JPH0379700A - Liquid detergent composition for rigid surface - Google Patents
Liquid detergent composition for rigid surfaceInfo
- Publication number
- JPH0379700A JPH0379700A JP21573789A JP21573789A JPH0379700A JP H0379700 A JPH0379700 A JP H0379700A JP 21573789 A JP21573789 A JP 21573789A JP 21573789 A JP21573789 A JP 21573789A JP H0379700 A JPH0379700 A JP H0379700A
- Authority
- JP
- Japan
- Prior art keywords
- surfactant
- hard surface
- composition
- alcohol
- surface liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 239000007788 liquid Substances 0.000 title claims description 16
- 239000003599 detergent Substances 0.000 title description 2
- 238000004140 cleaning Methods 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 12
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 9
- -1 aluminium halides Chemical class 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 6
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 6
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims abstract description 5
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 4
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 4
- 239000011701 zinc Substances 0.000 claims abstract description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 239000011369 resultant mixture Substances 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- UJBNRBMVPYBYKS-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol;ethanol Chemical compound CCO.CCCCOCCOCCO UJBNRBMVPYBYKS-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- UNMYWSMUMWPJLR-UHFFFAOYSA-L Calcium iodide Chemical compound [Ca+2].[I-].[I-] UNMYWSMUMWPJLR-UHFFFAOYSA-L 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- QNHKJSKLKSGFJF-UHFFFAOYSA-N [Br].[Ca] Chemical compound [Br].[Ca] QNHKJSKLKSGFJF-UHFFFAOYSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229940046413 calcium iodide Drugs 0.000 description 1
- 229910001640 calcium iodide Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野］
本発明はリビング、キッチン、トイレ等の硬質表面を清
掃・殺菌するのに適した硬質表面液体洗浄剤組成物に関
するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a hard surface liquid cleaning composition suitable for cleaning and disinfecting hard surfaces in living rooms, kitchens, toilets, etc.
［従来の技術及びその課題］
硬質表面に付着した汚れは、その直後に洗浄すれば容易
に脱落できるが、一般にはそのまま長期間放置されるこ
とになり、頑固に硬質表面に沈着するようになる。その
ために硬質表面液体洗浄剤には界面活性剤以外の成分と
してアルカリ剤、酸、次亜塩素酸ナトリウム、過炭酸ナ
トリウムあるいは溶剤の如き強力な薬剤が使用されてい
る。[Prior art and its problems] Dirt that has adhered to a hard surface can be easily removed by washing it immediately after cleaning, but in general, if it is left as it is for a long period of time, it becomes stubbornly deposited on the hard surface. . For this reason, strong agents such as alkaline agents, acids, sodium hypochlorite, sodium percarbonate, or solvents are used as ingredients other than surfactants in hard surface liquid cleaning agents.
硬質表面の洗浄においては、汚れを除去するのは当然で
あるが、その材質の損傷を防止するような配慮も必要と
なる。材質の損傷の例としては、金属腐食、木、例えば
白木の黄変化、コンクリート、タイル目地の損傷等があ
り、それぞれの対策が提案されている。When cleaning hard surfaces, it is natural to remove dirt, but care must also be taken to prevent damage to the material. Examples of material damage include metal corrosion, yellowing of wood, for example, plain wood, and damage to concrete and tile joints, and countermeasures have been proposed for each.
これらの材質に比較してプラスチックは一般的には耐化
学薬品性があるものとされ、各種の用途に使用されてい
る。しかしながら、ある種のプラスチック製品を硬質表
面液体洗浄剤で洗浄すると損傷を受けることが判明した
。そのようなプラスチック製品としては例えば、ポリカ
−ボネート製の電溶の傘、ＡＢＳ（アクリロニトリル／
ブタジェン／スチレン共重合体）製の便座等が挙げられ
る。これらの表面を硬質表面液体洗浄剤で洗浄するとヒ
ビ割れが発生することがある。Compared to these materials, plastic is generally considered to be more resistant to chemicals and is used for a variety of purposes. However, it has been found that certain plastic items can be damaged when cleaned with hard surface liquid cleaners. Examples of such plastic products include polycarbonate electrolyte umbrellas and ABS (acrylonitrile/
butadiene/styrene copolymer) toilet seats, etc. Cracking may occur when cleaning these surfaces with hard surface liquid cleaners.
その原因としては、アルキレンオキサイド付加タイプの
界面活性剤及び１価アルコール（但し炭素数１〜４のア
ルコール、例えばエチルアルコール、プロピルアルコー
ル等はプラスチックに損傷を与えないので除かれる）又
は多価アルコール及びその誘導体である溶剤を含有した
洗浄剤を用いたことと、かかる洗浄剤のｐＨがプラスチ
ック製品に影響すること等の理由によるものと推定され
る。The causes include alkylene oxide addition type surfactants, monohydric alcohols (however, alcohols with 1 to 4 carbon atoms, such as ethyl alcohol and propyl alcohol, are excluded because they do not damage the plastic), or polyhydric alcohols. This is presumed to be due to the use of a cleaning agent containing a solvent that is a derivative thereof, and the fact that the pH of this cleaning agent affects plastic products.
〔課題を解決するための手段］
本発明者らは上記の課題を解決すべく鋭意検討した結果
、ポリアルキレンオキサイド部分を有する界面活性剤及
び／又は溶剤を含有してなる洗浄剤であっても、かかる
洗浄剤に特定の金属化合物を添加し、また洗浄剤のｐＨ
を調整することによってプラスチックの劣化を防止でき
ることを見出し本発明を完成するに至った。[Means for Solving the Problems] As a result of intensive studies by the present inventors to solve the above problems, the present inventors found that even if the cleaning agent contains a surfactant and/or a solvent having a polyalkylene oxide moiety, , adding specific metal compounds to such cleaning agents, and adjusting the pH of the cleaning agents.
The inventors discovered that deterioration of plastics can be prevented by adjusting the amount, and completed the present invention.
すなわち本発明は、ポリアルキレンオキサイド部分を有
する界面活性剤及び／又は１価アルコール、多価アルコ
ール又はこれらの誘導体である溶剤を含有する硬質表面
液体洗浄剤ｍｒｆｉ、物において、アルカリ土類金属、
アルミニウム又は亜鉛のハロゲン化物及び硫酸亜鉛から
選ばれた１種又は２種以上の水溶性無機金属塩を組成物
中に０．１〜５重量％含有せしめ、且つ組成物のｐＨが
４〜１２であることを特徴とする硬質表面液体洗浄剤組
成物を提供するものである。That is, the present invention provides a hard surface liquid cleaning agent mrfi containing a surfactant having a polyalkylene oxide moiety and/or a solvent that is a monohydric alcohol, a polyhydric alcohol, or a derivative thereof.
The composition contains 0.1 to 5% by weight of one or more water-soluble inorganic metal salts selected from aluminum or zinc halides and zinc sulfate, and the pH of the composition is 4 to 12. A hard surface liquid cleaning composition is provided.
本発明の硬質表面液体洗浄剤組成物に用いられる界面活
性剤としてはポリアルキレンオキサイド部分を有する界
面活性剤、具体的には炭素数８〜２２の直鎖又は分岐鎖
を有する高級アルコールのポリエチレンオキサイド付加
物、炭素数８〜２２の直鎖又は分岐鎖を有するアルキル
フェノールポリエチレンオキサイド付加物、エチレンオ
キサイドとプロピレンオキサイドとのブロックポリマー
等の非イオン界面活性剤、あるいはそれらの非イオン末
端を硫酸化、カルボキシル化、リン酸エステル化等した
アニオン活性剤、又はカチオン化あるいは両性化した活
性剤等が挙げられる。The surfactant used in the hard surface liquid cleaning composition of the present invention is a surfactant having a polyalkylene oxide moiety, specifically polyethylene oxide of a higher alcohol having a linear or branched chain having 8 to 22 carbon atoms. Nonionic surfactants such as adducts, linear or branched alkylphenol polyethylene oxide adducts having 8 to 22 carbon atoms, block polymers of ethylene oxide and propylene oxide, or sulfated nonionic terminals, carboxyl Examples include anionic activators that have been converted into esters, phosphoric acid esters, etc., and cationic or amphoteric activators.
これらの界面活性剤は単独或いはアルキルベンゼンスル
ホン酸塩、アルキル硫酸塩、α−オレフィンスルホン酸
塩、アルキル（或いはアルケニル）スルホコハク酸塩、
アルキル（或いはアルケニル）コハク酸塩、α−スルホ
脂肪酸塩、α−スルホ脂肪酸エステル塩、石鹸等のアル
キレンオキサイド付加型の以外の界面活性剤と組み合わ
せて用いられる。These surfactants may be used alone or in the form of alkylbenzene sulfonates, alkyl sulfates, α-olefin sulfonates, alkyl (or alkenyl) sulfosuccinates,
It is used in combination with surfactants other than the alkylene oxide addition type, such as alkyl (or alkenyl) succinates, α-sulfo fatty acid salts, α-sulfo fatty acid ester salts, and soaps.
界面活性剤は、洗浄剤がエアゾール或いはトリガースプ
レーで直接対象面に散布する原液使用タイプの場合には
組成物中にｏ、ｏｉ〜５％、使用時に希釈して使用する
タイプの場合には３〜５０％配合される。The surfactant is added to the composition in the case of a undiluted type of cleaning agent that is sprayed directly onto the target surface with an aerosol or trigger spray, and 3% in the case of a type of cleaning agent that is diluted before use. ~50% is blended.
本発明の硬質表面液体洗浄剤組成物に使用される溶剤と
しては、１価アルコール、多価アルコール、又はこれら
アルコール類の誘導体（特にエステル誘導体）が挙げら
れる。具体的にはエチレングリコール、ポリエチレング
リコール、プロピレングリコール、ポリプロピレングリ
コール、ポリオキシエチレンポリオキシプロピレングリ
コール、或いはそれらグリコールと炭素数１〜８の低級
アルコールとのモノ、或いはジエステル、ヘキシレング
リコール、３−メチル−３−メトキシブタノール等が挙
げられる。溶剤は組成物中に０〜５０％配合される。Solvents used in the hard surface liquid cleaning compositions of the present invention include monohydric alcohols, polyhydric alcohols, or derivatives (especially ester derivatives) of these alcohols. Specifically, ethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, polyoxyethylene polyoxypropylene glycol, or mono- or diesters of these glycols and lower alcohols having 1 to 8 carbon atoms, hexylene glycol, and 3-methyl. -3-methoxybutanol and the like. The solvent is blended in the composition in an amount of 0 to 50%.
上記界面活性剤及び溶剤を含有する硬質表面液体洗浄剤
組成物はプラスチックにヒビ割れを発生させる原因とな
るが、本発明においては更にアルカリ土類金属、アルミ
ニウム、或いは亜鉛のハロゲン化物、硫酸亜鉛から選ば
れる水溶性の金属塩を添加することによりヒビ割れの発
生を防止することができる。The hard surface liquid cleaning composition containing the above-mentioned surfactant and solvent causes cracks in plastics, but in the present invention, it is further prepared from alkaline earth metals, aluminum, or zinc halides, and zinc sulfate. By adding a selected water-soluble metal salt, the occurrence of cracks can be prevented.
本発明の組成物に用いられる水溶性の金属塩としては、
塩化カルシウム（ＣａＣＩｚ） 、塩化マグネシウム（
ＭｇＣ１ｚ）、塩化アルミニウム（ＡＩＣｈ）、硫酸亜
鉛（ＺｎＳ０４） 、等が好適であり、また塩化亜鉛（
ＺｎＣ１ｚ）、臭化カリウム（ＫＢｒ）、ブロムカルシ
ウム（ＣａＢｒｚ）ヨウ化カルシウム（Ｃａｌ）等も使
用できる。これらの金属塩は組成物中に０．１〜５重景
％、好ましくは０．３〜３重量％配合される。The water-soluble metal salts used in the composition of the present invention include:
Calcium chloride (CaCIz), magnesium chloride (
Zinc chloride (MgC1z), aluminum chloride (AICh), zinc sulfate (ZnS04), etc. are suitable;
ZnC1z), potassium bromide (KBr), calcium bromine (CaBrz), calcium iodide (Cal), etc. can also be used. These metal salts are incorporated in the composition in an amount of 0.1 to 5 weight percent, preferably 0.3 to 3 weight percent.
配合量が０．１重量％未満では充分な効果が得られず、
また５重量％を越えると硬質表面液体洗浄剤に要求され
る貯蔵安定性等の他の性能を満足させることが容易でな
くなる。If the blending amount is less than 0.1% by weight, sufficient effects cannot be obtained,
Moreover, if it exceeds 5% by weight, it becomes difficult to satisfy other properties such as storage stability required for hard surface liquid cleaning agents.
プラスチックのヒビ割れの発生には洗浄剤組成物のｐＨ
も大、きく影響する。一般に、硬質表面液体洗浄剤には
ｐＨが強酸性からアルカリ性のものまで種々であるが、
本発明の硬質表面液体洗浄剤組成物は強酸性領域では効
果が低下するのでｐＨは４〜１２、好ましくは５〜９に
調整される。The pH of the cleaning composition is responsible for the occurrence of cracks in plastic.
It also has a big impact. In general, hard surface liquid cleaning agents vary in pH from strongly acidic to alkaline.
Since the hard surface liquid cleaning composition of the present invention becomes less effective in a strongly acidic region, the pH is adjusted to 4 to 12, preferably 5 to 9.
本発明の硬質表面液体洗浄剤組成物にはその他の成分と
して水酸化ナトリウム、水酸化カリウム、アンモニア、
モノエタノールアミン、ジェタノールアミン、トリエタ
ノ−ルアくン、ジエチルエタノールアミン等のアルカリ
剤、香料、染料、顔料、殺菌剤、金属腐食防止剤、ビル
ダーｉを必要に応じて併用することができる。Other ingredients in the hard surface liquid cleaning composition of the present invention include sodium hydroxide, potassium hydroxide, ammonia,
Alkali agents such as monoethanolamine, jetanolamine, triethanolamine, and diethylethanolamine, fragrances, dyes, pigments, bactericides, metal corrosion inhibitors, and builder i can be used in combination as necessary.
以下実施例にて本発明を説明するが、本発明はこれらの
実施例に限定されるものではない。The present invention will be explained below with reference to Examples, but the present invention is not limited to these Examples.
実施例１
ポリオキシエチレンアルキルエーテル（平均アルキル鎖
長１２；平均Ｉ！０付加モル数７）をＩ％及び表−１に
示すような金属塩を２％含有する水溶液を調製した。Example 1 An aqueous solution containing I% of polyoxyethylene alkyl ether (average alkyl chain length: 12; average number of added moles of I!0: 7) and 2% of metal salts as shown in Table 1 was prepared.
この洗浄剤水溶液を用いてＡＢＳ樹脂への損傷性を下記
の方法で評価した。Using this detergent aqueous solution, damage to ABS resin was evaluated by the following method.
＜ＡＢＳ ｉＭ脂への損傷性評価方法〉２３０ ｍ Ｘ
３５ｍｍ Ｘ ２ ｔｍのＡＢＳ樹脂（三菱モンサン
ト製）テストピースを作成する。このテストピースを直
径２６７ｍｎ１の塩ビバイブ表面に図−１のように固定
し、図−２に示す如＜ 、０．７４％の歪みを生じさせ
る。<ABS iM damage evaluation method> 230 m
A 35 mm x 2 tm ABS resin (manufactured by Mitsubishi Monsanto) test piece is prepared. This test piece was fixed on the surface of a PVC vibrator with a diameter of 267 mm as shown in Figure 1, and a strain of 0.74% was caused as shown in Figure 2.
歪みは以下の式によって求められる。Distortion is determined by the following formula.
−Ｌ
歪み（％） ＝ Ｘ１００
このように歪み、すなわち応力をかけたＡＢＳ樹脂を洗
浄剤水溶液１．７ｇを含浸した市販のティッシュペーパ
ー（乾燥時の重量でＩｇ）で１０回（ｌ往復が１回）拭
払いし、２０°Ｃ１６５％ＲＨで２４時間放置後、ＡＢ
Ｓ樹脂への損傷性を評価した。-L Strain (%) = AB
The damage to S resin was evaluated.
この時の評価基準は以下の通りである。The evaluation criteria at this time are as follows.
○：異常なし ×：ヒビ割れ有り この結果を表−１に示す。○: No abnormality ×: There are cracks The results are shown in Table-1.
表 −１
実施例２
３−メチル−３−メトキシブタノール１０％及び表−２
に示す金属塩を２％含有する水溶液を調製し、実施例１
と同様にしてＡＢＳ樹脂の損傷性を評価した。Table-1 Example 2 3-methyl-3-methoxybutanol 10% and Table-2
An aqueous solution containing 2% of the metal salt shown in Example 1 was prepared.
The damage resistance of ABS resin was evaluated in the same manner as above.
この結果を表−２に示す。The results are shown in Table-2.
表 −２
実施例３
下記組成の洗浄剤を調製し、実施例１と同様にしてＡＢ
Ｓ樹脂の損傷性を評価した。Table 2 Example 3 A cleaning agent with the following composition was prepared and AB
The damage property of S resin was evaluated.
この結果を表−３に示す。The results are shown in Table-3.
エタノール
ジエチレングリコールモノブチルエーテルポリエチレン
グリコール−２００
金属塩（ＣａＣｌｇｌＭｇＣｌｇ）
イオン交換水
０．３〜１．１
バランス
表−３
実施例４
実施例３の洗浄剤ｍ戒において、ＣａＣ１ｚ ｉ１１度
を０．５．１．０．１．５重量％になるように溶解して
、ＡＢＳ樹脂を２４時間放置する際の条件を２０°Ｃ１
６５％ＲＨから４０″Ｃ１６５％Ｒ１（に変更する以外
は実施例１と同様にして損傷性を評価した。Ethanol diethylene glycol monobutyl ether polyethylene glycol-200 Metal salt (CaClglMgClg) Ion-exchanged water 0.3-1.1 Balance table-3 Example 4 In the cleaning agent m precept of Example 3, CaC1z i11 degree was set to 0.5.1. The conditions for dissolving ABS resin to 0.1.5% by weight and leaving it for 24 hours were 20°C1.
Damage properties were evaluated in the same manner as in Example 1 except that 65%RH was changed to 40''C165%R1.
その結果を表−４に示す。The results are shown in Table 4.
表−４Table-4
図−１は実施例においてＡＢＳ樹脂に歪みを生じさせる
方法を示す略本図、図−２は歪みが生じたＡＢＳ樹脂の
断面図である。
１・・・塩ビバイブ
２・・・ＡＢＳ樹脂テストビースFIG. 1 is a schematic diagram showing a method of causing distortion in ABS resin in an example, and FIG. 2 is a cross-sectional view of the ABS resin with distortion. 1... PVC vibe 2... ABS resin test bead
Claims (1)
及び／又は１価アルコール、多価アルコール又はこれら
の誘導体である溶剤を含有する硬質表面液体洗浄剤組成
物において、アルカリ土類金属、アルミニウム又は亜鉛
のハロゲン化物及び硫酸亜鉛から選ばれた１種又は２種
以上の水溶性無機金属塩を組成物中に０．１〜５重量％
含有せしめ、且つ組成物のｐＨが４〜１２であることを
特徴とする硬質表面液体洗浄剤組成物。1. In a hard surface liquid cleaning composition containing a surfactant having a polyalkylene oxide moiety and/or a solvent that is a monohydric alcohol, a polyhydric alcohol, or a derivative thereof, an alkaline earth metal, aluminum or zinc halide and 0.1 to 5% by weight of one or more water-soluble inorganic metal salts selected from zinc sulfate in the composition.
A hard surface liquid cleaning composition characterized in that the pH of the composition is 4 to 12.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1215737A JPH0756038B2 (en) | 1989-08-22 | 1989-08-22 | Hard surface liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1215737A JPH0756038B2 (en) | 1989-08-22 | 1989-08-22 | Hard surface liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0379700A true JPH0379700A (en) | 1991-04-04 |
| JPH0756038B2 JPH0756038B2 (en) | 1995-06-14 |
Family
ID=16677363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1215737A Expired - Fee Related JPH0756038B2 (en) | 1989-08-22 | 1989-08-22 | Hard surface liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0756038B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0527625A2 (en) * | 1991-08-09 | 1993-02-17 | S.C. Johnson & Son, Inc. | Glass cleaning composition |
| US6362149B1 (en) | 2000-08-03 | 2002-03-26 | Ecolab Inc. | Plastics compatible detergent composition and method of cleaning plastics comprising reverse polyoxyalkylene block co-polymer |
| JP2002348596A (en) * | 2001-05-23 | 2002-12-04 | Kao Corp | Cleanser composition |
| WO2004003122A1 (en) * | 2002-06-29 | 2004-01-08 | Ecolab Inc. | Floor cleaning and/or floor care product |
| US10138155B2 (en) | 2013-12-03 | 2018-11-27 | Corning Incorporated | Apparatus and method for severing a moving ribbon of inorganic material |
| JP2021055215A (en) * | 2019-09-30 | 2021-04-08 | 大王製紙株式会社 | Water disintegrable sheet |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59102998A (en) * | 1982-12-06 | 1984-06-14 | 東レ株式会社 | Method of cleaning devices adhered with polyamide |
| JPS6341598A (en) * | 1986-08-08 | 1988-02-22 | 花王株式会社 | Detergent composition containing abrasive agent |
-
1989
- 1989-08-22 JP JP1215737A patent/JPH0756038B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59102998A (en) * | 1982-12-06 | 1984-06-14 | 東レ株式会社 | Method of cleaning devices adhered with polyamide |
| JPS6341598A (en) * | 1986-08-08 | 1988-02-22 | 花王株式会社 | Detergent composition containing abrasive agent |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0527625A2 (en) * | 1991-08-09 | 1993-02-17 | S.C. Johnson & Son, Inc. | Glass cleaning composition |
| US5750482A (en) * | 1991-08-09 | 1998-05-12 | S. C. Johnson & Son, Inc. | Glass cleaning composition |
| US6362149B1 (en) | 2000-08-03 | 2002-03-26 | Ecolab Inc. | Plastics compatible detergent composition and method of cleaning plastics comprising reverse polyoxyalkylene block co-polymer |
| US6838422B2 (en) | 2000-08-03 | 2005-01-04 | Ecolab Inc. | Plastics compatible detergent composition and method of cleaning plastics |
| JP2002348596A (en) * | 2001-05-23 | 2002-12-04 | Kao Corp | Cleanser composition |
| WO2004003122A1 (en) * | 2002-06-29 | 2004-01-08 | Ecolab Inc. | Floor cleaning and/or floor care product |
| US7563759B2 (en) | 2002-06-29 | 2009-07-21 | Ecolab Inc. | Floor cleaning and care compositions comprising two nonionic surfactants |
| US10138155B2 (en) | 2013-12-03 | 2018-11-27 | Corning Incorporated | Apparatus and method for severing a moving ribbon of inorganic material |
| JP2021055215A (en) * | 2019-09-30 | 2021-04-08 | 大王製紙株式会社 | Water disintegrable sheet |
| WO2021065423A1 (en) * | 2019-09-30 | 2021-04-08 | 大王製紙株式会社 | Hydrolyzable sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0756038B2 (en) | 1995-06-14 |
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