JPS635005B2 - - Google Patents
Info
- Publication number
- JPS635005B2 JPS635005B2 JP57219578A JP21957882A JPS635005B2 JP S635005 B2 JPS635005 B2 JP S635005B2 JP 57219578 A JP57219578 A JP 57219578A JP 21957882 A JP21957882 A JP 21957882A JP S635005 B2 JPS635005 B2 JP S635005B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- weight
- present
- amino acid
- smoothness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001296 polysiloxane Polymers 0.000 claims description 15
- 150000001413 amino acids Chemical class 0.000 claims description 10
- 125000002252 acyl group Chemical group 0.000 claims description 8
- 239000002537 cosmetic Substances 0.000 claims description 8
- 125000005907 alkyl ester group Chemical group 0.000 claims description 7
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- -1 pentyl ester Chemical class 0.000 description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 6
- 150000004665 fatty acids Chemical group 0.000 description 6
- 239000003676 hair preparation Substances 0.000 description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 150000003863 ammonium salts Chemical class 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 3
- 229960000541 cetyl alcohol Drugs 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000006210 lotion Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- OGNSCSPNOLGXSM-UHFFFAOYSA-N 2,4-diaminobutyric acid Chemical compound NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 2
- LAIUFBWHERIJIH-UHFFFAOYSA-N 3-Methylheptane Chemical compound CCCCC(C)CC LAIUFBWHERIJIH-UHFFFAOYSA-N 0.000 description 2
- 239000004475 Arginine Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- AHLPHDHHMVZTML-BYPYZUCNSA-N L-Ornithine Chemical compound NCCC[C@H](N)C(O)=O AHLPHDHHMVZTML-BYPYZUCNSA-N 0.000 description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 2
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- AHLPHDHHMVZTML-UHFFFAOYSA-N Orn-delta-NH2 Natural products NCCCC(N)C(O)=O AHLPHDHHMVZTML-UHFFFAOYSA-N 0.000 description 2
- UTJLXEIPEHZYQJ-UHFFFAOYSA-N Ornithine Natural products OC(=O)C(C)CCCN UTJLXEIPEHZYQJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 206010044625 Trichorrhexis Diseases 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229960003104 ornithine Drugs 0.000 description 2
- 229940071139 pyrrolidone carboxylate Drugs 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/893—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
本発明は、毛髪に対し光沢及びなめらかさを付
与する上で優れた効果を有する毛髪化粧料に関す
る。
毛髪は、通常、ヘアークリーム及びヘアーオイ
ル等の動植物油や毛髪自身から分泌される皮脂等
により覆われているが、石ケンや合成洗剤等で洗
髪すると、それらの油脂成分は必要以上に除去さ
れてしまう。そのため洗髪後の毛髪は、なめらか
さが失なわれ、パサパサした硬い感触となり、櫛
通りが悪くなつて裂毛や枝毛が生じ易くなつてし
まう。
このような不都合を解消するため、洗髪後の毛
髪処理剤として各種の毛髪化粧料が開発され、使
用されている。これら毛髪化粧料は、ジアルキル
ジメチルアンモニウムクロライドやアルキルトリ
メチルアンモニウムクロライドに代表される第４
級アンモニウム塩を主要有効成分とするものであ
る。このようなアンモニウム塩には水難溶性のも
のと水易溶性のものとがあり、従つて、それに対
応して、毛髪化粧料には「すすぐタイプ」のもの
と「すすがないタイプ」のものとがあつて、それ
ぞれ使用形態を異ならしめている。
洗髪後の毛髪のキシミやもつれを防ぎ、乾いた
状態の仕上り感をよくするためには、上記アンモ
ニウム塩の適量が毛髪に吸着されていなければな
らない。しかし、従来の毛髪化粧料は、どの使用
形態によつても、上記アンモニウム塩の離脱性や
吸着性に問題があり、満足すべきものとは言えな
かつた。特に、毛髪の光沢およびなめらかさにお
いて未だ不充分であつた。
また、従来より繊維柔軟剤等の各種繊維処理剤
が知られているが、繊維特に動物性繊維は、その
化学的構造において毛髪と類似であるが、物理的
構造において毛髪とは全く異なつているため、そ
のような繊維処理剤の毛髪への適用は困難であ
る。
また、最近の天然系指向の中で、より安全性の
高いものを求める風潮が強くなつてきている。
本発明は、上記事情の下になされたものであつ
て、すすぐタイプおよびすすがないタイプのいず
れのタイプに適用しても優れた光沢及びなめらか
さを毛髪に付与し得る毛髪化粧料を提供すること
を目的とする。
この目的は、モノＮ―長鎖アシル塩基性アミノ
酸低級アルキルエステル塩と、疎水性シリコーン
とを含有することを特徴とする毛髪化粧料を提供
することによつて達成される。
以下、本発明の毛髪化粧料について、更に詳細
に説明する。
本発明の毛髪化粧料の第１の必須成分であるモ
ノＮ―長鎖アシル塩基性アミノ酸の低級アルキル
エステル塩は、オルニチン、リジン、アルギニン
などの塩基性アミノ酸を原料とし、例えば特公昭
42−11926号又は特公昭43−9529号に記載の方法
によつて容易に製造することができる。
モノＮ―長鎖アシル塩基性アミノ酸低級アルキ
ルエステル塩の塩基性アミノ酸成分としては、オ
ルニチン、リジン、アルギニン等の天然アミノ酸
の他、α，γ―ジアミノ酪酸のような合成アミノ
酸も同様に用いられ、これらは光学活性体又はラ
セミ体のいずれであつてもよい。
モノＮ―長鎖アシル塩基性アミノ酸低級アルキ
ルエステル塩のアシル基は、炭素数８ないし22の
飽和又は不飽和の天然又は合成脂肪酸残基であ
り、例えばラウロイル基、ミリストイル基、パル
ミトイル基、ステアロイル基などの単一脂肪酸残
基の他、ヤシ油脂肪酸残基、牛脂脂肪酸残基など
の天然系の混合脂肪酸残基でもよい。
低級アルキルエステル成分としては、メチルエ
ステル、エチルエステル、プロピルエステル、ブ
チルエステル、ペンチルエステル、ヘキシルエス
テル、ヘプチルエステル、オクチルエステルが適
当である。
また、モノＮ―長鎖アシル塩基性アミノ酸エス
テルの塩としては、例えば塩酸塩、硫酸塩のよう
な無機酸塩、または、例えば酢酸塩、酒石酸塩、
クエン酸塩、Ｐ―トルエンスルホン酸塩、脂肪酸
塩、酸性アミノ酸塩、Ｌ又はDL―ピロリドンカ
ルボン酸塩のような有機酸塩が用いられる。これ
らのうち、酸性アミノ酸塩、塩酸塩、Ｌ又はDL
―ピロリドンカルボン酸塩が好ましい。
モノＮ―長鎖アシル塩基性アミノ酸低級アルキ
ルエステル塩の毛髪化粧料への配合量は0.1〜10
重量％、好ましくは0.2〜５重量％である。
本発明の第２の必須成分である疎水性シリコー
ンとは、25℃の水に対する溶解度が１重量％以
下、好ましくは0.5重量％以下のものであり、25
℃における粘度が１ないし1000センチストーク
ス、好ましくは５ないし500センチストークスの
範囲のものである。
上記疎水性シリコーンは、メチルポリシロキサ
ン、メチルフエニルポリシロキサン、脂肪酸変性
ポリシロキサン、脂肪族アルコール変性ポリシロ
キサン、ポリオキシアルキレン変性ポリシロキサ
ンなどを包含する。この疎水性シリコーンの具体
的な性状等を下記に示す。
Γ メチルポリシロキサンとしては下記の一般式
で表わされ、１ないし1000センチストークス
（25℃）の粘度を有するものである。
（CH3）3SiO〔（CH3）2SiO〕oSi（CH3）3
ｎ＝３〜350
Γ メチルフエニルポリシロキサンとしては下記
の一般式で表わされ10ないし1000センチストー
クス（25℃）の粘度を有するものである。
Γ 脂肪酸変性ポリシロキサンとしては下記の一
般式で表わされ、10〜1000センチストークス
（25℃）の粘度を有するものである。
Γ 脂肪族アルコール変性ポリシロキサンとして
は下記の一般式で表わされ、10〜1000センチス
トークス（25℃）の粘度を有するものである。
Γ ポリオキシアルキレン変性ポリシロキサンと
しては下記一般式で表わされ、10〜1000センチ
ストークス（25℃）の粘度を有するものであ
る。
この疎水性シリコーンは毛髪の臨界表面張力に
極めて近いか又は、それ以下の表面張力を有する
ため、毛髪表面に均一に拡張し、べたついたり重
くならない仕上りは勿論のこと、なめらかで光沢
のある仕上り効果を顕著に示す。
一方、親水性シリコーンは保水性が強く、水気
を多く含んだ風乾中又は湿気の多い気候下では重
くなりべたつくので本発明においては使用されな
い。
本発明の毛髪化粧料中におけるシリコーンの配
合量は通常0.05ないし10重量％、好ましくは0.1
ないし５重量％である。
本発明の化粧料は上述した必須成分の他に下記
の任意成分が本発明の効果に影響のない範囲で配
合されてもよい。即ち、任意成分としては流動パ
ラフイン、ワセリン、固型パラフイン、スクワラ
ン及びオレフインオリゴマー等の炭化水素；イソ
プロピルミリステート、イソプロピルパルミテー
ト、ステアリルステアレート、ミリスチン酸オク
チルドデシル、オレイン酸オクチルドデシル及び
２―エチルヘキサン酸トリグリセライド等のエス
テル；ポリオキシエチレンセチルエーテル、ポリ
オキシエチレンステアリン酸エステル及びポリオ
キシエチレンソルビタンモノラウレート等の乳化
剤；塩化ベンザルコニウム、塩化セチルトリメチ
ルアンモニウム、塩化セトステアリルトリメチル
アンモニウム、塩化ステアリルトリメチルアンモ
ニウム、塩化ベヘニルトリメチルアンモニウム、
塩化ジステアリルジメチルアンモニウム等のカチ
オン界面活性剤；Ｎ―（２―ヒドロキシエチル）
―Ｎ―〔ビス（２―カルボキシエチル）アミノエ
チル〕ラウリルアマイドジナトリウム塩、２―コ
コイル―Ｎ―カルボキシメチル―Ｎ―ヒドロキシ
エチルイミダゾリウムベタイン等の両性界面活性
剤；高級アルコールサルフエート、アルコールエ
ーテルサルフエート、α―オレフインスルホネー
ト等のアニオン界面活性剤；ラウリルアルコー
ル、セチルアルコール、ステアリルアルコール、
ベヘニルアルコール等の高級アルコール；パルミ
チン酸、ステアリン酸、ベヘニン酸等の高級脂肪
酸；エチレングリコール、プロピレングリコー
ル、１，３―ブチレングリコール、グリセリン及
びソルビトール等の保湿剤；及びその他溶剤、防
腐剤、香料等の小量成分である。
本発明の毛髪化粧料は、ヘアーリンス剤、ヘア
ーコンデシヨナー、ヘアーローシヨン等の各種用
途に利用することができる。
次に、本発明の実施例と比較例を示し、本発明
の効果をより具体的に説明する。なお、各例の説
明に先立つて、試験法について説明する。
なめらかさ
シヤンプー処理された毛束（５ｇ，20cm）に試
料0.5ｇを直接塗布し、手で均一に伸ばした後、
25℃，65％RHの雰囲気中で乾燥させ、一昼夜放
置後の毛束の「なめらかさ」について20名のパネ
ラーにより官能評価する。
評価基準は1.0重量％のステアリルトリメチル
アンモニウムクロライド、３重量％のセチルアル
コール、10重量％のプロピレングリコール、およ
び水（残部）からなる試料により得た評価を基準
とした５段階評価である。
◎：良い 〇：やや良い
△：同等 ×：やや劣る
××：劣る
光 沢
シヤンプー処理された毛束（５ｇ，20cm）に試
料0.5ｇを直接塗布し、手で均一にのばした後、
25℃，65％RHの雰囲気で乾燥させ、一昼夜放置
後の毛束の光沢（つや）について20名のパネラー
により視覚評価する。
光沢の評価基準は、1.0重量％のステアリルト
リメチルアンモニウムクロライド、３重量％のセ
チルアルコール、10重量％のプロピレングリコー
ル、および水（残部）からなる試料により得た評
価を基準とした５段階評価である。
◎：良い 〇：やや良い
△：同等 ×：やや劣る
××：劣る
試験例 １
第１表に示す配合組成のヘアリンス剤を調整
し、それらについて毛髪へのなめらかさおよび光
沢付与性能を評価した。その結果を同表に示す。
なお、表中の数字は重量％である。
TECHNICAL FIELD The present invention relates to hair cosmetics that have excellent effects in imparting luster and smoothness to hair. Hair is normally covered with animal and vegetable oils such as hair creams and hair oils, as well as sebum secreted from the hair itself, but when hair is washed with soap or synthetic detergents, these oils and fats are removed more than necessary. I end up. As a result, the hair after washing loses its smoothness and feels dry and stiff, making it difficult to comb through the hair, making it more likely to cause split ends and split ends. In order to eliminate such inconveniences, various hair cosmetics have been developed and used as hair treatment agents after hair washing. These hair cosmetics contain quaternary compounds such as dialkyldimethylammonium chloride and alkyltrimethylammonium chloride.
The main active ingredient is grade ammonium salt. There are two types of ammonium salts: those that are poorly soluble in water and those that are easily soluble in water.Therefore, hair cosmetics are divided into ``rinsing type'' and ``non-rinsing type''. There are different usage patterns for each type. In order to prevent hair from squeaking and tangling after washing and to improve the finish when dry, an appropriate amount of the above ammonium salt must be adsorbed to the hair. However, conventional hair cosmetics have problems with the release and adsorption properties of the ammonium salt, regardless of the form of use, and cannot be said to be satisfactory. In particular, the gloss and smoothness of the hair were still insufficient. In addition, various fiber treatment agents such as fiber softeners have been known for some time, but fibers, especially animal fibers, have a chemical structure similar to that of hair, but their physical structure is completely different from that of hair. Therefore, it is difficult to apply such fiber treatment agents to hair. In addition, with the recent trend towards natural products, there is a growing trend for products with higher safety. The present invention has been made under the above circumstances, and provides a hair cosmetic that can impart excellent gloss and smoothness to hair when applied to both rinsing and non-rinsing types. The purpose is to This object is achieved by providing a hair cosmetic containing a mono-N-long chain acyl basic amino acid lower alkyl ester salt and a hydrophobic silicone. Hereinafter, the hair cosmetic of the present invention will be explained in more detail. The lower alkyl ester salt of a mono-N-long chain acyl basic amino acid, which is the first essential component of the hair cosmetic of the present invention, is made from basic amino acids such as ornithine, lysine, and arginine, and is
It can be easily produced by the method described in No. 42-11926 or Japanese Patent Publication No. 43-9529. As the basic amino acid component of the mono-N-long chain acyl basic amino acid lower alkyl ester salt, in addition to natural amino acids such as ornithine, lysine, and arginine, synthetic amino acids such as α,γ-diaminobutyric acid are also used. These may be either optically active or racemic. The acyl group of the mono-N-long chain acyl basic amino acid lower alkyl ester salt is a saturated or unsaturated natural or synthetic fatty acid residue having 8 to 22 carbon atoms, such as lauroyl group, myristoyl group, palmitoyl group, stearoyl group. In addition to single fatty acid residues such as, natural mixed fatty acid residues such as coconut oil fatty acid residues and beef tallow fatty acid residues may be used. Suitable lower alkyl ester components include methyl ester, ethyl ester, propyl ester, butyl ester, pentyl ester, hexyl ester, heptyl ester, and octyl ester. Salts of mono-N-long chain acyl basic amino acid esters include, for example, inorganic acid salts such as hydrochloride and sulfate, or, for example, acetate, tartrate,
Organic acid salts such as citrate, P-toluenesulfonate, fatty acid salts, acidic amino acid salts, L or DL-pyrrolidone carboxylate are used. Among these, acidic amino acid salt, hydrochloride, L or DL
-Pyrrolidone carboxylate is preferred. The amount of mono-N-long chain acyl basic amino acid lower alkyl ester salt added to hair cosmetics is 0.1 to 10.
% by weight, preferably 0.2-5% by weight. The hydrophobic silicone, which is the second essential component of the present invention, has a solubility in water at 25°C of 1% by weight or less, preferably 0.5% by weight or less, and 25% by weight or less.
The viscosity at °C is in the range of 1 to 1000 centistokes, preferably 5 to 500 centistokes. The hydrophobic silicone includes methylpolysiloxane, methylphenylpolysiloxane, fatty acid-modified polysiloxane, aliphatic alcohol-modified polysiloxane, polyoxyalkylene-modified polysiloxane, and the like. Specific properties of this hydrophobic silicone are shown below. Γ Methylpolysiloxane is represented by the following general formula and has a viscosity of 1 to 1000 centistokes (25°C). (CH 3 ) 3 SiO [(CH 3 ) 2 SiO] o Si(CH 3 ) 3
n=3 to 350 Γ The methylphenyl polysiloxane is represented by the following general formula and has a viscosity of 10 to 1000 centistokes (25°C). The Γ fatty acid-modified polysiloxane is represented by the following general formula and has a viscosity of 10 to 1000 centistokes (25°C). The Γ aliphatic alcohol-modified polysiloxane is represented by the following general formula and has a viscosity of 10 to 1000 centistokes (25°C). The Γ polyoxyalkylene-modified polysiloxane is represented by the following general formula and has a viscosity of 10 to 1000 centistokes (25°C). This hydrophobic silicone has a surface tension that is very close to or lower than the critical surface tension of hair, so it spreads evenly over the hair surface, creating a smooth and glossy finish as well as a non-sticky or heavy finish. is clearly shown. On the other hand, hydrophilic silicones have strong water retention properties, and are not used in the present invention because they become heavy and sticky during air-drying containing a lot of moisture or in humid climates. The amount of silicone blended in the hair cosmetic of the present invention is usually 0.05 to 10% by weight, preferably 0.1% by weight.
and 5% by weight. In addition to the above-mentioned essential ingredients, the cosmetic of the present invention may contain the following optional ingredients within a range that does not affect the effects of the present invention. That is, optional components include hydrocarbons such as liquid paraffin, vaseline, solid paraffin, squalane and olefin oligomer; isopropyl myristate, isopropyl palmitate, stearyl stearate, octyldodecyl myristate, octyldodecyl oleate, and 2-ethylhexane. Esters such as acid triglycerides; Emulsifiers such as polyoxyethylene cetyl ether, polyoxyethylene stearate, and polyoxyethylene sorbitan monolaurate; benzalkonium chloride, cetyltrimethylammonium chloride, cetostearyltrimethylammonium chloride, stearyltrimethylammonium chloride , behenyltrimethylammonium chloride,
Cationic surfactants such as distearyldimethylammonium chloride; N-(2-hydroxyethyl)
-N-[bis(2-carboxyethyl)aminoethyl]laurylamide disodium salt, amphoteric surfactants such as 2-cocoyl-N-carboxymethyl-N-hydroxyethylimidazolium betaine; higher alcohol sulfates, alcohol ethers Anionic surfactants such as sulfate and α-olefin sulfonate; lauryl alcohol, cetyl alcohol, stearyl alcohol,
Higher alcohols such as behenyl alcohol; higher fatty acids such as palmitic acid, stearic acid, and behenic acid; humectants such as ethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin, and sorbitol; and other solvents, preservatives, fragrances, etc. It is a minor component. The hair cosmetic composition of the present invention can be used in various applications such as a hair rinse agent, a hair conditioner, and a hair lotion. Next, Examples and Comparative Examples of the present invention will be shown to explain the effects of the present invention more specifically. Before explaining each example, the test method will be explained. Smoothness Apply 0.5g of the sample directly to a shampooed hair bundle (5g, 20cm) and spread it evenly by hand.
After drying in an atmosphere of 25°C and 65% RH and leaving it for a day and night, 20 panelists sensory-evaluated the "smoothness" of the hair strands. The evaluation criteria is a 5-level evaluation based on the evaluation obtained with a sample consisting of 1.0% by weight stearyltrimethylammonium chloride, 3% by weight cetyl alcohol, 10% by weight propylene glycol, and water (remainder). ◎: Good 〇: Slightly good △: Equal ×: Slightly inferior ××: Inferior gloss Apply 0.5 g of the sample directly to a shampooed hair bundle (5 g, 20 cm), and spread it evenly by hand.
After drying in an atmosphere of 25°C and 65% RH, the gloss of the hair strands after being left overnight was visually evaluated by 20 panelists. The gloss evaluation standard is a 5-level evaluation based on the evaluation obtained with a sample consisting of 1.0% by weight stearyltrimethylammonium chloride, 3% by weight cetyl alcohol, 10% by weight propylene glycol, and water (the balance). . ◎: Good 〇: Slightly good △: Equal ×: Slightly inferior XX: Inferior Test Example 1 Hair rinses having the composition shown in Table 1 were prepared, and their smoothness and gloss imparting performance to hair were evaluated. The results are shown in the same table.
In addition, the numbers in the table are weight %.
【表】
第１表から明らかなように、本発明の必須成分
２つを含むヘアリンス剤は、優れた毛髪へのなめ
らかさおよび光沢付与性能を有している。比較例
１〜３は、本発明の必須成分のうち１つを含有し
ていないために本発明の目的を達成できない。
実施例 ２
第２表に示す組成を有するヘアトリートメント
組成物を調製し、その性能を評価した。[Table] As is clear from Table 1, the hair rinse agent containing the two essential ingredients of the present invention has excellent performance in imparting smoothness and shine to hair. Comparative Examples 1 to 3 cannot achieve the object of the present invention because they do not contain one of the essential components of the present invention. Example 2 A hair treatment composition having the composition shown in Table 2 was prepared and its performance was evaluated.
【表】【table】
【表】
上記ヘアトリートメント剤は毛髪に対する優れ
た光沢およびなめらかさ付与効果を示した。
実施例 ３
第３表に示す組成を有するヘアローシヨン組成
物を調製し、その性能を評価した。[Table] The above hair treatment agent showed an excellent effect of imparting shine and smoothness to hair. Example 3 A hair lotion composition having the composition shown in Table 3 was prepared and its performance was evaluated.
【表】
上記ヘアローシヨン組成物は、毛髪に対する優
れた光沢およびなめらかさ付与効果を示した。
実施例 ４
第４表に示す組成を有するヘアブラツシング剤
組成物を調製し、その性能を評価した。[Table] The above hair lotion composition exhibited excellent gloss and smoothing effects on hair. Example 4 A hair brushing agent composition having the composition shown in Table 4 was prepared and its performance was evaluated.
【表】【table】
【表】
上記ヘアブラツシング剤は実施例３と同様のす
ぐれた性能を示した。[Table] The above hair brushing agent showed excellent performance similar to that of Example 3.
Claims (1)
キルエステル塩と疎水性シリコーンとを含有する
ことを特徴とする毛髪化粧料。1. A hair cosmetic comprising a mono-N-long chain acyl basic amino acid lower alkyl ester salt and a hydrophobic silicone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21957882A JPS59110609A (en) | 1982-12-15 | 1982-12-15 | Hair cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21957882A JPS59110609A (en) | 1982-12-15 | 1982-12-15 | Hair cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59110609A JPS59110609A (en) | 1984-06-26 |
| JPS635005B2 true JPS635005B2 (en) | 1988-02-01 |
Family
ID=16737717
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21957882A Granted JPS59110609A (en) | 1982-12-15 | 1982-12-15 | Hair cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59110609A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0699431A1 (en) | 1994-08-24 | 1996-03-06 | Seiwa Kasei Co., Ltd. | Base material for cosmetics and uses of the same |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2558706B2 (en) * | 1987-06-19 | 1996-11-27 | ライオン株式会社 | Hair cosmetics |
| KR20030005257A (en) * | 2000-04-03 | 2003-01-17 | 아지노모토 가부시키가이샤 | Cosmetic compositions |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5692808A (en) * | 1979-12-27 | 1981-07-27 | Lion Corp | Cosmetic for hair |
-
1982
- 1982-12-15 JP JP21957882A patent/JPS59110609A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5692808A (en) * | 1979-12-27 | 1981-07-27 | Lion Corp | Cosmetic for hair |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0699431A1 (en) | 1994-08-24 | 1996-03-06 | Seiwa Kasei Co., Ltd. | Base material for cosmetics and uses of the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59110609A (en) | 1984-06-26 |
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