JPWO2020071544A1 - 樹脂組成物及び光ファイバ - Google Patents
樹脂組成物及び光ファイバ Download PDFInfo
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- JPWO2020071544A1 JPWO2020071544A1 JP2020551116A JP2020551116A JPWO2020071544A1 JP WO2020071544 A1 JPWO2020071544 A1 JP WO2020071544A1 JP 2020551116 A JP2020551116 A JP 2020551116A JP 2020551116 A JP2020551116 A JP 2020551116A JP WO2020071544 A1 JPWO2020071544 A1 JP WO2020071544A1
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- Prior art keywords
- meth
- acrylate
- resin composition
- resin layer
- optical fiber
- Prior art date
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- 239000011342 resin composition Substances 0.000 title claims abstract description 67
- 239000013307 optical fiber Substances 0.000 title claims description 44
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 110
- 229920005989 resin Polymers 0.000 claims abstract description 101
- 239000011347 resin Substances 0.000 claims abstract description 101
- 239000002245 particle Substances 0.000 claims abstract description 51
- 229910052809 inorganic oxide Inorganic materials 0.000 claims abstract description 43
- 239000000178 monomer Substances 0.000 claims abstract description 42
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims abstract description 27
- 239000003999 initiator Substances 0.000 claims abstract description 14
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 13
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 12
- -1 phenoxyethyl Chemical group 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- 239000003365 glass fiber Substances 0.000 claims description 14
- 239000011164 primary particle Substances 0.000 claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 74
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 18
- 239000002612 dispersion medium Substances 0.000 description 18
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 9
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 230000005540 biological transmission Effects 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 6
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- 229920001451 polypropylene glycol Polymers 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 3
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 3
- QPRQEDXDYOZYLA-UHFFFAOYSA-N 2-methylbutan-1-ol Chemical compound CCC(C)CO QPRQEDXDYOZYLA-UHFFFAOYSA-N 0.000 description 3
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 3
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 3
- 125000001165 hydrophobic group Chemical group 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229960002317 succinimide Drugs 0.000 description 3
- 230000002194 synthesizing effect Effects 0.000 description 3
- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical group C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 description 2
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- MXLMTQWGSQIYOW-UHFFFAOYSA-N 3-methyl-2-butanol Chemical compound CC(C)C(C)O MXLMTQWGSQIYOW-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- GHLKSLMMWAKNBM-UHFFFAOYSA-N dodecane-1,12-diol Chemical compound OCCCCCCCCCCCCO GHLKSLMMWAKNBM-UHFFFAOYSA-N 0.000 description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- GJBXIPOYHVMPQJ-UHFFFAOYSA-N hexadecane-1,16-diol Chemical compound OCCCCCCCCCCCCCCCCO GJBXIPOYHVMPQJ-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- JYVLIDXNZAXMDK-UHFFFAOYSA-N pentan-2-ol Chemical compound CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 description 2
- AQIXEPGDORPWBJ-UHFFFAOYSA-N pentan-3-ol Chemical compound CCC(O)CC AQIXEPGDORPWBJ-UHFFFAOYSA-N 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- AURYLBASVGNSON-UHFFFAOYSA-N (2,5-dioxopyrrolidin-3-ylidene)methyl prop-2-enoate Chemical compound C=CC(=O)OC=C1CC(=O)NC1=O AURYLBASVGNSON-UHFFFAOYSA-N 0.000 description 1
- BXSPZNVFEYWSLZ-UHFFFAOYSA-N (3-phenoxyphenyl)methyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 BXSPZNVFEYWSLZ-UHFFFAOYSA-N 0.000 description 1
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 1
- BQTPKSBXMONSJI-UHFFFAOYSA-N 1-cyclohexylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1CCCCC1 BQTPKSBXMONSJI-UHFFFAOYSA-N 0.000 description 1
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 1
- RESPXSHDJQUNTN-UHFFFAOYSA-N 1-piperidin-1-ylprop-2-en-1-one Chemical group C=CC(=O)N1CCCCC1 RESPXSHDJQUNTN-UHFFFAOYSA-N 0.000 description 1
- WLPAQAXAZQUXBG-UHFFFAOYSA-N 1-pyrrolidin-1-ylprop-2-en-1-one Chemical group C=CC(=O)N1CCCC1 WLPAQAXAZQUXBG-UHFFFAOYSA-N 0.000 description 1
- GGSRTHRSSCWGGK-UHFFFAOYSA-L 2,2-dibutyl-5-hydroxy-1,3,2-dioxastannepane-4,7-dione Chemical compound CCCC[Sn]1(CCCC)OC(=O)CC(O)C(=O)O1 GGSRTHRSSCWGGK-UHFFFAOYSA-L 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- PRIUALOJYOZZOJ-UHFFFAOYSA-L 2-ethylhexyl 2-[dibutyl-[2-(2-ethylhexoxy)-2-oxoethyl]sulfanylstannyl]sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS[Sn](CCCC)(CCCC)SCC(=O)OCC(CC)CCCC PRIUALOJYOZZOJ-UHFFFAOYSA-L 0.000 description 1
- QPXVRLXJHPTCPW-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-(4-propan-2-ylphenyl)propan-1-one Chemical compound CC(C)C1=CC=C(C(=O)C(C)(C)O)C=C1 QPXVRLXJHPTCPW-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 1
- RASDUGQQSMMINZ-UHFFFAOYSA-N 2-methyl-1-piperidin-1-ylprop-2-en-1-one Chemical group CC(=C)C(=O)N1CCCCC1 RASDUGQQSMMINZ-UHFFFAOYSA-N 0.000 description 1
- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 description 1
- OXYZDRAJMHGSMW-UHFFFAOYSA-N 3-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCl OXYZDRAJMHGSMW-UHFFFAOYSA-N 0.000 description 1
- SEGKJLWPIPSYSC-UHFFFAOYSA-N 3-ethyloctane-1,8-diol Chemical compound OCCC(CC)CCCCCO SEGKJLWPIPSYSC-UHFFFAOYSA-N 0.000 description 1
- RDFQSFOGKVZWKF-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanoic acid Chemical compound OCC(C)(C)C(O)=O RDFQSFOGKVZWKF-UHFFFAOYSA-N 0.000 description 1
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- KBQVDAIIQCXKPI-UHFFFAOYSA-N 3-trimethoxysilylpropyl prop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C=C KBQVDAIIQCXKPI-UHFFFAOYSA-N 0.000 description 1
- CCOQPGVQAWPUPE-UHFFFAOYSA-N 4-tert-butylcyclohexan-1-ol Chemical compound CC(C)(C)C1CCC(O)CC1 CCOQPGVQAWPUPE-UHFFFAOYSA-N 0.000 description 1
- 229940091886 4-tert-butylcyclohexanol Drugs 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 1
- MBXULDRFQBQSSK-UHFFFAOYSA-N N'-[3-[methoxy-[(2-methylpropan-2-yl)oxy]silyl]propyl]ethane-1,2-diamine Chemical compound NCCNCCC[SiH](OC(C)(C)C)OC MBXULDRFQBQSSK-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- LFOXEOLGJPJZAA-UHFFFAOYSA-N [(2,6-dimethoxybenzoyl)-(2,4,4-trimethylpentyl)phosphoryl]-(2,6-dimethoxyphenyl)methanone Chemical compound COC1=CC=CC(OC)=C1C(=O)P(=O)(CC(C)CC(C)(C)C)C(=O)C1=C(OC)C=CC=C1OC LFOXEOLGJPJZAA-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本出願は、2018年10月4日出願の日本出願第2018−189221号に基づく優先権を主張し、前記日本出願に記載された全ての記載内容を援用するものである。
光ファイバの側圧特性を向上する観点から、プライマリ樹脂層のヤング率を低減することが望ましいが、プライマリ樹脂層のヤング率が低くなるに伴い、プライマリ樹脂層の強度が低下して、光ファイバにボイドが発生し易くなる。
本開示によれば、ボイドの発生が抑制され、光ファイバの側圧特性を向上する樹脂層を形成できる光ファイバ被覆用の樹脂組成物、及び、当該樹脂組成物から形成されるプライマリ樹脂層を備える光ファイバを提供することができる。
最初に、本開示の実施形態の内容を列記して説明する。本開示の一態様に係る樹脂組成物は、ウレタン(メタ)アクリレートオリゴマー、フェノキシ基を有するモノマー、光重合開始剤及びシランカップリング剤を含有するベース樹脂と、疎水性の無機酸化物粒子とを含み、無機酸化物粒子の含有量が、樹脂組成物の総量を基準として1質量%以上45質量%以下である。
本開示の実施形態に係る樹脂組成物及び光ファイバの具体例を、必要により図面を参照しつつ説明する。なお、本発明はこれらの例示に限定されず、請求の範囲によって示され、請求の範囲と均等の意味及び範囲内でのすべての変更が含まれることが意図される。以下の説明では、図面の説明において同一の要素には同一の符号を付し、重複する説明を省略する。
本実施形態に係る樹脂組成物は、ウレタン(メタ)アクリレートオリゴマー、フェノキシ基を有するモノマー、光重合開始剤及びシランカップリング剤を含有するベース樹脂と、疎水性の無機酸化物粒子とを含む。
本実施形態に係るベース樹脂は、ウレタン(メタ)アクリレートオリゴマー、フェノキシ基を有するモノマー、光重合開始剤及びシランカップリング剤を含有する。フェノキシ基を有するモノマーを用いることで、ボイドの発生が抑制され、光ファイバの側圧特性を向上できる樹脂層を形成できる。
本実施形態に係る無機酸化物粒子は、その表面が疎水処理されている。本実施形態に係る疎水処理とは、無機酸化物粒子の表面に疎水性の基が導入されていることをいう。疎水性の基が導入された無機酸化物粒子は、樹脂組成物中の分散性に優れている。疎水性の基は、(メタ)アクリロイル基、ビニル基等の反応性基、又は、炭化水素基(例えば、アルキル基)、アリール基(例えば、フェニル基)等の非反応性基であってもよい。無機酸化物粒子が反応性基を有する場合、ヤング率が高い樹脂層を形成し易くなる。
図1は、本実施形態に係る光ファイバの一例を示す概略断面図である。光ファイバ10は、コア11及びクラッド12を含むガラスファイバ13と、ガラスファイバ13の外周に設けられたプライマリ樹脂層14及びセカンダリ樹脂層15を含む被覆樹脂層16とを備えている。
(オリゴマー)
オリゴマーとして、分子量4000のポリプロピレングリコール、イソホロンジイソシアネート、ヒドロキシエチルアクリレート及びメタノールを反応させることにより得られたウレタンアクリレートオリゴマーを準備した。
フェノキシ基を有するモノマーとして、ノニルフェノールEO変性アクリレート(東亞合成株式会社の商品名「アロニックスM−113」、n≒4)、ノニルフェノールEO変性アクリレート(東亞合成株式会社の商品名「アロニックスM−111、n≒1)、フェノールEO変性アクリレート(東亞合成株式会社の商品名「アロニックスM−101A、n≒2)、フェノールEO変性アクリレート(東亞合成株式会社の商品名「アロニックスM−102、n≒4)、フェノキシエチルアクリレート(共栄化学株式会社の商品名「ライトアクリレートPO−A」)、及び3−フェノキシベンジルアクリレート(共栄化学株式会社の商品名「ライトアクリレートPOB−A」)、2−ヒドロキシ−3−フェノキシプロピルアクリレート(共栄化学株式会社の商品名「エポキシエステルM−600A」)を準備した。
フェノキシ基を有しないモノマーとして、N−ビニルカプロラクタム及び1,6−ヘキサンジオールジアクリレートを準備した。
光重合開始剤として、2,4,6−トリメチルベンゾイルジフェニルホスフィンオキシドを準備した。
シランカップリング剤として、3−メルカプトプロピルトリメトキシシランを準備した。
無機酸化物粒子として、平均粒径が10nm以上15nm以下の疎水性シリカ粒子、平均粒径が70nm以上100nm以下の疎水性シリカ粒子、平均粒径が250nm以上350nm以下の疎水性シリカ粒子、及び平均粒径が450nm以上640nm以下の疎水性シリカ粒子を準備した。これらのシリカ粒子は、メタクリロイル基を有しており、メチルエチルケトン(MEK)に分散されていた。
まず、上記オリゴマー、モノマー、光重合開始剤及びシランカップリング剤を混合して、ベース樹脂を調製した。次いで、ベース樹脂とシリカ粒子とを混合した後、分散媒であるMEKの大部分を減圧除去して、実施例及び比較例の樹脂組成物をそれぞれ作製した。なお、樹脂組成物中に残存しているMEKの含有量は、5質量%以下であった。
スピンコータを用いて、樹脂組成物をポリエチレンテレフタレート(PET)フィルムの上に塗布した後、無電極UVランプシステム(Dバルブ)(ヘレウス製)を用いて、1000±100mJ/cm2の条件で硬化させ、PETフィルム上に厚み200±20μmの樹脂層を形成した。樹脂層をPETフィルムから剥がし、樹脂フィルムを得た。
分子量600のポリプロピレングリコール、2,4−トリレンジイソシアネート及び2−ヒドロキシエチルアクリレートの反応物であるウレタンアクリレートオリゴマー40質量部と、イソボルニルアクリレート35質量部と、ビスフェノールAジグリシジルエーテル アクリル酸付加物24質量部と、2,4,6−トリメチルベンゾイルジフェニルホスフィンオキシド0.5質量部と、1−ヒドロキシシクロヘキシルフェニルケトン0.5質量部とを混合して、セカンダリ樹脂層用の樹脂組成物A1を作製した。
10mの光ファイバを85℃で湿度85%の条件下で120日間保管した後、−40℃に16時間置いて、直径10μm以上のボイドの有無を顕微鏡で観察した。光ファイバ1m当たりのボイドの数が1個未満の場合を「A」、ボイドの数が1〜2個の場合を「B」、ボイドの数が2個を超える場合を「C」と評価した。
サンドペーパーで表面を覆った280mm径のボビンに、光ファイバを単層状に巻き付けた時の1550nmの波長の光の伝送損失を、OTDR(Optical Time Domain Reflectometer)法により測定した。また、サンドペーパーのない280mm径のボビンに、光ファイバ10を単層状に巻き付けた時の1550nmの波長の光の伝送損失を、OTDR法により測定した。測定した伝送損失の差を求め、伝送損失差が0.6dB/km以下の場合を側圧特性「OK」と、伝送損失差が0.6dB/km超の場合を側圧特性「NG」と判断した。
Claims (8)
- ウレタン(メタ)アクリレートオリゴマー、フェノキシ基を有するモノマー、光重合開始剤及びシランカップリング剤を含有するベース樹脂と、疎水性の無機酸化物粒子とを含む樹脂組成物であり、
前記無機酸化物粒子の含有量が、前記樹脂組成物の総量を基準として1質量%以上45質量%以下である、光ファイバ被覆用の樹脂組成物。 - 前記フェノキシ基を有するモノマーの含有量が、前記ベース樹脂の総量を基準として0.5質量%以上60質量%以下である、請求項1に記載の樹脂組成物。
- 前記無機酸化物粒子が、二酸化ケイ素、二酸化ジルコニウム、酸化アルミニウム、酸化マグネシウム、酸化チタン、酸化スズ及び酸化亜鉛からなる群より選ばれる少なくとも1種である、請求項1又は請求項2に記載の樹脂組成物。
- 前記無機酸化物粒子の平均一次粒径が、650nm以下である、請求項1から請求項3のいずれか一項に記載の樹脂組成物。
- 前記フェノキシ基を有するモノマーが、フェノールEO変性(メタ)アクリレート、ノニルフェノールEO変性(メタ)アクリレート、フェノキシエチル(メタ)アクリレート、2−ヒドロキシ−3−フェノキシプロピル(メタ)アクリレート、及び3−フェノキシベンジル(メタ)アクリレートからなる群より選ばれる少なくとも1種である、請求項1から請求項4のいずれか一項に記載の樹脂組成物。
- 請求項1から請求項5のいずれか一項に記載の樹脂組成物を含む、光ファイバのプライマリ被覆材料。
- コア及びクラッドを含むガラスファイバと、
前記ガラスファイバに接して該ガラスファイバを被覆するプライマリ樹脂層と、
前記プライマリ樹脂層を被覆するセカンダリ樹脂層と、を備え、
前記プライマリ樹脂層が、請求項1から請求項5のいずれか一項に記載の樹脂組成物の硬化物からなる、光ファイバ。 - 前記樹脂組成物の硬化物のヤング率が、23℃±2℃で4MPa以下である、請求項7に記載の光ファイバ。
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EP (1) | EP3862372A4 (ja) |
JP (1) | JPWO2020071544A1 (ja) |
KR (1) | KR20210071002A (ja) |
CN (1) | CN112789306A (ja) |
TW (1) | TWI828776B (ja) |
WO (1) | WO2020071544A1 (ja) |
Families Citing this family (3)
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CN111902442B (zh) * | 2018-04-02 | 2023-04-04 | 住友电气工业株式会社 | 树脂组合物、光纤用二次被覆材料及光纤 |
WO2019203236A1 (ja) | 2018-04-16 | 2019-10-24 | 住友電気工業株式会社 | 光ファイバ |
CN113939755A (zh) * | 2019-06-19 | 2022-01-14 | 住友电气工业株式会社 | 光纤 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0269706A (ja) * | 1988-09-06 | 1990-03-08 | Sumitomo Electric Ind Ltd | 被覆光ファイバ |
JP2001066474A (ja) * | 1999-07-27 | 2001-03-16 | Lucent Technol Inc | モード結合緩衝化光ファイバ装置及びその製造方法 |
JP2003315639A (ja) * | 2002-02-21 | 2003-11-06 | Sumitomo Electric Ind Ltd | 被覆光ファイバ心線、コネクタ付被覆光ファイバ心線、及び、光ファイバケーブル |
JP2010511770A (ja) * | 2006-12-05 | 2010-04-15 | ディーエスエム アイピー アセッツ ビー.ブイ. | 放射線硬化性被覆組成物 |
US20120321265A1 (en) * | 2009-11-26 | 2012-12-20 | Lidia Terruzzi | Optical fiber with double coating |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU723284B2 (en) * | 1997-01-20 | 2000-08-24 | Sumitomo Electric Industries, Ltd. | Coated optical fiber and method of making the same |
JP4555061B2 (ja) * | 2004-09-28 | 2010-09-29 | Jsr株式会社 | 光ファイバアップジャケット用放射線硬化型液状樹脂組成物 |
EP1995266A4 (en) * | 2006-03-15 | 2012-02-08 | Hitachi Chemical Co Ltd | PHENOXY RESIN FOR OPTICAL MATERIAL, RESIN COMPOSITION FOR OPTICAL MATERIAL, RESIN FILM FOR OPTICAL MATERIAL AND OPTICAL WAVEGUIDE THEREOF |
JP5962094B2 (ja) | 2012-03-16 | 2016-08-03 | 凸版印刷株式会社 | 積層基板の製造方法 |
JP2017007896A (ja) * | 2015-06-23 | 2017-01-12 | 住友電気工業株式会社 | 光ファイバ及び光ファイバテープ心線 |
JP6647492B2 (ja) | 2017-05-11 | 2020-02-14 | 株式会社エフ・イー・シー | 非接触駆動伝達装置 |
CN111902442B (zh) * | 2018-04-02 | 2023-04-04 | 住友电气工业株式会社 | 树脂组合物、光纤用二次被覆材料及光纤 |
-
2019
- 2019-10-04 TW TW108136032A patent/TWI828776B/zh active
- 2019-10-04 US US16/761,544 patent/US20200262749A1/en not_active Abandoned
- 2019-10-04 KR KR1020217011693A patent/KR20210071002A/ko unknown
- 2019-10-04 WO PCT/JP2019/039344 patent/WO2020071544A1/ja active Application Filing
- 2019-10-04 CN CN201980064377.4A patent/CN112789306A/zh active Pending
- 2019-10-04 JP JP2020551116A patent/JPWO2020071544A1/ja active Pending
- 2019-10-04 EP EP19869349.1A patent/EP3862372A4/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0269706A (ja) * | 1988-09-06 | 1990-03-08 | Sumitomo Electric Ind Ltd | 被覆光ファイバ |
JP2001066474A (ja) * | 1999-07-27 | 2001-03-16 | Lucent Technol Inc | モード結合緩衝化光ファイバ装置及びその製造方法 |
JP2003315639A (ja) * | 2002-02-21 | 2003-11-06 | Sumitomo Electric Ind Ltd | 被覆光ファイバ心線、コネクタ付被覆光ファイバ心線、及び、光ファイバケーブル |
JP2010511770A (ja) * | 2006-12-05 | 2010-04-15 | ディーエスエム アイピー アセッツ ビー.ブイ. | 放射線硬化性被覆組成物 |
US20120321265A1 (en) * | 2009-11-26 | 2012-12-20 | Lidia Terruzzi | Optical fiber with double coating |
Also Published As
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EP3862372A4 (en) | 2022-07-20 |
KR20210071002A (ko) | 2021-06-15 |
WO2020071544A1 (ja) | 2020-04-09 |
US20200262749A1 (en) | 2020-08-20 |
EP3862372A1 (en) | 2021-08-11 |
CN112789306A (zh) | 2021-05-11 |
TWI828776B (zh) | 2024-01-11 |
TW202033581A (zh) | 2020-09-16 |
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