JPS6341598A - Detergent composition containing abrasive agent - Google Patents
Detergent composition containing abrasive agentInfo
- Publication number
- JPS6341598A JPS6341598A JP18660486A JP18660486A JPS6341598A JP S6341598 A JPS6341598 A JP S6341598A JP 18660486 A JP18660486 A JP 18660486A JP 18660486 A JP18660486 A JP 18660486A JP S6341598 A JPS6341598 A JP S6341598A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- composition
- abrasive
- cleaning
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 40
- 239000003599 detergent Substances 0.000 title description 12
- 239000003082 abrasive agent Substances 0.000 title description 3
- 238000004140 cleaning Methods 0.000 claims description 22
- -1 polyoxyethylene Polymers 0.000 claims description 17
- 235000002639 sodium chloride Nutrition 0.000 claims description 8
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 235000011147 magnesium chloride Nutrition 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 150000003871 sulfonates Chemical class 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- 239000006185 dispersion Substances 0.000 description 12
- 238000005187 foaming Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000001771 impaired effect Effects 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 238000005498 polishing Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000007794 irritation Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000004129 EU approved improving agent Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004990 Smectic liquid crystal Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- VLSMHEGGTFMBBZ-UHFFFAOYSA-N alpha-Kainic acid Natural products CC(=C)C1CNC(C(O)=O)C1CC(O)=O VLSMHEGGTFMBBZ-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- VLSMHEGGTFMBBZ-OOZYFLPDSA-N kainic acid Chemical compound CC(=C)[C@H]1CN[C@H](C(O)=O)[C@H]1CC(O)=O VLSMHEGGTFMBBZ-OOZYFLPDSA-N 0.000 description 1
- 229950006874 kainic acid Drugs 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は安定な懸濁系液体洗浄剤組成物、更に詳しく言
えば、優れた洗浄力及び研磨力を有し、特に手肌にマイ
ルドな、かつ分散安定性に優れた、研磨剤を含有する液
体洗浄剤組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention provides a stable suspension-type liquid detergent composition, more specifically, a composition having excellent detergent and polishing power, and which is particularly mild to the skin of hands. The present invention relates to a liquid cleaning composition containing an abrasive and having excellent dispersion stability.
従来、野菜や食器洗いなどの台所用液体洗剤は界面活性
剤の洗浄力のみを利用する組成物が主流であった。この
種の洗浄剤は野菜類の洗浄や液状油、半固体油などの洗
浄力は優れているが、例えば食物の調理、或いは放置な
どにより変性したり半固形化した食物や固体油、焼成油
などに対する洗浄力は比較的弱く、これらが付着した食
器や調理器具の洗浄には通常粒状、粉末状或いは液状の
磨きクレンザ−が洗浄補助剤として用いられていた。Conventionally, liquid detergents for kitchen use, such as those used for washing vegetables and dishes, have mainly consisted of compositions that utilize only the cleaning power of surfactants. This type of cleaning agent has excellent cleaning power for cleaning vegetables, liquid oil, semi-solid oil, etc., but it can also be used to clean foods that have been denatured or semi-solid due to food cooking or being left unused, solid oil, and baking oil. The cleaning power against such substances is relatively weak, and granular, powdered, or liquid polishing cleansers are usually used as cleaning aids to clean tableware and cooking utensils that are contaminated with these substances.
他方、最近非水溶性研磨剤を含有する液体洗浄剤組成物
が種々提案されている。これらの洗浄剤は、非固着性の
汚れを落とす普通の洗浄力と、固着性の汚れを除去する
研磨力とを併有した好ましいものであるが、この種の洗
浄剤に於いては、研磨力を向上する為に、研磨剤の含有
量を増加させると被洗物を傷つげる傾向が高くなる上に
、貯蔵中にその中に含まれる研磨剤が沈澱して（るとい
う欠点がある。また、これらの欠点を改良するためにス
メクタイト又は複鎖状構造型粘土鉱物若しくはその両方
を主成分とする粘土によって分散安定性を重視する組成
にすると、粘度が上昇し使用感を損なうと同時に起泡力
や洗浄力の低下を免れない。或いは粘土鉱物配合時に十
分な剪断を加えない場合には分散安定性の極めて悪い組
成物しか得られず、初期の目的を達し得ない。また、脂
肪酸塩を増粘・分散安定化剤として使用すると室温での
分散安定性は向上するが、高温においてはこの中和物が
共存する界面活性剤によって可溶化されるため、或いは
中和物自身が融解するために、著しく粘度及びチクソト
ロピー性が下がり、分散安定性の極めて悪い組成物とな
っていまう傾向にあった。On the other hand, various liquid cleaning compositions containing water-insoluble abrasives have recently been proposed. These cleaning agents are preferable because they have both normal cleaning power for removing non-adhesive stains and abrasive power for removing adherent stains. Increasing the content of abrasive to improve the strength increases the tendency to damage the items to be washed, and has the disadvantage that the abrasive contained therein settles out during storage. In addition, in order to improve these drawbacks, if a composition is created that emphasizes dispersion stability by using clay mainly composed of smectite, multi-chain clay minerals, or both, the viscosity will increase and the feeling of use will be impaired. A decrease in foaming power and detergency is inevitable.Alternatively, if sufficient shearing is not applied when incorporating clay minerals, a composition with extremely poor dispersion stability will be obtained, and the initial purpose will not be achieved.Furthermore, fatty acid salts When used as a thickening/dispersion stabilizing agent, the dispersion stability at room temperature improves, but at high temperatures, this neutralized product is solubilized by the coexisting surfactant, or the neutralized product itself melts. Therefore, the viscosity and thixotropy properties tend to decrease significantly, resulting in a composition with extremely poor dispersion stability.
このために研磨力、洗浄力、起泡力などの洗浄特性が優
れ、しかも、容器から出し易いほど低粘度で、長時間に
渡って安定性を持続し得る研磨剤含有洗浄剤組成物の開
発が要望されていた。本発明者らは、このような要望に
答えるべく鋭意研究を重ねた結果、下記の成分を必須成
分として含有させ、更にそのｐＨを４．０〜６．５に調
整したものが、優れた洗浄力、起泡力及び研磨力を有し
、手肌にマイルドで、その粘度が２０００ｃｐ以下で非
常に容器から出し易いにもかかわらず、低温はもとより
高温に於いても優れた研磨剤の分散安定性を示すことを
見出し、この知見に基づいて本発明を完成するに至った
。To this end, we developed an abrasive-containing cleaning composition that has excellent cleaning properties such as polishing power, detergency, and foaming power, has a viscosity low enough to be easily taken out of the container, and can maintain stability for a long period of time. was requested. The inventors of the present invention have conducted intensive research in order to meet these demands, and have found that a product that contains the following components as essential components and further adjusts the pH to 4.0 to 6.5 has excellent cleaning properties. The abrasive has excellent dispersion stability not only at low temperatures but also at high temperatures, although it has strong foaming power, abrasive power, is mild to the skin of hands, and its viscosity is less than 2000 cp, making it very easy to remove from the container. Based on this finding, the present invention was completed.
本発明に於いて、組成物が低粘度であるにも拘わらず優
れた分散安定性を持つ理由は、本発明の洗浄剤組成物が
弱酸性領域に於いて陰イオン性界面活性剤とアミンオキ
シドとが強固な会合体を形成し、そのために可溶化領域
が増大し、適度な構造粘性を有して一１５℃〜＋７０℃
という広い温度範囲にわたって経時的、熱的に安定な１
相領域として存在するスメクチック液晶領域を形成する
ためであると考えられる。In the present invention, the reason why the composition has excellent dispersion stability despite its low viscosity is that the cleaning composition of the present invention has an anionic surfactant and an amine oxide in a weakly acidic region. forms a strong association, which increases the solubilization area and has an appropriate structural viscosity.
1, which is thermally stable over time and over a wide temperature range.
This is thought to be due to the formation of a smectic liquid crystal region that exists as a phase region.
即ち本発明は、
（ａ＋ ポリオキシエチレンアルキルエーテル硫酸塩
、アルキルベンゼンスルホン酸塩、α−オレフィンスル
ホン酸塩及びアルカンスルホン酸塩からなる群より選ば
れる１種又は２種以上の陰イオン性界面活性剤３〜２５
重量％（ｂｌ モノ直鎖アルキル第３級アミンオキシ
ド１〜ＩＯ重量％
（ｃ）塩化ナトリウム、塩化カリウム、塩化マグネシウ
ム、硫酸マグネシウムおよび硝酸マグネシウムからなる
群より選ばれる１種又は２種以上の水溶性無機塩０．１
〜５重量％（ｄ） 平均粒径１〜１００μでモース硬
さ２〜８をもつ水不溶性研磨剤１〜２５重量％
を含有し、かつ組成物のｐｉ（が４．０〜６．５である
ことを特徴とする研磨剤含有洗浄剤組成物を提供する。That is, the present invention provides (a+) one or more anionic surfactants selected from the group consisting of polyoxyethylene alkyl ether sulfates, alkylbenzene sulfonates, α-olefin sulfonates, and alkanesulfonates; 3-25
Weight % (bl Monolinear alkyl tertiary amine oxide 1 to IO weight % (c) One or more water-soluble types selected from the group consisting of sodium chloride, potassium chloride, magnesium chloride, magnesium sulfate, and magnesium nitrate Inorganic salt 0.1
~5% by weight (d) 1 to 25% by weight of a water-insoluble abrasive having an average particle size of 1 to 100μ and a Mohs hardness of 2 to 8; An abrasive-containing cleaning composition is provided.
ｆａｌ成分として用いる陰イオン性界面活性剤はポリオ
キシエチレンアルキルエーテル硫酸塩、アルキルベンゼ
ンスルホン酸塩、α−オレフィンスルホン酸塩及びアル
カンスルホン酸塩からなる群より選ばれる１種又は２種
以上の陰イオン性界面活性剤の何れでも使用できるが、
手肌に対するマイルド感から見ると次の一般式で表わさ
れるポリオキシエチレンアルキルエーテル硫酸塩
Ｒ＋０（ＣＨｚＣｆｌｚＯ）ｌｌＳＯＪ（式中、Ｒ１は
炭素数９〜１５の直鎖状又は分岐状アルキル基又はアル
ケニル基を示し、ｎは平均で０．５から７の実数、Ｈは
アルカリ金属、アルカリ土類金属、アンモニウム基又は
アルカノール置換アンモニウム基である）
が好ましい。この炭素数が９未満では洗浄性能が低く、
また１６以上ではすすぎ性が顕著に低下するばかりでな
く、組成物の研磨剤が沈澱しやすくなって経時的安定性
が損なわれる傾向にあるので好ましくない。特に好まし
い炭素数は１０〜１３の範囲である。また−形成中のエ
チレンオキサイド付加モル数ｎは、広い温度範囲にわた
って安定な液晶相の存在する領域或いは可溶化量の増大
した領域を得るには、平均０．５〜７の範囲内にあるこ
とが好ましい。この範囲を逸脱すると３５℃以上の高温
或いは一５℃以下の低温領域でこの液晶相は存在しにく
くなるために、研磨剤の分散安定性は損なわれる傾向に
ある。The anionic surfactant used as the fal component is one or more anions selected from the group consisting of polyoxyethylene alkyl ether sulfates, alkylbenzene sulfonates, α-olefin sulfonates, and alkanesulfonates. Although any surfactant can be used,
In terms of its mild feel on hand skin, polyoxyethylene alkyl ether sulfate R+0 (CHzCflzO)llSOJ is represented by the following general formula (wherein R1 is a linear or branched alkyl group or alkenyl group having 9 to 15 carbon atoms). , n is a real number on average from 0.5 to 7, and H is an alkali metal, an alkaline earth metal, an ammonium group, or an alkanol-substituted ammonium group). If the number of carbon atoms is less than 9, the cleaning performance is low;
Moreover, if it is 16 or more, not only the rinsing properties are markedly lowered, but also the abrasive of the composition tends to precipitate, which tends to impair the stability over time, which is not preferable. The particularly preferred carbon number is in the range of 10 to 13. In addition, the number n of moles of ethylene oxide added during formation should be within the average range of 0.5 to 7 in order to obtain a region where a stable liquid crystal phase exists over a wide temperature range or a region where the amount of solubilization is increased. is preferred. Outside this range, the liquid crystal phase becomes difficult to exist at high temperatures above 35°C or low temperatures below -5°C, and the dispersion stability of the abrasive tends to be impaired.
更に０．５未満の場合は手肌に対する刺激性を増加させ
る傾向にある。特に好ましいエチレンオキサイド付加モ
ル数ｎば２．０〜５．５の範囲である。さらに式中のＨ
はカリウムやナトリウムなどのアルカリ金属、又はマグ
ネシウムやカルシウムなどのアルカリ土類金属、アンモ
ニウム残基、ジェタノール置換アンモニウム残基やモノ
エタノール置換アンモニウム残基などのアルカノール置
換アンモニウム残基である。Furthermore, if it is less than 0.5, irritation to hand skin tends to increase. The particularly preferable number of moles of ethylene oxide added is in the range of 2.0 to 5.5. Furthermore, H in the formula
is an alkali metal such as potassium or sodium, or an alkaline earth metal such as magnesium or calcium, an ammonium residue, or an alkanol-substituted ammonium residue such as a jetanol-substituted ammonium residue or a monoethanol-substituted ammonium residue.
本発明に於ける前記（ａ）成分の含有量は３〜２５重量
％の範囲であって、この含有量が３重計％未満では洗浄
力・起泡力が不十分であり、また２５重量％を超えると
組成物の安定性が悪くなる。好ましい含有量は８〜１２
重量％の範囲である。The content of the component (a) in the present invention is in the range of 3 to 25% by weight, and if this content is less than 3% by weight, the detergency and foaming power will be insufficient, and if the content is less than 3% by weight, %, the stability of the composition deteriorates. The preferred content is 8-12
% by weight.
本発明の組成物に於いて（ｂ）成分として用いる千ノ直
鎖アルキル第３級アミンオキシドとしては、次の一般式
％式％
（式中のＲ２は炭素数１２〜１４の直鎖状又は分岐状ア
ルキル基及びＲ３，Ｒ４はメチル基又はエチル基である
）
で表わされる千ノ直鎖アルキルジ短鎖アルキル第３級ア
ミンオキシドが好ましい。Ｒ２の炭素数が１２未満では
組成物の洗浄性能が低く、また１４を超えると経時的安
定性が損なわれるので好ましくない。また−形成中のＲ
３及びＲ４はメチル基又はエチル基であり、これらは同
一であってもよいし、互いに異なってもよい。この第３
級アミンオキシドは洗浄剤組成物中１〜１０重量％の割
合で含有することが必要であり、含有量が前記範囲を逸
脱すると、（ａｌ成分との組み合わせに於いての洗浄力
が低くなるか又は安定性が損なわれる。The 1,000,000 straight chain alkyl tertiary amine oxide used as component (b) in the composition of the present invention has the following general formula % (in which R2 is a straight chain having 12 to 14 carbon atoms or A branched alkyl group and R3 and R4 are methyl or ethyl groups are preferred. If the number of carbon atoms in R2 is less than 12, the cleaning performance of the composition will be low, and if it exceeds 14, the stability over time will be impaired, which is not preferable. Also - R in formation
3 and R4 are a methyl group or an ethyl group, and these may be the same or different. This third
It is necessary to contain the class amine oxide in a proportion of 1 to 10% by weight in the detergent composition, and if the content deviates from the above range, (the detergency in combination with the Al component may decrease). or stability is impaired.
本発明の組成物に於ける（ｃ）成分として用いる水溶性
無機塩としては、塩化ナトリウム、塩化カリウム、塩化
マグネシウム、硫酸マグネシウム、硝酸マグネシウムか
らなる群から選ばれる１種又は２種以上のものを何れで
も使用できる。The water-soluble inorganic salt used as component (c) in the composition of the present invention is one or more selected from the group consisting of sodium chloride, potassium chloride, magnesium chloride, magnesium sulfate, and magnesium nitrate. You can use either.
その含有量は０．１〜５重量％の範囲であって、この含
有量が０．１重量％未満では十分な添加効果が得られず
、一方５重量％を超えると組成物の安定性が悪くなる。Its content is in the range of 0.1 to 5% by weight, and if the content is less than 0.1% by weight, a sufficient addition effect cannot be obtained, while if it exceeds 5% by weight, the stability of the composition may deteriorate. Deteriorate.
好ましい含有量は０．５〜３重量％の範囲である。The preferred content is in the range of 0.5 to 3% by weight.
本発明の組成物に於ける（ｄｌ成分として用いる水不溶
性研磨剤は平均粒径が１〜１００μで、モース硬さ２〜
８をもつものである。このモース硬さが２未満では研磨
力が小さすぎるため、十分な研磨性を与えず、また８を
超えると被洗物を傷つける傾向が大きくなるので不適当
である。In the composition of the present invention, the water-insoluble abrasive used as the dl component has an average particle size of 1 to 100μ and a Mohs hardness of 2 to 100μ.
8. If the Mohs hardness is less than 2, the abrasive power is too small and it does not provide sufficient abrasiveness, and if it exceeds 8, there is a greater tendency to damage the items to be washed, which is inappropriate.
適当な研磨剤の例としては、めのう、石英、シリカ、ア
ルミナ、珪藻土、パーライト、長石、アルミノ珪酸塩、
水酸化アルミニウム、エメリー、ドロマイト、酸化マグ
ネシウム、酸化チタン、炭化珪素、ポリスチレン、ポリ
アクリレート、ナイロンなどのプラスチックの粉末、砂
などの天然粉砕物などを挙げることができる。これらは
単独で用いてもよいし、また２種以上を組み合わせて用
いてもよい。この研磨剤の粒径は１μ未満のものである
と研磨力が極めて低く、また、余り大きすぎるとステン
レス、ガラス等の基材に対する傷つけ性が生じるので好
ましくない。本発明の組成物に於いての、前記非水溶性
研磨剤の含有量は１〜２５重景％の範囲であって、この
含有量が１重量％未満では研磨力が不十分であり、また
２５重量％を超えると洗浄剤絹酸物の粘度が上昇してし
まい、容器からの出し易さなどの使用感を損なうので好
ましくない。Examples of suitable abrasives include agate, quartz, silica, alumina, diatomaceous earth, perlite, feldspar, aluminosilicates,
Examples include powders of plastics such as aluminum hydroxide, emery, dolomite, magnesium oxide, titanium oxide, silicon carbide, polystyrene, polyacrylate, and nylon, and pulverized natural products such as sand. These may be used alone or in combination of two or more. If the particle size of this abrasive is less than 1 μm, the abrasive power will be extremely low, and if it is too large, it may damage base materials such as stainless steel or glass, which is not preferable. The content of the water-insoluble abrasive in the composition of the present invention is in the range of 1 to 25% by weight, and if this content is less than 1% by weight, the polishing power is insufficient; If it exceeds 25% by weight, the viscosity of the detergent silicate increases, impairing the usability such as ease of removal from the container, which is not preferable.
好ましい含有量は５〜１５重景％重量囲である。The preferred content is in the range of 5 to 15% by weight.
また、本発明における組成物のｐＨは４．０〜６．５で
あり、このｐｌ＋が４．０未満であると皮膚に対する刺
激性、及びガラス食器の洗浄後に撥水性が残るなどの仕
上がりに対する問題や洗浄剤組成物の粘度が上昇してし
まい、容器からの出し易さなどの使用感を損なうので好
ましくない。また、ｐｌ＋が６．５を超えると構造粘性
を失い、分散安定性を損なうので好ましくない。分散安
定性、皮膚に対する低刺激性、すすぎ性の点から好まし
いｐＨは５．０〜６．５の範囲である。In addition, the pH of the composition in the present invention is 4.0 to 6.5, and if this pl+ is less than 4.0, there will be irritation to the skin and problems with the finish such as water repellency remaining after washing glassware. This is not preferable because the viscosity of the detergent composition increases, impairing the usability such as the ease of taking it out from the container. Moreover, if pl+ exceeds 6.5, structural viscosity is lost and dispersion stability is impaired, which is not preferable. The preferred pH range is from 5.0 to 6.5 in terms of dispersion stability, low irritation to the skin, and rinsability.
本発明の組成物は、水を媒体として液剤化され、適度な
使用感を与える粘度、例えば室温で８００〜２０００Ｃ
ｐになるように調製される。The composition of the present invention is made into a liquid using water as a medium, and has a viscosity of, for example, 800 to 2000C at room temperature, giving a suitable feeling of use.
It is adjusted so that p.
また、本発明の組成物には、高級脂肪酸アルカノールア
ミド、炭素数１〜６の短鎖脂肪族カルボン酸、オキシ酸
もしくはその酸性塩、酸性アミノ酸もしくはその酸性塩
、芳香族カルボン酸、ニコチン酸、カイニン酸、ソルビ
ン酸、ベンゼンスルホン酸、トルエンスルホン酸及びピ
ロリドンカルボン酸群から選ばれる１種または２種以上
の有機酸もしくはその塩を配合すればより安定で低粘度
な組成物が得られる。高級脂肪酸アルカノールアミド、
酒石酸、リンゴ酸、クエン酸などのようなオキシカルボ
ン酸が特に好ましい。配合量は０．０５〜１０重量％、
特に０．５〜５重量％が適当である。Further, the composition of the present invention includes higher fatty acid alkanolamide, short chain aliphatic carboxylic acid having 1 to 6 carbon atoms, oxyacid or its acid salt, acidic amino acid or its acid salt, aromatic carboxylic acid, nicotinic acid, A more stable and low-viscosity composition can be obtained by blending one or more organic acids or salts thereof selected from the group of kainic acid, sorbic acid, benzenesulfonic acid, toluenesulfonic acid, and pyrrolidonecarboxylic acid. higher fatty acid alkanolamide,
Particularly preferred are oxycarboxylic acids such as tartaric acid, malic acid, citric acid, and the like. The blending amount is 0.05 to 10% by weight,
Particularly suitable is 0.5 to 5% by weight.
また、本発明の組成物には、目的とする性能を損じない
範囲で、通常の液体洗浄剤組成物に用いられている他の
任意成分、例えば多価アルコールなどのハイドロトロー
プ剤、泡質改良剤としてアルケニルコハク酸、グリセリ
ン、ソルビトールや、香料、色素、防腐、防かび剤、又
は他の界面活性剤や感触向上剤としてカチオン化セルロ
ースなどの高分子物質などを、所望に応じて添加するこ
とができる。In addition, the composition of the present invention may contain other optional ingredients used in ordinary liquid cleaning compositions, such as hydrotropes such as polyhydric alcohols, foam improving agents, etc., to the extent that the desired performance is not impaired. As desired, alkenylsuccinic acid, glycerin, sorbitol, fragrances, pigments, preservatives, antifungal agents, or other surfactants and polymeric substances such as cationized cellulose as feel improvers may be added as desired. Can be done.
本発明の洗浄剤組成物は、容器から出し易いなど極めて
使い易いものであるばかりでなく、従来知られているこ
の種の洗浄剤の種にの欠点が解消され、優れた洗浄力と
研磨力及び分散安定性を有し、かつ皮膚に対する刺激性
も穏やかな実用的価値の高い研磨剤含有洗浄剤組成物で
ある。The cleaning composition of the present invention is not only extremely easy to use, such as being easy to take out from the container, but also eliminates the drawbacks of conventional cleaning agents of this type, and has excellent cleaning and polishing power. The present invention is an abrasive-containing cleaning composition that has high practical value, has dispersion stability, and is mild in irritation to the skin.
次に、実施例によって本発明をさらに詳細に説明するが
、本発明はこれら実施例によって限定されるものではな
い。Next, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited by these Examples.
実施例１
表１に示す組成物を調製し、各組成物の洗浄力、起泡力
、粘度、保存安定性及び容器からの出し易さを調べた。Example 1 The compositions shown in Table 1 were prepared, and the detergency, foaming power, viscosity, storage stability, and ease of dispensing from the container of each composition were examined.
各例中に於ける洗浄剤組成物の各種性能の測定及び評価
は次のようにして行った。The various performances of the cleaning compositions in each example were measured and evaluated as follows.
く試 験 法〉
（洗浄力）
牛脂に指示薬としてスダン■（赤色色素）を０．１重量
％添加し、この５ｇを磁性の皿（直径２５ｃｍ）に塗付
したものを洗剤、水をしみこませたスポンジでこすり洗
いし、もはや皿より牛脂が清浄にとれなくなるまでの洗
浄された皿の枚数をもって示す。Test method〉 (Cleaning power) 0.1% by weight of Sudan ■ (red pigment) was added as an indicator to beef tallow, and 5g of this was applied to a magnetic plate (diameter 25cm), which was soaked with detergent and water. It is indicated by the number of dishes that have been cleaned until the tallow can no longer be removed by scrubbing them with a clean sponge.
（起泡力）
汚れ成分として市販のバターを洗剤濃度０．５重量％の
洗剤溶液に０．１重量％添加したときの起泡力を測定す
る。測定法は直径５ｃｍのガラス円筒にバターを添加し
た上記洗剤溶液を入れ、５分間回転攪拌を行い、停止後
の泡高を測定する。(Foaming power) The foaming power is measured when 0.1% by weight of commercially available butter is added as a stain component to a detergent solution having a detergent concentration of 0.5% by weight. The measurement method is to put the detergent solution to which butter has been added into a glass cylinder with a diameter of 5 cm, rotate and stir for 5 minutes, and measure the foam height after stopping.
（粘 度）
各組成物を２０℃に保った粘度ビーカーに入れ、Ｂ型粘
度計（ローター階３．２０００ｃρを超えるときはロー
ター階４；回転数６Ｏｒｐｍ）を用いて測定する。(Viscosity) Each composition is placed in a viscosity beaker maintained at 20° C., and measured using a B-type viscometer (rotor floor 4 when it exceeds 2000 cρ; rotation speed 6 Orpm).
（保存安定性）
各組成物１００ｍ１を内径４０ｍｍ、高さ７０ｍｍの１
００ｍ１ガラス瓶に採取し、密栓後で３か月保存したと
きの外観を肉眼観察する。このときの判定基準は以下の
通りとする。(Storage stability) 100 ml of each composition was placed in a container with an inner diameter of 40 mm and a height of 70 mm.
The sample was collected in a 00ml glass bottle, and the external appearance was observed with the naked eye after being stored for 3 months after sealing. The criteria for judgment at this time are as follows.
○・・・分離せず（安定）
△・・・やや分離する
×・・・完全に分離する
（容器からの出し易さ）
各組成物の市販の台所用洗剤の容器（６００ｍｌ）に１
５０＋ｎｌ充填したものを、角度４５°の傾斜をつけた
支持台に固定し、荷重２ｋｇの鉛のおもりを載せたとき
に容器キャンプ（口径３ 、０ｍｍ）からでる組成物の
重量を測定した。このときの判定基準は以下の通りであ
る。○: Does not separate (stable) △: Slightly separates ×: Completely separates (easy to remove from container) 1 ml per commercially available kitchen detergent container (600 ml) of each composition
The 50+nl filled container was fixed to a support stand inclined at an angle of 45°, and a lead weight with a load of 2 kg was placed on it, and the weight of the composition coming out of the container camp (caliber 3, 0 mm) was measured. The judgment criteria at this time are as follows.
○・・・７．０ｇ以上 □出し易い△・・・３．
０ｇ以上７．０ｇ未未満中や出し易い×・・・３．０ｇ
未満 □出しにくい実施例２
表２に示す組成物を調製し洗浄力、起泡力、粘度、保存
安定性及び容器からの出し易さを調べた。このとき容器
からの出し易さについては、主婦３０名に実際に家庭で
使ってもらい、次のように評価してもらった。○...More than 7.0g □Easy to take out△...3.
0g or more but less than 7.0g Medium or easy to dispense ×...3.0g
Less than □Difficult to take out Example 2 The compositions shown in Table 2 were prepared and examined for detergency, foaming power, viscosity, storage stability, and ease of taking out from the container. Regarding the ease of taking the product out of the container, 30 housewives actually used it at home and evaluated it as follows.
（評価法） ＋２・・・非常に出し易い ＋１・・・出し易い ０・・・どちらともいえない −１・・・やや出しにくい −２・・・出しにくい 表 ２ 本１：表中、「発」は本発明、「比」は欣列である。(Evaluation method) +2...Very easy to get out +1...Easy to put out 0...I can't say either -1: Slightly difficult to release -2...Difficult to release Table 2 Book 1: In the table, "departure" means the present invention, and "ratio" means the present invention.
＊２：土木工業社製ｒＴＭｃ−２００Ｊ （平均粒径
２０μ、モース硬度７）＊３ ： Ｒ，Ｔ、 Ｖａｎｄ
ｅｒｂｉｌｔ社製 ＶＥＥＧＬＩＭ Ｔ手続主甫正書印
発）
昭和６１年９月５日*2: rTMc-200J manufactured by Civil Engineering Co., Ltd. (average particle size 20μ, Mohs hardness 7) *3: R, T, Vand
Manufactured by erbilt VEEGLIM T procedure master official seal) September 5, 1986
Claims (1)
アルキルベンゼンスルホン酸塩、α −オレフィンスルホン酸塩及びアルカンス ルホン酸塩からなる群より選ばれる１種又 は２種以上の陰イオン性界面活性剤３〜２５重量％ （ｂ）モノ直鎖アルキル第３級アミンオキシド１〜１０
重量％ （ｃ）塩化ナトリウム、塩化カリウム、塩化マグネシウ
ム、硫酸マグネシウムおよび硝酸 マグネシウムからなる群より選ばれる１種 又は２種以上の水溶性無機塩０．１〜５重量％ （ｄ）平均粒径１〜１００μでモース硬さ２〜８をもつ
水不溶性研磨剤１〜２５重量％ を含有し、かつ組成物のｐＨが４．０〜６．５であるこ
とを特徴とする研磨剤含有洗浄剤組成物。[Claims] 1(a) polyoxyethylene alkyl ether sulfate,
3 to 25% by weight of one or more anionic surfactants selected from the group consisting of alkylbenzene sulfonates, α-olefin sulfonates, and alkanesulfonates (b) Monolinear tertiary alkyl Amine oxide 1-10
Weight % (c) 0.1 to 5 weight % of one or more water-soluble inorganic salts selected from the group consisting of sodium chloride, potassium chloride, magnesium chloride, magnesium sulfate, and magnesium nitrate (d) Average particle size 1 An abrasive-containing cleaning composition comprising 1 to 25% by weight of a water-insoluble abrasive having a Mohs hardness of 2 to 8 and a pH of 4.0 to 6.5. thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18660486A JPS6341598A (en) | 1986-08-08 | 1986-08-08 | Detergent composition containing abrasive agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18660486A JPS6341598A (en) | 1986-08-08 | 1986-08-08 | Detergent composition containing abrasive agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6341598A true JPS6341598A (en) | 1988-02-22 |
Family
ID=16191472
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18660486A Pending JPS6341598A (en) | 1986-08-08 | 1986-08-08 | Detergent composition containing abrasive agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6341598A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0379700A (en) * | 1989-08-22 | 1991-04-04 | Kao Corp | Liquid detergent composition for rigid surface |
| WO2002090477A3 (en) * | 2001-05-04 | 2007-10-25 | Unilever Nv | Liquid abrasive cleaning compositions |
-
1986
- 1986-08-08 JP JP18660486A patent/JPS6341598A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0379700A (en) * | 1989-08-22 | 1991-04-04 | Kao Corp | Liquid detergent composition for rigid surface |
| WO2002090477A3 (en) * | 2001-05-04 | 2007-10-25 | Unilever Nv | Liquid abrasive cleaning compositions |
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