JPS6447890A - Electrolytic synthesis method - Google Patents

Electrolytic synthesis method

Info

Publication number
JPS6447890A
JPS6447890A JP62202288A JP20228887A JPS6447890A JP S6447890 A JPS6447890 A JP S6447890A JP 62202288 A JP62202288 A JP 62202288A JP 20228887 A JP20228887 A JP 20228887A JP S6447890 A JPS6447890 A JP S6447890A
Authority
JP
Japan
Prior art keywords
bivalent
alcohol
mediator
electrolytic
electrolytic cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62202288A
Other languages
Japanese (ja)
Other versions
JPH0349993B2 (en
Inventor
Kenzo Yamaguchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP62202288A priority Critical patent/JPS6447890A/en
Publication of JPS6447890A publication Critical patent/JPS6447890A/en
Publication of JPH0349993B2 publication Critical patent/JPH0349993B2/ja
Granted legal-status Critical Current

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

PURPOSE:To efficiently synthesize a chemical product by an electrolytic synthesis method by utilizing an electrolyte of an electrolyte flow type electrolytic cell as a mediator for an oxidation reduction reaction. CONSTITUTION:An anode 5 is formed of carbon fibers and carbon fibers having >=0.02 surface atomic number ratio measured by an ESCA (photoelectron spectrochemical analysis method) of oxygen atoms or chlorine atoms with respect to carbon are used as a cathode 6 in the electrolytic cell segmented to an anode chamber 2 and a cathode chamber 3 by an anode plate 5, a cathode plate 6 and a cation exchange membrane 4. An aq. acidic iron chloride soln. of hydrochloric acid is used as an anolyte and an aq. acidic chromium chloride soln. of hydrochloric acid is used as a catholyte. The tervalent Cr in the catholyte is reduced to bivalent Cr by the electrolytic redaction and is admitted through an oxidation reaction mediator line 11a into a reaction vessel 10a where the chloroform contg. a non-water soluble aliphat. ketone introduced from an inlet 7a is reduced to alcohol. This alcohol is taken out of an outlet 8a. The bivalent Cr is oxidized to the tervalent Cr and is returned through the oxidation reaction mediator line 14a to the electrolytic cell 1 where the Cr is again reduced to the bivalent Cr and this Cr is cyclically used for synthesis of the alcohol again in the reaction vessel 9.
JP62202288A 1987-08-13 1987-08-13 Electrolytic synthesis method Granted JPS6447890A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62202288A JPS6447890A (en) 1987-08-13 1987-08-13 Electrolytic synthesis method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62202288A JPS6447890A (en) 1987-08-13 1987-08-13 Electrolytic synthesis method

Publications (2)

Publication Number Publication Date
JPS6447890A true JPS6447890A (en) 1989-02-22
JPH0349993B2 JPH0349993B2 (en) 1991-07-31

Family

ID=16455057

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62202288A Granted JPS6447890A (en) 1987-08-13 1987-08-13 Electrolytic synthesis method

Country Status (1)

Country Link
JP (1) JPS6447890A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014532812A (en) * 2011-11-08 2014-12-08 ザ ユニヴァーシティー コート オブ ザ ユニヴァーシティー オブ グラスゴーＴｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｃｏｕｒｔ Ｏｆ Ｔｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｇｌａｓｇｏｗ Apparatus and method for electrochemical generation of oxygen and / or hydrogen
CN104451767A (en) * 2014-12-29 2015-03-25 甘肃银光聚银化工有限公司 Oxidation device and method
CN105209667A (en) * 2013-03-12 2015-12-30 麦克德米德尖端有限公司 Electrolytic generation of manganese (III) ions in strong sulfuric acid
JP2016504492A (en) * 2012-11-15 2016-02-12 マクダーミッド アキューメン インコーポレーテッド Electrolytic production of manganese (III) ions in concentrated sulfuric acid
WO2024106161A1 (en) * 2022-11-18 2024-05-23 Ｅｎｅｏｓ株式会社 Electrolysis system and electrolysis device

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014532812A (en) * 2011-11-08 2014-12-08 ザ ユニヴァーシティー コート オブ ザ ユニヴァーシティー オブ グラスゴーＴｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｃｏｕｒｔ Ｏｆ Ｔｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｇｌａｓｇｏｗ Apparatus and method for electrochemical generation of oxygen and / or hydrogen
JP2016504492A (en) * 2012-11-15 2016-02-12 マクダーミッド アキューメン インコーポレーテッド Electrolytic production of manganese (III) ions in concentrated sulfuric acid
CN105209667A (en) * 2013-03-12 2015-12-30 麦克德米德尖端有限公司 Electrolytic generation of manganese (III) ions in strong sulfuric acid
CN104451767A (en) * 2014-12-29 2015-03-25 甘肃银光聚银化工有限公司 Oxidation device and method
WO2024106161A1 (en) * 2022-11-18 2024-05-23 Ｅｎｅｏｓ株式会社 Electrolysis system and electrolysis device

Also Published As

Publication number Publication date
JPH0349993B2 (en) 1991-07-31

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