KR100823897B1 - Rubber compound for snow tire - Google Patents
Rubber compound for snow tire Download PDFInfo
- Publication number
- KR100823897B1 KR100823897B1 KR1020070030557A KR20070030557A KR100823897B1 KR 100823897 B1 KR100823897 B1 KR 100823897B1 KR 1020070030557 A KR1020070030557 A KR 1020070030557A KR 20070030557 A KR20070030557 A KR 20070030557A KR 100823897 B1 KR100823897 B1 KR 100823897B1
- Authority
- KR
- South Korea
- Prior art keywords
- rubber
- weight
- parts
- snow
- sulfur
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
본 발명은 스노우 타이어용 고무조성물에 관한 것으로서 보다 상세하게는 스노우 타이어용 고무조성물에 있어서, 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드[co-poly-(paraphenylene/3,4'-oxydiphenlylene terephthalamide)]의 아라미드 단섬유와 황(sulfur)이 배합된 마스터배치를 포함하여 스노우 특성, 마모성능이 향상된 스노우 타이어용 고무조성물에 관한 것이다.The present invention relates to a rubber composition for snow tires, and more particularly, to a rubber composition for snow tires, co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide [co-poly- (paraphenylene / 3,4'-oxydiphenlylene terephthalamide)] relates to a rubber composition for snow tires with improved snow characteristics and wear performance, including a masterbatch containing aramid short fibers and sulfur.
기존에는 타이어의 스틸 코드나 섬유 코드를 보강시키기 위해서 사용되는 고무 조성물에 단섬유를 적용하여 왔다. 또한, 상기의 보강성 향상 이외에도 스노우 특성이 요구되는 고무 조성물에 스노우 특성을 향상시키기 위해 단섬유를 적용시키고 있다.Previously, short fibers have been applied to rubber compositions used to reinforce steel cords or fiber cords of tires. In addition, in addition to the above reinforcing properties, short fibers are applied to rubber compositions that require snow properties to improve snow properties.
스노우 타이어에 있어서, 스노우 타이어의 트레드 고무에 단섬유를 적용시, 고무조성물의 견인력 등은 크게 향상하나, 조성물의 주요 성분을 차지하는 폴리머와 단섬유의 상용성이 크게 하락하므로 인해 고무조성물의 마모특성이 하락하고 히스테리시스(hysteresis) 에너지 손실이 많으며 단섬유가 고무조성물로부터 이탈되 어 요구되는 특성이 급격히 하락하는 문제가 있다.In the snow tire, when the short fiber is applied to the tread rubber of the snow tire, the traction of the rubber composition is greatly improved, but the wear characteristics of the rubber composition are greatly reduced because the compatibility between the polymer and the short fiber, which constitutes the main component of the composition, is greatly reduced. There is a problem that this fall, there is a lot of hysteresis energy loss, and short fibers are separated from the rubber composition, the required properties are sharply dropped.
본 발명은 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치를 사용함으로써, 상기 마스터배치 중의 아라미드 단섬유는 종래의 폴리-파라페닐렌 테레프탈아미드[Poly-(paraphenylene terephthalamide)]의 아라미드 단섬유에 비해 반응성 그룹이 증가하고, 또한 황으로 말단처리하여 반응성을 키우므로 인해 고무와의 친화력을 높여 상기의 마스터배치를 포함하는 고무조성물로 이루어진 고무를 포함하는 타이어는 오랜 시간 동안 주행하여도 상기 고무내에서 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유의 이탈성이 감소하여 마모성능이 항상되고, 시스테리시스 손실을 작게하여 스노우 특성을 향상시킬 수 있다.The present invention uses a masterbatch in which aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide are combined, whereby the short aramid fibers in the masterbatch are conventional poly-paraphenyls. Compared to the short aramid fibers of poly- (paraphenylene terephthalamide), the reactive group is increased, and the sulfur is terminated with sulfur to increase the reactivity, thereby increasing the affinity with the rubber. Tires, including rubbers made of rubber, have reduced wearability of the aramid short fibers of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide in the rubber even after long running. As a result, the snow characteristics can be improved by reducing the loss of hysteresis.
본 발명은 상기에서 언급한 문제를 해결하기 위해 기존의 하기 식(1)의 폴리-파라페닐렌 테레프탈아미드[Poly-(paraphenylene terephthalamide)]의 아라미드 단섬유 대신 하기 식(2)의 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드[co-poly-(paraphenylene/3,4'-oxydiphenlylene terephthalamide)]의 아라미드 단섬유와 황(sulfur)이 배합된 마스터배치를 스노우 타이어용 고무조성물에 포함하도록 하여 스노우 특성, 마모성능이 향상된 스노우 타이어용 고무조성물의 제공을 목적으로 한다.In order to solve the above-mentioned problems, the present invention replaces the aramid short fibers of the poly- (paraphenylene terephthalamide) of the following formula (1) with the co-poly- of the formula (2). Masterbatch blended with aramid short fibers and sulfur of paraphenylene / 3,4'-oxydiphenylene terephthalamide It is intended to provide a rubber composition for snow tires with improved snow properties and wear performance by being included in the rubber composition.
상기 식(1)에서 n은 1∼50의 자연수이다.In said formula (1), n is a natural number of 1-50.
식(2)Formula (2)
상기 식(2)에서 m은 1∼50의 자연수이고, n은 1∼50의 자연수이다.In said Formula (2), m is a natural number of 1-50, n is a natural number of 1-50.
한편 본 발명은 상기의 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치를 포함하는 고무조성물로 이루어진 고무를 포함하는 스노우 타이어의 제공을 다른 목적으로 한다.On the other hand, the present invention provides a snow tire comprising a rubber composed of a rubber composition comprising a masterbatch blended with aramid short fibers and sulfur of the co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide. For other purposes.
본 발명은 스노우 타이어용 고무조성물에 있어서, 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치를 포함하여 스노우 특성, 마모특성이 우수한 스노우 타이어용 고무조성물을 나타낸다.The present invention provides a rubber composition for snow tires, including a masterbatch of aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide, having excellent snow and wear characteristics. A rubber composition for snow tires is shown.
본 발명은 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치를 포함한다.The present invention includes a masterbatch in which aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide are combined.
본 발명은 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 1∼9:9∼1의 중량비로 배합된 마스터배치를 포함한다.The present invention includes a masterbatch in which aramid short fibers of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide and sulfur are blended in a weight ratio of 1-9: 9-1.
본 발명은 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 1:1의 중량비로 배합된 마스터배치를 포함한다.The present invention includes a masterbatch in which aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide are combined in a weight ratio of 1: 1.
본 발명의 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치의 일예로 밴버리 믹서에 코-폴리-파라페닐렌/3,4-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 유황(Sulfur)을 넣어서 20∼25℃의 상온에서 80∼100℃의 설정온도에 도달할 때까지 믹싱하여 물리적 결합을 시킴으로써 마스터배치를 제조할 수 있다.Co-poly-paraphenylene / 3,4- in a Banbury mixer as an example of a masterbatch of aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide of the present invention. Masterbatch can be prepared by adding aramid short fibers of oxydiphenylene terephthalamide and sulfur (Sulfur) and mixing until it reaches a set temperature of 80 to 100 ℃ at room temperature of 20 to 25 ℃.
상기에서 코-폴리-파라페닐렌/3,4-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 유황(Sulfur)을 밴버리 믹서에 넣을 때 코-폴리-파라페닐렌/3,4-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 유황(Sulfur)을 1:1의 중량비로 넣을 수 있다.When the aramid short fibers and sulfur of co-poly-paraphenylene / 3,4-oxydiphenylene terephthalamide are added to a Banbury mixer, the co-poly-paraphenylene / 3,4-oxydiphenyl is used. Aramid short fibers and sulfur of lene terephthalamide may be added in a weight ratio of 1: 1.
상기에서 마스터배치는 상온에서 설정온도까지 0.5℃/min∼2℃/min의 속도로 승온시키면서 제조할 수 있다.In the above, the master batch can be produced while heating up at a rate of 0.5 ℃ / min ~ 2 ℃ / min from room temperature to the set temperature.
본 발명의 스노우 타이어용 고무조성물은 원료고무 100중량부에 대하여 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치 1∼15중량부를 포함할 수 있다.The rubber composition for snow tires of the present invention comprises 1 to 15 parts by weight of a masterbatch in which aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide are blended with respect to 100 parts by weight of raw rubber. It may include.
본 발명의 스노우 타이어용 고무조성물에 있어서 원료고무 100중량부에 대하여 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치 1중량부 미만 사용하면 스노우특성, 마모성능이 향상되지 못하는 문제가 있고, 15중량부 초과하여 사용하면 고무조성물의 제반물성이 감소할 울려가 있다. 따라서 본 발명의 스노우 타이어용 고무조성물은 원료고무 100중량부에 대하여 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치 1∼15중량부 사용하는 것이 좋다.In the rubber composition for snow tires of the present invention, less than 1 part by weight of a masterbatch containing aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide based on 100 parts by weight of raw rubber. If used, there is a problem that the snow characteristics, wear performance is not improved, and when used in excess of 15 parts by weight, there is a ring to decrease the overall physical properties of the rubber composition. Therefore, the rubber composition for snow tires of the present invention is 1 to 15 weight of masterbatch in which aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide are blended with respect to 100 parts by weight of raw rubber. It is good to use vice.
본 발명의 스노우 타이어 고무조성물에서 원료고무는 천연고무, 합성고무 및 천연고무와 합성고무가 혼합된 혼합고무 중에서 선택된 어느 하나를 사용할 수 있다. In the snow tire rubber composition of the present invention, the raw rubber may be any one selected from natural rubber, synthetic rubber, and mixed rubber mixed with natural rubber and synthetic rubber.
상기에서 천연고무와 합성고무가 혼합된 혼합고무를 원료고무로 사용하는 경우 원료고무 100중량부 중에서 천연고무 5∼95중량부 및 합성고무 5∼95중량부가 혼합된 혼합고무를 사용할 수 있다. In the case of using the mixed rubber mixed with natural rubber and synthetic rubber as the raw material rubber, it is possible to use mixed rubber mixed with 5 to 95 parts by weight of natural rubber and 5 to 95 parts by weight of synthetic rubber from 100 parts by weight of raw rubber.
상기에서 합성고무는 한 종류의 합성고무를 원료고무로 사용할 수 있고, 둘 이상의 합성고무가 혼합된 혼합 합성고무를 원료고무를 사용할 수 있다.In the above synthetic rubber, one kind of synthetic rubber may be used as a raw material rubber, and raw synthetic rubber may be used as a mixed synthetic rubber in which two or more synthetic rubbers are mixed.
상기에서 합성고무는 스티렌 부타디엔 고무, 부타디엔 고무, 부틸고무, 할로겐화 부틸 고무, 이소프렌이 함유된 스티렌 부타디엔 고무, 니트릴을 포함하는 스티렌 부타디엔 고무, 네오프렌 고무 중에서 선택된 어느 하나 이상을 사용할 수 있다. The synthetic rubber may be any one or more selected from styrene butadiene rubber, butadiene rubber, butyl rubber, halogenated butyl rubber, styrene butadiene rubber containing isoprene, styrene butadiene rubber including nitrile and neoprene rubber.
상기에서 원료고무의 일예로 비닐함량이 50∼60%, 스티렌 함량이 10∼15%인 스티렌 부타디엔 고무(SBR)를 사용할 수 있다.As an example of the raw rubber, styrene butadiene rubber (SBR) having a vinyl content of 50 to 60% and a styrene content of 10 to 15% may be used.
상기에서 원료고무의 일예로 비닐함량이 65∼75%, 스티렌 함량이 20∼25%인 스티렌 부타디엔 고무를 사용할 수 있다. As an example of the raw rubber, styrene butadiene rubber having a vinyl content of 65 to 75% and a styrene content of 20 to 25% may be used.
상기에서 원료고무의 일예로 비닐함량이 50∼60%, 스티렌 함량이 10∼15%인 스티렌 부타디엔 고무(SBR)와 비닐함량이 65∼75%, 스티렌 함량이 20∼25%인 스티렌 부타디엔 고무의 혼합고무를 사용할 수 있다. Examples of the raw material rubbers include styrene butadiene rubber (SBR) having a vinyl content of 50 to 60%, a styrene content of 10 to 15%, and a styrene butadiene rubber having a vinyl content of 65 to 75% and a styrene content of 20 to 25%. Mixed rubber can be used.
상기에서 원료고무의 일예로 원료고무 100중량부 중에 비닐함량이 50∼60%, 스티렌 함량이 10∼15%인 스티렌 부타디엔 고무(SBR)와 비닐함량이 65∼75%, 스티렌 함량이 20∼25%인 스티렌 부타디엔 고무를 1:9∼9:1의 중량비로 혼합된 혼합고무를 사용할 수 있다.As an example of the raw material rubber, styrene butadiene rubber (SBR) having a vinyl content of 50 to 60%, a styrene content of 10 to 15%, a vinyl content of 65 to 75%, and a styrene content of 20 to 25 in 100 parts by weight of the raw material rubber Mixed rubbers containing styrene butadiene rubber (%) in a weight ratio of 1: 9 to 9: 1 may be used.
상기에서 원료고무의 일예로 원료고무 100중량부 중에 천연고무와 부타디엔 고무가 1:1의 중량비로 혼합된 혼합고무를 사용할 수 있다.As an example of the raw material rubber, a mixed rubber in which natural rubber and butadiene rubber are mixed in a weight ratio of 1: 1 in 100 parts by weight of raw rubber may be used.
본 발명의 스노우 타이어용 고무조성물에 있어서, 다양한 성분, 함량 등의 조건에 의해 타이어용 고무조성물을 적용한바, 본 발명의 목적을 달성하기 위해서는 상기에서 언급한 조건의 스노우 타이어용 고무조성물이 바람직함을 알 수 있었다.In the rubber composition for snow tires of the present invention, the rubber composition for tires is applied under various conditions such as various components and contents. In order to achieve the object of the present invention, the rubber composition for snow tires is preferably used. And it was found.
본 발명의 스노우 타이어용 고무조성물은 상기에서 언급한 원료고무, 마스터배치 이외에 종래 타이어용 고무조성물에 사용되는 보강충진제, 활성제, 노화방지제, 공정유, 가류제, 가류촉진제와 같은 각종 첨가제를 필요에 따라 적의 선택하여 소정의 함량으로 사용할 수 있다. 그러나 이들은 종래 타이어용 고무조성물에 사용되는 일반적인 성분으로서 본원발명의 필수 구성성분이 아니므로 이하 자세한 내용은 생략하기로 한다.The rubber composition for snow tires of the present invention requires various additives such as reinforcing fillers, activators, anti-aging agents, process oils, vulcanizing agents, and vulcanization accelerators, which are used in rubber compositions for conventional tires in addition to the above-mentioned raw rubber and master batch. Depending on the choice can be used in a predetermined amount. However, these are general components used in a rubber composition for a tire and are not essential components of the present invention.
한편 본 발명은 상기에서 언급한 스노우 타이어용 고무조성물에 의해 제조된 고무를 포함한다.On the other hand, the present invention includes a rubber produced by the above-mentioned rubber composition for snow tires.
본 발명은 상기에서 언급한 스노우 타이어용 고무조성물에 의해 제조된 고무를 함유하는 타이어를 포함한다.The present invention includes a tire containing a rubber produced by the above-mentioned rubber composition for snow tires.
본 발명은 상기에서 언급한 스노우 타이어용 고무조성물에 의해 제조된 고무를 트레드, 트레드 캡, 또는 하부 트레드로 함유하는 타이어를 포함한다.The present invention includes a tire containing the rubber produced by the above-mentioned rubber composition for snow tires as a tread, a tread cap, or a lower tread.
상기에서 타이어는 자동차용 타이어, 버스용 타이어, 트럭용 타이어, 항공기용 타이어, 오토바이용 타이어 중에서 선택된 어느 하나를 나타낸다.The tire represents any one selected from a tire for an automobile, a tire for a bus, a tire for a truck, an tire for an aircraft, and a tire for a motorcycle.
이하 본 발명을 다음의 제조예, 비교예, 실시예, 시험예에 의하여 설명하고자 한다. 그러나 이들은 본 발명의 일실시예로서 이들에 의해 본 발명의 권리범위가 한정되는 것은 아니다. Hereinafter, the present invention will be described by the following Preparation Examples, Comparative Examples, Examples, and Test Examples. However, these are not limited to the scope of the present invention by these as an embodiment of the present invention.
<제조예><Production example>
밴버리 믹서에 하기 식(2)의 코-폴리-파라페닐렌/3,4-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 유황(Sulfur)을 1:1의 중량비로 넣어서 20℃에서 100℃의 온도에 도달할 때까지 1.5℃/min의 속도로 승온시키면서 믹싱하여 물리적 결합으로 배합하여 마스터배치를 제조하였다.In the Banbury mixer, aramid short fibers and sulfur (Sulfur) of co-poly-paraphenylene / 3,4-oxydiphenylene terephthalamide of the following formula (2) were added in a weight ratio of 1: 1, and the temperature was reduced from 20 ° C to 100 ° C. Master batches were prepared by mixing and mixing with physical bonding while raising the temperature at a rate of 1.5 ° C./min until reaching a temperature.
식(2)Formula (2)
상기 식(2)에서 m은 10이고, n은 10이다.In Formula (2), m is 10 and n is 10.
<비교예 1>Comparative Example 1
천연고무 50중량부, 부타디엔고무 50중량부로 구성된 원료고무 100중량부에 대하여 실리카 30중량부, 카본블랙 20중량부, TESPT(bis-(3-triethoxisilyl)-propyl-tetrasulfide) 2.6중량부, 산화아연 3중량부, 스테아린산 2.0중량부, 점착제(para octyl phenol resin) 1.0중량부, 노화방지제(2,2,4-trimethyl-1,2-dihydroquinoline, RD) 3.0중량부, 유황(Sulfur) 2.0중량부, 가류촉진제(N-cyclohexyl-2-benzothiazolsulfen amide, CZ) 2.0중량부를 밴버리 믹서에서 혼합하고 160℃에서 15분 동안 가류하여 고무 시편을 제조하였다. 30 parts by weight of silica, 20 parts by weight of carbon black, 2.6 parts by weight of TESPT (bis- (3-triethoxisilyl) -propyl-tetrasulfide) based on 100 parts by weight of the raw material rubber consisting of 50 parts by weight of natural rubber and 50 parts by weight of butadiene rubber 3 parts by weight, 2.0 parts by weight of stearic acid, 1.0 parts by weight of para octyl phenol resin, 3.0 parts by weight of anti-aging agent (2,2,4-trimethyl-1,2-dihydroquinoline, RD), 2.0 parts by weight of sulfur (Sulfur) , 2.0 parts by weight of a vulcanization accelerator (N-cyclohexyl-2-benzothiazolsulfen amide, CZ) were mixed in a Banbury mixer and vulcanized at 160 ° C. for 15 minutes to prepare rubber specimens.
<비교예 2>Comparative Example 2
아라미드 단섬유 1중량부를 추가로 더 첨가하는 것을 제외하고는 상기 비교예 1과 동일한 방법으로 고무 시편을 제조하였다. A rubber specimen was prepared in the same manner as in Comparative Example 1 except for further adding 1 part by weight of aramid short fibers.
상기에서 아라미드 단섬유는 하기 식(1)의 폴리-파라페닐렌 테레프탈아미드 단섬유(Poly-(paraphenylene terephthalamide))를 사용하였다.As the aramid short fibers, poly-paraphenylene terephthalamide short fibers (Poly- (paraphenylene terephthalamide)) of Formula (1) was used.
상기 식(1)에서 n은 10이다.In formula (1), n is 10.
<실시예 1><Example 1>
천연고무 50중량부, 부타디엔고무 50중량부로 구성된 원료고무 100중량부에 대하여 실리카 30중량부, 카본블랙 20중량부, TESPT 2.6중량부, 산화아연 3중량부, 스테아린산 2.0중량부, 점착제(para octyl phenol resin) 1.0중량부, 노화방지제(RD) 3.0중량부, 유황(Sulfur) 1중량부, 가류촉진제(CZ) 2.0중량부, 상기 제조예에서 얻은 마스터배치 2중량부를 밴버리 믹서에서 혼합하고 160℃에서 15분 동안 가류하여 고무 시편을 제조하였다.30 parts by weight of silica, 20 parts by weight of carbon black, 2.6 parts by weight of TESPT, 3 parts by weight of zinc oxide, 2.0 parts by weight of stearic acid, and an adhesive (para octyl) based on 100 parts by weight of a raw material rubber composed of 50 parts by weight of natural rubber and 50 parts by weight of butadiene rubber. phenol resin) 1.0 parts by weight, anti-aging agent (RD) 3.0 parts by weight, sulfur (Sulfur) 1 part by weight, vulcanization accelerator (CZ) 2.0 parts by weight, 2 parts by weight of the masterbatch obtained in the above preparation in a Banbury mixer and mixed Rubber specimens were prepared by vulcanization at 15 minutes.
<실시예 2><Example 2>
유황을 사용하지 않고, 상기 제조예에서 얻은 마스터배치 4중량부를 사용하는 것을 제외하고는 상기 실시예 1과 동일한 방법으로 고무 시편을 제조하였다. A rubber specimen was prepared in the same manner as in Example 1, except that 4 parts by weight of the masterbatch obtained in the Preparation Example was used without using sulfur.
<실시예 3><Example 3>
유황을 사용하지 않고, 상기 제조예에서 얻은 마스터배치 8중량부를 사용하는 것을 제외하고는 상기 실시예 1과 동일한 방법으로 고무 시편을 제조하였다. A rubber specimen was prepared in the same manner as in Example 1, except that 8 parts by weight of the masterbatch obtained in the Preparation Example was used without using sulfur.
<실시예 4><Example 4>
유황을 사용하지 않고, 상기 제조예에서 얻은 마스터배치 12중량부를 사용하 는 것을 제외하고는 상기 실시예 1과 동일한 방법으로 고무 시편을 제조하였다. A rubber specimen was prepared in the same manner as in Example 1, except that 12 parts by weight of the masterbatch obtained in the Preparation Example was used without using sulfur.
표 1. 비교예 및 실시예의 고무 조성(단위 : 중량부)Table 1. Rubber composition of comparative example and example (unit: parts by weight)
<시험예><Test Example>
상시 비교예, 실시예의 고무시편을 ASTM 관련 규정에 의해 경도, 300％-모듈러스, 점도, 마모성능, 찢김특성, 스노우성능, 단섬유 이탈성, 내구성을 측정하고 그 결과를 아래의 표 2에 정리하여 나타내었다.The rubber specimens of Comparative Examples and Examples were measured for hardness, 300% -modulus, viscosity, abrasion performance, tearing property, snow performance, short fiber detachment and durability according to ASTM-related regulations, and the results are summarized in Table 2 below. It is shown.
표 2. 비교예 및 실시예의 고무시편의 물성Table 2. Physical Properties of Rubber Specimens of Comparative Examples and Examples
* 비교예1의 단섬유 이탈정도는 측정하지 않았음* The degree of short fiber detachment of Comparative Example 1 was not measured
* 상기 표 2에서 마모성능, 찢김특성 및 스노우성능에 대한 비교예 2 및 실 시예 1-4의 값은 비교예 1의 값을 100으로 하였을 때 환산한 수치로서 수치가 높을수록 각각의 특성이 우수함을 의미한다.* In Table 2, the values of Comparative Example 2 and Examples 1-4 for wear performance, tearing property, and snow performance were converted when the value of Comparative Example 1 was 100, and the higher the value, the better each characteristic. Means.
상술한 바와 같이, 본 발명의 바람직한 실시예를 참조하여 설명하였지만 해당 기술 분야의 숙련된 당업자라면 하기의 특허청구범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 본 발명을 다양하게 수정 및 변경시킬 수 있음을 이해할 수 있을 것이다. As described above, although described with reference to a preferred embodiment of the present invention, those skilled in the art will be variously modified and modified within the scope of the present invention without departing from the spirit and scope of the present invention described in the claims below. It will be appreciated that it can be changed.
상기 표 2의 시험예의 결과에서 보듯이, 본 발명의 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치를 포함하는 실시예의 고무는 상기 마스터배치를 사용하지 않은 비교예 1, 종래 일반적인 아라미드 단섬유를 사용한 비교예 2의 고무에 비해 각각 경도, 300％-모듈러스, 점도, 마모성능, 찢김특성, 스노우성능, 단섬유 이탈성, 내구성이 우수함을 알 수 있다.As shown in the results of the test example of Table 2, the rubber of the embodiment comprising a masterbatch of aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide of the present invention Compared to the rubber of Comparative Example 1, Comparative Example 2 using the conventional aramid short fibers without using the masterbatch, hardness, 300% -modulus, viscosity, abrasion performance, tearing properties, snow performance, short fiber detachability, durability It can be seen that this is excellent.
따라서 본 발명의 코-폴리-파라페닐렌/3,4'-옥시다이페닐렌 테레프탈아미드의 아라미드 단섬유와 황이 배합된 마스터배치를 포함하는 고무조성물은 스노우 타이어에 적용하여 스노우 특성과 마모특성을 향상시킬 수 있다. Therefore, the rubber composition including the masterbatch of aramid short fibers and sulfur of co-poly-paraphenylene / 3,4'-oxydiphenylene terephthalamide of the present invention is applied to snow tires to improve snow characteristics and wear characteristics. Can be improved.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020070030557A KR100823897B1 (en) | 2007-03-28 | 2007-03-28 | Rubber compound for snow tire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020070030557A KR100823897B1 (en) | 2007-03-28 | 2007-03-28 | Rubber compound for snow tire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR100823897B1 true KR100823897B1 (en) | 2008-04-21 |
Family
ID=39572100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020070030557A KR100823897B1 (en) | 2007-03-28 | 2007-03-28 | Rubber compound for snow tire |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR100823897B1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4514541A (en) | 1984-05-21 | 1985-04-30 | E. I. Du Pont De Nemours And Company | Fiber containing particulate elastomeric composition |
| KR20020048494A (en) * | 2000-12-18 | 2002-06-24 | 신형인 | A rubber composition having improved anti-cutting and anti-chipping ability |
| JP2003039912A (en) | 2001-05-24 | 2003-02-13 | Bridgestone Corp | Rubber-fiber composite material, and rubber article using the material |
| KR100582005B1 (en) | 2005-06-03 | 2006-05-22 | 한국타이어 주식회사 | Rubber composition for tread of studless tire |
| KR100683952B1 (en) | 2005-06-30 | 2007-02-16 | 금호타이어 주식회사 | Rubber composition for tire capply |
-
2007
- 2007-03-28 KR KR1020070030557A patent/KR100823897B1/en active IP Right Grant
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4514541A (en) | 1984-05-21 | 1985-04-30 | E. I. Du Pont De Nemours And Company | Fiber containing particulate elastomeric composition |
| KR20020048494A (en) * | 2000-12-18 | 2002-06-24 | 신형인 | A rubber composition having improved anti-cutting and anti-chipping ability |
| JP2003039912A (en) | 2001-05-24 | 2003-02-13 | Bridgestone Corp | Rubber-fiber composite material, and rubber article using the material |
| KR100582005B1 (en) | 2005-06-03 | 2006-05-22 | 한국타이어 주식회사 | Rubber composition for tread of studless tire |
| KR100683952B1 (en) | 2005-06-30 | 2007-02-16 | 금호타이어 주식회사 | Rubber composition for tire capply |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1967387B1 (en) | Rubber composition and tire sidewall with such a composition comprising emulsion styrene/butadiene rubber, cis1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber | |
| US9233578B2 (en) | Pneumatic vehicle tire | |
| EP2033812B1 (en) | Rubber composition and tire having component containing combination of emulsion SBR and tackifying resins | |
| US9150714B2 (en) | Sulfur-crosslinkable rubberizing mixture | |
| KR20170077614A (en) | Modifying agent, preparation method of modified conjugated diene polymer using the modifying agent and modified conjugated diene polymer | |
| KR102167117B1 (en) | Rubber composition and tire comprising the same | |
| KR100823897B1 (en) | Rubber compound for snow tire | |
| KR101834384B1 (en) | Rubber composition for tire | |
| KR20140051561A (en) | Wet master batch of tyre rubber with silica and rubber composite thereof | |
| KR100911613B1 (en) | Rubber composition of tire having polybutene | |
| KR102460721B1 (en) | Tyre tread rubber and tire by using it | |
| KR101609613B1 (en) | Rubber compound having organic vulcanizate improved dynamic fatigue property for tire and tire manufactured thereof | |
| KR102567414B1 (en) | Tire tread rubber composition | |
| KR102289643B1 (en) | Rubber composition for tire tread | |
| KR100827322B1 (en) | Tire tread rubber composition improved wet grip | |
| KR102526787B1 (en) | Rubber composition for tire-tread and tire using it | |
| KR100548149B1 (en) | Rubber composition for tire tread | |
| KR101854614B1 (en) | Rubber composition for tire tread comprising styrenic oil | |
| KR100959168B1 (en) | Rubber composition for carcass improving adhesion and scorch properties | |
| KR20100041400A (en) | Heavy dury tire bead insulation rubber composition | |
| JP2003073502A (en) | Rubber composition | |
| KR20240019432A (en) | Tire tread rubber composition and tire containing the same | |
| EP0643099B1 (en) | Method of making vulcanisable rubber compositions | |
| KR100578098B1 (en) | Rubber composition for tire tread | |
| KR100961059B1 (en) | A carcass rubber composition for tire |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20130402 Year of fee payment: 6 |
|
| FPAY | Annual fee payment |
Payment date: 20140402 Year of fee payment: 7 |
|
| FPAY | Annual fee payment |
Payment date: 20160404 Year of fee payment: 9 |
|
| FPAY | Annual fee payment |
Payment date: 20170404 Year of fee payment: 10 |
|
| FPAY | Annual fee payment |
Payment date: 20180403 Year of fee payment: 11 |
|
| FPAY | Annual fee payment |
Payment date: 20190409 Year of fee payment: 12 |