JPS63218319A - Method for reclaiming filler containing fluororesin waste material - Google Patents
Method for reclaiming filler containing fluororesin waste materialInfo
- Publication number
- JPS63218319A JPS63218319A JP62052745A JP5274587A JPS63218319A JP S63218319 A JPS63218319 A JP S63218319A JP 62052745 A JP62052745 A JP 62052745A JP 5274587 A JP5274587 A JP 5274587A JP S63218319 A JPS63218319 A JP S63218319A
- Authority
- JP
- Japan
- Prior art keywords
- waste material
- tetrafluoroethylene resin
- inorganic filler
- resin waste
- mold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 9
- 239000000945 filler Substances 0.000 title claims description 6
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011256 inorganic filler Substances 0.000 claims abstract description 9
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 9
- 239000003365 glass fiber Substances 0.000 claims abstract description 6
- 238000010583 slow cooling Methods 0.000 claims abstract 3
- 238000004064 recycling Methods 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims 1
- 238000000465 moulding Methods 0.000 abstract description 3
- 238000000137 annealing Methods 0.000 abstract 1
- 238000010791 quenching Methods 0.000 abstract 1
- 230000000171 quenching effect Effects 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000463 material Substances 0.000 description 5
- 238000012669 compression test Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- BDZGJPFBTVYBOA-UHFFFAOYSA-N ethene Chemical group C=C.C=C.C=C.C=C.C=C BDZGJPFBTVYBOA-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000004154 testing of material Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、無機充填材を配合した四ふつ化エチレン樹脂
廃材の再生法に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for recycling tetrafluoroethylene resin waste mixed with an inorganic filler.
従来の技術及び発明が解決
しようとする問題点
従来、無１１充填材入りの四ふつ化エチレンｇｉｆ脂は
、主として、無給油タイプの軸受材、ピストンリング等
の機械部材として多く使用されてきたが。Conventional technology and problems to be solved by the invention Conventionally, tetrafluoroethylene GIF fat containing no 11 filler has been mainly used as mechanical parts such as oil-free bearing materials and piston rings. .
その廃材は再生の目途もなく鹿采処分されていた。The waste wood was disposed of with no prospect of recycling.
本発明は、無機充填材入りの四ふり化エチレンＳ脂の廃
材を再生して％所望の成型ができるようにすると共に、
機械部材その他の用途に新品に優る物性に再生できるよ
うにした充填材入りふっ素樹脂廃材の再生法を提供する
ものである。The present invention regenerates waste material of tetrafluorinated ethylene S resin containing inorganic filler so that it can be molded into a desired shape.
The present invention provides a method for recycling fluororesin waste material containing fillers that can be recycled into mechanical parts and other uses with physical properties superior to new ones.
問題点を解決するための手段
すなわち、本発明充填材入りふっ素樹脂廃材の再生法は
、ガラスファイバー、グラファイト等ノ無機充填材を配
合した四ふっ化エチレンＩ脂廃材の細片を、８２７℃以
上に加熱したのち、８０ｋｇｆ／ａｍ２以上に加圧して
成型し、除冷又は急冷後焼鈍するものである。A means for solving the problem, that is, a method for recycling filler-containing fluororesin waste according to the present invention, is to heat strips of tetrafluoroethylene I fat waste mixed with inorganic fillers such as glass fiber and graphite at temperatures above 827°C. After being heated to a temperature of 80 kgf/am2 or more, it is molded and then slowly cooled or rapidly cooled and then annealed.
本発明において、無機充填材は、前述したガラスファイ
バー、グラファイトのほか二硫化モリブテン、フロンズ
、雲母、けい酸アルミ、滑石、金属酸化物等が使用され
、四ふつ化エチレン樹脂への配合量は、通常５〜８０重
量％である。無機充填材入り四ぶつ化エチレン樹脂の廃
材は、切削により綱片化される。この際、切削は超硬工
具によることが望ましい。加熱は、通常、前記細片化し
た廃材を金型に入れ、３２７℃以上４２０℃以下の温度
で、内部まで均一温度になるまで長時開戸の中で行われ
る。加圧は、前記１材の溶融粘度が約ｌＯポイズ程度前
後になったとき、前記金型を炉から出して、前記金型に
８０ｋｇｆ／ｃｍ２〜１５０ ｋｇｆ ／ｃｍ２程度の
圧力を短時間かけることにより行われる。加圧後は、前
記廃材を金型から押出しその他の方法により取り出し成
型品を得、これを除冷するか、急冷したのち焼鈍処理し
て再生製品とする。In the present invention, in addition to the above-mentioned glass fibers and graphite, the inorganic fillers used include molybdenum disulfide, freon, mica, aluminum silicate, talc, metal oxides, etc., and the amount blended into the tetrafluoroethylene resin is as follows: It is usually 5 to 80% by weight. Waste material of tetraethylene ethylene resin containing inorganic filler is cut into pieces of rope. At this time, it is preferable to use a carbide tool for cutting. Heating is usually carried out by putting the shredded waste material into a mold and keeping the door open for a long time at a temperature of 327° C. or more and 420° C. or less until the temperature reaches a uniform temperature throughout the inside. Pressurization is performed by taking the mold out of the furnace and applying a pressure of about 80 kgf/cm2 to 150 kgf/cm2 to the mold for a short time when the melt viscosity of the first material reaches about 10 poise. This is done by After pressurization, the waste material is extruded from the mold or by other methods to obtain a molded product, which is slowly cooled or rapidly cooled and then annealed to produce a recycled product.
実施例１
ガラスファイバー粉２５ｍ！ｆｆｉ％入り四ふつ化エチ
レン樹脂廃材を集めて紐状に切削してシリンダ状金型に
入れ、この金型を炉内に入れて約８６０℃で約８時間加
熱したのち、前記金型を炉から取り出し、プランジャ状
円柱を前記金型の一端から入れて１２０ ｋｇｆ ／
ｃｍ２ｔ’ １５分間加ｒｉシタノチ、押し出し除冷し
再生製品を得た。Example 1 Glass fiber powder 25m! Collected ffi%-containing tetrafluoroethylene resin waste material, cut it into a string shape, and placed it in a cylindrical mold.The mold was placed in a furnace and heated at approximately 860°C for approximately 8 hours, and then the mold was placed in a furnace. A plunger-shaped cylinder was put into one end of the mold and the mold was heated to 120 kgf/
cm2t' The mixture was heated for 15 minutes, extruded and slowly cooled to obtain a recycled product.
実施例２
ガラスファイバー粉２０重量％、グラファイト５％入り
の四ふつ化エチレン受脂廃材を集めて実施例１と同様の
処理を施し再生製品を得た。Example 2 Tetrafluoroethylene fat absorbing waste containing 20% by weight of glass fiber powder and 5% of graphite was collected and treated in the same manner as in Example 1 to obtain a recycled product.
発明の効果
実施例１、比較例１、実施例２及び比較例２について、
比重試験、圧縮試験、摩擦摩耗試験、引張試験を行った
結果、次の結果が得られた。Effects of the invention Regarding Example 1, Comparative Example 1, Example 2, and Comparative Example 2,
As a result of conducting a specific gravity test, compression test, friction and wear test, and tensile test, the following results were obtained.
比較例１は、実施例１と同じ配合の充填材入りの純四ふ
つ化エチレン樹脂新製品、比較例２は実施例２と同じ配
合の充Ｊ！４材入りの純四ぶつ化エチレン労脂折製品で
、いずれも新規に生産されたもので廃材から得られたも
のではない。Comparative Example 1 is a new pure tetrafluoroethylene resin product containing a filler with the same formulation as in Example 1, and Comparative Example 2 is a new pure tetrafluoroethylene resin product with the same formulation as in Example 2. It is a pure tetrabutylene ethylene product containing four materials, all of which are newly produced and not obtained from waste materials.
（ｍ数値はいずれも平均比重を示す。(All m values indicate average specific gravity.
平均比重は、実施例と比較例では誤差の範囲内にあり差
はないものとみられる。The average specific gravity is within the error range between the example and the comparative example, and there appears to be no difference.
（２）圧縮試験
第１図及び第２図に示すように、応力−歪曲線は、実施
例１及び実施例２とも、比較例１及び比較例２より優れ
ている。(2) Compression Test As shown in FIGS. 1 and 2, the stress-strain curves of both Example 1 and Example 2 are superior to Comparative Example 1 and Comparative Example 2.
なお、圧縮試験は、試験片（幅１４９５ ミリメートル
、高さ１４Ｂ５ ミリメートル、長さ８．８ミリメー
トル）を島津ＲＥＩ−１０圧縮試験機（試験スピード１
．２５ミリメートル／分）を用いて行った。The compression test was performed using a test piece (width 1495 mm, height 14B5 mm, length 8.8 mm) using a Shimadzu REI-10 compression testing machine (test speed 1).
．． 25 mm/min).
（８）摩擦摩耗試験 スピンチル摩耗試験機を用い、次の試験条件で行った。(8) Friction and wear test The test was conducted using a spin chill abrasion tester under the following test conditions.
試験条件
荷重： １０ ｋｇ／ｃｍ２．速度： ８ｒｒｌ ／
８ ｅ Ｃｔ Ｑ滑：ＤＲＹ、相手軸材：Ｆｅ１２．荷
重方向：成形方向に１１．運転時間２４時間、馴み運転
＝９０分、繰返し数：２
実権例１及び実施例２は、比較例１及び比較例２に比べ
て同等か若干優れている。Test condition load: 10 kg/cm2. Speed: 8rrl/
8 e Ct Q slip: DRY, mating shaft material: Fe12. Load direction: 11. in the molding direction. Operating time: 24 hours, break-in = 90 minutes, number of repetitions: 2 Actual Example 1 and Example 2 are equivalent to or slightly superior to Comparative Example 1 and Comparative Example 2.
（４）引張試験
Ｆ８Ｐ−８００捜レバ一式材料試験機を用い、次の試験
条件で行った。(4) Tensile test Tensile test was carried out using an F8P-800 lever set material testing machine under the following test conditions.
試験条件
試験速度：１９８ミ！Ｊメートル／分、繰返し数：２．
試験片：マイクロダンベルによる打ち抜キ（幅５ミリメ
ートル×厚み８ミリメートル）実施例１及び実施例２は
、いずれも比較例１及び比較例２よりも引張強さは若干
劣り伸び率は小さいが、ピストンリング、軸受等の用途
には何らの不都合はない。Test conditions Test speed: 198 mi! J meters/min, number of repetitions: 2.
Test piece: punched with a micro dumbbell (width 5 mm x thickness 8 mm) Both Examples 1 and 2 have slightly lower tensile strength and lower elongation than Comparative Examples 1 and 2, but There is no problem in applications such as piston rings and bearings.
以上のように、無機光＃４材入りの四ふつ化エチレン樹
脂廃材の再生製品は、利用用途の多くで新製品と同等又
は若干優れた性能を示し、本発明再生法の実用価値を高
めるものである。As described above, recycled products of tetrafluoroethylene resin waste containing inorganic Hikari #4 material exhibit performance equivalent to or slightly superior to new products in many applications, increasing the practical value of the recycling method of the present invention. It is.
発明者 神 谷 幸 −Inventor: Yuki Kamiya -
Claims (1)
した四ふつ化エチレン樹脂廃材の細片を、８２７℃以上
に加熱したのち、８０ｋｇｆ／ｃｍ＾２以上に加圧して
成型し、除冷又は急冷後焼鈍することを特徴とした充填
材入りふつ素樹脂廃材の再生法。Small pieces of tetrafluoroethylene resin waste mixed with inorganic fillers such as glass fiber and graphite are heated to 827°C or higher, then pressurized to 80 kgf/cm^2 or higher to form them, and annealed after slow cooling or rapid cooling. A method for recycling fluororesin waste material containing fillers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62052745A JPS63218319A (en) | 1987-03-06 | 1987-03-06 | Method for reclaiming filler containing fluororesin waste material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62052745A JPS63218319A (en) | 1987-03-06 | 1987-03-06 | Method for reclaiming filler containing fluororesin waste material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63218319A true JPS63218319A (en) | 1988-09-12 |
Family
ID=12923456
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62052745A Pending JPS63218319A (en) | 1987-03-06 | 1987-03-06 | Method for reclaiming filler containing fluororesin waste material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63218319A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048267C (en) * | 1995-03-11 | 2000-01-12 | 张洪法 | Regenerated polytetrafluoroethylene products and producing method thereof |
| JP2005178192A (en) * | 2003-12-19 | 2005-07-07 | Taiyo Kogyo Corp | Recycling method for making tent sheet containing ptfe reusable material |
| US7223800B2 (en) * | 2000-07-24 | 2007-05-29 | Daikin Industries, Ltd. | Method for producing regenerated fluororesin and regenerated fluororesin article |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5222025A (en) * | 1975-08-13 | 1977-02-19 | Fuji Funen Kenzai Kougiyou Kk | Method of manufacturing fireproof building materials |
| JPS5332827A (en) * | 1976-09-09 | 1978-03-28 | Nakata Giken Kk | Moulding method by using waterrsoluble paste as binder |
| JPS5822339A (en) * | 1981-07-30 | 1983-02-09 | Denka Consult & Eng Co Ltd | Double-pipe multi-hole lance |
-
1987
- 1987-03-06 JP JP62052745A patent/JPS63218319A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5222025A (en) * | 1975-08-13 | 1977-02-19 | Fuji Funen Kenzai Kougiyou Kk | Method of manufacturing fireproof building materials |
| JPS5332827A (en) * | 1976-09-09 | 1978-03-28 | Nakata Giken Kk | Moulding method by using waterrsoluble paste as binder |
| JPS5822339A (en) * | 1981-07-30 | 1983-02-09 | Denka Consult & Eng Co Ltd | Double-pipe multi-hole lance |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048267C (en) * | 1995-03-11 | 2000-01-12 | 张洪法 | Regenerated polytetrafluoroethylene products and producing method thereof |
| US7223800B2 (en) * | 2000-07-24 | 2007-05-29 | Daikin Industries, Ltd. | Method for producing regenerated fluororesin and regenerated fluororesin article |
| JP2005178192A (en) * | 2003-12-19 | 2005-07-07 | Taiyo Kogyo Corp | Recycling method for making tent sheet containing ptfe reusable material |
| JP4685345B2 (en) * | 2003-12-19 | 2011-05-18 | 太陽工業株式会社 | Recycling method to convert tent sheet containing PTFE into reusable material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3756982A (en) | Antifriction polymer materials and method of producing same | |
| CN100463940C (en) | Bridge bearing gliding material and method for preparing the same | |
| Zhang et al. | Preparation of rubber composites from ground tire rubber reinforced with waste‐tire fiber through mechanical milling | |
| Hambir et al. | Sintering of ultra high molecular weight polyethylene | |
| Kalkornsurapranee et al. | Influence of grafting content on the properties of cured natural rubber grafted with PMMAs using glutaraldehyde as a cross‐linking agent | |
| Mokoena et al. | Composites of linear low density polyethylene and short sisal fibres: The effects of peroxide treatment | |
| JPS63218319A (en) | Method for reclaiming filler containing fluororesin waste material | |
| Ding et al. | Recovery of polyimide waste film by mechanical method to improve the heat fade resistance of BPR matrix friction composites | |
| RU2324708C2 (en) | Method of items manufacturing out of composite materials based on polytetrafluorinethylene | |
| Ramakrishna et al. | Effect of fly ash content on impact, compression, and water absorption properties of epoxy toughened with epoxy phenol cashew nut shell liquid–fly ash composites | |
| US5304338A (en) | Carbon fiber reinforced polyimide composites | |
| JP2015108126A (en) | Method for recycling fluororesin | |
| Jauffres et al. | Yield, creep, and wear properties of ultra high molecular weight polyethylene processed by high velocity compaction | |
| Yadav et al. | Mechanical and Hygroscopic Behaviour of Teak Wood Sawdust Filled Recycled Polypropylene Composites | |
| RU2266925C2 (en) | Method for making polymer-base composition materials | |
| Bilym et al. | Carbon fiber plastics for vehicles manufactured by resource-saving formation technology | |
| CN110452435A (en) | A kind of wear resistant composite material and preparation method thereof of tetraphenyltin modified ultra-high molecular weight polyethylene | |
| JPS58145608A (en) | Manufacture of precision molded article of hard carbonaceous material | |
| RU2603673C1 (en) | Method of making articles from polytetrafluoroethylene based composite materials | |
| Dvorko et al. | Foams Based on Modified Powder Novolac Phenol–Formaldehyde Composites | |
| Kamińska et al. | Effect of mechanical reclamation cycle on strength parameters of loose self-hardening sands based on furfuryl resin | |
| JP4512770B2 (en) | Method for producing a novel fiber-reinforced fluororesin composite material | |
| SU529193A1 (en) | Polymer composition | |
| JPS59179537A (en) | Regeneration of silicone rubber scrap | |
| CN107338382A (en) | A kind of transformer case material and preparation method thereof |