JPS6352035B2 - - Google Patents
Info
- Publication number
- JPS6352035B2 JPS6352035B2 JP59209979A JP20997984A JPS6352035B2 JP S6352035 B2 JPS6352035 B2 JP S6352035B2 JP 59209979 A JP59209979 A JP 59209979A JP 20997984 A JP20997984 A JP 20997984A JP S6352035 B2 JPS6352035 B2 JP S6352035B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- atom
- dimethyl
- silane
- hydrogen atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 methylenedioxy group Chemical group 0.000 claims description 43
- 150000001875 compounds Chemical class 0.000 claims description 32
- 230000000895 acaricidal effect Effects 0.000 claims description 14
- 239000002917 insecticide Substances 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 239000000642 acaricide Substances 0.000 claims description 11
- 125000005843 halogen group Chemical group 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 8
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 claims description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 125000001153 fluoro group Chemical group F* 0.000 claims description 4
- 125000004970 halomethyl group Chemical group 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 150000001491 aromatic compounds Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 20
- 238000012360 testing method Methods 0.000 description 16
- 230000000749 insecticidal effect Effects 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 241000255925 Diptera Species 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000004480 active ingredient Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 229910000077 silane Inorganic materials 0.000 description 6
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 125000004344 phenylpropyl group Chemical group 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000251468 Actinopterygii Species 0.000 description 3
- 241001674044 Blattodea Species 0.000 description 3
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 3
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229960005235 piperonyl butoxide Drugs 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- ZJZURWFWIYFHIP-UHFFFAOYSA-N (4-chlorophenyl)-dimethyl-[3-(3-phenoxyphenyl)propyl]silane Chemical compound C=1C=C(Cl)C=CC=1[Si](C)(C)CCCC(C=1)=CC=CC=1OC1=CC=CC=C1 ZJZURWFWIYFHIP-UHFFFAOYSA-N 0.000 description 2
- LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 description 2
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- 241001414720 Cicadellidae Species 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 description 2
- 241000257226 Muscidae Species 0.000 description 2
- 241001477931 Mythimna unipuncta Species 0.000 description 2
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 2
- 241001454295 Tetranychidae Species 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000004440 column chromatography Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000003958 fumigation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 2
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229960005199 tetramethrin Drugs 0.000 description 2
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- VXJILKJPONNCPI-UHFFFAOYSA-N (4-ethoxyphenyl)-dimethyl-[(3-phenoxyphenyl)methoxymethyl]silane Chemical compound C1=CC(OCC)=CC=C1[Si](C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 VXJILKJPONNCPI-UHFFFAOYSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- ZRPAUEVGEGEPFQ-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2 ZRPAUEVGEGEPFQ-UHFFFAOYSA-N 0.000 description 1
- 241001143309 Acanthoscelides obtectus Species 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241000238657 Blattella germanica Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- NENBAISIHCWPKP-UHFFFAOYSA-N Clofenamide Chemical compound NS(=O)(=O)C1=CC=C(Cl)C(S(N)(=O)=O)=C1 NENBAISIHCWPKP-UHFFFAOYSA-N 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000256054 Culex <genus> Species 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 241000252233 Cyprinus carpio Species 0.000 description 1
- 241001555556 Ephestia elutella Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241001466042 Fulgoromorpha Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- PWKSKIMOESPYIA-BYPYZUCNSA-N L-N-acetyl-Cysteine Chemical compound CC(=O)N[C@@H](CS)C(O)=O PWKSKIMOESPYIA-BYPYZUCNSA-N 0.000 description 1
- 241000406668 Loxodonta cyclotis Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000005916 Methomyl Substances 0.000 description 1
- 241000721621 Myzus persicae Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000320508 Pentatomidae Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000500441 Plutellidae Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 244000088415 Raphanus sativus Species 0.000 description 1
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 1
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- PDGSORGDLNUSQJ-UHFFFAOYSA-N [SiH4].[K] Chemical compound [SiH4].[K] PDGSORGDLNUSQJ-UHFFFAOYSA-N 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- 125000005228 aryl sulfonate group Chemical group 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- RBHJBMIOOPYDBQ-UHFFFAOYSA-N carbon dioxide;propan-2-one Chemical compound O=C=O.CC(C)=O RBHJBMIOOPYDBQ-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- PNSSAIWWQLYKCQ-UHFFFAOYSA-N chloro-(4-chlorophenyl)-dimethylsilane Chemical compound C[Si](C)(Cl)C1=CC=C(Cl)C=C1 PNSSAIWWQLYKCQ-UHFFFAOYSA-N 0.000 description 1
- RTYNSTRFACIKRL-UHFFFAOYSA-N chloro-(4-methoxyphenyl)-dimethylsilane Chemical compound COC1=CC=C([Si](C)(C)Cl)C=C1 RTYNSTRFACIKRL-UHFFFAOYSA-N 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 244000013123 dwarf bean Species 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000021331 green beans Nutrition 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- LBORZFICAPONTF-UHFFFAOYSA-N lithium;silane Chemical compound [Li].[SiH4] LBORZFICAPONTF-UHFFFAOYSA-N 0.000 description 1
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 description 1
- VOEYXMAFNDNNED-UHFFFAOYSA-N metolcarb Chemical compound CNC(=O)OC1=CC=CC(C)=C1 VOEYXMAFNDNNED-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- WLLGXSLBOPFWQV-OTHKPKEBSA-N molport-035-783-878 Chemical compound C([C@H]1C=C2)[C@H]2C2C1C(=O)N(CC(CC)CCCC)C2=O WLLGXSLBOPFWQV-OTHKPKEBSA-N 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 230000000422 nocturnal effect Effects 0.000 description 1
- 239000003992 organochlorine insecticide Substances 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 230000024241 parasitism Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- PWYIUEFFPNVCMW-UHFFFAOYSA-N propaphos Chemical compound CCCOP(=O)(OCCC)OC1=CC=C(SC)C=C1 PWYIUEFFPNVCMW-UHFFFAOYSA-N 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 229940048383 pyrethrum extract Drugs 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 230000011685 response to pyrethroid Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 210000000115 thoracic cavity Anatomy 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
æ¬çºæã¯äžè¬åŒ
ïŒåŒäžãR1ãR2ã¯åäžåã¯çžç°ãªããæ°ŽçŽ ååã
ããã²ã³ååãççŽ æ°ãïŒãïŒã®ã¢ã«ãã«åºãã
ãã¡ãã«åºãã¡ããã·åºããšããã·åºããžãã«ãª
ãã¡ããã·åºãããã¯R1ãšR2ã§ã¡ãã¬ã³ãžãªã
ã·åºãè¡šããã ã¯é žçŽ ååãŸãã¯ã¡ãã¬ã³åºã§ãããã¯é ž
çŽ ååãã¡ãã¬ã³åºãã¢ããåºãã¡ãã«ã¢ããåº
ãããã¯ãã«ãã«ã¢ããåºãè¡šãããR3ã¯æ°ŽçŽ
åååã¯ããçŽ ååããR4ã¯æ°ŽçŽ ååãããã²
ã³åååã¯ã¡ãã«åºãè¡šãããïŒ ã§è¡šããããææ©ã±ã€çŽ ç³»è³éŠæã¢ã«ã«ã³èªå°äœ
ãæå¹æåãšããŠå«æããããšãç¹åŸŽãšãã殺
è«ã殺ããå€åã³ãã®è£œæ³ã«é¢ããã è¿å¹Žã倩ç¶ã®æ®ºè«æåã§ãããã¬ããªã³ã®ååŠ
æ§é ãæ¹å€ããé¡çžäœã®ç 究ãåºãé²ããããäž
è¬åŒïŒïŒ ïŒããã«ãR1ãR2ãR3ãR4ã¯åè¿°ãšåãæå³ã
è¡šãããïŒã§è¡šããããååç©çŸ€ã®ä»ããšã¹ãã«
éšåãä»ã®åºã«çœ®ãæããäŸãã°ïŒïŒ ã§ç€ºãããååç©ã«é«ã殺è«æŽ»æ§ãèŠãåºããã
ïŒç¹éæ58â201737å·å ¬å ±ïŒã ãããã®ååç©ã¯ãåŸæ¥ã®ææ©ãªã³å€ãã«ãŒã
ã¡ãŒãå€ã«æ¿ãã蟲è¬ãšããŠåºãéçºãé²ããã
ãŠããããå°æ¥å°æ¥ããã§ããããã¬ã¹ãã€ã
æµææ§åé¡ã«åå察åŠã§ããªããæ€ç©äœå ãžã®
浞éæ§ã«ä¹ãããç¹ã«ïŒïŒã®ã¿ã€ãã®ååç©
ã«ã€ããŠã¯éæ¯æ§ãé«ãçããã¬ã¹ãã€ãã«çœ®ã
ããåºæã®åé¡ç¹ã¯ãªãååæ¹åãããŠããªãã æ¬çºæè ãã¯æŽã«æçšãªæ®ºè«ã殺ããæåãæ¢
玢ãã¹ãéæç 究ãç¶ããçµæãççŽ å çŽ ã®ä»£æ¿
å çŽ ã§ããã±ã€çŽ å çŽ ãå°å ¥ããããšã«ãã€ãŠäž
èšããã®æ¬ ç¹ãèããæ¹åãããäžæ¹ãã
ãšã®ååç©ã«èŒã¹æ®ºè«å¹åãå¢åŒ·ããæž©è¡åç©ã«
察ããæ¯æ§ãæŽã«è»œæžãããããšãç¥ããæ¬çºæ
ãå®æãããã±ã€çŽ å çŽ ã®å°å ¥ãå¹æçãªçç±ã«
ã€ããŠã¯ãªãäžæãªç¹ãå€ãããã±ã€çŽ ååã®å€
æ®»ã«ååšãã空ã®3dè»éã«èµ·å ãããã®ãšæšå®
ãããã æ¬çºæã§æå¹æåãšããŠçšããäžèšåŒïŒïŒã§
è¡šããããååç©ã¯äžè¬åŒïŒïŒ ïŒåŒäžãR1ãR2ã¯åäžåã¯çžç°ãªããæ°ŽçŽ ååã
ããã²ã³ååãççŽ æ°ãïŒãïŒã®ã¢ã«ãã«åºãã
ãã¡ãã«åºãã¡ããã·åºããšããã·åºããžãã«ãª
ãã¡ããã·åºãããã¯R1ãšR2ã§ã¡ãã¬ã³ãžãªã
ã·åºãè¡šãããåãïŒã¯éå±ååïŒNaããLi
çïŒãè¡šãããïŒã§ç€ºãããææ©ã±ã€çŽ è³éŠæå
åç©ãšäžè¬åŒ ïŒåŒäžãã¯é žçŽ ååãŸãã¯ã¡ãã¬ã³ååã§ã
ããã¯é žçŽ ååãã¡ãã¬ã³åºãã¢ããåºãã¡ã
ã«ã¢ããåºãããã¯ãã«ãã«ã¢ããåºãè¡šããã
R3ã¯æ°ŽçŽ åååã¯ããçŽ ååããR4ã¯ãæ°ŽçŽ å
åãããã²ã³åååã¯ã¡ãã«åºãè¡šããããŸã
ã¯ããã²ã³ååãããã¯æ°Žé žåºã®åå¿æ§èªå°äœã
è¡šãããïŒã§è¡šããããååç©ãåå¿ãããŠèª¿è£œ
ããããåå¿ã¯é©åœãªæº¶åªäžã§ãå¿ èŠã«ãã觊åª
ã®ååšäžã«å¿ èŠã«ããå ç±äžã«è¡ãªããããäžèš
åŒïŒïŒã§ç€ºãããååç©ã®ä»£è¡šäŸã瀺ãã°æ¬¡ã®
éãã§ããããæ¬çºæã¯ãã¡ãããããã®ã¿ã«é
å®ããããã®ã§ã¯ãªãã (1) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïœïŒâïŒïŒâ
ããšããã·ïŒããšãã«ãããã«ïœã·ã©ã³
n20 D 1.5641 (2) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïŒïŒâããš
ããã·ãã³ãžã«ãªãã·ã¡ãã«ïŒã·ã©ã³
n20 D 1.5653 (3) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïœïŒâïŒïŒâ
ããšããã·âïŒâãã«ãªãïŒããšãã«ããã
ã«ïœã·ã©ã³ n20 D 1.5638 (4) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïœïŒâïŒïŒâ
ã¢ããªãïŒããšãã«ãããã«ïœã·ã©ã³
n20 D 1.5690 (5) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïŒïŒâãã³
ãžã«ãã³ãžã«ãªãã·ã¡ãã«ïŒã·ã©ã³
n20 D 1.5682 (6) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒãïŒâïœïŒâ
ïŒïŒ®âã¡ãã«âïŒâã¯ããã¢ããªãïŒããšãã«ïœ
ãããã«ãã·ã©ã³ n20 D 1.5706 (7) ãžã¡ãã«ïŒïŒïŒïŒâãžã¯ããããšãã«ïŒïœïŒâ
ïŒïŒâãã«ãªãããšããã·ïŒâïŒâãã«ãªããã³
ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³ n20 D 1.5612 (8) ãžã¡ãã«ïŒïŒâãžãã«ãªãã¡ããã·ããšãã«ïŒ
ãïŒâïœïŒâïŒïŒ®âãã«ãã«âïŒâã¡ãã«ã¢ããª
ãïŒããšãã«ïœãããã«ãã·ã©ã³ n20 D 1.5738 (9) ãžã¡ãã«ïŒïŒïŒïŒâã¡ãã¬ã³ãžãªãã·ããšã
ã«ïŒïŒïŒâã¢ããªãâïŒâãã«ãªããã³ãžã«ãª
ãã·ã¡ãã«ïŒã·ã©ã³ n20 D 1.5790 (10) ãžã¡ãã«ïŒïŒâã¿ãŒã·ã¢ãªããã«ããšãã«ïŒ
ãïŒâïœïŒâïŒïŒâããã¢ãã³ãžã«ïŒããšãã«ïœ
ãããã«ãã·ã©ã³ n20 D 1.5765 (11) ãžã¡ãã«ããšãã«ïŒâïœïŒâïŒïŒâããšããã·ïŒ
ããšãã«ãããã«ïœã·ã©ã³ n20 D 1.5477 (12) ãžã¡ãã«ïŒïŒâã¡ããã·ããšãã«ïŒïœïŒâïŒïŒ®â
ã¡ãã«ã¢ããªãïŒâïŒâãã«ãªããã³ãžã«ãªã
ã·ã¡ãã«ïœã·ã©ã³ n20 D 1.5692 (13) ãžã¡ãã«ïŒïŒâã¯ããâïŒâããªãã«ãªãã¡ã
ã«ããšãã«ïŒïœïŒâïŒïŒ®âãã«ãã«âïŒâãã«ãª
ãã¢ããªãïŒâïŒâãã«ãªããã³ãžã«ãªãã·ã¡
ãã«ïœã·ã©ã³ n20 D 1.5728 (14) ãžã¡ãã«ïŒïŒïŒïŒâãžã¡ãã«ããšãã«ïŒãïŒâ
ïœïŒâïŒïŒâãã«ãªãããšããã·ïŒããšãã«ïœã
ããã«ãã·ã©ã³ n20 D 1.5586 (15) ãžã¡ãã«ïŒïŒâã¯ããâïŒâãšãã«ããšãã«ïŒ
ïœïŒâïŒïŒâããã¢ã¢ããªãïŒãã³ãžã«ãªãã·ã¡
ãã«ïœã·ã©ã³ n20 D 1.5833 (16) ãžã¡ãã«ïŒïŒâã¡ããã·âïŒâã¯ããã¡ãã«ã
ãšãã«ïŒïœïŒâïŒïŒâãã³ãžã«âïŒâãã«ãªãã
ãšãã«ïŒãããã«ïœã·ã©ã³ n20 D 1.5725 (17) ãžã¡ãã«ïŒïŒâã¡ãã«âïŒâãã«ãªãããšã
ã«ïŒïœïŒâïŒïŒâããã¢ããšããã·ïŒâïŒâãã«
ãªããã³ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³
n20 D 1.5780 (18) ãžã¡ãã«ïŒïŒâã€ãœãããã«ããšãã«ïŒïœïŒâ
ïŒïŒ®âã¡ãã«ã¢ããªãïŒãã³ãžã«ãªãã·ã¡ãã«ïœ
ã·ã©ã³ n20 D 1.5686 (19) ãžã¡ãã«ïŒïŒâããã¢âïŒâããã¢ãã«ãªãã¡
ãã«ããšãã«ãïŒâïœïŒâïŒïŒâã¡ãã«ããšãã
ã·ïŒâïŒâãã«ãªãããšãã«ïœãããã«ãã·ã©
ã³ n20 D 1.5794 (20) ãžã¡ãã«ïŒïŒïŒïŒâã¡ãã¬ã³ãžãªãã·ããšã
ã«ïŒïœïŒâïŒïŒâãšãŒããã³ãžã«ãã³ãžã«ãªãã·
ã¡ãã«ïœã·ã©ã³ n20 D 1.5751 (21) ãžã¡ãã«ïŒïŒâã¯ããããšãã«ïŒãïŒâïœïŒâ
ïŒïŒâãã«ãªãã¢ããªãïŒããšãã«ïœãããã«ã
ã·ã©ã³ n20 D 1.5677 (22) ãžã¡ãã«ïŒïŒâãã«ãªãâïŒâãããã«ããšã
ã«ïŒïœïŒâïŒïŒ®âãã«ãã«âïŒâã¯ããã¢ããª
ãïŒãã³ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³
n20 D 1.5740 (23) ãžã¡ãã«ïŒïŒâãžãã«ãªãã¡ããã·ããšãã«ïŒ
ïœïŒâïŒïŒâã¯ããããšããã·ïŒâïŒâãã«ãªã
ãã³ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³ n20 D 1.5659 (24) ãžã¡ãã«ïŒïŒâã¯ããããšãã«ïŒïœïŒâïŒïŒâã
ãšããã·ããšãã«ïŒãããã«ïœã·ã©ã³
n20 D 1.5592 (25) ãžã¡ãã«ïŒïŒâã¯ããããšãã«ïŒïœïŒâïŒïŒâã
ã«ãªãããšããã·ïŒãã³ãžã«ãªãã·ã¡ãã«ïœã·
ã©ã³ n20 D 1.5605 æ¬çºæã®æ®ºè«ã殺ããå€ã§æå¹æåãšããŠçšã
ãååç©ã¯æ°èŠååç©ã§ãããåžžæž©ã§åºäœãŸãã¯
液äœã§ãã€ãŠææ©æº¶å€äžè¬ã«æ溶ã§ãããåŸã€ãŠ
æ£åžçšæ®ºè«ã殺ããå€ãšããŠã¯ãä¹³å€ãæ²¹å€ãç²
å€ãæ°Žåå€ããšã¢ãŸãŒã«å€ãªã©ãšããŠçšããããš
ãã§ããåãæšç²ãã®ä»é©åœãªåºæãšæ··åããŠè
åç·éŠã®åŠãç»èžçšæ®ºè«ã殺ããå€ãšããŠäœ¿çšã
ãããšãã§ãããåããã®æå¹æåãé©åœãªææ©
溶å€ã«æº¶è§£ããŠå°çŽã«æµžãŸããåã¯é©åœãªæº¶å€ã«
溶ãããŠé©åœãªå ç±äœã«ãã€ãŠå ç±èžæ£ãããã
ãããé»æ°èåãšããŠäœ¿çšããå Žåãèåç·éŠãš
åæ§ããããå¹æã瀺ãããªãæ¬çºæã®ååç©ã¯
åŸæ¥ã®ãã¬ã¹ãã€ãã«æ¯ã¹å ã«å®å®ã§ããããã
ã殺è«ã殺ããã¹ãã¯ãã©ã ãåºãããšãäœæ¯æ§
ã§ããããšãéæ¯æ§ãäœãããšãå®äŸ¡ã§ããããš
ããåŸæ¥ã®ææ©ãªã³å€ãææ©å¡©çŽ 系殺è«å€ã«æ¿ã
ã蟲åèžçšæ®ºè«ã殺ããå€ãšããŠäœ¿çšããããšã
ã§ããã æ¬çºæ殺è«ã殺ããå€ã®çšéãšããŠãããšã
èããŽãããªçã®è¡ç害è«ãã¯ãããææ©ãªã³
å€ãã«ãŒãã¡ãŒãå€æµææ§ããã°ããšã³ãã€ããŠ
ã³ã«é¡ãããã«ã¡ã€ããŠãŠãã«ã¡ã ã·é¡ããšããŠ
ã¬ãã³ãã¬ãã¿ãã³ã¬ããã¡ãŸãŠã ã·ãã€ã¬ãã¢
ã³ã·ãããšãŠãã¯ãªã±ã ã·ãããããã¢ãã©ã
ã·ãã«ã€ã¬ã©ã ã·é¡çã®èŸ²æ¥å®³è«ãã³ã¯ãŸãŠçã®
貯ç©å®³è«ãããé¡çã®é²é€ã«æ¥µããŠæçšã§ããã
æŽã«æ¬çºæã®ååç©ã¯åŸæ¥ã®ãã¬ã¹ãã€ãã«æ¯ã¹
ãŠéæ¯æ§ãèãã軜æžããããŸãæ€ç©äœãžã®æµžé
æ§ãå å³ãããŠæ°Žçš²çšæ®ºè«å€ãšããŠã®é©çšãå¯èœ
ãšãªã€ãããŸããæ¬çºæã®æ®ºè«ã殺ããå€ã«ïŒ®â
ãªã¯ãã«ãã·ã¯ããããã³ãžã«ã«ããã·ã€ãã
ïŒåååMGKâ264ïŒãâãªã¯ãã«ãã·ã¯ãã
ããã³ãžã«ã«ããã·ã€ãããšã¢ãªãŒã«ã¹ã«ãã³é ž
å¡©ãšã®æ··åç©ïŒåååMGKâ5026ïŒããµã€ãã
ãªã³500ããªã¯ã¿ã¯ãããžãããã«ãšãŒãã«ãã
ãããã«ããããµã€ããªã©ã®å ±åå€ãå ãããšã
ã®æ®ºè«å¹æãäžå±€é«ããããšãã§ããããŸããæ¬
çºæã®æ®ºè«ã殺ããå€ã«ä»ã®æ®ºè«å€ãäŸãã°ããš
ãããããªã³ãDDVPããã€ã¢ãžãã³ãããã
ãã¹ãããªãããšã³ããªã³ãªã©ã®ææ©ãªã³å€ã
NACãMTMCãBPMCãPHCãªã©ã®ã«ãŒãã¡
ãŒãå€ããã¬ããªã³ãã¢ã¬ã¹ãªã³ããã¿ãŒã«ã¹ãª
ã³ããã©ã¡ããªã³ãããšãããªã³ããã«ã¡ããª
ã³ããµã€ãã«ã¡ããªã³ããã«ã¡ããªã³ãããšã³ã
ã¬ã¬ãŒããããšã³ãããããŒããªã©ã®åŸæ¥ã®ãã¬
ã¹ãã€ã系殺è«å€ãã«ã«ã¿ãããã¯ãã«ããšãã
ãžã³ãã¡ãœãã«ãªã©ã®æ®ºè«å€ãããã¯æ®ºããå€ã
殺èå€ã殺ç·è«å€ãé€èå€ãæ€ç©çé·èª¿æŽå€ãè¥
æãã®ä»ã®èŸ²è¬ãæ··åããããšã«ãã€ãŠå¹æã®ã
ãããå€ç®ççµæç©ãåŸãããåŽåã®çååãè¬
å€éã®çžä¹å¹æãå åæåŸ ããããã®ã§ããã 次ã«æ¬çºæã§æå¹æåãšããŠçšããååç©ã®å
æå®æœäŸã瀺ãã äžè¬åŒïŒïŒã§ç€ºãããéå±ææ©ã±ã€çŽ è³éŠæ
ååç©ã¯ãå³ïŒã«åŸããã¯ããã·ã©ã³ã«Naãã
Liã®ãããªéå±å çŽ ãåå¿ãããŠåŸãããã ãå³ïŒã äžæ¹ãäžè¬åŒïŒïŒã®ååç©ã¯ããã¬ã¹ãã€ã
ãæ§æããã¢ã«ã³ãŒã«æåãçšããŠå³ïŒã«åŸãã
調補ããããšãã§ããã ãå³ïŒã åæå®æœäŸ ïŒ ä¹Ÿç¥ããã©ããããã©ã³50mläžã«çªçŽ æ°æµäžã«
éå±ãªããŠã 0.4ïœãå ããããã©ã€ã¢ã€ã¹âã¢
ã»ãã³ã§â50âãŸã§å·åŽãããã®æžæ¿æ¶²ã«ãžã¡ã
ã«ïŒïŒâã¯ããããšãã«ïŒã¯ããã·ã©ã³4.1ïœã
也ç¥ããã©ããããã©ã³20mlã«æº¶è§£ãã液ã30å
éã§æ»Žäžããããã®æž©åºŠã§ïŒæéåå¿åŸã液枩ã
ïŒâãŸã§åŸã ã«äžããæŽã«ïŒæéããæããŠãªã
ãŠã ã·ã©ã³ãçæããããåå¿æ¶²ãâ20âã«å·åŽ
ããã²ãç¶ãçªçŽ æ°æµäžã«ãïŒâïŒïŒâããšãã
ã·ïŒããšãã«ãããã«ã¯ãã©ã€ã4.9ïœã也ç¥ã
ãã©ããããã©ã³40mlã«æº¶è§£ãã液ãïŒæéã§æ»Ž
äžãããæŽã«å®€æž©ã§ïŒæéããæåŸãå·åŽããªã
ããåå¿æ¶²ã«æ°Žã泚ææ·±ã滎äžããŠéå°ã®ãªããŠ
ã ãå解ããããã³ãŒã³ã§æœåºåŸããã³ãŒã³æº¶æ¶²
ã飜åé£å¡©æ°Žã§æŽæµãããŒãç¡ã«ãŠä¹Ÿç¥ãããæž
å§äžã«ãã³ãŒã³ãçå»ããŠåŸãããæ²¹ç¶ç©ãã·ãª
ã«ã²ã«100ïœã®ã«ã©ã ã¯ãããã°ã©ãã€ã«ãã粟
補ãããžã¡ãã«ïŒïŒâã¯ããããšãã«ïŒïœïŒâïŒïŒ
âããšããã·ããšãã«ïŒãããã«ïœã·ã©ã³6.4ïœ
ãåŸãã åæå®æœäŸ ïŒ ä¹Ÿç¥ãšãŒãã«40mläžã«çªæ°æ°æµäžã«éå±ã«ãªãŠ
ã 0.9ïœãå ãããã®æžæ¿æ¶²ãâ40âã«å·åŽããã
ãžã¡ãã«ïŒïŒâã¡ããã·ããšãã«ïŒã¯ããã·ã©ã³
4.0ïœã也ç¥ãšãŒãã«20mlã«æº¶ããã液ããåèš
æžæ¿æ¶²ã«30åéã§æ»Žäžãããâ40âã§ïŒæéãã
æåŸã液枩ãïŒâãŸã§åŸåŸã«äžããæŽã«ïŒæéã
ãæããŠãã«ãªãŠã ã·ã©ã³ã®çæãå®çµãããã
åå¿æ¶²ãåã³â40âã«å·åŽããçªçŽ æ°æµäžã«ãïŒ
âïŒïŒ®âã¡ãã«ã¢ããªãïŒâïŒâãã«ãªããã³ãžã«
ãªãã·ã¡ãã«ã¯ãã©ã€ã5.6ïœã也ç¥ãšãŒãã«40
mlã«æº¶è§£ãã液ãïŒæéã§æ»Žäžãããâ40âã§ïŒ
æéã宀枩ã§äžå€åå¿åŸæ°Žãå ãããšãŒãã«å±€ã
å液ããã溶åªãçå»åŸåŸãããæ®æž£ãã·ãªã«ã²
ã«100ïœã®ã«ã©ã ã¯ãããã°ã©ãã€ã«ãã粟補ã
ãŠç®çãšãããžã¡ãã«ïŒïŒâã¡ããã·ããšãïŒ
ïœïŒâïŒïŒ®âã¡ãã«ã¢ããªãïŒâïŒâãã«ãªããã³
ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³6.8ïœãåŸãã åæ§ã«ããœãã€ãŠã ããžã¡ãã«ïŒïŒâã¡ããã·
âïŒâã¯ããã¡ãã«ããšãã«ïŒã·ã©ã³ãšïŒâïŒïŒ
âãã³ãžã«âïŒâãã«ãªãããšãã«ïŒãããã«ã
ããã€ãããããžã¡ãã«ïŒïŒâã¡ããã·âïŒâã¯
ããã¡ãã«ããšãã«ïŒïœïŒâïŒïŒâãã³ãžã«âïŒâ
ãã«ãªãããšãã«ïŒãããã«ïœã·ã©ã³ãããªããŠ
ã ãžã¡ãã«ïŒïŒâãã«ãªãâïŒâãããã«ããšã
ã«ïŒã·ã©ã³ãšïŒâïŒïŒ®âãã«ãã«âïŒâã¯ããã¢
ããªãïŒãã³ãžã«ãªãã·ã¡ãã«ã¢ã«ã³ãŒã«ã®ïœâ
ãã«ãšã³ã¹ã«ãã³é žãšã¹ãã«ãšãããžã¡ãã«ïŒïŒ
âãã«ãªãâïŒâãããã«ããšãã«ïŒïœïŒâïŒïŒ®â
ãã«ãã«âïŒâã¯ããã¢ããªãïŒãã³ãžã«ãªãã·
ã¡ãã«ïœã·ã©ã³ãåŸãã 次ã«æ¬çºæã«ãã€ãŠæäŸãããçµæç©ãããã
ããã®ã§ããããšãããæããã«ããããå¹æã®
è©Šéšæ瞟ã瀺ãã è©ŠéšäŸ ïŒ æ£åžã«ãã殺è«è©Šéš æ¬çºæã®ååç©ã®0.2ïŒ çœç¯æº¶æ¶²(A)ã0.2ïŒ ãšãµ
ã€ãããªã³500 0.8ïŒ ã®çœç¯æº¶æ¶²(B)ã0.1ïŒ ãšãã¿
ãŒã«ã¹ãªã³0.1ïŒ ã®çœç¯æº¶æ¶²(C)ãåã³ãã¿ãŒã«ã¹
ãªã³ãååç©(A)ã®åã 0.2ïŒ ã®çœç¯æº¶æ¶²ã«ã€ãã€
ãšããšã®èœäžä»°è»¢çãæ±ãäŸè©Šè¬å€ã®çžå¯Ÿæå¹åºŠ
ãç®åºããæŽã«24æéåŸã®èŽæ»çãæ±ãããšãã
次ã®åŠãã§ããã
ããã²ã³ååãççŽ æ°ãïŒãïŒã®ã¢ã«ãã«åºãã
ãã¡ãã«åºãã¡ããã·åºããšããã·åºããžãã«ãª
ãã¡ããã·åºãããã¯R1ãšR2ã§ã¡ãã¬ã³ãžãªã
ã·åºãè¡šããã ã¯é žçŽ ååãŸãã¯ã¡ãã¬ã³åºã§ãããã¯é ž
çŽ ååãã¡ãã¬ã³åºãã¢ããåºãã¡ãã«ã¢ããåº
ãããã¯ãã«ãã«ã¢ããåºãè¡šãããR3ã¯æ°ŽçŽ
åååã¯ããçŽ ååããR4ã¯æ°ŽçŽ ååãããã²
ã³åååã¯ã¡ãã«åºãè¡šãããïŒ ã§è¡šããããææ©ã±ã€çŽ ç³»è³éŠæã¢ã«ã«ã³èªå°äœ
ãæå¹æåãšããŠå«æããããšãç¹åŸŽãšãã殺
è«ã殺ããå€åã³ãã®è£œæ³ã«é¢ããã è¿å¹Žã倩ç¶ã®æ®ºè«æåã§ãããã¬ããªã³ã®ååŠ
æ§é ãæ¹å€ããé¡çžäœã®ç 究ãåºãé²ããããäž
è¬åŒïŒïŒ ïŒããã«ãR1ãR2ãR3ãR4ã¯åè¿°ãšåãæå³ã
è¡šãããïŒã§è¡šããããååç©çŸ€ã®ä»ããšã¹ãã«
éšåãä»ã®åºã«çœ®ãæããäŸãã°ïŒïŒ ã§ç€ºãããååç©ã«é«ã殺è«æŽ»æ§ãèŠãåºããã
ïŒç¹éæ58â201737å·å ¬å ±ïŒã ãããã®ååç©ã¯ãåŸæ¥ã®ææ©ãªã³å€ãã«ãŒã
ã¡ãŒãå€ã«æ¿ãã蟲è¬ãšããŠåºãéçºãé²ããã
ãŠããããå°æ¥å°æ¥ããã§ããããã¬ã¹ãã€ã
æµææ§åé¡ã«åå察åŠã§ããªããæ€ç©äœå ãžã®
浞éæ§ã«ä¹ãããç¹ã«ïŒïŒã®ã¿ã€ãã®ååç©
ã«ã€ããŠã¯éæ¯æ§ãé«ãçããã¬ã¹ãã€ãã«çœ®ã
ããåºæã®åé¡ç¹ã¯ãªãååæ¹åãããŠããªãã æ¬çºæè ãã¯æŽã«æçšãªæ®ºè«ã殺ããæåãæ¢
玢ãã¹ãéæç 究ãç¶ããçµæãççŽ å çŽ ã®ä»£æ¿
å çŽ ã§ããã±ã€çŽ å çŽ ãå°å ¥ããããšã«ãã€ãŠäž
èšããã®æ¬ ç¹ãèããæ¹åãããäžæ¹ãã
ãšã®ååç©ã«èŒã¹æ®ºè«å¹åãå¢åŒ·ããæž©è¡åç©ã«
察ããæ¯æ§ãæŽã«è»œæžãããããšãç¥ããæ¬çºæ
ãå®æãããã±ã€çŽ å çŽ ã®å°å ¥ãå¹æçãªçç±ã«
ã€ããŠã¯ãªãäžæãªç¹ãå€ãããã±ã€çŽ ååã®å€
æ®»ã«ååšãã空ã®3dè»éã«èµ·å ãããã®ãšæšå®
ãããã æ¬çºæã§æå¹æåãšããŠçšããäžèšåŒïŒïŒã§
è¡šããããååç©ã¯äžè¬åŒïŒïŒ ïŒåŒäžãR1ãR2ã¯åäžåã¯çžç°ãªããæ°ŽçŽ ååã
ããã²ã³ååãççŽ æ°ãïŒãïŒã®ã¢ã«ãã«åºãã
ãã¡ãã«åºãã¡ããã·åºããšããã·åºããžãã«ãª
ãã¡ããã·åºãããã¯R1ãšR2ã§ã¡ãã¬ã³ãžãªã
ã·åºãè¡šãããåãïŒã¯éå±ååïŒNaããLi
çïŒãè¡šãããïŒã§ç€ºãããææ©ã±ã€çŽ è³éŠæå
åç©ãšäžè¬åŒ ïŒåŒäžãã¯é žçŽ ååãŸãã¯ã¡ãã¬ã³ååã§ã
ããã¯é žçŽ ååãã¡ãã¬ã³åºãã¢ããåºãã¡ã
ã«ã¢ããåºãããã¯ãã«ãã«ã¢ããåºãè¡šããã
R3ã¯æ°ŽçŽ åååã¯ããçŽ ååããR4ã¯ãæ°ŽçŽ å
åãããã²ã³åååã¯ã¡ãã«åºãè¡šããããŸã
ã¯ããã²ã³ååãããã¯æ°Žé žåºã®åå¿æ§èªå°äœã
è¡šãããïŒã§è¡šããããååç©ãåå¿ãããŠèª¿è£œ
ããããåå¿ã¯é©åœãªæº¶åªäžã§ãå¿ èŠã«ãã觊åª
ã®ååšäžã«å¿ èŠã«ããå ç±äžã«è¡ãªããããäžèš
åŒïŒïŒã§ç€ºãããååç©ã®ä»£è¡šäŸã瀺ãã°æ¬¡ã®
éãã§ããããæ¬çºæã¯ãã¡ãããããã®ã¿ã«é
å®ããããã®ã§ã¯ãªãã (1) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïœïŒâïŒïŒâ
ããšããã·ïŒããšãã«ãããã«ïœã·ã©ã³
n20 D 1.5641 (2) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïŒïŒâããš
ããã·ãã³ãžã«ãªãã·ã¡ãã«ïŒã·ã©ã³
n20 D 1.5653 (3) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïœïŒâïŒïŒâ
ããšããã·âïŒâãã«ãªãïŒããšãã«ããã
ã«ïœã·ã©ã³ n20 D 1.5638 (4) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïœïŒâïŒïŒâ
ã¢ããªãïŒããšãã«ãããã«ïœã·ã©ã³
n20 D 1.5690 (5) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒïŒïŒâãã³
ãžã«ãã³ãžã«ãªãã·ã¡ãã«ïŒã·ã©ã³
n20 D 1.5682 (6) ãžã¡ãã«ïŒïŒâãšããã·ããšãã«ïŒãïŒâïœïŒâ
ïŒïŒ®âã¡ãã«âïŒâã¯ããã¢ããªãïŒããšãã«ïœ
ãããã«ãã·ã©ã³ n20 D 1.5706 (7) ãžã¡ãã«ïŒïŒïŒïŒâãžã¯ããããšãã«ïŒïœïŒâ
ïŒïŒâãã«ãªãããšããã·ïŒâïŒâãã«ãªããã³
ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³ n20 D 1.5612 (8) ãžã¡ãã«ïŒïŒâãžãã«ãªãã¡ããã·ããšãã«ïŒ
ãïŒâïœïŒâïŒïŒ®âãã«ãã«âïŒâã¡ãã«ã¢ããª
ãïŒããšãã«ïœãããã«ãã·ã©ã³ n20 D 1.5738 (9) ãžã¡ãã«ïŒïŒïŒïŒâã¡ãã¬ã³ãžãªãã·ããšã
ã«ïŒïŒïŒâã¢ããªãâïŒâãã«ãªããã³ãžã«ãª
ãã·ã¡ãã«ïŒã·ã©ã³ n20 D 1.5790 (10) ãžã¡ãã«ïŒïŒâã¿ãŒã·ã¢ãªããã«ããšãã«ïŒ
ãïŒâïœïŒâïŒïŒâããã¢ãã³ãžã«ïŒããšãã«ïœ
ãããã«ãã·ã©ã³ n20 D 1.5765 (11) ãžã¡ãã«ããšãã«ïŒâïœïŒâïŒïŒâããšããã·ïŒ
ããšãã«ãããã«ïœã·ã©ã³ n20 D 1.5477 (12) ãžã¡ãã«ïŒïŒâã¡ããã·ããšãã«ïŒïœïŒâïŒïŒ®â
ã¡ãã«ã¢ããªãïŒâïŒâãã«ãªããã³ãžã«ãªã
ã·ã¡ãã«ïœã·ã©ã³ n20 D 1.5692 (13) ãžã¡ãã«ïŒïŒâã¯ããâïŒâããªãã«ãªãã¡ã
ã«ããšãã«ïŒïœïŒâïŒïŒ®âãã«ãã«âïŒâãã«ãª
ãã¢ããªãïŒâïŒâãã«ãªããã³ãžã«ãªãã·ã¡
ãã«ïœã·ã©ã³ n20 D 1.5728 (14) ãžã¡ãã«ïŒïŒïŒïŒâãžã¡ãã«ããšãã«ïŒãïŒâ
ïœïŒâïŒïŒâãã«ãªãããšããã·ïŒããšãã«ïœã
ããã«ãã·ã©ã³ n20 D 1.5586 (15) ãžã¡ãã«ïŒïŒâã¯ããâïŒâãšãã«ããšãã«ïŒ
ïœïŒâïŒïŒâããã¢ã¢ããªãïŒãã³ãžã«ãªãã·ã¡
ãã«ïœã·ã©ã³ n20 D 1.5833 (16) ãžã¡ãã«ïŒïŒâã¡ããã·âïŒâã¯ããã¡ãã«ã
ãšãã«ïŒïœïŒâïŒïŒâãã³ãžã«âïŒâãã«ãªãã
ãšãã«ïŒãããã«ïœã·ã©ã³ n20 D 1.5725 (17) ãžã¡ãã«ïŒïŒâã¡ãã«âïŒâãã«ãªãããšã
ã«ïŒïœïŒâïŒïŒâããã¢ããšããã·ïŒâïŒâãã«
ãªããã³ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³
n20 D 1.5780 (18) ãžã¡ãã«ïŒïŒâã€ãœãããã«ããšãã«ïŒïœïŒâ
ïŒïŒ®âã¡ãã«ã¢ããªãïŒãã³ãžã«ãªãã·ã¡ãã«ïœ
ã·ã©ã³ n20 D 1.5686 (19) ãžã¡ãã«ïŒïŒâããã¢âïŒâããã¢ãã«ãªãã¡
ãã«ããšãã«ãïŒâïœïŒâïŒïŒâã¡ãã«ããšãã
ã·ïŒâïŒâãã«ãªãããšãã«ïœãããã«ãã·ã©
ã³ n20 D 1.5794 (20) ãžã¡ãã«ïŒïŒïŒïŒâã¡ãã¬ã³ãžãªãã·ããšã
ã«ïŒïœïŒâïŒïŒâãšãŒããã³ãžã«ãã³ãžã«ãªãã·
ã¡ãã«ïœã·ã©ã³ n20 D 1.5751 (21) ãžã¡ãã«ïŒïŒâã¯ããããšãã«ïŒãïŒâïœïŒâ
ïŒïŒâãã«ãªãã¢ããªãïŒããšãã«ïœãããã«ã
ã·ã©ã³ n20 D 1.5677 (22) ãžã¡ãã«ïŒïŒâãã«ãªãâïŒâãããã«ããšã
ã«ïŒïœïŒâïŒïŒ®âãã«ãã«âïŒâã¯ããã¢ããª
ãïŒãã³ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³
n20 D 1.5740 (23) ãžã¡ãã«ïŒïŒâãžãã«ãªãã¡ããã·ããšãã«ïŒ
ïœïŒâïŒïŒâã¯ããããšããã·ïŒâïŒâãã«ãªã
ãã³ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³ n20 D 1.5659 (24) ãžã¡ãã«ïŒïŒâã¯ããããšãã«ïŒïœïŒâïŒïŒâã
ãšããã·ããšãã«ïŒãããã«ïœã·ã©ã³
n20 D 1.5592 (25) ãžã¡ãã«ïŒïŒâã¯ããããšãã«ïŒïœïŒâïŒïŒâã
ã«ãªãããšããã·ïŒãã³ãžã«ãªãã·ã¡ãã«ïœã·
ã©ã³ n20 D 1.5605 æ¬çºæã®æ®ºè«ã殺ããå€ã§æå¹æåãšããŠçšã
ãååç©ã¯æ°èŠååç©ã§ãããåžžæž©ã§åºäœãŸãã¯
液äœã§ãã€ãŠææ©æº¶å€äžè¬ã«æ溶ã§ãããåŸã€ãŠ
æ£åžçšæ®ºè«ã殺ããå€ãšããŠã¯ãä¹³å€ãæ²¹å€ãç²
å€ãæ°Žåå€ããšã¢ãŸãŒã«å€ãªã©ãšããŠçšããããš
ãã§ããåãæšç²ãã®ä»é©åœãªåºæãšæ··åããŠè
åç·éŠã®åŠãç»èžçšæ®ºè«ã殺ããå€ãšããŠäœ¿çšã
ãããšãã§ãããåããã®æå¹æåãé©åœãªææ©
溶å€ã«æº¶è§£ããŠå°çŽã«æµžãŸããåã¯é©åœãªæº¶å€ã«
溶ãããŠé©åœãªå ç±äœã«ãã€ãŠå ç±èžæ£ãããã
ãããé»æ°èåãšããŠäœ¿çšããå Žåãèåç·éŠãš
åæ§ããããå¹æã瀺ãããªãæ¬çºæã®ååç©ã¯
åŸæ¥ã®ãã¬ã¹ãã€ãã«æ¯ã¹å ã«å®å®ã§ããããã
ã殺è«ã殺ããã¹ãã¯ãã©ã ãåºãããšãäœæ¯æ§
ã§ããããšãéæ¯æ§ãäœãããšãå®äŸ¡ã§ããããš
ããåŸæ¥ã®ææ©ãªã³å€ãææ©å¡©çŽ 系殺è«å€ã«æ¿ã
ã蟲åèžçšæ®ºè«ã殺ããå€ãšããŠäœ¿çšããããšã
ã§ããã æ¬çºæ殺è«ã殺ããå€ã®çšéãšããŠãããšã
èããŽãããªçã®è¡ç害è«ãã¯ãããææ©ãªã³
å€ãã«ãŒãã¡ãŒãå€æµææ§ããã°ããšã³ãã€ããŠ
ã³ã«é¡ãããã«ã¡ã€ããŠãŠãã«ã¡ã ã·é¡ããšããŠ
ã¬ãã³ãã¬ãã¿ãã³ã¬ããã¡ãŸãŠã ã·ãã€ã¬ãã¢
ã³ã·ãããšãŠãã¯ãªã±ã ã·ãããããã¢ãã©ã
ã·ãã«ã€ã¬ã©ã ã·é¡çã®èŸ²æ¥å®³è«ãã³ã¯ãŸãŠçã®
貯ç©å®³è«ãããé¡çã®é²é€ã«æ¥µããŠæçšã§ããã
æŽã«æ¬çºæã®ååç©ã¯åŸæ¥ã®ãã¬ã¹ãã€ãã«æ¯ã¹
ãŠéæ¯æ§ãèãã軜æžããããŸãæ€ç©äœãžã®æµžé
æ§ãå å³ãããŠæ°Žçš²çšæ®ºè«å€ãšããŠã®é©çšãå¯èœ
ãšãªã€ãããŸããæ¬çºæã®æ®ºè«ã殺ããå€ã«ïŒ®â
ãªã¯ãã«ãã·ã¯ããããã³ãžã«ã«ããã·ã€ãã
ïŒåååMGKâ264ïŒãâãªã¯ãã«ãã·ã¯ãã
ããã³ãžã«ã«ããã·ã€ãããšã¢ãªãŒã«ã¹ã«ãã³é ž
å¡©ãšã®æ··åç©ïŒåååMGKâ5026ïŒããµã€ãã
ãªã³500ããªã¯ã¿ã¯ãããžãããã«ãšãŒãã«ãã
ãããã«ããããµã€ããªã©ã®å ±åå€ãå ãããšã
ã®æ®ºè«å¹æãäžå±€é«ããããšãã§ããããŸããæ¬
çºæã®æ®ºè«ã殺ããå€ã«ä»ã®æ®ºè«å€ãäŸãã°ããš
ãããããªã³ãDDVPããã€ã¢ãžãã³ãããã
ãã¹ãããªãããšã³ããªã³ãªã©ã®ææ©ãªã³å€ã
NACãMTMCãBPMCãPHCãªã©ã®ã«ãŒãã¡
ãŒãå€ããã¬ããªã³ãã¢ã¬ã¹ãªã³ããã¿ãŒã«ã¹ãª
ã³ããã©ã¡ããªã³ãããšãããªã³ããã«ã¡ããª
ã³ããµã€ãã«ã¡ããªã³ããã«ã¡ããªã³ãããšã³ã
ã¬ã¬ãŒããããšã³ãããããŒããªã©ã®åŸæ¥ã®ãã¬
ã¹ãã€ã系殺è«å€ãã«ã«ã¿ãããã¯ãã«ããšãã
ãžã³ãã¡ãœãã«ãªã©ã®æ®ºè«å€ãããã¯æ®ºããå€ã
殺èå€ã殺ç·è«å€ãé€èå€ãæ€ç©çé·èª¿æŽå€ãè¥
æãã®ä»ã®èŸ²è¬ãæ··åããããšã«ãã€ãŠå¹æã®ã
ãããå€ç®ççµæç©ãåŸãããåŽåã®çååãè¬
å€éã®çžä¹å¹æãå åæåŸ ããããã®ã§ããã 次ã«æ¬çºæã§æå¹æåãšããŠçšããååç©ã®å
æå®æœäŸã瀺ãã äžè¬åŒïŒïŒã§ç€ºãããéå±ææ©ã±ã€çŽ è³éŠæ
ååç©ã¯ãå³ïŒã«åŸããã¯ããã·ã©ã³ã«Naãã
Liã®ãããªéå±å çŽ ãåå¿ãããŠåŸãããã ãå³ïŒã äžæ¹ãäžè¬åŒïŒïŒã®ååç©ã¯ããã¬ã¹ãã€ã
ãæ§æããã¢ã«ã³ãŒã«æåãçšããŠå³ïŒã«åŸãã
調補ããããšãã§ããã ãå³ïŒã åæå®æœäŸ ïŒ ä¹Ÿç¥ããã©ããããã©ã³50mläžã«çªçŽ æ°æµäžã«
éå±ãªããŠã 0.4ïœãå ããããã©ã€ã¢ã€ã¹âã¢
ã»ãã³ã§â50âãŸã§å·åŽãããã®æžæ¿æ¶²ã«ãžã¡ã
ã«ïŒïŒâã¯ããããšãã«ïŒã¯ããã·ã©ã³4.1ïœã
也ç¥ããã©ããããã©ã³20mlã«æº¶è§£ãã液ã30å
éã§æ»Žäžããããã®æž©åºŠã§ïŒæéåå¿åŸã液枩ã
ïŒâãŸã§åŸã ã«äžããæŽã«ïŒæéããæããŠãªã
ãŠã ã·ã©ã³ãçæããããåå¿æ¶²ãâ20âã«å·åŽ
ããã²ãç¶ãçªçŽ æ°æµäžã«ãïŒâïŒïŒâããšãã
ã·ïŒããšãã«ãããã«ã¯ãã©ã€ã4.9ïœã也ç¥ã
ãã©ããããã©ã³40mlã«æº¶è§£ãã液ãïŒæéã§æ»Ž
äžãããæŽã«å®€æž©ã§ïŒæéããæåŸãå·åŽããªã
ããåå¿æ¶²ã«æ°Žã泚ææ·±ã滎äžããŠéå°ã®ãªããŠ
ã ãå解ããããã³ãŒã³ã§æœåºåŸããã³ãŒã³æº¶æ¶²
ã飜åé£å¡©æ°Žã§æŽæµãããŒãç¡ã«ãŠä¹Ÿç¥ãããæž
å§äžã«ãã³ãŒã³ãçå»ããŠåŸãããæ²¹ç¶ç©ãã·ãª
ã«ã²ã«100ïœã®ã«ã©ã ã¯ãããã°ã©ãã€ã«ãã粟
補ãããžã¡ãã«ïŒïŒâã¯ããããšãã«ïŒïœïŒâïŒïŒ
âããšããã·ããšãã«ïŒãããã«ïœã·ã©ã³6.4ïœ
ãåŸãã åæå®æœäŸ ïŒ ä¹Ÿç¥ãšãŒãã«40mläžã«çªæ°æ°æµäžã«éå±ã«ãªãŠ
ã 0.9ïœãå ãããã®æžæ¿æ¶²ãâ40âã«å·åŽããã
ãžã¡ãã«ïŒïŒâã¡ããã·ããšãã«ïŒã¯ããã·ã©ã³
4.0ïœã也ç¥ãšãŒãã«20mlã«æº¶ããã液ããåèš
æžæ¿æ¶²ã«30åéã§æ»Žäžãããâ40âã§ïŒæéãã
æåŸã液枩ãïŒâãŸã§åŸåŸã«äžããæŽã«ïŒæéã
ãæããŠãã«ãªãŠã ã·ã©ã³ã®çæãå®çµãããã
åå¿æ¶²ãåã³â40âã«å·åŽããçªçŽ æ°æµäžã«ãïŒ
âïŒïŒ®âã¡ãã«ã¢ããªãïŒâïŒâãã«ãªããã³ãžã«
ãªãã·ã¡ãã«ã¯ãã©ã€ã5.6ïœã也ç¥ãšãŒãã«40
mlã«æº¶è§£ãã液ãïŒæéã§æ»Žäžãããâ40âã§ïŒ
æéã宀枩ã§äžå€åå¿åŸæ°Žãå ãããšãŒãã«å±€ã
å液ããã溶åªãçå»åŸåŸãããæ®æž£ãã·ãªã«ã²
ã«100ïœã®ã«ã©ã ã¯ãããã°ã©ãã€ã«ãã粟補ã
ãŠç®çãšãããžã¡ãã«ïŒïŒâã¡ããã·ããšãïŒ
ïœïŒâïŒïŒ®âã¡ãã«ã¢ããªãïŒâïŒâãã«ãªããã³
ãžã«ãªãã·ã¡ãã«ïœã·ã©ã³6.8ïœãåŸãã åæ§ã«ããœãã€ãŠã ããžã¡ãã«ïŒïŒâã¡ããã·
âïŒâã¯ããã¡ãã«ããšãã«ïŒã·ã©ã³ãšïŒâïŒïŒ
âãã³ãžã«âïŒâãã«ãªãããšãã«ïŒãããã«ã
ããã€ãããããžã¡ãã«ïŒïŒâã¡ããã·âïŒâã¯
ããã¡ãã«ããšãã«ïŒïœïŒâïŒïŒâãã³ãžã«âïŒâ
ãã«ãªãããšãã«ïŒãããã«ïœã·ã©ã³ãããªããŠ
ã ãžã¡ãã«ïŒïŒâãã«ãªãâïŒâãããã«ããšã
ã«ïŒã·ã©ã³ãšïŒâïŒïŒ®âãã«ãã«âïŒâã¯ããã¢
ããªãïŒãã³ãžã«ãªãã·ã¡ãã«ã¢ã«ã³ãŒã«ã®ïœâ
ãã«ãšã³ã¹ã«ãã³é žãšã¹ãã«ãšãããžã¡ãã«ïŒïŒ
âãã«ãªãâïŒâãããã«ããšãã«ïŒïœïŒâïŒïŒ®â
ãã«ãã«âïŒâã¯ããã¢ããªãïŒãã³ãžã«ãªãã·
ã¡ãã«ïœã·ã©ã³ãåŸãã 次ã«æ¬çºæã«ãã€ãŠæäŸãããçµæç©ãããã
ããã®ã§ããããšãããæããã«ããããå¹æã®
è©Šéšæ瞟ã瀺ãã è©ŠéšäŸ ïŒ æ£åžã«ãã殺è«è©Šéš æ¬çºæã®ååç©ã®0.2ïŒ çœç¯æº¶æ¶²(A)ã0.2ïŒ ãšãµ
ã€ãããªã³500 0.8ïŒ ã®çœç¯æº¶æ¶²(B)ã0.1ïŒ ãšãã¿
ãŒã«ã¹ãªã³0.1ïŒ ã®çœç¯æº¶æ¶²(C)ãåã³ãã¿ãŒã«ã¹
ãªã³ãååç©(A)ã®åã 0.2ïŒ ã®çœç¯æº¶æ¶²ã«ã€ãã€
ãšããšã®èœäžä»°è»¢çãæ±ãäŸè©Šè¬å€ã®çžå¯Ÿæå¹åºŠ
ãç®åºããæŽã«24æéåŸã®èŽæ»çãæ±ãããšãã
次ã®åŠãã§ããã
ãè¡šã
è©ŠéšäŸ ïŒ
ç»èžã«ãã殺è«è©Šéš
殺è«æåãšããŠ0.5ïŒ
ãå«æããèåç·éŠãäœ
ããã¢ã«ã€ãšã«ã®æè«ãèœäžä»°è»¢ããããå¹æã
è©Šéšããããã®å®éšã¯é²è«ç§åŠ16å·»ïŒ1951幎ïŒç¬¬
176é ãé·æ²¢ãåç°çã®æ¹æ³ã«åŸããåèšç·éŠã®
çžå¯Ÿæå¹åºŠãç®åºãããšãã次ã®åŠãã§ãããäŸ
è©Šè¬å€çªå·ã¯åèšæå¹æåäŸã®ãã®ãšåäžã§ã
ãã
ããã¢ã«ã€ãšã«ã®æè«ãèœäžä»°è»¢ããããå¹æã
è©Šéšããããã®å®éšã¯é²è«ç§åŠ16å·»ïŒ1951幎ïŒç¬¬
176é ãé·æ²¢ãåç°çã®æ¹æ³ã«åŸããåèšç·éŠã®
çžå¯Ÿæå¹åºŠãç®åºãããšãã次ã®åŠãã§ãããäŸ
è©Šè¬å€çªå·ã¯åèšæå¹æåäŸã®ãã®ãšåäžã§ã
ãã
ãè¡šã
è©ŠéšäŸ ïŒ
埮é滎äžæ³ã«ãã殺è«è©Šéš
察ç
§ååç©(A)ãåã³æ¬çºæååç©ã®åã
ãšãã
ããã«ããããã«ããããµã€ããããããæå¹æ
åã®ïŒåéæ·»å ãæå®æ¿åºŠã®ã¢ã»ãã³æº¶æ¶²ãšãã
ãã®ããã€ã¯ãã·ãªã³ãžã«ãŠã€ãšããšæè«ã®èžéš
èæ¿ã«æœçšãã24æéåŸã®æ»è«çããå¯Ÿç §ååç©
ã«å¯Ÿããçžå¯Ÿæ®ºè«ååã³ããããã«ããããµã€ã
ã«ããå ±åå¹æã調ã¹ããšãã次ã®åŠãã§ããã
ããã«ããããã«ããããµã€ããããããæå¹æ
åã®ïŒåéæ·»å ãæå®æ¿åºŠã®ã¢ã»ãã³æº¶æ¶²ãšãã
ãã®ããã€ã¯ãã·ãªã³ãžã«ãŠã€ãšããšæè«ã®èžéš
èæ¿ã«æœçšãã24æéåŸã®æ»è«çããå¯Ÿç §ååç©
ã«å¯Ÿããçžå¯Ÿæ®ºè«ååã³ããããã«ããããµã€ã
ã«ããå ±åå¹æã調ã¹ããšãã次ã®åŠãã§ããã
ãè¡šã
次ã«è£œå€åã®å®æœäŸã瀺ããã補å€åã«ããã€
ãŠã¯äžè¬èŸ²è¬ã«æºããŠäœãã®ç¹å¥ãªæ¡ä»¶ãå¿ èŠãš
ãããåœæ¥æè¡è ã®çç¥ããæ¹æ³ã«ãã€ãŠèª¿è£œã
ããã åèäŸ ïŒ æ¬çºæååç©(1)0.2éšã«çœç¯æ²¹ãå ããŠå šäœã
100éšãšããŠ0.2ïŒ æ²¹å€ãåŸãã åèäŸ ïŒ æ¬çºæååç©(4)0.2éšãšããããã«ããããµã€
ã0.8éšã«çœç¯æ²¹ãå ããŠå šäœã100éšãšããŠæ²¹å€
ãåŸãã åèäŸ ïŒ æ¬çºæååç©(7)20éšã«ãœã«ããŒã«SMâ200ïŒæ±
éŠååŠç»é²åæšåïŒ10éšããã·ããŒã«70éšãå ã
ãŠããææ··å溶解ããŠ20ïŒ ä¹³å€ãåŸãã åèäŸ ïŒ æ¬çºæååç©(9)0.4éšãã¬ã¹ã¡ããªã³0.1éšããª
ã¯ã¿ã¯ãããžãããã«ãšãŒãã«1.5éšã粟補ç¯æ²¹
28éšã«æº¶è§£ãããšã¢ãŸãŒã«å®¹åšã«å å¡«ãããã«ã
éšåãåãä»ããåŸã該ãã«ãéšåãéããŠåŽå°
å€ïŒæ¶²åç³æ²¹ã¬ã¹ïŒ70éšãå å§å å¡«ããŠãšã¢ãŸãŒ
ã«ãåŸãã åèäŸ ïŒ æ¬çºæååç©ïŒ14ïŒ0.5ïœãBHT0.5ïœãé€è«è
æœåºç²ç²ãæšç²ããã³ç²ãªã©ã®èåç·éŠçšåºæ
99.0ïœã«åäžã«æ··åããå ¬ç¥ã®æ¹æ³ã«ãã€ãŠèå
ç·éŠãåŸãã åèäŸ ïŒ æ¬çºæååç©ïŒ17ïŒ0.4ïœãMGKâ5026 1.0ïœ
ãèåç·éŠçšåºæ98.6ïœã«åäžã«æ··åããå ¬ç¥ã®
æ¹æ³ã«ãã€ãŠèåç·éŠãåŸãã åèäŸ ïŒ æ¬çºæååç©ïŒ21ïŒ0.3éšãšã¯ã¬ãŒ99.7éšãç²
ç æ··åããŠ0.3ïŒ ç²å€ãåŸãã åèäŸ ïŒ æ¬çºæååç©ïŒ24ïŒ40éšãç¡ è»å35éšãã¯ã¬ãŒ
20éšãã©ãŠãªã«ã¹ã«ãã³é žå¡©ïŒéšãã«ã«ããã·ã¡
ãã«ã»ã«ããŒãºïŒéšãç²ç æ··åããŠæ°Žåå€ãåŸ
ãã è©ŠéšäŸ ïŒ ã¢ã¢ã¢ã«ã¢ãã©ã ã·ã®å€æ°çºçããäžé¢ã®ïŒã
ïŒèæã®å€§æ ¹çã«åèäŸïŒã«ãã€ãŠåŸãããä¹³å€
ã®ãã¡æ¬çºæååç©(3)ã(7)ã(10)ãïŒ13ïŒãïŒ18ïŒã
ïŒ22ïŒããã³ïŒ25ïŒãå«ãåã ã®ä¹³å€ã®æ°Žã«ãã
1000ååžé液ã100ïŒåãããæ£åžãããïŒæ¥
åŸã®å¯çç調æ»ã§æ£åžåå¯åºŠã®1/10以äžã«ååºå ±
ã«æžå°ããŠããã è©ŠéšäŸ ïŒ åèäŸïŒã§åŸãããä¹³å€ã®ãã¡æ¬çºæååç©
(2)ã(4)ã(7)ã(11)ãïŒ15ïŒãïŒ17ïŒããã³ïŒ23ïŒã®
2000ååžé液ã«ããããçèãè¬æ¶²äžã«çŽïŒç§é
浞挬ããè¬æ¶²ä¹Ÿç¥åŸã·ã€ãŒã¬ã«å ¥ãããšããŠã ã·
ã®å¥å šå¹Œè«10é ãæŸé£Œããããã®äŸè©Šè«ã®æŸé£Œã¯
çè浞挬åœæ¥ãïŒæ¥åŸã®ïŒåè¡ãªã24æéåŸã®æ»
è«çãæ±ããã
ãŠã¯äžè¬èŸ²è¬ã«æºããŠäœãã®ç¹å¥ãªæ¡ä»¶ãå¿ èŠãš
ãããåœæ¥æè¡è ã®çç¥ããæ¹æ³ã«ãã€ãŠèª¿è£œã
ããã åèäŸ ïŒ æ¬çºæååç©(1)0.2éšã«çœç¯æ²¹ãå ããŠå šäœã
100éšãšããŠ0.2ïŒ æ²¹å€ãåŸãã åèäŸ ïŒ æ¬çºæååç©(4)0.2éšãšããããã«ããããµã€
ã0.8éšã«çœç¯æ²¹ãå ããŠå šäœã100éšãšããŠæ²¹å€
ãåŸãã åèäŸ ïŒ æ¬çºæååç©(7)20éšã«ãœã«ããŒã«SMâ200ïŒæ±
éŠååŠç»é²åæšåïŒ10éšããã·ããŒã«70éšãå ã
ãŠããææ··å溶解ããŠ20ïŒ ä¹³å€ãåŸãã åèäŸ ïŒ æ¬çºæååç©(9)0.4éšãã¬ã¹ã¡ããªã³0.1éšããª
ã¯ã¿ã¯ãããžãããã«ãšãŒãã«1.5éšã粟補ç¯æ²¹
28éšã«æº¶è§£ãããšã¢ãŸãŒã«å®¹åšã«å å¡«ãããã«ã
éšåãåãä»ããåŸã該ãã«ãéšåãéããŠåŽå°
å€ïŒæ¶²åç³æ²¹ã¬ã¹ïŒ70éšãå å§å å¡«ããŠãšã¢ãŸãŒ
ã«ãåŸãã åèäŸ ïŒ æ¬çºæååç©ïŒ14ïŒ0.5ïœãBHT0.5ïœãé€è«è
æœåºç²ç²ãæšç²ããã³ç²ãªã©ã®èåç·éŠçšåºæ
99.0ïœã«åäžã«æ··åããå ¬ç¥ã®æ¹æ³ã«ãã€ãŠèå
ç·éŠãåŸãã åèäŸ ïŒ æ¬çºæååç©ïŒ17ïŒ0.4ïœãMGKâ5026 1.0ïœ
ãèåç·éŠçšåºæ98.6ïœã«åäžã«æ··åããå ¬ç¥ã®
æ¹æ³ã«ãã€ãŠèåç·éŠãåŸãã åèäŸ ïŒ æ¬çºæååç©ïŒ21ïŒ0.3éšãšã¯ã¬ãŒ99.7éšãç²
ç æ··åããŠ0.3ïŒ ç²å€ãåŸãã åèäŸ ïŒ æ¬çºæååç©ïŒ24ïŒ40éšãç¡ è»å35éšãã¯ã¬ãŒ
20éšãã©ãŠãªã«ã¹ã«ãã³é žå¡©ïŒéšãã«ã«ããã·ã¡
ãã«ã»ã«ããŒãºïŒéšãç²ç æ··åããŠæ°Žåå€ãåŸ
ãã è©ŠéšäŸ ïŒ ã¢ã¢ã¢ã«ã¢ãã©ã ã·ã®å€æ°çºçããäžé¢ã®ïŒã
ïŒèæã®å€§æ ¹çã«åèäŸïŒã«ãã€ãŠåŸãããä¹³å€
ã®ãã¡æ¬çºæååç©(3)ã(7)ã(10)ãïŒ13ïŒãïŒ18ïŒã
ïŒ22ïŒããã³ïŒ25ïŒãå«ãåã ã®ä¹³å€ã®æ°Žã«ãã
1000ååžé液ã100ïŒåãããæ£åžãããïŒæ¥
åŸã®å¯çç調æ»ã§æ£åžåå¯åºŠã®1/10以äžã«ååºå ±
ã«æžå°ããŠããã è©ŠéšäŸ ïŒ åèäŸïŒã§åŸãããä¹³å€ã®ãã¡æ¬çºæååç©
(2)ã(4)ã(7)ã(11)ãïŒ15ïŒãïŒ17ïŒããã³ïŒ23ïŒã®
2000ååžé液ã«ããããçèãè¬æ¶²äžã«çŽïŒç§é
浞挬ããè¬æ¶²ä¹Ÿç¥åŸã·ã€ãŒã¬ã«å ¥ãããšããŠã ã·
ã®å¥å šå¹Œè«10é ãæŸé£Œããããã®äŸè©Šè«ã®æŸé£Œã¯
çè浞挬åœæ¥ãïŒæ¥åŸã®ïŒåè¡ãªã24æéåŸã®æ»
è«çãæ±ããã
ãè¡šã
è©ŠéšäŸ ïŒ
é¢æ€ãã®ãœã©è±ãžæ®ºè«æåãé©çšããïŒæ¥åã«
ïŒæ¬ã®æšã«å¯ŸããŠã¢ãã©ã ã·ãçŽ200å¹å¯çãã
ããåèäŸïŒã«ãã€ãŠåŸãããæ°Žåå€ã®ãã¡(2)ã
(6)ã(7)ãïŒ14ïŒãïŒ16ïŒãïŒ19ïŒããã³ïŒ24ïŒã®4000
ååžé液ã害è«ãã€ããèãžå§çž®ç©ºæ°ã¹ãã¬ãŒæ³
ã§10mlïŒããããããæ£åžããïŒæ¥åŸã®è¢«å®³åºŠã
芳å¯ããããã®çµæããããã«ãã€ãŠã被害床ã®
å¢å€§ã¯èªããããªãã€ãã è©ŠéšäŸ ïŒ åèäŸïŒã«ãã€ãŠåŸããã(1)ã(5)ã(8)ã(12)ã
ïŒ17ïŒããã³ïŒ21ïŒã®åã ã®ç²å€ãçŽåŸ14cmã®è °
é«ã¬ã©ã¹ã·ã€ãŒã¬åºé¢ã«ïŒïœïŒm2ã®å²åã§åäžã«
æ£åžããåºéšçŽïŒcmãæ®ããŠãã¿ãŒãå£é¢ã«å¡åž
ããããã®äžã«ãã€ãããŽãããªæè«ãïŒçŸ€10å¹
ãšããŠæŸã¡ã30åéæ¥è§Šããæ°ãã容åšã«ãŽãã
ãªã移ãã°ïŒæ¥åŸã«ã¯ãããã®ç²å€ã«ãã€ãŠã80
ïŒ ä»¥äžã®ãŽãããªã殺è«ããããšãã§ããã è©ŠéšäŸ ïŒ æçš®ïŒæ¥åŸã®é¢æ€ããã«ãã·ã€ã³ã²ã³ïŒèã«ïŒ
èããã10é ã®ãã»ãããããéæè«ãå¯çãã
27âã®æ枩宀ã§ä¿ç®¡ãããïŒæ¥åŸãåèäŸïŒã§åŸ
ãããä¹³å€(4)ã(7)ã(10)ãïŒ15ïŒãïŒ20ïŒããã³ïŒ22
ïŒ
ãæ°Žã§æå¹æå100ppmã«åžéããè¬æ¶²ããã¿ãŒ
ã³ããŒãã«äžã§ïŒé¢ããã10mlæ£åžãã10æ¥åŸæ€
ç©äœäžã®ãã»ãããããã®å¯çæ°ã調æ»ãããã
ã®çµæããããã®æ¬çºæ殺è«ã殺ããå€ã«ãããŠ
ãå¯Ÿç §è¬å€ã«ãŸãã殺ããå¹æãèªããããã
ïŒæ¬ã®æšã«å¯ŸããŠã¢ãã©ã ã·ãçŽ200å¹å¯çãã
ããåèäŸïŒã«ãã€ãŠåŸãããæ°Žåå€ã®ãã¡(2)ã
(6)ã(7)ãïŒ14ïŒãïŒ16ïŒãïŒ19ïŒããã³ïŒ24ïŒã®4000
ååžé液ã害è«ãã€ããèãžå§çž®ç©ºæ°ã¹ãã¬ãŒæ³
ã§10mlïŒããããããæ£åžããïŒæ¥åŸã®è¢«å®³åºŠã
芳å¯ããããã®çµæããããã«ãã€ãŠã被害床ã®
å¢å€§ã¯èªããããªãã€ãã è©ŠéšäŸ ïŒ åèäŸïŒã«ãã€ãŠåŸããã(1)ã(5)ã(8)ã(12)ã
ïŒ17ïŒããã³ïŒ21ïŒã®åã ã®ç²å€ãçŽåŸ14cmã®è °
é«ã¬ã©ã¹ã·ã€ãŒã¬åºé¢ã«ïŒïœïŒm2ã®å²åã§åäžã«
æ£åžããåºéšçŽïŒcmãæ®ããŠãã¿ãŒãå£é¢ã«å¡åž
ããããã®äžã«ãã€ãããŽãããªæè«ãïŒçŸ€10å¹
ãšããŠæŸã¡ã30åéæ¥è§Šããæ°ãã容åšã«ãŽãã
ãªã移ãã°ïŒæ¥åŸã«ã¯ãããã®ç²å€ã«ãã€ãŠã80
ïŒ ä»¥äžã®ãŽãããªã殺è«ããããšãã§ããã è©ŠéšäŸ ïŒ æçš®ïŒæ¥åŸã®é¢æ€ããã«ãã·ã€ã³ã²ã³ïŒèã«ïŒ
èããã10é ã®ãã»ãããããéæè«ãå¯çãã
27âã®æ枩宀ã§ä¿ç®¡ãããïŒæ¥åŸãåèäŸïŒã§åŸ
ãããä¹³å€(4)ã(7)ã(10)ãïŒ15ïŒãïŒ20ïŒããã³ïŒ22
ïŒ
ãæ°Žã§æå¹æå100ppmã«åžéããè¬æ¶²ããã¿ãŒ
ã³ããŒãã«äžã§ïŒé¢ããã10mlæ£åžãã10æ¥åŸæ€
ç©äœäžã®ãã»ãããããã®å¯çæ°ã調æ»ãããã
ã®çµæããããã®æ¬çºæ殺è«ã殺ããå€ã«ãããŠ
ãå¯Ÿç §è¬å€ã«ãŸãã殺ããå¹æãèªããããã
ãè¡šã
è©ŠéšäŸ ïŒ
ã³ã€ã察象ãšããŠçšããå瀺蟲æ¿ïŒ¢ç¬¬2735å·
ïŒæå40幎11æ25æ¥ïŒéé¡ã«å¯Ÿããæ¯æ§è©Šéšæ³ã«
æºããŠè¡ãªããæ¬çºæååç©(2)ã(8)ã(11)ãïŒ16ïŒ
ããã³ïŒ21ïŒã®TLm48ïŒppmïŒãæ±ãããšããã
ããã«ãããŠã20以äžã§ãã€ãã
ïŒæå40幎11æ25æ¥ïŒéé¡ã«å¯Ÿããæ¯æ§è©Šéšæ³ã«
æºããŠè¡ãªããæ¬çºæååç©(2)ã(8)ã(11)ãïŒ16ïŒ
ããã³ïŒ21ïŒã®TLm48ïŒppmïŒãæ±ãããšããã
ããã«ãããŠã20以äžã§ãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžè¬åŒ ïŒåŒäžãR1ãR2ã¯åäžåã¯çžç°ãªããæ°ŽçŽ ååã
ããã²ã³ååãççŽ æ°ãïŒãïŒã®ã¢ã«ãã«åºãã
ãã¡ãã«åºãã¡ããã·åºããšããã·åºããžãã«ãª
ãã¡ããã·åºãããã¯R1ãšR2ã§ã¡ãã¬ã³ãžãªã
ã·åºãè¡šããã ã¯é žçŽ ååãŸãã¯ã¡ãã¬ã³åºã§ãããã¯é ž
çŽ ååãã¡ãã¬ã³åºãã¢ããåºãã¡ãã«ã¢ããåº
ãããã¯ãã«ãã«ã¢ããåºãè¡šãããR3ã¯æ°ŽçŽ
åååã¯ããçŽ ååããR4ã¯ãæ°ŽçŽ ååããã
ã²ã³åååã¯ã¡ãã«åºãè¡šãããïŒ ã§è¡šããããææ©ã±ã€çŽ ç³»è³éŠæã¢ã«ã«ã³èªå°äœ
ãå«æããããšãç¹åŸŽãšãã殺è«ã殺ããå€ã ïŒ äžè¬åŒ ïŒåŒäžãR1ãR2ã¯åäžåã¯çžç°ãªããæ°ŽçŽ ååã
ããã²ã³ååãççŽ æ°ãïŒãïŒã®ã¢ã«ãã«åºãã
ãã¡ãã«åºãã¡ããã·åºããšããã·åºããžãã«ãª
ãã¡ããã·åºãããã¯R1ãšR2ã§ã¡ãã¬ã³ãžãªã
ã·åºãè¡šãããåãïŒã¯éå±ååïŒNaããLi
çïŒãè¡šãããïŒã§ç€ºãããææ©ã±ã€çŽ è³éŠæå
åç©ãšäžè¬åŒ ïŒåŒäžãã¯é žçŽ ååãŸãã¯ã¡ãã¬ã³ååã§ã
ããã¯é žçŽ ååãã¡ãã¬ã³åºãã¢ããåºãã¡ã
ã«ã¢ããåºãããã¯ãã«ãã«ã¢ããåºãè¡šããã
R3ã¯æ°ŽçŽ åååã¯ããçŽ ååããR4ã¯ãæ°ŽçŽ å
åãããã²ã³åååã¯ã¡ãã«åºãè¡šããããŸã
ã¯ããã²ã³ååãããã¯æ°Žé žåºã®åå¿æ§èªå°äœã
è¡šãããïŒã§è¡šããããååç©ãåå¿ãããŠåŸã
ããäžè¬åŒ ïŒããã«ãR1ãR2ãR3ãR4ããã¯åè¿°ãšå
ãæå³ãè¡šãããïŒã§è¡šããããææ©ã±ã€çŽ ç³»è³
éŠæã¢ã«ã«ã³èªå°äœãå«æããããšãç¹åŸŽãšãã
殺è«ã殺ããå€ã®è£œæ³ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59209979A JPS6187687A (ja) | 1984-10-05 | 1984-10-05 | ææ©ã±ã€çŽ ç³»è³éŠæã¢ã«ã«ã³èªå°äœãå«æãã殺è«ã殺ããå€åã³ãã®è£œæ³ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59209979A JPS6187687A (ja) | 1984-10-05 | 1984-10-05 | ææ©ã±ã€çŽ ç³»è³éŠæã¢ã«ã«ã³èªå°äœãå«æãã殺è«ã殺ããå€åã³ãã®è£œæ³ |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62322350A Division JPS63170386A (ja) | 1987-12-19 | 1987-12-19 | ææ©ã±ã€çŽ ç³»è³éŠæã¢ã«ã«ã³èªå°äœåã³ãã®è£œé æ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6187687A JPS6187687A (ja) | 1986-05-06 |
| JPS6352035B2 true JPS6352035B2 (ja) | 1988-10-17 |
Family
ID=16581845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59209979A Granted JPS6187687A (ja) | 1984-10-05 | 1984-10-05 | ææ©ã±ã€çŽ ç³»è³éŠæã¢ã«ã«ã³èªå°äœãå«æãã殺è«ã殺ããå€åã³ãã®è£œæ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6187687A (ja) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61263988A (ja) * | 1985-05-16 | 1986-11-21 | Shionogi & Co Ltd | ã·ãªã«çœ®æãšâãã«é¡ããã³æ®ºè«ã»æ®ºããå€ |
| EP0224024B1 (de) * | 1985-10-26 | 1990-06-20 | Hoechst Aktiengesellschaft | Neue Silanderivate, Verfahren zu ihrer Herstellung, sie enthaltende Mittel und ihre Verwendung als SchÀdlingsbekÀmpfungsmittel |
| EP0390228A3 (en) * | 1986-03-04 | 1991-03-13 | Imperial Chemical Industries Plc | Chemical intermediates |
| CN1025470C (zh) * | 1986-05-31 | 1994-07-20 | 赫圻æ¯ç¹è¡ä»œå ¬åž | å«æ°åç¡ ç·è¡çç©çåè¯ïŒæè«ååæèšåç»åç© |
| US4709068A (en) * | 1986-06-02 | 1987-11-24 | Fmc Corporation | Substituted phenyltrialkylsilane insecticides |
| US4883789A (en) * | 1986-06-02 | 1989-11-28 | Fmc Corporation | Substituted phenyltrialkylsilane insecticides |
| JPH01131104A (ja) * | 1986-08-19 | 1989-05-24 | Dainippon Jochugiku Co Ltd | ææ©ã±ã€çŽ ååç©ãå«æãã殺è«ã殺ããå€åã³ãã®è£œé æ³ |
| EP0295271B1 (de) * | 1986-12-17 | 1992-05-27 | RhÃŽne-Poulenc Viscosuisse SA | Polyurethanelastomerfaden und dessen verwendung |
| JP2798939B2 (ja) * | 1988-10-19 | 1998-09-17 | 倧æ¥æ¬é€è²èæ ªåŒäŒç€Ÿ | 蟲åèžçšåå£åŠç殺è«å€ |
| DE4401542A1 (de) * | 1994-01-20 | 1995-07-27 | Hoechst Schering Agrevo Gmbh | Synergistische Kombinationen von Ammoniumsalzen |
| CN102696665A (zh) * | 2012-05-15 | 2012-10-03 | éæ±åžèçŸæ€ä¿äžäžåäœè瀟 | å«æèè«åšçæè«åç»åç© |
| CN105211092A (zh) * | 2014-06-16 | 2016-01-06 | æ±èç绿çŸæ€ä¿åè¯å®éªæéå ¬åž | å«æä¹åºå€æèçŽ çæè«åç»åç© |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60123491A (ja) * | 1983-12-08 | 1985-07-02 | Sumitomo Chem Co Ltd | ææ©ã±ã€çŽ ååç©ããã®è£œé æ³ããã³ãã®ååç©ãæå¹æåãšãã殺è«å€ |
-
1984
- 1984-10-05 JP JP59209979A patent/JPS6187687A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60123491A (ja) * | 1983-12-08 | 1985-07-02 | Sumitomo Chem Co Ltd | ææ©ã±ã€çŽ ååç©ããã®è£œé æ³ããã³ãã®ååç©ãæå¹æåãšãã殺è«å€ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6187687A (ja) | 1986-05-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| PL112140B1 (en) | Insecticide | |
| JPS6352035B2 (ja) | ||
| JPH0351717B2 (ja) | ||
| JP2976038B2 (ja) | æ°èŠã¢ããžã³èªå°äœãåã³ãããå«æãã殺è«ã殺ããå€ | |
| JPH0534321B2 (ja) | ||
| JPH0258242B2 (ja) | ||
| JPS6366303B2 (ja) | ||
| JPS6134410B2 (ja) | ||
| JPH0349911B2 (ja) | ||
| JPS6223740B2 (ja) | ||
| KR820000772B1 (ko) | α-ììë ž-3-íì¥ìë²€ì§-S-(+)-2-(4-íŽë¡ë¡íë)ìŽìë°ë 륎ì°ì ì ì¡°ë°©ë² | |
| JPS6310944B2 (ja) | ||
| JPH0161082B2 (ja) | ||
| JPH031282B2 (ja) | ||
| JPS59157004A (ja) | æ°èŠïŒâããšãã«ãããã«ãšâãã«èªå°äœãå«æãã殺è«ã殺ããå€åã³ãã®è£œé æ³ | |
| JPS60193902A (ja) | 害è«é²é€çšçµæç© | |
| JPS59152303A (ja) | æ°èŠããªãžã«ã¡ãã«èªå°äœãå«æãã殺è«å€ã殺ããå€åã³ãã®è£œé æ³ | |
| JPS60209503A (ja) | æ°èŠè³éŠæã¢ã«ã«ã³èªå°äœãå«æãã殺è«ïŒæ®ºããå€åã³ãã®è£œæ³ | |
| JPS5920659B2 (ja) | ã·ã¯ããããã³ã«ã«ãã³é žãšã¹ãã«èªå°äœãã·ã¯ããããã³ã«ã«ãã³é žãšã¹ãã«èªå°äœã®è£œé æ³ãã·ã¯ããããã³ã«ã«ãã³é žãšã¹ãã«èªå°äœãå«æãã殺è«å€ | |
| JPS6144872B2 (ja) | ||
| JPH0251883B2 (ja) | ||
| JPS629583B2 (ja) | ||
| JPS6144871B2 (ja) | ||
| JPH0212210B2 (ja) | ||
| JPS6124585A (ja) | ã¡ãã¬ã³ãžãªãã·ãã³ãžã«ãšâãã«ååç©ããã®è£œé æ³ããã³è©²ååç©ãããªã殺è«å¹åå¢åŒ·å€ |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20081017 Year of fee payment: 20 |
|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20081017 Year of fee payment: 20 |