JPS6317995A - Rinsing aid composition - Google Patents
Rinsing aid compositionInfo
- Publication number
- JPS6317995A JPS6317995A JP16119386A JP16119386A JPS6317995A JP S6317995 A JPS6317995 A JP S6317995A JP 16119386 A JP16119386 A JP 16119386A JP 16119386 A JP16119386 A JP 16119386A JP S6317995 A JPS6317995 A JP S6317995A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- fatty acid
- rinse aid
- aid composition
- rinsing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title description 17
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 19
- 229930195729 fatty acid Natural products 0.000 claims description 19
- 239000000194 fatty acid Substances 0.000 claims description 19
- -1 fatty acid ester Chemical class 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 16
- 235000011187 glycerol Nutrition 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 7
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 claims description 6
- 229940066675 ricinoleate Drugs 0.000 claims description 6
- 229930006000 Sucrose Natural products 0.000 claims description 5
- 239000005720 sucrose Substances 0.000 claims description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000002904 solvent Substances 0.000 description 7
- 238000005187 foaming Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 235000013373 food additive Nutrition 0.000 description 3
- 239000002778 food additive Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は自動食器洗浄機において、すすぎ助剤として使
用するに適した組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a composition suitable for use as a rinse aid in automatic dishwashing machines.
従来よりすすぎ助剤の成分として、プルロニック系界面
活性剤、食品添加物として認められているソルビタン脂
肪酸エステル、シ＝Ｉｔｉ脂肪酸エステル、プロピレン
グリコール脂肪酸エステル、グリセリン脂肪酸エステル
、ポリグリセリン脂肪酸エステルの界面活性剤を用いる
ことが公知である。Conventional rinse aid ingredients include pluronic surfactants, sorbitan fatty acid esters, ci-Iti fatty acid esters, propylene glycol fatty acid esters, glycerin fatty acid esters, and polyglycerin fatty acid ester surfactants that are recognized as food additives. It is known to use
しかし、プルロニック系界面活性剤は食品添加物として
認められておらず、人体に対する安全性の面で問題があ
り、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル
、プロピレングリコール脂肪酸エステル、グリセリン脂
肪酸エステル、ポリグリセリン脂肪酸エステルは水溶性
が悪く、プロピレングリコール、グリセリン、エタノー
ルなどの可溶化剤を用いて安定な製品にするのが通常の
方法である。However, pluronic surfactants are not approved as food additives and have safety issues for the human body. Esters have poor water solubility, and the usual method is to use solubilizers such as propylene glycol, glycerin, and ethanol to make them stable products.
しかし、これらの溶剤のうち、 ・エタノールは引火点が低く、危険性が大きい。However, among these solvents, ・Ethanol has a low flash point and is highly dangerous.
・プロピレングリコールは昭和５６年から無制限食品添
加物から外され、安全性に問題がある。・Propylene glycol has been removed from the list of unrestricted food additives since 1981, and there are safety issues.
・グリセリンは可溶化能力が十分ではない。・Glycerin does not have sufficient solubilizing ability.
といった問題点がある。また、これらの溶剤はすすぎ助
剤としての性能に何等効力を発揮せず、単に製品を安定
に保つ為だけの役割しかなく、製品コストをアップし、
製品コスト上大きな負担となる。There are some problems. In addition, these solvents do not have any effect on the performance as rinsing aids, and only serve to keep the product stable, which increases product costs.
This poses a large burden on product costs.
溶剤を用いない乳状すすぎ助剤として、例えば特開昭４
９−９０７０６号公報に［水に分散性乃至可溶性のショ
糖脂肪酸エステルの中に、常温で液体の油性ソルビタン
脂肪酸エステルを１０〜４０重量部配合し、加熱溶融し
て得られる混合物４０重量部以下と水６０重量部以上を
混合溶解して得られるゲル状物の中に糖、糖アルコール
類、中性無機塩類、アルカリ性無機塩類、有機酸塩類、
アミノ酸塩類の中から選ばれた１種或いは２種以上の混
合物を配合することを特徴とする発泡性の少ない、リン
ス効果の優れた流動性及び低温安定性の良好な乳液状リ
ンス剤組成物」があるが、このすすぎ助剤は製造に加熱
等の必要があることから、工業的製造法としては単純で
はなく、また、得られるすすぎ助剤は粘度が高く、実際
の使用に困難であり、すすぎ助剤として具備すべきリン
ス性能も十分とは言えない。As a milky rinse aid that does not use a solvent, for example, JP-A-4
No. 9-90706 [40 parts by weight or less of a mixture obtained by blending 10 to 40 parts by weight of an oily sorbitan fatty acid ester that is liquid at room temperature into a water-dispersible or soluble sucrose fatty acid ester and melting the mixture by heating] Sugar, sugar alcohols, neutral inorganic salts, alkaline inorganic salts, organic acid salts,
A milky lotion rinse agent composition with low foaming properties, excellent fluidity with excellent rinsing effect, and good low-temperature stability, characterized by containing one or a mixture of two or more selected from amino acid salts. However, this rinsing aid requires heating, etc. to manufacture, so it is not a simple industrial manufacturing method, and the resulting rinsing aid has a high viscosity, making it difficult to use in practice. The rinsing performance that a rinsing aid should have is also not sufficient.
本発明者らは、可溶化剤を用いずにすすぎ助剤として優
れた性能を有し、かつ製造容易な安定な乳状すすぎ助剤
組成物を得る為に種々検討した結果、本発明を完成した
。The present inventors completed the present invention as a result of various studies in order to obtain a stable emulsion rinse aid composition that has excellent performance as a rinse aid without using a solubilizer and is easy to manufacture. .
即ち、本発明の乳状すすぎ助剤組成物は、重合度２〜１
２のポリグリセリンの縮合リシノレート５〜５０重量％
、特に好ましくは６〜１５重量％と、
ＨＬＢ ６〜１３のポリグリセリン脂肪酸エステル５〜
５０重量％、特に好ましくは６〜１５重量％と、ショ糖
、グリセリン、ソルビタン、ソルバイト、ソルビットか
らなる群より選ばれた１種または２種以上の多価アルコ
ールと、炭素原子数６〜１０個の脂肪酸との部分エステ
ル１〜１０重量％、特に好ましくは２〜６重景％
とを必須成分として含有し、残部、特に好ましくは５０
重量％以上の水からなることを特徴とする。That is, the milky rinse aid composition of the present invention has a degree of polymerization of 2 to 1.
5 to 50% by weight of condensed ricinoleate of polyglycerin No. 2
, particularly preferably 6 to 15% by weight, and a polyglycerin fatty acid ester with an HLB of 6 to 13.
50% by weight, particularly preferably 6 to 15% by weight, one or more polyhydric alcohols selected from the group consisting of sucrose, glycerin, sorbitan, sorbite, and sorbitol, and 6 to 10 carbon atoms. 1 to 10% by weight, particularly preferably 2 to 6% by weight, of partial esters with fatty acids, and the balance, particularly preferably 50% by weight.
It is characterized by consisting of more than % by weight of water.
なお上記ポリグリセリン脂肪酸エステルの肛Ｂの計算方
法は以下の通りである。Note that the calculation method for the volume B of the polyglycerol fatty acid ester is as follows.
本発明の乳状すすぎ助剤組成物の必須成分中、重合度２
〜１２のポリグリセリンの縮合リシノレートは、乳状す
すぎ助剤を得る為に特に必須な成分であり、例えばヘキ
サグリセリン縮合リシノレート（版本薬品のｓｙグリス
ターＣＲ−５００）、テトラグリセリン縮合リシノレー
ト（版本薬品のＳＹグリスターＣＲ〜３１０）等が好ま
しく、特にヘキサグリセリン縮合リシノレートが好まし
い。Among the essential components of the emulsified rinse aid composition of the present invention, the degree of polymerization is 2.
~12 polyglycerin condensed ricinoleates are particularly essential components for obtaining milky rinse aids, such as hexaglycerin condensed ricinoleate (Hanhon Yakuhin's SY Glister CR-500), tetraglycerin condensed ricinoleate (Hanhon Yakuhin's SY Glister CR-310) and the like are preferred, and hexaglycerin condensed ricinoleate is particularly preferred.
この重合度２〜１２のポリグリセリンの縮合リシノレー
トがないと、白色乳状のすすぎ助剤は得られない。）Ｉ
ＬＢ ６〜１３のポリグリセリン脂肪酸エステルとして
は、テトラグリセリンモノラウレート（版本薬品（７）
ＳＹグ１７７！、 ター ＭＬ−３１０）や、テトラグ
リセリンモノオレエート（版本薬品のＳＹグリスターＭ
Ｏ−３１０）が特に好ましい。Without this condensed ricinoleate of polyglycerin with a degree of polymerization of 2 to 12, a white milky rinse aid cannot be obtained. )I
As the polyglycerin fatty acid ester of LB 6 to 13, tetraglycerin monolaurate (Hanhon Yakuhin (7)
SYgu177! , Tar ML-310) and tetraglycerin monooleate (Hanhon Yakuhin's SY Glister M
O-310) is particularly preferred.
ショ糖、グリセリン、ソルビタン、ソルバイト、ソルビ
ットから成る群から選ばれた１種又は２種以上の多価ア
ルコールと炭素原子数６〜１０個の脂肪酸との部分エス
テルとしては、ソルビタンモノカプリレート、グリセリ
ンモノカプリレート等があり、これらは使用濃度におけ
るすすぎ助剤溶液の泡立ちを抑え、食器に光沢を与える
。Partial esters of one or more polyhydric alcohols selected from the group consisting of sucrose, glycerin, sorbitan, sorbite, and sorbitol and fatty acids having 6 to 10 carbon atoms include sorbitan monocaprylate, glycerin These include monocaprylates, which suppress foaming of the rinse aid solution at the concentrations used and add shine to dishes.
これらの必須成分中の何れかが欠けると、安定な乳状す
すぎ助剤組成物は得られない。If any of these essential components are missing, a stable emulsified rinse aid composition will not be obtained.
更に本発明のすすぎ助剤組成物には、上記の必須成分以
外に本発明の成分以外のショ糖脂肪酸エステル、グリセ
リン脂肪酸エステル、プロピレングリコール脂肪酸エス
テル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪
酸エステル等の使用制限のない食器添加物界面活性剤、
ソルビット、エタノール、グリセリン、プロピレングリ
コール、グリシン、乳酸等を可溶化、防腐の目的で含む
ことができる。Furthermore, in addition to the above-mentioned essential components, the rinse aid composition of the present invention has restrictions on the use of sucrose fatty acid esters, glycerin fatty acid esters, propylene glycol fatty acid esters, sorbitan fatty acid esters, polyglycerin fatty acid esters, etc. Tableware additives without surfactants,
It may contain sorbitol, ethanol, glycerin, propylene glycol, glycine, lactic acid, etc. for the purpose of solubilization and preservation.
本発明の乳状すすぎ助剤組成物は、既に安定な乳状であ
る為、使用濃度ですすぎ水中で均一な微粒子となる。従
って優れたすすぎ性を有し、食器に水滴跡や筋を残さず
、泡立ちも少ない。Since the emulsified rinse aid composition of the present invention is already in a stable emulsion, it forms uniform fine particles in the rinse water at the concentration used. Therefore, it has excellent rinsing properties, leaves no water droplets or streaks on tableware, and produces little foaming.
更に可溶化剤を配合しな（でも済むことから、コストメ
リットもある。また、使用量における過マンガン酸カリ
ウム消費量が少な（、実質的な引火点も存在せず、非常
に安全で人体にも無害であり、長期保存安定性にも優れ
た乳状すすぎ助剤組成物である。Furthermore, there is a cost advantage as it does not require the addition of a solubilizer.In addition, the amount of potassium permanganate consumed is small (there is no substantial flash point, so it is extremely safe and harmful to the human body). It is also an emulsified rinse aid composition that is harmless and has excellent long-term storage stability.
更に本発明の乳状すすぎ助剤組成物は、単に必須成分を
室温で混合するだけで得ることができ、成分をいかなる
順序で混合しても長期安定性に優れたものが得られ、更
に高粘度になったり、ゲル状にならずに流動性があって
作業性が優れているという利点がある。高価な可溶化剤
を使用せずに済むことから、コストの面でも利点があり
、また、引火点が存在しないので安全性にも優れている
。Furthermore, the emulsified rinse aid composition of the present invention can be obtained simply by mixing the essential ingredients at room temperature, and can have excellent long-term stability even when the ingredients are mixed in any order; It has the advantage that it does not become sticky or gel-like, has fluidity, and has excellent workability. It is advantageous in terms of cost since it does not require the use of expensive solubilizers, and it is also excellent in safety as there is no flash point.
以下、実施例をもって本発明を更に詳細に説明するが、
本発明はこれらの実施例に限定されるものではない。Hereinafter, the present invention will be explained in more detail with reference to Examples.
The present invention is not limited to these examples.
実施例１〜１９、比較例１〜１１
自動食器洗浄機を使用し、磁製皿（径３０ｃｍ）、ガラ
スプレート（３０Ｘ ３０ｃｍ）をアルカリ洗浄剤で洗
浄し、下記の第１表、第２表で示される組成を有するす
すぎ助剤を１／１５０００に希釈した８０℃の熱湯です
すいだ後の食器の乾燥速度、ガラスプレートの仕上がり
具合（表面の斑点の有無）を評価した。また、すすぎ助
剤の室温安定性、泡立ち等の性状も評価した。Examples 1 to 19, Comparative Examples 1 to 11 Using an automatic dishwasher, a porcelain plate (diameter 30 cm) and a glass plate (30 x 30 cm) were washed with an alkaline detergent, and the following Tables 1 and 2 were washed. After rinsing with 80° C. hot water diluted with a rinsing aid having the composition shown below, the drying speed of the dishes and the finish of the glass plate (presence or absence of spots on the surface) were evaluated. In addition, properties such as room temperature stability and foaming of the rinse aid were also evaluated.
洗浄機：石川島播磨重工業■製ＪＷＤ−６型洗浄剤ニア
デカクリーンエイド製ウォソシュメイ トＳ （０，
２％）
すすぎ助剤：第１表、第２表に記載
測定方法：
（食器の乾燥速度及び仕上がり具合）
ガラスプレート１枚、磁製皿４枚を洗浄し、全ての食器
が完全に乾燥するまでの時間、ガラスプレートの仕上が
り状態を評価した。Cleaning machine: JWD-6 type manufactured by Ishikawajima Harima Heavy Industries ■Wososumeite S manufactured by Near Deka Clean Aid (0,
2%) Rinse aid: Listed in Tables 1 and 2 Measurement method: (Drying speed and finish of tableware) Wash 1 glass plate and 4 porcelain plates, and ensure that all tableware is completely dry. The finished state of the glass plate was evaluated.
（泡立ち）
食器洗浄機に７０ｆの湯を入れ、表に記載した組成物を
１／１００００の濃度になるように溶解した後、洗浄機
を２分間運転する。停止３０秒後の泡の高さを測る。(Foaming) Pour 70 f hot water into a dishwasher, dissolve the composition listed in the table to a concentration of 1/10,000, and then run the dishwasher for 2 minutes. Measure the height of the bubbles 30 seconds after stopping.
第１表〜第２表において◎○△×は下記のことを表して
いる。In Tables 1 to 2, ◎○△× represents the following.
また、上記のすすぎ助剤組成物を溶解せしめた熱湯を水
質基準に関する省令（昭４１．５．６厚令１１）に定め
られた方法で検査したところ、上記省令に定められた基
準に適合するものであった。In addition, when the hot water in which the above-mentioned rinse aid composition was dissolved was tested in accordance with the method stipulated in the Ministerial Ordinance on Water Quality Standards (May 6, 1972, Health Ordinance 11), it was found that it met the standards stipulated in the above-mentioned Ministerial Ordinance. It was something.
Claims (1)
〜５０重量％と、 ＨＬＢ６〜１３のポリグリセリン脂肪酸エステル５〜５
０重量％と、 ショ糖、グリセリン、ソルビタン、ソルバイト、ソルビ
ットからなる群より選ばれた１種または２種以上の多価
アルコールと、炭素原子数６〜１０個の脂肪酸との部分
エステル１〜１０重量％ とを必須成分として含有し、残部水からなる安定な乳状
すすぎ助剤組成物。[Claims] Condensed ricinoleate of polyglycerin with a degree of polymerization of 2 to 12 5
~50% by weight and polyglycerin fatty acid ester with HLB 6-13 5-5
1 to 10 partial esters of 0% by weight, one or more polyhydric alcohols selected from the group consisting of sucrose, glycerin, sorbitan, sorbite, and sorbitol, and fatty acids having 6 to 10 carbon atoms. % by weight as an essential component, with the remainder being water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61161193A JPH0678550B2 (en) | 1986-07-09 | 1986-07-09 | Rinse aid composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61161193A JPH0678550B2 (en) | 1986-07-09 | 1986-07-09 | Rinse aid composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6317995A true JPS6317995A (en) | 1988-01-25 |
| JPH0678550B2 JPH0678550B2 (en) | 1994-10-05 |
Family
ID=15730351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61161193A Expired - Lifetime JPH0678550B2 (en) | 1986-07-09 | 1986-07-09 | Rinse aid composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0678550B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04506367A (en) * | 1989-06-26 | 1992-11-05 | ユニリーバー・ナームローゼ・ベンノートシヤープ | liquid detergent composition |
| US6759481B2 (en) | 2001-01-24 | 2004-07-06 | Tat Hung Tong | Shape memory styrene copolymer |
| US6827325B2 (en) | 2000-08-28 | 2004-12-07 | Johnson & Johnson Vision Care, Inc. | Shape memory polymer or alloy ophthalmic lens mold and methods of forming ophthalmic products |
| JP2014181337A (en) * | 2013-03-19 | 2014-09-29 | Cxs Co Ltd | Drying and finishing agent composition for plastic tableware |
| JP2019052300A (en) * | 2017-09-12 | 2019-04-04 | 株式会社Adeka | Rinsing assistant composition, rinsing method of tableware, and composition for washing vegetable and fruit |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59187096A (en) * | 1983-04-06 | 1984-10-24 | ライオンハイジーン株式会社 | Rinsing aid |
| JPS6053599A (en) * | 1983-09-02 | 1985-03-27 | 旭電化工業株式会社 | Rinsing aid |
| JPS60149699A (en) * | 1984-01-13 | 1985-08-07 | 花王株式会社 | Detergent composition good for washing foods, dishes or like |
-
1986
- 1986-07-09 JP JP61161193A patent/JPH0678550B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59187096A (en) * | 1983-04-06 | 1984-10-24 | ライオンハイジーン株式会社 | Rinsing aid |
| JPS6053599A (en) * | 1983-09-02 | 1985-03-27 | 旭電化工業株式会社 | Rinsing aid |
| JPS60149699A (en) * | 1984-01-13 | 1985-08-07 | 花王株式会社 | Detergent composition good for washing foods, dishes or like |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04506367A (en) * | 1989-06-26 | 1992-11-05 | ユニリーバー・ナームローゼ・ベンノートシヤープ | liquid detergent composition |
| US6827325B2 (en) | 2000-08-28 | 2004-12-07 | Johnson & Johnson Vision Care, Inc. | Shape memory polymer or alloy ophthalmic lens mold and methods of forming ophthalmic products |
| US6759481B2 (en) | 2001-01-24 | 2004-07-06 | Tat Hung Tong | Shape memory styrene copolymer |
| JP2014181337A (en) * | 2013-03-19 | 2014-09-29 | Cxs Co Ltd | Drying and finishing agent composition for plastic tableware |
| JP2019052300A (en) * | 2017-09-12 | 2019-04-04 | 株式会社Adeka | Rinsing assistant composition, rinsing method of tableware, and composition for washing vegetable and fruit |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0678550B2 (en) | 1994-10-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |