JPS6379934A - Intermetallic compound grain dispersion-strengthened-type alloy and its production - Google Patents
Intermetallic compound grain dispersion-strengthened-type alloy and its productionInfo
- Publication number
- JPS6379934A JPS6379934A JP22519486A JP22519486A JPS6379934A JP S6379934 A JPS6379934 A JP S6379934A JP 22519486 A JP22519486 A JP 22519486A JP 22519486 A JP22519486 A JP 22519486A JP S6379934 A JPS6379934 A JP S6379934A
- Authority
- JP
- Japan
- Prior art keywords
- alloy
- intermetallic compound
- powder
- particle dispersion
- dispersion strengthened
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 51
- 239000000956 alloy Substances 0.000 title claims abstract description 51
- 229910000765 intermetallic Inorganic materials 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 20
- 239000011159 matrix material Substances 0.000 claims abstract description 12
- 238000004512 die casting Methods 0.000 claims abstract description 10
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims description 34
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 26
- 239000006185 dispersion Substances 0.000 claims description 22
- 229910001151 AlNi Inorganic materials 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 13
- 229910018507 Al—Ni Inorganic materials 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000013019 agitation Methods 0.000 abstract 3
- 239000000463 material Substances 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- 229910000990 Ni alloy Inorganic materials 0.000 description 4
- 229910018505 Ni—Mg Inorganic materials 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000009830 intercalation Methods 0.000 description 3
- 230000002687 intercalation Effects 0.000 description 3
- 230000013011 mating Effects 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000009770 conventional sintering Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 231100000241 scar Toxicity 0.000 description 2
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、金属間化合物粒子分散強化型合金及びその製
造方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an intermetallic compound particle dispersion strengthened alloy and a method for producing the same.
金属間化合物ＡｌＮｉは高い規則化エネルギーを持ち、
ＮｉとＡｌの結合が強い故に優れた耐酸化性及び高硬度
を持つＢ ｅ ｒ ｔ ｈｏ ７１７３ ｉ ｄｅ型化
合物である。The intermetallic compound AlNi has high ordering energy,
It is a Bertho 7173 i de type compound that has excellent oxidation resistance and high hardness due to the strong bond between Ni and Al.
又、ＡｌＮｉ、ばＬｌ、型構造を持ち、耐酸化性及び高
温強度を持つ金属間化合物である。Furthermore, AlNi is an intermetallic compound that has a type structure and has oxidation resistance and high-temperature strength.
これら金属間化合物は、アルミ合金溶湯中へ直接添加す
ることで短時間に溶解する為、従来、金属間化合物粒子
分散強化型合金は焼結法によって製造している。Conventionally, intermetallic compound particle dispersion-strengthened alloys have been manufactured by a sintering method because these intermetallic compounds dissolve in a short time when directly added to molten aluminum alloy.
従来の焼結法は、母相の微細金属粉末に、金属間化合物
粉末を添加して機械的に攪拌混合を行い、これをプレス
成形し、加熱焼結して金層間化合物粒子分散強化型合金
を製造するもので、加熱焼結したものを押出機、圧延機
により目的とする製品を製造する方法である。In the conventional sintering method, intermetallic compound powder is added to the fine metal powder of the matrix, mechanically stirred and mixed, then press-formed, and heated and sintered to create a gold intercalation compound particle dispersion-strengthened alloy. This is a method of producing the desired product by heating and sintering the product using an extruder or rolling mill.
しかしながら、従来の焼結法では、金属間化合物粉末と
母合金粉末を機械的に攪拌混合するのであるが、母合金
粉末に金属間化合物粉末を均一にマトリックスに分散混
合することは、粒子間の凝集、比重差等の為に困難であ
った。However, in the conventional sintering method, the intermetallic compound powder and the master alloy powder are mechanically stirred and mixed, but it is difficult to uniformly disperse and mix the intermetallic compound powder in the matrix. This was difficult due to agglomeration, differences in specific gravity, etc.
又、プレス成形、加熱焼結に際して酸化が伴なう為に、
加熱焼結する過程で酸化防止方法及び装置が必要であり
、それ故に、寸法精度の高い製品、又強度的にも制約が
あり、経費の点でもかなりの問題をもっている為、安価
に粒子分散型合金を大量生産することは困難である問題
点がある。In addition, since oxidation occurs during press forming and heating sintering,
Oxidation prevention methods and equipment are required during the heating and sintering process, and therefore products with high dimensional accuracy and strength are limited, and there are considerable problems in terms of cost. There is a problem in that it is difficult to mass produce the alloy.
本発明は上記問題点を解消しようとしたもので、従来、
金属間化合物粒子を合金溶湯中に添加すると溶解する為
に直接溶湯中に添加することは不可能とされていたもの
を、ダイカストマシンを使用することによって、直接溶
湯中に添加できて短時間の機械的攪拌により溶解せずに
金属間化合物を均一にマトリックスに分散させることが
でき、このことによって、延性を減じることなく、優れ
た機械的特性を有する金属間化合物粒子分散強化型合金
と、その製造方法を提供しようとするのが、その目的で
ある。The present invention attempts to solve the above problems, and conventionally,
When intermetallic compound particles are added to the molten alloy, they dissolve, so it was considered impossible to directly add them to the molten metal. However, by using a die-casting machine, it is possible to add them directly to the molten metal in a short time. Mechanical stirring allows the intermetallic compounds to be uniformly dispersed in the matrix without dissolution, thereby creating an intermetallic particle dispersion strengthened alloy with excellent mechanical properties without reducing ductility. Its purpose is to provide a manufacturing method.
即ち本発明は、ニッケル粉末あるいはニッケル基金属間
化合物粉末を直接溶湯合金中へ添加し、攪拌混合した後
、ダイカストマシンに給湯することによって、粉末を均
一にマトリックスに分散させるようにして、上記問題点
を解決したのである。That is, the present invention solves the above problem by directly adding nickel powder or nickel-based intermetallic compound powder to a molten alloy, stirring and mixing, and then supplying hot water to a die-casting machine to uniformly disperse the powder in a matrix. This solved the problem.
以下本発明の合金と、その製造方法の実施例を詳述する
。Examples of the alloy of the present invention and its manufacturing method will be described in detail below.
Ａ１５Ｎ＋ 、 Ａ４ Ｎｒ 、 ＡｉＮｒｓ 金属
間化合物粒子（４４μ直径以下）を直接Ａｌ１−３．．
５ｗｔ％〜８．Ｏｗｔ％Ｎｉ合金溶湯（６４０℃〜７０
０℃〕に投入添加し、この合金溶湯＋粉末１を、第１図
に示した攪拌混合装置の攪拌混合槽２に収容し、攪拌羽
根３をモーター４で回転させ、攪拌混合した。A15N+, A4Nr, AiNrs intermetallic compound particles (44μ diameter or less) were directly mixed with Al1-3. ．．
5wt%~8. Owt%Ni alloy molten metal (640℃~70℃
The molten alloy + powder 1 was placed in the stirring mixing tank 2 of the stirring mixing device shown in FIG. 1, and the stirring blade 3 was rotated by the motor 4 to stir and mix.
攪拌混合後、ダイカストマシンに給湯した。After stirring and mixing, hot water was supplied to the die-casting machine.
こ〜で、上記Ａｌ−３．５ｗｔ％〜８．Ｑｗｔ％Ｎｉ合
金は、優れた機械的性質を持ち、
かつ価格的にも低Ｎｉ％であるが為にマトリックスとし
て適している。Here, the above Al-3.5wt%~8. Qwt%Ni alloy is suitable as a matrix because it has excellent mechanical properties and is inexpensive and has a low Ni%.
第２図はＡｌ−Ｎｉ組織状態を示し、第３図（イ）、Ｉ
ｐ）は１０ｗｔ％ＡｌＮｉ金属間化合物粉末を、Ａｌ−
５．７ｗｔ％〜６． Ｏｗ ｔ％Ｎ１溶湯中に投し、添
加攪拌混合後、金型にダイカストマシンで注湯して得ら
れた試験片の組織を示した写真である。Figure 2 shows the Al-Ni structure, Figure 3 (a), I
p) is 10wt% AlNi intermetallic compound powder, Al-
5.7wt%~6. This is a photograph showing the structure of a test piece obtained by pouring the molten metal into a molten metal of Ow t%N1, stirring and mixing it, and then pouring the molten metal into a mold using a die-casting machine.
又、第３図（ハ）は、溶湯投入前の粒子を、第３５．７
ｗｔ％
図に）は、ｌＱｗｔ％Ｎｉ粒子をＡＪ −Ｎｉ溶湯中に
投入添加し、攪拌後、金型にダイカストマシンで注湯し
て得られた試験片の組織を夫々示した写真である。In addition, Fig. 3 (c) shows the particles before being added to the molten metal in Fig. 35.7.
(wt%) is a photograph showing the structure of a test piece obtained by adding 1Qwt% Ni particles to molten AJ-Ni, stirring, and pouring the molten metal into a mold using a die-casting machine.
第３図（イ）〜に）の各写真には、ＡｌＮｉ金属間化合
物粒子、およびＮｉ粒子が母合金に均一に分散している
ことが示されている。The photographs in FIGS. 3(a) to 3(a) show that AlNi intermetallic compound particles and Ni particles are uniformly dispersed in the master alloy.
Ｎｉ粒子及び金属間化合物ＡｌＮｉ粒子はＡ／−Ｎｉ合
金マトリックスとの結合力、又濡れ性は良いが、ＡＪ−
Ｎｉ合金溶湯中に長時間（１０分以上）保持し、攪拌混
合すると溶解する。Ni particles and intermetallic compound AlNi particles have good bonding strength and wettability with the A/-Ni alloy matrix, but AJ-
When kept in the molten Ni alloy for a long time (10 minutes or more) and stirred and mixed, it dissolves.
上述の金属間化合物粒子を合金溶湯中に投入添加して攪
拌混谷後、ダイカストマシンに給湯して引張試験用試験
片及び摩耗試験片を鋳造し、夫々の試験を行った。The above-mentioned intermetallic compound particles were added to the molten alloy and stirred, and then hot water was supplied to a die-casting machine to cast a tensile test specimen and an abrasion test specimen, and each test was conducted.
尚、摩耗試験は大越式摩耗試験により無潤滑条件下で最
終荷重２．１ｋｇ、滑り距離２ｏｏ？？ｌ、滑り速度を
変化させて行い、摩耗痕幅より比摩耗量を測定した。The wear test was conducted using the Okoshi type wear test under non-lubricated conditions with a final load of 2.1kg and a sliding distance of 2oo? ? 1. The sliding speed was varied and the specific wear amount was measured from the wear scar width.
この試験結果を表−１、表−２及び第４図、第５図に示
す。The test results are shown in Table 1, Table 2, and Figures 4 and 5.
以下余白
表−１
供試材基 ３９０Ｒ，ＡＩ！−Ｎｉ−Ｍｇ、 Ｓｉ、Ｎ
、ＡＤＣＩＯ，ＡｌＮｉ／Ａｌ−Ｎｉ標準回転円板材料
名 ＰＣ２５
表−２
供試材基 ３９０Ｒ，ＡＪ−Ｎｉ−Ｍｇ、Ｓｉ、Ｎ、／
ＡＤＣＩＯ，ＡｌＮｉ／Ａｌ−Ｎｉ標準回転円板材料名
ＳＵＪ ２
表−１は、相手材としてはＦｅ１２材を使用した時の３
９ＯＲ，ＡＡ’−Ｎｉ−Ｍｇ合金、Ｓｉ、Ｎ、粒子分散
強化合金、ＡｌＮｉ金属間化合物分散強化複合材（本発
明の材料〕の摩耗速度、摩耗距離、最終荷重、摩耗痕幅
、比摩耗量の結果であり、第４図はそれをプロットした
グラフであって、横軸に滑り速度を、縦軸に比摩耗量を
とったものである。Margin table below-1 Test material base 390R, AI! -Ni-Mg, Si, N
, ADCIO, AlNi/Al-Ni standard rotating disc material name PC25 Table-2 Test material base 390R, AJ-Ni-Mg, Si, N, /
ADCIO, AlNi/Al-Ni Standard Rotating Disc Material Name SUJ 2 Table 1 shows 3 when Fe12 material is used as the mating material.
9OR, AA'-Ni-Mg alloy, Si, N, particle dispersion strengthened alloy, AlNi intermetallic compound dispersion strengthened composite material (material of the present invention) wear rate, wear distance, final load, wear scar width, specific wear amount FIG. 4 is a graph plotting the results, with the horizontal axis representing the sliding speed and the vertical axis representing the specific wear amount.
同図より、高速滑り速度の場合１．＋ＪＮｉ粒子分散強
化合金はＳｉ、Ｎ、粒子分散強化合金の倍以上の耐摩耗
性を有する。From the same figure, in the case of high sliding speed 1. +JNi particle dispersion strengthened alloy has wear resistance more than twice that of Si, N, particle dispersion strengthened alloy.
表−２は相手材として、５ＵＪＺ材を使用した時の３９
ＯＲ、ｋｌ−Ｎｉ−Ｍｇ合金、Ｓｉ、 Ｎ番粒子分散強
化合金、ＡＪＮｉ全Ｎｉ化合物分散強化合金の摩耗量の
結果であり、第５図は、それをプロットしたグラフであ
り、横軸に滑り速度を、縦軸に比摩耗量をとったもので
ある。Table 2 shows 39 when using 5UJZ material as the mating material.
The results are the wear amount of OR, kl-Ni-Mg alloy, Si, N-number particle dispersion strengthened alloy, and AJNi all-Ni compound dispersion strengthened alloy. Figure 5 is a graph plotting the results, with slip on the horizontal axis. The velocity is plotted on the vertical axis, and the specific wear amount is plotted on the vertical axis.
同図より、高速及び低速滑り速度の場合、本発明の合金
（ＡＩ！Ｎｉ分散強化合金）は８１ｓｌ’Ｌ粒子分散強
化合金の倍近くの耐摩耗性が示された。The figure shows that at high and low sliding speeds, the alloy of the present invention (AI!Ni dispersion strengthened alloy) has nearly twice the wear resistance as the 81sl'L particle dispersion strengthened alloy.
更に、機械的性質として、本発明合金（ＡｌＮｉ粒子分
散強化合金）と、Ｓｉ、Ｎ、粒子分散強化合金を比べた
場合、伸びはＡｌＮｉ粒子材＜、７１１〜５７ｗｔ％Ｎ
ｉ ）か３．６〜５．Ｑｗｔ％、Ｓｉ、Ｎ、粒子分散材
（／ＡＤＣ１０，ｌは０．８〜０．９％であった。表−
３に機械的性質を示す。Furthermore, in terms of mechanical properties, when comparing the present invention alloy (AlNi particle dispersion strengthened alloy) with Si, N, particle dispersion strengthened alloy, the elongation is AlNi particle material <, 711 to 57 wt%N
i) or 3.6-5. Qwt%, Si, N, particle dispersion material (/ADC10,l was 0.8 to 0.9%. Table-
3 shows the mechanical properties.
表−３機械的性質
〔発明の効果〕
以上説明したように本発明に係る金属間化合物粒子分散
強化型合金によれば、ニッケル粉末あるいはニッケル基
金属間化合物粉末が母合金に均一にマトリックスに分散
されていることによって耐摩耗性及び延性を向上でき、
もって優れた機械的特性を有する効果がある。Table 3 Mechanical Properties [Effects of the Invention] As explained above, according to the intermetallic compound particle dispersion strengthened alloy according to the present invention, nickel powder or nickel-based intermetallic compound powder is uniformly dispersed in the matrix of the mother alloy. The wear resistance and ductility can be improved by
This has the effect of providing excellent mechanical properties.
又、本発明の製造方法ζこよれば、上記Ｎｉ粒子を上記
母合金溶湯中に添加し、短時間の機械的攪拌混合後、直
接ダイカストマシンによって均一にマトリックスに分散
させるようにしたから、凝集等の問題が起ることなく均
一に分散できて優れた耐摩耗性及び延性の粒子分散強化
型合金が得られると共に、ダイカスト鋳造法を利用する
ので、従来の焼結、粉末冶金法のように、コスト高な表
面処理方法や酸化防止方法及び装置−を必要としないの
で、従来法と比較して加工費を低減でき、又複雑形状を
容易に製造でき、多くの工程を省略化できるので安価に
粒子分散型強化合金を大量生産することができる利点が
ある。Moreover, according to the manufacturing method of the present invention, the Ni particles are added to the molten master alloy, and after a short period of mechanical stirring and mixing, they are uniformly dispersed in the matrix directly by a die-casting machine, so that no agglomeration occurs. A particle dispersion-strengthened alloy with excellent wear resistance and ductility can be obtained by uniformly dispersing the particles without problems such as sintering and powder metallurgy. Because it does not require expensive surface treatment methods, oxidation prevention methods, or equipment, processing costs can be reduced compared to conventional methods, and complex shapes can be easily manufactured, and many processes can be omitted, making it inexpensive. This method has the advantage of being able to mass-produce particle-dispersed reinforced alloys.
第１図は本発明に係る金層間化合物粒子分散強化型合金
の製造方法に用いられる攪拌混合装置の一例を一部断面
して示した正面図、第２図金型にダイカストマシンで注
湯して得られた各試験片の各組織を夫々示した各写真、
第４図、第５図は各試験片の相手材に対する滑り速度と
比摩耗量との関係を夫々示した各グラフである。Fig. 1 is a partially sectional front view of an example of the stirring and mixing device used in the method for manufacturing a gold intercalation compound particle dispersion strengthened alloy according to the present invention, and Fig. 2 is a partially cross-sectional front view of an example of a stirring and mixing device used in the method for manufacturing a gold intercalation compound particle dispersion strengthened alloy. Each photograph showing each structure of each test piece obtained by
FIGS. 4 and 5 are graphs showing the relationship between the sliding speed and specific wear amount of each test piece relative to the mating material.
Claims (6)
末を直接溶湯合金中へ添加し、攪拌混合して均一に分散
させてなることを特徴とする金属間化合物粒子分散強化
型合金。(1) An intermetallic compound particle dispersion strengthened alloy characterized in that nickel powder or nickel-based intermetallic compound powder is directly added to a molten alloy and uniformly dispersed by stirring and mixing.
末を直接溶湯合金中へ添加し、攪拌混合した後、ダイカ
ストマシンに給湯することによって、粉末を均一にマト
リックスに分散させることを特徴とする金属間化合物粒
子分散強化型合金の製造方法。(2) An intermetallic compound characterized in that nickel powder or nickel-based intermetallic compound powder is directly added to a molten alloy, stirred and mixed, and then the powder is uniformly dispersed in a matrix by supplying hot water to a die-casting machine. A method for producing a particle dispersion strengthened alloy.
、ＮｉあるいはＡｌＮｉ＿３である特許請求の範囲第１
項、第２項記載の金属間化合物粒子分散強化型合金及び
その製造方法。(3) The nickel-based intermetallic compound is AlNi, Al_3
, Ni or AlNi_3
2. The intermetallic compound particle dispersion strengthened alloy and its manufacturing method according to item 2.
金マトリックスである特許請求の範囲第１項、第２項に
記載の金属間化合物粒子分散強化型合金及びその製造方
法。(4) The intermetallic compound particle dispersion strengthened alloy and its manufacturing method according to claims 1 and 2, wherein the molten alloy is a molten aluminum alloy or an AlNi alloy matrix.
ｗｔ％範囲のＡｌＮｉ、ＡｌＮｉ＿３、Ａｌ＿３Ｎｉの
金属間化合物合粉末である特許請求の範囲第１項、第２
項記載の金属間化合物粒子分散強化型合金及びその製造
方法。(5) Nickel-based intermetallic compound powder is 10 wt to 20 wt.
Claims 1 and 2 are intermetallic compound composite powders of AlNi, AlNi_3, and Al_3Ni in the wt% range.
Intermetallic compound particle dispersion strengthened alloy and method for producing the same as described in 1.
ｉ合金マトリックスである特許請求の範囲第１項、第２
項記載の金属間化合物粒子分散強化型合金及びその製造
方法。(6) Molten alloy is Al-3.5wt~8.0wt%N
Claims 1 and 2, which are i-alloy matrix.
Intermetallic compound particle dispersion strengthened alloy and method for producing the same as described in 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22519486A JPS6379934A (en) | 1986-09-23 | 1986-09-23 | Intermetallic compound grain dispersion-strengthened-type alloy and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22519486A JPS6379934A (en) | 1986-09-23 | 1986-09-23 | Intermetallic compound grain dispersion-strengthened-type alloy and its production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6379934A true JPS6379934A (en) | 1988-04-09 |
| JPH0320453B2 JPH0320453B2 (en) | 1991-03-19 |
Family
ID=16825443
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22519486A Granted JPS6379934A (en) | 1986-09-23 | 1986-09-23 | Intermetallic compound grain dispersion-strengthened-type alloy and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6379934A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0920940A (en) * | 1994-12-19 | 1997-01-21 | Inco Ltd | Alloy containing insoluble phase and its production |
| CN106884100A (en) * | 2015-12-16 | 2017-06-23 | 湖南科技大学 | A kind of preparation method of nickel aluminium base multiphase alloy |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5512178A (en) * | 1978-12-28 | 1980-01-28 | Toyo Jozo Co Ltd | Carrier having s-s exchange reactivity |
| JPS55122849A (en) * | 1973-05-17 | 1980-09-20 | Alcan Res & Dev | Dispersion intensified aluminum alloy |
| JPS61115657A (en) * | 1984-11-08 | 1986-06-03 | Nissan Motor Co Ltd | Production of cam shaft |
| JPS62218526A (en) * | 1986-03-18 | 1987-09-25 | Showa Alum Corp | Manufacture of extruded aluminum alloy material having superior modulus of elasticity |
-
1986
- 1986-09-23 JP JP22519486A patent/JPS6379934A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55122849A (en) * | 1973-05-17 | 1980-09-20 | Alcan Res & Dev | Dispersion intensified aluminum alloy |
| JPS5512178A (en) * | 1978-12-28 | 1980-01-28 | Toyo Jozo Co Ltd | Carrier having s-s exchange reactivity |
| JPS61115657A (en) * | 1984-11-08 | 1986-06-03 | Nissan Motor Co Ltd | Production of cam shaft |
| JPS62218526A (en) * | 1986-03-18 | 1987-09-25 | Showa Alum Corp | Manufacture of extruded aluminum alloy material having superior modulus of elasticity |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0920940A (en) * | 1994-12-19 | 1997-01-21 | Inco Ltd | Alloy containing insoluble phase and its production |
| CN106884100A (en) * | 2015-12-16 | 2017-06-23 | 湖南科技大学 | A kind of preparation method of nickel aluminium base multiphase alloy |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0320453B2 (en) | 1991-03-19 |
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