JPS63250658A - One component toner - Google Patents
One component tonerInfo
- Publication number
- JPS63250658A JPS63250658A JP62085140A JP8514087A JPS63250658A JP S63250658 A JPS63250658 A JP S63250658A JP 62085140 A JP62085140 A JP 62085140A JP 8514087 A JP8514087 A JP 8514087A JP S63250658 A JPS63250658 A JP S63250658A
- Authority
- JP
- Japan
- Prior art keywords
- toner
- nuclei
- insulating material
- type semiconductor
- development
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004065 semiconductor Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 9
- 239000000696 magnetic material Substances 0.000 claims abstract description 8
- 239000011230 binding agent Substances 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims abstract description 5
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 5
- QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000000463 material Substances 0.000 claims description 10
- 238000004040 coloring Methods 0.000 claims description 3
- 239000011810 insulating material Substances 0.000 abstract description 17
- 238000002347 injection Methods 0.000 abstract description 7
- 239000007924 injection Substances 0.000 abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- 230000002209 hydrophobic effect Effects 0.000 abstract description 3
- 239000008119 colloidal silica Substances 0.000 abstract description 2
- -1 etc. Substances 0.000 abstract description 2
- 229910001566 austenite Inorganic materials 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 1
- 238000000034 method Methods 0.000 description 25
- 238000007639 printing Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 241001531478 Trigonium Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 241001342990 Xylia Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 239000006247 magnetic powder Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/097—Plasticisers; Charge controlling agents
- G03G9/09708—Inorganic compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- G03G9/08726—Polymers of unsaturated acids or derivatives thereof
- G03G9/08731—Polymers of nitriles
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/09—Colouring agents for toner particles
- G03G9/0906—Organic dyes
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野〕
本発明は、電子写Ｊ’Ｌで使用される一成分トリ・−の
ミ１１成及び構造に閃する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention is directed to the composition and structure of a one-component tri-layer used in electrophotography J'L.
近年、電子写真技術を利用した印刷装置が種々実用化し
利用されるに至っている。この技術において利用されて
いるトナーについて概説すると、［カールソンプロセス
」を利用した印刷装置の場合は、２成分磁気ブラシ現像
法やフロート電極効果現像法＜ ｒ： ＋： Ｅ Ｄ法
）においては絶縁性非磁性トリー−、ジャンピング現像
法においては絶縁性磁性トナーが用いられており、エレ
クトロファクスの場合には、導電性磁性トナーが用いら
れている。また、最近では、プ１」セスの大幅な商略化
の可能を秘める、露光と現像を１１時に行なって画像を
形成する新しい電子写真技術を利用した方法（以ＩＳ１
同時法と呼ぶ）が、各所で倹ｉＦされ、例えば特開昭５
８−１５３９５７にｔ！２案されている。この同ｎｒｉ
法によれば、従来の電子写真技術による印刷装置７ｒで
必要である、帯電器、除電器、クリーリ゛の各プロセス
が不要となり、また排トリ・−も生じない為、プロセス
の囲路化とトナーの節約が図れ、装置の小型化、低コス
ト化が可能となる。この同時法を概説すると、露光中に
バイアス電圧を印加した導電性磁性トナーのブラシで、
光導電体層を含んでいるＮＮ像形成体の表面を擦過する
方ｌＪ：が最適の現像法として考えられており、光導電
体が絶縁体として作用する時（未露光部）と、ｆＪ電体
として作用する時（露光部）（！−で、バイアス電圧に
よる画像形成表面に［＆触しているトリーへの１．ＩＥ
人電何量にちがいが生じ、その電何量のＸ：か画像形成
（ト表面への静電ＣＩ’ ｒ：力の差となってトナー画
像形成が可能となっている。In recent years, various printing devices using electrophotographic technology have been put into practical use and used. To give an overview of the toners used in this technology, in the case of printing devices using the Carlson process, insulating toners are used in two-component magnetic brush development method and float electrode effect development method Insulating magnetic toner is used in non-magnetic tree and jumping development methods, and conductive magnetic toner is used in electrofaxing. Recently, a method using new electrophotographic technology (hereinafter referred to as "IS1") that forms images by performing exposure and development at 11 o'clock has been developed, which has the potential to significantly commercialize the IS1 process.
(referred to as the simultaneous method) has been used extensively in various places, for example, in JP-A-5
T on 8-153957! Two proposals have been proposed. This same nri
According to the law, the processes of chargers, static eliminators, and cleaners that are required in conventional electrophotographic printing equipment 7r are no longer required, and there is no discharge, so the process can be enclosed. Toner can be saved, and the device can be made smaller and lower in cost. To outline this simultaneous method, a brush of conductive magnetic toner is applied with a bias voltage during exposure.
The method of rubbing the surface of the NN image forming body containing the photoconductor layer is considered to be the optimal development method, and when the photoconductor acts as an insulator (unexposed area) and when the fJ voltage is When acting as a body (exposure section) (!-, the imaging surface by a bias voltage [& 1.IE to the tree touching
There is a difference in the amount of human electricity, and the difference in the amount of electricity X: image formation (electrostatic CI' r: force on the surface) makes it possible to form a toner image.
しかし、同時法で用いるトリー−は、そのミノ４性のた
めに、トリ°−の電荷が短い緩和１１１７間で中和され
、紙への静電付着力が弱まるので、周知の静電転”Ｔ
ｌｌζでは、紙への転ＴＩ率が低下する。特に高湿時に
おいては紙への導電性が高まり、紙からトナーへ逆極性
の電荷注入が生じる結果、周知の静電転写法では紙への
転写が全くできなくなるという欠点をイｒしていた。However, due to the mini-4 nature of the trees used in the simultaneous method, the electric charge of the trees is neutralized during a short relaxation period, weakening the electrostatic adhesion to the paper, and this is due to the well-known electrostatic transfer. T
At llζ, the transfer TI rate to paper decreases. Particularly in high humidity conditions, the electrical conductivity of the paper increases, causing charge injection of the opposite polarity from the paper to the toner, which eliminates the drawback that the well-known electrostatic transfer method cannot transfer to paper at all. .
本発明の目的は、同時法において現（Ｑが可能で、かつ
コ１１す“転写法で′Ｂ通紙への転写が行なえるトナー
を提供する平にある。It is an object of the present invention to provide a toner that can be transferred to a passing paper using a simultaneous transfer method and a transfer method using a transfer method.
本発明における一成分トナーは↑＋’ｉ首セＪ４指とし
て熱可りｚ芝Ｔｉ ４３＋脂、：１′、導体材として、
Ｎ型゛１１ξ体であるＩ／、＋化水銀（ｂ Ｉ ａ ｃ
ｋ ） （ＩＩ ＨＳ ）を用い、その他イ′１色
材と磁性材を加えてなる゛１′−導体トリ“−の表面に
、絶縁性物質を被覆率ｌＯ〜００％にコーテイングする
事を特徴とする。The one-component toner in the present invention is ↑ + 'i neck se J4 finger as heatable z Shiba Ti 43 + fat, :1', as conductor material.
Mercury chloride (b I a c
k) (II HS), and is characterized by coating the surface of the ``1''-conductor tri'', which is made by adding coloring material and magnetic material, with an insulating material to a coverage rate of 10 to 00%. shall be.
本発明の上記の！＋’？成によれば、同時ｔノＪにおけ
る像形成１１１！の画像形成体表面に接触しているトリ
゛−への電゛荷注入はＮ型゛ｒ）０体の負の、＋ｒ・シ
リアの移動によって行ない、転７Ｔ ”ｊの紙への静電
（４’ ４’？カは、紙との接触により、注入されたキ
シリアが紙を通して中和されるのるで、逆極性（正）の
電荷注入は行なわれないため、あらかじめ帯電させであ
るトナー拉ｒ・表面の絶縁性部の電荷に１Ｕ当させる７
１ｊによって静電転写を行う事ができる。The above of the present invention! +'? According to Seiji, image formation at the same time t no J 111! The charge injection into the trigonium in contact with the surface of the image forming body is carried out by the movement of the negative +r Syria of the N-type ゛r) 0 body, and the electrostatic charge ( 4'4'?The reason is that the injected xylia is neutralized through the paper by contact with the paper, so there is no reverse polarity (positive) charge injection, so the toner is pre-charged. r・Apply 1U to the charge of the insulating part on the surface 7
1j enables electrostatic transfer.
第１図に、本発明の実施例におけるトリ°−の断面図を
示す。本発明におけるトリ゛−は結ｆ１樹脂１の中に、
半導体材２、磁性材３、σ１ｔ１４とその他添加剤が分
散したトリ゛−核５の表面に絶縁材６が点在している（
１１４造となっている。バインダーＪａｌ ｌｌｔとし
ては、通常使用されている公知の熱可塑性樹脂であるも
のが望ましく、ボリスチレ／及びその共重合体、ポリエ
ステル及びその共重合体、ポリエヂレ／及びその共重合
体、アクリル系樹脂、ビニル系（に・１脂などが弔独あ
るいはｌ足台して用いる。FIG. 1 shows a sectional view of a tray in an embodiment of the present invention. In the present invention, the trie is in the resin 1,
Insulating materials 6 are dotted on the surface of trigonium 5 in which semiconductor material 2, magnetic material 3, σ1t14 and other additives are dispersed (
It is made of 114 buildings. The binder Jal llt is desirably a commonly used thermoplastic resin, such as polyethylene/and its copolymer, polyester and its copolymer, polyester/and its copolymer, acrylic resin, vinyl, etc. Types (ni, 1 fat, etc.) are used as condolences or l footstools.
磁性材としては、公知の磁性体粉末である、四三酸化鉄
、γ−酸化第二鉄、二酸化り（ｌ Ｉ−ｓ、ニラゲルフ
ェライト、鉄合金粉末などを用いる。Ｍ ｆ：［として
は、カーボンプラ・ツク、スピリットブラック、ニゲＩ
ノシンなどを用いる。さらにその他の添加剤として、流
動性向上化剤を添加するのが好ましい。As the magnetic material, known magnetic powders such as triiron tetroxide, γ-ferric oxide, sulfur dioxide (I-s), nila gel ferrite, iron alloy powder, etc. are used. , Carbon Pla Tsuku, Spirit Black, Nige I
Use Nosine etc. Furthermore, it is preferable to add a fluidity improver as another additive.
又、本トリ”−に使用する絶縁性物質としては、疎水性
コロイダルシリカあるいはシリカ微粒子を使用する。Further, as the insulating material used in this case, hydrophobic colloidal silica or silica fine particles are used.
上記＋１；ｆ ｆ′）を使用してトリー−核５を製造す
る方法としては、混１：Ｉｔ 、粉砕法及びスプレー法
を用いることができる。さらに該トナー核５に、絶縁性
物７′ｉを所定１１１被覆する方法としては、熱気流中
＾即ｌノ：及びボールミル処理法で被覆後、高外気温あ
るいは、超音波振動により絶縁性物質を所定量除去する
ことにより行なわれる。As a method for producing the tree core 5 using the above +1; f f'), mixing 1:It, a pulverization method, and a spray method can be used. Furthermore, as a method of coating the toner cores 5 with a predetermined amount of the insulating material 7'i, the insulating material 7'i is coated immediately in a hot air stream and by a ball milling method, and then the insulating material 7'i is coated with the insulating material 7'i at high outside temperature or by ultrasonic vibration. This is done by removing a predetermined amount of.
〔実ｈ１１１例１〕
熱１＋７塑＋’＋ １７４脂として、１！リアクリ１１
ントリル（１１ＡＮ）、’１′−存体材として硫化水銀
（１１５：Ｓ）％磁ｔ’＋： ＋４としてγ−酸化鉄１
．Ｔ７色剤としてスピリットブラックを用い、表１に示
す、９１１成にＩｉ；ｆ ｊ）を秤１１１し、該１’、
；ｉ ｎをアセトンにｉ８解、分散してスプレー法で１
０〜１５μｍのｌ・す“−核を製造した。次に上記トリ
ー核に絶縁性物質として疎水性Ｔｌ ｒＪイダルシリノ
Ｊを用いて、ボールミル
超１“７波振動により表２に示−Ｊ、ＩＪｉ定の被覆率
にＪ．！Ｊ整してトリー−を製造した。表面被覆率は、
Ｓｌζ間及び゛「ＩζＮ１写Ｊ’（より求めた。[Actual h111 example 1] As heat 1 + 7 plastic + '+ 174 fat, 1! Reakuri 11
(11AN), '1'-mercury sulfide (115:S) as existing material, % magnetic t'+: γ-iron oxide 1 as +4
．． Using spirit black as the T7 coloring agent, the 911 compositions shown in Table 1 were weighed, and the 1',
;I 8 solution in acetone, disperse and spray 1
A 0 to 15 μm l·S"-nucleus was produced. Next, using hydrophobic Tl rJ Idarsilino J as an insulating material on the above tree nucleus, a ball mill ultra 1" 7-wave vibration was applied to the tree nucleus as shown in Table 2. J. ! A tree was prepared by preparing J. The surface coverage is
Between Slζ and ``IζN1 copy J' (obtained from.
表１
表２
次にこの・す゛ンプルＮｏ、１〜４のトリ°−咳に、各
々、表２のＡ −１）の被覆率を施した一成分トリ°−
を用いて、同１１′７法により、現像、転写、定着を行
なったところ、良好な定管像を得ることができた。Table 1 Table 2 Next, the one-component tri-cough samples Nos. 1 to 4 were each given the coverage of A-1) in Table 2.
When development, transfer and fixing were carried out using the same 11'7 method, a good fixed tube image could be obtained.
〔比較例１〕
〔実施例１〕と同（、′Ｑな原料と製造方法により表３
に示すトリ・−核を製造し、表４に示す被覆率を施した
。[Comparative Example 1] Same as [Example 1] (Table 3)
The tri-core shown in Table 4 was produced and the coverage shown in Table 4 was applied.
表３
表４
次にこのサンプルＮｏ、５〜８のトリ°−核に、各々表
４のＩＥ〜１１の被覆率を施した一成分トリ゛−を用い
て、現像、転写、定行を行なったところ、良好な定着像
を得る事ができなかった。この原因は、ＩＩ ｓｒ Ｓ
の含有はが５０％を超えると樹脂と磁１′１．材の割合
が少なくなり、現像あるいは定刻ができなくなるからで
ある。またＩＩ ｆｆ Ｓの含イｆ量が２０％より少な
くなると樹脂が半導電性を示さなくなり現像を行なうこ
とができない。従ってＩＩ ｆｆ Ｓの含イｒ’ 、２
ｔは２０〜５０％が好ましい。また絶縁性物質の被覆率
については、００％を超えると充分な電イ：ｉｊｌ二人
が行なわれず、現像を行なうことができない、また１０
％より少なくなると帯電ｈｔが不足して転写を行なう事
ができない。従って絶縁性物質の肢ＩＭ率は１０〜９０
％が好ましい。Table 3 Table 4 Next, development, transfer, and regular printing were performed on the sample No. 5 to 8 tri-nuclei using one-component tri-nuclei having coverage rates of IE to 11 in Table 4, respectively. However, a good fixed image could not be obtained. The cause of this is II sr S
If the content exceeds 50%, resin and magnetic 1'1. This is because the proportion of the material decreases, making it impossible to develop or engrave. Further, when the i f content of II ff S is less than 20%, the resin exhibits no semiconductivity and development cannot be performed. Therefore, the inclusion r' of II ff S, 2
t is preferably 20 to 50%. Regarding the coverage rate of the insulating material, if it exceeds 00%, sufficient electricity will not be applied and development will not be possible.
%, charging ht is insufficient and transfer cannot be performed. Therefore, the limb IM rate of insulating materials is 10-90
% is preferred.
〔実施例２〕
熱可塑性（÷１脂としてアクリル樹脂、半導体材として
ＩＩ Ｉｒ Ｓ 、磁性材として四三酸化鉄、４ｒｒ色
剤としてニゲｌＩシンを用い、〔実施例Ｉ〕の表１と同
Ｆｉの４・１１成に秤けする。その後スクリュー押出機
で混練、ジ、ットミルで’ｔｂ ｅ）砕、気流分級機で
分級のプ［Ｉセスを行ない１０〜貫５μｍのトリ・−？
亥を製造した。次に」二足トリ゛−値に絶縁性物質とじ
て峠水性：Ｉ Ｉ＋イダルシリ力を用いて、〔実施例１
〕の表２とト１１．Ｔｌ！な被覆率になる様に、秤Ｌｔ
Ｌ 、−に記トナー核とｆＩＸ、合後、熱気流中にＩ
！ＩＴ霧して被覆を行なった。ｋ面被ｉＸｌ率はＳ Ｅ
Ｍ及びＴＩζＭより求めた。[Example 2] Same as Table 1 of [Example I] using thermoplastic (÷1) acrylic resin as the resin, II Ir S as the semiconductor material, triiron tetroxide as the magnetic material, and Nigelshin as the 4rr coloring agent. After that, the mixture was kneaded using a screw extruder, crushed using a jet mill, and subjected to a classification process using an air classifier.
produced a boar. Next, using the two-legged tri-value as an insulating material and the water resistance: I + Idarushiri force, [Example 1
] Table 2 and G11. Tl! The scale Lt is adjusted so that the coverage rate is
L, - After the toner nucleus and fIX are combined, I is placed in the hot air flow.
! Coating was done by IT misting. The k-plane iXl coverage rate is S E
It was determined from M and TIζM.
次にこれらのサンプルについて〔実施（’Ａ ｌ ）と
同様に、同時法により現像、転７７、定イ′ｔを行なっ
たところ良好な定着像を得ることができた。Next, these samples were subjected to development, transfer 77, and fixation using the same method as in Example ('A l ), and a good fixed image was obtained.
〔比較例２〕
〔実施例２〕と同様なｈ；１料と製造方法により、〔比
較例！〕の表３と同様な組成と表４の被覆率でトリ“−
を製造した。[Comparative Example 2] [Comparative Example! ] with the same composition as in Table 3 and the coverage in Table 4.
was manufactured.
次にこれらのサンプルについて〔比較例１〕と同ト′口
に現像、転写、定行を行にったとこる良好な定着像を得
る事ができなかった。これより、ｌ１ｇ５の含イ１°率
は２０〜５０％が好ましい。また、絶縁性物グ１の被覆
率は１０〜９０％が好ましい。Next, these samples were developed, transferred, and printed in the same manner as in [Comparative Example 1], but it was not possible to obtain a good fixed image. From this, it is preferable that the 1° content of l1g5 is 20 to 50%. Moreover, the coverage rate of the insulating material 1 is preferably 10 to 90%.
以上述べたように本発明によれば、電子写ＪＮ用トリー
において、結ｒｔ樹脂として熱可塑性樹脂、半導体材と
して、Ｎ型半ＪＯ体である硫化水（ＩＩ（ｂｌａｃｋ）
を用い、その伸行色材と磁性材を加えてなる半導体トナ
ーの表面に、絶縁性物質を被覆した７１（により、現像
時の電荷注入は半導体部によって行なわれ、転写は半Ｃ
体部への逆極性の７１ｉ荷の注入がないので、あらかじ
め帯電させである絶縁性部の電荷によって行なうことが
できる。これにより本トナーを同時法に使用するならば
、湿度の影響を受けず、良好な転写画像を得る事ができ
る為、小型、低価格の印刷装置を提供するＪＩＣができ
る。As described above, according to the present invention, in the electronic copy JN tree, thermoplastic resin is used as the binder rt resin, and sulfide water (II (black)), which is an N-type semi-JO body, is used as the binder rt resin.
The surface of the semiconductor toner is coated with an insulating material (71), which is made by adding a stretching coloring material and a magnetic material, so that the charge injection during development is performed by the semiconductor part, and the transfer is carried out in half-C.
Since there is no injection of 71i charges of opposite polarity into the body, this can be done by charging the insulating part, which is pre-charged. As a result, if this toner is used in the simultaneous method, it is not affected by humidity and a good transferred image can be obtained, allowing JIC to provide a compact, low-cost printing device.
第１ｒＡは本発明におけるトナーの実施例を示す図。 ２・・・半導体材 ６・・・絶縁材 以 −ヒ 出願人 セイコーエプソン株式会社 第１図 1rA is a diagram showing an embodiment of the toner according to the present invention. 2...Semiconductor material 6...Insulating material -H Applicant: Seiko Epson Corporation Figure 1
Claims (1)
脂、半導体材として、Ｎ型半導体である硫化水銀ＨｇＳ
（ｂｌａｃｋ）を用い、その他着色材と磁性材を加えて
なる半導体トナーの表面に、絶縁性物質を被覆率１０〜
９０％にコーティングする事を特徴とする一成分トナー
。In electrophotographic toner, thermoplastic resin is used as the binder resin, and mercury sulfide HgS, which is an N-type semiconductor, is used as the semiconductor material.
(black) and other coloring materials and magnetic materials are added to the surface of the semiconductor toner.
A one-component toner characterized by a 90% coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62085140A JPS63250658A (en) | 1987-04-07 | 1987-04-07 | One component toner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62085140A JPS63250658A (en) | 1987-04-07 | 1987-04-07 | One component toner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63250658A true JPS63250658A (en) | 1988-10-18 |
Family
ID=13850352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62085140A Pending JPS63250658A (en) | 1987-04-07 | 1987-04-07 | One component toner |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63250658A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04204658A (en) * | 1990-11-30 | 1992-07-27 | Mita Ind Co Ltd | Electrophotographic one component system developer |
| JPH04204664A (en) * | 1990-11-30 | 1992-07-27 | Mita Ind Co Ltd | Electrophotographic magnetic developer |
| JPH04204665A (en) * | 1990-11-30 | 1992-07-27 | Mita Ind Co Ltd | One component system magnetic developer |
-
1987
- 1987-04-07 JP JP62085140A patent/JPS63250658A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04204658A (en) * | 1990-11-30 | 1992-07-27 | Mita Ind Co Ltd | Electrophotographic one component system developer |
| JPH04204664A (en) * | 1990-11-30 | 1992-07-27 | Mita Ind Co Ltd | Electrophotographic magnetic developer |
| JPH04204665A (en) * | 1990-11-30 | 1992-07-27 | Mita Ind Co Ltd | One component system magnetic developer |
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