KR100584718B1 - Method for deposited in the colour and motifs on a surface forming products of thermoplastic synthetic resin - Google Patents

Method for deposited in the colour and motifs on a surface forming products of thermoplastic synthetic resin Download PDF

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KR100584718B1
KR100584718B1 KR1020030072043A KR20030072043A KR100584718B1 KR 100584718 B1 KR100584718 B1 KR 100584718B1 KR 1020030072043 A KR1020030072043 A KR 1020030072043A KR 20030072043 A KR20030072043 A KR 20030072043A KR 100584718 B1 KR100584718 B1 KR 100584718B1
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South Korea
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pattern
transfer paper
synthetic resin
thermoplastic synthetic
dye
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KR1020030072043A
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Korean (ko)
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KR20030086524A (en
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김태원
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주식회사 디와이일렉트론
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00—Inking and printing with a printer's forme
    • B41M1/26—Printing on other surfaces than ordinary paper
    • B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/382—Contact thermal transfer or sublimation processes
    • B41M5/38235—Contact thermal transfer or sublimation processes characterised by transferable colour-forming materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/382—Contact thermal transfer or sublimation processes
    • B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments

Abstract

본 발명은 열가소성 합성수지성형제품의 표면이나 금속제품의 표면에 열가소성 합성수지를 피복하여 만든 제품의 표면에 색채문양(글씨포함)을 구성하는 염료 또는 안료가 침착(浸着)되도록 이적시켜 문양 외측에 탑코팅을 하지않아도 표면이 평활하고 미려하며 내구적으로 유지되는 색채문양을 얻을 수 있게한 색채문양의 침착방법에 관한 것이다.The present invention transfers the dye or pigment constituting the color pattern (including letters) onto the surface of the product made by coating the thermoplastic synthetic resin on the surface of the thermoplastic synthetic resin molded product or the surface of the metal product to be deposited (양 着) The present invention relates to a method of depositing color patterns, which makes it possible to obtain color patterns that are smooth, beautiful and durable even without coating.

즉, 열가소성 합성수지 성형물 및 금속제품표면에 열가소성 합성수지를 피복하여 만든 피도체의 표면에 문양을 전사시킴에 있어서, In other words, in transferring the pattern to the surface of the object formed by coating the thermoplastic synthetic resin molded product and the surface of the metal product thermoplastic thermoplastic resin,

염료 또는 안료를 곡물을 원료로하는 풀에 혼합한 잉크로 공지된 방법에 따라 종이표면에 문양을 인쇄하여 전사지를 제조하고,A transfer paper is prepared by printing a pattern on a paper surface according to a method known as an ink mixed with a dye or a pigment with grass paste.

증류수에 유기용매인 아세톤과 침투매체를 1:0.5:0.5의 중량비율로 혼합하여 조성시킨 침투제를 준비하며,A penetrant prepared by mixing acetone, which is an organic solvent, and a penetration medium in distilled water at a weight ratio of 1: 0.5: 0.5, is prepared.

광유계 오일을 증류수와 1:2의 중량비율로 혼합하여 이형제를 제조한 다음 피도체의 표면에 침투제를 도포하고 전사지를 밀착시켜 전사지의 이면에 이형제를 도포한 후 약 20초가 경과되면 전사지를 벗겨내고 표면을 상온에서 건조시키므로서 피도체의 표면에 색채문양을 구성하는 염료 또는 안료가 침착되어 색채문양을 형성케한 것인데 이러한 제조방법을 통해 열가소성 합성수지성형제품 또는 금속제품의 표면에 열가소성합성수지를 피복하여 만든 피도체의 표면에 전사지에 인쇄된 문양의 염료와 안료를 안전하게 침착시켜 문양이 전사되게하므로서 문양표면에 탑코팅 을 하지 않고도 내구적으로 유지시킬 수 있는 효과를 얻게한 것이다.After the mineral oil is mixed with distilled water in a weight ratio of 1: 2 to prepare a release agent, a penetrant is applied to the surface of the subject, and the transfer paper is brought into close contact with the release paper on the back of the transfer paper. Dye or pigment constituting the color pattern is deposited on the surface of the subject by drying the surface at room temperature and forming the color pattern.The thermoplastic resin is coated on the surface of the thermoplastic synthetic resin molded product or the metal product through this manufacturing method. It securely deposits the dye and pigment of the pattern printed on the transfer paper on the surface of the made object so that the pattern can be transferred so that the effect can be maintained durable without top coating on the surface of the pattern.

피도체, 침투제, 전사지, 이형제, 문양Subject, Penetrant, Transfer Paper, Release Agent, Glyph

Description

열가소성 합성수지 성형제품의 표면에 색채 문양을 침착(浸着)시키는 방법{METHOD FOR DEPOSITED IN THE COLOUR AND MOTIFS ON A SURFACE FORMING PRODUCTS OF THERMOPLASTIC SYNTHETIC RESIN} METHODS FOR DEPOSITED IN THE COLOR AND MOTIFS ON A SURFACE FORMING PRODUCTS OF THERMOPLASTIC SYNTHETIC RESIN}             

도 1은 본 발명을 창호에 실시한 예시도1 is an exemplary view of the present invention in a window

도 2는 본 발명을 좌변기 덮개에 실시한 예시도Figure 2 is an exemplary view carried out the toilet seat cover the present invention

도 3은 본 발명의 제조방법을 보이는 처리단계 예시도이다.3 is an exemplary view showing a processing step showing a manufacturing method of the present invention.

* 도면의 중요부분에 대한 부호의 설명* Explanation of symbols for important parts of the drawings

1 : 피도체 2 : 침투제1: conductor 2: penetrant

3 : 전사지 3a : 문양3: transfer paper 3a: glyph

4 : 이형제4: release agent

본 발명은 열가소성 합성수지성형제품의 표면이나 금속제품의 표면에 열가소성 합성수지를 피복하여 형성시킨 제품의 표면에 색채문양(글씨포함)을 구성하는 염료나 안료를 침착시켜 침착된 문양 외면에 탑코팅(마감코팅)을 하지 않아도 표면이 평활하고 미려하며 내구성이 유지되는 색채문양을 침착시키는 방법에 관한 것이다.The present invention is a top coating (finish) on the outer surface of the pattern formed by depositing a dye or pigment constituting the color pattern (including letters) on the surface of the thermoplastic synthetic resin molded product or the surface of the metal product formed by coating the thermoplastic synthetic resin The present invention relates to a method of depositing color patterns that have a smooth, beautiful and durable surface without coating.

우리주위에 흔히 볼 수 있는 열가소성 합성수지 성형제품은 창호를 비롯하여 욕조, 싱크 등 다양한 제품으로 생산 공급되고 있으며 또 금속제품의 표면에 열가소성 합성수지를 코팅하여 만들어지는 제품도 그 종류가 다양하지만 열가소성 합성수지 성형제품과 마찬가지로 그 코팅층이 열에 약하기 때문에 승화성 염료를 사용하여 무늬를 전사시킬 수 없다. 때문에, 종래에는 인쇄가 되어 있는 장식용 의장지를 성형된 제품표면에 접착시켜 표면문양을 형성하거나 성형물의 표면에 스크린 인쇄를 하는 방법을 사용하여 인쇄문양을 표현하고 있다.Thermoplastic synthetic resin molded products commonly seen around us are produced and supplied in various products such as windows, bathtubs, sinks, etc. Also, there are various kinds of products made by coating thermoplastic synthetic resin on the surface of metal products. Similarly, because the coating is weak to heat, it is not possible to transfer the pattern using a sublimable dye. Therefore, conventionally, the printing pattern is expressed by using a method of forming a surface pattern by adhering a decorative decorative sheet printed on the molded product surface or by screen printing on the surface of the molded article.

따라서 상기 방법들은 공정이 까다롭고 작업시간이 많이 소요되기 때문에 생산성이 저하되는 문제가 있고, 또 PVC계열의 합성수지가 사용되기 때문에 화재가 발생하면 클로라이트라는 독성물질이 발생하여 사람이 흡입하면 질식사를 하게 되는 위험 요소가 있어서 건축용 창호나 실내용 가구등에 사용을 기피하는 불편이 있었다.Therefore, the above methods have a problem that productivity is lowered because the process is difficult and takes a long time, and since PVC-based synthetic resin is used, a toxic substance called chlorite is generated when a fire occurs, and when a person inhales, There was a risk of being inconvenient to avoid its use in building windows and indoor furniture.

본 발명은 상기 문제점을 해소시키기 위하여 유해물이 발생되지 않는 염료 또는 안료를 곡물을 원료로한 풀에 혼합하여 잉크를 만들고 이를 사용하여 종이에 문양을 인쇄한 전사지를 만들고 열가소성 합성수지 성형제품 또는 금속제품의 표면에 열가소성 합성수지를 피복시킨 제품의 표면에 전사지를 밀착시켜서 가열하지 않고 종이에 인쇄되어 있는 문양의 염료와 안료를 피도체의 표면에 이적시켜 문양을 구성하는 염료 또는 안료가 침착되게 하므로서 피도체의 표면에 아름답고 내구적인 문양을 표현할 수 있게 개발한 것인데 이를 보다 상세히 설명하면 다음과 같다.In order to solve the above problems, a dye or pigment which does not generate harmful substances is mixed with a paste made from grains to make an ink, and a transfer paper printed with a pattern on paper is used to make a thermoplastic synthetic resin molded product or a metal product. By transferring the transfer paper to the surface of the product coated with thermoplastic resin on the surface, the dye and pigment printed on the paper are transferred to the surface of the subject without heating, thereby depositing the dye or pigment constituting the pattern. It was developed to express beautiful and durable patterns on the surface.

본 발명은 시중에서 판매되고 있는 염료나 안료를 곡물을 원료한 풀에 혼합하여 잉크를 만들고 이것을 사용하여 종이위에 특정된 문양(3a)를 인쇄한 전사지(3)를 제조한 다음 열가소성 합성수지 성형제품 또는 금속제품의 표면에 열가소성 합성수지를 피복한 제품으로 된 피도체(1) 위에 침투제(2)를 도포하고 그 위에 전사지(3)를 밀착시켜서 전사지의 이면에 이형제(4)를 도포한 다음 20초정도 경과한 후 전사지를 박리하므로서 전사지에 인쇄된 문양을 구성하는 염료나 안료가 피도체로 이적되어 피도체(1)의 표면에 문양이 표현되게 하는 방법이다.The present invention is made by mixing a commercially available dye or pigment in the grass raw material to make an ink and using this to produce a transfer paper (3) printing a specific pattern (3a) on a paper and then a thermoplastic synthetic resin molded product or Applying the penetrant (2) on the object (1) made of a product coated with a thermoplastic synthetic resin on the surface of the metal product, the transfer paper (3) is in close contact thereon and the release agent (4) is applied to the back of the transfer paper for about 20 seconds After the passage of time, the transfer paper is peeled off so that the dye or pigment constituting the pattern printed on the transfer paper is transferred to the subject so that the pattern is expressed on the surface of the subject 1.

이를 위해 본 발명은 ABS수지를 비롯하여 폴리카보네이트, 폴리우레탄과 같은 형상안정성이 뛰어난 소재인 열가소성 합성수지 성형제품 또는 금속제품의 열가소성 합성수지를 코팅한 제품을 선택하여 피도체로 삼고 피도체의 표면에 침투제를 도포하여 전사지를 밀착시키고 전사지 이면에 이형제를 도포하여 약20초간 유지한 후 전사지를 벗겨내므로서 제조가 되는 것이다.To this end, the present invention selects a thermoplastic synthetic resin molded product or a product coated with a thermoplastic synthetic resin of a metal product having excellent shape stability, such as ABS resin, polycarbonate, polyurethane, and the like as a coating material and a penetration agent on the surface of the subject It is manufactured by applying the release paper to close contact with the transfer paper, and applying a release agent to the back of the transfer paper and holding it for about 20 seconds, then peeling off the transfer paper.

따라서 본 발명의 침투제(2)는 (주)동남합성의 THB를 침투매체로 선정하여 대하여 유기용매인 아세톤과 순수한 물(증류수)을 0.5:0.5:1.0의 중량비로 혼합하여 제조한 것이고,Therefore, the penetrant (2) of the present invention is prepared by mixing THB of Dongnam Synthetics Co., Ltd. as an infiltration medium and mixing acetone, which is an organic solvent, and pure water (distilled water) in a weight ratio of 0.5: 0.5: 1.0,

이형제(4)는 광유계오일인 (주)범우의 WB40을 증류수와 1:2의 중량비로 혼합하여 제조한 것을 사용하므로서 발명의 목적을 달성하게된다.Release agent (4) achieves the object of the invention by using a mixture of WB40 of Bumwoo Co., Ltd., a mineral oil-based oil in a weight ratio of 1: 2.

이와같이 제조된 본 발명은 열가소성수지 성형물인 피도체 또는 금속제품의 표면에 열가소성 합성수지를 피복한 제품인 피도체를 선정하여 실시를 하게되는데 피도체의 표면에 본 발명의 침투제를 도포하고 그 위에 전사지를 피복하면 성형물의 표면에 침투제가 작용하여 순식간에 피도체의 표면이 부풀어올라 수 많은 간격을 형성하게 되고 전사지의 이면에 이형제를 도포하였기 때문에 전사지에서 문양을 형성하는 염료나 안료가 분리되어 피도체의 표면에 형성된 간격 이 사이로 전사지의 문양을 구성하는 안료 또는 염료가 침투하여 전사지의 문양이 피도체의 표면으로 이적되게 되는데 침투제는 표면을 부풀어 오르게하고, 이형제는 전사지의 이면에서 문양을 구성하는 염료 또는 안료에 작용하여 이들을 피도체의 표면으로 이적시키는 것을 도와 주는 역활을 하므로서 20초정도의 짧은 시간내에 이적 전사가 이루어지고 전사지를 박리하고 표면을 건조시키면 부풀어진 피도체의 표면에 묻어 있는 휘발성 침투제가 휘발하고 피도체의 표면은 원상으로 복귀하여 수축하므로 피도체의 표면이 평활해지고 침투된 문양은 피도체의 표면에서 내측으로 침투된 상태로 안정이 되어 문양을 표출하게 되므로 문양외측에 별도의 코팅을 하지 않아도 문양 부분이 매끄럽게 원상복귀되어 아름다운 표면을 유지하는 것이다.The present invention prepared as described above is carried out by selecting a coating material coated with a thermoplastic synthetic resin on the surface of the thermoplastic resin molded object or a metal product coated with the penetrant of the present invention on the surface of the coated material and coating the transfer paper thereon. When the penetrating agent acts on the surface of the molding, it quickly swells the surface of the object to form a large number of gaps, and since the release agent is applied on the back of the transfer paper, the dye or pigment forming the pattern on the transfer paper is separated and the surface of the subject is separated. The pigment or dye constituting the pattern of the transfer paper penetrates between the gaps formed in the transfer paper so that the pattern of the transfer paper transfers to the surface of the subject. The penetrating agent swells the surface, and the release agent dyes or pigments constituting the pattern on the back side of the transfer paper. To transfer them to the surface of the subject As the state plays a role, transfer transfer takes place within a short time of about 20 seconds, and when the transfer paper is peeled off and the surface is dried, the volatile penetrant on the surface of the swollen object volatilizes, and the surface of the subject returns to its original shape and contracts. The surface of the conductor is smoothed and the infiltrated pattern is stabilized while penetrating inward from the surface of the conductor to express the pattern. Therefore, the pattern part is smoothly returned to its original shape without a separate coating on the outside of the pattern to maintain a beautiful surface. will be.

따라서 본 발명의 제조방법에 의하면 피도체의 표면을 가열하지 않고 전사지의 문양을 이적시켜 피도체에 표현할 수 있기 때문에 문양이 벗겨지거나 표면변형이 없이 매끈한 상태로 소망하는 문양을 표현하여 내구적으로 유지시킬 수 있는 효과를 얻기 때문에 평면은 물론 곡면에도 실시가 가능하여 다양한 제품에 적용할수 있는 장점이 있고 곡물을 원료로하는 풀을 사용하여 염료 또는 안료잉크를 만들기 때문에 이적부에 인쇄피박을 만들지 않아서 인쇄된 표면이 매끈하게 처리되는 이점이 있고 이로인해 코팅이 필요없기때문에 능율적인 작업이 가능케되며 화재시에 유해물이 발생하지 않아서 건축용 내장품이나 창호등에 안전하게 적용시킬수 있는 이점을 얻을 수 있으며 문양 이적시간이 짧기 때문에 생산성이 높아져서 능율적인 작업이 가능하고 설비비용등이 저렴하므로 경제성이 높은 이점을 얻을 수 있는 것이다.Therefore, according to the manufacturing method of the present invention, since the pattern of the transfer paper can be transferred and expressed on the subject without heating the surface of the subject, the pattern is peeled off or the desired pattern is expressed in a smooth state without surface deformation and maintained. It can be applied to flat and curved surfaces because it can be applied to various products, and it is possible to apply dyes or pigment inks using pastes made from grains. It has the advantage that the surface is smoothly processed, which makes it possible to work efficiently because there is no coating, and it can be safely applied to building interiors or windows because it does not generate harmful substances in the fire. This increases productivity and enables efficient work The high cost of equipment is low, and thus the economical advantage can be obtained.

Claims (3)

열가소성 합성수지 성형물로 된 피도체의 표면에 색채문양을 전사함에 있어서 염료 또는 안료를 곡물을 원료로하는 풀에 혼합시킨 잉크로 종이위에 문양을 인쇄하여 전사지를 만들고 증류수에 유기용매인 아세톤과 침투매체를 1:0.5:0.5의 중량비율로 혼합하여 조성시킨 침투제를 제조하고 광유계 오일을 증류수와 1:2의 비율로 혼합하여 이형제를 제조하여 피도체의 표면에 침투제를 도포하고 전사지를 밀착시켜 전사지의 이면에 이형제를 도포한 후 20초 동안 밀착시켜 피도체의 표면이 부풀게한 곳에 전사지에 인쇄된 염료 또는 안료가 침투되게하고 전사지를 벗긴다음 표면을 건조시켜 부푼표면이 복원되게하므로서 염료 또는 안료가 표면속으로 침착되게하는 수단으로 이루어지는 열가소성 합성수지성형제품의 표면에 색체문양을 침착시키는 방법.In transferring color patterns on the surface of the thermoplastic synthetic resin molding, ink is mixed with dye or pigment with grass paste as a raw material. A pattern is printed on paper to make a transfer paper, and acetone and an infiltration medium which are organic solvents in distilled water. A penetrant prepared by mixing at a weight ratio of 1: 0.5: 0.5 was prepared, a mineral oil-based oil was mixed with distilled water at a ratio of 1: 2 to prepare a release agent, a penetrant was applied to the surface of the subject, and the transfer paper was brought into close contact with the transfer paper. After applying the release agent on the back, it adheres for 20 seconds, so that the dye or pigment printed on the transfer paper penetrates to the place where the surface of the subject swells, peels off the transfer paper, and then dries the surface to restore the swollen surface. A method of depositing a color pattern on a surface of a thermoplastic synthetic resin molded article comprising means for depositing into the inside. 상기 1항에서 침투제는 (주)동남합성의 THB를 침투매체로 선정하여 유기용매인 아세톤과 증류수를 혼합한 조성으로 그 혼합비는 침투매체 0.5 아세톤 0.5, 증류수 1.0의 중량비로 혼합시킨 것일 것을 특징으로 하는 열가소성 합성수지성형제품의 표면에 색체문양을 침착시키는 방법.The penetrant is selected from THB of Dongnam Synthetic Co., Ltd. as a penetrating medium, and acetone, which is an organic solvent, is mixed with distilled water, and the mixing ratio is mixed by a weight ratio of 0.5 acetone 0.5 and 1.0 of distilled water. Method of depositing the color pattern on the surface of the thermoplastic synthetic resin molded article. 상기 1항에서 이형제는 광유계 오일인 (주)범우의 WB40과 증류수를 혼합한 것으로 그 혼합비가 1:2의 중량비로 혼합시킨 조성물일 것을 특징으로 하는 열가소성 합성수지성형제품의 표면에 색체문양을 침착시키는 방법.The release agent in claim 1 is a mixture of WB40 and Bumwoo Co., Ltd., a mineral oil-based oil and distilled water, wherein the mixing ratio is a composition in which the weight ratio is 1: 2, and the color pattern is deposited on the surface of the thermoplastic synthetic resin molded product. How to let.
KR1020030072043A 2003-10-16 2003-10-16 Method for deposited in the colour and motifs on a surface forming products of thermoplastic synthetic resin KR100584718B1 (en)

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