JPS63218396A - Image-receiving sheet for thermal transfer recording - Google Patents
Image-receiving sheet for thermal transfer recordingInfo
- Publication number
- JPS63218396A JPS63218396A JP61263577A JP26357786A JPS63218396A JP S63218396 A JPS63218396 A JP S63218396A JP 61263577 A JP61263577 A JP 61263577A JP 26357786 A JP26357786 A JP 26357786A JP S63218396 A JPS63218396 A JP S63218396A
- Authority
- JP
- Japan
- Prior art keywords
- image
- ink
- receiving
- chlorinated
- receiving sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000098 polyolefin Polymers 0.000 claims abstract description 15
- 239000004743 Polypropylene Substances 0.000 claims abstract description 4
- -1 polypropylene Polymers 0.000 claims abstract description 4
- 229920001155 polypropylene Polymers 0.000 claims abstract description 4
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 239000001023 inorganic pigment Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 5
- 238000005660 chlorination reaction Methods 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical class C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 235000019646 color tone Nutrition 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000005671 trienes Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は溶融型熱転写記録における受像シートに係り、
特にカラー記録、高速記録、高解像度記録にすぐれた熱
転写記録用受像シートに関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to an image receiving sheet for melt-type thermal transfer recording,
In particular, it relates to an image-receiving sheet for thermal transfer recording that is excellent in color recording, high-speed recording, and high-resolution recording.
溶融型熱転写記録は、第１図に示す様にシート状の基体
１であるコンデンサー紙あるいはポリエステルフィルム
、合成紙等の片面に、ホットメルト固体材料と着色成分
材料とからなる記録インク層２が塗布されている記録シ
ート６に、熱エネルギー５を加えることにより溶融また
は軟化したインク４が受像シート３上に転写されるとい
う簡単な原理により記録を行うものである。In melt-type thermal transfer recording, as shown in Fig. 1, a recording ink layer 2 made of a hot-melt solid material and a coloring component material is coated on one side of a sheet-like substrate 1 such as capacitor paper, polyester film, or synthetic paper. Recording is performed on a simple principle in that by applying thermal energy 5 to a recording sheet 6, the ink 4 which has been melted or softened is transferred onto the image receiving sheet 3.
この際、受像シートとしては特別なものが必要でなく、
一般的な印刷用紙や、合成紙、ポリエステルフィルム等
の表面平滑な合成樹脂フィルムが用いられている。しか
し、最近の熱転写記録方式では記録スピードの上昇や、
カラー写真的な記録方法として階調記録再現がなされる
ようになってきた。In this case, there is no need for a special image receiving sheet;
General printing paper, synthetic paper, and synthetic resin films with smooth surfaces such as polyester films are used. However, recent thermal transfer recording methods have increased recording speed,
Gradation recording reproduction has come to be used as a color photographic recording method.
このため、前述の一般的な受像シートでは画点（画像）
の欠けや抜けなどのため、解像力の低下や、細かい線な
どが呈現されにくい間項が出始しめた。For this reason, on the general image receiving sheet mentioned above, the pixel (image)
Due to chipping and omissions in the image, the resolution has decreased and fine lines have begun to appear in the image.
このような転写むらをなくす手法として、溶融した転写
インクを内部に浸透させて解決しようとの考え方から、
ワックスを主成分とする層を基材シートに設けたり（特
開昭５９−２２９３９４号）、あるいは多孔質顔料を多
液含有する塗工剤を１０μ以上の厚みで基材シートに塗
布する（特開昭６１−８３８５号）試みがおこなわれて
いる。しかしながら、これらの受像シートはインクが内
部に浸透するため、全体の色調がくすんだ感じとな抄、
かならずしも満足されない。As a method to eliminate such uneven transfer, the idea was to infiltrate the inside of the product with molten transfer ink.
A layer containing wax as the main component is provided on the base sheet (Japanese Unexamined Patent Publication No. 59-229394), or a coating agent containing a large amount of porous pigment is applied to the base sheet to a thickness of 10μ or more (Japanese Patent Laid-Open No. 59-229394). (No. 8385/1983) is being attempted. However, because the ink penetrates into these image-receiving sheets, the overall color tone becomes dull and dull.
Not always satisfied.
転写むらをなくすためには、供給される熱エネルギーに
応じて常に同じインク量転写されることが必要であし、
このためには■記録シートと受像シート間に接触ムラの
ないことの他に、■記録シートが受像シートから引き離
される際にはインクの溶解部分が完全に受像シートに接
着していることが必要である。In order to eliminate uneven transfer, it is necessary to always transfer the same amount of ink depending on the supplied thermal energy.
To achieve this, it is necessary that ■ There is no uneven contact between the recording sheet and the image-receiving sheet, and ■ The dissolved part of the ink must be completely adhered to the image-receiving sheet when the recording sheet is separated from the image-receiving sheet. It is.
〔発明の目的〕
本発明は、溶ｍ型熱転写記録方式において、転写ムラの
ない高画質の記録を可能にする熱転写起源用受像シート
を提供することを目的とする。[Object of the Invention] An object of the present invention is to provide an image-receiving sheet for thermal transfer origin that enables high-quality recording without transfer unevenness in a melt-type thermal transfer recording system.
本発明は受像シートの基体シート７のインク受容面側に
、塩素化ポリオレフィンを含有するインク受像層形成塗
工剤を塗布し、乾燥することにより、基体シート７上に
インク受像層８を設はインクの溶融部分に対する受像シ
ート３の接着性を向上した。In the present invention, an ink image-receiving layer 8 is formed on the base sheet 7 by applying an ink image-receiving layer forming coating agent containing chlorinated polyolefin to the ink-receiving surface side of the base sheet 7 of the image-receiving sheet and drying it. The adhesion of the image receiving sheet 3 to the melted part of the ink is improved.
ここで塩素化ポリオレフィンとは、ポリオレフィンを有
機溶剤に溶解した９、水にｉ消したり、あるいは気相中
で塩素化したものであり、このうち、塩素化ポリエチレ
ン、塩素化ポリプロピレン、塩素化エチレン・酢酸ビニ
ル共重合体が有効で、これら１種もしくは２種以上の混
合物を使用に供する。通常、塩素比率が２０〜５０％の
ものが好ましく、塩素化率２０〜４０％のものが特に有
効である。かかる塩素化ポリオレフィンはゴム弾性を持
ったポリマーであ抄、インクの溶融部分に対する受像シ
ートの密着性を向上し、接触ムラをなくすことにも寄与
していると考えられる。Here, chlorinated polyolefin refers to polyolefin dissolved in an organic solvent9, quenched in water, or chlorinated in a gas phase. Among these, chlorinated polyethylene, chlorinated polypropylene, chlorinated ethylene, Vinyl acetate copolymers are effective, and one or a mixture of two or more of these may be used. Usually, a chlorine ratio of 20 to 50% is preferred, and a chlorination ratio of 20 to 40% is particularly effective. Such chlorinated polyolefin is a polymer with rubber elasticity and is thought to improve the adhesion of the image receiving sheet to the molten portion of the ink and also contribute to eliminating contact unevenness.
更に、インクの溶融部分に対する受像シートの接触むら
をなくす手段として、インク受滓層に塩素化ポリオレフ
ィンの他、平均粒径０．２〜１０μの無機顔料を添加す
ることが有効である。これは単なる表面平滑性を高める
だけでは困雛な接触むらを、均一でかつ微少な凹凸面に
することで解決するためである１、かかる電機顔料とし
ては、シリカ、クレー、タルク、炭酸カルシウム、ケイ
酸アルミニウム、酸化チタン、水酸化アルミニウム等の
微粉末が挙げられる。塩素化ポリオレフィン囚と櫃機顔
料ＣＢ）との割合（Ａ：Ｂ）はｌＯ二θ〜４：６が好ま
しく、９：１〜６：４が特に有効である。Furthermore, as a means for eliminating uneven contact between the image receiving sheet and the melted portion of the ink, it is effective to add an inorganic pigment having an average particle size of 0.2 to 10 .mu.m in addition to the chlorinated polyolefin to the ink slag receiving layer. This is to solve the problem of contact unevenness, which is difficult to achieve by simply increasing the surface smoothness, by creating a uniform and slightly uneven surface1.Such electrical pigments include silica, clay, talc, calcium carbonate, Examples include fine powders of aluminum silicate, titanium oxide, aluminum hydroxide, and the like. The ratio (A:B) of the chlorinated polyolefin powder to the machine pigment CB) is preferably from lO2θ to 4:6, and particularly from 9:1 to 6:4.
受像層形成用塩素化ポリオレフィンは、通常トルエン、
キシレン等の芳香族炭化水素系の有機溶剤に溶解、分散
して固型分が５〜４０重敞シの塗工剤溶液とした後、固
型分として０．１〜１０ｆ／−になる様に受像シートの
基体７表面上に塗布さ江る。The chlorinated polyolefin for forming the image-receiving layer is usually toluene,
After dissolving and dispersing in an aromatic hydrocarbon organic solvent such as xylene to make a coating agent solution with a solid content of 5 to 40 kg, the solid content should be 0.1 to 10 f/-. It is coated on the surface of the substrate 7 of the image-receiving sheet.
以下に実施例を挙げて説明する。 Examples will be described below.
実施例１
塩素化ポリプロピレン ７０重な部（塩素含
有率３０％）
酸化チタン（平均粒径０．４８μ） ａｏｉｉ部ト
ルエン ９００重喰１からなる組
成の塗工剤溶液を、固型分として１．５？／ｍ′となる
様に市販の合成紙（王子油化合成紙株式会社製１ユボＦ
ＰＧ−１１０”）の片面に塗布、乾燥して受像シートを
作製した。Example 1 A coating agent solution having a composition of 70 parts of chlorinated polypropylene (chlorine content 30%), 1 part of titanium oxide (average particle size 0.48 μ), 900 parts of toluene, 1 part by weight was prepared as a solid component. 5? commercially available synthetic paper (1 Yubo F manufactured by Oji Yuka Synthetic Paper Co., Ltd.)
PG-110'') and dried to prepare an image-receiving sheet.
作製した受像シートを用いて、市販のフルカラー熱転写
プリンターで印字したところ、サーマルヘッドの加熱に
より、溶融したインクが受滓シート表面によく接着し、
冷却後剥離する際にも、インクが受像層に固着したまま
残るので、転写不良を生じることなく、色調群やかな画
像が得られた。When printing was performed using a commercially available full-color thermal transfer printer using the prepared image-receiving sheet, the molten ink adhered well to the surface of the slag-receiving sheet due to the heating of the thermal head.
Even when the ink was peeled off after cooling, the ink remained fixed to the image-receiving layer, so that an image with clear tones was obtained without causing transfer defects.
実施例２
塩素化エチレン・酢酸ビニル共重合体
（酢酸ビニル含ｒ＃１４％、塩素化率２８％）９０重計
部
合成シリカ（平均粒径１．４μ） １０重縫部トリ
エン ９００重磨１からなる組
成物を市販のＯＰＰフィルム（１００μ）の片面に塗布
、乾燥して受像シートを作製した。Example 2 Chlorinated ethylene/vinyl acetate copolymer (vinyl acetate content r#14%, chlorination rate 28%) 90 weight parts Synthetic silica (average particle size 1.4μ) 10 weight seams Triene 900 weight grinding 1 to The composition was coated on one side of a commercially available OPP film (100μ) and dried to prepare an image-receiving sheet.
作製した受像シートを用いて、フルカラー熱転写したと
ころ、転写性が良く、接着性の優れた色調群やかな画像
が得られた。尚、受像層を設けない合成紙およびＯＰＰ
フィルムを受像シートどした比較例では転写不良が１は
められた。When full-color thermal transfer was performed using the produced image-receiving sheet, an image with good transferability, excellent adhesiveness, and bright color tones was obtained. In addition, synthetic paper and OPP without an image-receiving layer
In a comparative example in which the film was used as an image-receiving sheet, there was one transfer defect.
以上の説明から明らかな様に、本発明からなる感熱転写
記録用受像シートは転写インク受像性に優れているので
、カラー記録、高速記録、高解像度記録足すぐれたもの
である。As is clear from the above description, the image-receiving sheet for thermal transfer recording according to the present invention has excellent transfer ink image receptivity, and is therefore suitable for color recording, high-speed recording, and high-resolution recording.
第１図は熱転写記録の状態を示す図である。 第１図 FIG. 1 is a diagram showing the state of thermal transfer recording. Figure 1
Claims (1)
フィンを含有するインク受像層を設けたことを特徴とす
る熱転写記録用受像シート。 ２）、塩素化ポリオレフィンが、塩素化ポリエチレン、
塩素化ポリプロピレンおよび／または塩素化エチレン、
酢酸ビニル共重合体であることを特徴とする特許請求の
範囲第１項記載の熱転写記録用受像シート。 ３）、インク受像層は、塩素化ポリオレフィンと平均粒
径０．２〜１０μの無機顔料を含有することを特徴とす
る特許請求の範囲第１項記載の熱転写記録用受像シート
。[Scope of Claims] 1) An image-receiving sheet for thermal transfer recording, characterized in that an ink-receiving layer containing a chlorinated polyolefin is provided on the ink-receiving surface side of a base sheet. 2), the chlorinated polyolefin is chlorinated polyethylene,
chlorinated polypropylene and/or chlorinated ethylene,
The image-receiving sheet for thermal transfer recording according to claim 1, wherein the image-receiving sheet is a vinyl acetate copolymer. 3) The image-receiving sheet for thermal transfer recording according to claim 1, wherein the ink image-receiving layer contains a chlorinated polyolefin and an inorganic pigment having an average particle size of 0.2 to 10 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61263577A JPS63218396A (en) | 1986-11-05 | 1986-11-05 | Image-receiving sheet for thermal transfer recording |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61263577A JPS63218396A (en) | 1986-11-05 | 1986-11-05 | Image-receiving sheet for thermal transfer recording |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63218396A true JPS63218396A (en) | 1988-09-12 |
Family
ID=17391485
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61263577A Pending JPS63218396A (en) | 1986-11-05 | 1986-11-05 | Image-receiving sheet for thermal transfer recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63218396A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02219755A (en) * | 1989-02-09 | 1990-09-03 | Japan Crown Cork Co Ltd | Resin cap for indicating prize winning mark |
| JPH02219756A (en) * | 1989-02-09 | 1990-09-03 | Japan Crown Cork Co Ltd | Resin cap for indicating prize winning mark |
| JPH05254266A (en) * | 1992-03-16 | 1993-10-05 | Nippon Paper Ind Co Ltd | Thermal transfer image receiving paper |
| KR100272258B1 (en) * | 1998-06-16 | 2001-06-01 | 토마스 더블유. 버크맨 | Thermal transfer recording medium |
-
1986
- 1986-11-05 JP JP61263577A patent/JPS63218396A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02219755A (en) * | 1989-02-09 | 1990-09-03 | Japan Crown Cork Co Ltd | Resin cap for indicating prize winning mark |
| JPH02219756A (en) * | 1989-02-09 | 1990-09-03 | Japan Crown Cork Co Ltd | Resin cap for indicating prize winning mark |
| JPH05254266A (en) * | 1992-03-16 | 1993-10-05 | Nippon Paper Ind Co Ltd | Thermal transfer image receiving paper |
| KR100272258B1 (en) * | 1998-06-16 | 2001-06-01 | 토마스 더블유. 버크맨 | Thermal transfer recording medium |
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