JPS6345203A - Agricultural chemical dust - Google Patents
Agricultural chemical dustInfo
- Publication number
- JPS6345203A JPS6345203A JP62089313A JP8931387A JPS6345203A JP S6345203 A JPS6345203 A JP S6345203A JP 62089313 A JP62089313 A JP 62089313A JP 8931387 A JP8931387 A JP 8931387A JP S6345203 A JPS6345203 A JP S6345203A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- added
- powder
- agricultural chemical
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003905 agrochemical Substances 0.000 title claims abstract description 77
- 239000000428 dust Substances 0.000 title abstract description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000005977 Ethylene Substances 0.000 claims abstract description 13
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004711 α-olefin Substances 0.000 claims abstract description 13
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 9
- 239000011707 mineral Substances 0.000 claims abstract description 9
- 239000012188 paraffin wax Substances 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims description 68
- 239000000575 pesticide Substances 0.000 claims description 16
- 239000012868 active agrochemical ingredient Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 abstract description 29
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract description 18
- 239000004480 active ingredient Substances 0.000 abstract description 18
- 239000010734 process oil Substances 0.000 abstract description 12
- 239000007788 liquid Substances 0.000 abstract description 9
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 6
- 229930195733 hydrocarbon Natural products 0.000 abstract description 6
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 6
- 230000004071 biological effect Effects 0.000 abstract description 5
- 238000000354 decomposition reaction Methods 0.000 abstract description 5
- 238000003860 storage Methods 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000005662 Paraffin oil Substances 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract description 2
- 239000003814 drug Substances 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- 239000004927 clay Substances 0.000 description 42
- 239000002994 raw material Substances 0.000 description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 description 14
- 239000000654 additive Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- MSHXTAQSSIEBQS-UHFFFAOYSA-N s-[3-carbamoylsulfanyl-2-(dimethylamino)propyl] carbamothioate;hydron;chloride Chemical compound [Cl-].NC(=O)SCC([NH+](C)C)CSC(N)=O MSHXTAQSSIEBQS-UHFFFAOYSA-N 0.000 description 7
- 229940057995 liquid paraffin Drugs 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 238000007667 floating Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 241000209094 Oryza Species 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical group CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- -1 2-phenyl-6-pyridazinyl Chemical group 0.000 description 3
- GTCAXTIRRLKXRU-UHFFFAOYSA-N carbamic acid methyl ester Natural products COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920001083 polybutene Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 229940088679 drug related substance Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- JARYYMUOCXVXNK-CSLFJTBJSA-N validamycin A Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-CSLFJTBJSA-N 0.000 description 2
- OHVLMTFVQDZYHP-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical group N1N=NC=2CN(CCC=21)C(CN1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O OHVLMTFVQDZYHP-UHFFFAOYSA-N 0.000 description 1
- ZETPHGFJUHEJSB-UHFFFAOYSA-N 1-phenoxy-3-(propoxymethyl)benzene Chemical compound CCCOCC1=CC=CC(OC=2C=CC=CC=2)=C1 ZETPHGFJUHEJSB-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- DFGKGUXTPFWHIX-UHFFFAOYSA-N 6-[2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]acetyl]-3H-1,3-benzoxazol-2-one Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)C1=CC2=C(NC(O2)=O)C=C1 DFGKGUXTPFWHIX-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000256251 Spodoptera frugiperda Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229930195482 Validamycin Natural products 0.000 description 1
- JARYYMUOCXVXNK-UHFFFAOYSA-N Validamycin A Natural products OC1C(O)C(OC2C(C(O)C(O)C(CO)O2)O)C(CO)CC1NC1C=C(CO)C(O)C(O)C1O JARYYMUOCXVXNK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- GNVMUORYQLCPJZ-UHFFFAOYSA-N carbamothioic s-acid Chemical compound NC(S)=O GNVMUORYQLCPJZ-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- QPPQHRDVPBTVEV-UHFFFAOYSA-N isopropyl dihydrogen phosphate Chemical compound CC(C)OP(O)(O)=O QPPQHRDVPBTVEV-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- PVTHJAPFENJVNC-MHRBZPPQSA-N kasugamycin Chemical compound N[C@H]1C[C@H](NC(=N)C(O)=O)[C@@H](C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O PVTHJAPFENJVNC-MHRBZPPQSA-N 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000010550 living polymerization reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VOEYXMAFNDNNED-UHFFFAOYSA-N metolcarb Chemical compound CNC(=O)OC1=CC=CC(C)=C1 VOEYXMAFNDNNED-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000002054 transplantation Methods 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- JVFFWGJAAQAIBS-UHFFFAOYSA-K trisodium 2,2-dioctyl-3-sulfonatobutanedioate Chemical compound [Na+].C(CCCCCCC)C(C(C(=O)[O-])S(=O)(=O)[O-])(C(=O)[O-])CCCCCCCC.[Na+].[Na+] JVFFWGJAAQAIBS-UHFFFAOYSA-K 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、改良された農薬粉剤に関する。更に詳しくは
、農薬活性成分及び鉱物質粉状担体に、炭化水素系粘稠
液体の一種から数種を配合することにより飛散性が抑え
られる等の改良がなされた農薬粉剤に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to an improved agrochemical powder. More specifically, the present invention relates to an agrochemical powder in which scattering properties are suppressed by blending one to several hydrocarbon-based viscous liquids with an agrochemical active ingredient and a mineral powder carrier.
従来の技術
農薬粉剤の散布の際、目的とする圃場以外に粉剤が飛散
し、池の動植物への悪影響を及ぼすことを避けるため、
農薬粉剤のドリフト防止が、強く要望されており、これ
らの方法として、微粒剤、粗粉剤のような、粗大粒へと
粒度を調整した剤型にするか、あるいは、流動パラフィ
ン、ポリブテン、ポリイソブチン等の湿潤性物質等を添
加する方法が知られており、例えば、特公昭５３−２３
３８３及び特公昭５５−３７５２１等に、後者の方法が
提案されている。Conventional technology When spraying pesticide powder, in order to prevent the powder from scattering in areas other than the intended field and having a negative impact on the animals and plants in the pond,
There is a strong demand for preventing the drift of pesticide powders, and these methods include making formulations with adjusted particle size into coarse particles such as fine particles and coarse powders, or using liquid paraffin, polybutene, polyisobutyne, etc. A method of adding a wetting substance, etc. is known, for example, Japanese Patent Publication No. 53-23
The latter method has been proposed in Japanese Patent Publication No. 383 and Japanese Patent Publication No. 55-37521.
発明が解決しようとする問題点
しかし、これらのドリフト防止方法のうち、特に前者の
方法では、特殊な造粒装置が必要となり、又粗大粒に造
粒された農薬は、作物等の表面に付着しにくく、かつ吸
収されにくいという欠点があり、効果を奏し始めるのに
時間を要する。その間風雨により流失される可能性もあ
り、更に効果が低下することは免れない。Problems to be Solved by the Invention However, among these drift prevention methods, the former method in particular requires a special granulation device, and the agricultural chemicals granulated into coarse particles tend to adhere to the surface of crops, etc. It has the disadvantage of being difficult to administer and absorb, and it takes time for it to begin to take effect. During that time, there is a possibility that it will be washed away by wind and rain, which will inevitably reduce its effectiveness further.
又、後者の方法は、流動性、分散性、吐扮性及び付着性
等の物性を失うことなく、かつ農薬活性成分のドリフト
を抑制できるという要求を、十分に充たししかも経済的
にも有利な方法とは言い難かった。In addition, the latter method satisfies the requirements of being able to suppress the drift of agricultural chemical active ingredients without losing physical properties such as fluidity, dispersibility, dispersibility, and adhesion, and is also economically advantageous. It was hard to say how.
而して特殊な装置も要せず、低コストで扱い易く、粉剤
自体の流動性、付着性等の物性を失うことなく、しかも
それ自体毒性等安全面で問題のない、ドリフト防止の為
の添加剤が要望されていた。It does not require special equipment, is low cost, easy to handle, does not lose the physical properties such as fluidity and adhesion of the powder itself, and has no safety problems such as toxicity. Additives were requested.
本発明の目的は、農薬活性成分のドリフトを、効率的で
、経済的にも有利な方法で抑制し得る農薬粉剤を提供す
ることにある。An object of the present invention is to provide an agrochemical powder that can suppress the drift of agrochemical active ingredients in an efficient and economically advantageous manner.
問題点を解決するための手段
本発明は、前記のような農薬粉剤中の農薬活性成分のド
リフト防止のための添加剤を種々検討した結果、（１）
エチレンとα−オレフィンのコオリゴマーあるいは、こ
れに更にイソブチレンのオリゴマー及び塩素化パラフィ
ンの一種又は両者を加えたもの、（１１）プロセスオイ
ルあるいは、これに更にイソブチレンのオリゴマー、エ
チレンとα−オレフィンのコオリゴマーおよび塩素化パ
ラフィンの一種以上を加えたもの、又は（ｉｉｉ）ブタ
ジェン系オリゴマーあるいは、これに更にイソブチレン
のオリゴマー、エチレンとα−オレフィンのコオリゴマ
ー、塩素化パラフィン及びプロセスオイルの一種以上を
加えたもののいずれかを、農薬活性物質及び鉱物質粉状
担体に配合した場合、流動性、分散性、吐粉性及び付着
性等を失うことなく活性成分の飛散性、浮遊性が、顕著
に低減されることを見出す一方、意外にも農薬活性成分
の安定性が改良され、その結果薬効が向上するという予
想外の効果も奏することも見出して本発明を完成するに
至った。Means for Solving the Problems The present invention was developed as a result of various studies on additives for preventing the drift of pesticide active ingredients in pesticide powders as described above.
Cooligomer of ethylene and α-olefin, or a co-oligomer of isobutylene and one or both of chlorinated paraffin, (11) process oil, or co-oligomer of isobutylene, ethylene and α-olefin. or (iii) a butadiene-based oligomer, or one or more oligomers of isobutylene, cooligomers of ethylene and α-olefins, chlorinated paraffins, and process oils. When either of these is blended with a pesticide active substance and a mineral powder carrier, the scattering and floating properties of the active ingredient are significantly reduced without losing fluidity, dispersibility, dust dispersion properties, adhesion properties, etc. At the same time, the present inventors have also discovered that the stability of agricultural chemical active ingredients is improved, resulting in improved medicinal efficacy, which is an unexpected effect, leading to the completion of the present invention.
すなわち、本発明は（１）エチレンとα−オレフィンの
コオリゴマーあるいは、これに更にイソブチレンのオリ
ゴマー及び塩素化バラフ、ｆンの一種又は両者を加えた
もの、（１１）プロセスオイルあるいは、これに更にイ
ソブチレンのオリゴマー、エチレンとα−オレフィンの
コオリゴマーおよび塩素化パラフィンの一種以上を加え
たもの、又は（ｉｉｉ）ブタジェン系オリゴマーあるい
は、これに更にイソブチレンのオリゴマー、エチレンと
α−オレフィンのコオリゴマー、塩素化パラフィン及び
プロセスオイルの一種以上を加えたもののいずれかを、
含有することを特徴とする農薬粉剤であり、本発明の農
薬粉剤は、かかる炭化水素系粘稠液体の添加により、農
薬活性成分の飛散性、浮遊性が低減し、更には、農薬活
性成分の貯蔵時の分解が防がれ、ひいては農薬としての
薬効が向上し、生物効果が優れているという特徴を有す
る。That is, the present invention provides (1) a cooligomer of ethylene and α-olefin, or a cooligomer of isobutylene and one or both of chlorinated baraf and f; (11) a process oil; Isobutylene oligomers, ethylene and α-olefin cooligomers, and one or more chlorinated paraffins added, or (iii) butadiene oligomers, or isobutylene oligomers, ethylene and α-olefin cooligomers, chlorine paraffin and one or more types of process oil,
The agrochemical powder of the present invention is characterized in that, by adding such a hydrocarbon-based viscous liquid, the scattering and floating properties of the agrochemical active ingredient are reduced, and furthermore, the agrochemical active ingredient is It is characterized by preventing decomposition during storage, improving its medicinal efficacy as an agrochemical, and having excellent biological effects.
本発明に用いられる、府記炭化水素系帖稠液体について
以下に詳迂する。（１）エチレンとα−オレフィンのコ
オリゴマーとしては、例えば［（ＣＩ（−ＣＨｔ）−（
ｃ Ｈｔ ＣＨ） ］ｘ ｙ
ｐ
（式中ＲはＣｎ１（ｔｎ＋１でｘ、 ｙ、 ｐ及びｎは
、３ｏ≦ｘ、ｙ≦７０．５≦ｐ≦８．ｎ＝ １〜３の整
数を表す）で表わされるオリゴマーが好都合に用いられ
る。上記式において、ｎ＝ １ 、Ｘ＝Ｙ＝ ５０及び
ｐ＝１０〜６０を満たす構造を有するものがより好まし
く、［Ｆ］
就中、ルーカント （ＨＣ−１０，ＨＣ−２０，ＨＣ
−４０，ＨＣ−１００，ＨＣ−１５０，）（Ｃ−６００
及びＨＣ−２０００の各銘柄を含む、三井石油化学工業
（株）製）が、特に好ましい。The detailed hydrocarbon-based liquid used in the present invention will be described below. (1) As a cooligomer of ethylene and α-olefin, for example, [(CI(-CHt)-(
c Ht CH) ]x y
An oligomer represented by p (wherein R is Cn1 (tn+1 and x, y, p and n represent an integer of 3o≦x, y≦70.5≦p≦8.n=1 to 3) is conveniently used. In the above formula, those having a structure satisfying n = 1,
-40, HC-100, HC-150,) (C-600
and HC-2000 (manufactured by Mitsui Petrochemical Industries, Ltd.) are particularly preferred.
これに更に加えて用いてもよい添加剤のイソブチレンの
オリゴマーとしては、例えば
わされるオリゴマーが好ましく、就中、例えば、ＩＰソ
ルヘント−２３３５（数平均分子ｆ（ｔ２７０）及びＩ
ｐソルベント−２Ｏ２８（数平均分子ｆｆ１２２０）１
ともに出光石油化学（昧）製］が、好都合に用いられる
。As the isobutylene oligomer that may be used as an additive, for example, a diluted oligomer is preferable, and among them, for example, IP Solgent-2335 (number average molecular f(t270) and I
p-solvent-2O28 (number average molecule ff1220)1
Both manufactured by Idemitsu Petrochemical (Madhi)] are conveniently used.
又、更に併用してもよいもう一種の添加剤である塩素化
パラフィンは、パラフィンを塩素化して得られる液体で
あり、例えば、パラフィンワックスあるいは低分子ノル
マルパラフィンを原料に、塩素を含有量４０〜７０％で
含有し、比重１．１０〜１．７０、平均分子量３５０〜
１１００のものが好都合に用いられ、好ましく（よ、ト
ヨパ５７，８■「東洋曹達工業（株）製］、更に好まし
くは、トヨバラックスＡ−４０、トヨパラックス１４５
及びトヨパラックス１５０． ［塩素含有量は、それぞ
れ４０．５％、 ４３．５％。In addition, chlorinated paraffin, which is another type of additive that may be used in combination, is a liquid obtained by chlorinating paraffin. Contains 70%, specific gravity 1.10-1.70, average molecular weight 350-
1100 is conveniently used, preferably Toyopa 57.8 (manufactured by Toyo Soda Kogyo Co., Ltd.), more preferably Toyo Barax A-40, Toyo Barax 145.
and Toyoparax 150. [Chlorine content is 40.5% and 43.5%, respectively.
５０％、比重はそれぞれ１．１６（２５℃）、 １．１
６（２５℃）及び１．２５（２５℃）コの銘柄が用いら
れる。50%, specific gravity is 1.16 (25℃) and 1.1, respectively.
6 (25°C) and 1.25 (25°C) brands are used.
（１１）プロセスオイルは、通常は、合成ゴムの軟化剤
として用いられているものであり、一般に原油を、常圧
蒸留し、更に減圧蒸留後、溶剤精製法。(11) Process oil is usually used as a softener for synthetic rubber, and is generally produced by distilling crude oil under normal pressure and then distilling it under reduced pressure, followed by solvent refining.
水素化仕上法、水素化改質法、硫酸精製法等の適当な精
製工程を経て製造されるものが含まれる。This includes those produced through appropriate purification processes such as hydrofinishing, hydrogen reforming, and sulfuric acid refining.
これらのうち、例えば、原油を常圧蒸留した際得られる
重油留分を、減圧蒸留装置に通して得られる留出油を、
高温高圧下で触媒を用いて水添する、いわゆる水素化改
質法により、精製し、更にプロパン、ペンゾールケトン
、メチルエチルケトン等の溶剤による溶剤膜ろう等を経
て得られるプロセスオイルが好都合に用いられる。特に
好ましい例として、出光興産（株）製のプロセスオイル
ＰＳ−３２、同ＮＭ−２８０等の銘柄が挙げられる。こ
れに更に加えて用いてもよい添加剤であるイソブチレン
のオリゴマー、エチレンとα−オレフィンのコオリゴマ
ー、及び塩素化パラフィンは前記した通りである。（１
１）ブタジェン系オリゴマーとは、ブタジェンを数平均
分子量が５００〜４０００程度に重合して得られるもの
をいい、例えば、末端官能基を持たない式
（式中 ｌＯ≦ｎ≦７０）
で表わされるブタジェンホモオリゴマー及び例えば両末
端に第一ヒドロキシ基をもつ式
（式中 ｌＯ≦ｎ≦７０）
で表わされるブタジェンオリゴマー・グリコール、ある
いは両末端にカルボキシル基をもつ式（式中 ＩＯ≦ｎ
≦７０）
で表わされるブタジェンオリゴマー・ジカルボン酸等が
含まれる。上記の構造を持つオリゴマーとしては、例え
ば、ブタジェンを、リビング重合して得られ、分子量分
布がシャープで、重量平均分子量Ｍｙと数平均分子量Ｍ
ｎの比Ｍ Ｗ ／ Ｍ ｎがほとんど！１ｏ近い、Ｎｌ
５ＳＯＰＢ” Ｅ日本曹達（株）製］の各銘柄（ＮＩ
ＳＳＯ−ＰＢ Ｂ−１０００，同Ｂ−２０００，同Ｂ−
３０００、同Ｇ−１０００，同Ｇ−２０００，同Ｇ−３
０００，同Ｃ−１０００）が特に好ましい。これに更に
加えて用いてらよい、イソブチレンのオリゴマー、エチ
レンとα−オレフィンのオリゴマー、塩素化パラフィン
及びプロセスオイルは前記した通りである。Among these, for example, distillate oil obtained by passing the heavy oil fraction obtained when crude oil is distilled under atmospheric pressure through a vacuum distillation apparatus,
Process oils that are purified by the so-called hydroreforming method, in which hydrogenation is carried out using a catalyst under high temperature and high pressure, and then obtained through solvent film waxing with a solvent such as propane, penzole ketone, methyl ethyl ketone, etc., are conveniently used. . Particularly preferred examples include process oils such as PS-32 and NM-280 manufactured by Idemitsu Kosan Co., Ltd. The additives that may be used in addition to this, such as an oligomer of isobutylene, a cooligomer of ethylene and α-olefin, and a chlorinated paraffin, are as described above. (1
1) Butadiene-based oligomers refer to those obtained by polymerizing butadiene to a number average molecular weight of about 500 to 4,000. Gen homooligomers and butadiene oligomer glycols having the formula (in the formula IO≦n≦70) having primary hydroxyl groups at both ends, or butadiene oligomers/glycols having carboxyl groups at both ends (in the formula IO≦n
≦70) Butadiene oligomers and dicarboxylic acids represented by the following formula are included. For example, the oligomer having the above structure is obtained by living polymerization of butadiene, has a sharp molecular weight distribution, has a weight average molecular weight My and a number average molecular weight M.
The ratio of n is almost M W / M n! Close to 1o, Nl
5SOPB” E manufactured by Nippon Soda Co., Ltd.)
SSO-PB B-1000, B-2000, B-
3000, G-1000, G-2000, G-3
000, C-1000) are particularly preferred. The oligomers of isobutylene, oligomers of ethylene and α-olefin, chlorinated paraffin, and process oil that may be used in addition to these are as described above.
これら添加剤の添加量は、特に制限されないが、単独に
添加される場合は、当該添加剤の添加量が、複数添加さ
れる場合は、その併せた添加量が粉剤１００重量部に対
して０．１ないし１０重量部好ましくは０．２ないし５
．０重量部使用するのが特に効果的である。The amount of these additives to be added is not particularly limited, but when added singly, the amount of the additive is 0.0% when multiple additives are added to 100 parts by weight of the powder. .1 to 10 parts by weight, preferably 0.2 to 5 parts by weight
．． It is particularly effective to use 0 parts by weight.
本発明において、使用される農薬活性成分は殺虫、殺菌
、除草などの活性を有するもので、施用時ドリフト性を
軽減させる必要のある農薬粉剤ならば、すべて本発明の
技術を適用することが出来、特に制限はされないが、例
えば次のような化合物があげられる。ビスチオリン酸
０．０−ジメチル二〇−４−ニトロ−ｍ−）ジル。フェ
ニルホスホノチオン酸〇−エチル＝０−ｐ−ニトロフェ
ニル、チオリン酸０−２．３−ジヒドロ−３−オキソ−
２−フェニル−６−ピリダジニル＝０．０−ジエチル、
ジチオリン酸Ｓ−１，２−ビス（エトキジカルボニル）
エチル二〇、○−ジメチル、ジチオリン酸 Ｓ−［α−
（エトキシカルボニル）ペンジルコ＝０．０−ジメチル
、ジチオリン酸０．０−ジメチル＝Ｓ−（Ｎ−メチルカ
ルバモイルメチル）。In the present invention, the agrochemical active ingredient used has activities such as insecticidal, bactericidal, and herbicidal, and the technology of the present invention can be applied to all agrochemical powders that need to reduce drift during application. Although not particularly limited, examples include the following compounds. bisthiophosphoric acid
0.0-dimethyl20-4-nitro-m-)dyl. 〇-Ethyl phenylphosphonothionate = 0-p-nitrophenyl, 0-2.3-dihydro-3-oxo-thiophosphoric acid
2-phenyl-6-pyridazinyl=0.0-diethyl,
S-1,2-bis(ethoxydicarbonyl) dithiophosphate
Ethyl 20, ○-dimethyl, dithiophosphoric acid S-[α-
(Ethoxycarbonyl)penzylco=0.0-dimethyl, 0.0-dimethyl dithiophosphate=S-(N-methylcarbamoylmethyl).
Ｎ−アセチルホスホロアミドチオール酸 ｏ、Ｓ−ジメ
チル（以下アセフェートと称する）、２，２゜２−トリ
クロロ−１−ヒドロキシエチルホスホン酸ジメチル、メ
チルカルバミド酸 ０−５ｅｃ−ブチルフェニル（以下
ＢＰＭＣと称する）、メチルカルバミド酸ｌ−ナフチル
、メチルカルバミド酸ｍ−トリル、メチルカルバミド酸
０−クメニル（以下Ｍ Ｉ Ｐ Ｃと称する）、ビス（
チオカルバミン酸）Ｓ、Ｓ’−［２−（ジメチルアミノ
）トリメチレン〕（以下カルタップと称する）、テトラ
クロロイソフタロニトリル、チオリン酸 Ｓ−ベンジル
−０１Ｏ−ジイソプロピル、ジチオリン酸 〇−エチル
＝Ｓ、Ｓ−ジフェニル、プラストサイジンＳ、カスガマ
イシン、バリダマイシンＡ、Ｓ、Ｓ’−２−ジメチルア
ミノトリメチレンジ（ベンゼンチオスルホネート）（以
下ベンスルタップと略称する）、２−（４−エトキシフ
ェニル）−２−メチルプロピル３−フェノキシベンジル
エーテル（以下エトフェンブロックスと略称する）、リ
ン酸２−クロロ−１−（２，４−ジクロロフェニル）ビ
ニルニジエチル等があげられる。しかし本発明はこれら
の例示に制限されるものではない。又これらは適宜目的
に応じ単独で用いても又二種以上を組み合せて用いても
よい。これら活性成分は通常、単独で用いる場合は、当
該単独の活性成分の使用量が複数種を併用する場合は、
その全量が粉剤１００重量部に対し０．０００１ないし
５０重量部、好ましくは０．００１ないし２０重承部
用いられるが、その使用量は特に制限されるものではな
い。o,S-dimethyl N-acetylphosphoramidothiolate (hereinafter referred to as acephate), dimethyl 2,2゜2-trichloro-1-hydroxyethylphosphonate, 0-5ec-butylphenyl methylcarbamate (hereinafter referred to as BPMC) ), l-naphthyl methylcarbamate, m-tolyl methylcarbamate, 0-cumenyl methylcarbamate (hereinafter referred to as M I P C), bis(
thiocarbamic acid) S, S'-[2-(dimethylamino)trimethylene] (hereinafter referred to as cartap), tetrachloroisophthalonitrile, S-benzyl-01O-diisopropyl thiophosphate, 〇-ethyl dithiophosphate = S, S -Diphenyl, plasticidin S, kasugamycin, validamycin A, S, S'-2-dimethylaminotrimethylene di(benzenethiosulfonate) (hereinafter abbreviated as bensultap), 2-(4-ethoxyphenyl)-2-methyl Examples include propyl 3-phenoxybenzyl ether (hereinafter abbreviated as ethofenbrox), 2-chloro-1-(2,4-dichlorophenyl)vinylnidiethyl phosphate, and the like. However, the present invention is not limited to these examples. Further, these may be used alone or in combination of two or more depending on the purpose. When these active ingredients are used alone, the usage amount of the single active ingredient is usually the same as when multiple types are used in combination.
The total amount used is 0.0001 to 50 parts by weight, preferably 0.001 to 20 parts by weight, per 100 parts by weight of the powder, but the amount used is not particularly limited.
鉱物質粉状担体成分としては特に制限はされないがより
具体的には、たとえばクレイ、カオリン、ベントナイト
、酸性白土、タルク類（滑石粉、ロウ石粉など）、シリ
カ類（ホワイトカーボン、珪藻土、雲母粉など）及び炭
酸カルシウムが繁用される。Mineral powder carrier components are not particularly limited, but more specifically include clay, kaolin, bentonite, acid clay, talcs (talc powder, waxite powder, etc.), silicas (white carbon, diatomaceous earth, mica powder, etc.). etc.) and calcium carbonate are frequently used.
本発明の農薬粉剤には上記添加剤による効果をそこなわ
ない安定剤、展着剤、防腐剤等を適宜加えてもよい。こ
のような安定剤としては、例えば、リン酸、イソプロピ
ルアシドホスフェート［日本化学（株）製、以下ＰＡＰ
と称するｌ ＥＤＴＡ（エチレンジアミン四酢酸）、エ
ポキシ化アマニ油。A stabilizer, a spreading agent, a preservative, etc. may be added to the agrochemical powder of the present invention, as appropriate, without impairing the effects of the above-mentioned additives. Examples of such stabilizers include phosphoric acid, isopropyl acid phosphate [manufactured by Nippon Kagaku Co., Ltd., hereinafter referred to as PAP]
EDTA (ethylenediaminetetraacetic acid), epoxidized linseed oil.
チオ尿素、ホウ酸等が、防腐剤としては、ソルビン酸、
ソルビン酸カリウム、デバイドロ酢酸、デバイドロ酢酸
ナトリウム塩、ｐ−オキシ安息香酸ブチルエステル等が
又、展着剤としては、アルキルベンゼンスルホン酸塩、
ジオクチルスルホコハク酸ナトリウム塩、ポリオキシエ
チレンアルキルエーテル等がそれぞれ挙げられる。Thiourea, boric acid, etc. are used as preservatives, and sorbic acid,
Potassium sorbate, debaydoacetic acid, sodium debaydoacetate, p-oxybenzoic acid butyl ester, etc. are also used as spreading agents, and alkylbenzene sulfonates,
Examples include dioctyl sulfosuccinic acid sodium salt and polyoxyethylene alkyl ether.
本発明の農薬粉剤は、例えば、次のように製造される。The agrochemical powder of the present invention is produced, for example, as follows.
鉱物質粉状担体、及び農薬活性成分に、本発明の前記炭
化水素系粘性稠液体（ｉ）〜（ｉｉｉ）を適宜注加して
、混合する。次いで、鉱物質粉状担体並びに／又は、増
量・希釈剤を適量加えて、更に、昆合し、粗粉砕して、
農薬粉剤を得る。上記混合においては、例えば、ナＩク
ターミキサー（細則ミクロン（株）製）が、好ましく用
いられ、又粗粉砕に際しては、例えば、ハンマーミキサ
ーが好都合に用いられる。The hydrocarbon viscous liquids (i) to (iii) of the present invention are appropriately added to the mineral powder carrier and the agricultural chemical active ingredient and mixed. Next, an appropriate amount of a mineral powder carrier and/or a bulking/diluent is added, and the mixture is further kneaded and coarsely ground.
Obtain pesticide powder. For the above-mentioned mixing, for example, a Natal mixer (manufactured by Hosei Micron Co., Ltd.) is preferably used, and for coarse pulverization, for example, a hammer mixer is conveniently used.
作用
本発明において、添加される前記炭化水素系粘稠性液体
は、農薬粉剤に湿潤性を与え、特にドリフト発生に問題
となるｌＯμ以下の粒子の飛散や浮遊を完全に抑えられ
る。更に、本発明においては、粒子を粗大に造粒する等
の手段は施こす必要はなく、かつ前記特定添加剤はいず
れも、粉剤の流動性１分散性、付着性を著しくそこなう
ことなく、これら農薬粉剤として必要な、粉体物性を満
たすため、適宜粒度を下げることも可能である。Function In the present invention, the hydrocarbon-based viscous liquid added imparts wettability to the agrochemical powder, and can completely suppress the scattering and floating of particles of 1Oμ or less, which especially cause problems in the occurrence of drift. Furthermore, in the present invention, there is no need to take measures such as coarsely granulating the particles, and all of the above-mentioned specific additives can be used without significantly impairing the fluidity, dispersibility, or adhesion of the powder. In order to satisfy the powder physical properties required for an agricultural chemical powder, it is also possible to reduce the particle size as appropriate.
一方、農薬活性成分が、不安定な場合、とりわけ、水に
不安定な成分については、本発明の農薬粉剤に適用され
た場き、生物活性の向上が著しい。On the other hand, when the agrochemical active ingredient is unstable, especially a water-unstable ingredient, when applied to the agrochemical powder of the present invention, the biological activity is significantly improved.
これら水に不安定な成分は、一般にクレー等の鉱物質粉
状担体と混合、接触した際にこれら担体の付着水分によ
って分解され易く、貯蔵安定性や薬効の点で、短点があ
るが、前記粘稠液体を添加する本発明の農薬粉剤におい
ては、かかる添加剤による油膜により活性成分が、保護
されクレー等担体の持つ水による分解が防がれ、安定性
が改良される結果、薬効が向上するものと推察される。Generally, these water-unstable components are easily decomposed by moisture attached to mineral powder carriers such as clay when they are mixed with or come into contact with mineral powder carriers, so they have shortcomings in terms of storage stability and medicinal efficacy. In the agrochemical powder of the present invention in which the above-mentioned viscous liquid is added, the active ingredient is protected by the oil film formed by the additive and prevented from being decomposed by the water contained in the carrier such as clay, improving the stability and improving the medicinal efficacy. It is assumed that this will improve.
かくして、特にベンスルタップ、カルタップ。Thus, especially Bensurtap, Kartap.
アセフェートあるいはバリダマイシン等で代表される水
に不安定な農薬活性成分を含有する農薬粉剤の製造にあ
たって、本発明を適用した場合にドリフトを抑えかつ生
物活性を改良するという本発明の効果が顕著といえる。When the present invention is applied to the production of agrochemical powders containing water-unstable agricultural active ingredients such as acephate or validamycin, it can be said that the effects of the present invention in suppressing drift and improving biological activity are remarkable. .
実施例
以下、本発明の詳細な説明するが、本発明は実施例によ
り、何ら制限されるものではない。EXAMPLES The present invention will be described in detail below, but the present invention is not limited by the Examples.
文中単に部とあるのは、すべて重量部を示す。All parts in the text indicate parts by weight.
実施例１
ナウターミキサ−（線用ミクロン（味）製）に農薬用微
粉クレー３部及びベンスルタップ原体２．５部を加えＩ
Ｐソルベント−２８３５０，２５部、ルーカントＨＣ−
４００，５部を成功して５分間混合する。Example 1 Add 3 parts of finely powdered clay for agricultural chemicals and 2.5 parts of Bensultap raw material to a Nauta mixer (manufactured by Micron (Aji) for wires).
P Solvent-28350, 25 parts, Lucant HC-
Mix 400.5 parts successfully for 5 minutes.
次いでホワイトカーボン０．５部及び農薬用微粉クレー
９３．２５部を加えて更にｌＯ分間混合し、ハンマーミ
ルで粗粉砕して本発明の農薬粉剤を得る。Next, 0.5 part of white carbon and 93.25 parts of finely powdered clay for agricultural chemicals are added, mixed for an additional 10 minutes, and coarsely pulverized with a hammer mill to obtain the agricultural chemical powder of the present invention.
実施例２
ナウターミキサ−（線用ミクロン（株）製）に農薬用微
粉クレー５部及びベンスルタップ原体２．５部。Example 2 5 parts of finely powdered clay for agricultural chemicals and 2.5 parts of Bensultap raw material were placed in a Nauta mixer (manufactured by Line Micron Co., Ltd.).
ＭＩＰＣ原体２．０部を加３ＩＰソルベント−２８３５
２，５部、ルーカント）（Ｃ−２００００，３０部を成
功して５分間混合する。次いでホワイトカーボン１．０
部、ＰＡＰ Ｑ、５部及び農薬用微粉クレー８６２部を
加えて更に１０分間混合し、ハンマーミルで粗粉砕して
本発明の農薬粉剤を得る。Add 2.0 parts of MIPC technical substance to 3IP Solvent-2835
2.5 parts of Lucant) (C-20000, 30 parts are successfully mixed for 5 minutes. Then white carbon 1.0
1 part, PAP Q, 5 parts, and 862 parts of agrochemical fine powder clay were added thereto, mixed for further 10 minutes, and coarsely ground with a hammer mill to obtain the agrochemical powder of the present invention.
実施例３
ナウターミキサ−（線用ミクロン（株）製）に農薬用微
粉クレー３．５部及びベンスルタップ原体２．５部。Example 3 3.5 parts of fine powdered clay for agricultural chemicals and 2.5 parts of Bensultap raw material were added to a Nauta mixer (manufactured by Line Micron Co., Ltd.).
Ｂ Ｐ Ｍ Ｃ原体３．５部を加えＩＰソルベント−２
８３５０，７５部、ルーカントＨＣ−２００００，４部
を成功して５分間混合する。次いでホワイトカーボン０
．３部、ＰＡＰ Ｏ，５部及び農薬用微粉クレー８８．
５５部を加えて更に１０分間混合し、ハンマーミルで粗
粉砕して本発明の農薬粉剤を得る。Add 3.5 parts of B PMC original substance and IP solvent-2
75 parts of Lucant HC-20000 and 4 parts of Lucant HC-20000 are successfully mixed for 5 minutes. Then white carbon 0
．． 3 parts, PAP O, 5 parts and fine powder clay for agricultural chemicals 88.
55 parts of the mixture were added, mixed for an additional 10 minutes, and coarsely ground using a hammer mill to obtain the agrochemical powder of the present invention.
実施例４
ナウターミキサ−（線用ミクロン（株）製）に農薬用微
粉クレー２部及びベンスルタップ原体２．０部及びパリ
ダマ、ｆシンＡ原体０．３部を加えＩＰソルベント−２
８３５１，２部、ルーカントＨＣ−２００，５５部を成
功して５分間混合する。次いでホワイトカーボン１，０
部及び農薬用微粉クレー９４７部を加えて更に１０分間
混合し、ハンマーミルで粗粉砕して本発明の農薬粉剤を
得る。Example 4 2 parts of fine clay for agricultural chemicals, 2.0 parts of Bensultap drug substance, and 0.3 parts of Pallidama and f-Syn A drug substance were added to a Nauta mixer (manufactured by Line Micron Co., Ltd.) to prepare IP Solvent-2.
2 parts of Lucant HC-200 and 55 parts of Lucant HC-200 are successfully mixed for 5 minutes. Then white carbon 1,0
1 part and 947 parts of finely powdered clay for agricultural chemicals were added thereto, mixed for further 10 minutes, and coarsely ground with a hammer mill to obtain the agricultural chemical powder of the present invention.
実施例５
ナウターミキサ−（線用ミクロン（株）製）に農薬用微
粉クレー５部及びベンスルタップ原体２．０部並びにエ
トフェンブロックス原体０．５部を加えＩＰソルベント
−２８３５１，５部、ルーカントＨＣ−６０００，７５
部を成功して５分間混合する。次いでホワイトカーボン
１．５部及び農薬用微粉クレー８８．７５部を加えて更
に１０分間混合し、ハンマーミル咀粉砕して本発明の農
薬粉剤を得る。Example 5 In a Nauta mixer (manufactured by Line Micron Co., Ltd.), 5 parts of fine clay for agricultural chemicals, 2.0 parts of Bensultap raw material, and 0.5 part of Ethofenbrox raw material were added, and 5 parts of IP Solvent-28351 and Lucant were added. HC-6000,75
Mix well for 5 minutes. Next, 1.5 parts of white carbon and 88.75 parts of finely powdered clay for agricultural chemicals were added, mixed for further 10 minutes, and crushed using a hammer mill to obtain the agricultural chemical powder of the present invention.
実施例６
ナウターミキサ−（線用ミクロン（株）製）に農薬用微
粉クレー３．５部及びベンスルタップ原体２．５部。Example 6 3.5 parts of agrochemical fine powder clay and 2.5 parts of Bensultap raw material were added to a Nauta mixer (manufactured by Line Micron Co., Ltd.).
エトフエンブロックス原体０５部を加えＩＰソルベント
−２０２８２，０部、ルーカントＨＣ−２０１，５部を
成功して５分間混合する。次いでホワイトカーボン２．
０部及び農薬用微粉クレー８８部を加えて更にｌＯ分間
混合し、ハンマーミルで粗粉砕して本発明の農薬粉剤を
得る。Add 05 parts of Etofenebrox raw material, 0 parts of IP Solvent-20282, and 1.5 parts of Lucant HC-20 and mix for 5 minutes. Next, white carbon 2.
0 parts and 88 parts of finely powdered clay for pesticides are added, mixed for further 10 minutes, and coarsely ground with a hammer mill to obtain the pesticide powder of the present invention.
実施例７
ナウターミキサ−（線用ミクロン（株）製）に農薬用微
粉クレー５部及びベンスルタップ原体２．５部を加えル
ーカントＨＣ−６００３，３部を成功して５分間、見合
する。次いでホワイトカーボン１．０部及び農薬用微粉
クレー９０．７部を加えて更に１０分間混合し、ハンマ
ーミルで粗粉砕して本発明の農薬粉剤を得る。Example 7 5 parts of finely powdered clay for agricultural chemicals and 2.5 parts of Bensultap raw material were added to a Nauta mixer (manufactured by Line Micron Co., Ltd.), 3 parts of Lucant HC-6003 were added, and the mixture was mixed for 5 minutes. Next, 1.0 part of white carbon and 90.7 parts of finely powdered clay for pesticides are added, mixed for further 10 minutes, and coarsely ground with a hammer mill to obtain the pesticide powder of the present invention.
実施例８
ナウターミキサ−（ｍ用ミクロン（株）製）に農薬用微
粉クレー３部及びベンスルタップ原体１．０部。Example 8 3 parts of fine powder clay for agricultural chemicals and 1.0 part of Bensultap raw material were added to a Nauta mixer (manufactured by Micron Co., Ltd. for m).
Ｍ Ｉ Ｐ Ｃ原体２．０部を加えＩＰソルベント−２
０２８０，３部、ルーカント！（Ｃ−６０００，３部及
びトヨバラックスＡ−４０１，０部を圧加して５分間混
合する。次いでホワイトカーボン２．０部及び農薬用微
粉クレー９０．４部を加えて更に１００分間混し、ハン
マーミルで粗粉砕して本発明の農薬粉剤を得る。Add 2.0 parts of MIP C active substance to IP Solvent-2.
0280, Part 3, Lucant! (3 parts of C-6000 and 1.0 parts of Toyovarax A-400 are mixed under pressure for 5 minutes. Then, 2.0 parts of white carbon and 90.4 parts of fine powder clay for agricultural chemicals are added and mixed for an additional 100 minutes. The agrochemical powder of the present invention is obtained by coarsely grinding with a hammer mill.
実施例９
ナウターミキサ−（細川ミクロン（株）製）に農薬用微
粉クレー３部及びカルタップ塩酸塩原体１．５部を加え
ルーカントＩＣ−４０１，５部、トヨバラックス１５０
１．０部を圧加して５分間混合する。次いでＰＡＰ
Ｏ，５部、ホワイトカーボン２，０部及び農薬用微粉
クレー９０．５部を加えて更にｌＯ０分間混し、ハンマ
ーミルで粗粉砕して不発明の農薬粉剤を得る。Example 9 3 parts of fine clay for agricultural chemicals and 1.5 parts of Cartap hydrochloride raw material were added to a Nauta mixer (manufactured by Hosokawa Micron Co., Ltd.), and 1.5 parts of Lucant IC-401 and Toyobarax 150 were added.
Add 1.0 part under pressure and mix for 5 minutes. Then P.A.P.
5 parts of O, 2.0 parts of white carbon, and 90.5 parts of finely powdered clay for agricultural chemicals are added, mixed for further 10 minutes, and coarsely pulverized with a hammer mill to obtain a non-inventive agricultural chemical powder.
実施例１Ｏ
ナウターミキサ−（細川ミクロン（株）製）に農薬用微
粉クレー３部及びカルタップ塩酸塩原体２．５ｉ、ＭＩ
Ｐｃ原体２．５部を加えプロセスオイルＰＳ−３２２部
及びトヨバラックス１４５ ０．８部を圧加して５分間
混合する。次いでホワイトカーボン１．５部及び農薬用
微粉クレー８７７部を加えて更にｌＯ０分間混し、・＼
ンマーミル徂粉砕して本発明の農薬粉剤を得る。Example 1O In a Nauta mixer (manufactured by Hosokawa Micron Co., Ltd.), 3 parts of fine powdered clay for agricultural chemicals and 2.5i of Cartap hydrochloride raw material, MI
2.5 parts of Pc raw material is added, and 22 parts of process oil PS-32 and 0.8 parts of Toyovarax 145 are added and mixed for 5 minutes under pressure. Next, 1.5 parts of white carbon and 877 parts of finely powdered clay for agricultural chemicals were added, and the mixture was further mixed for 100 minutes.
The agrochemical powder of the present invention is obtained by pulverizing in a hummer mill.
実施例１１
ナウターミキサ−（細川ミクロン（味）製）に農薬用微
粉クレー３部及びカルタップ塩酸塩原体１．５部、ＢＰ
〜ＩＣ原体２．０部を加えプロセスオイルＮＭｌａｏ
１．２部及びルーカントＨＣ−１００，５部を圧加し
て５分間、足台する。次いでホワイトカーボン１．３部
及び農薬用微粉クレー９０．５部を加えて更にｌＯ０分
間混し、ハンマーミルで粗粉砕して本発明の農薬粉剤を
得る。Example 11 In a Nauta mixer (manufactured by Hosokawa Micron (Aji)), 3 parts of fine powder clay for agricultural chemicals and 1.5 parts of Cartap hydrochloride raw material, BP
~Add 2.0 parts of IC raw material to process oil NMlao
1.2 parts and 5 parts of Lucant HC-100 are pressurized and kept for 5 minutes. Next, 1.3 parts of white carbon and 90.5 parts of finely powdered clay for agricultural chemicals are added, mixed for further 100 minutes, and coarsely pulverized with a hammer mill to obtain the agricultural chemical powder of the present invention.
実施例１２
ナウターミキサ−（細川ミクロン（味）製）に農薬用微
粉クレー３部及びカルタップ塩酸塩原体２．０部、エト
フェンブロックス原体０．５部を加えＮｌ５ＳＯ−ＰＢ
Ｂ−２００００，５部及びＮｌ５ＳＯ−ＰＢ Ｇ−１０
０００７５部を圧加して５分間混合する。次いでホワイ
トカーボン１．２部及び農薬用微粉クレー９２０５部を
加えて更にｌＯ０分間混し、ハンマーミルで粗粉砕して
本発明の農薬粉剤を得る。Example 12 In a Nauta mixer (manufactured by Hosokawa Micron (Aji)), 3 parts of fine clay for agricultural chemicals, 2.0 parts of cartap hydrochloride raw material, and 0.5 part of etofenbrox raw material were added to Nl5SO-PB.
B-20000, 5 parts and Nl5SO-PB G-10
00075 parts under pressure and mix for 5 minutes. Next, 1.2 parts of white carbon and 9205 parts of finely powdered clay for pesticides were added, mixed for 100 minutes, and coarsely ground with a hammer mill to obtain the pesticide powder of the present invention.
実施例１３
ナウターミキサ−（細川ミクロン（株）製）に農薬用微
粉クレー３部及びヘンスルタップ原体２．５部。Example 13 3 parts of fine powder clay for agricultural chemicals and 2.5 parts of Hensultap raw material were placed in a Nauta mixer (manufactured by Hosokawa Micron Co., Ltd.).
ＭＩＰＣ原体２５部を加えＮｌ５ＳＯ−ＰＢ Ｃ−１０
０００８部及びＩＰソルヘント−２８３５０，８５部を
圧加して５分間混合する。次いでホワイトカーボン１５
部及び農薬用微粉クレー８８８５部を加えて更に１００
分間混し、ハンマーミルで粗粉砕して本発明の農薬粉剤
を得る。Add 25 parts of MIPC substance to Nl5SO-PB C-10
0008 parts and 85 parts of IP Solgent-28350 are mixed under pressure for 5 minutes. Then White Carbon 15
100 parts and 8885 parts of finely powdered clay for agricultural chemicals.
The mixture is mixed for a minute and coarsely ground using a hammer mill to obtain the agricultural chemical powder of the present invention.
実施例１．１
ナウターミキサ−（細川ミクロン（株）製）に農薬用微
粉クレー３部及びカルタップ塩酸塩原体２．５部を加え
ＩＰソルベント−２８３５０，２５部、ルーカントＨＣ
−４００，５部を注加してＰＡＰ Ｏ，５部を加え５
分間混合する。次いでホワイトカーボン０．５部及び農
薬用微粉クレー９３２５部を加えて更に１００分間混し
、ハンマーミルて粗粉砕して本発明の農薬粉剤を得る。Example 1.1 In a Nauta mixer (manufactured by Hosokawa Micron Co., Ltd.), 3 parts of fine clay for agricultural chemicals and 2.5 parts of Cartap hydrochloride raw material were added, and 25 parts of IP Solvent-28350 and Lucant HC were added.
- Add 400.5 parts and add 5 parts of PAP O.5
Mix for a minute. Next, 0.5 part of white carbon and 9325 parts of finely powdered clay for agricultural chemicals are added, mixed for an additional 100 minutes, and coarsely pulverized using a hammer mill to obtain the agricultural chemical powder of the present invention.
次に、本発明の効果を更に詳述するために、本発明に属
さない下記製剤と比較した試験例を示す。Next, in order to explain the effects of the present invention in more detail, test examples will be shown in comparison with the following formulations that do not belong to the present invention.
対照製剤例１
ナウターミキサ−（細川ミクロン（味）製）に農薬用微
粉クレー３部及びベンスルタップ原体２．５部を加え流
動パラフィンｒＷＩＴｃｏ Ｃｈｅｍｉｃａｌ Ｃｏｒ
ｐｏｒａ−ｔｉｏｎ（米国）製］ｏ、７５部を圧加して
５分間混合する。Control Formulation Example 1 3 parts of agrochemical fine clay and 2.5 parts of Bensultap raw material were added to a Nauta mixer (manufactured by Hosokawa Micron (Aji)), and liquid paraffin rWITco Chemical Cor was added.
[manufactured by Pora-tion (USA)] 75 parts were mixed under pressure for 5 minutes.
次いでホワイトカーボン０．５部及び農薬用微粉クレー
９３２５部を加えて更に１００分間混し、ハンマーミル
で粗粉砕して農薬粉剤を得る。Next, 0.5 part of white carbon and 9325 parts of finely powdered clay for agricultural chemicals are added, mixed for an additional 100 minutes, and coarsely ground with a hammer mill to obtain an agricultural chemical powder.
対照製剤例２
ナウターミキサ−（細川ミクロン（株）製）に農薬用微
粉クレー５部及びベンスルタップ原体２５部。Control Formulation Example 2 5 parts of agrochemical fine powder clay and 25 parts of bensultap raw material were added to a Nauta mixer (manufactured by Hosokawa Micron Co., Ltd.).
Ｍ Ｉ Ｐ Ｃ原体２．０部を加えポリブテン（銘柄１
００Ｈ；出光石油化学（株）製）２．８部を圧加して５
分間混合する。次いでホワイトカーボン１．０部、ＰＡ
Ｐ０５部及び農薬用微粉クレー８６２部を加えて更に１
００分間混し、ハンマーミルで粗粉砕して農薬粉剤を得
る。Add 2.0 parts of M I P C raw material and add polybutene (brand 1
00H; 2.8 parts (manufactured by Idemitsu Petrochemical Co., Ltd.) was pressurized to 5
Mix for a minute. Next, 1.0 part of white carbon, PA
Add 5 parts of P0 and 862 parts of fine powdered clay for agricultural chemicals, and add 1
Mix for 00 minutes and coarsely grind with a hammer mill to obtain agrochemical powder.
対照製剤例３
ナウターミキサー（細川ミクロン（株）製ンに農薬用微
粉クレー５部及びベンスルタップ原体２．５部。Control Formulation Example 3 Nauta Mixer (manufactured by Hosokawa Micron Co., Ltd.) contained 5 parts of finely powdered clay for agricultural chemicals and 2.5 parts of Bensultap raw material.
ＭＩＰＣ原体２．０部を加え流動パラフィンＣＮＩＴＣ
ＯＣｈｅｍｉｃａｌ Ｃｏｒｐｏｒａｔｉｏｎ（米国）
製］２．８部を注加して５分間混合する。次いでホワイ
トカーボン１０部。Add 2.0 parts of MIPC and liquid paraffin CNITC
O Chemical Corporation (USA)
Add 2.8 parts of the product and mix for 5 minutes. Next, 10 parts of white carbon.
ＰＡＰ Ｏ，５部及び農薬用微粉クレー８６．２部を
加えて更にＩＯ分間混合し、ハンマーミルで粗粉砕して
農薬粉剤を得る。5 parts of PAP O and 86.2 parts of finely powdered clay for agricultural chemicals are added, mixed for an additional 10 minutes, and coarsely pulverized with a hammer mill to obtain an agricultural chemical powder.
対照製剤例４
ナウターミキサ−（細川ミクロン（味）製）に農薬用微
粉クレー５部及びベンスルタップ原体２．５部を加え流
動パラフィン［ＷＩＴＣＯＣｈｅｍｉｃａｌ Ｃｏｒｐ
ｏｒａ−ｔｉｏｎ（米国）製コ３．３部を注加して５分
間混合する。Control Formulation Example 4 5 parts of fine clay for agricultural chemicals and 2.5 parts of Bensultap raw material were added to a Nauta mixer (manufactured by Hosokawa Micron (Aji)), and liquid paraffin [WITCO Chemical Corp.
Add 3.3 parts of Ora-tion (USA) and mix for 5 minutes.
次いでホワイトカーボン１．０部及び農薬用微粉クレー
８８．２部を加えて更にＩＯ分間混合し、ハンマーミル
で粗粉砕して農薬粉剤を得る。Next, 1.0 part of white carbon and 88.2 parts of finely powdered clay for agricultural chemicals are added, mixed for an additional 10 minutes, and coarsely ground with a hammer mill to obtain an agricultural chemical powder.
対照製剤例５
ナウターミキサ−（細川ミクロン（味）製）に農薬用微
粉クレー３部、カルタップ塩酸塩原体２．５部を加え流
動パラフィン［ＷＩＴＣＯＣｈｅｍｉｃａｌ Ｃｏｒｐ
ｏｒａ−ｔｉｏｎ（米国）製］０．７５部を注加して５
分間混合する。Control Formulation Example 5 3 parts of agrochemical fine clay and 2.5 parts of Cartap hydrochloride raw material were added to a Nauta mixer (manufactured by Hosokawa Micron (Aji)), and liquid paraffin [WITCO Chemical Corp.
ora-tion (USA)] by adding 0.75 parts.
Mix for a minute.
次いでホワイトカーボン０．５ｗＪ及び農薬用微粉クレ
ー９３２５部を加えて更に１０分間混合し、ハンマーミ
ルで粗粉砕して農薬粉剤を得る。Next, 0.5 wJ of white carbon and 9325 parts of finely powdered clay for agricultural chemicals are added, mixed for further 10 minutes, and coarsely ground with a hammer mill to obtain an agricultural chemical powder.
試験例１ 浮遊性指数
農薬粉剤を圃場で散布した時見掛の飛散性を定量的に表
現するため、昭和５５年１０月３日付にて農林水産省農
薬検査所より指示されたｒＤＬ粉剤新規申請に必要な提
出資料について」に記載の浮遊性指数測定法により浮遊
性指数を測定し、その結果を表１に示した。Test Example 1 Floatability Index In order to quantitatively express the apparent scattering properties of pesticide powders when sprayed in fields, a new application for rDL powder was ordered by the Agriculture, Forestry and Fisheries Ministry of Agriculture, Forestry and Fisheries Pesticide Inspection Center on October 3, 1981. The buoyancy index was measured using the buoyancy index measurement method described in ``Required Submission Materials'', and the results are shown in Table 1.
（以下余白）
表１
試験例２ 有効成分の飛散性
試験例１で浮遊性を、１１１足した同じ装置を用いて１
４０ｃｍ）から空気を３０Ｑ吸引し、有効成分を捕集し
定量して、有効成分の飛散性を調べその結果を表２に示
した。(Leaving space below) Table 1 Test Example 2 Active ingredient scattering properties Using the same equipment in which 111 was added to the floating properties in Test Example 1, 1
30Q of air was suctioned from 40 cm), the active ingredient was collected and quantified, and the scattering properties of the active ingredient were examined. The results are shown in Table 2.
表２
試験例３ 有効成分の安定性
実施例に示した本発明による改良された農薬粉剤及び対
照製剤をそれぞれ・１０°Ｃ恒温器中で３０し、分解率
を求め、その結果を表３に示した。Table 2 Test Example 3 Stability of Active Ingredients The improved pesticide powder according to the present invention shown in the example and the control formulation were each incubated in a 10°C thermostat to determine the decomposition rate, and the results are shown in Table 3. Indicated.
表３
試験例４ 殺虫効力試験
１０．０００分の１アールのポットに植えた移植５０日
後（草丈６０ｃｍ）のイネ（品種中生新千本）をベルツ
ヤ−ダスター（内径３０ｃｍ、高さ５０ｃｍ）内に立て
、真空ポンプで６０ ｃｍＨｇに減圧して散布した。Table 3 Test Example 4 Insecticidal Efficacy Test Rice (variety Nakasei Shinsenbon) 50 days after transplantation (plant height 60 cm) planted in a 1/10.000 are pot was placed in a Beltsya Duster (inner diameter 30 cm, height 50 cm). The spray was applied under reduced pressure of 60 cmHg using a vacuum pump.
散布後２時間してイネの茎葉部を切り取りポリカップ（
内径１０．５ｃ＋ａ、高さ６ ｃｍ）に入れそこへアワ
ヨトウ幼虫（３令）をイネ１株当り１０頭を放ち殺虫効
力を調べ表４に示した。Two hours after spraying, cut off the stems and leaves of the rice plants and place them in polycups (
10 fall armyworm larvae (3rd instar) per rice plant were released into the rice pot (inner diameter 10.5c+a, height 6cm), and the insecticidal efficacy was determined and shown in Table 4.
表４
注、ポット当り有効成分として２００ｍｇ散布した時の
試験成績を示す。Table 4 Note: Test results are shown when 200 mg of the active ingredient was sprayed per pot.
本発明による改良製剤の浮遊性指数は表１に示す通り良
好である。本発明者らは更に研究を続け、有効成分の飛
散性についても測定上の工夫をこらし測定した結果、表
２に示した通り、本発明の改良製剤は、飛散性が顕著に
改善されており、有効成分の植物体への付着性良好なこ
とがわかる。このことは表３に示す本発明品の有効成分
の分解率が少ないことと合わせて、本発明の改良粉剤の
殺虫効力が高まった原因と推察される。The floatability index of the improved formulation according to the present invention is good as shown in Table 1. The present inventors continued their research and measured the dispersibility of the active ingredient by devising a measurement method.As shown in Table 2, the improved formulation of the present invention has significantly improved dispersibility. It can be seen that the adhesion of the active ingredient to the plant body is good. This, together with the low decomposition rate of the active ingredient of the product of the present invention shown in Table 3, is presumed to be the reason for the increased insecticidal efficacy of the improved powder of the present invention.
発明の効果
府記試験例からも明らかなように特定粘稠性液体を含有
する本発明の農薬粉剤は、人や家畜をはじめ動植物に対
する悪影響が問題となっているドリフトを、粒度を調節
することにより防止する方法あるいは、流動パラフィン
やポリブテン等を添加して、抑止する従来の方法に比べ
、低コストで植物体上での付着性、展着性、吸収性がそ
こなわれることなく、優れた生物活性を有し、かつ飛散
性、浮遊性を低減してドリフトが抑えられるという効果
を有する。加えて、本発明の農薬粉剤は農薬活性成分の
分解が防止され、貯蔵安定性や薬効が向上するという予
想外の効果も有する。Effects of the Invention As is clear from the test examples, the agrochemical powder of the present invention containing a specific viscous liquid has the ability to control particle size to prevent drift, which has been a problem with adverse effects on humans, livestock, and other animals and plants. Compared to the conventional method of deterring by adding liquid paraffin, polybutene, etc., it is lower cost and has excellent adhesion, spreadability, and absorption on the plant body. It has biological activity and has the effect of reducing scattering and floating properties and suppressing drift. In addition, the agrochemical powder of the present invention has the unexpected effect of preventing the decomposition of the agrochemical active ingredient and improving storage stability and medicinal efficacy.
Claims (1)
とα−オレフィンのコオリゴマーを含有することを、特
徴とする農薬粉剤 ２）さらにイソブチレンのオリゴマーおよび、塩素化パ
ラフィンの一種又は、両者を含有していてもよい、特許
請求の範囲第一項記載の農薬粉剤[Scope of Claims] 1) A pesticide powder characterized by containing an agrochemical active ingredient, a mineral powder carrier, and a cooligomer of ethylene and α-olefin 2) An oligomer of isobutylene and a chlorinated paraffin The agricultural chemical powder according to claim 1, which may contain one or both of the following:
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8626686 | 1986-04-14 | ||
| JP61-86266 | 1986-04-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6345203A true JPS6345203A (en) | 1988-02-26 |
| JP2515541B2 JP2515541B2 (en) | 1996-07-10 |
Family
ID=13882015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62089313A Expired - Fee Related JP2515541B2 (en) | 1986-04-14 | 1987-04-10 | Pesticide powder |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2515541B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0629346A2 (en) * | 1993-06-16 | 1994-12-21 | Sumitomo Chemical Company, Limited | Pesticidal compositions |
| US6463639B1 (en) | 1998-06-23 | 2002-10-15 | Kabushiki Kaisha Tokai-Rika-Denki-Siesakusho | Buckle |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101032256B (en) * | 2007-04-13 | 2010-06-02 | 彭国均 | Pesticide of composite jinggangmycin |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57159701A (en) * | 1981-03-27 | 1982-10-01 | Hokko Chem Ind Co Ltd | Improved dust of agricultural chemical |
-
1987
- 1987-04-10 JP JP62089313A patent/JP2515541B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57159701A (en) * | 1981-03-27 | 1982-10-01 | Hokko Chem Ind Co Ltd | Improved dust of agricultural chemical |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0629346A2 (en) * | 1993-06-16 | 1994-12-21 | Sumitomo Chemical Company, Limited | Pesticidal compositions |
| FR2706247A1 (en) * | 1993-06-16 | 1994-12-23 | Sumitomo Chemical Co | Method for stabilizing pesticidal compositions containing acephate, and pesticidal compositions obtained. |
| EP0629346A3 (en) * | 1993-06-16 | 1995-04-26 | Sumitomo Chemical Co | Pesticidal compositions. |
| US6335026B1 (en) * | 1993-06-16 | 2002-01-01 | Sumitomo Chemical Co., Ltd. | Pesticidal compositions |
| US6463639B1 (en) | 1998-06-23 | 2002-10-15 | Kabushiki Kaisha Tokai-Rika-Denki-Siesakusho | Buckle |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2515541B2 (en) | 1996-07-10 |
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