JPS628097B2 - - Google Patents
Info
- Publication number
- JPS628097B2 JPS628097B2 JP55131502A JP13150280A JPS628097B2 JP S628097 B2 JPS628097 B2 JP S628097B2 JP 55131502 A JP55131502 A JP 55131502A JP 13150280 A JP13150280 A JP 13150280A JP S628097 B2 JPS628097 B2 JP S628097B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- weight
- carbon atoms
- general formula
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 10
- 239000002537 cosmetic Substances 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 125000005526 alkyl sulfate group Chemical group 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- 239000000203 mixture Substances 0.000 description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 239000003676 hair preparation Substances 0.000 description 7
- -1 polyoxyethylene cetyl ether Polymers 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 229960000541 cetyl alcohol Drugs 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 235000013772 propylene glycol Nutrition 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 206010044625 Trichorrhexis Diseases 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000003766 combability Effects 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- DGSZGZSCHSQXFV-UHFFFAOYSA-N 2,3-bis(2-ethylhexanoyloxy)propyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(OC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DGSZGZSCHSQXFV-UHFFFAOYSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- IPTLKMXBROVJJF-UHFFFAOYSA-N azanium;methyl sulfate Chemical compound N.COS(O)(=O)=O IPTLKMXBROVJJF-UHFFFAOYSA-N 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- CDIPRYKTRRRSEM-UHFFFAOYSA-M docosyl(trimethyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C CDIPRYKTRRRSEM-UHFFFAOYSA-M 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- SFFVATKALSIZGN-UHFFFAOYSA-N hexadecan-7-ol Chemical compound CCCCCCCCCC(O)CCCCCC SFFVATKALSIZGN-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- MRAPAFWHXSJNRN-UHFFFAOYSA-M icosyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCC[N+](C)(C)C MRAPAFWHXSJNRN-UHFFFAOYSA-M 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
本発明は毛髪に対し光沢およびなめらかさを付
与する上で優れた効果を有する毛髪化粧料に関す
る。
通常、毛髪は、ヘアークリームやヘアーオイル
等の動植物油および毛髪自身から分泌される皮脂
等により覆われているが、石鹸や合成洗剤等で洗
髪すると、それらの油脂成分は必要以上に除去さ
れてしまう。そのため洗髪後の毛髪はなめらかさ
が失なわれ、パサパサした硬い感触となり、櫛通
りが悪くなつて裂毛や枝毛が生じ易くなつてしま
う。
このような不都合を解消するため、洗髪後の毛
髪処理剤として各種の毛髪化粧料が開発され、使
用されている。これら毛髪化粧料は、ジアルキル
メチルアンモニウムクロライドやアルキルトリメ
チルアンモニウムクロライドに代表される第４級
アンモニウム塩を主要有効成分とするものであ
る。このようなアンモニウム塩には水難溶性のも
のと水易溶性のものとがあり、従つてそれに対応
して、毛髪化粧料には「すすぐタイプ」のものと
「すすがないタイプ」のものとがつて、それぞれ
の使用形態を異ならしめている。
洗髪後等の毛髪のキシミやもつれを防ぎ、乾い
た状態の仕上り感をよくするためには、上記アン
モニウム塩が毛髪に吸着されていなければならな
い。しかし、従来の毛髪化粧料は、どの使用形態
によつても上記アンモニウム塩の離脱性や吸着性
に問題があり、充分満足すべきものではなかつ
た。特に、毛髪の光沢およびなめらかさにおいて
未だ不充分であつた。
また、従来、繊維柔軟剤等の各種繊維処理剤が
知られているが、繊維特に動物性繊維は、その化
学的構造において毛髪と類似であるが、物理的構
造において毛髪とは全く異なつているため、その
ような繊維処理剤の毛髪への適用は困難である。
本発明は、上記事情の下になされたものであつ
て、すすぐタイプおよびすすがないタイプのいず
れのタイプに適用しても優れた光沢およびなめら
かさを毛髪に付与し得る毛髪化粧料を提供するこ
とを目的とする。
即ち、本発明の毛髪化粧料は下記一般式（）
で表わされる第４級アンモニウム塩0.1ないし３
重量％と、下記一般式（）で表わされる第４級
アンモニウム塩0.1ないし３重量％と、下記一般
式（）で表わされる脂肪酸0.1ないし5.0重量％
とを必須成分として含有し、かつ（）／（）
の重量比は1/3ないし3/1であることを特徴とす
る。
一般式（）：
（式中、R1は炭素数16〜18のアルキル基、
R2，R3およびR4は炭素数１〜３のアルキル基又
はヒドロキシアルキル基、Ｘはハロゲン原子又は
アルキル基の炭素原子数が１又は２のアルキル硫
酸基を示す。）
一般式（）：
（式中、R5は炭素数20〜22のアルキル基、
R6，R7およびR8は炭素数１〜３のアルキル基又
はヒドロキシアルキル基、Ｘはハロゲン原子又は
アルキル基の炭素数が１又は２のアルキル硫酸基
を示す。）
一般式（）：
RCOOH
（式中、Ｒは炭素数15〜21の脂肪酸残基を示
す。）
上述の一般式（）で示された第１の必須成分
である第４級アンモニウム塩の配合量は、毛髪化
粧料全体に対し0.1ないし3.0重量％、好ましくは
0.1ないし2.0重量％である。0.1重量％未満では本
発明の効果は発揮されず、3.0重量％を越えると
毛髪のべたつきが増して櫛通り性が劣る。
第１の必須成分の代表例として以下の物質があ
る。
パルミチルトリメチルアンモニウムクロリド、
ステアリルトリメチルアンモニウムクロリド、水
素添加牛脂アルキルトリメチルアンモニウムクロ
リド、水素添加牛脂アルキルトリメチルアンモニ
ウムブロミド、水素添加牛脂アルキルトリエチレ
ンアンモニウムメチルサルフエート。
上述の一般式（）で示された第２の必須成分
である第４級アンモニウム塩の配合量は、毛髪化
粧料全体に対し0.1ないし3.0重量％、好ましくは
0.1ないし2.0重量％である。0.1重量％未満では本
発明の効果は発揮されず、3.0重量％を越えると
毛髪のべたつきが増して櫛通り性が劣る。
第２の必須成分の代表例として以下の物質があ
る。
エイコシルトリメチルアンモニウムクロリド、
ヘンエイコシルトリメチルアンモニウムクロリ
ド、ドコシルトリメチルアンモニウムクロリド、
ドコシルトリメチルアンモニウムブロミド、ドコ
シルトリエチルアンモニウムクロリド、ドコシル
トリメチルアンモニウムメチルサルフエート。
本発明の毛髪化粧料においては、上述の一般式
（）の第４級アンモニウム塩と一般式（）の
第４級アンモニウム塩との重量比（）／（）
が1/3ないし3/1の範囲にある必要がある。特に好
ましくは（）／（）＝１／1.25〜2.5／１であ
る。（）／（）が1/3未満であるか、又は3/1
を越える場合には本発明の効果を得ることができ
ない。
本発明において第３の必須成分として用いられ
る上述の一般式（）で表わされる脂肪酸の配合
量は毛髪化粧料全体に対し、0.1〜5.0重量％であ
る。0.1重量％未満では本発明の効果である毛髪
の光沢およびなめらかさを得られず、5.0重量％
を越えると、ごわつきが増し好ましくない。
上記脂肪酸において、特に好ましい脂肪酸はＲ
がC21のものである。又、本発明のこれら脂肪酸
として、例えばパルミチン酸、オレイン酸、ベヘ
ニン酸があり、これらは単独又は混合物として使
用される。
本発明の毛髪化粧料中には、他の任意成分を、
本発明の効果に影響のない範囲で配合することが
可能である。そのような任意成分として以下の物
質がある。
流動パラフイン、ワセリン、固形パラフイン、
スクワランおよびオレフインオリゴマー等の炭化
水素；イソプロピルミリステート、イソプロピル
パルミテート、ステアリルステアレート、ミリス
チン酸オクチルドデシル、オレイン酸オクチルド
デシルおよび２−エチルヘキサン酸トリグリセラ
イド等のエステル；セタノール、ステアリルアル
コール、ベヘニルアルコールおよびヘキシルデカ
ノール等の高級アルコール；グリセリルモノステ
アレート、ソルビタンモノパルミテート、ポリオ
キシエチレンセチルエーテル、ポリオキシエチレ
ンステアリン酸エステルおよびポリオキシエチレ
ンソルビタンモノラウレート等の乳化剤；メチル
セルロース、ヒドロキシエチルセルロース、ヒド
ロキシプロピルセルロースおよびカチオン化セル
ロース等のセルロース誘導体；天然高分子類等の
増粘剤；エチレングリコール、プロピレングリコ
ール、１，３−ブチレングリコール、グリセリン
およびソルビトール等の保湿剤；およびその他溶
剤、殺菌剤、香料等の少量成分である。
本発明の毛髪化粧料は、ヘアーリンス剤、スプ
レー型又はデイスペンサー型のヘアコンデシヨナ
ー、ヘアーローシヨン等の各種用途に利用するこ
とができる。
次に、本発明の実施例と比較例を示し、本発明
の効果をより具体的に説明する。なお、各例の説
明に先立つて、試験法について説明する。
なめらかさ
シヤンプー処理された毛束（５ｇ、20cm）に試
料0.5ｇを直接塗布し、手で均一に伸ばしたのち
25℃、65％RHの雰囲気で乾燥させ、一昼夜放置
後の毛束の「なめらかさ」について20名のパネラ
ーにより官能評価する。
評価基準は1.0重量％のステアリルトリメチル
アンモニウムクロライド、３重量％のセチルアル
コール、10重量％のプロピレングリコール、およ
び水（残部）からなる試料（比較例１）により得
た評価を基準とした５段階評価である。
◎：良い 〇：やや良い △：同等 ×：やや
劣る ××：劣る
光 沢
シヤンプー処理された毛束（５ｇ、20cm）に試
料0.5ｇを直接塗布し、手で均一に伸ばしたのち
25℃、65％RHの雰囲気で乾燥させ、一昼夜放置
後の毛束の光沢（つや）について20名のパネラー
により視覚評価する。
光沢の評価基準は1.0重量％のステアリルトリ
メチルアンモニウムクロライド、３重量％のセチ
ルアルコール、10重量％のプロピレングリコー
ル、および水（残部）からなる試料（比較例１）
により得た評価を基準とした５段階評価である。
◎：良い 〇：やや良い △：同等 ×：やや
劣る ××：劣る
試験例 １
表−１に示す組成を有する19種の毛髪化粧料を
調整し、性能（光沢およびなめらかさ）を試験し
た。その結果を同表に示す。なお配合量は重量％
である（他の試験例でも同様）。
The present invention relates to hair cosmetics that have excellent effects in imparting shine and smoothness to hair. Normally, hair is covered with animal and vegetable oils such as hair creams and hair oils, as well as sebum secreted from the hair itself, but when hair is washed with soap or synthetic detergents, these oils and fats are removed more than necessary. Put it away. As a result, the hair after washing loses its smoothness, feels dry and stiff, and becomes difficult to comb, making it more likely to cause split ends and split ends. In order to eliminate such inconveniences, various hair cosmetics have been developed and used as hair treatment agents after hair washing. These hair cosmetics contain quaternary ammonium salts such as dialkylmethylammonium chloride and alkyltrimethylammonium chloride as the main active ingredient. There are two types of ammonium salts: those that are poorly soluble in water and those that are easily soluble in water.Therefore, correspondingly, there are two types of hair cosmetics: ``rinse type'' and ``non-rinse type.'' Therefore, each type of usage is different. In order to prevent hair from squeaking and tangling after washing, etc., and to improve the finish when dry, the above ammonium salt must be adsorbed to the hair. However, conventional hair cosmetics have problems with the release and adsorption properties of the ammonium salt, regardless of the form of use, and are not fully satisfactory. In particular, the gloss and smoothness of the hair were still insufficient. In addition, various fiber treatment agents such as fiber softeners have been known, but fibers, especially animal fibers, have a chemical structure similar to hair, but a physical structure that is completely different from hair. Therefore, it is difficult to apply such fiber treatment agents to hair. The present invention has been made under the above circumstances, and provides a hair cosmetic that can impart excellent gloss and smoothness to hair when applied to both rinsing and non-rinsing types. The purpose is to That is, the hair cosmetic of the present invention has the following general formula ()
Quaternary ammonium salt represented by 0.1 to 3
% by weight, 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (), and 0.1 to 5.0% by weight of a fatty acid represented by the following general formula ().
Contains as an essential component, and ()/()
The weight ratio of is 1/3 to 3/1. General formula (): (In the formula, R 1 is an alkyl group having 16 to 18 carbon atoms,
R 2 , R 3 and R 4 represent an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, and X represents a halogen atom or an alkyl sulfate group having 1 or 2 carbon atoms in the alkyl group. ) General formula (): (In the formula, R 5 is an alkyl group having 20 to 22 carbon atoms,
R 6 , R 7 and R 8 represent an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, and X represents a halogen atom or an alkyl sulfate group having 1 or 2 carbon atoms in the alkyl group. ) General formula (): RCOOH (In the formula, R represents a fatty acid residue having 15 to 21 carbon atoms.) Blend of quaternary ammonium salt, which is the first essential component, shown in the above general formula () The amount is 0.1 to 3.0% by weight based on the entire hair cosmetic, preferably
0.1 to 2.0% by weight. If it is less than 0.1% by weight, the effect of the present invention will not be exhibited, and if it exceeds 3.0% by weight, the hair will become sticky and the combability will be poor. The following substances are representative examples of the first essential component. palmityltrimethylammonium chloride,
Stearyltrimethylammonium chloride, hydrogenated tallow alkyltrimethylammonium chloride, hydrogenated tallow alkyltrimethylammonium bromide, hydrogenated tallow alkyltriethylene ammonium methyl sulfate. The amount of the quaternary ammonium salt, which is the second essential component represented by the above general formula (), is 0.1 to 3.0% by weight, preferably 0.1 to 3.0% by weight based on the total hair cosmetic.
0.1 to 2.0% by weight. If it is less than 0.1% by weight, the effect of the present invention will not be exhibited, and if it exceeds 3.0% by weight, the hair will become sticky and the combability will be poor. Representative examples of the second essential component include the following substances. eicosyltrimethylammonium chloride,
Heneicosyltrimethylammonium chloride, docosyltrimethylammonium chloride,
Docosyltrimethylammonium bromide, docosyltriethylammonium chloride, docosyltrimethylammonium methyl sulfate. In the hair cosmetic of the present invention, the weight ratio ()/() of the quaternary ammonium salt of the above-mentioned general formula () to the quaternary ammonium salt of the general formula () is
must be in the range of 1/3 to 3/1. Particularly preferably, ()/()=1/1.25 to 2.5/1. ()/() is less than 1/3 or 3/1
If the amount exceeds 100%, the effects of the present invention cannot be obtained. The amount of the fatty acid represented by the above general formula () used as the third essential component in the present invention is 0.1 to 5.0% by weight based on the total hair cosmetic composition. If it is less than 0.1% by weight, the hair gloss and smoothness that is the effect of the present invention cannot be obtained, and if it is less than 5.0% by weight,
If it exceeds this, the stiffness will increase and this is not desirable. Among the above fatty acids, a particularly preferable fatty acid is R
is that of C 21 . Further, these fatty acids of the present invention include, for example, palmitic acid, oleic acid, and behenic acid, which may be used alone or as a mixture. The hair cosmetic of the present invention contains other optional ingredients,
It is possible to mix them within a range that does not affect the effects of the present invention. Such optional ingredients include the following substances. liquid paraffin, vaseline, solid paraffin,
Hydrocarbons such as squalane and olefin oligomers; esters such as isopropyl myristate, isopropyl palmitate, stearyl stearate, octyldodecyl myristate, octyldodecyl oleate and 2-ethylhexanoic acid triglyceride; cetanol, stearyl alcohol, behenyl alcohol and hexyldecanol, etc. higher alcohols; emulsifiers such as glyceryl monostearate, sorbitan monopalmitate, polyoxyethylene cetyl ether, polyoxyethylene stearate and polyoxyethylene sorbitan monolaurate; methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and cationized cellulose cellulose derivatives such as; thickeners such as natural polymers; humectants such as ethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin and sorbitol; and other small amounts of ingredients such as solvents, disinfectants, and fragrances. . The hair cosmetic composition of the present invention can be used in various applications such as a hair rinse agent, a spray-type or dispenser-type hair conditioner, and a hair lotion. Next, Examples and Comparative Examples of the present invention will be shown to explain the effects of the present invention more specifically. Before explaining each example, the test method will be explained. Smoothness Apply 0.5g of the sample directly to a shampooed hair bundle (5g, 20cm) and spread it evenly by hand.
After drying in an atmosphere of 25°C and 65% RH and leaving it for a day and night, 20 panelists sensory-evaluated the "smoothness" of the hair strands. The evaluation criteria is a 5-level evaluation based on the evaluation obtained with a sample (Comparative Example 1) consisting of 1.0% by weight stearyltrimethylammonium chloride, 3% by weight cetyl alcohol, 10% by weight propylene glycol, and water (balance). It is. ◎: Good 〇: Slightly good △: Equal ×: Slightly inferior ××: Inferior gloss Apply 0.5g of the sample directly to a shampooed hair bundle (5g, 20cm) and spread it evenly by hand.
After drying in an atmosphere of 25°C and 65% RH, the gloss of the hair strands after being left overnight was visually evaluated by 20 panelists. The evaluation criteria for gloss was a sample consisting of 1.0% by weight stearyltrimethylammonium chloride, 3% by weight cetyl alcohol, 10% by weight propylene glycol, and water (balance) (Comparative Example 1)
This is a 5-level evaluation based on the evaluation obtained by. ◎: Good 〇: Slightly good △: Equal ×: Slightly inferior ××: Inferior Test Example 1 19 types of hair cosmetics having the compositions shown in Table 1 were prepared and their performance (gloss and smoothness) was tested. The results are shown in the same table. The compounding amount is weight%
(The same applies to other test examples).
【表】【table】
【表】【table】
【表】
表−１から明らかのようにモノC16-18アルキル
第４級アンモニウム塩（※１）、モノC20-22アル
キル第４級アンモニウム塩（※３）およびC22脂
肪酸（※５）を含有する本発明の組成物（実施例
１）以外の組成物（比較例１〜18）は光沢および
なめらかさが不充分であることがわかる。
試験例 ２
表−２に示す11種の毛髪化粧料を調整し、これ
らの性能を試験した。その結果を同表に示す。[Table] As is clear from Table 1, mono C 16-18 alkyl quaternary ammonium salt (*1), mono C 20-22 alkyl quaternary ammonium salt (*3) and C 22 fatty acid (*5) It can be seen that the compositions (Comparative Examples 1 to 18) other than the composition of the present invention (Example 1) containing the above compositions have insufficient gloss and smoothness. Test Example 2 Eleven types of hair cosmetics shown in Table 2 were prepared and their performance was tested. The results are shown in the same table.
【表】
表−２から明らかのようにモノC16-18アルキル
第４級アンモニウム塩と、モノC20-22アルキル第
４級アンモニウム塩との重量比がが1/3〜3/1のと
き、いずれも優れた光沢およびなめらかさを示す
ことがわかる。
試験例 ３
表−３に示す配合組成の２種のヘアーリンス組
成物を製造し、その性能を評価した。
性能評価は40℃のヘアーリンス組成物の２％希
釈液200mlに毛束（8.5ｇ、20cm）を５秒間浸漬
し、40℃の温水200mlで30秒間づつ２回すすいで
乾燥した後のものについて行なつた。[Table] As is clear from Table 2, when the weight ratio of mono C 16-18 alkyl quaternary ammonium salt to mono C 20-22 alkyl quaternary ammonium salt is 1/3 to 3/1 , it can be seen that both exhibit excellent gloss and smoothness. Test Example 3 Two types of hair rinse compositions having the formulation shown in Table 3 were manufactured and their performance was evaluated. Performance evaluation was performed after immersing a hair bundle (8.5 g, 20 cm) in 200 ml of a 2% diluted hair rinse composition at 40°C for 5 seconds, rinsing twice with 200 ml of 40°C warm water for 30 seconds each, and drying. I did it.
【表】
表−３から明らかのように、本発明のヘアーリ
ンス組成物は、従来のものよりも優れた光沢およ
びなめらかさを有していることがわかる。
試験例 ４
下記の表−４に示す配合組成のヘアークリーム
組成物を調整し、その性能を評価した。[Table] As is clear from Table 3, the hair rinse composition of the present invention has better gloss and smoothness than conventional ones. Test Example 4 A hair cream composition having the composition shown in Table 4 below was prepared and its performance was evaluated.
【表】
本発明のヘアークリーム組成物は従来のヘアー
クリームにない優れた光沢およびなめらかさを有
していた。[Table] The hair cream composition of the present invention had excellent gloss and smoothness not found in conventional hair creams.
Claims (1)
ニウム塩0.1ないし３重量％と、下記一般式
（）で表わされる第４級アンモニウム塩0.1ない
し３重量％と、下記一般式（）で表わされる脂
肪酸0.1ないし5.0重量％とを必須成分として含有
し、かつ（）／（）の重量比は1/3ないし3/1
であることを特徴とする毛髪化粧料。 一般式（） （式中、R1は炭素数16〜18のアルキル基、
R2，R3およびR4は炭素数１〜３のアルキル基又
はヒドロキシアルキル基、Ｘはハロゲン原子又は
アルキル基の炭素原子数が１又は２のアルキル硫
酸基を示す。） 一般式（）： （式中、R5は炭素数20〜22のアルキル基、
R6，R7およびR8は炭素数１〜３のアルキル基又
はヒドロキシアルキル基、Ｘはハロゲン原子又は
アルキル基の炭素数が１又は２のアルキル硫酸基
を示す。） 一般式（）： RCOOH （式中、Ｒは炭素数15〜21の脂肪酸残基を示
す。）[Scope of Claims] 1 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (); 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (); and 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (); Contains 0.1 to 5.0% by weight of fatty acids represented by () as an essential component, and the weight ratio of ()/() is 1/3 to 3/1.
A hair cosmetic characterized by: General formula () (In the formula, R 1 is an alkyl group having 16 to 18 carbon atoms,
R 2 , R 3 and R 4 represent an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, and X represents a halogen atom or an alkyl sulfate group having 1 or 2 carbon atoms in the alkyl group. ) General formula (): (In the formula, R 5 is an alkyl group having 20 to 22 carbon atoms,
R 6 , R 7 and R 8 represent an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, and X represents a halogen atom or an alkyl sulfate group having 1 or 2 carbon atoms in the alkyl group. ) General formula (): RCOOH (In the formula, R represents a fatty acid residue having 15 to 21 carbon atoms.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13150280A JPS5756412A (en) | 1980-09-24 | 1980-09-24 | Hair cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13150280A JPS5756412A (en) | 1980-09-24 | 1980-09-24 | Hair cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5756412A JPS5756412A (en) | 1982-04-05 |
| JPS628097B2 true JPS628097B2 (en) | 1987-02-20 |
Family
ID=15059510
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13150280A Granted JPS5756412A (en) | 1980-09-24 | 1980-09-24 | Hair cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5756412A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5978113A (en) * | 1982-10-28 | 1984-05-04 | Shiseido Co Ltd | Hair cosmetic |
| JPH0791178B2 (en) * | 1986-09-03 | 1995-10-04 | ライオン株式会社 | Oral composition |
| JPS63212028A (en) * | 1987-02-26 | 1988-09-05 | Matsutani Seisakusho:Kk | String fitting device for eyeless needle |
| JP3208237B2 (en) * | 1993-11-19 | 2001-09-10 | 花王株式会社 | Hair cosmetics |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53118531A (en) * | 1977-03-24 | 1978-10-17 | Lion Corp | Liquid hair conditioning composition |
| JPS55108811A (en) * | 1979-02-10 | 1980-08-21 | Lion Corp | Hair-treating composition |
-
1980
- 1980-09-24 JP JP13150280A patent/JPS5756412A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53118531A (en) * | 1977-03-24 | 1978-10-17 | Lion Corp | Liquid hair conditioning composition |
| JPS55108811A (en) * | 1979-02-10 | 1980-08-21 | Lion Corp | Hair-treating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5756412A (en) | 1982-04-05 |
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