JPS6292323A - Dry etching method - Google Patents

Dry etching method

Info

Publication number
JPS6292323A
JPS6292323A JP23267585A JP23267585A JPS6292323A JP S6292323 A JPS6292323 A JP S6292323A JP 23267585 A JP23267585 A JP 23267585A JP 23267585 A JP23267585 A JP 23267585A JP S6292323 A JPS6292323 A JP S6292323A
Authority
JP
Japan
Prior art keywords
film
layer
gas
etching
chlorine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP23267585A
Other languages
Japanese (ja)
Inventor
Tadahiko Murata
村田 孔彦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP23267585A priority Critical patent/JPS6292323A/en
Publication of JPS6292323A publication Critical patent/JPS6292323A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To prevent the formation of a horn shape in the re-adhesion of a Pt layer by using a gas for chlorine series as the principal ingredient as an etching gas in the reactive ion etching of the Pt layer. CONSTITUTION:A Ti layer 2 and a Pt layer 3 are shaped onto a substrate 1. An Au film 4 is formed selectively onto the Pt film 3. When the Pt layer 3 is etched selectively by employing the Au film 4, a chlorine group gas is used as the principal ingredient as an etching gas. The chlorine group gas consists of at least one kind of Cl2, Cl4, SiCl4, CCl2F2 and CClF2. Accordingly, the formation of a horn shape in the re-adhesion of the Pt layer 3 is prevented.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、ドライエツチング方法に関し1%にAu層を
マスクとして18層を反応性イオンマツチングするため
のドライマツチング方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a dry etching method, and relates to a dry etching method for reactive ion matching of 18 layers using a 1% Au layer as a mask.

〔従来の技術〕[Conventional technology]

Pt層を加工する場合、従来の技術としては、イオンシ
リング法を用いて、Aukマスクにして加工することが
知られている。
When processing a Pt layer, it is known as a conventional technique to use an ion silling method to process the Pt layer using an Auk mask.

このような従来のPt層の加工方法としてバイポーラト
ランジスタの金電極品種であるT、−P。
As a conventional method for processing such a Pt layer, T and -P, which are gold electrode types of bipolar transistors, are used.

−Au 電極構造を例にとって説明する。まず、第2図
(alのように、基板+11上に11層2、P、63を
形成する。さらにs Au層4を選択的に形成する。
-Au electrode structure will be explained as an example. First, as shown in FIG. 2 (al), 11 layers 2, P, 63 are formed on the substrate +11. Further, an s Au layer 4 is selectively formed.

このAu層4の形成は、蒸着+リフトオフ法、蒸着+エ
ツチング方法、Auメッキ法などを用いて選択的に形成
する。次に第2図(blのようにイオンシリング法を用
いて、Au4t−マスクにして・ Pi3全エツチング
加工する。次に第2図(clのように、Au膜4及びP
、膜3をマスクとして、Ti  膜2を反応性イオンマ
ツチングする。
The Au layer 4 is selectively formed using a vapor deposition+lift-off method, a vapor deposition+etching method, an Au plating method, or the like. Next, as shown in Fig. 2 (bl), using the ion silling method, the entire Pi3 is etched using the Au4T mask.Next, as shown in Fig. 2 (cl), the Au film 4 and P3 are etched.
, Ti film 2 is subjected to reactive ion matching using film 3 as a mask.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

上述した従来のイオンシリング法は、第1表に示すよう
にAu膜(4)のエツチング速度が最もはやい。Ptに
対して約2倍もある。
As shown in Table 1, the above-mentioned conventional ion silling method has the fastest etching rate for the Au film (4). It is about twice that of Pt.

第  1   表 したがって、第2図(blに示すように加工途中に於い
て、除去されたPt膜3がAu膜4の側壁に付着し、さ
らにエツチングレートの差によりPt 付着物5がツノ
のようになってしまい、パリとなり電極間ショート又は
外観不良を誘発する。
Therefore, as shown in FIG. 2 (bl), during processing, the removed Pt film 3 adheres to the side wall of the Au film 4, and furthermore, due to the difference in etching rate, the Pt deposits 5 form like horns. This results in the formation of cracks, which can lead to short circuits between electrodes or poor appearance.

さらvcPtをエツチングする時にAuが2倍マツチン
グされるため、できめがシの札の膜厚を考えて、Auの
膜厚をかなシ厚く形成する必要があシ、コスト、加工精
度に於いても問題となっていた。
Furthermore, since Au is matched twice when etching vcPt, it is necessary to form the Au film quite thickly, considering the film thickness of the textured tag, which reduces cost and processing accuracy. was also a problem.

〔問題点を解決するだめの手段〕[Failure to solve the problem]

本発明の目的は上記欠点を除去し、P−の反応性イオン
マツチングに於いて、再付着の発生しないマスク材のA
、膜がエツチングされにくくできるドライエツチング方
法を提供することでめる。
The purpose of the present invention is to eliminate the above-mentioned drawbacks, and to provide a mask material that does not cause redeposition in P- reactive ion matching.
The present invention provides a dry etching method that makes it difficult for a film to be etched.

本発明によればマツチングガスとして塩累系ガスを主成
分として用い、Au系ガスなどに添加することによシP
t膜を反応性イオンエツチングすることを有している。
According to the present invention, a salt-based gas is used as a matching gas as a main component, and by adding it to Au-based gas, etc., P
t-film by reactive ion etching.

〔実施例〕〔Example〕

次に本発明について、図面を径照して説明する。 Next, the present invention will be explained with reference to the drawings.

第1図は本発明の一実施例の縦断面図である。FIG. 1 is a longitudinal sectional view of an embodiment of the present invention.

まず、第1図(alのように基板1上にTl 2− P
t aを形成する。さらK Au膜4を選択的に形成す
る。
First, Tl 2-P is placed on the substrate 1 as shown in FIG.
Form ta. Furthermore, a K Au film 4 is selectively formed.

このハ膜4の形成に、蒸着+リフトオフ法、蒸着十エツ
チング法、Auメ・ツキ法などケ用いて選択的に形成す
る。
The film 4 is selectively formed using a vapor deposition+lift-off method, a vapor deposition/etching method, an Au plating method, or the like.

次に第1図(blのように、反応性イオンエツチング装
置を用いて、例えばマグ系トロン型反応性イオンエツチ
ング装置を用いて、エツチング室内の一方の電極上に前
記試料を配置し、CC4FgエツチングガスにAuガス
を導入すると共に、各電極間に高周波電圧全印加する。
Next, as shown in FIG. 1 (bl), using a reactive ion etching apparatus, for example, a magtron type reactive ion etching apparatus, the sample was placed on one electrode in the etching chamber, and CC4Fg etching was performed. Au gas is introduced into the gas, and a high frequency voltage is fully applied between each electrode.

この時の6膜のエツチング速度は第2表に示す様に、C
C/、F、にArを添加することによ、9、Au膜のエ
ツチング速度全低下させることができる。さらに本構造
の場合は下地膜としてTi 2膜を用いるため、さらに
02を添加してTiのエツチング速In低下させる。
The etching rates of the six films at this time are as shown in Table 2.
By adding Ar to C/, F, the etching rate of the 9.Au film can be completely reduced. Furthermore, in the case of this structure, since a Ti 2 film is used as the base film, 02 is further added to reduce the etching rate In of Ti.

このようなCCl5F諺+A r十Og  エツチング
ガス勿用いることによシ、第1図1b)に示すように、
Au4’tマスクにしてPt膜3を選択的にエツチング
することができる。
By using no etching gas, as shown in FIG. 1b),
The Pt film 3 can be selectively etched using the Au4't mask.

さらに第1図(C1のようにTi膜(21’t A u
膜(4)+Pt膜(3)ヲマスクにして1反応性イオン
エツチングする。ここで、Pt−Ti’i連続でエツチ
ング室去してもかまわない。
Furthermore, as shown in Figure 1 (C1), a Ti film (21't A u
One reactive ion etching is performed using the film (4)+Pt film (3) as a mask. Here, Pt-Ti'i may be removed from the etching chamber in succession.

=5− 第   2   表 〔発明の効果〕 以上説明したように本発明音用いれは、Au膜をマスク
に用いてPt膜をエツチングする場合。
=5- Table 2 [Effects of the Invention] As explained above, the present invention is used when etching a Pt film using an Au film as a mask.

Au膜がほとんどエツチングされないため、Ptの再付
着によるツノのようになってしまうことがない。さらに
、Au をあらかじめ厚く形成する必要もなくなるため
コスト、加工精度に於いても効果がめる。
Since the Au film is hardly etched, it does not become horn-like due to re-deposition of Pt. Furthermore, since there is no need to form thick Au in advance, costs and processing accuracy can be improved.

【図面の簡単な説明】[Brief explanation of drawings]

第1図(al〜((Jは本発明の一実施例を示す製造工
程の断面図、第2図ta+〜(C1は従来の製造工程の
断面図である。 1・・・・・・基板%2・・・・・・Ti膜、3・・・
・・・Pt膜、4・・・・・・Au膜、5・・・・・・
Pt再付着によ)発生したジノ”。 享71!1
FIG. 1(al~((J is a sectional view of the manufacturing process showing one embodiment of the present invention, FIG. 2 ta+~(C1 is a sectional view of the conventional manufacturing process. 1...Substrate %2...Ti film, 3...
...Pt film, 4...Au film, 5...
"Gino caused by Pt re-deposition".Kyo 71!1

Claims (3)

【特許請求の範囲】[Claims] (1)Pt層を、該層上に形成されたAuマスクパター
ンを用いて選択的にエッチングするドライマッチング方
法に於いて、前記マッチングガスとして、塩素ガスを主
成分として用いたことを特徴とするドライマッチング方
法。
(1) A dry matching method in which a Pt layer is selectively etched using an Au mask pattern formed on the layer, characterized in that chlorine gas is used as the main component as the matching gas. Dry matching method.
(2)前記塩素系ガスを主付とするガスは、Cl_2、
Cl_4、SiCl_4、CCl_2F_2およびCC
lF_3のうち少なくとも1種からなるものであること
を特徴とする特許請求の範囲第1項記載のドライマッチ
ング方法。
(2) The gas mainly composed of chlorine-based gas is Cl_2,
Cl_4, SiCl_4, CCl_2F_2 and CC
The dry matching method according to claim 1, characterized in that the dry matching method comprises at least one type of IF_3.
(3)前記塩素ガスを主体とするガスは、Ar、He、
N_2およびO_2のうち少なくとも1種をさらに添加
ガスとして混合したものであることを特徴とする特許請
求の範囲第2項記載のドライエッチング方法。
(3) The gas mainly composed of chlorine gas includes Ar, He,
3. The dry etching method according to claim 2, wherein at least one of N_2 and O_2 is further mixed as an additive gas.
JP23267585A 1985-10-17 1985-10-17 Dry etching method Pending JPS6292323A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23267585A JPS6292323A (en) 1985-10-17 1985-10-17 Dry etching method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23267585A JPS6292323A (en) 1985-10-17 1985-10-17 Dry etching method

Publications (1)

Publication Number Publication Date
JPS6292323A true JPS6292323A (en) 1987-04-27

Family

ID=16943029

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23267585A Pending JPS6292323A (en) 1985-10-17 1985-10-17 Dry etching method

Country Status (1)

Country Link
JP (1) JPS6292323A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0284734A (en) * 1987-10-27 1990-03-26 Nec Corp Manufacture of semiconductor device
JPH07130712A (en) * 1993-11-02 1995-05-19 Nec Corp Method for etching pt-based alloy
US5426331A (en) * 1993-03-19 1995-06-20 Nec Corporation Semiconductor device with multi-layered heat-resistive electrode in titanium-titanium nitride-plantinum-gold system
US5618754A (en) * 1994-12-22 1997-04-08 Nec Corporation Method of fabricating a semiconductor device having an Au electrode
EP0795896A2 (en) * 1996-03-15 1997-09-17 ROHM Co., Ltd. Dry etching method
US5679213A (en) * 1993-11-08 1997-10-21 Fujitsu Limited Method for patterning a metal film
US5840200A (en) * 1996-01-26 1998-11-24 Matsushita Electronics Corporation Method of manufacturing semiconductor devices
US5976394A (en) * 1996-04-17 1999-11-02 Samsung Electronics Co., Ltd. Method for dry-etching a platinum thin film

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0284734A (en) * 1987-10-27 1990-03-26 Nec Corp Manufacture of semiconductor device
US5426331A (en) * 1993-03-19 1995-06-20 Nec Corporation Semiconductor device with multi-layered heat-resistive electrode in titanium-titanium nitride-plantinum-gold system
JPH07130712A (en) * 1993-11-02 1995-05-19 Nec Corp Method for etching pt-based alloy
US5679213A (en) * 1993-11-08 1997-10-21 Fujitsu Limited Method for patterning a metal film
US5618754A (en) * 1994-12-22 1997-04-08 Nec Corporation Method of fabricating a semiconductor device having an Au electrode
US5840200A (en) * 1996-01-26 1998-11-24 Matsushita Electronics Corporation Method of manufacturing semiconductor devices
EP0795896A2 (en) * 1996-03-15 1997-09-17 ROHM Co., Ltd. Dry etching method
EP0795896A3 (en) * 1996-03-15 1999-06-02 ROHM Co., Ltd. Dry etching method
US5976394A (en) * 1996-04-17 1999-11-02 Samsung Electronics Co., Ltd. Method for dry-etching a platinum thin film

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