명한다.Hereinafter, a semiconductor device forming method including an STI forming method according to a 90nm design rule according to the present invention will be described in detail with reference to the accompanying drawings.
도 2a 내지 도 2e는 본 발명에 따른 반도체 소자 형성방법을 설명하기 위한 단면도이다.2A through 2E are cross-sectional views illustrating a method of forming a semiconductor device in accordance with the present invention.
먼저, 도 2a를 참조하면, 소정의 반도체 회로 소자들(예를 들면, 트랜지스터, 다층의 금속 배선 등)을 포함하는 실리콘 반도체 기판(200) 상에 제1 실리콘 질화막(202), 실리콘 산화막(204), 제2 실리콘 질화막(206)을 순차적으로 적층한 절연막(201)을 형성한다. 이때, 상기 제1 실리콘 질화막(202) 및 상기 제2 실리콘 질화막(206)은 SiN 막을 이용할 수 있으며, 상기 실리콘 산화막(204)은 SiO2 막을 이용할 수 있다.First, referring to FIG. 2A, a first
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그런 다음, 상기 제2 실리콘 질화막(206) 상에 트렌치를 형성시키기 위한 포토 레지스트 패턴(Photo Resist Pattern)(208)이 형성한다. 상기 포토 레지스트 패턴(208)은 상기 제2 실리콘 질화막(206) 상부에 포토 레지스트 물질(예를 들어, ArF용 PR)을 소정의 두께로 도포한 후, 사진식각공정(PEP: Photo etching process)을 통해 형성한다. 이때, 상기 포토레지스트 패턴(208)에 불규칙적인 러프네스가 형성된다.Then, a
상기 불규칙적인 러프네스(212)가 형성된 포토레지스트 패턴(208)을 식각 마스크(Mask)로 상기 절연막 하부의 반도체 기판에 노출될 때까지 상기 절연막(201)을 식각한다. 그러면, 도 2b에 도시된 바와 같이, 상기 식각된 절연막(201)의 측벽에도 불규칙적인 러프네스가 형성된다. The
따라서, 상기 불규칙적인 러프네스가 형성된 포토레지스트 패턴(208)을 식각 마스크로 상기 절연막(201)을 식각하면, 도 2b 및 도 2c에 도시된 바와 같이, 식각 대상물인 상기 절연막(201)의 내측벽에도 불규칙한 러프네스(212) 예를 들어, LER(Line Edge Roughness)가 형성됨을 알 수 있다.Therefore, when the
도 2c는 포토레지스트 패턴(208)을 식각 마스크로 절연막(201)을 식각한 후, 그 상면을 SEM(Scanning Electron Microscope)을 통해 촬영한 이미지이다.2C is an image obtained by etching the
상기 식각 공정을 통해 절연막(201)을 식각한 후, 에싱(ashing) 및 세정(cleaning) 공정을 통해 상기 절연막(201) 상에 잔존하는 포토 레지스트 패턴(208)을 제거한 후, 러프네스 제거공정을 수행하여 상기 절연막(201)의 내측벽에 형성된 불규칙적인 러프네스(212)를 제거한다. 그러면, 도 2d에서 도시된 바와 같이, 상기 절연막(201) 내측벽의 평탄도를 향상시킬 수 있다.After the
도 2d는 상기와 같은 러프네스 제거공정을 통해 불규칙적인 러프네스가 제거된 실리콘 기판(200)의 상면을 SEM을 통해 촬영한 이미지이다.FIG. 2D illustrates an image of the top surface of the
이때, 상기 러프네스 제거공정은, 예를 들어, 5~30mTorr의 압력으로 유지되는 공정 챔버 내에서 CF계의 공정가스를 이용하여 300~800W의 소스파워(source power) 및 10~80W의 바이어스 파워(bias power)로 5~20sec 동안 반응성 이온식각을 수행하는 것이다.
상기 제시된 러프네스 제거공정 조건을 이용하여 절연막(201) 내측 벽에 형성된 불규칙적인 러프네스 제거 동작을 상세히 설명하면, 5~30mTorr의 압력이 유지되는 공정챔버 내에서 5~20sec 동안, 300~800W의 소스파워와 10~80W의 바이어스 파워로 CF계의 공정가스를 이용하여 반응성 이온 식각 공정을 수행하는 것이다. 이때, 상기 CF계의 공정가스는, 예를 들어, 20~80sccm의 CF계 가스에 수소가 첨가된 CF계 가스와 Cl계 가스를 포함하되, 상기 수소가 첨가된 CF계 가스인 CH2F2 가스를 1~10sccm으로 포함하고, Cl계 가스인 Cl2 가스를 1~5sccm으로 포함한다. At this time, the roughness removal process, for example, using a CF-based process gas in the process chamber maintained at a pressure of 5 ~ 30mTorr 300 ~ 800W source power (bias power) and 10 ~ 80W bias power (bias power) to perform reactive ion etching for 5-20 sec.
Using the roughness removal process conditions described above, the irregular roughness removal operation formed on the inner wall of the
삭제delete
이와 같은 CF계의 공정가스를 이용하여, 반응성 이온 식각(RIE:Reactive Ion Etching) 또는 자기강화 반응성 이온식각(MERIE:Magnetic Enhanced Reative Ion Etching) 방법을 통해 절연막(201) 내측 벽에 형성된 불규칙한 러프네스를 도 2e에서 도시된 바와 같이 절연막의 내측벽을 평탄하게 식각한 후(불규칙적인 러프네스 제거), STI(Shallow Trench Isolation) 공정을 통해 실리콘 기판(200a)에 STI(208)를 형성한다. Using such a CF-based process gas, irregular roughness formed on the inner wall of the
따라서, 본 발명을 통해 90nm 이하의 STI 형성공정에서 발생하는 LER을 개선하여 패턴을 형성할 수 있으므로, 종래 실리콘 기판의 활성화 영역에서 누설전류가 증가하여 발생하는 것을 방지할 수 있다.Therefore, according to the present invention, since the pattern can be formed by improving the LER generated in the STI forming process of 90 nm or less, it is possible to prevent the leakage current from increasing in the activation region of the conventional silicon substrate.
이상과 같이 본 발명은 비록 한정된 실시 예와 도면에 의해 설명되었으나, 본 발명은 상기의 실시 예에 한정되는 것은 아니며, 본 발명이 속하는 분야에서 통상의 지식을 가진 자라면, 이러한 기재로부터 다양한 수정 및 변형이 가능하다.As described above, although the present invention has been described with reference to the limited embodiments and the drawings, the present invention is not limited to the above-described embodiments, and those skilled in the art to which the present invention pertains, various modifications and Modifications are possible.
그러므로 본 발명의 범위는 설명된 실시 예에 국한되어 정해져서는 아니 되 며, 후술하는 특허청구범위뿐만 아니라 이 특허 청구범위와 균등한 것들에 의해 정해져야 한다.Therefore, the scope of the present invention should not be limited to the described embodiments, but should be determined not only by the claims below but also by the equivalents of the claims.
이상에서 설명한 바와 같이, 본 발명에 따른 반도체 소자 형성방법은, 러프네스 제거공정을 추가적으로 수행하여 절연막 내측 벽에 형성된 불규칙적인 러프네스를 제거함으로써, 실리콘 기판의 활성화 영역을 형성 후에 누설 전류가 증가하는 현상을 방지할 수 있는 효과가 있다. As described above, in the method of forming a semiconductor device according to the present invention, by additionally performing a roughness removing process to remove irregular roughness formed on the inner wall of the insulating layer, leakage current increases after forming the active region of the silicon substrate. There is an effect that can prevent the phenomenon.
Claims (7)
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