JPS628441B2 - - Google Patents

Info

Publication number: JPS628441B2
Authority: JP; Japan
Prior art keywords: polymerization; viscosity; polymer latex; latex; amount
Prior art date: 1978-02-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP53010773A

Other languages

English (en)

Japanese (ja)

Other versions

JPS54103497A (en

Inventor

Shinsuke Yamazaki

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-02-02

Filing date

1978-02-02

Publication date

1987-02-23

1978-02-02 Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology

1978-02-02 Priority to JP1077378A priority Critical patent/JPS54103497A/ja

1979-08-14 Publication of JPS54103497A publication Critical patent/JPS54103497A/ja

1987-02-23 Publication of JPS628441B2 publication Critical patent/JPS628441B2/ja

Status Granted legal-status Critical Current

Links

238000006116 polymerization reaction Methods 0.000 claims description 65
239000004816 latex Substances 0.000 claims description 61
229920000126 latex Polymers 0.000 claims description 61
229920000642 polymer Polymers 0.000 claims description 53
239000000178 monomer Substances 0.000 claims description 22
239000002245 particle Substances 0.000 claims description 21
239000003792 electrolyte Substances 0.000 claims description 14
239000012736 aqueous medium Substances 0.000 claims description 13
239000003638 chemical reducing agent Substances 0.000 claims description 13
-1 sulfoxy compound Chemical class 0.000 claims description 9
239000003945 anionic surfactant Substances 0.000 claims description 8
238000007720 emulsion polymerization reaction Methods 0.000 claims description 7
238000004519 manufacturing process Methods 0.000 claims description 6
238000007717 redox polymerization reaction Methods 0.000 claims description 6
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
230000002209 hydrophobic effect Effects 0.000 claims description 4
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 4
239000003505 polymerization initiator Substances 0.000 claims description 4
229910001428 transition metal ion Inorganic materials 0.000 claims description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
125000005907 alkyl ester group Chemical group 0.000 claims description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
239000011882 ultra-fine particle Substances 0.000 description 14
238000003756 stirring Methods 0.000 description 13
239000003995 emulsifying agent Substances 0.000 description 9
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 8
239000000203 mixture Substances 0.000 description 8
238000002834 transmittance Methods 0.000 description 7
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 6
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 6
235000011114 ammonium hydroxide Nutrition 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
238000000034 method Methods 0.000 description 6
239000012966 redox initiator Substances 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
239000013078 crystal Substances 0.000 description 4
239000001103 potassium chloride Substances 0.000 description 4
235000011164 potassium chloride Nutrition 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
239000005696 Diammonium phosphate Substances 0.000 description 3
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
238000007334 copolymerization reaction Methods 0.000 description 3
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 3
229910000388 diammonium phosphate Inorganic materials 0.000 description 3
235000019838 diammonium phosphate Nutrition 0.000 description 3
239000011521 glass Substances 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
235000019333 sodium laurylsulphate Nutrition 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
238000001246 colloidal dispersion Methods 0.000 description 2
239000002131 composite material Substances 0.000 description 2
229910001431 copper ion Inorganic materials 0.000 description 2
229910000365 copper sulfate Inorganic materials 0.000 description 2
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000009776 industrial production Methods 0.000 description 2
239000012528 membrane Substances 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
238000001139 pH measurement Methods 0.000 description 2
239000012071 phase Substances 0.000 description 2
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
239000000047 product Substances 0.000 description 2
238000010992 reflux Methods 0.000 description 2
239000000344 soap Substances 0.000 description 2
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
235000019345 sodium thiosulphate Nutrition 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
239000002253 acid Substances 0.000 description 1
238000007605 air drying Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
229910001429 cobalt ion Inorganic materials 0.000 description 1
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000001493 electron microscopy Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
150000003840 hydrochlorides Chemical class 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
239000010985 leather Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000002609 medium Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
XCRKXBODIZFDLP-UHFFFAOYSA-N n-ethyl-n-propan-2-ylhydroxylamine Chemical compound CCN(O)C(C)C XCRKXBODIZFDLP-UHFFFAOYSA-N 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
239000005486 organic electrolyte Substances 0.000 description 1
239000003973 paint Substances 0.000 description 1
230000035699 permeability Effects 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000005498 polishing Methods 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000001007 puffing effect Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000011160 research Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
238000005507 spraying Methods 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
UDVJSHMSCJKUAP-UHFFFAOYSA-L trisodium;n-sulfonatosulfamate Chemical compound [Na+].[Na+].[Na+].[O-]S(=O)(=O)NS([O-])(=O)=O UDVJSHMSCJKUAP-UHFFFAOYSA-L 0.000 description 1
238000009423 ventilation Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Landscapes

Polymerisation Methods In General (AREA)
Polymerization Catalysts (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP1077378A 1978-02-02 1978-02-02 Preparation of ultra-fine polymer latex by emulsion polymerization Granted JPS54103497A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP1077378A JPS54103497A (en)	1978-02-02	1978-02-02	Preparation of ultra-fine polymer latex by emulsion polymerization

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP1077378A JPS54103497A (en)	1978-02-02	1978-02-02	Preparation of ultra-fine polymer latex by emulsion polymerization

Publications (2)

Publication Number	Publication Date
JPS54103497A JPS54103497A (en)	1979-08-14
JPS628441B2 true JPS628441B2 (zh)	1987-02-23

Family

ID=11759640

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP1077378A Granted JPS54103497A (en)	1978-02-02	1978-02-02	Preparation of ultra-fine polymer latex by emulsion polymerization

Country Status (1)

Country	Link
JP (1)	JPS54103497A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0368997U (zh) *	1989-10-26	1991-07-08

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS60226509A (ja) *	1984-04-25	1985-11-11	Nippon Carbide Ind Co Ltd	酢ビ系エマルジヨンの製法
US4812510A (en) *	1986-04-17	1989-03-14	The Glidden Company	Small particle size latex based on vinyl acetate polymers
DE4407069A1 (de) *	1994-03-03	1995-09-07	Basf Ag	Formmasse
CN101506251B (zh)	2006-07-05	2012-05-16	索维公司	用于制备一种氯化乙烯基聚合物胶乳的方法
JP6233886B2 (ja) *	2014-08-06	2017-11-22	関西ペイント株式会社	親水性塗料組成物及び熱交換器用アルミニウムフィン材

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5061484A (zh) *	1973-10-03	1975-05-27

1978
- 1978-02-02 JP JP1077378A patent/JPS54103497A/ja active Granted

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5061484A (zh) *	1973-10-03	1975-05-27

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0368997U (zh) *	1989-10-26	1991-07-08

Also Published As

Publication number	Publication date
JPS54103497A (en)	1979-08-14

Publication	Publication Date	Title
US5496882A (en)	1996-03-05	Aqueous polymer dispersion
JP4880853B2 (ja)	2012-02-22	重合可能な化合物及びその用途
IE57180B1 (en)	1992-05-20	Crotonate-containing copolymers,processes for their preparation and their use as thickeners in aqueous systems and as sizing agents
JPS61136502A (ja)	1986-06-24	重合用乳化剤
EP0120265A1 (en)	1984-10-03	High-solid self-adhesive and process for the production thereof
JPH0250923B2 (zh)	1990-11-05
JPS628441B2 (zh)	1987-02-23
EP0784060B1 (en)	2002-04-03	Copolymer latex and process for producing the same
JPS6254806B2 (zh)	1987-11-17
JPS6334196B2 (zh)	1988-07-08
JP3429062B2 (ja)	2003-07-22	紙塗工用共重合体ラテックスの製造方法及び紙塗工用組成物
JP3508171B2 (ja)	2004-03-22	塩化ビニル系樹脂の製造方法
JP3153570B2 (ja)	2001-04-09	共重合体ラテックスの製造方法
JP2001049038A (ja)	2001-02-20	共重合体ラテックスおよび紙塗工用組成物
JPS63175057A (ja)	1988-07-19	塩化ビニル系重合体組成物
JPH0445102A (ja)	1992-02-14	乳化重合体の製造方法及びその製造方法で得られる乳化重合体
JP4228203B2 (ja)	2009-02-25	共重合体ラテックスの製造方法
JPS6011987B2 (ja)	1985-03-29	サチンホワイト水分散液の製造方法
JPS6157439B2 (zh)	1986-12-06
JP3417583B2 (ja)	2003-06-16	高酸価アクリル樹脂の製造方法
JPH02184332A (ja)	1990-07-18	分散剤
JPS6353202B2 (zh)	1988-10-21
JPS60203603A (ja)	1985-10-15	高濃度乳化重合体の製造方法
JPH10139801A (ja)	1998-05-26	塩化ビニルの重合方法
JPH024714B2 (zh)	1990-01-30

JPS628441B2 - - Google Patents

Info

Links

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=11759640

Family Applications (1)

Country Status (1)

Cited By (1)

Families Citing this family (5)

Citations (1)

Patent Citations (1)

Cited By (1)

Also Published As

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