JPS6393164A - Manufacture of photovoltaic element - Google Patents
Manufacture of photovoltaic elementInfo
- Publication number
- JPS6393164A JPS6393164A JP61239501A JP23950186A JPS6393164A JP S6393164 A JPS6393164 A JP S6393164A JP 61239501 A JP61239501 A JP 61239501A JP 23950186 A JP23950186 A JP 23950186A JP S6393164 A JPS6393164 A JP S6393164A
- Authority
- JP
- Japan
- Prior art keywords
- film
- cds
- cdte
- epoxy resin
- sintered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 229910004613 CdTe Inorganic materials 0.000 claims abstract description 11
- 239000003822 epoxy resin Substances 0.000 claims abstract description 10
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 10
- 238000007650 screen-printing Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 12
- 229910052799 carbon Inorganic materials 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004615 ingredient Substances 0.000 abstract 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 241000287828 Gallus gallus Species 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 230000010415 tropism Effects 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 206010020649 Hyperkeratosis Diseases 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/543—Solar cells from Group II-VI materials
Landscapes
- Photovoltaic Devices (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、電源用もしくは民生用の太陽電池などに使用
可能なＣｄＳ／ＣｄＴｅ系の光起電力素子の製造方法に
関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for manufacturing a CdS/CdTe-based photovoltaic element that can be used for power sources or consumer solar cells.
従来の技術
セラミック基板またはガラス基板上に順次スクリーン印
刷し、焼結したＣｄＳ、ＣｄＴｅカーボン及びＡｇＩｎ
膜からなるＣｄＳ／ＣｄＴｅ系太陽電池では、その信頼
性向上ならびにＣｄ、Ｔｅの危険物流出防止のために、
樹脂コートを行なっていた（例えば特開昭６５−４６５
１０号公報）。Prior Art CdS, CdTe carbon and AgIn sequentially screen printed and sintered on ceramic or glass substrates
In order to improve the reliability of CdS/CdTe solar cells made of films and to prevent the leakage of hazardous materials such as Cd and Te,
Resin coating was applied (for example, Japanese Patent Application Laid-Open No. 65-465)
10).
発明が解決しようとする問題点
しかし、従来のスクリーン印刷可能なエポキシ樹脂はそ
の粘度、チキソトロピー性が低く、スクリーン印刷後の
乾燥過程で下地のカーボン電極層にしみ込み、下地のカ
ーボン電極層の凹凸が表われて外観が悪くなり、又膜厚
も薄くなって極端な場合は、カーボン電極がむき出す場
合がある。この為、水分等がセルに浸入しやすく、光が
当たることによりＣｄＳとＣｄＴｅの電気化学的な反応
が起こり最大出力の劣化が約３０％あった。Problems to be Solved by the Invention However, conventional screen-printable epoxy resins have low viscosity and thixotropy, and during the drying process after screen printing, they soak into the underlying carbon electrode layer, causing unevenness of the underlying carbon electrode layer. appears, resulting in poor appearance, and in extreme cases, the carbon electrode may become exposed as the film thickness becomes thinner. For this reason, moisture etc. easily entered the cell, and exposure to light caused an electrochemical reaction between CdS and CdTe, resulting in a deterioration of the maximum output by about 30%.
本発明は、かかる点に鑑みてなされたもので、エポキシ
樹脂の主剤の分子量を増加して、粘度、チキントロピー
性、表面張力等を増加させて性能劣化を防止するもので
ある。The present invention has been made in view of this point, and is intended to prevent performance deterioration by increasing the molecular weight of the main ingredient of an epoxy resin to increase viscosity, chicken tropism, surface tension, etc.
問題点を解決するだめの手段
ニ粘及、チキントロピー性が低く、カーボン電極層の凹
凸が外観に吃れて外観が悪化する上に、凹凸のため、樹
脂が薄い部分もあり、したがって信頼性も悪かった。The only way to solve the problem is that the chicken tropism is low, and the unevenness of the carbon electrode layer deteriorates the appearance, and the unevenness also makes the resin thin in some parts, so the reliability is low It was also bad.
本発明は用いるエポキシ樹脂主剤の分子量を従来の１０
００から２０００〜３０００とし、粘度、チキソトロピ
ー性、表面張力等を上昇させて、樹脂の膜厚を従来の２
ｏ〜３０μｍより６０〜６０μｍまで厚くし、カーボン
電極層の凹凸を外観に出さない様にして外観ならびに信
頼性を向上させたものである。In the present invention, the molecular weight of the epoxy resin base resin used is lower than that of the conventional one.
00 to 2,000 to 3,000, increasing the viscosity, thixotropy, surface tension, etc., and reducing the film thickness of the resin from the conventional 2
The thickness is increased from 0.about.30 .mu.m to 60.about.60 .mu.m, and the unevenness of the carbon electrode layer is not visible in appearance, thereby improving the appearance and reliability.
作 用
本発明による光起電力素子の製造方法によれば、外観の
改善、耐水性向上、信頼性向上がし、特性の安定がはか
れる。Function: According to the method for manufacturing a photovoltaic device according to the present invention, the appearance is improved, water resistance is improved, reliability is improved, and characteristics are stabilized.
実施例
以下本発明の実施例について第１図をもとに説明してい
く、ＣｄＳ粉末に融剤としてＣｄＣｌ２を加え、それに
粘結剤としてプロピレングリコールを加えて泥状にした
ものを第１図に示す様にバリウム硼珪酸ガラス基板１上
にスクリーン印刷した後乾燥し、セラミック製の有孔蓋
付き容器に入れて、ベルト式焼結炉で焼結を行なう。こ
の様に焼結されたｎ形ＣｄＳ焼結膜２上に、Ｃｄ粉末と
Ｔｅ粉末を等モル比で配合し、それに融剤としてＣｄＣ
ｌ２をＣｄとＴｏの総重量に対して０．５重量％、粘結
剤としてプロピレングリコールの適量を加えて混合し、
泥状にしたものをスクリーン印刷し、ＣｄＳと同様乾燥
焼成を行なう。この様にしてＣｄＴｅ焼結膜３を形成し
た。次にＣｄＴｅ焼結膜上に適量のアクセプター不純物
を添加した泥状カーボンをスクリーン印刷して乾燥、焼
結を行ないカーボン膜４を形成する。次にＣｄＳ焼結膜
２上およびカーボン膜４上にそれぞれオーミック電極で
あるＡｇ Ｉ ｎ膜５，６をスクリーン印刷し乾燥、焼
結して形成した。この様にして得られた素子の信頼性、
耐水性を向上させるため主剤の分子量を２５００とした
エポキシ樹脂７をスクリーン印刷し、温度１２０℃で２
時間乾燥熱処理を行なって、図に示す素子をこのように
本発明は、Ｃｄ Ｓ ／Ｃｄ Ｔ ｅ系太陽電池のコー
テイング材として使用するエポキシ樹脂の主剤の分子量
を増加して、外観の改善、高信頼性で特性劣化のないも
のにすることができる効果が得られた。Examples Examples of the present invention will be explained below with reference to Fig. 1. Fig. 1 shows a slurry made by adding CdCl2 as a flux to CdS powder and propylene glycol as a binder. As shown in Figure 2, a barium borosilicate glass substrate 1 is screen printed, dried, placed in a ceramic container with a perforated lid, and sintered in a belt-type sintering furnace. On the n-type CdS sintered film 2 sintered in this way, Cd powder and Te powder are mixed in an equimolar ratio, and Cd powder is added as a flux.
12 by 0.5% by weight based on the total weight of Cd and To, and an appropriate amount of propylene glycol as a binder are added and mixed,
The slurry is screen printed and dried and fired in the same way as CdS. In this manner, a CdTe sintered film 3 was formed. Next, muddy carbon containing an appropriate amount of acceptor impurities is screen printed on the CdTe sintered film, dried and sintered to form the carbon film 4. Next, Ag I n films 5 and 6 as ohmic electrodes were screen printed on the CdS sintered film 2 and the carbon film 4, respectively, and were dried and sintered. The reliability of the device obtained in this way,
In order to improve water resistance, epoxy resin 7 with a main resin molecular weight of 2500 was screen printed and
The present invention improves the appearance and improves the appearance by increasing the molecular weight of the main ingredient of the epoxy resin used as a coating material for CdS/CdTe solar cells. The effect of achieving reliability and no deterioration of characteristics was obtained.
第１図はエポキシ樹脂をスクリーン印刷してコーティン
グしたＣｄＳ／ＣｄＴｅ光超電力素子の断面図である。
１・・・・・ガラス基板、２・・・・・・ＣｄＳ膜、３
・・・・・・ＣｃｌＴｅ膜、４・・・・・・カーボン膜
、５．６・・・・・・オーミック電極をなすＡｇＩｎ膜
、７・・・・・・エポキシ樹脂。
代理人の氏名 弁理士 中 尾 敏 男 ほか１名第
ｆ 図 １−、カ°ラ
ス、基、不受２−Ｃｄ５嗅
３−−−Ｃｄ ７？、誘
仔−−−カー２ピ′ン月ヌ麺FIG. 1 is a cross-sectional view of a CdS/CdTe optical superpower device coated with epoxy resin by screen printing. 1...Glass substrate, 2...CdS film, 3
. . . CclTe film, 4 . . . Carbon film, 5.6 . . . AgIn film forming an ohmic electrode, 7 . . . Epoxy resin. Name of agent: Patent attorney Toshio Nakao and 1 other person
f Figure 1-, callus, group, fujutsu 2-Cd5 smell 3---Cd 7? , Yingchai---car 2-pin moon noodles
Claims (1)
０００〜３０００のエポキシ樹脂をスクリーン印刷して
１２０℃で２時間熱処理してコーティングすることを特
徴とする光起電力素子の製造方法。In the bare CdS/CdTe photovoltaic device, the molecular weight of the base material is 2.
1. A method for producing a photovoltaic device, which comprises screen printing an epoxy resin of 000 to 3000 and heat-treating it at 120° C. for 2 hours to coat it.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61239501A JPS6393164A (en) | 1986-10-08 | 1986-10-08 | Manufacture of photovoltaic element |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61239501A JPS6393164A (en) | 1986-10-08 | 1986-10-08 | Manufacture of photovoltaic element |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6393164A true JPS6393164A (en) | 1988-04-23 |
Family
ID=17045723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61239501A Pending JPS6393164A (en) | 1986-10-08 | 1986-10-08 | Manufacture of photovoltaic element |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6393164A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5340409A (en) * | 1992-04-23 | 1994-08-23 | Canon Kabushiki Kaisha | Photovoltaic element and method for forming the same |
| WO2013147979A3 (en) * | 2012-03-14 | 2013-12-27 | Ppg Industries Ohio, Inc. | Coating-encapsulated photovoltaic modules and methods of making same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5546510A (en) * | 1978-09-28 | 1980-04-01 | Agency Of Ind Science & Technol | Method of manufacturing solar battery embedded in resin |
| JPS5555580A (en) * | 1978-10-17 | 1980-04-23 | Agency Of Ind Science & Technol | Method of fabricating solar battery |
-
1986
- 1986-10-08 JP JP61239501A patent/JPS6393164A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5546510A (en) * | 1978-09-28 | 1980-04-01 | Agency Of Ind Science & Technol | Method of manufacturing solar battery embedded in resin |
| JPS5555580A (en) * | 1978-10-17 | 1980-04-23 | Agency Of Ind Science & Technol | Method of fabricating solar battery |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5340409A (en) * | 1992-04-23 | 1994-08-23 | Canon Kabushiki Kaisha | Photovoltaic element and method for forming the same |
| WO2013147979A3 (en) * | 2012-03-14 | 2013-12-27 | Ppg Industries Ohio, Inc. | Coating-encapsulated photovoltaic modules and methods of making same |
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