JPS63132952A - Vinyl chloride resin composition - Google Patents
Vinyl chloride resin compositionInfo
- Publication number
- JPS63132952A JPS63132952A JP27933286A JP27933286A JPS63132952A JP S63132952 A JPS63132952 A JP S63132952A JP 27933286 A JP27933286 A JP 27933286A JP 27933286 A JP27933286 A JP 27933286A JP S63132952 A JPS63132952 A JP S63132952A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- plasticizer
- chloride resin
- weight
- moles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000011342 resin composition Substances 0.000 title description 22
- 239000004014 plasticizer Substances 0.000 claims abstract description 65
- 239000011347 resin Substances 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 13
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- -1 phthalate ester Chemical class 0.000 claims description 26
- 229910019142 PO4 Inorganic materials 0.000 claims description 14
- 239000010452 phosphate Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 13
- 150000002148 esters Chemical class 0.000 abstract description 8
- 238000012856 packing Methods 0.000 abstract description 2
- 239000002216 antistatic agent Substances 0.000 description 13
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 11
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 10
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 238000002834 transmittance Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000003063 flame retardant Substances 0.000 description 6
- 230000000740 bleeding effect Effects 0.000 description 5
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000002923 metal particle Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- YYQRGCZGSFRBAM-UHFFFAOYSA-N Triclofos Chemical compound OP(O)(=O)OCC(Cl)(Cl)Cl YYQRGCZGSFRBAM-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000008029 phthalate plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 229960001147 triclofos Drugs 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、塩化ビニル系樹脂組成物に関し、さらに詳細
には帯電防止性、導電性、難燃性、透明性に優れた塩化
ビニル系樹脂フィルムあるいはシートを提供することが
可能な塩化ビニル系樹脂組成物に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a vinyl chloride resin composition, and more particularly to a vinyl chloride resin composition that has excellent antistatic properties, conductivity, flame retardancy, and transparency. The present invention relates to a vinyl chloride resin composition that can be used to form films or sheets.
従来、帯電防止性、難燃性を有する透明塩化ビニル系樹
脂成形品、例えば帯電防止性、難燃性を有する透明塩化
ビニル樹脂フィルムあるいはシートを製造する方法とし
そは、■難燃性可塑剤であるリン酸エステル系可塑剤（
例えば、トリクレジルホスフェートなど）を配合して得
られる塩化ビニル系樹脂組成物から透明フィルム（シー
ト）を製造し、このフィルム表面に超微粒子金属とバイ
ンダー樹脂と溶剤とを混合して得られた導電性処理剤を
全面にコーティングする方法やカーボンブラックとバイ
ンダー樹脂と溶剤とを混合して得られた導電性処理剤を
網目状にコーティングする方法、■難燃性を有するトリ
クレジルホスフェートなどのリン酸エステル系可塑剤の
ほかに帯電防止剤を配合した塩化ビニル系樹脂組成物を
採用する方法、■前記リン酸エステル系可塑剤などによ
って難燃性を付与された塩化ビニル系樹脂組成物よりフ
ィルムあるいはシートを製造し、この表面に帯電防止剤
をコーティングする方法などが提案されている。Conventionally, methods for manufacturing transparent vinyl chloride resin molded products with antistatic and flame retardant properties, such as transparent vinyl chloride resin films or sheets with antistatic and flame retardant properties, are as follows: ■Flame retardant plasticizer A phosphate ester plasticizer (
For example, a transparent film (sheet) is produced from a vinyl chloride resin composition obtained by blending tricresyl phosphate, etc.), and ultrafine metal particles, a binder resin, and a solvent are mixed on the surface of this film. A method of coating the entire surface with a conductive treatment agent, a method of coating a conductive treatment agent obtained by mixing carbon black, a binder resin, and a solvent in a mesh pattern, A method of adopting a vinyl chloride resin composition containing an antistatic agent in addition to a phosphate ester plasticizer, ■ a method of using a vinyl chloride resin composition that has been imparted with flame retardancy by the above-mentioned phosphate ester plasticizer, etc. A method has been proposed in which a film or sheet is manufactured and the surface thereof is coated with an antistatic agent.
しかしながら、前記■導電性処理剤をコーティングする
方法では、フィルムあるいはシート表面にカーボンブラ
ックや超微粒子金属がコーティングされているため、例
えば全光線透過率が８０％以上であるという完全に透明
に近いものは得られないのが現状である。また、カーボ
ンブラックで処理されたものは、黒く着色されており、
色相上用途が制限されるし、超微粒子金属で処理された
ものでは、ヘイズ値が大きくなるという欠点をも有する
。さらに、この方法では、表面コーティングによって導
電性を得ているが、過酷な使用条件では、導電性塗膜が
溶解または剥離する場合がある。However, in the method (1) of coating with a conductive treatment agent, the surface of the film or sheet is coated with carbon black or ultrafine metal particles, so it is almost completely transparent, with a total light transmittance of 80% or more. Currently, it is not possible to obtain In addition, those treated with carbon black are colored black,
Its uses are limited due to its hue, and those treated with ultrafine metal particles also have the disadvantage of increased haze value. Furthermore, in this method, conductivity is obtained by surface coating, but under severe usage conditions, the conductive coating may dissolve or peel off.
また、前記■難燃性可塑剤と帯電防止剤とを配合した塩
化ビニル系樹脂組成物を使用する場合には、従来の帯電
防止剤を併用しており、これでは充分な導電性効果が得
られず、充分な帯電防止効果を得よるために帯電防止剤
を多量に添加すると、逆に激しいブリード、ブルーム現
象が生起して、フィルムやシートの外観、透明性を損な
うことになり、実用に供し得ないものである。しかも、
フィルムやシート表面にブリードした帯電防止剤を拭き
取った場合、導電性効果が元に戻るのに、かなりの日数
を要することになる。In addition, when using a vinyl chloride resin composition containing a flame-retardant plasticizer and an antistatic agent mentioned above, a conventional antistatic agent is also used, but this does not provide sufficient electrical conductivity. If a large amount of antistatic agent is added to obtain a sufficient antistatic effect, severe bleeding and blooming phenomena will occur, impairing the appearance and transparency of the film or sheet, making it impractical for practical use. It cannot be provided. Moreover,
If the antistatic agent that has bled onto the surface of a film or sheet is wiped off, it will take a considerable number of days for the conductive effect to return to its original state.
さらに、前記■フィルムやシートの表面に単に帯電防止
剤をコーティングする方法では、導電性効果の永続性に
欠けるものである。Furthermore, the above-mentioned method (2) of simply coating the surface of a film or sheet with an antistatic agent lacks the permanence of the conductive effect.
本発明は、前記従来技術の問題点を背景になされたもの
で、難燃性を有し、透明で（全光線透過率が８０％以上
）、導電性（表面抵抗１０９〜１０１茸Ω）を有し、永
続的に難燃性、導電性を有する透明なフィルム、シート
を製造することが可能な塩化ビニル系樹脂組成物を提供
することにある。The present invention was made against the background of the problems of the prior art, and has flame retardant, transparent (total light transmittance of 80% or more), and electrical conductivity (surface resistance of 109 to 101 ohms). The object of the present invention is to provide a vinyl chloride resin composition that can be used to produce transparent films and sheets that have permanent flame retardancy and electrical conductivity.
すなわち、本発明は、塩化ビニル系樹脂１００重量部に
対して、下記一般式で表されるフタル酸エステル系可塑
剤（■）（以下「可塑剤（Ｉ）」ということがある）と
、リン酸エステル系可塑剤（ＩＩ）（以下「可塑剤（Ｉ
Ｉ）」ということがある）とを、（１）＋ （ＩＩ）が
３０〜６０重量部で、かつ（１） ／ （ＩＩ）の重量
比が４／１〜１／４となるように配合したことを特徴と
する塩化ビニル系樹脂組成物を提供するものである。That is, the present invention uses a phthalate ester plasticizer (■) represented by the following general formula (hereinafter sometimes referred to as "plasticizer (I)") and phosphorus to 100 parts by weight of a vinyl chloride resin. Acid ester plasticizer (II) (hereinafter referred to as "plasticizer (I)")
(sometimes referred to as "I)") in such a way that (1) + (II) is 30 to 60 parts by weight, and the weight ratio of (1) / (II) is 4/1 to 1/4. The present invention provides a vinyl chloride resin composition characterized by the following.
（式中、Ｒは同一または異なっていてもよく、炭素数３
〜１５の長鎖状または分岐状アルキル基、Ａは炭素数２
〜４のアルキレン基、ｍＳｎは同一または異なっていて
もよく、１〜７の整数、ただし、Ａ＋Ｈの炭素数は５〜
１７である。）本発明に使用され乏塩化ビニル系樹脂と
は、塩化ビニル単独重合体（ポリ塩化ビニル）、あるい
は塩化ビニルと他のモノマー、例えばエチレン、酢酸ビ
ニル、ビニルエーテル、マレイン酸エステル、（メタ）
アクリル酸、（メタ）アクリル酸エステルとの共重合体
をも含むものである。(In the formula, R may be the same or different, and has 3 carbon atoms.
~15 long-chain or branched alkyl groups, A having 2 carbon atoms
The alkylene group of ~4, mSn may be the same or different, and is an integer of 1 to 7, provided that the number of carbon atoms in A+H is 5 to
It is 17. ) The poor vinyl chloride resin used in the present invention is a vinyl chloride homopolymer (polyvinyl chloride), or vinyl chloride and other monomers, such as ethylene, vinyl acetate, vinyl ether, maleate ester, (meth)
It also includes copolymers with acrylic acid and (meth)acrylic esters.
本発明の樹脂組成物は、かかる塩化ビニル系樹脂に、帯
電防止性、導電性を付与するために前記フタル酸エステ
ル系可塑剤（１）と、難燃性を与えるためにリン酸エス
テル系可塑剤（Ｉｆ）とを特定の割合で配合したもので
ある。The resin composition of the present invention contains the above-mentioned phthalate ester plasticizer (1) to impart antistatic properties and conductivity to the vinyl chloride resin, and phosphate ester plasticizer (1) to impart flame retardancy to the vinyl chloride resin. (If) in a specific ratio.
ここで、前記一般式で表されるフタル酸エステル系可塑
剤（１）は、特開昭５９−１０５０３７号公報において
既に提案されたものであるが、本発明らは、この可塑剤
（１）と可塑剤（ＩＩ）とを塩化ビニル系樹脂に対して
特定割合で併用して混合すると、導電性、難燃性が相乗
的に著しく発現されることを見出したものである。Here, the phthalate ester plasticizer (1) represented by the above general formula has already been proposed in JP-A-59-105037; It has been discovered that when a vinyl chloride resin and a plasticizer (II) are mixed together in a specific ratio, conductivity and flame retardance are significantly enhanced synergistically.
この可塑剤（１）について、前記公開公報の一部を援用
して説明すると、このものは、炭素数１〜３の直鎖状ま
たは分岐状脂肪族アルコールに炭素数２〜４のアルキレ
ンオキサイドを１〜７モル付加し、アルコールとアルキ
レンオキサイドの合計炭素数が５〜１７である末端ヒド
ロキシル化合物と、フタル酸とを、一般的なフタル酸エ
ステルの製造方法に準じて製造することができる。This plasticizer (1) will be explained with reference to a part of the above-mentioned publication. This plasticizer (1) is a linear or branched aliphatic alcohol having 1 to 3 carbon atoms and an alkylene oxide having 2 to 4 carbon atoms. A terminal hydroxyl compound in which 1 to 7 moles of alcohol and alkylene oxide are added and the total carbon number of the alcohol and alkylene oxide is 5 to 17, and phthalic acid can be produced according to a general method for producing phthalate esters.
アルコールの炭素数、アルキレンオキサイドの付加モル
数およびアルコールとアルキレンオキサイド合計炭素数
は、前記一般式で規定した範囲を外れると、導電性を有
する可塑剤としてのバランスが失われ好ましくない、ア
ルコールにアルキレンオキサイドを付加する場合、付加
モル量が単一にならず、前後に分岐するケースがみられ
るが、前記一般式に含まれる範囲であれば、単一物のみ
ならず、付加モル量の異なったものの混合物であっても
よい。If the number of carbon atoms in the alcohol, the number of moles added to the alkylene oxide, and the total number of carbon atoms in the alcohol and alkylene oxide are out of the range specified in the above general formula, the balance as a conductive plasticizer will be lost, which is undesirable. When adding oxides, there are cases where the added molar amount is not single and branches before and after, but as long as it is within the range included in the above general formula, not only a single product but also different molar amounts of added oxides can be added. It may be a mixture of things.
かかる可塑剤（１）としては、例えばプロパツールに、
エチレンオキサイド１〜７モル、プロピレンオキサイド
１〜４モル、もしくはブチレンオキサイド１〜３モルを
付加させた化合物、ブタノールに、エチレンオキサイド
１〜６モル、プロピレンオキサイド１〜４モル、もしく
はブチレンオキサイド１〜３モル付加させた化合物、ヘ
キサノールに、エチレンオキサイド１〜５モル、プロピ
レンオキサイド１〜３モル、もしくはブチレンオキサイ
ド１〜２モル付加させた化合物、ヘプタツールに、エチ
レンオキサイド１〜５モル、プロピレンオキサイド１〜
３モル、もしくはブチレンオキサイド１〜２モル付加さ
せた化合物、オクタツールに、エチレンオキサイド１〜
４モル、プロピレンオキサイド１〜３モル、もしくはブ
チレンオキサイド１〜２モル付加させた化合物、ノナノ
ールに、エチレンオキサイド１〜４モル、プロピレンオ
キサイド１〜２モル、もしくはブチレンオキサイド１〜
２モル付加させた化合物、デカノールに、エチレンオキ
サイド１〜３モル、プロピレンオキサイド１〜２モル、
もしくはブチレンオキサイド１モル付加させた化合物、
ドデカノールに、エチレンオキサイド１〜２モル、プロ
ピレンオキサイド１モル、もしくはブチレンオキサイド
１モル付加させた化合物、トリデカノールに、エチレン
オキサイド１〜２モル、プロピレンオキサイド１モル、
もしくはブチレンオキサイド１モル付加させた化合物、
テトラデカノールに、エチレンオキサイド１モル、もし
くはプロピレンオキサイド１モル付加させた化合物、ペ
ンタデカノールに、エチレンオキサイド１モル付加させ
た化合物、またはそれぞれに該当する第２級アルコール
に、該当するアルキレンオキサイドを付加させた化合物
の単独または混合物の、フタル酸ジエステル（置換エス
テルを含む）が挙げられる。Such plasticizers (1) include, for example, propatool,
Compound with 1 to 7 moles of ethylene oxide, 1 to 4 moles of propylene oxide, or 1 to 3 moles of butylene oxide added to butanol, 1 to 6 moles of ethylene oxide, 1 to 4 moles of propylene oxide, or 1 to 3 moles of butylene oxide A compound in which 1 to 5 moles of ethylene oxide, 1 to 3 moles of propylene oxide, or 1 to 2 moles of butylene oxide is added to heptatool, 1 to 5 moles of ethylene oxide, 1 to 5 moles of propylene oxide to heptatool.
A compound with 3 moles or 1 to 2 moles of butylene oxide added to octatool, and 1 to 1 to 2 moles of ethylene oxide.
4 moles, 1 to 3 moles of propylene oxide, or 1 to 2 moles of butylene oxide, to nonanol, 1 to 4 moles of ethylene oxide, 1 to 2 moles of propylene oxide, or 1 to 1 moles of butylene oxide.
2 moles of compound added to decanol, 1 to 3 moles of ethylene oxide, 1 to 2 moles of propylene oxide,
Or a compound to which 1 mole of butylene oxide is added,
A compound obtained by adding 1 to 2 moles of ethylene oxide, 1 mole of propylene oxide, or 1 mole of butylene oxide to dodecanol; 1 to 2 moles of ethylene oxide, 1 mole of propylene oxide to tridecanol;
Or a compound to which 1 mole of butylene oxide is added,
A compound in which 1 mole of ethylene oxide or 1 mole of propylene oxide is added to tetradecanol, a compound in which 1 mole of ethylene oxide is added to pentadecanol, or a corresponding alkylene oxide to the corresponding secondary alcohol. Examples include phthalic acid diesters (including substituted esters), alone or in mixtures of added compounds.
次に、可塑剤（Ｉｆ）としては、通常使用されるリン酸
エステル系可塑剤が全て使用できるが、例えば一般式Ｐ
Ｏ（ＯＡＯＲ）ｓ （式中、ＡおよびＲは前記に同じ
であり、Ｒは同一または異なっていてもよく、炭素数３
〜１５の長鎖状または分岐状アルキル基、Ａは炭素数２
〜４のアルキレン基である）で表されるリン酸エステル
（具体的にはトリブトキシエチルホスフェートなど）、
トリクレジルホスフェート（ＴＣＰ） 、）リブチルホ
スフェート、トリフェニルホスツブエート、トリクロル
エチルホスフェート、トリオクチルホスフェート、ジフ
ェニルクレジルホスフェートなどを挙げることができろ
か、好ましくは前記一般式ＰＯ（ＯＡＯＲ）ｓで表され
るリン酸エステル、またはトリクレジルホスフェートで
ある。Next, as the plasticizer (If), all commonly used phosphate ester plasticizers can be used, but for example, general formula P
O(OAOR)s (wherein A and R are the same as above, R may be the same or different, and have 3 carbon atoms
~15 long-chain or branched alkyl groups, A having 2 carbon atoms
~4 alkylene group) (specifically tributoxyethyl phosphate, etc.),
Tricresyl phosphate (TCP), butyl phosphate, triphenylphostubate, trichloroethyl phosphate, trioctyl phosphate, diphenyl cresyl phosphate, etc., preferably with the general formula PO(OAOR)s It is a phosphoric acid ester represented by the formula, or tricresyl phosphate.
本発明では、塩化ビニル系樹脂に可塑剤（りと可塑剤（
ＩＩ）とを特定量含有させたものであるが、その他の可
塑剤、例えばジブチルフタレート、ジオクチルフタレー
ト、ブチルベンジルフタレートなどのフタル酸エステル
；ジオクチルアジペート、ジオクチルアゼレート、ジオ
クチルセバケートなどの脂肪族多塩基酸エステル；さら
にクエン酸エステル、エポキシ系可塑剤、ポリエステル
系可塑剤、ウレタン系可塑剤などを、難燃性および導電
効果を阻害しない範囲で併用することもできる。In the present invention, a plasticizer is added to the vinyl chloride resin.
II), but other plasticizers such as phthalate esters such as dibutyl phthalate, dioctyl phthalate, and butylbenzyl phthalate; aliphatic polyesters such as dioctyl adipate, dioctyl azelate, and dioctyl sebacate. Basic acid esters; citric acid esters, epoxy plasticizers, polyester plasticizers, urethane plasticizers, etc. can also be used in combination as long as the flame retardancy and conductivity effects are not impaired.
可塑剤（１）と可塑剤（Ｉｆ）の使用割合は、塩化ビニ
ル系樹脂１００重量部に対して、（■）＋（ＩＩ）が３
０〜６０重量部、好ましくは３５〜６０重量部であり、
３０重量部未満では帯電防止性、導電性に乏しいものと
なり、一方６０重量部を超えると帯電防止性、導電性が
比例的に増大せず、経済的でないばかりか、難燃性を得
ることが難しくなり、いずれも好ましくない。The usage ratio of plasticizer (1) and plasticizer (If) is (■) + (II) is 3 parts by weight for 100 parts by weight of vinyl chloride resin.
0 to 60 parts by weight, preferably 35 to 60 parts by weight,
If it is less than 30 parts by weight, the antistatic properties and conductivity will be poor, while if it exceeds 60 parts by weight, the antistatic properties and conductivity will not increase proportionately, and it will not only be uneconomical but also difficult to obtain flame retardancy. Both are difficult and undesirable.
この可塑剤（１）と可塑剤（ＩＩ）の使用比率は目的と
する製品の風合によって異なるが、（Ｉ）／（ＩＩ）の
重量比で、４／１−１／４、好ましくは３／１〜１／３
である。The ratio of plasticizer (1) and plasticizer (II) used varies depending on the desired texture of the product, but the weight ratio of (I)/(II) is 4/1 to 1/4, preferably 3 /1~1/3
It is.
なお、本発明の組成物において、リン酸エステル系可塑
剤（ＩＩ）として、一般式ＰＯ（ＯＡＯＲ）ｓ表される
リン酸エステル（トリプトキシエチルホスフェートなど
）を使用する場合には、塩化ビニル系樹脂１００重量部
に対して（１）＋ （ＩＩ）が３０〜６０重量部、かつ
リン酸エステル系可塑剤（ＩＩ）の割合が、全可塑剤（
（１） ＋ （Ｉｆ） ）に対して２５〜８３重量％に
なすことが好ましい。In addition, in the composition of the present invention, when using a phosphate ester represented by the general formula PO(OAOR)s (such as tryptoxyethyl phosphate) as the phosphate ester plasticizer (II), vinyl chloride plasticizer (II) may be used. (1) + (II) is 30 to 60 parts by weight per 100 parts by weight of the resin, and the proportion of the phosphate ester plasticizer (II) is as low as the total plasticizer (
(1) + (If)) is preferably 25 to 83% by weight.
また、本発明の組成物において、リン酸エステル系可塑
剤（Ｉｆ）として、トリクレジルホスフェート（ＴＣＰ
）をを使用する場合には、塩化ビニル系樹脂１００重量
部に対して（Ｉ） ＋ （ＩＩ）が４０〜６０重１部、
かつフタル酸エステル系可塑剤（りの割合が、全可塑剤
（（１） ＋ （ＩＩ） ）に対して３３〜７０重景％
に重量ことが好ましい。Furthermore, in the composition of the present invention, tricresyl phosphate (TCP) is used as the phosphate plasticizer (If).
), 1 part by weight of (I) + (II) is 40 to 60 parts by weight per 100 parts by weight of vinyl chloride resin,
and phthalate ester plasticizer (ratio of 33 to 70% relative to total plasticizer ((1) + (II))
Weight is preferred.
本発明の組成物には、さらに必要に応じて安定剤、着色
剤、滑剤などを含有していていもよい。The composition of the present invention may further contain stabilizers, colorants, lubricants, etc., if necessary.
この安定剤としては、例えばジブチルスズラウレートな
どのスズ系安定剤、ステアリン酸亜鉛、ステアリン酸カ
ルシウムなどの金属石鹸などを挙げることができる。ま
た、滑剤としては、例えば高級脂肪酸エステル、低分子
量ポリエチレンなどの通常塩化ビニル系樹脂組成物に使
用される滑剤が使用される。Examples of the stabilizer include tin-based stabilizers such as dibutyltin laurate, and metal soaps such as zinc stearate and calcium stearate. Further, as the lubricant, for example, a lubricant commonly used in vinyl chloride resin compositions such as higher fatty acid ester or low molecular weight polyethylene is used.
本発明の塩化ビニル系樹脂組成物は、従来の塩化ビニル
系樹脂組成物と同様にして、混合、混煉され、例えばカ
レンダー加工などによって、フィルム、シートとして使
用される。The vinyl chloride resin composition of the present invention is mixed and kneaded in the same manner as conventional vinyl chloride resin compositions, and used as a film or sheet by, for example, calendering.
すなわち、スーパーミキサー、ブレングーなどの混合機
により塩化ビニル系樹脂、可塑剤（１）および（ＩＩ）
、必要に応じて安定剤、着色剤、他の可塑剤、滑剤など
を混合され、バンバリーミキサ−、ミキシングロール、
押し出し機などにより混練され、さらに必要に応じて造
粒され、フィルムあるいシート用材料として使用される
。That is, vinyl chloride resin, plasticizers (1) and (II) are mixed using a mixer such as a super mixer or a blender.
, stabilizers, colorants, other plasticizers, lubricants, etc. are mixed as necessary, and Banbury mixer, mixing roll,
The mixture is kneaded using an extruder, granulated if necessary, and used as a film or sheet material.
本発明の塩化ビニル系樹脂組成物は、フィルム、シート
のほか、塩化ビニル系樹脂成形品のあらゆる分野、例え
ばパツキン、チューブ、ホース、レザー、電線被覆、ジ
ャバラ状成形品、自動車のバンパー、自転車のハンドル
グリップ、電子機器の基材などにも利用することができ
る。In addition to films and sheets, the vinyl chloride resin composition of the present invention can be used in all fields of vinyl chloride resin molded products, such as packing, tubes, hoses, leather, electric wire coverings, bellows-shaped molded products, automobile bumpers, and bicycle parts. It can also be used for handle grips, base materials for electronic devices, etc.
本発明の塩化ビニル系樹脂組成物は、フタル酸エステル
系可塑剤（１）が帯電防止性、導電性を与え、またリン
酸エステエル系可塑剤（ＩＩ）が難燃性を与えると同時
に、これらの可塑剤（１）および（ＩＩ）が相乗的に作
用して、難燃性、帯電防止性、導電性を著しく高めるも
のである。In the vinyl chloride resin composition of the present invention, the phthalate plasticizer (1) provides antistatic properties and conductivity, and the phosphate plasticizer (II) provides flame retardancy. The plasticizers (1) and (II) act synergistically to significantly improve flame retardancy, antistatic properties, and electrical conductivity.
以下、実施例を挙げ、本発明をさらに具体的に説明する
が、本発明は以下の実施例に限定されるものではない。EXAMPLES Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to the following Examples.
なお、実施例中、表面抵抗はＪＩＳ−に６９１１に、全
光線透過率はＪＩＳ Ｋ７１０５に、難燃性は消防法
施行規則第４条の３に、それぞれ準拠して測定したもの
であり、また強制ブリードはサンプルを４０℃×湿度８
０％の雰囲気下に１週間放置したあとの状態を観察し、
○が外観に変化なし、Δが若干ブリード、×が激しくブ
リードとして評価したものである。In addition, in the examples, surface resistance was measured in accordance with JIS-6911, total light transmittance was measured in accordance with JIS K7105, and flame retardancy was measured in accordance with Article 4-3 of the Fire Service Act Enforcement Regulations. For forced bleed, sample at 40℃ x humidity 8
Observe the condition after leaving it in a 0% atmosphere for one week,
○ indicates no change in appearance, Δ indicates slight bleeding, and × indicates severe bleeding.
実施例１
塩化ビニル系樹脂（ＰＶＣ）１００重量部に対し、フタ
ル酸エステル系可塑剤（１）として、新日本理化■製、
サンソサイザーＣ−１１００、リン酸エステル系可塑剤
（ＩＩ）として、トリクレジルホスフェート（ＴＣＰ）
を使用し、可塑剤の総計量を５０重量部とし、可塑剤（
りと（ＩＩ）の混合比率を種々変えて塩化ビニル系樹脂
組成物を作製し、これを用いてテストロールにて厚さ０
．３鶴のフィルムを製造し、表面抵抗、全光線透過率、
難燃性を評価した。結果を第１表に示す。Example 1 To 100 parts by weight of vinyl chloride resin (PVC), as a phthalate ester plasticizer (1),
Sansocizer C-1100, tricresyl phosphate (TCP) as phosphate ester plasticizer (II)
was used, the total amount of plasticizer was 50 parts by weight, and the plasticizer (
Vinyl chloride resin compositions were prepared by varying the mixing ratio of Rito (II), and the compositions were rolled to a thickness of 0 using a test roll.
．． Manufacture 3 Tsuru films and measure surface resistance, total light transmittance,
Flame retardancy was evaluated. The results are shown in Table 1.
第１表
＊１）平均重合度；下−１０５０の塩化ビニル単独重合
体
＊２）Ｂａ−Ｚｎ系安定剤
＄３）Ｂａ−Ｚｎ系金属石鹸
第１表から明らかなように、実験阻１−５〜１−６は、
表面抵抗の値は小さいものの、消防法施行規則第４条の
３の規定による難燃性試験において炭化面積の基準を満
たしておらず、また実験ぬ１−７は、難燃性に優れてい
るが、表面抵抗の値が大きく、帯電防止性に劣るもので
ある。Table 1 *1) Average degree of polymerization: -1050 vinyl chloride homopolymer *2) Ba-Zn stabilizer $3) Ba-Zn metal soap 5 to 1-6 are
Although the value of surface resistance is small, it does not meet the criteria for charred area in the flame retardancy test according to Article 4-3 of the Fire Service Act Enforcement Regulations, and Test No. 1-7 has excellent flame retardancy. However, the surface resistance value is large and the antistatic property is poor.
これに対し、実験１１ｋ１１−１〜１−４は、表面抵抗
の値および難燃性のいずれの面からも基準を満足してい
る。On the other hand, Experiments 11k11-1 to 11-4 satisfied the standards in terms of both surface resistance and flame retardancy.
実施例２
可塑剤の総計量を４ｏｍｔ部とし、可塑剤（１）と（Ｉ
ｆ）の混合比率を種々変えた以外は、実施例１と同様に
してフィルムを製造し、表面抵抗、全光線透過率、難燃
性を評価した。結果を併せ、第２表に示す。Example 2 The total amount of plasticizer was 4 omt parts, and plasticizer (1) and (I
Films were produced in the same manner as in Example 1, except that the mixing ratio of f) was varied, and the surface resistance, total light transmittance, and flame retardance were evaluated. The results are shown in Table 2.
（以下余白）
第２表
実施例３
可塑剤の総計量を６０重量部とし、可塑剤（Ｉ）と（Ｉ
Ｉ）の混合比率を種々変えた以外は、実施例１と同様に
してフィルムを製造し、表面抵抗、全光線透過率、難燃
性を評価した。結果を第３表に示す。(Margin below) Table 2 Example 3 The total amount of plasticizer was 60 parts by weight, and plasticizer (I) and (I
Films were produced in the same manner as in Example 1, except that the mixing ratio of I) was varied, and the surface resistance, total light transmittance, and flame retardance were evaluated. The results are shown in Table 3.
第３表
実施例４
下記配合処方で塩化ビニル系樹脂組成物を調製し、この
組成物を用いて実施例１と同様にしてフィルムを製造し
、流水処理による帯電防止性能の変化を実験した。結果
を第４表に示す。Table 3 Example 4 A vinyl chloride resin composition was prepared according to the following formulation, and a film was produced using this composition in the same manner as in Example 1. Changes in antistatic performance by running water treatment were tested. The results are shown in Table 4.
第４表
＊４）大協化成■製、カチオン系帯電防止剤＊５）フィ
ルム上に、カチオン系帯電防止剤（花王側製、エレクト
ロストリッパーＱＮ）の１重量％水溶液をスプレー処理
した。Table 4 *4) Cationic antistatic agent manufactured by Daikyo Kasei *5) A 1% by weight aqueous solution of a cationic antistatic agent (Electro Stripper QN, manufactured by Kao Corporation) was sprayed onto the film.
第４表から明らかなように、本発明の樹脂組成物より得
られるフィルムは、流水に２４時間浸漬後も帯電防止性
に優れたものであるが（実験隘４−１）、これに対し可
塑剤（１）の代わりにり。As is clear from Table 4, the film obtained from the resin composition of the present invention has excellent antistatic properties even after being immersed in running water for 24 hours (Experiment 4-1). Substitute for agent (1).
Ｐを使用し、かつ通常の帯電防止剤を練り込んだもの（
実験Ｎ１４−２） 、あるいは可塑剤（１）の代わりに
ＤＯＰを使用し、かつ通常の帯電防止剤をフィルム表面
にコーティングしたもの（実験光４−３）では、耐久性
に劣りいずれも流水２４時間浸漬後の帯電防止性能が悪
化している。P and mixed with a normal antistatic agent (
Experiment N14-2), or a film in which DOP was used instead of plasticizer (1) and a normal antistatic agent was coated on the film surface (Experiment Light 4-3), the durability was poor and both of them The antistatic performance deteriorates after soaking for a period of time.
実施例５
塩化ビニル系樹脂（ＰＶＣ）１００重量部に対し、フタ
ル酸エステル系可塑剤（１）として、新日本理化■製、
サンソサイザーＣ−１１００、リン酸エステル系可塑剤
（ＩＩ）として、大へ化学■製、ＴＢＸＰを使用し、可
塑剤の総計量を３０重量部とした以外は、実施例１と同
様にして実験し、表面抵抗、全光線透過率、難燃性、強
制ブリードを評価した。結果を第５表に示す。Example 5 To 100 parts by weight of vinyl chloride resin (PVC), as a phthalate ester plasticizer (1),
The experiment was carried out in the same manner as in Example 1, except that Sansocizer C-1100 and TBXP manufactured by Ohe Kagaku ■ were used as the phosphate ester plasticizer (II), and the total amount of plasticizer was 30 parts by weight. The surface resistance, total light transmittance, flame retardance, and forced bleed were evaluated. The results are shown in Table 5.
第５表
第５表から明らかなように、実験Ｎａ５−５は、表面抵
抗、難燃性に優れるが、ブリードの点で実用性に劣り、
また実験光５−５〜５−６は、表面抵抗の値は小さいも
のの、消防法施行規則第４条の３の規定による難燃性試
験において、炭化面積の基準を満たしていない。これに
対し、実験１１ｈ５−１〜５−４は、表面抵抗の値およ
び難燃性のいずれの面からも基準を満足し、ブリードの
点でも実用に耐えるものである。Table 5 As is clear from Table 5, experimental Na5-5 has excellent surface resistance and flame retardancy, but is inferior in practicality in terms of bleeding.
Although the experimental lights 5-5 to 5-6 had small surface resistance values, they did not meet the criteria for carbonized area in the flame retardancy test pursuant to Article 4-3 of the Fire Service Act Enforcement Regulations. On the other hand, Experiments 11h5-1 to 5-4 satisfied the standards in terms of both surface resistance and flame retardancy, and were practical in terms of bleeding.
実施例６
可塑剤の総計量を４０重量部とし、可塑剤（１）と（Ｉ
Ｉ）の混合比率を種々変えた以外は、実施例５と同様に
して実験した。結果を併せ、第６表に示す。Example 6 The total amount of plasticizers was 40 parts by weight, and plasticizers (1) and (I
An experiment was carried out in the same manner as in Example 5, except that the mixing ratio of I) was varied. The results are shown in Table 6.
（以下余白）
第６表
実施例７
可塑剤の総計量を５０重量部とした以外は、実施例５と
同様に実験した。結果を第７表に示す。(The following is a blank space) Table 6 Example 7 An experiment was carried out in the same manner as in Example 5 except that the total amount of plasticizer was 50 parts by weight. The results are shown in Table 7.
第７表
実施例８
可塑剤の総計量を６０重量部とした以外は、実施例５と
同様に実験した。結果を第８表に示す。Table 7 Example 8 An experiment was carried out in the same manner as in Example 5 except that the total amount of plasticizer was 60 parts by weight. The results are shown in Table 8.
第８表
実施例９
下記配合処方で塩化ビニル系樹脂組成物を調製し、この
組成物を用いて実施例１と同様にしてフィルムを製造し
、実施例４と同様にして流水処理による帯電防止性能の
変化を実験した。Table 8 Example 9 A vinyl chloride resin composition was prepared with the following formulation, a film was produced using this composition in the same manner as in Example 1, and antistatic treatment was carried out in the same manner as in Example 4 by running water treatment. We experimented with changes in performance.
結果を第９表に示す。The results are shown in Table 9.
第９表
第９表から明らかなように、本発明の樹脂組成物より得
られるフィルムは、流水に２４時間浸漬後も帯電防止性
に優れたものであるが（実験ｔｌｋＬ９−１）、これに
対し可塑剤（１）の代わりにり。Table 9 As is clear from Table 9, the film obtained from the resin composition of the present invention has excellent antistatic properties even after being immersed in running water for 24 hours (experiment tlkL9-1); On the other hand, instead of plasticizer (1).
Ｐを、また可塑剤（ＩＩ）としてＴＣＰを併用し、かつ
通常の帯電防止剤を練り込んだもの（実験隘９−２）、
あるいは可塑剤（１）の代わりにＤＯＰを、また可塑剤
（ＩＩ）としてＴＣＰを併用し、かつ通常の帯電防止剤
をフィルム表面にコーティングしたもの（実験１に９−
３）では、耐久性に劣りいずれも流水２４時間浸漬後の
帯電防止性能が悪化していることが分かる。P and TCP as a plasticizer (II) were used together, and a normal antistatic agent was mixed in (Experiment No. 9-2),
Alternatively, DOP was used instead of the plasticizer (1) and TCP was used as the plasticizer (II), and the film surface was coated with a normal antistatic agent (9-
It can be seen that in case 3), the durability is poor and the antistatic performance after immersion in running water for 24 hours deteriorates.
本発明は、難燃性を有し、透明で（全光線透過率が８０
％以上）、導電性（表面抵抗１０９〜１０１８Ω）であ
り、永続的に難燃性、導電性を有するフィルム、シート
を製造することが可能な塩化ビニル系樹脂組成物を提供
することができる。The present invention has flame retardancy, is transparent (total light transmittance is 80
% or more), electrical conductivity (surface resistance of 109 to 1018 Ω), and a vinyl chloride resin composition capable of producing permanently flame-retardant and electrically conductive films and sheets.
Claims (1)
般式で表されるフタル酸エステル系可塑剤（ I ）と、
リン酸エステル系可塑剤（II）とを、（ I ）＋（II）
が３０〜６０重量部で、かつ（ I ）／（II）の重量比
が４／１〜１／４となるように配合したことを特徴とす
る塩化ビニル系樹脂組成物。 ▲数式、化学式、表等があります▼ （式中、Ｒは同一または異なっていてもよく、炭素数３
〜１５の長鎖状または分岐状アルキル基、Ａは炭素数２
〜４のアルキレン基、ｍ、ｎは同一または異なっていて
もよく、１〜７の整数、ただし、Ａ＋Ｒの炭素数は５〜
１７である。）(1) A phthalate ester plasticizer (I) represented by the following general formula with respect to 100 parts by weight of vinyl chloride resin,
Phosphate ester plasticizer (II) and (I) + (II)
30 to 60 parts by weight, and the weight ratio of (I)/(II) is 4/1 to 1/4. ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R may be the same or different, and the number of carbon atoms is 3.
~15 long-chain or branched alkyl groups, A having 2 carbon atoms
~4 alkylene groups, m and n may be the same or different, and are integers of 1 to 7, provided that the number of carbon atoms in A+R is 5 to
It is 17. )
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61279332A JPH0826201B2 (en) | 1986-11-22 | 1986-11-22 | Transparent film or sheet made of vinyl chloride resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61279332A JPH0826201B2 (en) | 1986-11-22 | 1986-11-22 | Transparent film or sheet made of vinyl chloride resin composition |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7163114A Division JP2713243B2 (en) | 1995-06-07 | 1995-06-07 | Transparent film or sheet made of vinyl chloride resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63132952A true JPS63132952A (en) | 1988-06-04 |
| JPH0826201B2 JPH0826201B2 (en) | 1996-03-13 |
Family
ID=17609703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61279332A Expired - Fee Related JPH0826201B2 (en) | 1986-11-22 | 1986-11-22 | Transparent film or sheet made of vinyl chloride resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0826201B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5969029A (en) * | 1992-07-29 | 1999-10-19 | Sumitomo Chemical Company, Limited | Process for producing a gas barrier resin composition |
| JP2011225634A (en) * | 2010-04-15 | 2011-11-10 | Adeka Corp | Antistatic agent and thermoplastic resin composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59105037A (en) * | 1982-12-09 | 1984-06-18 | New Japan Chem Co Ltd | Novel plasticizer |
| JPS59133241A (en) * | 1983-01-19 | 1984-07-31 | Dainichi Nippon Cables Ltd | Flame-retarding composition |
| JPS62265338A (en) * | 1986-05-12 | 1987-11-18 | Furukawa Electric Co Ltd:The | Resin composition for antistatic or dust removal use |
-
1986
- 1986-11-22 JP JP61279332A patent/JPH0826201B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59105037A (en) * | 1982-12-09 | 1984-06-18 | New Japan Chem Co Ltd | Novel plasticizer |
| JPS59133241A (en) * | 1983-01-19 | 1984-07-31 | Dainichi Nippon Cables Ltd | Flame-retarding composition |
| JPS62265338A (en) * | 1986-05-12 | 1987-11-18 | Furukawa Electric Co Ltd:The | Resin composition for antistatic or dust removal use |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5969029A (en) * | 1992-07-29 | 1999-10-19 | Sumitomo Chemical Company, Limited | Process for producing a gas barrier resin composition |
| JP2011225634A (en) * | 2010-04-15 | 2011-11-10 | Adeka Corp | Antistatic agent and thermoplastic resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0826201B2 (en) | 1996-03-13 |
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