KR100574842B1 - Cinnabar glaze composite for ceramics - Google Patents

Cinnabar glaze composite for ceramics Download PDF

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Publication number
KR100574842B1
KR100574842B1 KR1020040061777A KR20040061777A KR100574842B1 KR 100574842 B1 KR100574842 B1 KR 100574842B1 KR 1020040061777 A KR1020040061777 A KR 1020040061777A KR 20040061777 A KR20040061777 A KR 20040061777A KR 100574842 B1 KR100574842 B1 KR 100574842B1
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porcelain
cinnabar
glaze
weight
mirror
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KR1020040061777A
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Korean (ko)
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KR20060013013A (en
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김선식
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김선식
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/22—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions containing two or more distinct frits having different compositions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Glass Compositions (AREA)

Abstract

본 발명은 도자기 진사유약 조성물에 관한 것으로, 더욱 구체적으로는 도자기에서 붉은색을 내는 유화안료인 진사유(辰砂釉)에 경면주사를 첨가하여 진붉은 청록색의 선명도를 지닌 발색력을 갖고 도자기에 접합력을 높이면서 유리모양의 두꺼운 결정으로 새로운 색감을 지닐 수 있도록 한 도자기 진사유약 조성물에 관한 것이다.The present invention relates to a porcelain cinnabar glaze composition, and more specifically, adding mirror-mirror to cinnabar oil, which is an emulsifying pigment that produces a red color in porcelain, to have a bonding power to a porcelain having a color development with a deep reddish-green clarity. The present invention relates to a porcelain cinnabar glaze composition which allows to have a new color with glassy crystals while increasing.

즉, 도자기의 유약조성물에 있어서, 장석, 규석, 석회석을 주성분으로 한 94~96중량%와 여기에 산화동 1~3중량%와, 경면주사 2~4중량%가 혼합된 조성비로 이루어진 것을 특징으로 하는 도자기 진사유약 조성물이다That is, in the glaze composition of porcelain, the composition consists of 94 to 96% by weight of feldspar, quartz and limestone, 1 to 3% by weight of copper oxide, and 2 to 4% by weight of mirror injection. Ceramic cinnabar glaze composition

도자기, 진사, 유약, 경면주사, 산화동Porcelain, cinnabar, glaze, mirror injection, copper oxide

Description

도자기 진사유약 조성물{CINNABAR GLAZE COMPOSITE FOR CERAMICS }Ceramics Jinsa Glaze Composition {CINNABAR GLAZE COMPOSITE FOR CERAMICS}

본 발명은 도자기 진사유약 조성물에 관한 것으로, 더욱 구체적으로는 도자기에서 붉은색을 내는 유화안료인 진사유(辰砂釉)에 경면주사를 첨가하여 진붉은 청록색의 선명도를 지닌 발색력을 갖고 도자기에 접합력을 높이면서 유리모양의 두꺼운 결정으로 새로운 색감을 지닐 수 있도록 한 도자기 진사유약 조성물에 관한 것이다.The present invention relates to a porcelain cinnabar glaze composition, and more specifically, adding mirror-mirror to cinnabar oil, which is an emulsifying pigment that produces a red color in porcelain, to have a bonding power to a porcelain having a color development with a deep reddish-green clarity. The present invention relates to a porcelain cinnabar glaze composition which allows to have a new color with glassy crystals while increasing.

종래의 도자기 표면을 처리하기 위해 사용되는 진사유약의 성분은 주로 장석, 규석, 석회석을 주성분으로 하여 95중량%정도사용하고 나머지 산화동 5중량% 정도를 혼합한 진사유약조성물로 도자기 표면을 도포하여 진사유약을 유리질화시킨 도자기를 제조하게 된다.
이때 상기의 조성물에서 도자기의 색감을 내는데 사용되는 산화동의 특성은 유약의 비중이 얇을수록 푸른색이 돋보이며 시유가 두꺼우면 검은색으로 남는 특성이 있으므로 접착력이 떨어져서 내구성이 좋지않고 유리모양의 두꺼운 결정등을 형성할 수 없기 때문에 다양하고 특색있는 표현이나 선명도 등을 높이는데 어려움이 있었다.The main component of cinnabar glaze used to treat the surface of conventional ceramics is 95% by weight mainly of feldspar, quartz and limestone, and cinnabar is applied with cinnabar glaze composition mixed with 5% by weight of the remaining copper oxide. It will produce ceramic glazed glass.
At this time, the characteristics of copper oxide used to express the color of porcelain in the above composition is that the thinner the specific gravity of the glaze, the more blue color stands out, and the thicker the oil, the more the characteristic of being left black. Since it was impossible to form a back, there was a difficulty in increasing various and distinctive expressions and clarity.

본 발명은 이러한 문제점을 해결하기 위하여 장석, 규석, 석회석을 주성분으로 하고 여기에 산화동을 혼합하는 도자기 진사유약 조성물에서 상기 진사유인 산화동에 황화합물로 황화수은(HgS)성분을 주로하는 천연광물인 경면주사를 첨가하여 경면주사에 의해 접합성이 좋고 선명도를 높이며 두꺼운 결정으로 다양한 색감을 나타낼 수 있는 진사유약을 제공함에 있다.In order to solve the above problems, the present invention is a mirror-injection which is a natural mineral mainly containing mercury sulfide (HgS) as a sulfur compound in copper cinnamic, which is the cinnabar oil in ceramic porcelain glaze composition having feldspar, silica, and limestone as main components and mixing copper oxide. It is to provide a true-glaze glaze that can add a variety of colors with thick crystals by improving the adhesion and sharpness by mirror scanning.

본 발명의 도자기 유약조성물은 장석(Feldspar) 규석(Flint Quartz) 석회석(Limistone)을 주성분으로 하고, 여기에 소량의 산화동과 함께 황화수은(HgS)성분을 주로하는 천연광물인 경면주사를 첨가한 유약조성물을 특징으로 한다.Porcelain glaze composition of the present invention is a main component of Feldspar (Flint Quartz) Limestone (Limistone), glaze with a small amount of copper oxide plus a mirror injection, which is a natural mineral mainly composed of mercury sulphide (HgS) component Characterized by a composition.

본 발명에 의한 유약조성물은 장석, 규석, 석회석을 주성분으로 하는 94~96중량%와 산화동 1~3중량%, 경면주사 2~4중량%로 조성되는 것이 바람직하다.Glaze composition according to the present invention is preferably composed of 94 to 96% by weight feldspar, silica, limestone as the main component, 1 to 3% by weight copper oxide, 2 to 4% by weight mirror scanning.

이와 같은 유약조성물의 구성성분들이 상기 범위를 첨가하게 되면 유약조성물의 색감이 떨어지고 매끄럽지 못한 문제점이 발생한다.When the components of the glaze composition are added to the above range, the color of the glaze composition may be degraded and may not be smooth.

본 발명에서 장석(長石)은 산화규소(SiO2)성분을 주로하는 것으로 알루미나 성분과 작용하여 점토에 융착시키는 작용을 한다.
규석(硅石)은 유리질(규소성분)을 주로하여 치밀하고 불에 견디는 도자기를 만드는 유약원료로 많이 사용된다.In the present invention, feldspar (長 石) mainly to the silicon oxide (SiO 2 ) component and acts to fused to the clay by working with the alumina component.
Quartzite (硅石) is mainly used as a glazing material to make dense and fire-resistant ceramics mainly by glass (silicon).

산화동(酸化同)은 환원소성하면 가마의 분위기에 따라 색이 달라지는 특성이 있는 것으로 환원분위에서 소성하면 Cu20에 의해 붉은 색을 내지만 약간의 연한녹색을 띠게 되며, 휘발성이 강하여 유약두께의 조절이 중요하고, 비중이 얇을수록 푸른색이 돋보이고 두꺼우면 검은색을 띠게 된다.
경면주사(鏡面朱砂)는 단사(丹砂), 광명사(光名沙)로도 불리는 육방정계에 속하는 광물로서 입상, 괴상, 피막상을 이루는 것으로 황화수은(HgS)성분을 주로하는 것으로 독성이 없고 부적의 붉은 문양재료도 사용되는 등 주홍색을 띠는 천연광물이다.Copper oxide has the characteristic of changing color depending on the atmosphere of the kiln when it is reduced-baking. When fired in a reducing atmosphere, it is reddish by Cu 2 0 but has a slight pale green color. Adjustment is important, and the thinner the specific gravity, the more blue color stands out and the thicker it becomes black.
Mirror injection is a mineral belonging to the hexagonal system, also called single yarn and light mineral yarn. It is composed of granular, blocky, and film form. It is a natural mineral that has a scarlet red color.

<실시예><Example>

본 발명은 도자기의 표면을 처리하기 위한 유약은 장석, 규석, 석회석을 주성분으로 하는 95중량%와, 여기에 산화동 2중량%와 경면주사 3중량%로 하는 조성물을 볼밀에서 미세하게 분쇄하고 물과 혼합하여 겔(gel)상으로 만든 도자기진사유약을 제조하였다.
상기와 같은 제조된 진사유약을 도자기 표면에 도포하였더니 선명도가 높으면서 진붉은 청록색을 띤 새로운 색감이 발현되었으며, 유리모양과 같이 두꺼운 결정으로 표현하더라도 태토와 유약간의 접합강도를 충분히 유지하면서 붉은 색감을 충분히 발휘되었다.In the present invention, the glaze for treating the surface of porcelain is 95% by weight mainly composed of feldspar, quartz and limestone, and 2% by weight copper oxide and 3% by weight mirror injection are finely pulverized in a ball mill. Porcelain cinnabar glaze was prepared by mixing the gel.
After applying the prepared cinnabar glaze on the surface of porcelain, a new color with dark reddish-green color appeared with high clarity, and even if expressed as a thick crystal like glass shape, red color was maintained while maintaining the bonding strength between the clay and the glaze sufficiently. Fully exerted.

이와 같이 본 발명의 도자기의 진사유약은 장석, 규석, 석회석을 주성분으로 하고 여기에 산화동과 경면주사가 혼합된 조성물질로 구성되어 경면주사에 의해 진붉은 청록색을 띤 새로운 색감과 선명도가 높은 발색력을 갖게 되고 유리모양과 같이 두꺼운 결정을 표현하면서도 태토와 유약의 접합력을 높여주므로 진붉은 청록색의 새로운 색감과 함께 내구성도 크게 향상시킨 효과가 있다.As described above, the cinnamic glaze of the ceramics of the present invention is composed of a composition containing feldspar, quartz, and limestone as a main component, and copper oxide and mirror injection are mixed to give a new color with high red color and vivid color by mirror injection. It expresses the thick crystals like glass and improves the bond between the clay and the glaze, so the new color of dark red and turquoise and the durability are greatly improved.

Claims (1)

도자기의 유약조성물에 있어서, 장석, 규석, 석회석을 주성분으로 한 94~96중량%와 여기에 산화동 1~3중량%와, 경면주사 2~4중량%가 혼합된 조성비로 이루어진 것을 특징으로 하는 도자기 진사유약 조성물In the glaze composition of porcelain, porcelain characterized by consisting of 94 to 96% by weight of feldspar, silica and limestone as a main component, 1 to 3% by weight of copper oxide and 2 to 4% by weight of mirror injection Jinsa Glaze Composition
KR1020040061777A 2004-08-05 2004-08-05 Cinnabar glaze composite for ceramics KR100574842B1 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100931830B1 (en) 2008-04-30 2009-12-15 김용득 Assimilation glaze composition and preparation method thereof
KR100947819B1 (en) 2008-05-16 2010-03-15 구성회 Cinnabar glaze composite for ceramics and manufacturing method thereof
KR101315126B1 (en) * 2012-05-08 2013-10-07 최인규 Cinnabar glaze composite for porcelain and manufacturing method of porcelain using the composite
KR20200066034A (en) 2018-11-30 2020-06-09 유태근 Ceramics fabricating method using glaze composition including garlic ash
KR20200066037A (en) 2018-11-30 2020-06-09 김상구 Ceramics fabricating method using glaze composition including cheongsu grape tree ash

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100840270B1 (en) * 2007-11-07 2008-06-20 김성웅 Ceramic vessel and a process thereof
KR101054253B1 (en) * 2009-05-27 2011-08-08 명지대학교 산학협력단 Method for preparing a green-ceramic pigment for reduction fire using copper oxide and a green ceramic thereof
KR102014653B1 (en) * 2018-09-04 2019-08-26 김경선 Ceramics manufacturing method and ceramics manufactured by the manufacturing method using kudzu vine

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100931830B1 (en) 2008-04-30 2009-12-15 김용득 Assimilation glaze composition and preparation method thereof
KR100947819B1 (en) 2008-05-16 2010-03-15 구성회 Cinnabar glaze composite for ceramics and manufacturing method thereof
KR101315126B1 (en) * 2012-05-08 2013-10-07 최인규 Cinnabar glaze composite for porcelain and manufacturing method of porcelain using the composite
KR20200066034A (en) 2018-11-30 2020-06-09 유태근 Ceramics fabricating method using glaze composition including garlic ash
KR20200066037A (en) 2018-11-30 2020-06-09 김상구 Ceramics fabricating method using glaze composition including cheongsu grape tree ash

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