JPWO2008072627A1 - Perfume beads and cigarette filters - Google Patents

Perfume beads and cigarette filters Download PDF

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JPWO2008072627A1
JPWO2008072627A1 JP2008549318A JP2008549318A JPWO2008072627A1 JP WO2008072627 A1 JPWO2008072627 A1 JP WO2008072627A1 JP 2008549318 A JP2008549318 A JP 2008549318A JP 2008549318 A JP2008549318 A JP 2008549318A JP WO2008072627 A1 JPWO2008072627 A1 JP WO2008072627A1
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fragrance
glucan
bead
film
perfume
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JP4876296B2 (en
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正浩 千田
正浩 千田
泰宏 中川
泰宏 中川
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Japan Tobacco Inc
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Japan Tobacco Inc
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    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
    • A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes

Abstract

香料ビーズは、粒子状担体と、前記粒子状担体により支持されたグルカン膜と、香料を含む。香料は、グルカン膜によりその香気の放出が抑制されているが、前記グルカン膜が、タバコ主流煙との接触によりその少なくとも一部が溶解することにより、その香気が放出されるように、香料ビーズにより担持されている。The perfume beads include a particulate carrier, a glucan membrane supported by the particulate carrier, and a perfume. In the fragrance, the release of the fragrance is suppressed by the glucan film. It is carried by.

Description

本発明は、香料ビーズおよびこれを含むシガレット用フィルタに関する。   The present invention relates to a perfume bead and a cigarette filter including the same.

葉タバコ刻に添加される香料には、ケーシングソースとしての第１香料とトップフレーバーとしての第２香料が含まれる。第２香料の成分は、比較的揮発性が高く、また熱分解を受けやすい。したがって、第２香料を有するシガレットは、その保管中に第２香料が揮散し、喫煙時の香喫味が減少するばかりでなく、チャコールフィルタを備えたシガレットにおいては、第２香料がチャコールに移行・吸着されて一層香喫味が減少する。第２香料を吸着したチャコールは、タバコの主流煙中の成分除去能が低下する。   The fragrance | flavor added to a tobacco leaf includes the 1st fragrance | flavor as a casing source, and the 2nd fragrance | flavor as a top flavor. The component of the 2nd fragrance | flavor is comparatively high in volatility, and is easy to receive thermal decomposition. Therefore, in the cigarette having the second fragrance, the second fragrance is volatilized during the storage, and not only the taste when smoking is reduced, but in the cigarette equipped with the charcoal filter, the second fragrance is transferred to the charcoal. The flavor is further reduced by adsorption. The charcoal adsorbing the second fragrance has a reduced ability to remove components in the mainstream smoke of tobacco.

特許第２７０９０７７号明細書は、第２香料を、天然多糖類でマイクロカプセル化し、そのマイクロカプセルをいわゆるキャビティ充填によりタバコフィルターに添加することを開示している。香料は、天然多糖類からなるマイクロカプセル内に封入されているため、保管時の香料の移行、揮散が生じず、したがって、チャコールフィルタとともに用いても、チャコールフィルタの、タバコの主流煙中の成分除去能を低下させることもない。   Japanese Patent No. 2,709,077 discloses that the second perfume is microencapsulated with a natural polysaccharide and the microcapsules are added to the tobacco filter by so-called cavity filling. Since the fragrance is encapsulated in a microcapsule made of natural polysaccharide, the fragrance does not migrate or volatilize during storage. Therefore, even when used with a charcoal filter, the charcoal filter is a component in the mainstream smoke of tobacco. It does not reduce the removal ability.

しかしながら、マイクロ化カプセル中の香料は、シガレットの喫煙時に指で押し潰したり、擦り潰したりすること（外力の適用）によって、初めて味わうことができるものである。しかし、外力の適用は面倒であり、また外力の適用によって流出した香料はフィルタ全体に均一に分布し得ず、その結果喫煙時の喫味が一定しない。   However, the fragrance | flavor in a micro-ized capsule can be tasted for the first time by crushing with a finger | toe at the time of smoking of a cigarette, or crushing (application of external force). However, the application of external force is troublesome, and the fragrance discharged by the application of external force cannot be uniformly distributed throughout the filter, and as a result, the taste during smoking is not constant.

したがって、本発明は、非喫煙時に香料の揮散・移行を抑制でき、喫煙時には外力の適用を要することなく、香喫味を安定に味わうことができる香料ビーズおよびシガレット用フィルタを提供することを目的とする。   Accordingly, an object of the present invention is to provide a fragrance bead and a cigarette filter that can suppress the volatilization and migration of the fragrance during non-smoking, and can stably taste the fragrance without requiring the application of external force during smoking. To do.

本発明の１つの側面によると、香料ビーズであって、粒子状担体と、前記粒子状担体により支持されたグルカン膜と、香料を包含し、前記香料は、前記グルカン膜によりその香気の放出が抑制されているが、前記グルカン膜が、タバコ主流煙との接触によりその少なくとも一部が溶解することにより、その香気が放出されるように、香料ビーズにより担持されている香料ビーズが提供される。   According to one aspect of the present invention, a perfume bead comprising a particulate carrier, a glucan membrane supported by the particulate carrier, and a perfume, wherein the perfume releases the aroma by the glucan membrane. Although being suppressed, a perfume bead supported by a perfume bead is provided such that the aroma is released when at least a part of the glucan membrane is dissolved by contact with mainstream tobacco smoke. .

また、本発明の他の側面によると、本発明の香料ビーズを含むシガレット用フィルタが提供される。   Moreover, according to the other aspect of this invention, the filter for cigarettes containing the fragrance | flavor bead of this invention is provided.

図１は、本発明の１つの態様に係る香料ビーズの拡大概略断面図。FIG. 1 is an enlarged schematic cross-sectional view of a fragrance bead according to one embodiment of the present invention. 図２は、本発明の他の態様に係る香料ビーズの拡大概略断面図。FIG. 2 is an enlarged schematic cross-sectional view of a fragrance bead according to another embodiment of the present invention. 図３は、本発明の１つの態様に係るフィルタを備えたシガレットの概略縦断面図。FIG. 3 is a schematic longitudinal sectional view of a cigarette including a filter according to one aspect of the present invention. 図４は、本発明の他の態様に係るフィルタを備えたシガレットの概略縦断面図。FIG. 4 is a schematic longitudinal sectional view of a cigarette provided with a filter according to another aspect of the present invention.

以下、図面を参照しながら、本発明の種々の態様を説明する。全図に渡って、同様の要素は、同じ符号で示されている。   Hereinafter, various aspects of the present invention will be described with reference to the drawings. Throughout the drawings, similar elements are designated with the same reference numerals.

本発明の香料ビーズは、粒子状担体と、前記粒子状担体により支持されたグルカン膜と、香料を包含する。香料は、グルカン膜によりその香気の放出が抑制されているが、前記グルカン膜が、タバコ主流煙との接触によりその少なくとも一部が溶解することにより、その香気が放出されるように、香料ビーズにより担持されている。   The perfume beads of the present invention include a particulate carrier, a glucan membrane supported by the particulate carrier, and a perfume. In the fragrance, the release of the fragrance is suppressed by the glucan film, but the fragrance beads are released so that the fragrance is released when at least part of the glucan film is dissolved by contact with the mainstream tobacco smoke. It is carried by.

本発明の第１の態様において、グルカン膜は、香料を含有し、粒子状担体の表面を直接覆う。第１の態様による香料ビーズは、粒子状担体と、前記粒子状担体の表面を覆って設けられ、香料を保持したグルカン膜を備える。   In the first aspect of the present invention, the glucan film contains a fragrance and directly covers the surface of the particulate carrier. The fragrance bead according to the first aspect includes a particulate carrier and a glucan film provided so as to cover the surface of the particulate carrier and holding the fragrance.

本発明の第２の態様において、香料は固体香料であり、これが粒子状担体の表面を直接覆い、この固体香料膜をグルカン膜が覆う。第２の態様による香料ビーズは、粒子状担体、前記担体の表面を覆って設けられたメントール膜、および前記メントール膜の表面を覆って設けられたグルカン膜を備える。   In the second aspect of the present invention, the fragrance is a solid fragrance, which directly covers the surface of the particulate carrier, and this solid fragrance film is covered by a glucan film. The flavor bead according to the second aspect includes a particulate carrier, a menthol membrane provided so as to cover the surface of the carrier, and a glucan membrane provided so as to cover the surface of the menthol membrane.

本発明に使用される粒子状担体は、炭酸カルシウム粒子、活性炭粒子、糖結晶粒子（例えば、グラニュー糖）、コーヒー豆粒子等によって構成することができる。粒子状担体は、平均粒径が７５μｍ〜２０００μｍのもの、例えば平均粒径が７５μｍ〜３５０μｍのものを好適に使用することができる。   The particulate carrier used in the present invention can be composed of calcium carbonate particles, activated carbon particles, sugar crystal particles (for example, granulated sugar), coffee bean particles and the like. As the particulate carrier, those having an average particle diameter of 75 μm to 2000 μm, for example, those having an average particle diameter of 75 μm to 350 μm can be suitably used.

グルカン膜は、例えば、プルラン、マルトデキストリン、ヒドロキシプロピルセルロースなどにより構成され、水溶性である。   The glucan membrane is composed of, for example, pullulan, maltodextrin, hydroxypropylcellulose, etc. and is water-soluble.

香料としては、食品用香料およびタバコ用香料を用いることができる。そのような香料の例を挙げると、ラベンダー、シナモン、カルダモン、セレリー、丁子、カスカリラ、ナツメグ、サンダルウッド、ベルガモット、ゼラニウム、ハチミツエッセンス、ローズ油、バニラ、レモン、オレンジ、ハッカ、ケイ皮、キャラウェー、コニャック、ジャスミン、カモミール、メントール、カシャ、イランイラン、セージ、スペアミント、フェンネル、ヒメント、ジンジャ、アニス、コリアンダ、コーヒー等の精油等である。   As the fragrance, a food fragrance and a tobacco fragrance can be used. Examples of such fragrances include lavender, cinnamon, cardamom, celery, clove, cascarilla, nutmeg, sandalwood, bergamot, geranium, honey essence, rose oil, vanilla, lemon, orange, mint, cinnamon, caraway , Essential oils such as cognac, jasmine, chamomile, menthol, kasha, ylang ylang, sage, spearmint, fennel, himent, ginger, anise, coriander, coffee.

図１は、本発明の第１の態様に係る香料ビーズ１０の拡大概略断面図である。この香料ビーズ１０は、粒子状担体（核）１２の表面をグルカン膜１４が覆っているものである。グルカン膜１４中には、香料が含有されている。   FIG. 1 is an enlarged schematic cross-sectional view of a fragrance bead 10 according to the first embodiment of the present invention. In this fragrance bead 10, the surface of a particulate carrier (core) 12 is covered with a glucan film 14. The glucan film 14 contains a fragrance.

香料を含有するグルカン膜１４は、香料とグルカンの水溶液または水分散液等から形成することができる。この水溶液または水分散液において、香料は、グルカンの重量の２０％以下に相当する量（０％を超える）で用いることが望ましい。グルカン膜１４の厚さに特に制限はないが、喫煙時の香料の放出能の観点から、最終香料ビーズの重量の０．２５％〜５％に相当する量のグルカンを用いてグルカン膜を形成することが好ましい。   The glucan film 14 containing a fragrance can be formed from an aqueous solution or an aqueous dispersion of a fragrance and glucan. In this aqueous solution or aqueous dispersion, the fragrance is desirably used in an amount corresponding to 20% or less of the weight of glucan (exceeding 0%). Although there is no restriction | limiting in particular in the thickness of the glucan film | membrane 14, from a viewpoint of the discharge | release ability of the fragrance | flavor at the time of smoking, a glucan film | membrane is formed using the amount of glucan equivalent to 0.25-5% of the weight of a final fragrance | flavor bead. It is preferable to do.

第１の態様による香料ビーズは、例えば、次の方法により製造することができる。すなわち、炭酸カルシウム等の粒子状担体を、流動造粒乾燥機に入れ、例えば８０℃以下の温風を吹き込みながら、上記香料を含有するグルカン水溶液または水分散液を連続的または間欠的に粒子状担体の表面に噴霧し、乾燥させる。その場合、香料の種類はグルカン溶液の組成によっては速やかに冷却させる。こうして、粒子状担体の表面に、香料を保持したグルカン膜が形成される。   The perfume beads according to the first aspect can be produced, for example, by the following method. That is, a particulate carrier such as calcium carbonate is put into a fluidized granulation dryer, and the glucan aqueous solution or aqueous dispersion containing the fragrance is continuously or intermittently particulated while blowing warm air of 80 ° C. or less, for example. Spray onto the surface of the carrier and dry. In that case, depending on the composition of the glucan solution, the type of the fragrance is quickly cooled. Thus, a glucan film holding a fragrance is formed on the surface of the particulate carrier.

第１の態様による香料ビーズは、香料が、ガス透過性の低いグルカン膜に内包されているので、保管時における香料の揮散、変質を低減させることが可能となる。そして、喫煙時にタバコ主流煙と接触した際にはじめて、タバコ主流煙中の主に高極性成分（水分等）によりグルカン膜が一部溶解し、内包された香料成分が主流煙中に拡散し、香料の香喫味を安定して味わうことができる。本発明の香料ビーズは、香喫味を味わうために、マイクロカプセルのように外力の適用を要することがない。   Since the fragrance | flavor by the 1st aspect is enclosed in the glucan film | membrane with low gas permeability, the fragrance | flavor volatilization at the time of storage and a quality change can be reduced. And only when it comes into contact with tobacco mainstream smoke during smoking, the glucan film is partially dissolved mainly by high-polar components (moisture etc.) in the tobacco mainstream smoke, and the encapsulated fragrance component diffuses into the mainstream smoke, It is possible to taste the flavor of the fragrance stably. The fragrance beads of the present invention do not require application of external force unlike microcapsules in order to taste the savory taste.

図２は、本発明の第２の態様に係る香料ビーズ２０の拡大概略断面図である。この香料ビーズ２０は、粒子状担体（核）２２の表面全体をメントールのような固体香料膜２４が覆い、固体香料膜２４の表面全体をグルカン膜２６が覆っているものである。   FIG. 2 is an enlarged schematic cross-sectional view of the fragrance bead 20 according to the second aspect of the present invention. In this fragrance bead 20, the entire surface of the particulate carrier (core) 22 is covered with a solid fragrance film 24 such as menthol, and the entire surface of the solid fragrance film 24 is covered with a glucan film 26.

固体香料膜２４は、後述するように、メントールのような固体香料の結晶を微粉末化し、粒子状担体１２と混合し、固体香料微粉末を粒子状担体２２に付着させ、これを粒子状担体２２上で加熱溶融した後、冷却により再結晶化させることにより形成することができる。この冷却時にメントール等の固体香料を柱状結晶となるまで成長させないようにするために、固体香料に脂肪酸、グリセリン、プロピレングリコール等の結晶成長抑制剤を添加しておくことが好ましい。この結晶成長抑制剤は、メントール等の固体香料の重量の０．１〜１．０％に相当する量で用いることができる。また、固体香料膜１４には、固体香料以外の香料を含めることができる。   As will be described later, the solid fragrance film 24 pulverizes a solid fragrance crystal such as menthol, mixes it with the particulate carrier 12, and attaches the solid fragrance fine powder to the particulate carrier 22. It can be formed by heating and melting on 22 and then recrystallizing by cooling. In order to prevent the solid fragrance such as menthol from growing until it becomes columnar crystals during cooling, it is preferable to add a crystal growth inhibitor such as fatty acid, glycerin, propylene glycol or the like to the solid fragrance. This crystal growth inhibitor can be used in an amount corresponding to 0.1 to 1.0% of the weight of a solid fragrance such as menthol. Further, the solid fragrance film 14 can include a fragrance other than the solid fragrance.

固体香料膜２４の厚さに特に制限はないが、固体香料膜２４は、最終香料ビーズの重量の１〜２０％に相当する量の固体香料により形成することが好ましい。   Although there is no restriction | limiting in particular in the thickness of the solid fragrance | flavor film | membrane 24, It is preferable to form the solid fragrance | flavor film | membrane 24 with the solid fragrance | flavor of the quantity corresponded to 1-20% of the weight of a final fragrance | flavor bead.

グルカン膜２６は、グルカンの水溶液、水分散液等から形成することができる。グルカン膜２６の厚さに特に制限はないが、グルカン膜２６は、非喫煙時の固体香料の保香性および喫煙時のメントールの放出能の観点から、最終香料ビーズの重量の０．２５〜５％に相当する量のグルカンにより形成することが好ましい。   The glucan film 26 can be formed from an aqueous solution of glucan, an aqueous dispersion, or the like. The thickness of the glucan film 26 is not particularly limited, but the glucan film 26 has a weight of 0.25 to 0.25 of the weight of the final fragrance bead from the viewpoint of the fragrance retention property of the solid fragrance when not smoked and the ability to release menthol when smoked. It is preferable to form with an amount of glucan corresponding to 5%.

第２の態様に係る香料ビーズは、例えば、次の方法により製造することができる。すなわち、粒子状担体と固体香料結晶の微粉末および必要に応じて結晶成長抑制剤、他の香料をリボンミキサーで混合・加熱する。この混合初期には、固体香料結晶の微粉末が各粒子状担体の表面に付着し、加温温度が固体香料の融点（例えばメントールでは約４２℃）となったところで固体香料結晶の微粉末が溶融し始める。攪拌混合を続けることで、溶融した固体香料が各粒子状担体の表面に均一に塗布される。この加温混合後、例えばリボンミキサー缶体を冷却するか、あるいはリボンミキサー内に冷風を吹き込むことにより、粒子状担体を速やかに冷却する。この冷却により、溶融した固体香料は再結晶化し、各粒子状担体の表面を膜状に覆うことができる。この固体香料膜で覆われた粒子状担体を、流動造粒乾燥機に入れ、例えば４０℃以下の温風を吹き込みながら、グルカンの水溶液あるいはグルカンの水分散液等を間欠的に噴霧し、冷却する。こうして、粒子状担体の表面に形成された固体香料膜の表面にグルカンの皮膜が形成される。   The perfume beads according to the second aspect can be produced, for example, by the following method. That is, a particulate carrier, a fine powder of solid fragrance crystals, and if necessary, a crystal growth inhibitor and other fragrances are mixed and heated with a ribbon mixer. At the initial stage of mixing, the fine powder of the solid fragrance crystals adheres to the surface of each particulate carrier, and when the heating temperature reaches the melting point of the solid fragrance (for example, about 42 ° C. in menthol), the fine powder of the solid fragrance crystals is formed. Start to melt. By continuing the stirring and mixing, the molten solid fragrance is uniformly applied to the surface of each particulate carrier. After this warming mixing, for example, the ribbon mixer can is cooled, or cold air is blown into the ribbon mixer to quickly cool the particulate carrier. By this cooling, the melted solid perfume can be recrystallized and the surface of each particulate carrier can be covered in a film form. The particulate carrier covered with the solid perfume film is put into a fluidized granulator and dried, for example, by spraying an aqueous solution of glucan or an aqueous dispersion of glucan intermittently while blowing warm air of 40 ° C. or lower, and cooling. To do. Thus, a glucan film is formed on the surface of the solid fragrance film formed on the surface of the particulate carrier.

あるいは、上に述べたように粒子状担体の表面に固体香料膜を設けた後、そのままリボンミキサー中で、または転動造粒機中で、固体香料膜を有する粒子状担体にグルカンの水溶液あるいは水分散液を噴霧し、固体香料膜をグルカン膜で覆った後、冷却することによっても、第２の態様に係る香料ビーズを製造することができる。   Alternatively, as described above, after providing a solid fragrance film on the surface of the particulate carrier, in a ribbon mixer or in a rolling granulator, an aqueous solution of glucan or The fragrance beads according to the second embodiment can also be produced by spraying an aqueous dispersion, covering the solid fragrance film with a glucan film, and then cooling.

第２の態様による香料ビーズは、粒子状担体の表面に設けられた固体香料膜が、ガス透過性の低いグルカン膜により覆われているので、通常の保管時にメントールが揮散したり、チャコールにより吸着されたりすることがない。シガレットを喫煙することにより発生する主流煙中の水分等の親水性成分と接触すると、グルカン膜が一部形状変化し、溶解することにより下層の固体香料膜から香気が放出され、香料の香喫味を味わうことができる。本発明の香料ビーズは、香喫味を味わうために、マイクロカプセルのように外力の適用を要することがない。   In the fragrance beads according to the second aspect, since the solid fragrance film provided on the surface of the particulate carrier is covered with a glucan film having low gas permeability, menthol is volatilized during normal storage or adsorbed by charcoal. It will never be done. When it comes into contact with hydrophilic components such as moisture in the mainstream smoke generated by smoking cigarettes, the glucan film partially changes its shape, and when dissolved, the fragrance is released from the lower solid fragrance film, and the flavor of the fragrance Can taste. The fragrance beads of the present invention do not require application of external force unlike microcapsules in order to taste the savory taste.

本発明のシガレット用フィルタは、本発明の香料ビーズを含む。   The cigarette filter of the present invention includes the fragrance bead of the present invention.

以下、図３および図４を参照して、本発明のフィルタを有するシガレットを説明する。図３および図４において、同様の要素は、同じ参照符号により示されている。   Hereinafter, with reference to FIG. 3 and FIG. 4, the cigarette which has the filter of this invention is demonstrated. 3 and 4, like elements are denoted by the same reference numerals.

図３は、本発明の１つの態様に係るシガレット用フィルタを備えたシガレット（フィルタ付きシガレット）３０の概略断面図である。フィルタ付きシガレット３０は、タバコ刻等のタバコ充填材３２１をシガレット巻紙３２２で巻装したシガレット部３２を備える。シガレット部３２は、通常のシガレットと同様のものである。   FIG. 3 is a schematic cross-sectional view of a cigarette (cigarette with filter) 30 including a cigarette filter according to one aspect of the present invention. The cigarette 30 with a filter includes a cigarette portion 32 in which a tobacco filler 321 such as a tobacco cut is wound with a cigarette wrapping paper 322. The cigarette part 32 is the same as a normal cigarette.

シガレット部３２の一端には、フィルタ部３４が付設されている。フィルタ部３４はシガレット部３２の一端に直接接して設けられたチャコールフィルタセクション３４１と、主流煙の流れ方向に対しチャコールフィルタセクションの下流側端に設けられた香料ビーズ入りフィルタセクション３４２を備える。   A filter part 34 is attached to one end of the cigarette part 32. The filter unit 34 includes a charcoal filter section 341 provided in direct contact with one end of the cigarette unit 32 and a filter section 342 containing fragrance beads provided at the downstream end of the charcoal filter section with respect to the flow direction of mainstream smoke.

チャコールフィルタセクション３４１は、チャコール粒子３４１ｂを分散させた例えばセルロースアセテート繊維３４１ａをフィルタ巻取紙３４１ｃで巻装したものであり、通常のチャコールフィルタと同様のものである。   The charcoal filter section 341 is obtained by winding, for example, cellulose acetate fiber 341a in which charcoal particles 341b are dispersed with a filter web 341c, and is similar to a normal charcoal filter.

香料ビーズ入りフィルタセクション３４２は、本発明の香料ビーズＦＢを分散させた例えばセルロースアセテート繊維３４２ａをフィルタ巻取紙３４２ｂで巻装したものである。   The filter section 342 containing the fragrance beads is obtained by winding, for example, cellulose acetate fiber 342a in which the fragrance beads FB of the present invention are dispersed, with a filter web 342b.

フィルタセクション３２１および３２２からなるフィルタ部３４は、チップペーパ３６によりシガレット部３２に取り付けられている。   The filter section 34 including the filter sections 321 and 322 is attached to the cigarette section 32 by a chip paper 36.

図４は、本発明の別の態様に係るシガレット用フィルタを備えたシガレット（フィルタ付きシガレット）４０の概略断面図である。このフィルタ付きシガレット４０において、シガレット部３２にチップペーパ３６により取り付けられたフィルタ部４２は、シガレット部３２の一端に直接取り付けられたチャコールフィルタセクション３４１と、このチャコールフィルタセクション３４１と間隔を空けて設けられたプレーンフィルタセクション４２２を備え、その全体が、フィルタ巻取紙４６により巻装されている。プレーンフィルタセクション４２２は、例えばセルロースアセテート繊維４２２ａのトウからなる。チャコールフィルタセクション３４１とプレーンフィルタセクション４２２との間の空洞（キャビティ）４４には、本発明の香料ビーズＦＢが充填されている。   FIG. 4 is a schematic cross-sectional view of a cigarette (cigarette with filter) 40 including a cigarette filter according to another aspect of the present invention. In the cigarette 40 with a filter, the filter portion 42 attached to the cigarette portion 32 by the chip paper 36 is provided with a charcoal filter section 341 directly attached to one end of the cigarette portion 32, and spaced apart from the charcoal filter section 341. The entire plain filter section 422 is wound by a filter web 46. The plain filter section 422 is made of, for example, a tow of cellulose acetate fiber 422a. A cavity 44 between the charcoal filter section 341 and the plain filter section 422 is filled with the fragrance beads FB of the present invention.

以下、本発明を具体例により説明するが、本発明はそれらの具体例により限定されるものではない。   EXAMPLES Hereinafter, although this invention is demonstrated by a specific example, this invention is not limited by those specific examples.

例１
予め調製したプルラン１０重量％のプルラン水分散液に、コーヒーオイル２重量％を添加した。この混合液を、乳化機中で強攪拌（乳化機回転数２５００ｒｐｍ）し、香料分散液を調製した。他方、平均粒径２５０μｍの炭酸カルシウム粒子１００ｇを流動造粒乾燥機に入れ、７５℃の温風を０．６ｍ／秒の流速で吹き込みながら、速やかに上記香料分散液を間欠噴霧（噴霧１分後３０分噴霧停止サイクルの繰り返し）し、合計１０ｇの香料分散液を炭酸カルシウム粒子表面に噴霧し、乾燥した。その後、速やかに流動層内を室温まで冷却し、所望の香料ビーズを得た。Example 1
2% by weight of coffee oil was added to a 10% by weight pullulan aqueous dispersion prepared beforehand. This mixed solution was vigorously stirred in an emulsifier (emulsifier rotation speed: 2500 rpm) to prepare a fragrance dispersion. On the other hand, 100 g of calcium carbonate particles having an average particle size of 250 μm are put into a fluidized granulator and the above-described perfume dispersion is rapidly sprayed intermittently (spraying for 1 minute while blowing warm air at 75 ° C. at a flow rate of 0.6 m / second. After 30 minutes, the spray stop cycle was repeated, and a total of 10 g of the fragrance dispersion was sprayed on the surface of the calcium carbonate particles and dried. Thereafter, the inside of the fluidized bed was quickly cooled to room temperature to obtain desired fragrance beads.

例２
平均粒径２５０μｍの炭酸カルシウム粒子１００ｇを流動造粒乾燥機に入れ、３０℃の温風を１．０ｍ／秒の流速で吹き込みながら、バニリンを添加したタバコ用香料１重量％とプルラン９重量％を含む香料混合水溶液を連続的に噴霧し、合計５ｇの混合水溶液を炭酸カルシウム粒子表面に噴霧、乾燥した。その後、速やかに温風温度を室温まで下げ、０．４ｍ／秒の流速で冷却し、所望の香料ビーズを得た。Example 2
100 g of calcium carbonate particles having an average particle size of 250 μm are placed in a fluidized granulation dryer, and 1% by weight of a tobacco fragrance to which vanillin is added and 9% by weight of pullulan while blowing warm air at 30 ° C. at a flow rate of 1.0 m / second. The fragrance | flavor mixture aqueous solution containing was sprayed continuously, and the mixed aqueous solution of a total of 5g was sprayed and dried on the calcium carbonate particle surface. Thereafter, the temperature of the warm air was quickly lowered to room temperature and cooled at a flow rate of 0.4 m / sec to obtain desired fragrance beads.

例３
予め調製したプルラン１０重量％のプルラン水分散液に、コーヒーオイル１重量％およびレシチン０．５重量％を添加した。この混合液を、乳化機中で強攪拌（乳化機回転数７５００ｒｐｍ、１５分）し、香料分散液を調製した。他方、粒径２５０μｍ〜１．４ｍｍの粉砕コーヒー豆粒子３００ｇを転動流動造粒乾燥機（フロイント産業（株）製ＳＦＣ−ＭＩＮＩ）に入れ、底部回転目皿板を約５００ｒｐｍ、造粒防止用攪拌翼を約４００ｒｐｍで回転させ、７５℃の温風を０．６ｍ／秒の流速で吹き込み、粉砕コーヒー豆粒子の流動層を形成した。この流動層へ、上記香料分散液を４０℃に保温しながら、連続的に噴霧することにより、合計９０ｇの香料分散液をコーヒー豆粒子表面に噴霧し、乾燥した。その後、速やかに温風温度を室温まで下げ、０．４ｍ／秒の流速で冷却し、所望の香料ビーズを得た。Example 3
1% by weight of coffee oil and 0.5% by weight of lecithin were added to a 10% by weight pullulan aqueous dispersion prepared in advance. This liquid mixture was vigorously stirred in an emulsifier (emulsifier rotation speed: 7500 rpm, 15 minutes) to prepare a perfume dispersion. On the other hand, 300 g of pulverized coffee bean particles having a particle size of 250 μm to 1.4 mm are placed in a tumbling fluidized granulator / dryer (SFC-MINI manufactured by Freund Sangyo Co., Ltd.), and the bottom rotating plate is about 500 rpm for preventing granulation. The stirring blade was rotated at about 400 rpm, and warm air at 75 ° C. was blown at a flow rate of 0.6 m / second to form a fluidized bed of ground coffee bean particles. A 90 g total of the fragrance dispersion was sprayed onto the surface of the coffee bean particles and dried by continuously spraying the fragrance dispersion on the fluidized bed while keeping the temperature at 40 ° C. Thereafter, the temperature of the warm air was quickly lowered to room temperature and cooled at a flow rate of 0.4 m / sec to obtain desired fragrance beads.

例４
例１〜３でそれぞれ得られた香料ビーズをそれぞれ用いて、図３に示すフィルタ付きシガレットを作製した。それぞれの場合、フィルタセクション３４２に添加した香料ビーズの量は、フィルタ長１０ｍｍ当たり、最大１００ｍｇであった。これらシガレットは、保管時において、香料の香気が発生しなかった。しかしながら、このシガレットを喫煙すると、香料の香喫味を安定して味わうことができた。Example 4
The cigarette with a filter shown in FIG. 3 was produced using the fragrance beads obtained in Examples 1 to 3, respectively. In each case, the amount of perfume beads added to the filter section 342 was a maximum of 100 mg per 10 mm filter length. These cigarettes did not generate a fragrance aroma during storage. However, when this cigarette was smoked, it was possible to taste the flavor of the fragrance stably.

例５
平均粒径約２００μｍの炭酸カルシウム粒子９０ｇと、メントール結晶を粉砕して得たメントール微粉末１０ｇ、およびグリセリン０．５ｇをリボンミキサーに入れ、攪拌混合しながら全体を４０℃まで加温し、５分間さらに混合した。全てのメントールを溶融させ、炭酸カルシウム粒子に付着・コーティングさせた後、リボンミキサー内に１５℃の冷風を吹き込んで冷却した。こうして、表面がメントール結晶の膜で覆われた各炭酸カルシウム粒子を得た。これらメントール膜を有する炭酸カルシウム粒子を流動造粒機に入れ、４０℃の温風を１．０ｍ／秒の流速で吹き込みながら、速やかに、プルランの５重量％水溶液を間欠的に噴霧し、合計１５ｇのプルラン水溶液を炭酸カルシウム粒子に噴霧した。しかる後、２５℃まで冷却し、所望のメントール香料ビーズを得た。Example 5
90 g of calcium carbonate particles having an average particle size of about 200 μm, 10 g of menthol fine powder obtained by pulverizing menthol crystals, and 0.5 g of glycerin were put in a ribbon mixer, and the whole was heated to 40 ° C. while stirring and mixed. Further mixing for minutes. After all the menthol was melted and adhered and coated on the calcium carbonate particles, it was cooled by blowing cold air of 15 ° C. into the ribbon mixer. Thus, each calcium carbonate particle whose surface was covered with a menthol crystal film was obtained. The calcium carbonate particles having these menthol membranes are put into a fluid granulator, and a 5% by weight aqueous solution of pullulan is sprayed intermittently while blowing warm air at 40 ° C. at a flow rate of 1.0 m / sec. 15 g of an aqueous pullulan solution was sprayed onto the calcium carbonate particles. Thereafter, the mixture was cooled to 25 ° C. to obtain desired menthol fragrance beads.

例６
例５で得られたメントール香料ビーズを用いて、図３に示すフィルタ付きシガレットを作製した。フィルタセクション３４２に添加したメントール香料ビーズの量は、メントール量換算でシガレット１本あたり３ｍｇであった。このシガレットは、通常の保管条件下ではメントールの香気が発生しなかった。しかしながら、このシガレットを喫煙すると、メントールの香喫味を味わうことができた。Example 6
Using the menthol flavor beads obtained in Example 5, a cigarette with a filter shown in FIG. 3 was produced. The amount of menthol flavor beads added to the filter section 342 was 3 mg per cigarette in terms of menthol amount. This cigarette did not generate a menthol aroma under normal storage conditions. However, smoking this cigarette allowed me to taste the menthol flavor.

Claims (11)

香料ビーズであって、粒子状担体と、前記粒子状担体により支持されたグルカン膜と、香料を包含し、前記香料は、前記グルカン膜によりその香気の放出が抑制されているが、前記グルカン膜が、タバコ主流煙との接触によりその少なくとも一部が溶解することにより、その香気が放出されるように、香料ビーズにより担持されている香料ビーズ。   A perfume bead comprising a particulate carrier, a glucan membrane supported by the particulate carrier, and a perfume, wherein the perfume is suppressed in release of the aroma by the glucan membrane. However, the perfume beads carried by the perfume beads so that the aroma is released when at least a part thereof is dissolved by contact with mainstream tobacco smoke. 前記粒子状担体が、炭酸カルシウム粒子、活性炭粒子、糖結晶粒子およびコーヒー豆粒子からなる群の中から選ばれる請求項１に記載の香料ビーズ。   The fragrance bead according to claim 1, wherein the particulate carrier is selected from the group consisting of calcium carbonate particles, activated carbon particles, sugar crystal particles, and coffee bean particles. 前記グルカン膜が、プルランにより構成されている請求項１に記載の香料ビーズ。   The fragrance bead according to claim 1, wherein the glucan membrane is composed of pullulan. 前記香料が、ラベンダー、シナモン、カルダモン、セレリー、丁子、カスカリラ、ナツメグ、サンダルウッド、ベルガモット、ゼラニウム、ハチミツエッセンス、ローズ油、バニラ、レモン、オレンジ、ハッカ、ケイ皮、キャラウェー、コニャック、ジャスミン、カモミール、メントール、カシャ、イランイラン、セージ、スペアミント、フェンネル、ヒメント、ジンジャ、アニス、コリアンダおよびコーヒーの精油から選ばれる請求項１に記載の香料ビーズ。   The fragrance is lavender, cinnamon, cardamom, celery, clove, cascarilla, nutmeg, sandalwood, bergamot, geranium, honey essence, rose oil, vanilla, lemon, orange, mint, cinnamon, caraway, cognac, jasmine, chamomile A fragrance bead according to claim 1, selected from essential oils of menthol, menthol, cacha, ylang ylang, sage, spearmint, fennel, himent, ginger, anise, corianda and coffee. 前記グルカン膜が、香料ビーズの総重量の０．２５％〜５％に相当する量のグルカンを用いて形成されている請求項１に記載の香料ビーズ。   The fragrance bead according to claim 1, wherein the glucan membrane is formed using an amount of glucan corresponding to 0.25% to 5% of the total weight of the fragrance bead. 前記グルカン膜が、前記香料を含有し、前記粒子状担体の表面を直接覆っている請求項１に記載の香料ビーズ。   The fragrance bead according to claim 1, wherein the glucan film contains the fragrance and directly covers the surface of the particulate carrier. 前記香料が、グルカンの重量の２０％以下に相当する量で存在する請求項６に記載の香料ビーズ。   The fragrance bead according to claim 6, wherein the fragrance is present in an amount corresponding to 20% or less of the weight of glucan. 前記香料が固体香料であり、これが前記粒子状担体の表面を直接覆う膜を形成し、前記グルカン膜が前記固体香料の膜を覆っている請求項１に記載の香料ビーズ。   The fragrance bead according to claim 1, wherein the fragrance is a solid fragrance, which forms a film directly covering the surface of the particulate carrier, and the glucan film covers the solid fragrance film. 前記固体香料が、メントールを包含する請求項８に記載の香料ビーズ。   The fragrance bead according to claim 8, wherein the solid fragrance includes menthol. 前記固体香料膜が、香料ビーズの総重量の１〜２０％に相当する量の固体香料を用いて形成されている請求項８に記載の香料ビーズ。   The fragrance | flavor bead of Claim 8 in which the said solid fragrance | flavor film | membrane is formed using the amount of solid fragrance | flavor equivalent to 1 to 20% of the total weight of a fragrance | flavor bead. 請求項１に記載の香料ビーズを含むシガレット用フィルタ。   A cigarette filter comprising the fragrance bead according to claim 1.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590931A (en) * 2016-12-14 2017-04-26 江西中烟工业有限责任公司 Preparation method of cigarette protein-polysaccharide composite emulsion carrier system and application of carrier system in cigarettes
CN107629876A (en) * 2017-10-31 2018-01-26 鹰潭中投科技有限公司 Improve flavouring essence for tobacco and its preparation and the application of reconstituted tobacco cigarette quality

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2447819C1 (en) 2008-03-18 2012-04-20 Джапан Тобакко Инк. Adsorbent for cigarette smoke main flow components and cigarette filter
WO2009157240A1 (en) * 2008-06-25 2009-12-30 日本たばこ産業株式会社 Smoking article
TW201032739A (en) * 2009-01-08 2010-09-16 Japan Tobacco Inc Filter for cigarette
GB2469842A (en) * 2009-04-29 2010-11-03 British American Tobacco Co Aerosol generating material for a smoking article
GB0910373D0 (en) * 2009-06-16 2009-07-29 Filtrona Int Ltd Tabacco smoke filter
KR101720739B1 (en) * 2009-11-30 2017-04-11 (주)아모레퍼시픽 Natural fragrance composition having anti-oxidation effect
JP2011205914A (en) * 2010-03-29 2011-10-20 British American Tobacco (Investments) Ltd Smoking article
US20110271968A1 (en) * 2010-05-07 2011-11-10 Carolyn Rierson Carpenter Filtered Cigarette With Modifiable Sensory Characteristics
EP2401929A1 (en) * 2010-06-30 2012-01-04 Philip Morris Products S.A. Filter for a smoking article
WO2012053048A1 (en) * 2010-10-18 2012-04-26 日本たばこ産業株式会社 Method for manufacturing flavor-releasing granules, flavor-releasing granules, and cigarette filter containing flavor-releasing granules
EP2462822A1 (en) * 2010-12-13 2012-06-13 Philip Morris Products S.A. Smoking article including flavour granules
CN102068038A (en) * 2010-12-31 2011-05-25 贵州中烟工业有限责任公司 Method for preparing heat-sensitive moisture-retaining central line filter stick of cigarette
RU2448589C1 (en) * 2011-01-21 2012-04-27 Олег Иванович Квасенков Method for production of non-smoking products of rustic tobacco
IT1404015B1 (en) * 2011-02-04 2013-11-08 Hsd Holding Smart Device S R L USE OF A DESTRANO POLYMER RETICULATED AS A FILTER AGAINST INHALATION OF HEALTH HARMFUL SUBSTANCES
GB201110369D0 (en) 2011-06-17 2011-08-03 Filtrona Filter Prod Dev Co Tobacco smoke filter with activated carbon
GB201110863D0 (en) 2011-06-27 2011-08-10 British American Tobacco Co Smoking article filter and insertable filter unit thereof
MY170282A (en) * 2011-07-15 2019-07-16 Japan Tobacco Inc Flavorant-carrying adsorbent particle, cigarette filter, filter-tipped cigarette, and method for producing flavorant-carrying adsorbent particle.
RU2570785C2 (en) * 2011-07-15 2015-12-10 Джапан Тобакко Инк. Aromatiser-carrying weakly-adsorbing particle, cigarette filter, filter-tipped cigarette and method of producing aromatiser-carrying weakly-adsorbing particle
EP2554060A1 (en) * 2011-08-01 2013-02-06 JT International S.A. Filter element incorporating a breakable capsule, method of manufacturing a cigarette having a filter element incorporating a breakable capsule and apparatus for manufacturing the cigarette having a filter element incorporating a breakable capsule
CN102432921B (en) * 2011-09-16 2013-04-17 中国烟草总公司郑州烟草研究院 Pullulan additive and application thereof in cigarettes
UA112328C2 (en) * 2011-11-07 2016-08-25 Філіп Морріс Продактс С.А. MENTAL CONTINUOUS SMOKING PRODUCTS
CN102533445B (en) * 2012-02-05 2013-09-18 云南正邦生物技术有限公司 Method for preparing active release type cigarette flavor complementing particles
KR102183809B1 (en) * 2012-08-02 2020-11-30 필립모리스 프로덕츠 에스.에이. Smoking article with menthol filter
CN102823945A (en) * 2012-09-17 2012-12-19 川渝中烟工业有限责任公司 Essence particle additive as well as preparation method and application thereof
CN102987563A (en) * 2012-11-28 2013-03-27 红塔烟草(集团)有限责任公司 Cigarette paper filter material containing orchid fragrance
CN103054184A (en) * 2012-11-28 2013-04-24 红塔烟草(集团)有限责任公司 Cigarette paper filter materials with lavender fragrance
GB2516104A (en) * 2013-07-12 2015-01-14 British American Tobacco Co Material for inclusion in a smoking article
US10849358B2 (en) * 2014-10-29 2020-12-01 Altria Client Services Llc E-vaping cartridge
US10772352B2 (en) 2014-10-29 2020-09-15 Altria Client Services Llc Ethanol-free gel formulation cartridge for e-vaping device
CN104856223B (en) * 2015-04-29 2019-05-10 湖北中烟工业有限责任公司 A kind of cigarette is with solid flavoring pearl and preparation method thereof
CN104997158B (en) * 2015-05-29 2017-01-18 湖北中烟工业有限责任公司 Preparation method and application of spicy tobacco flavor extract product
CN105029700A (en) * 2015-06-17 2015-11-11 云南中烟工业有限责任公司 Plant composite glycerol triacetate extract and application thereof in cigarettes
CN104939307B (en) * 2015-07-17 2019-08-09 云南中烟工业有限责任公司 A kind of cigarette polarity fragrance load core and application
CN105001988B (en) * 2015-07-17 2018-07-24 云南中烟工业有限责任公司 A kind of preparation facilities and its application process of three-layer sandwich structure spice slow-releasing additives of filter tip
CN105105327B (en) * 2015-07-21 2019-07-23 中国烟草总公司广东省公司 A kind of champignon cigarette and preparation method thereof containing full constituent tobacco extract
CN105231480B (en) * 2015-11-10 2017-07-04 江苏中烟工业有限责任公司 A kind of method that calcium carbonate is applied as perfuming carrier in reconstituted tobacco coating fluid
US20170265517A1 (en) * 2016-03-15 2017-09-21 Rai Strategic Holdings, Inc. Multi-Layered Micro-Beads for Electronic Cigarettes
ITUA20162010A1 (en) * 2016-03-24 2017-09-24 Gd Spa Smoking item and method for its realization.
GB201608943D0 (en) * 2016-05-20 2016-07-06 British American Tobacco Co Capsule for tobacco industry product
JP6831384B2 (en) * 2016-08-17 2021-02-17 日本たばこ産業株式会社 Filters and tobacco products
CN107022414A (en) * 2017-04-27 2017-08-08 河南中烟工业有限责任公司 A kind of cigarette quick-fried pearl vanilla flavored essence and its application in cigarette
US10492522B2 (en) 2017-05-03 2019-12-03 R.J. Reynolds Tobacco Company Flavored menthol-containing objects for application to smoking article components
CN107419593A (en) * 2017-10-11 2017-12-01 云南中烟工业有限责任公司 A kind of sweet odor type cigarette paper and preparation method thereof
CN110574961A (en) * 2018-06-08 2019-12-17 湖南中烟工业有限责任公司 Preparation method of lemon essence for cigarettes, and bead blasting cigarettes for cigarettes
CN108523217A (en) * 2018-06-08 2018-09-14 滁州卷烟材料厂 A kind of cigarette filter rod with tar reduction flavouring performance
CN108851214B (en) * 2018-08-06 2020-06-30 江西中烟工业有限责任公司 Fine cigarette holder rod containing single solid aromatic bead particles and preparation method thereof
CN110629590A (en) * 2019-09-20 2019-12-31 河南中烟工业有限责任公司 Cigar flavor essence, cigar flavor gloss oil and cigarette tipping paper
CN110801049B (en) * 2019-11-07 2022-02-01 云南中烟工业有限责任公司 Cigarette filter tip aroma sustained-release particles and preparation method thereof
CN110934333A (en) * 2019-12-27 2020-03-31 山东中烟工业有限责任公司 Cigarette filter tip based on nanofiber structure and cigarette
JP7362891B2 (en) * 2020-03-04 2023-10-17 日本たばこ産業株式会社 Flavor-carrying components of tobacco products, tobacco products, and manufacturing methods thereof
RU2767511C2 (en) * 2020-07-13 2022-03-17 Бритиш Америкэн Тобэкко (Инвестментс) Лимитед Plug-in filter element for product heated without burning
KR102571393B1 (en) * 2020-08-28 2023-08-25 주식회사 케이티앤지 Filter with improved flavor persistence and smoking article including the same
CN112914144B (en) * 2020-12-31 2022-10-21 中国农业科学院烟草研究所 Tobacco base section of heating cigarette and manufacturing method thereof
CN114775333B (en) * 2022-04-13 2023-09-19 江苏卫星新材料股份有限公司 Sweetener tipping paper and preparation method thereof

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3297041A (en) * 1965-03-15 1967-01-10 American Filtrona Corp Tobacco smoke filter or the like
JPS5932108B2 (en) * 1977-04-20 1984-08-06 日本たばこ産業株式会社 Microcapsules with flavoring as the core material and tobacco products containing them
US5060676A (en) * 1982-12-16 1991-10-29 Philip Morris Incorporated Process for making a carbon heat source and smoking article including the heat source and a flavor generator
JP2709077B2 (en) * 1987-05-29 1998-02-04 日本たばこ産業株式会社 Tobacco filter
US5070891A (en) * 1989-07-12 1991-12-10 International Flavors & Fragrances, Inc. Method for imparting flavors and aromas, flavor-imparting articles, and methods for preparation and use thereof
US5258185A (en) * 1989-08-23 1993-11-02 Bauer Kurt H Highly active, rapidly absorbable formulations of glibenclamide, processes for the production thereof and their use
US5144964A (en) * 1991-03-14 1992-09-08 Philip Morris Incorporated Smoking compositions containing a flavorant-release additive
TR28670A (en) * 1993-06-02 1996-12-17 Procter & Gamble Perfume release system containing zeolites.
US5396909A (en) * 1993-12-16 1995-03-14 R. J. Reynolds Tobacco Company Smoking article filter
JP3118462B2 (en) * 1994-01-26 2000-12-18 日本たばこ産業株式会社 Flavored goods
US5845649A (en) * 1994-01-26 1998-12-08 Japan Tobacco Inc. Flavor-tasting article
JPH0928366A (en) * 1995-07-24 1997-02-04 Japan Tobacco Inc Cigarette
MY135471A (en) * 2002-01-09 2008-04-30 Philip Morris Prod Cigarette filter with beaded carbon
US20050100640A1 (en) * 2002-02-11 2005-05-12 Pearce Tony M. Microcapsule edibles
DE60333759D1 (en) * 2002-06-12 2010-09-23 Traptek Llc CAPSULATED ACTIVE PARTICLES AND METHOD FOR THEIR PREPARATION AND USE
US20050172976A1 (en) * 2002-10-31 2005-08-11 Newman Deborah J. Electrically heated cigarette including controlled-release flavoring
US7381277B2 (en) * 2004-07-29 2008-06-03 R.U. Reynolds Tobacco Company Flavoring a cigarette by using a flavored filter plug wrap
US20060144410A1 (en) * 2004-12-30 2006-07-06 Philip Morris Usa Inc. Surface-modified activated carbon in smoking articles
JP5393032B2 (en) * 2005-02-04 2014-01-22 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム Filter with added cigarette and cellulose flavors
US20060251786A1 (en) * 2005-04-19 2006-11-09 Luca Turin Cyclopropanated coumarin derivatives
WO2007010407A2 (en) * 2005-06-21 2007-01-25 V. Mane Fils Smoking device incorporating a breakable capsule, breakable capsule and process for manufacturing said capsule
US20070231387A1 (en) * 2006-04-04 2007-10-04 Luigi Levi Film-coated solid dosage forms
US8356606B2 (en) * 2007-06-01 2013-01-22 Philip Morris Usa Inc. Production of micronized encapsulated tobacco particles for tobacco flavor delivery from an oral pouch
RU2447819C1 (en) * 2008-03-18 2012-04-20 Джапан Тобакко Инк. Adsorbent for cigarette smoke main flow components and cigarette filter

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590931A (en) * 2016-12-14 2017-04-26 江西中烟工业有限责任公司 Preparation method of cigarette protein-polysaccharide composite emulsion carrier system and application of carrier system in cigarettes
CN107629876A (en) * 2017-10-31 2018-01-26 鹰潭中投科技有限公司 Improve flavouring essence for tobacco and its preparation and the application of reconstituted tobacco cigarette quality

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MY157908A (en) 2016-08-15
TW200848505A (en) 2008-12-16
EP2093276A4 (en) 2010-02-17
CN101558143B (en) 2012-09-26
TWI384063B (en) 2013-02-01
RU2405810C1 (en) 2010-12-10
CA2671004A1 (en) 2008-06-19
KR20090089357A (en) 2009-08-21
EP2093276A1 (en) 2009-08-26
EP2093276B1 (en) 2012-11-21
ES2396593T3 (en) 2013-02-22
CA2671004C (en) 2013-03-12
HK1133034A1 (en) 2010-03-12
JP4876296B2 (en) 2012-02-15

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