JPS6312657B2 - - Google Patents

Info

Publication number: JPS6312657B2
Authority: JP; Japan
Prior art keywords: carrier; catalyst; oxyhalogenation; chloride; basic
Prior art date: 1980-11-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP55157626A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5781833A (en

Inventor

Toshuki Takada

Masataka Mori

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Tokuyama Corp

Original Assignee

Tokuyama Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-11-11

Filing date

1980-11-11

Publication date

1988-03-22

1980-11-11 Application filed by Tokuyama Corp filed Critical Tokuyama Corp

1980-11-11 Priority to JP15762680A priority Critical patent/JPS5781833A/ja

1982-05-22 Publication of JPS5781833A publication Critical patent/JPS5781833A/ja

1988-03-22 Publication of JPS6312657B2 publication Critical patent/JPS6312657B2/ja

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 claims description 28
150000001879 copper Chemical class 0.000 claims description 17
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
239000003153 chemical reaction reagent Substances 0.000 claims description 11
238000004519 manufacturing process Methods 0.000 claims description 8
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 4
150000001339 alkali metal compounds Chemical class 0.000 claims description 4
238000000034 method Methods 0.000 claims description 4
239000002243 precursor Substances 0.000 claims description 4
239000005751 Copper oxide Substances 0.000 claims description 3
229910000431 copper oxide Inorganic materials 0.000 claims description 3
238000005979 thermal decomposition reaction Methods 0.000 claims description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
230000002378 acidificating effect Effects 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
239000003795 chemical substances by application Substances 0.000 description 7
230000007423 decrease Effects 0.000 description 7
230000000694 effects Effects 0.000 description 7
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
239000005977 Ethylene Substances 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 6
235000002639 sodium chloride Nutrition 0.000 description 6
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
150000008044 alkali metal hydroxides Chemical class 0.000 description 4
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 4
238000010304 firing Methods 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
238000001354 calcination Methods 0.000 description 3
238000007598 dipping method Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
238000007086 side reaction Methods 0.000 description 3
239000011780 sodium chloride Substances 0.000 description 3
UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
239000002253 acid Substances 0.000 description 2
-1 alkali metal salt Chemical class 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
239000007789 gas Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
239000000017 hydrogel Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
238000007654 immersion Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000004317 sodium nitrate Substances 0.000 description 2
235000010344 sodium nitrate Nutrition 0.000 description 2
KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
229910001948 sodium oxide Inorganic materials 0.000 description 2
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
229910021555 Chromium Chloride Inorganic materials 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910001514 alkali metal chloride Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910001617 alkaline earth metal chloride Inorganic materials 0.000 description 1
239000002610 basifying agent Substances 0.000 description 1
AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000007809 chemical reaction catalyst Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
239000004927 clay Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229940116318 copper carbonate Drugs 0.000 description 1
OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
229960003280 cupric chloride Drugs 0.000 description 1
230000007547 defect Effects 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
229960003750 ethyl chloride Drugs 0.000 description 1
FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
229910001947 lithium oxide Inorganic materials 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
239000000463 material Substances 0.000 description 1
PGSADBUBUOPOJS-UHFFFAOYSA-N neutral red Chemical compound Cl.C1=C(C)C(N)=CC2=NC3=CC(N(C)C)=CC=C3N=C21 PGSADBUBUOPOJS-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
229910001950 potassium oxide Inorganic materials 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000008262 pumice Substances 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
239000004576 sand Substances 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000000243 solution Substances 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
HFFLGKNGCAIQMO-UHFFFAOYSA-N trichloroacetaldehyde Chemical compound ClC(Cl)(Cl)C=O HFFLGKNGCAIQMO-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Landscapes

Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

JP15762680A 1980-11-11 1980-11-11 Catalyst for oxyhalogenation Granted JPS5781833A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP15762680A JPS5781833A (en)	1980-11-11	1980-11-11	Catalyst for oxyhalogenation

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP15762680A JPS5781833A (en)	1980-11-11	1980-11-11	Catalyst for oxyhalogenation

Publications (2)

Publication Number	Publication Date
JPS5781833A JPS5781833A (en)	1982-05-22
JPS6312657B2 true JPS6312657B2 (fr)	1988-03-22

Family

ID=15653835

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP15762680A Granted JPS5781833A (en)	1980-11-11	1980-11-11	Catalyst for oxyhalogenation

Country Status (1)

Country	Link
JP (1)	JPS5781833A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP5084135B2 (ja) *	2005-11-24	2012-11-28	日揮触媒化成株式会社	オキシクロリネーション用触媒およびその製造方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS4995904A (fr) *	1973-01-09	1974-09-11

1980
- 1980-11-11 JP JP15762680A patent/JPS5781833A/ja active Granted

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS4995904A (fr) *	1973-01-09	1974-09-11
JPS5322182A (en) *	1973-01-09	1978-03-01	Ici Ltd	Oxyhalogenation catalysts and manufacture thereof

Also Published As

Publication number	Publication date
JPS5781833A (en)	1982-05-22

Publication	Publication Date	Title
JP2544925B2 (ja)	1996-10-16	銀含有触媒の製造方法
US5063195A (en)	1991-11-05	High efficiency silver catalyst for the production of ethylene oxide via ethylene oxidation
JP4052673B2 (ja)	2008-02-27	エポキシ化触媒および工程
KR100483574B1 (ko)	2005-04-19	산화 에틸렌 제조용 촉매의 담체, 산화 에틸렌 제조용촉매 및 산화 에틸렌의 제조방법
KR20080096678A (ko)	2008-10-31	올레핀 산화 촉매용 담체, 그 제조 방법 및 적용
CA1045145A (fr)	1978-12-26	Synthese de l'oxyde d'ethylene
CZ281977B6 (cs)	1997-04-16	Ethylenoxidový katalyzátor a způsob jeho výroby a použití
JP4638975B2 (ja)	2011-02-23	触媒およびそれを用いたオキシ塩素化法
JPH11507007A (ja)	1999-06-22	触媒担体
KR940000865B1 (ko)	1994-02-03	은-함유 촉매 및 그 제조방법과, 이 촉매에 의해 산화에틸렌을 제조하는 방법
JP2645467B2 (ja)	1997-08-25	オキシ塩素化用触媒
CA1283899C (fr)	1991-05-07	Methode de preparation d'un catalyseur a l'argent
US4728634A (en)	1988-03-01	Ethylene oxide catalyst
JPH0230740B2 (fr)	1990-07-09
JPH05329368A (ja)	1993-12-14	エチレンオキシド製造用銀触媒およびその製造方法
JPH05261286A (ja)	1993-10-12	炭化水素水蒸気改質用触媒及びその製造方法
JP2002535119A (ja)	2002-10-22	ニッケル、ルテニウム及びランタンを担持する触媒担体
JPH0324258B2 (fr)	1991-04-02
JP2548575B2 (ja)	1996-10-30	銀含有触媒の製造法
JPS6312657B2 (fr)	1988-03-22
JPS62216643A (ja)	1987-09-24	成形担持触媒
KR20000035381A (ko)	2000-06-26	에틸렌을 1,2-디클로로에탄으로 전환시키는 옥시-염소화반응용 촉매
JP4726349B2 (ja)	2011-07-20	酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法
JPH05220397A (ja)	1993-08-31	炭化水素水蒸気改質触媒
JP3233652B2 (ja)	2001-11-26	エチレンオキシド製造用銀触媒