JPS638631A - Liquid crystal display device - Google Patents

Liquid crystal display device

Info

Publication number
JPS638631A
JPS638631A JP61152190A JP15219086A JPS638631A JP S638631 A JPS638631 A JP S638631A JP 61152190 A JP61152190 A JP 61152190A JP 15219086 A JP15219086 A JP 15219086A JP S638631 A JPS638631 A JP S638631A
Authority
JP
Japan
Prior art keywords
liquid crystal
substrates
theta
chiral agent
display device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61152190A
Other languages
Japanese (ja)
Inventor
Kiyoshi Shobara
潔 庄原
Yoshinori Kato
加藤 芳紀
Yoshihiro Kinoshita
木下 喜宏
Shoichi Matsumoto
正一 松本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP61152190A priority Critical patent/JPS638631A/en
Priority to US07/064,001 priority patent/US4779958A/en
Priority to EP87305597A priority patent/EP0251665B1/en
Priority to DE87305597T priority patent/DE3787055T2/en
Priority to KR1019870006576A priority patent/KR900006939B1/en
Publication of JPS638631A publication Critical patent/JPS638631A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements

Landscapes

  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Liquid Crystal (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Polarising Elements (AREA)

Abstract

PURPOSE:To attain dot matrix display based on high time division driving and to remove disturbance in orientation by providing the titled device with a pair of substrates arranged oppositely to each other, molecular orientation films for orientating liquid crystal molecules formed on the opposite surfaces of the substrates with twist and a liquid crystal component containing a chiral agent corresponding to a specific range of twisting efficiency. CONSTITUTION:The device is provided with a pair of oppositely arranged sub strate, the molecular orientation films formed on the opposite surfaces of these substrates so that liquid crystal molecules are orientated between the pair of substrates with twist corresponding to a prescribed angle 180 deg. and the liquid crystal component held between the substrates and containing the chiral agent corresponding to theta-10 deg.-theta-60 deg. range of twisting efficiency. When the liquid crystal display device constituted by setting up the setting angle theta of twisting orientation of the liquid crystal molecules to 180 deg. (rubbing method), 220 deg. (rubbing method) or 270 deg. (SiO oblique vacuum evaporation method) and adding the chiral agent corresponding to theta-10 deg.-theta-60 deg. range of twisting efficiency is driven with time division at 1/200 duty ratio, required display free from disturbance in orientation and having high contrast can be obtained.

Description

【発明の詳細な説明】 [発明の目的] (産業上の利用分野) 本発明は、高時弁v1駆動による表示をするのに最適な
液晶表示装置に関する。
DETAILED DESCRIPTION OF THE INVENTION [Object of the Invention] (Industrial Application Field) The present invention relates to a liquid crystal display device that is most suitable for displaying by driving a high-temperature valve v1.

(従来の技術) 一般に液晶表示装置において、2枚の電極基板間で液晶
分子を捩れ配向させるには、ラビング法や斜め蒸着法等
により各電極基板対向面に配向処理を施し、これら電極
基板の配向方向を液晶の捩れ配向の角度で設定対向させ
る。そして電極基板間の外周を封止剤により封着すると
ともに電極基板間に液晶を封入することにより行われる
。なお、上記電極基板間には液晶を封入するとともにカ
イラル剤が添加され、適当なツイスト能が付与されてい
る。
(Prior Art) In general, in a liquid crystal display device, in order to twist and align liquid crystal molecules between two electrode substrates, alignment treatment is performed on the facing surfaces of each electrode substrate by rubbing method, oblique vapor deposition method, etc. The orientation direction is set at the angle of the twisted orientation of the liquid crystal and the liquid crystals are made to face each other. Then, the outer periphery between the electrode substrates is sealed with a sealant, and liquid crystal is sealed between the electrode substrates. Note that a liquid crystal is sealed between the electrode substrates and a chiral agent is added thereto to impart appropriate twisting ability.

従来からこのような液晶表示装置の中で視野角あるいは
コン1へラストを向上させたものがいくつか開示されて
いる。
Several such liquid crystal display devices have been disclosed in the past that have improved viewing angle or contrast.

例えば特開昭60−107020@においては、液晶分
子の捩れ配向の設定角度Oが180°〜360°、カイ
ラル剤が添加され、液晶層厚dとピッチpとの比が、 d/p=θ/ 360’ とされている。
For example, in JP-A-60-107020@, the set angle O of the twisted orientation of liquid crystal molecules is 180° to 360°, a chiral agent is added, and the ratio of the liquid crystal layer thickness d to the pitch p is d/p=θ / 360'.

また特開昭60−50511号においては、液晶分子の
捩れ配向の設定角度θが160°〜200°、一定量の
カイラル剤が添加されている。
Further, in JP-A No. 60-50511, the set angle θ of the twisted orientation of liquid crystal molecules is 160° to 200°, and a certain amount of chiral agent is added.

ざらに特開昭60−73525号においては、液晶分子
の捩れ配向の82定角度がほぼ270’ 、液晶層厚d
とピッチpとの関係は、 dくpく2d とされ、上下の偏光板の透過軸または吸収軸同志とが互
いになす角度が90°±20°とされている。
In JP-A No. 60-73525, the 82 constant angle of the twisted orientation of liquid crystal molecules is approximately 270', and the liquid crystal layer thickness d
The relationship between and the pitch p is d×p×2d, and the angle between the transmission axes or absorption axes of the upper and lower polarizing plates is 90°±20°.

(発明が解決しようとする問題点) ところで液晶分子を180°以上の設定角度で捩れ配向
させた液晶表示装置においては、上記したカイラル剤の
添加によるツイスト能に起因して顕著なヒスプリシス現
象やリバース発生等が生じることがある。しかしながら
上記したいずれの液晶表示装置においても、上記ツイス
ト能についての設定が明確でない。またツイスト能の値
が適当でないと、配向膜れや電気光学特性の低下が生じ
、また高時分割駆動によるドツトマトリクス表示ができ
ないことがある。
(Problems to be Solved by the Invention) By the way, in a liquid crystal display device in which liquid crystal molecules are twisted and oriented at a set angle of 180° or more, remarkable hysteresis phenomenon and reverse Occasionally, outbreaks may occur. However, in any of the liquid crystal display devices described above, the setting of the twist ability is not clear. Furthermore, if the value of the twist ability is not appropriate, alignment film cracking or deterioration of electro-optical properties may occur, and dot matrix display by high time division driving may not be possible.

本発明は上記した事情に鑑みて創案されたもので、高時
分割駆動によるドツトマトリクス表示が可能で、かつ配
向膜れがなく高コントラストの表示を得ることのできる
液晶表示装置を提供することを目的としている。
The present invention has been devised in view of the above-mentioned circumstances, and an object of the present invention is to provide a liquid crystal display device that is capable of dot matrix display by high time division driving and that can obtain a high contrast display without alignment film blur. The purpose is

[発明の構成] (問題点を解決するための手段) すなわち本発明の液晶表示装置は、対向配置された一対
の基板と、これらの基板の対向面に形成され、液晶分子
を前記一対の基板間で180°以上の所定の角度θで捩
れ配向させる分子配向膜と、前記基板間に挟持され、ツ
イスト能がθ−10’乃至θ−60’の範囲となるカイ
ラル剤が添加された液晶組成物とを具備している。
[Structure of the Invention] (Means for Solving the Problems) That is, the liquid crystal display device of the present invention includes a pair of substrates disposed opposite to each other, and a liquid crystal display device formed on the opposing surfaces of these substrates, and in which liquid crystal molecules are connected to the pair of substrates. A liquid crystal composition sandwiched between a molecular alignment film that twists and aligns at a predetermined angle θ of 180° or more between the substrates and a chiral agent having a twist ability in the range of θ-10' to θ-60'. Equipped with things.

(作用) 本発明の液晶表示装置において、液晶分子を180°以
上の設定した角度θで捩れ配向させる液晶セルに、ツイ
スト能がθ−10’〜θ−60’に相当する量のカイラ
ル剤が添加されているので、高時分割駆動によるドツト
マトリクス表示が可能となり、配向膜れがなく高コント
ラストを得ることができるようになる。
(Function) In the liquid crystal display device of the present invention, a chiral agent in an amount corresponding to a twist ability of θ-10' to θ-60' is added to the liquid crystal cell that twists and aligns liquid crystal molecules at a set angle θ of 180° or more. Since it is added, it becomes possible to perform dot matrix display by high time division driving, and it becomes possible to obtain high contrast without alignment film blur.

(実施例) 以下、本発明の実施例の詳細を図面に基づいて説明する
(Example) Hereinafter, details of an example of the present invention will be described based on the drawings.

第2図はこの実施例の複屈折効果を利用した液晶表示装
置を示す図である。同図に示すこの装置は、液晶セル1
の両側に偏光板2.2を配置してなる。液晶セル1は、
表面に透明閑化インジウム導電ll5l(以下単に「電
極」と呼ぶ。)3が形成された2枚の厚さ1.1mmの
ガラス基板4をそれぞれ電極3面を内側にしてス・1向
配置さけ、これらのガラス基板4間の外周を封止剤6に
て到着ざUて液晶5を封入させる。またそれぞれのガラ
ス基板4上の電極3面を覆うようにポリイミドからなる
分子配向膜7が形成され、これらの表面にラビング法に
よる配向処理が施され、ざらに第3図に示すように、こ
れらの配向処理方向が180°以上の角度θに交差対向
され、液晶5の捩れ配向の設定角度がθとされている。
FIG. 2 is a diagram showing a liquid crystal display device utilizing the birefringence effect of this embodiment. This device shown in the figure consists of a liquid crystal cell 1
Polarizing plates 2.2 are arranged on both sides of the polarizing plate 2.2. The liquid crystal cell 1 is
Two 1.1 mm thick glass substrates 4 on which transparent conductive indium conductors (hereinafter simply referred to as "electrodes") 3 are formed are arranged facing toward each other with the electrodes 3 facing inside. Then, a sealant 6 is applied to the outer periphery between these glass substrates 4, and the liquid crystal 5 is sealed therein. In addition, a molecular alignment film 7 made of polyimide is formed to cover the surface of the electrodes 3 on each glass substrate 4, and these surfaces are subjected to an alignment treatment by a rubbing method, as roughly shown in FIG. The orientation treatment directions of the liquid crystals 5 are arranged to cross each other at an angle θ of 180° or more, and the setting angle of the twisted orientation of the liquid crystal 5 is θ.

またこの液晶ヒル1の両側に配置された隔光板2の透過
軸および吸収軸の方向が各ガラス基板4に近接する液晶
分子のダイレクタ百、百′と異なるものとされ、ざらに
偏光板2の透過軸PとP′とがなす角度Aが20’〜8
0’の範囲内とされている。
Furthermore, the directions of the transmission and absorption axes of the partition plates 2 disposed on both sides of the liquid crystal hill 1 are different from those of the directors of liquid crystal molecules adjacent to each glass substrate 4. The angle A between the transmission axes P and P' is 20' to 8
It is considered to be within the range of 0'.

上記液晶5の組成物としては、フェニルシクロへキリン
系液晶であり、ざらに後述する呈の左回りのカイラル剤
(S−811: E−メルク社製)が添加されている。
The composition of the liquid crystal 5 is a phenylcyclohekirin liquid crystal, to which a counterclockwise chiral agent (S-811, manufactured by E-Merck), which will be briefly described later, is added.

また本実施例において、時分割駆動特性を示す値につい
ては、以下に示すように定義した。
Further, in this embodiment, values indicating time-division drive characteristics are defined as shown below.

すなわち第4図に示す型液晶表示装置の鋳型的な電圧−
透過率特性において、透過率が90%となる電圧をV2
O,透過率が50%となる電圧をV2Oとしたとき、時
分割駆動特性を示すlIl:trをγ= (V5O−V
9O) /V9o×100(%) としている。この場合、γの値が小ざいものほど高時分
割駆動が可能となる。例えばデユーティ比が1/200
ではγが7.3%以下であることが必要とされる。
That is, the mold voltage of the type liquid crystal display device shown in FIG.
In the transmittance characteristics, the voltage at which the transmittance becomes 90% is V2.
When the voltage at which the transmittance becomes 50% is V2O, lIl:tr, which indicates the time-division drive characteristic, is expressed as γ= (V5O-V
9O) /V9o×100(%). In this case, the smaller the value of γ, the more time divisional driving becomes possible. For example, the duty ratio is 1/200
Therefore, γ is required to be 7.3% or less.

そして液晶5の捩れ配向の設定角度θが180゜および
220°のそれぞれについてカイラル剤の添加徂を変化
すなわらツイスト能を変化させ、これらの電圧−透過率
特性を測定し、上記した時分割駆動特性を示す値γを求
めた。
Then, when the setting angle θ of the twisted orientation of the liquid crystal 5 is 180° and 220°, the addition range of the chiral agent is changed and the twisting ability is changed, and these voltage-transmittance characteristics are measured, and the above-mentioned time division A value γ indicating the driving characteristics was determined.

第1図(a)、(b)に上記した条件により測定された
電圧−透過率特性から求められた時分割駆動特性を示す
値γを示す。
FIGS. 1(a) and 1(b) show the value γ indicating the time-division drive characteristic determined from the voltage-transmittance characteristic measured under the above-mentioned conditions.

同図に示すように、ツイスト能がθ−10°以上の範囲
■および■、θ−60’より小さい範囲■に相当する量
のカイラル剤を添加した場合においては、γの値が7.
3%より大きくなり、デユーティ比が1/200での時
分割駆動は困難となる。またツイスト能がθ+10°以
上の範囲■に相当する量のカイラル剤を添加した場合に
おいては、顕著なヒステリシス現象やリバース発生等に
起因して配向膜れが生じ、時分割駆動は不可能となる。
As shown in the figure, when a chiral agent is added in an amount corresponding to ranges (1) and (2) where the twist ability is θ-10° or more, and a range (2) where the twist ability is less than θ-60', the value of γ is 7.
If it becomes larger than 3%, time-division driving at a duty ratio of 1/200 becomes difficult. In addition, when a chiral agent is added in an amount corresponding to the range ■ where the twist ability is θ + 10° or more, alignment film failure occurs due to significant hysteresis phenomenon and reverse occurrence, making time-division driving impossible. .

一方、ツイスト能がθ−10°〜θ−60°の範囲■に
相当するHのカイラル剤を添加した場合においては、γ
の値が7.3%以下となり、デユーティ比が17200
での時分割駆動が可能となる。
On the other hand, when a chiral agent of H whose twist ability corresponds to the range θ-10° to θ-60° is added, γ
The value of is 7.3% or less, and the duty ratio is 17200.
This enables time-division driving.

次に上述の液晶表示装置における分子配向膜7の配向処
理を上記したラビング法の代わりにSiO斜め真空蒸着
法によるものを施し、液晶分子の捩れ配向の設定角度θ
が270°のものについて上述と同様にカイラル剤の添
加量を変化させつまりツイスト能を変化させ、この電圧
−透過率特性を測定し同様に時分割駆動特性を示す値γ
を求めた。
Next, the alignment treatment of the molecular alignment film 7 in the above-mentioned liquid crystal display device is performed by SiO oblique vacuum deposition method instead of the above-mentioned rubbing method, and the set angle θ of the twisted orientation of the liquid crystal molecules is applied.
When the angle is 270°, the amount of chiral agent added is changed in the same way as described above, that is, the twisting ability is changed, and the voltage-transmittance characteristics are measured.
I asked for

第1図(C)に上記した条件により測定された電圧−透
過率特性から求められた時分割駆動特性を示す値γを示
す。
FIG. 1(C) shows the value γ indicating the time-division drive characteristic determined from the voltage-transmittance characteristic measured under the above-mentioned conditions.

この場合においても、第1図(a)、(b)に示したも
のと同様の結果が得られる。すなわらツイスト能がθ−
10°〜θ−60’の範囲■に相当する量のカイラル剤
を添加すればデユーティ比が17200での時分割駆動
が可能となる。
In this case as well, results similar to those shown in FIGS. 1(a) and 1(b) can be obtained. In other words, the twist ability is θ−
By adding a chiral agent in an amount corresponding to the range (1) of 10° to θ-60', time-division driving with a duty ratio of 17200 becomes possible.

以上のような結果に基づいて、液晶分子の捩れ配向の設
定角度θが180°(ラビング法)、220° (ラビ
ング法)、270’  (SiO斜め真空蒸着法)で、
ツイスト能がθ−10°〜θ−60°の範囲内に相当す
る量のカイラル剤を添加してなる液晶表示装置を、1/
200のデユーティ比で時分割駆動させた結果、配向膜
れがなく高コントラストの所望の表示が得られた。
Based on the above results, when the set angle θ of the twisted orientation of liquid crystal molecules is 180° (rubbing method), 220° (rubbing method), and 270' (SiO oblique vacuum evaporation method),
A liquid crystal display device in which a chiral agent is added in an amount corresponding to a twist ability in the range of θ-10° to θ-60° is
As a result of time-division driving at a duty ratio of 200, a desired display with high contrast and no alignment film was obtained.

なお、上述した実施例においては、液晶5の組成物とし
てフェニルシクロヘキサン系のものが用いられていたが
、本発明はこれに限定されることなく、ビフェニル系、
ビシクロヘキサン系、ピリミジン系、エステル系等の液
晶においても同様な効果を得ることができる。
In addition, in the above-mentioned embodiment, a phenylcyclohexane-based composition was used as the composition of the liquid crystal 5, but the present invention is not limited to this, and biphenyl-based,
Similar effects can be obtained with bicyclohexane-based, pyrimidine-based, ester-based, etc. liquid crystals.

また添h口されたカイラル剤としてS−811(E−メ
ルク社製)であったが、これに限定されず、他のカイラ
ル剤であっても上述したようにツイスト能がθ−10°
〜θ−60”の範囲内に相当する量のカイラル剤を添加
すれば同様の効果を得ることができる。
In addition, although S-811 (manufactured by E-Merck Co., Ltd.) was used as the chiral agent that was added, it is not limited to this, and even other chiral agents may have a twisting ability of θ-10° as described above.
A similar effect can be obtained by adding a chiral agent in an amount corresponding to the range of .theta.-60''.

[発明の効果] 以上説明したように本発明の液晶表示装置によれば、高
時分割駆動による表示が可能となり、かつ配向膜れがな
く高コントラストの表示を得ることができる。
[Effects of the Invention] As described above, according to the liquid crystal display device of the present invention, it is possible to perform display by high time division driving, and to obtain a high contrast display without alignment film blur.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施例の液晶表示装置の時分割駆動
特性を示す値を示す図、第2図はこの実施例の型液晶表
示装置を示す縦断正面図、第3図はこの実施例の液晶表
示装置を示す概略的平面図、第4図は型液晶表示装置の
典型的な電圧−透過率特性を示す図である。 γ・・・・・・・・・時分割駆動特性を示す1直出願人
      株式会社 東 芝 代理人 弁理士  須 山 (左 − ツメスト嘴し 第1図 第 20 第3図 印ηυ先/iV 第4図
FIG. 1 is a diagram showing values indicating time division drive characteristics of a liquid crystal display device according to an embodiment of the present invention, FIG. 2 is a longitudinal sectional front view showing a liquid crystal display device according to this embodiment, and FIG. FIG. 4 is a schematic plan view showing an example liquid crystal display device, and is a diagram showing typical voltage-transmittance characteristics of a type liquid crystal display device. γ・・・・・・・1 direct applicant showing time-division drive characteristics Toshiba Corporation Patent attorney Suyama (Left - Tsumesto beak Figure 1 Figure 20 Figure 3 Mark ηυ tip/iV Figure 4

Claims (1)

【特許請求の範囲】[Claims] (1)対向配置された一対の基板と、 これらの基板の対向面に形成され、液晶分子を前記一対
の基板間で180°以上の所定の角度θで捩れ配向させ
る分子配向膜と、 前記基板間に挟持され、ツイスト能がθ−10°乃至θ
−60°の範囲となるカイラル剤が添加された液晶組成
物と を備えた液晶表示装置。
(1) a pair of substrates arranged opposite to each other; a molecular alignment film formed on the opposing surfaces of these substrates to twist and align liquid crystal molecules at a predetermined angle θ of 180° or more between the pair of substrates; and the substrates. The twisting ability is between θ-10° and θ.
A liquid crystal display device comprising: a liquid crystal composition to which a chiral agent is added that has an angle of -60°.
JP61152190A 1986-06-28 1986-06-28 Liquid crystal display device Pending JPS638631A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP61152190A JPS638631A (en) 1986-06-28 1986-06-28 Liquid crystal display device
US07/064,001 US4779958A (en) 1986-06-28 1987-06-19 Liquid crystal device having different natural and induced twists
EP87305597A EP0251665B1 (en) 1986-06-28 1987-06-23 Liquid crystal device
DE87305597T DE3787055T2 (en) 1986-06-28 1987-06-23 Liquid crystal device.
KR1019870006576A KR900006939B1 (en) 1986-06-28 1987-06-27 Liquid crystal display

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61152190A JPS638631A (en) 1986-06-28 1986-06-28 Liquid crystal display device

Publications (1)

Publication Number Publication Date
JPS638631A true JPS638631A (en) 1988-01-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP61152190A Pending JPS638631A (en) 1986-06-28 1986-06-28 Liquid crystal display device

Country Status (2)

Country Link
JP (1) JPS638631A (en)
KR (1) KR900006939B1 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6280622A (en) * 1985-10-04 1987-04-14 Konishiroku Photo Ind Co Ltd Liquid crystal display device
JPS62194224A (en) * 1986-02-20 1987-08-26 Sharp Corp Twisted nematic type liquid crystal display element

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6280622A (en) * 1985-10-04 1987-04-14 Konishiroku Photo Ind Co Ltd Liquid crystal display device
JPS62194224A (en) * 1986-02-20 1987-08-26 Sharp Corp Twisted nematic type liquid crystal display element

Also Published As

Publication number Publication date
KR890000919A (en) 1989-03-17
KR900006939B1 (en) 1990-09-25

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