JPS6342933A - Production of decorative compression white noble metal yarn - Google Patents
Production of decorative compression white noble metal yarnInfo
- Publication number
- JPS6342933A JPS6342933A JP18169686A JP18169686A JPS6342933A JP S6342933 A JPS6342933 A JP S6342933A JP 18169686 A JP18169686 A JP 18169686A JP 18169686 A JP18169686 A JP 18169686A JP S6342933 A JPS6342933 A JP S6342933A
- Authority
- JP
- Japan
- Prior art keywords
- compressed
- silver
- precious metal
- white
- diameter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 229910000510 noble metal Inorganic materials 0.000 title description 14
- 230000006835 compression Effects 0.000 title description 7
- 238000007906 compression Methods 0.000 title description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 66
- 239000010970 precious metal Substances 0.000 claims description 36
- 229910052709 silver Inorganic materials 0.000 claims description 33
- 239000004332 silver Substances 0.000 claims description 33
- 229910052697 platinum Inorganic materials 0.000 claims description 31
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 238000005491 wire drawing Methods 0.000 claims description 7
- 238000005034 decoration Methods 0.000 claims description 4
- 229920005992 thermoplastic resin Polymers 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 38
- 239000010410 layer Substances 0.000 description 23
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 15
- 229910052737 gold Inorganic materials 0.000 description 15
- 239000010931 gold Substances 0.000 description 15
- 239000004744 fabric Substances 0.000 description 13
- 239000003973 paint Substances 0.000 description 13
- 244000062175 Fittonia argyroneura Species 0.000 description 12
- 229920003002 synthetic resin Polymers 0.000 description 12
- 239000000057 synthetic resin Substances 0.000 description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 241000218202 Coptis Species 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000009941 weaving Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000010946 fine silver Substances 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241001085205 Prenanthella exigua Species 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000001055 blue pigment Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- DLMVDBDHOIWEJZ-UHFFFAOYSA-N isocyanatooxyimino(oxo)methane Chemical compound O=C=NON=C=O DLMVDBDHOIWEJZ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000002991 Coptis groenlandica Nutrition 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000001062 red colorant Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008733 trauma Effects 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Landscapes
- Wire Processing (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は織編物に使用する高純度の銀又は白金細線を用
いた装飾用白色貴金属系の製造方法に関する。より詳し
くは、高純度の銀又は白金細線を同心撚りしたものを、
その外径より小さい径の線引きダイスに通して円型に圧
縮し、外層の線間に凹部を設け、該凹部に着色性合成樹
脂又は塗料を充填してその外観に白銀色との色縞模様を
スパイラル状に形成することを特徴とする装飾用白色貴
金属系の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for producing a decorative white precious metal using fine silver or platinum wire of high purity for use in woven or knitted fabrics. More specifically, high-purity silver or platinum thin wires are concentrically twisted.
It is passed through a wire drawing die with a diameter smaller than its outer diameter and compressed into a circular shape, with recesses formed between the wires of the outer layer, and the recesses are filled with a colored synthetic resin or paint to create a white-silver colored striped appearance. The present invention relates to a method for manufacturing a white noble metal for decoration, which is characterized by forming the metal in a spiral shape.
(従来技術)
従来より金銀糸を作る方法としては雁皮祇に金銀箔を貼
着したものを細長に細截し芯糸に巻付けたり、下撚りを
施した片撚糸に金銀粉を混和した糊状液を糊付けし、乾
燥して強撚りの上撚りを施したり、基体シート上に金銀
を真空蒸着した後、その上に合成樹脂塗料で保護層を設
けたものを細長に細截して芯糸に巻付けたものが知られ
ている。(Prior art) Conventional methods for making gold and silver thread include gampi gi pasted with gold and silver foil, cut into thin strips and wrapped around a core thread, and glue mixed with gold and silver powder in single-stranded thread that has been pre-twisted. After pasting the liquid and drying it and giving it a strong ply twist, gold and silver are vacuum-deposited on the base sheet, a protective layer is provided on top with a synthetic resin paint, and then the core is cut into thin strips. It is known to be wrapped around a thread.
(発明が解決しようとする問題点)
前記に述べたように、雅皮紙に金銀箔を貼着するか、又
は基体シート上に金銀を真空蒸着させたものを細長に裁
断した金銀糸は、外観が装飾的にすぐれていても、前者
の場合には均一厚の金銀箔の製造が高価につき、且つ金
銀箔を貼着するのに特殊な技術が必要である。後者の場
合には真空蒸着による金銀の飛散による損失が大きく、
歩留りが悪くなる。(Problems to be Solved by the Invention) As mentioned above, gold and silver threads made by pasting gold and silver foil on paper or vacuum-depositing gold and silver on a base sheet and cutting them into thin strips have a different appearance. However, in the former case, it is expensive to produce gold and silver foil of uniform thickness, and a special technique is required to apply the gold and silver foil. In the latter case, losses due to scattering of gold and silver during vacuum evaporation are large;
Yield deteriorates.
したがって、上記の金銀糸は、基体シート上にアルミを
真空蒸着して得た装飾用金銀糸にくらべて相当に割高と
なるのに対して、織編物が汚染されたり、使用によるい
たみを生じた場合において、金銀としての貴金属の回収
が事実上困難なものとなるため豪華な織編物もその資産
的価値は皆無となる欠点を有している。Therefore, the above-mentioned gold and silver threads are considerably more expensive than decorative gold and silver threads obtained by vacuum-depositing aluminum on a base sheet, but they do not cause contamination of woven or knitted fabrics or damage due to use. In some cases, recovery of precious metals in the form of gold and silver becomes virtually difficult, so even luxurious woven and knitted fabrics have the disadvantage of having no asset value.
しかしながら、芯糸を種々な色彩として間隙を設けて巻
付けられたこれらの金銀糸は幾何的なスパイラル状の色
縞模様を呈し、外観的に美麗であって装飾的な見映を有
している。However, these gold and silver threads, which are wound around core threads in various colors with gaps, exhibit a geometric spiral color striped pattern and have a beautiful and decorative appearance. There is.
このような色縞模様が高純度の銀又は白金細線で形成で
きないものかは一つの課題でもある。One issue is whether such colored striped patterns can be formed using thin wires of high-purity silver or platinum.
本発明者らは、直径が0.05〜0.3mmφの純銀又
は純白金の軟質細線を用いて1M編物に織成したが、各
細線単独の破断荷重、屈曲性、可撓性が織成加工条件に
適合しないため容易に断線したり、折れ曲ったり、又は
織成時の作業性を著しく阻害する問題を生じる共に、得
られた織編物の外観は平面的で立体感がなく、優雅な白
銀色を呈するが幾何的な陰影による色縞模様を呈しない
。The present inventors woven a 1M knitted fabric using pure silver or pure platinum soft thin wires with a diameter of 0.05 to 0.3 mmφ, but the breaking load, bendability, and flexibility of each thin wire alone were determined by the weaving process. Because the wires do not meet these conditions, they easily break or bend, or the workability during weaving is significantly hindered, and the appearance of the resulting woven or knitted fabric is flat and lacks a three-dimensional effect, giving it an elegant silvery-white appearance. Although it exhibits color, it does not exhibit color stripes due to geometric shading.
例えば、銀又は白金細線の表面に塗料などによって間欠
的なリングマークによる色縞模様を付けることができる
とすれば、その外観はより装飾的なものとなる。しかし
本発明に使用する銀又は白金細線はその直径が極めて小
さいため、リングマーク法による塗装着色は至極困難で
ある。仮りに作られたとしても織編時においてリングマ
ークを付けた部分が節々となって折れ曲ったり、又はそ
の後の使用においてリングマークの着色部分は、摩擦、
摩耗、屈曲および外傷等を受けて塗装着色されたリング
マークが剥離、脱落して装飾的価値を失うことになる。For example, if a colored striped pattern with intermittent ring marks can be applied to the surface of a thin silver or platinum wire using paint or the like, the appearance will become more decorative. However, since the silver or platinum fine wire used in the present invention has an extremely small diameter, it is extremely difficult to paint and color it by the ring mark method. Even if it were made, the part with the ring mark may become knotted and bend during weaving or knitting, or the colored part of the ring mark may be damaged by friction or damage during subsequent use.
Due to abrasion, bending, trauma, etc., the painted and colored ring marks will peel off and fall off, causing them to lose their decorative value.
そこで、第3図に示すように、銀又は白金細線の1本を
中心線(2)として、その上に同一線径の同質細線を同
心撚りした7本構成の白色貴金属系(1)について、該
糸外径のダイスを用いて外層線間の谷間(8)に着色性
合成樹脂又は塗料(6)を充填して銀又は白金との色縞
模様を形成させることを試みた結果、第4図のように白
色貴金属系の外周全面に着色性合成樹脂又は塗料(6)
が全面に被覆され、外層の銀又は白金細線が表面に露出
されないので、白色貴金属系(1)の装飾的価値を皆無
にするものであった。Therefore, as shown in Fig. 3, regarding a white precious metal system (1) consisting of seven thin silver or platinum wires, with one thin wire of silver or platinum set as the center line (2) and homogeneous thin wires of the same wire diameter concentrically twisted on top of the center line (2), As a result of trying to fill the valleys (8) between the outer layer wires with a colored synthetic resin or paint (6) using a die having the outer diameter of the yarn to form a colored striped pattern with silver or platinum, the fourth Colorable synthetic resin or paint (6) on the entire outer periphery of white precious metal as shown in the figure.
Since the outer layer of silver or platinum fine wires are not exposed on the surface, the white noble metal type (1) has no decorative value.
本発明は係る問題を解決することを目的とするものであ
って、高純度の銀又は白金細線を同心撚りした白色貴金
属系を円形に圧縮形成して外層の線間に凹部を設け、該
凹部に着色性合成樹脂又は塗料を充填して、その外観を
白銀色の光輝のあるスパイラル状のすしと凹部の充填樹
脂などとの明暗の色縞模様とする装飾用圧縮白色貴金属
系の製造方法を提供するものである。The present invention is aimed at solving this problem, and consists of compressing a white noble metal system in which fine silver or platinum wires of high purity are concentrically twisted into a circular shape, providing recesses between the wires of the outer layer, and forming recesses between the wires of the outer layer. A method for producing a compressed white precious metal for decorative use, in which the material is filled with a colored synthetic resin or paint, and the appearance is a bright and dark color striped pattern of a shiny spiral-shaped sushi of silver color and the filling resin in the recesses. This is what we provide.
本発明の他の目的は、本発明に係る装飾用圧縮白色貴金
属系を織編物に織成した後、該織編物が汚染されたり、
いたみを生じた場合に織編物に使用されている高純度の
銀又は白金細線を貴金属として回収し、wA編物の責産
価値を高める得ることも併せ提供するものである。Another object of the present invention is that after the decorative compressed white precious metal system according to the present invention is woven into a woven or knitted fabric, the woven or knitted fabric is not contaminated.
The present invention also provides the ability to recover high-purity silver or platinum thin wires used in woven and knitted fabrics as precious metals in the event of damage, thereby increasing the liability value of wA knitted fabrics.
(問題点を解決するための手段)
本発明の目的を解決するための手段は、直径が0.05
〜0.211IIlφの高純度の銀又は白金細線のうち
、いずれかの1本若しくは2〜5本を撚り合せたものを
中心線とし、その上に同一線径の同質細線を同心状に、
撚りピッチを最外層の線の中心を通る円の直径(以下、
層心径という)の50倍以下として撚り合せ、撚り構成
の総本数を7〜61本の撚り合せ白色貴金属系とする。(Means for Solving the Problems) Means for solving the objects of the present invention have a diameter of 0.05 mm.
The center line is one or two to five of high-purity silver or platinum thin wires of ~0.211IIlφ, and a homogeneous thin wire of the same wire diameter is placed concentrically on the center line.
The twist pitch is defined as the diameter of the circle passing through the center of the outermost layer (hereinafter referred to as
The layer core diameter is 50 times or less, and the total number of strands in the strand structure is 7 to 61 to form a white noble metal system.
かくして構成される種々の撚り合せ白色貴金属系を圧縮
率3%以上として、線糸の仕上外径より小さい径の線引
きダイスに通して円型に圧縮した後、該圧縮白色貴金属
系を500±10℃の温度範囲で短時間軟質に調質し、
該圧縮白色貴金属系の外層線間に形成される凹部の間隙
に着色性の熱可塑性樹脂又は熱硬化性樹脂を充填して、
圧縮白色貴金属系の外観に白銀色と着色性合成樹脂との
色縞模様をスパイラル状に形成させることを特徴とする
ものである。After compressing the various twisted white precious metal systems thus constructed into a circular shape through a wire drawing die with a diameter smaller than the finished outer diameter of the wire yarn at a compression rate of 3% or more, the compressed white precious metal systems are Temperature softened for a short time in the temperature range of ℃,
Filling the gap between the recesses formed between the outer layer wires of the compressed white noble metal with a colored thermoplastic resin or thermosetting resin,
It is characterized by forming a spiral colored striped pattern of white silver and colored synthetic resin on the appearance of a compressed white precious metal.
次に、圧縮前の撚り合せ白色貴金属系の構成最小限、す
なわち中心線径0.05mmφ、撚り本数7木とするの
は、この構成未満では機械的性質の破断荷重が低くなり
、織編物の織成加工時に断線を生じる恐れがあるためで
ある。Next, the reason why the composition of the twisted white precious metal system before compression is set to the minimum, that is, the center wire diameter is 0.05 mmφ and the number of twists is 7, is that if the composition is less than this, the mechanical property breaking load will be low, and the woven or knitted material will This is because there is a risk of wire breakage occurring during the weaving process.
又、構成の最大限にすなわち中心線径0.2m11+φ
、撚り本数61本とするのは、この構成以上では白色貴
金属系の仕上外径が大きくなり、織編物の織成加工時の
作業性に支障をきたす恐れがあるためである。Also, to the maximum of the configuration, that is, the center line diameter is 0.2 m11 + φ
The reason why the number of twists is 61 is that if the structure exceeds this configuration, the finished outer diameter of the white precious metal will become large, which may impede the workability during weaving of the woven or knitted material.
撚り合せ白色貴金属系の好ましい構成範囲は中心線径0
.07〜0.15mmφ、撚り本数7〜37本である。The preferred configuration range for the twisted white precious metal system is a center wire diameter of 0.
.. The diameter is 07 to 0.15 mm, and the number of twists is 7 to 37.
撚り合せ白色貴金属系の撚りピッチは層心径の50倍以
下とするのが好ましい。その値以上ではIa編物の織成
時に受ける曲げ応力によって撚りかもどけやすくなるた
めである。好ましい撚りピッチは層心径の10〜25倍
の範囲であり、好ましい圧縮率は4〜15%である。撚
り合せ白色貴金属系について圧縮率が3%未満では線引
きダイスによって圧縮され、研磨される外層の円弧部が
小さくなり、外層線間の凹部に充填される着色性合成樹
脂の帯状すじが大きくなって外観の装飾的価値を失うこ
とになるためである。圧縮率を大にすると撚り合せ白色
貴金属系はソリッド状を呈し好ましくない。The twisting pitch of the twisted white precious metal is preferably 50 times or less the diameter of the layer core. This is because if the value exceeds that value, the twist will easily unravel due to the bending stress received during weaving of the Ia knitted material. The preferred twisting pitch is in the range of 10 to 25 times the layer core diameter, and the preferred compression ratio is in the range of 4 to 15%. When the compression rate of the twisted white precious metal type is less than 3%, the arcuate portion of the outer layer that is compressed by the wire drawing die and polished becomes smaller, and the band-like streaks of the colored synthetic resin filled in the recesses between the outer layer wires become larger. This is because the decorative value of the appearance will be lost. If the compression rate is increased, the twisted white precious metal system will take on a solid shape, which is not preferable.
更に、本発明に使用する銀又は白金細線は高純度(僅か
な他の添加元素を含むもので、銀又は白金の純度が90
%以上のもの)以上であり、好ましいのは純銀又は純白
金である。高純度以下では織編物に織成されている圧縮
白色貴金属系を貴金属として回収する場合、その回収価
格が低くり、資産的効果を失うことになるためである。Furthermore, the silver or platinum thin wire used in the present invention has a high purity (contains a small amount of other additive elements, and the purity of silver or platinum is 90%).
% or more), and pure silver or pure platinum is preferred. This is because if the compressed white precious metal woven into the woven or knitted fabric is recovered as a precious metal if the purity is lower than that, the recovery price will be low and the asset effect will be lost.
使用する熱可塑性樹脂又は熱硬化性樹脂のビカット式軟
化温度(JISK’7206)は60℃以上が好ましい
。その理由は使用又は保管中に装飾用圧縮白色貴金属系
が受ける環境温度を考慮するためである。The Vicat softening temperature (JISK'7206) of the thermoplastic resin or thermosetting resin used is preferably 60° C. or higher. The reason for this is to take into account the environmental temperature to which the decorative compressed white precious metal system is subjected during use or storage.
(作 用)
これを第1図および第2図に示す7本構成の圧縮白色貴
金属系について説明する。同心状に撚り合せた白色貴金
属系(1)を線引きダイスを用いて円型に圧縮すると、
中心線(2)は変形を受けないが、外層の銀又は白金線
m (3)は太き(変形し、線引きダイスによって研磨
された大きな円弧部(4)と外層の線間に凹部(5)を
形成する。(Function) This will be explained for the compressed white noble metal system having seven components shown in FIGS. 1 and 2. When concentrically twisted white precious metal (1) is compressed into a circular shape using a wire drawing die,
The center line (2) is not deformed, but the outer layer silver or platinum wire m (3) is thick (deformed) and there is a recess (5 ) to form.
該凹部の間隙に着色性の熱可塑性樹脂又は熱硬化性樹脂
(6)を充填すると、円弧部(4)と凹部に充填された
着色性合成樹脂は圧縮白色貴金属系(7)の長さ方向に
対して、前者では光輝のある白銀色の帯状のすしとして
、後者では着色性合成樹脂が帯状のすしとなって交互に
スパイラル状の色縞模様を呈し、その外観は優雅な装飾
用圧縮白色貴金属系となる。When the gap between the recesses is filled with colored thermoplastic resin or thermosetting resin (6), the arcuate portion (4) and the colored synthetic resin filled in the recesses are compressed in the length direction of the white precious metal-based material (7). On the other hand, in the former, the sushi is a bright white silver band, and in the latter, the colored synthetic resin is used as band-shaped sushi that alternates with spiral colored stripes, and the appearance is an elegant decorative compressed white. It is made of precious metals.
以上、7本構成の着色性の圧縮白色貴金属系の一例につ
いて説明したが、多層撚り構成の各圧縮白色貴金属系の
外観も前記と同様に白銀色と着色性樹脂との色縞模様を
呈する。An example of a colored compressed white noble metal system having a seven-strand structure has been described above, but the appearance of each compressed white noble metal system having a multilayer twist structure also exhibits a colored striped pattern of silvery white and colored resin as described above.
(実施例)
実施例1
直径0.1±8/1000mmφの純銀細線を中心線と
して、その上に同質同一線径の銀細線6本を同心状に、
撚りピッチを層心径の30倍として右撚りに撚り合せて
銀糸とする。該銀糸を圧縮率7%とする径の線引きダイ
スに通して円型に圧縮した後、トリクレン溶剤で脱脂を
行ない温度500±10℃に調整した連続軟化装置によ
って軟質に調質して圧縮銀糸とした。該圧縮銀糸をエポ
キシ−イソシアネート樹脂 (1:1)20部、カーボ
ンブランク0.1部、酢酸エチル35部、メチルエチル
ケトン35部、シクロヘキサノン15部からなる樹脂塗
料中に浸漬させ、仕上外径に相当するダイスに通して引
き上げて加熱乾燥し、圧縮銀糸の外層線間の凹部に黒色
樹脂を充填した。得られた圧縮白色貴金属系の外観は、
光輝のある白銀色の帯状のすしと凹部に充填された黒色
の帯状のすしとが交互にスパイラル状となり美麗な幾何
的な色縞模様を呈していた。(Example) Example 1 A thin pure silver wire with a diameter of 0.1±8/1000 mmφ was set as the center line, and six thin silver wires of the same quality and the same wire diameter were placed concentrically on the center line.
The twisting pitch is set to 30 times the layer core diameter, and the silver thread is twisted in a right-handed manner. The silver thread is passed through a wire drawing die with a compression rate of 7% and compressed into a circular shape, and then degreased with a trichloride solvent and tempered to a soft state using a continuous softening device adjusted to a temperature of 500±10°C to form a compressed silver thread. did. The compressed silver thread was immersed in a resin paint consisting of 20 parts of epoxy-isocyanate resin (1:1), 0.1 part of carbon blank, 35 parts of ethyl acetate, 35 parts of methyl ethyl ketone, and 15 parts of cyclohexanone, and a resin paint corresponding to the finished outer diameter was immersed. It was passed through a die and pulled up and dried by heating, and the recesses between the outer layer lines of the compressed silver thread were filled with black resin. The appearance of the resulting compressed white precious metal is as follows:
The bright silver bands of sushi and the black bands of sushi filled in the recesses alternated in a spiral shape, creating a beautiful geometric striped pattern.
実施例2
直径0.1±8/1000mmφの純白金細線を中心線
として、その上に同質同一線径の白金細線6本を同心状
に左撚りし、更に同質同一線径の白金細線12本を同心
状に、最外層の撚りピッチを層心径の20倍として右撚
りに撚り合せて白金糸とする。Example 2 A pure platinum thin wire with a diameter of 0.1±8/1000 mmφ is set as the center line, and on top of it, 6 platinum thin wires of the same quality and diameter are twisted left-handed concentrically, and further 12 platinum thin wires of the same quality and the same diameter are twisted on the center line. are twisted concentrically in a right-handed manner with the twisting pitch of the outermost layer being 20 times the core diameter of the layer to obtain a platinum thread.
該金糸を圧縮率6%とする径の線引きダイスに通して円
型に圧縮した後、トリクレン溶剤で脱脂を行ない温度5
00±10℃に調整した連続軟化装置によって軟質に調
質して圧縮白金糸とした。After passing the gold thread through a wire drawing die with a diameter of 6% and compressing it into a circular shape, it was degreased with trichlene solvent and heated to a temperature of 5%.
The compressed platinum thread was softened by a continuous softening device adjusted to 00±10°C.
該圧縮白金糸を実施例1と同様なエポキシ−イソシアネ
ート樹脂塗料中に浸漬させ、仕上外径に相当するダイス
に通して引き上げて加熱乾燥し、圧縮白金糸の外層線間
の凹部に黒色樹脂を充填した。The compressed platinum thread was immersed in the same epoxy-isocyanate resin paint as in Example 1, pulled up through a die corresponding to the finished outer diameter, and heated and dried to coat the black resin in the recesses between the outer layer lines of the compressed platinum thread. Filled.
得られた圧縮白色貴金属系の外観は実施例1と同様に、
光輝ある白銀色の帯状のすしと、黒色の帯状のすしとが
交互にスパイラル状となり美麗な幾何的色縞模様を呈し
ていた。The appearance of the obtained compressed white precious metal was similar to that of Example 1.
Shiny silver bands of sushi and black bands of sushi alternated in a spiral shape, creating a beautiful geometric striped pattern.
実施例3
直径0.15±8/1000mmφの純銀細線を用い、
実施例1と同様にして同心撚りの軟質圧縮銀糸を作り、
該圧縮銀糸をエポキシ−フェノール樹脂(1:1)50
部、セロソルブ150部、キジロール50部、青色顔料
若干部からなる樹脂塗料中に浸漬させ、仕上外径に相当
するダイスに通して引き上げて加熱乾燥し、圧縮白金糸
の外層線間の凹部に青色樹脂を充填した。Example 3 Using a fine pure silver wire with a diameter of 0.15±8/1000 mm,
A concentrically twisted soft compressed silver thread was made in the same manner as in Example 1,
The compressed silver thread was coated with epoxy-phenol resin (1:1) 50
150 parts of Cellosolve, 50 parts of Kijiroll, and a small amount of blue pigment.It is immersed in a resin paint consisting of 150 parts of Cellosolve, 50 parts of Kijiroll, and a small amount of blue pigment, pulled up through a die corresponding to the finished outer diameter, heated and dried, and a blue color is applied to the recesses between the outer layer lines of the compressed platinum thread Filled with resin.
得られた圧縮白色貴金属系の外観は光輝のある白銀色の
帯状のすしと凹部に充填された青色の帯状のすしとが交
互にスパイラル状となり、美麗な幾何的な色縞模様を呈
していた。The appearance of the resulting compressed white precious metal was a beautiful geometric striped pattern of bright white silver strips and blue strips filled in the recesses that alternated in a spiral shape. .
実施例4
直径0.15±8/1000mmφの純白金細線を用い
、実施例2と同様にして同心撚りの軟質の圧縮白金糸を
作り、該圧縮白金糸を塩化ビニル−酢酸ビニル共重合樹
脂10部、可塑剤3部、ペンゾール50部、アセトン2
0部、酢酸エチル25部、赤色着色剤若干部からなる樹
脂塗料中に浸漬させ、仕上外径に相当するダイスに通し
て引き上げて加熱乾燥し、圧縮白金糸の外層線間の凹部
に赤色樹脂を充填した。Example 4 Using pure platinum fine wire with a diameter of 0.15±8/1000 mmφ, concentrically twisted soft compressed platinum thread was made in the same manner as in Example 2, and the compressed platinum thread was coated with vinyl chloride-vinyl acetate copolymer resin 10 parts, plasticizer 3 parts, penzole 50 parts, acetone 2 parts
The compressed platinum thread is immersed in a resin paint consisting of 25 parts of ethyl acetate, 25 parts of ethyl acetate, and some part of a red colorant, pulled up through a die corresponding to the finished outer diameter, and heated and dried. filled with.
得られた圧縮白色貴金属系の外観は各実施例と同様に白
銀色と赤色との帯状のすしが交互にスパイラル状となり
、美麗な色縞模様を呈していた。The appearance of the obtained compressed white noble metal-based product was similar to each of the Examples, with white silver and red bands forming an alternating spiral pattern, and a beautiful colored striped pattern.
以上の実施例以外に同一線径の純銀又は純白金細線と純
金細線とを交互に撚り合せた複合貴金属系を前記実施例
と同様に、円型に圧縮した後、温度500±10℃に調
整した連続軟化装置によって軟質に調質し、液系の外層
線間の凹部に着色樹脂を充填して装飾用圧縮複合貴金属
系とすることができる。In addition to the above examples, a composite precious metal system in which pure silver or pure platinum thin wires and pure gold thin wires of the same wire diameter are twisted alternately is compressed into a circular shape in the same manner as in the above examples, and then the temperature is adjusted to 500 ± 10 ° C. A compressed composite noble metal system for decoration can be obtained by softening the material using a continuous softening device, and filling the recesses between the outer layer lines of the liquid system with a colored resin.
(発明の効果)
本発明の方法により得られた装飾用圧縮白色貴金属系の
外観は、その長さ方向において鏡面光輝のある白銀色の
帯状のすしと圧縮白金糸の外層凹部に充填された着色性
合成樹脂の帯状のすしとが交互にスパイラル状となり、
優雅な色縞模様を呈するのでより装飾的な効果がある。(Effects of the Invention) The appearance of the decorative compressed white noble metal-based material obtained by the method of the present invention is that it has a silver band shape with specular luster in its length direction and the coloring that fills the concave portions of the outer layer of the compressed platinum thread. The sushi strips made of synthetic resin alternate in a spiral shape,
It has an elegant color stripe pattern, which gives it a more decorative effect.
更に、本発明の方法により得られた装飾用圧縮白色貴金
属系は、織編物に織成した後、織編物が汚染されたり、
いたみを生じた場合に、該圧縮白色貴金属系を貴金属と
して回収することができるのでwR編物の資産的効果を
高め得るので需要に寄与する度合が多大である。Furthermore, after the decorative compressed white precious metal system obtained by the method of the present invention is woven into a woven or knitted fabric, the woven or knitted fabric may be contaminated or
In the event of damage, the compressed white precious metal system can be recovered as a precious metal, which can enhance the asset value of wR knitted fabrics, thereby making a large contribution to demand.
第1図は本発明方法により製造された装飾用圧縮白色貴
金属系の横断面の拡大図の一実施例、第2図は7本構成
の圧縮白色貴金属系の横断面の拡大図、第3図は銀又は
白金細線の1本を中心線とし、その上に同質同一線径の
細線6本を同心状に撚り合せた白色貴金属系の横断面の
拡大図、第4図は第3図の白色貴金属系上に着色性合成
樹脂を被覆した横断面の拡大図である。
図面の主要な符号
1:同心状に撚り合せた白色貴金属系、2:銀又は白金
細線の中心線、3:外層の銀又は白金細線、4:光沢の
ある円弧部、5:外層線間の凹部、6:着色性合成樹脂
塗料、7:圧縮白色貴金属系、8二外NvA間の谷間。
代理人 弁理士 水 口 孝 −
第1図 L。
l31i¥II4−IffiFig. 1 is an example of an enlarged cross-sectional view of a compressed white precious metal system for decoration manufactured by the method of the present invention, Fig. 2 is an enlarged cross-sectional view of a compressed white precious metal system with seven pieces, and Fig. 3 Figure 4 is an enlarged cross-sectional view of a white noble metal material in which one thin silver or platinum wire is used as the center line, and six thin wires of the same quality and diameter are twisted concentrically on top of it. FIG. 2 is an enlarged cross-sectional view of a noble metal-based material coated with a colored synthetic resin. Main symbols in the drawing 1: Concentrically twisted white precious metal system, 2: Center line of thin silver or platinum wires, 3: Fine silver or platinum wires in outer layer, 4: Shiny arc portion, 5: Between outer layer wires Concave portion, 6: Colored synthetic resin paint, 7: Compressed white precious metal system, 8 Valley between two outer NvA. Agent Patent Attorney Takashi Mizuguchi - Figure 1 L. l31i¥II4-Iffi
Claims (1)
のうち、いずれか1本若しくは2〜5本を撚り合せたも
のを中心線とし、その上に同一線径の同質細線を同心状
に撚り合せ、その撚り合せ構成総本数7〜61本とし、
かくして構成される撚り合せ白色貴金属系を線引きダイ
スに通して円型に圧縮した後、該圧縮糸を加熱処理して
軟質とし、該圧縮白色貴金属系の外層線間に形成される
凹部の間隙に着色性の熱可塑性樹脂又は熱硬化性樹脂を
充填することを特徴とする装飾用圧縮白色貴金属系の製
造方法。One or two to five high-purity silver or platinum thin wires with a diameter of 0.05 to 0.2 mmφ are twisted together as the center line, and homogeneous thin wires with the same wire diameter are placed concentrically on top of that. The total number of strands in the twisted configuration is 7 to 61,
After the thus constructed twisted white precious metal is passed through a wire drawing die and compressed into a circular shape, the compressed yarn is heat-treated to make it soft, and the compressed white precious metal is inserted into the gap between the recesses formed between the outer layer wires. 1. A method for producing a compressed white precious metal for decoration, which comprises filling a colored thermoplastic resin or thermosetting resin.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18169686A JPS6342933A (en) | 1986-07-31 | 1986-07-31 | Production of decorative compression white noble metal yarn |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18169686A JPS6342933A (en) | 1986-07-31 | 1986-07-31 | Production of decorative compression white noble metal yarn |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6342933A true JPS6342933A (en) | 1988-02-24 |
Family
ID=16105262
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18169686A Pending JPS6342933A (en) | 1986-07-31 | 1986-07-31 | Production of decorative compression white noble metal yarn |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6342933A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2694306A1 (en) * | 1992-07-31 | 1994-02-04 | Louyot Comptoir Lyon Alemand | Wires comprising a helical element, their assemblies and the use of said assemblies as catalyst and / or for recovering precious metals. |
WO2013110626A1 (en) * | 2012-01-24 | 2013-08-01 | Heraeus Materials Technology Gmbh & Co. Kg | Flat structure which contains precious metal wire and is, in particular, textile |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5288650A (en) * | 1976-01-13 | 1977-07-25 | Nippon Steel Wire Rope | Condensing bonded metal wires and thier manufacture |
-
1986
- 1986-07-31 JP JP18169686A patent/JPS6342933A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5288650A (en) * | 1976-01-13 | 1977-07-25 | Nippon Steel Wire Rope | Condensing bonded metal wires and thier manufacture |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2694306A1 (en) * | 1992-07-31 | 1994-02-04 | Louyot Comptoir Lyon Alemand | Wires comprising a helical element, their assemblies and the use of said assemblies as catalyst and / or for recovering precious metals. |
WO1994003665A1 (en) * | 1992-07-31 | 1994-02-17 | Comptoir Lyon-Alemand-Louyot | Wires incorporating a helical component, assemblies thereof, and use of said assemblies as catalyser and/or to recover precious metals |
TR26971A (en) * | 1992-07-31 | 1994-09-12 | Louyot Comptoir Lyon Alemand | Yarns consisting of a helical element are used to assemble these yarns and to use said assemblies as catalysts and / or to recover precious metals. |
WO2013110626A1 (en) * | 2012-01-24 | 2013-08-01 | Heraeus Materials Technology Gmbh & Co. Kg | Flat structure which contains precious metal wire and is, in particular, textile |
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