JPS63108091A - Aerosol composition - Google Patents
Aerosol compositionInfo
- Publication number
- JPS63108091A JPS63108091A JP25203986A JP25203986A JPS63108091A JP S63108091 A JPS63108091 A JP S63108091A JP 25203986 A JP25203986 A JP 25203986A JP 25203986 A JP25203986 A JP 25203986A JP S63108091 A JPS63108091 A JP S63108091A
- Authority
- JP
- Japan
- Prior art keywords
- feeling
- aerosol composition
- aerosol
- chlorofluorocarbon
- sticky
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 29
- 239000000203 mixture Substances 0.000 title claims description 37
- -1 polyoxyethylene Polymers 0.000 claims abstract description 19
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 17
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 claims abstract description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 4
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 abstract description 4
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 abstract description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 abstract description 4
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 abstract description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 abstract description 2
- 229940032094 squalane Drugs 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000006260 foam Substances 0.000 description 7
- 239000006210 lotion Substances 0.000 description 5
- 238000010008 shearing Methods 0.000 description 5
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- MPDGHEJMBKOTSU-UHFFFAOYSA-N Glycyrrhetinsaeure Natural products C12C(=O)C=C3C4CC(C)(C(O)=O)CCC4(C)CCC3(C)C1(C)CCC1C2(C)CCC(O)C1(C)C MPDGHEJMBKOTSU-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 206010044565 Tremor Diseases 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 229960003720 enoxolone Drugs 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- UQOXSYQRUXKNQH-UHFFFAOYSA-N 1-hexadecoxyhexadecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC UQOXSYQRUXKNQH-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229950004959 sorbitan oleate Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000008733 trauma Effects 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Emergency Medicine (AREA)
- Fats And Perfumes (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
〔技術分野〕
本発明は、圧力を解除するとフオームを形成し、このフ
オームをせん断に服せしめるとパチパチ音を発生するエ
アゾール組成物の改良に関する。DETAILED DESCRIPTION OF THE INVENTION TECHNICAL FIELD The present invention relates to improvements in aerosol compositions that form a foam upon release of pressure and generate a crackling sound when the foam is subjected to shear.
圧力の解除によってフオームを形成しうる加圧組成物は
、エアゾール組成物を混ぜ合わせる分野においてよく知
られており、たとえばひげそり前後のローション、香水
やコローン水、アストリンゼン等の化粧品、防臭剤ある
いは発汗防止剤として広く実用化されている。Pressurized compositions, which can form a foam upon release of pressure, are well known in the field of compounding aerosol compositions, such as pre- and post-shave lotions, perfumes and cologne waters, cosmetics such as Astrinzen, deodorants or antiperspirants. It is widely used as an agent.
また、使用者が手で皮膚上にあるフオームを擦った場合
、パチパチという音を発生し、使用者の肌に刺激を与え
ると共に精神的、心理的な充足感をもたらすように工夫
されたエアゾール組成物も知られている（特公昭４５−
３２０５３号）。In addition, when the user rubs the foam on the skin with their hands, the aerosol composition is designed to produce a crackling sound, stimulating the user's skin and providing a sense of mental and psychological satisfaction. Things are also known (Tokuko 1977-
No. 32053).
このエアゾール組成物は、ポリエチレングリコール、ポ
リプロピレングリコールあるいはこれらの混合物のアル
キルエーテル、アンモニウムアルキル硫酸塩、アルキル
ベンゼンスルフォネート、高級アルコールのアミド等の
水分散性界面活性剤を用いてクロルフルオルカーボンを
乳化したものであって、フオームをせん断に服せしめる
時に、パチパチという音が得られ、高度の販売上の魅力
を有するものであるが、安定な乳濁物を生成することが
難かしく、また使用時において［べたつき感」や「ぬる
つき感」が顕著にみられるため、その使用感が劣るとい
う欠点があった。The aerosol composition emulsifies the chlorofluorocarbon using a water-dispersible surfactant such as an alkyl ether of polyethylene glycol, polypropylene glycol, or a mixture thereof, an ammonium alkyl sulfate, an alkylbenzene sulfonate, or an amide of a higher alcohol. Although they produce a crackling sound when the foam is subjected to shearing and have a high degree of commercial appeal, they are difficult to produce stable emulsions and are difficult to use. It had the disadvantage that the feeling of use was poor because a sticky feeling and a slimy feeling were observed in the product.
本発明は、圧力を解除するとフオームを形成し、このフ
オームをせん断に服せしめるとパチパチ音を発生すると
共にべたつき感やぬるつき感がなく、その使用感に優れ
たエアゾール組成物を提供することを目的とする。An object of the present invention is to provide an aerosol composition that forms a foam when pressure is released, generates a crackling sound when the foam is subjected to shearing, does not have a sticky or slimy feeling, and has an excellent feeling of use. purpose.
本発明によれば、クロルフルオルカーボンを含み、せん
断に服せしめるとパチパチ音を発するエアゾール組成物
において、更にポリオキシエチレンアルキルフェニルエ
ーテルを配合しその使用感を向上したことを特徴とする
エアゾール組成物が提供される。According to the present invention, an aerosol composition containing chlorofluorocarbon and emitting a crackling sound when subjected to shearing is further blended with polyoxyethylene alkyl phenyl ether to improve the feeling of use. things are provided.
本発明のエアゾール組成物は、界面活性剤として、ポリ
オキシエチレンアルキルフェニルエーテルを用いたこと
から、クロルフルオルカーボンの含量を大きくしてもこ
のものを容易に乳濁化できるため、せん断に服せしめる
と快適なパチパチ音を発すると共に使用時における「べ
たつき感」や「ぬるつき感」がなく使用感に優れたもの
である。Since the aerosol composition of the present invention uses polyoxyethylene alkyl phenyl ether as a surfactant, it can be easily emulsified even if the content of chlorofluorocarbon is increased, so it is resistant to shearing. When pressed, it emits a pleasant crackling sound and has an excellent feeling of use, with no "sticky" or "slimy" feeling during use.
更に、本発明においては、前記特定の界面活性剤を含有
させたことにより、シリコーン化合物のように被乳化性
が悪く、その配合が困難とされていた成分も配合するこ
とができるため、更に「べたつき感」や「ぬるつき感」
が解消され、その使用感が一層向」ニしたエアゾール組
成物を得ることもできる。Furthermore, in the present invention, by including the above-mentioned specific surfactant, it is possible to incorporate ingredients such as silicone compounds, which have poor emulsifying properties and are difficult to blend. "sticky feeling" or "slimy feeling"
It is also possible to obtain an aerosol composition in which the above problems are eliminated and the feeling of use is even more improved.
本発明において用いるポリオキシエチレンアルキルフェ
ニルエーテル型界面活性剤は、下記の一般式（１）で示
される。The polyoxyethylene alkylphenyl ether type surfactant used in the present invention is represented by the following general formula (1).
（式中、Ｒは炭素数８〜１２のアルキル基を、ｎは６〜
３０の整数を表わす。）
上記一般式（１）で示されるポリオキシエチレンアルキ
ルフェニルエーテル型界面活性剤の配合量は、組成物全
量に対し１通常０．０１〜２重量％、好ましくはＯ６旧
〜０．０５重量％である。(In the formula, R is an alkyl group having 8 to 12 carbon atoms, and n is 6 to 12 carbon atoms.
Represents an integer of 30. ) The blending amount of the polyoxyethylene alkylphenyl ether type surfactant represented by the above general formula (1) is usually 0.01 to 2% by weight, preferably O6 old to 0.05% by weight based on the total amount of the composition. It is.
その配合量が０．０１重量％未満では十分な安定性を示
すクロルフルオルカーボン乳濁液が得られないため、せ
ん断に服せしめた際に発生する音が悪くなる。またその
配合量が２重量２を超えると、使用時において「べたつ
き感」や「ぬるつき感」が顕著となり、その使用感が悪
化する。If the amount is less than 0.01% by weight, a chlorofluorocarbon emulsion with sufficient stability cannot be obtained, and the noise generated when subjected to shearing becomes worse. If the blending amount exceeds 2 weight 2, "sticky feeling" or "slimy feeling" will become noticeable during use, and the feeling during use will deteriorate.
本発明のエアゾール組成物は、圧力発生成分としてクロ
ルフルオルカーボンを用いる。The aerosol composition of the present invention uses chlorofluorocarbon as a pressure generating component.
クロルフルオルカーボンはこの種のエアゾール組成物に
おいて汎用されているものであり、本発明においては、
２５℃で１〜３ｋｇ／ａ＃（ゲージ圧）を持つものであ
ればいかなる化合物でも使用することができるが、使用
時の音の効果的な発生、取扱いの容易性の面から、ジク
ロルテトラフルオルエタン、あるいはジクロルテトラフ
ルオルエタン、ジクロルジフルオルメタン混合物を用い
ることが好ましい。Chlorfluorocarbon is commonly used in this type of aerosol composition, and in the present invention,
Any compound with a pressure of 1 to 3 kg/a# (gauge pressure) at 25°C can be used, but from the viewpoint of effective sound generation during use and ease of handling, dichlortetra It is preferable to use fluoroethane or a mixture of dichlorotetrafluoroethane and dichlorodifluoromethane.
本発明におけるクロルフルオルカーボンの配合量は、エ
アゾール組成物全量に対し、６０〜９５重量％、好まし
くは８０〜９２重景％で重量。その配合量が６０重−４
＝
量２未満では使用時のパチパチ音が小さくなり、また９
５重量％を超えると、安定な乳濁物が得られなくなる。The amount of chlorofluorocarbon in the present invention is 60 to 95% by weight, preferably 80 to 92% by weight, based on the total amount of the aerosol composition. Its blending amount is 60 weight-4
= If the amount is less than 2, the crackling sound during use will be small, and if the amount is less than 9
If it exceeds 5% by weight, a stable emulsion cannot be obtained.
また、本発明においては、前記必須成分に加え、更にシ
リコーン化合物を配合することにより、使用時における
「べたつき感」や「ぬるつき感」を解消させ、より優れ
た使用感を示すエアゾール組成物を得ることができる。Furthermore, in the present invention, in addition to the above-mentioned essential ingredients, a silicone compound is further blended to eliminate the "sticky feeling" and "slimy feeling" during use, thereby creating an aerosol composition that exhibits a better feeling of use. Obtainable.
このようなシリコーン化合物としては、メチルフェニル
ポリシロキサン、メチルポリシロキサン等の鎖状シロキ
サン、デカメチルシクロペンタンシロキサン、オクタメ
チルシクロテトラシロキサン等の環状シロキサンが挙げ
られるが、効果の発現性からみて環状シロキサンを用い
ることが望ましい。Examples of such silicone compounds include chain siloxanes such as methylphenylpolysiloxane and methylpolysiloxane, and cyclic siloxanes such as decamethylcyclopentanesiloxane and octamethylcyclotetrasiloxane. It is desirable to use
このシリコーン化合物の配合量はエアゾール組成物全量
に対して０゜２〜２重量Ｉ、好ましくは０．４〜１．０
重量％である。The amount of this silicone compound blended is 0.2 to 2 weight I, preferably 0.4 to 1.0, based on the total amount of the aerosol composition.
Weight%.
その配合量が０．２重量％未満であると使用感の向上効
果が小さく、また１重量％を超えると、使用時に発生す
るパチパチ音が低下し、またその感触も悪くなるので好
ましくない。If the amount is less than 0.2% by weight, the effect of improving the feeling of use will be small, and if it exceeds 1% by weight, the crackling sound generated during use will decrease and the feel will be poor, which is not preferable.
本発明のエアゾール組成物には、基剤成分として、常温
で液状あるいは組成物中の他の成分に溶解する物質、例
えばスクワラン、イソプロピルミリステート、エタノー
ル、プロピレングリコール、ワックス等を含有させるこ
とができる。The aerosol composition of the present invention may contain, as a base component, a substance that is liquid at room temperature or dissolves in other components in the composition, such as squalane, isopropyl myristate, ethanol, propylene glycol, and wax. .
また、本発明においては、必要に応じ、通常、この種の
化粧料、医薬品等に用いられている各種添加物、薬効成
分、例えば、殺菌剤、防腐剤、香料、紫外線吸収剤、抗
生物質、抗炎症剤、ビタミン類などを必要に応じ配合す
ることも出来る。In addition, in the present invention, various additives and medicinal ingredients normally used in cosmetics, pharmaceuticals, etc. of this type, such as bactericides, preservatives, fragrances, ultraviolet absorbers, antibiotics, Anti-inflammatory agents, vitamins, etc. can also be added as necessary.
本発明のエアゾール組成物は、界面活性剤としてポリオ
キシエチレンアルキルフェニルエーテルを用いたことか
ら、クロルフルオルカーボンの含量を多くしてもこのも
のを容易に乳濁できるため、せん断に服せしめると快適
なパチパチ音を発すると共に使用時における「べたつき
感」や「ぬるつき感」がなく使用感に優れたものである
。Since the aerosol composition of the present invention uses polyoxyethylene alkyl phenyl ether as a surfactant, it can be easily emulsified even if the content of chlorofluorocarbon is increased. It emits a pleasant crackling sound and has no sticky or slimy feeling during use, giving it an excellent feeling of use.
更に、本発明においては、前記特定の界面活性剤を含有
させたことにより、シリコーン化合物のように被乳化性
が悪く、その配合が困難とされていた成分も配合するこ
とができるため、更に「べたつき感」や「ぬるつき感」
が解消され、その使用感が一層向上したエアゾール組成
物を得ることもできる。Furthermore, in the present invention, by including the above-mentioned specific surfactant, it is possible to incorporate ingredients such as silicone compounds, which have poor emulsifying properties and are difficult to blend. "sticky feeling" or "slimy feeling"
It is also possible to obtain an aerosol composition in which the above problems are eliminated and the usability is further improved.
次に、実施例により本発明を更に詳細に説明する。 Next, the present invention will be explained in more detail with reference to Examples.
実施例１〜７．比較例１〜１４
表−１に示す配合組成のエアゾール組成物を各々調製し
、エアゾール缶（ビン）に入れた。Examples 1-7. Comparative Examples 1 to 14 Aerosol compositions having the formulations shown in Table 1 were prepared and placed in aerosol cans (bottles).
つぎに、各エアゾール組成物の乳濁物の生成能、及びこ
のエアゾール組成物を掌に吐出させ塗布した際のべたつ
き感、ぬるつき感を試験した。その結果を表−１に示す
。Next, the ability of each aerosol composition to form an emulsion and the sticky feeling and slimy feeling when applied by discharging this aerosol composition onto the palm of the hand were tested. The results are shown in Table-1.
なお、試験法及び判定基準は以下によった。The test method and criteria were as follows.
（１）乳濁物の形成能
エアゾール組成物を常温で手により振とうさせ、その振
とう回数でランク付けした。(1) Emulsion forming ability The aerosol compositions were shaken by hand at room temperature and ranked based on the number of times they were shaken.
Ｏ：常温で振どう１００回以内に乳濁物が形成する。O: An emulsion is formed within 100 shakings at room temperature.
ｏ：１１２００回以内
△： ７１５００回以内
Ｘ： ７１５００回以上でも乳濁物が形成しない
。o: 11,200 times or less Δ: 71,500 times or less X: No emulsion was formed even after 71,500 times or more.
（２）べたつき感 エアゾール組成物の塗布後のパネラ−の感触によった。(2) Sticky feeling The test was based on the feel of the panel after application of the aerosol composition.
５：べたつきをほとんど感じない。5: Almost no stickiness felt.
４：べたつきをやや感じる。4: Slightly sticky feeling.
３：べたつきを感じる。3: Feels sticky.
２：べたつきを強く感じる。2: Feels strongly sticky.
１：べたつきを非常に強く感じる。1: Feels very sticky.
（３）ぬるつき感 エアゾール組成物の塗布後のパネラ−の感触によった。(3) Slimy feeling The test was based on the feel of the panel after application of the aerosol composition.
５：ぬるつきをほとんど感じない。5: Almost no feeling of sliminess.
４：ぬるつきをやや感じる。4: Feels slightly slimy.
３：ぬるつきを感じる。3: Feels slimy.
２：ぬるつきを強く感じる。2: I feel a strong sense of sliminess.
１：ぬるつきを非常に強く感じる。1: I feel a very strong feeling of sliminess.
表−１から明らかなように、実施例１のものは、手によ
る振とうにより容易に乳濁物を形成した。As is clear from Table 1, the emulsion of Example 1 was easily formed by manual shaking.
またこの組成物を掌に吐出させ塗布したところ、べたつ
き感、ぬるつき感が少なく良好であった。When this composition was applied by dispensing it onto the palm of the hand, the result was good with little stickiness or slimy feeling.
比較例１〜７は、実施例１の界面活性剤をＰＯＥ（２０
）ＰＯＰ （８）セチルアルコール、ＰＯＥ（８０）硬
化ヒマシ油、ＰＯＥ（５）セチルエーテルリン酸Ｎａ、
ＰＯＥ（６０）ソルビットテトラオレエート、ＰＯＥ
（２０）ソルビタンオレエート、ＰＯＥ（２０）ステア
リン酸及びＰＯＥ（１０）オレイルエーテルに代えたも
のである。In Comparative Examples 1 to 7, the surfactant of Example 1 was mixed with POE (20
) POP (8) Cetyl alcohol, POE (80) Hydrogenated castor oil, POE (5) Sodium cetyl ether phosphate,
POE (60) Sorbittetraoleate, POE
(20) sorbitan oleate, POE (20) stearic acid and POE (10) oleyl ether.
これら比較例の界面活性剤を用いた場合、ジクロルナ１
〜ラフルオルカーボンの乳濁剤は５００回の振とうでは
生成しなかった。When using the surfactants of these comparative examples, dichlorna 1
- No emulsion of fluorocarbon was formed after 500 shakings.
また、実施例２〜７に示すごとく、各種油分添加剤等を
配合した場合も実施例１と同様に良好な乳濁物形成能を
示した６
比較例８〜１４は比較例１〜６で用いた各界面活性剤の
配合量を増量した例であるが、乳濁物生成能が劣り、使
用感も劣ることがわかる。In addition, as shown in Examples 2 to 7, when various oil additives, etc. were blended, good emulsion forming ability was shown as in Example 16. This is an example in which the amount of each surfactant used was increased, but it can be seen that the emulsion-forming ability is inferior and the feeling of use is also inferior.
さらに同一の製造方法で各種添加物を配合した例を実施
例８〜９に示す。Further, Examples 8 and 9 show examples in which various additives were blended using the same manufacturing method.
実施例８ 日焼は肌用ローション
ＰＯＥ（１０）ノニルフェニルエーテル ０．０
５％環状シロキサン ０．５％
エタノール ２．０％グ
リチルレチン酸 ０．０２％紫外線
吸収剤 ０．１％バラヒドロ
キシ安息香酸メチル ０．０１％ビタミンＥ
Ｏ，０２％ジクロルテ
トラフルオルエタン ９０．ＯＯ％香 料
０．０１％精
製 水 バランス得られた組
成物は音が発生し、また吐出物の冷却効果及び優れた使
用感を持った日焼は肌用ローションであった。Example 8 Sunburn skin lotion POE (10) Nonylphenyl ether 0.0
5% cyclic siloxane 0.5%
Ethanol 2.0% Glycyrrhetinic acid 0.02% UV absorber 0.1% Methyl hydroxybenzoate 0.01% Vitamin E
O, 02% dichlorotetrafluoroethane 90. OO% fragrance
0.01% Purified Water Balance The resulting composition was a tanning skin lotion that generated noise and had a cooling effect on the discharge and an excellent feeling of use.
実施例９ 外傷用ローション
ＰＯＥ（１０）ノニルフェニルエーテル ０．０
５％エタノール ０．５
％硫硫酸シラジオマイシン ０．００１５％
グリチルレチン酸 ０．００２％バ
ラヒドロキシ安息香酸メチル ０．０１％ジクロ
ルテトラフルオルエタン ９０．００％精 製
水 バランス上記組成物は外傷
部位に触れることなく有効酸物を塗布することができ、
また吐出物が低温であることにより痛みをやわらげるこ
とができる。さらに使用感が優れることから外傷部以外
に付着した場合も不快感を与えることがない外傷用ロー
ションであった。Example 9 Lotion for trauma POE (10) Nonylphenyl ether 0.0
5% ethanol 0.5
% sulfuric acid siladiomycin 0.0015%
Glycyrrhetinic acid 0.002% Methyl hydroxybenzoate 0.01% Dichlorotetrafluoroethane 90.00% purified
Water balance The above composition allows effective acid to be applied without touching the traumatized area,
Furthermore, the pain can be alleviated by the low temperature of the discharged material. Furthermore, since the lotion has excellent usability, it does not cause discomfort even if it adheres to areas other than the injured area.
Claims (3)
めるとパチパチ音を発するエアゾール組成物において、
更にポリオキシエチレンアルキルフェニルエーテルを配
合しその使用感を向上したことを特徴とするエアゾール
組成物。(1) In an aerosol composition containing chlorofluorocarbon and emitting a crackling sound when subjected to shear,
An aerosol composition characterized in that it further contains polyoxyethylene alkyl phenyl ether to improve its usability.
第１項記載のエアゾール組成物。(2) The aerosol composition according to claim 1, further comprising a silicone compound.
求の範囲第２項記載のエアゾール組成物。(3) The aerosol composition according to claim 2, wherein the silicone compound is a cyclic siloxane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25203986A JPS63108091A (en) | 1986-10-24 | 1986-10-24 | Aerosol composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25203986A JPS63108091A (en) | 1986-10-24 | 1986-10-24 | Aerosol composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63108091A true JPS63108091A (en) | 1988-05-12 |
Family
ID=17231723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25203986A Pending JPS63108091A (en) | 1986-10-24 | 1986-10-24 | Aerosol composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63108091A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991001712A1 (en) * | 1989-07-28 | 1991-02-21 | Hisamitsu Pharmaceutical Co., Inc. | Foamed aerosol preparation |
| EP0414920B1 (en) * | 1989-03-17 | 1997-05-14 | Taisho Pharmaceutical Co. Ltd | Aerosol preparation for external use |
-
1986
- 1986-10-24 JP JP25203986A patent/JPS63108091A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0414920B1 (en) * | 1989-03-17 | 1997-05-14 | Taisho Pharmaceutical Co. Ltd | Aerosol preparation for external use |
| WO1991001712A1 (en) * | 1989-07-28 | 1991-02-21 | Hisamitsu Pharmaceutical Co., Inc. | Foamed aerosol preparation |
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