KR100454288B1 - Functional fertilizer for garden products and its preparation method thereof - Google Patents

Functional fertilizer for garden products and its preparation method thereof Download PDF

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KR100454288B1
KR100454288B1 KR10-2002-0014939A KR20020014939A KR100454288B1 KR 100454288 B1 KR100454288 B1 KR 100454288B1 KR 20020014939 A KR20020014939 A KR 20020014939A KR 100454288 B1 KR100454288 B1 KR 100454288B1
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fertilizer
functional fertilizer
functional
anthrax
present
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KR20030075621A (en
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이태식
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    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C5/00—Fertilisers containing other nitrates
    • C05C5/02—Fertilisers containing other nitrates containing sodium or potassium nitrate
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C9/00—Fertilisers containing urea or urea compounds

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  • Organic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

본 발명은 원예작물용 기능성비료로서 원예작물의 역병 및 탄저병을 예방 치료할 수 있는 기능성 비료 및 그의 제조 방법을 제공한다. 고추 등 원예작물의 생육을 왕성하게 하기 위하여 질소와 가리는 7:3의 비율로 조성하고 피해가 극심한 역병, 탄저병의 발생을 억제하기 위하여 유황(S), 동(Cu), 아연(Zn) 등 금속 이온 물질을 더 첨가하여 그 금속이온을 활성화시켜 pH14의 강알칼리성 진청색 비료를 제공하는 뛰어난 효과가 있다.The present invention provides a functional fertilizer capable of preventing and treating late blight and anthrax of horticultural crops as a functional fertilizer for horticultural crops and a method for producing the same. In order to thrive the growth of horticultural crops such as red pepper, the ratio is 7: 3 with nitrogen, and metals such as sulfur (S), copper (Zu), zinc (Zn), etc. are used to suppress the occurrence of severe plague and anthrax. The addition of an ionic material further activates the metal ions to provide a strong alkaline deep blue fertilizer with a pH of 14.

Description

원예작물용 기능성 비료 및 그 제조방법{FUNCTIONAL FERTILIZER FOR GARDEN PRODUCTS AND ITS PREPARATION METHOD THEREOF}FUNCTIONAL FERTILIZER FOR GARDEN PRODUCTS AND ITS PREPARATION METHOD THEREOF}

본 발명은 원예작물용 기능성 비료 및 그 제조방법에 관한 것이다. 고추, 수박 등 1년생 작물의 경우, 강알칼리성의 농약과 비료를 사용할 때 잎의 위축현상 및 생육정지 현상 등 약해를 방지하고 더 나아가 약효를 증진하는 기능성 비료가 절실히 요구되고 있다. 예컨데 고추의 중요한 병해인 역병, 탄저병을 들 수 있는데 이들 병해를 예방, 치료하기 위해 사용하는 약제로는 석회보르도액(4-4식)을 들 수 있다. 그러나, 석회보르도액을 사과, 배, 포도 등 다년생 원예작물에 살포시용하는 경우에는 생육기간 중 엽 및 과실에 사용해도 약해가 나타나지 않지만 1년생 작물인 고추 또는 수박에 고농도로 살포시용되면 일시적으로 생육이 정지될뿐만 아니라, 생육후기인 수확기에는 붉은 고추열매에 하얀 흔적이 나타나 수확후 고추열매를 세척해야하는 번거러움이 부수적으로 생겨나게 되어 경제적으로 불리하다. 이러한 현상을 없애기 위해 "칼슘을 함유하지 않은 보르도액"이 개발되어 사용하고 있지만, 1년생 작물인 고추, 수박의 경우에는 앞에서 지적했듯이 생육 위축 현성이 일어나고 일부 품종에 따라서는 매우 심각할 수도 있다.The present invention relates to a functional fertilizer for horticultural crops and a method for producing the same. In the case of annual crops such as red pepper and watermelon, functional fertilizers are required to prevent weakness such as leaf atrophy and growth stoppage and to further enhance drug efficacy when using strong alkaline pesticides and fertilizers. For example, the most important diseases of pepper include late blight and anthrax. Lime Bordeaux liquid (4-4 meals) is used to prevent and treat these diseases. However, when lime Bordeaux is applied to perennial horticultural crops such as apples, pears, grapes, etc., it does not show any weakness even if it is used for leaves and fruits during the growing period. In addition to being stopped, the late harvest season has a white mark on the red pepper fruit, resulting in the inconvenience of having to wash the pepper fruit after harvesting is disadvantageous economically. In order to eliminate this phenomenon, Bordeaux liquid without calcium has been developed and used, but the annual crop of red pepper and watermelon, as mentioned above, may cause growth atrophy and may be severe in some varieties.

그런데, 이러한 현상을 제거하기 위해서 0.5% 이상의 질소 및 가리비료를 엽면시비함이 필요한데, 이러한 이중적인 작업을 하게 되면 작업비용이 이중적으로 소요되므로 이를 하나로 통합하여 고추역병, 탄저병에 효과를 나타내면서 동시에 약해를 일으키지 않을 뿐아니라, 오히려 약효를 증진할 수 가 있는 것이다.However, in order to eliminate this phenomenon, it is necessary to fertilize more than 0.5% of nitrogen and scallops. When doing such a double work, the work cost is doubled, thus integrating them into one and showing the effect on pepper blight and anthrax. Not only does it occur, but rather can enhance the efficacy.

따라서, 본 발명은 고추, 수박 등을 다비성 작물로서 전재배과정에서 5회 수준의 시비를 수행하는 시비방법을 제공함을 그 목적으로 한다. 본 발명의 다른 목적은 기능성 비료를 시비하므로써 영양보충과 예방 및 탄저병을 예방 또는 치료하는 기능을 동시에 가지는 비료를 제공한다. 본 발명의 또다른 목적은 상기 목적에 부응하는 기능성 비료 제조방법을 제공한다.Therefore, an object of the present invention is to provide a fertilization method for performing fertilization of five times in the whole cultivation process of red pepper, watermelon, and the like as a fertile crop. Another object of the present invention is to provide a fertilizer having a function of simultaneously supplementing nutrition and preventing and treating anthrax by fertilizing functional fertilizers. Another object of the present invention to provide a method for producing a functional fertilizer corresponding to the above object.

본 발명의 상기 목적은 기능성 비료를 제조하고 이를 살포시용하여 고추를 재배한 다음 그 결과를 평가함으로써 달성하였다. 이하, 본발명의 구성을 실시예를 들어 상세히 설명한다.The above object of the present invention was achieved by preparing a functional fertilizer and cultivating it to grow red pepper and then evaluating the result. Hereinafter, the configuration of the present invention will be described in detail by way of examples.

도 1은 발명의 바람직한 공정을 설명한 공정의 개략적인 흐름도이다.1 is a schematic flowchart of a process illustrating a preferred process of the invention.

원예작물의 생육적온은 10-35°C로서 생육한계 최저온도는 10°C이다. 비교적 건조 및 습해에 약하며 다비성이고 중성토양에서 비교적 생육이 잘 된다.The growth temperature of horticultural crops is 10-35 ° C, and the minimum growth temperature is 10 ° C. It is relatively weak to dry and wet, fertile and relatively well grown in neutral soils.

그런데, 고추연작지의 경우, 고추역병에 의한 피해가 가장 많이 발행하며 이는 고추역병에 관여하는 미생물이 토양전염을 하고 병원균의 밀도증가 및 땅심의 감소에 기인한다. 또, 고추역병은 육묘에서 수확기에 이르는 전 생육기간에 발생하며 뿌리, 줄기, 잎, 과실 등에 발생한다.By the way, in the case of pepper arable land, the damage caused by pepper blight is most frequently caused by the microorganisms involved in pepper blight, which causes soil infection, increases the density of pathogens, and decreases the core. In addition, red pepper disease occurs during the entire growing season from seedling to harvest, and occurs in roots, stems, leaves and fruits.

한편, 고추탄저병은 역병과 함께 가장 심각한 병으로 과실을 주로 썩게 함으로 그 피해가 가장 직접적이고 치명적이다. 또 이병은 6월 하순경에 장마에 의해 시작되며 비바람을 타고 포자상으로 전파되어 병을 일으키므로 수분이 필수적이므로 밀식하여 통풍이 잘 되지 않을 때 병발생이 더욱 심하다.On the other hand, pepper anthrax is the most serious disease with late blight, which causes the fruit to rot. The damage is the most direct and fatal. In addition, this disease is started by the rainy season in late June and spreads in spores in rainy weather, causing the disease, so moisture is essential, so the disease is more severe when not well ventilated.

이하에, 본발명의 기능성 비료의 제조방법과 상기 기능성 비료를 이용한 고추재배 방법을 기술한다.Hereinafter, the manufacturing method of the functional fertilizer of this invention and the pepper cultivation method using the said functional fertilizer are described.

<실시예 1> 본 발명 고추재배용 기능성 비료 제조Example 1 Preparation of Functional Fertilizer for Red Pepper Cultivation of the Present Invention

다음과 같은 원료를 선택하여 도 1에 첨부한 바와 같이 하기 단계별로 본 발명 고추 역병균과 탄저병균에 기능성 비료를 제조 완성하였다.The following raw materials were selected to complete the functional fertilizer in the present invention pepper blight and anthrax bacterium according to the following steps as shown in FIG.

제 1단계, 고추역병균과 탄저병균에 효능이 있는 금속이온 공급원으로 황(S), 구리(Cu), 아연(Zn)을 선택한다.In the first step, sulfur (S), copper (Cu), and zinc (Zn) are selected as sources of metal ions that are effective against red pepper germ and anthrax.

제 2단계, 순수 물(H20)을 투입하고 KOH를 이용하여 pH를 6.5로 조정한 다음 1차 교반한다.In the second step, pure water (H 2 0) was added and the pH was adjusted to 6.5 using KOH, followed by first stirring.

제 3단계, 요소와 황산가리를 7:3의 비율로 투입한 다음 미량 요소인 붕소(B)와 몰리브덴(Mo)을 투입한다.In the third step, urea and ferric sulfate are added at a ratio of 7: 3, followed by addition of trace elements boron (B) and molybdenum (Mo).

제 4단계, 분산제로서 설탕을 투입가당한다.Step 4, Sugar is added as a dispersant.

제 5단계, 물 잔량을 투입하고 KOH를 이용 pH 14로 조정한다.In the fifth step, the remaining amount of water is added and adjusted to pH 14 using KOH.

제 6단계-제 7단계, 물 투입이 끝난후 약 20분간 계속 교반 혼합한다. pH조절물질로는 KOH 또는 NaOH로 하되 KOH가 더욱 바람직하다. 최종 수소이온 농도는 pH 14가 적절하다. 여과 후, 숙성시킨 후 제조된 비료의 색깔은 진청색이었다. 본 발명 기능성 비료 제조방법의 구체적인 사항은 하기 표 1과 같다.Step 6-Step 7, stirring is continued for about 20 minutes after the addition of water. The pH adjusting material is KOH or NaOH, but KOH is more preferable. The final hydrogen ion concentration is pH 14 appropriate. After filtration, the color of the fertilizer prepared after aging was dark blue. Specific matters of the functional fertilizer manufacturing method of the present invention are shown in Table 1 below.

본 발명 고추재배용 기능성 비료의 원료 조성비Raw material composition ratio of functional fertilizer for red pepper cultivation of the present invention 비료성분Fertilizer 비료원료Fertilizer 순도(%)water(%) 투입량(kg)Input (kg) 조성비(%)Composition ratio (%) 비고Remarks 질소(N)Nitrogen (N) 요소Element 9898 300300 15.015.0 다량요소Massive element 칼리(K)Cali (K) 황산가리Sulfuric acid 9898 120120 6.06.0 다량요소Massive element 황(S)Sulfur (S) 유황brimstone 99.599.5 3030 1.51.5 금속이온Metal ion 구리(Cu)Copper (Cu) 황산동Copper sulfate 9999 168168 8.48.4 금속이온Metal ion 아연(Zn)Zinc (Zn) 황산아연Zinc sulfate 9898 3030 1.51.5 약해경감제Weakening agent 붕소(B)Boron (B) 붕사borax 8282 22 0.10.1 미량요소Trace elements 몰리브덴(Mo)Molybdenum (Mo) 암모늄몰리브덴Ammonium molybdenum 9898 1One 0.050.05 미량요소Trace elements 당Party 설탕Sugar 9999 1212 0.60.6 분산제Dispersant 물(H2O)Water (H 2 O) 물water 100100 1,3371,337 66.8566.85 증량제extender 총계sum 2,0002,000 100.00100.00

본 발명 기능성비료의 주요 성분 중 질소는 엽록소, 단백질, 효소 등의 구성성분이며 결핍하면 황백화 현상이 나타난다. 그리고 칼리는 탄수화물, 단백질형성, 세포내 수분공급, 증산에 의한 수분상실의 제어 등의 역할을 하며 결핍하면 생장점이 말라죽는다. 황은 단백질, 아미노산, 효소의 구성성분이며 엽록소의 형성에 관여하며, 결핍하면 세포분열이 억제된다. 구리는 광합성, 호흡작용에 관여하고 엽록소의 생성도 조장한다. 특히 식물의 호흡작용에 있어서 중요한 역할을 하는 효소 Tyrosinase의 구성성분이다. 결핍하면 황백화, 괴사, 조기낙엽을 일으킨다.Nitrogen in the main component of the functional fertilizer of the present invention is a component of chlorophyll, protein, enzymes and the like, if lacking, yellowing phenomenon appears. Kali plays a role in carbohydrates, protein formation, intracellular hydration, and control of water loss by transpiration. Sulfur is a component of proteins, amino acids and enzymes and is involved in the formation of chlorophyll, which, when deficient, inhibits cell division. Copper is involved in photosynthesis, respiration and encourages the production of chlorophyll. In particular, it is a component of the enzyme Tyrosinase, which plays an important role in plant respiration. Deficiency can cause yellowing, necrosis and early deciduous leaves.

한편, 아연은 생체세포 내에서 다양한 화학반응의 촉매 또는 반응조절물질로 작용하며 단백질, 탄수화물의 대사에 관여한다. 결핍되면 황백화, 괴사를 일으킨다.On the other hand, zinc acts as a catalyst or reaction regulator of various chemical reactions in living cells and is involved in the metabolism of proteins and carbohydrates. Deficiency causes yellowing, necrosis.

<실시예 2> 본 발명 기능성 비료를 사용한 고추재배Example 2 Pepper cultivation using the functional fertilizer of the present invention

본 발명의 기능성 비료 중 다음 [표2]와 같이 시용하여 재배하였다.Among the functional fertilizers of the present invention it was cultivated by application as shown in the following [Table 2].

고추는 1년생 다비성 작물이므로 생육기간 동안 5번 정도 비료를 시용하였다. 1차는 밑거름(기비)으로 정식 2-3주전에 300평당 요소 28kg, 용성인비 15kg, 황산가리 10kg, 퇴비 2,000kg, 석회비료 150kg를 주고, 생육을 함께 시용하였다. 기간 중 웃거름(추비)으로 요소와 황산가리를 4차례 걸쳐 나누어 주는데 이때 본 발명의 기능성 웃거름(추비) 사용시기는 정식후 20일 후부터 시용하며 그 이후 20-25일 간격으로 4차례 나누어 시비하였다.Since red pepper is a year-round fertilizer, fertilizer was applied about five times during the growing season. The first was manure (air), which was given 2-3 kg of urea, 15 kg of soluble phosphorus, 15 kg of sulphate, 10 kg of compost, 2,000 kg of compost, and 150 kg of lime fertilizer. Urea and ferric sulfate are divided into four times during the period of the manure (chubby), wherein the use time of the functional manure (chubby) of the present invention is applied from 20 days after the formulation and then divided into 4 times at intervals of 20-25 days.

고추에 대한 본 발명 기능비료의 효과적인 시비법(kg/10a)Effective fertilization method of the functional fertilizer of the present invention for red pepper (kg / 10a) 비료명Fertilizer 시용총량Total amount of application 밑거름(300평기준)Base manure (based on 300 pyeong) 웃거름Laughter 1차Primary 2차Secondary 3차3rd 4차4th 요소Element 5656 2828 66 66 77 77 용성인비Yongsung 1515 1515 황산가리Sulfuric acid 2525 1010 55 55 55 퇴비compost 2,0002,000 2,0002,000 고토석회Goto Lime 150150 150150 시비시기Fertilization 정식2-3주전2-3 weeks before 정식 후20일20 days after the meal 1차 후25일25 days after the 1st 2차 후25일25 days after the 2nd 3차 후25일25 days after 3rd round

<실시예 3> 본 발명 기능성 비료의 엽면살포Example 3 Foliar Spray of Functional Fertilizer of the Present Invention

상기 실시예 1에 따라 제조된 본 발명 고추재배용 기능성 비료의 엽면시비법을 확립하였다.The foliar fertilization method of the functional fertilizer for red pepper cultivation of the present invention prepared according to Example 1 was established.

일반적으로, 엽면시비는 작물에 미량요소의 결핍이 나타났을 때 그리고 작물이 동해, 풍수해, 병충해 등의 해를 받아 생육이 쇠퇴한 경우 및 뿌리가 병충해, 습해, 환원성 유해 물질 등에 의해 해를 받았을 때에 실시한다.In general, foliar fertilization is when the crop is deficient in trace elements, and when the crop is deteriorated due to damage such as east sea, feng shui, pest, etc. Conduct.

본 발명의 기능성 비료를 엽면시비할 때 적정사용농도를 우선 고추에 대하여 조사하였다.When fertilizing the functional fertilizer of the present invention, the optimum use concentration was first examined for red pepper.

고추에 액상비료를 사용할 경우 살포액의 농도가 높을수록 체내에 흡수가 빨랐으며, 가장 안전한 사용농도는 질소; 0.5-2중량%, 칼리; 1중량%, 황; 1-2중량%, 아연; 0.3중량%, 구리; 1-1.5중량%, 붕소; 1-1.2%, 몰리브덴; 0.01%으로 조사되었다.When the liquid fertilizer was used in the pepper, the higher the concentration of the spray solution, the faster the absorption into the body. The safest concentration was nitrogen; 0.5-2% by weight Kali; 1 weight percent sulfur; 1-2% by weight zinc; 0.3 wt% copper; 1-1.5% by weight boron; 1-1.2%, molybdenum; 0.01% was investigated.

본 발명 기능성 비료를 사용하여 고추를 정식한 후 20일, 45일, 60일, 85일후 상기 비료성분 농도를 10X액 및 20X, 40X 그리고 80X 액을 대조구로한 고추 역병 및 탄저병 예방을 위한 엽면 시비(살포) 효과는 다음 [표 3] 및 [표 4]와 같다.20 days, 45 days, 60 days, 85 days after the red pepper was formulated using the functional fertilizer of the present invention, the fertilizer concentration was 10X and 20X, 40X and 80X liquid as a control, foliar fertilization for the prevention of pepper blight and anthrax (Spray) effect is shown in the following [Table 3] and [Table 4].

고추역병에 대한 예방 효과Prevention effect against pepper blight 사용농도Concentration 병 발생주수(주/100주)Disease outbreak (week / 100) 예방효과(%)Prevention effect (%) 비고Remarks 10X(기본구)10X (base ball) -- 100100 20X(대조구)20X (control) 22 9898 40X(대조구)40X (control) 2525 74.574.5 80X(대조구)80X (control) 4040 59.259.2 무처리(통제구)No treatment (control area) 9898 --

고추탄저병에 대한 예방효과Preventive Effect on Pepper Anthrax 사용농도Concentration 병 발생주수(주/100주)Disease outbreak (week / 100) 예방효과(%)Prevention effect (%) 비고Remarks 10X(기본구)10X (base ball) 99 91.191.1 20X(대조구)20X (control) 1919 80.980.9 40X(대조구)40X (control) 3838 61.761.7 80X(대조구)80X (control) 7070 29.329.3 무처리(통제구)No treatment (control area) 9999 --

상기 실험결과로부터 본 발명 강알칼리성 기능성 비료는 비료원료의 선택에 의하여 다양한 과수 및 화훼 원예작물에도 응용할 수 있는 효과가 있을 것이다. 특히, 강알칼리 용액 내에서 금속이온이 활성화 되어 있는 본 발명 기능성 비료 용액은 음성대전(Negative Charge) 하는 모든 병원성 미생물의 생리 활성을 교란시켜 고질적인 질병을 통제할 수 있는 것이다.From the above test results, the strong alkaline functional fertilizer of the present invention will have an effect that can be applied to various fruit trees and flower garden crops by the selection of fertilizer raw materials. In particular, the functional fertilizer solution of the present invention in which the metal ion is activated in the strong alkali solution can control the chronic disease by disturbing the physiological activity of all pathogenic microorganisms with negative charge.

이상에서 설명한 바와 같이, 본 발명은 병원성 미생물에 의해 발생하는 고질적인 식물질환을 통제할 수 있는 기능성 비료를 제공하는 뛰어난 효과가 있으므로 농약 및 비료산업상 매우 유용한 발명인 것이다.As described above, the present invention is a very useful invention in the pesticide and fertilizer industry because it has an excellent effect of providing a functional fertilizer that can control the chronic plant diseases caused by pathogenic microorganisms.

Claims (6)

요소 15.0중량%, 황산가리 6.0중량%, 유황 1.5중량%, 황산동 8.4중량%, 황산아연 1.5중량%, 붕사 0.1중량%, 암모늄몰리브덴 0.05중량%, 설탕 0.6중량% 및 물 66.85중량%로 구성되며 KOH에 의해 pH가 14로 조절된 원예작물 질환에 대해 예방 또는 치료효과를 나타내는 기능성 비료.It consists of 15.0% of urea, 6.0% of sulfur sulfate, 1.5% of sulfur, 8.4% of copper sulfate, 1.5% of zinc sulfate, 0.1% of borax, 0.05% of ammonium molybdenum, 0.6% of sugar and 66.85% of water. Functional fertilizer that has a prophylactic or therapeutic effect against a horticultural crop disease whose pH is adjusted to 14 by KOH. 삭제delete 제 1항에 있어서, 상기 원예작물은 고추 또는 수박인 것을 특징으로 하는 기능성 비료.The functional fertilizer according to claim 1, wherein the horticultural crop is red pepper or watermelon. 삭제delete 제 1항에 있어서, 상기 질환은 역병 또는 탄저병인 것을 특징으로 하는 기능성 비료.The functional fertilizer according to claim 1, wherein the disease is late blight or anthrax. 금속이온을 공급하는 물질을 선택하는 단계와; 물을 투입하고 비료 원료와 미량요소를 투입하는 단계와; 분산제를 투입 가당하는 단계와; pH 조절물질을 투입하여 pH14로 조절하는 단계와; 교반 혼합 및 여과 숙성하는 단계로 구성됨을 특징으로 하는 원예작물용 기능성 비료 제조방법Selecting a material for supplying metal ions; Injecting water and injecting fertilizer raw materials and trace elements; Inputting a dispersant; adding a pH adjusting material to adjust pH to 14; Functional fertilizer manufacturing method for horticultural crops characterized in that it comprises a step of stirring and filtration aging
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KR102389496B1 (en) 2021-07-16 2022-04-25 주식회사 유일 Functional composite fertilizer composition for foliar application and method for manufacturing the same

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