JPS628092B2 - - Google Patents
Info
- Publication number
- JPS628092B2 JPS628092B2 JP55126714A JP12671480A JPS628092B2 JP S628092 B2 JPS628092 B2 JP S628092B2 JP 55126714 A JP55126714 A JP 55126714A JP 12671480 A JP12671480 A JP 12671480A JP S628092 B2 JPS628092 B2 JP S628092B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- weight
- general formula
- alkyl
- ammonium salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- -1 Polyoxyethylene glyceryl monopyroglutamate monoisostearate Polymers 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 239000002537 cosmetic Substances 0.000 claims description 12
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 125000005526 alkyl sulfate group Chemical group 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 6
- 239000003676 hair preparation Substances 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 150000003863 ammonium salts Chemical class 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 235000013772 propylene glycol Nutrition 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- LAIUFBWHERIJIH-UHFFFAOYSA-N 3-Methylheptane Chemical compound CCCCC(C)CC LAIUFBWHERIJIH-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- 206010044625 Trichorrhexis Diseases 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- FFULXQXOVCEBGZ-LVDJIYQJSA-N 2,3-dihydroxypropyl (2S)-5-oxopyrrolidine-2-carboxylate 16-methylheptadecanoic acid Chemical compound OCC(O)COC(=O)[C@@H]1CCC(=O)N1.CC(C)CCCCCCCCCCCCCCC(O)=O FFULXQXOVCEBGZ-LVDJIYQJSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- IEJVXCHYRORLNC-UHFFFAOYSA-M di(docosyl)-diethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](CC)(CC)CCCCCCCCCCCCCCCCCCCCCC IEJVXCHYRORLNC-UHFFFAOYSA-M 0.000 description 1
- QBGCXIWJBVFOFO-UHFFFAOYSA-M di(docosyl)-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCCCCCC QBGCXIWJBVFOFO-UHFFFAOYSA-M 0.000 description 1
- VKKVMDHHSINGTJ-UHFFFAOYSA-M di(docosyl)-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCCCCCC VKKVMDHHSINGTJ-UHFFFAOYSA-M 0.000 description 1
- SUJJVADBDGTKJX-UHFFFAOYSA-M di(docosyl)-dimethylazanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCCCCCC SUJJVADBDGTKJX-UHFFFAOYSA-M 0.000 description 1
- OCTAKUVKMMLTHX-UHFFFAOYSA-M di(icosyl)-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCCCC OCTAKUVKMMLTHX-UHFFFAOYSA-M 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- MUDOAHDTTYJSHX-UHFFFAOYSA-M docosyl-icosyl-dimethylazanium chloride Chemical compound [Cl-].C[N+](CCCCCCCCCCCCCCCCCCCCCC)(CCCCCCCCCCCCCCCCCCCC)C MUDOAHDTTYJSHX-UHFFFAOYSA-M 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、毛髪に対し光沢およびなめらかさを
付与する上で優れた効果を有する毛髪化粧料に関
する。
通常、毛髪は、ヘアークリームやヘアーオイル
等の動植物油および毛髪自身から分泌される皮脂
等により覆われているが、石鹸や合成洗剤等で洗
髪すると、それらの油脂成分は必要以上に除去さ
れてしまう。そのため洗髪後の毛髪はなめらかさ
が失なわれ、パサパサした硬い感触となり、櫛通
りが悪くなつて裂毛や枝毛が生じ易くなつてしま
う。
このような不都合を解消するため、洗髪後の毛
髪処理剤として各種の毛髪化粧料が開発され、使
用されている。これら毛髪化粧料は、ジアルキル
ジメチルアンモニウムクロライドやアルキルトリ
メチルアンモニウムクロライドに代表される第４
級アンモニウム塩を主要有効成分とするものであ
る。このようなアンモニウム塩には水難溶性のも
のと水易溶性のものとがあり、従つてそれに対応
して、毛髪化粧料には「すすぐタイプ」のものと
「すすがないタイプ」のものとがあつて、それぞ
れその使用形態を異ならしめている。
洗髪後等の毛髪のキシミやもつれを防ぎ、乾い
た状態の仕上り感をよくするためには、上記アン
モニウム塩が毛髪に吸着されていなければならな
い。しかし、従来の毛髪化粧料は、どの使用形態
によつても上記アンモニウム塩の離脱性や吸着性
にも問題があり、充分満足すべきものではなかつ
た。特に、毛髪の光沢およびなめらかさにおいて
未だ不充分であつた。
また、従来、繊維柔軟剤等の各種繊維処理剤が
知られているが、繊維特に動物性繊維は、その化
学的構造において毛髪と類似であるものの、物理
的構造において毛髪とは全く異なつているため、
そのような繊維処理剤の毛髪への適用は困難であ
る。
本発明は、上記事情の下になされたものであつ
て、すすぐタイプおよびすすがないタイプのいず
れのタイプに適用しても優れた光沢およびなめら
かさを毛髪に付与し得る性能を発揮する毛髪化粧
料を提供することを目的とする。
即ち、本発明の毛髪化粧料は、下記一般式
（）で表わされる第４級アンモニウム塩0.1ない
し３重量％と、下記一般式（）で表わされる第
４級アンモニウム塩0.1ないし３重量％と、下記
一般式（）で表わされる化合物0.1〜5.0重量％
とを必須成分として含有し、かつ（）／（）
の重量比は1/3ないし3/1であることを特徴とす
る。
一般式（）：
（式中、R1およびR2は炭素数16〜18のアルキ
ル基、R3およびR4は炭素数１〜３のアルキル基
又はヒドロキシアルキル基、Ｘはハロゲン原子又
はアルキル基の炭素数が１又は２のアルキル硫酸
基を示す。）
一般式（）：
（式中、R5およびR6は炭素数20〜22のアルキ
ル基、R7およびR8は炭素数１〜３のアルキル基
又はヒドロキシアルキル基、Ｘはハロゲン原子又
はアルキル基の炭素数が１又は２のアルキル硫酸
基を示す。）
一般式（）：
（ポリオキシエチレングリセリールモノピログ
ルタメートモノイソステアレート）
以下、本発明の毛髪化粧料について更に詳細に
説明する。
本発明の毛髪化粧料の第１の必須成分は、下記
の一般式（）で表わされるジ−Ｃ16-18アルキル
基第４級アンモニウム塩である。
一般式（）：
（式中、R1およびR2は炭素数16〜18のアルキ
ル基、R3およびR4は炭素数１〜３のアルキル基
又はヒドロキシアルキル基、Ｘはハロゲン原子又
はアルキル基の炭素数が１又は２のアルキル硫酸
基を示す。）
第１の必須成分の配合量は、毛髪化粧料全体に
対し0.1ないし3.0重量％、好ましくは0.1ないし
2.0重量％である。0.1重量％未満では本発明の効
果は発揮されず、3.0重量％を越えると毛髪のべ
たつきが増して櫛通り性が劣る。
第１の必須成分の代表例として以下の物質があ
る。
ジパルミチル・ジメチルアンモニウムクロリ
ド、ジステアリル・ジメチルアンモニウムクロリ
ド、ジ−水素添加牛脂アルキル・ジメチルアンモ
ニウムクロリド、ジ−水素添加牛脂アルキル・ジ
メチルアンモニウムブロミド、ジ−水素添加牛脂
アルキル・ジエチルアンモニウムメチルサルフエ
ート。
本発明の毛髪化粧料の第２の必須成分は、以下
の一般式（）で表わされるジ−Ｃ20-22アルキル
第４級アンモニウム塩である。
一般式（）：
（式中、R5およびR6は炭素数20〜22のアルキ
ル基、R7およびR8は炭素数１〜３のアルキル基
又はヒドロキシアルキル基、Ｘはハロゲン原子又
はアルキル基の炭素数が１又は２のアルキル硫酸
基を示す。）
第２の必須成分の配合量は、毛髪化粧料全体に
対し0.1ないし3.0重量％、好ましくは0.1ないし
2.0重量％である。0.1重量％未満では本発明の効
果は発揮されず、3.0重量％を越えると毛髪のべ
たつきが増加し、好ましくない。
第２の必須成分の代表例として以下の物質があ
る。
ジエイコシル・ジメチルアンモニウムクロリ
ド、ジヘンエイコシル・ジメチルアンモニウムク
ロリド、ジドコシル・ジメチルアンモニウムクロ
リド、ジドコシル・ジメチルアンモニウムブロミ
ド、ジドコシル・ジエチルアンモニウムクロリ
ド、ジドコシル・ジメチルアンモニウムメチルサ
ルフエート、ドコシル・エイコシル・ジメチルア
ンモニウムクロリド。
これらの物質は、ナタネ油を原料として、公知
の製造法により得られる。具体的には、ナタネ油
を原料として製造した脂肪酸を蒸留、精製したの
ち、脱水触媒下でアンモニアと反応させてニトリ
ルを合成し、このニトリルを水添触媒下で還元し
てジアルキル二級アミンを製造し、更にこれに塩
化メチルと苛性ソーダ液を加えて４級化すること
により得られる。
本発明の毛髪化粧品においては、上述の一般式
（）の第４級アンモニウム塩と一般式（）の
第４級アンモニウム塩との重量比（）／（）
が1/3〜3/1の範囲にある必要がある。特に好まし
くは、（）／（）＝1/2.5〜2.5/1である。
（）／（）が3/1を越えると毛髪の“しつとり
感”が低下するので好ましくない。1/3未満であ
ると毛髪の“なめらかさ”および“しつとり感”
共に低下するので好ましくない。
本発明の毛髪化粧料においては、上述の第１お
よび第２の必須成分に対し、更に下記の一般式
（）に示す化合物（ポリエキシエチレングリセ
リールモノピログルタメートモノイソステアレー
ト）が第３の必須成分として加えられる。
一般式（）：
第３の必須成分の配合量は、毛髪化粧料全体に
対し0.1〜5.0重量％、好ましくは0.1〜3.0重量％
である。0.1重量％未満では本発明の効果である
毛髪の光沢およびなめらかさが得られず、5.0重
量％を越えると、べたつきが増し好ましくない。
また、第３の必須成分は、一般式（）におけ
るａ＋ｂ＋ｃが20〜25のものであり、この範囲外
のものでは本発明の効果を得ることができない。
本発明の毛髪化粧料中は、他の任意成分を本発
明の効果に影響のない範囲で配合することが可能
である。そのような任意成分として以下の物質が
ある。
流動パラフイン、ワセリン、固形パラフイン、
スクワランおよびオレフインオリゴマー等の炭化
水素；イソプロピルミリステート、イソプロピル
パルミテート、ステアリルステアレート、ミリス
チン酸オクチルドデシル、オレイン酸オクチルド
デシルおよび２−エチルヘキサントリグリセライ
ド等のエステル；セタノール、ステアリルアルコ
ール、ベヘニルアルコールおよびヘキシルデカノ
ール等の高級アルコール；グリセリルモノステア
レート、ソルビタンモノパルミテート、ポリオキ
シエチレンセチルエーテル、ポリオキシエチレン
ステアリン酸エステルおよびポリオキシエチレン
ソルビタンモノラウレート等の乳化剤；メチルセ
ルロース、ヒドロキシエチルスルロース、ヒドロ
キシプロピルセルロースおよびカチオン化セルロ
ース等のセルロース誘導体；天然高分子類等の増
粘剤；エチレングリコール、プロピレングリコー
ル、１，３−ブチレングリコール、グリセリンお
よびソルビトール等の保湿剤；およびその他溶
剤、殺菌剤、香料等の少量成分である。
本発明の毛髪化粧料は、ヘアーリンス剤、スプ
レー型又はデイスペンサー型のヘアコンデイシヨ
ナー、ヘアーローシヨン等の各種用途に利用する
ことができる。
次に、本発明の実施例と比較例を示し、本発明
の効果をより具体的に説明する。なお、各例の説
明に先立つて、試験法について説明する。
なめらかさ
シヤンプー処理された毛束（５ｇ、20cm）に試
料0.5ｇを直接塗布し、手で均一に伸ばしたのち
25℃、65％RHの雰囲気で乾燥させ、一昼夜放置
後の毛束の「なめらかさ」について20名のパネラ
ーにより官能評価する。
評価基準は1.0重量％のステアリルトリメチル
アンモニウムクロライド、３重量％のセチルアル
コール、10重量％のプロピレングリコール、およ
び水（残部）からなる試料（比較例１）により得
た評価を基準とした５段階評価である。
◎：良い 〇：やや良い △：同等 ×：やや
劣る ××：劣る
光 沢
シヤンプー処理された毛束（５ｇ、20cm）に試
料0.5ｇを直接塗布し、手で均一に伸ばしたのち
25℃、65％RHの雰囲気で乾燥させ、一昼夜放置
後の毛束の光沢（つや）について20名のパネラー
により視覚評価する。
光沢の評価基準は1.0重量％のステアリルトリ
メチルアンモニウムクロライド、３重量％のセチ
ルアルコール、10重量％のプロピレングリコー
ル、および水（残部）からなる試料（比較例１）
により得た評価を基準とした５段階評価である。
◎：良い 〇：やや良い △：同等 ×：やや
劣る ××：劣る
試験例 １
種々の第４級アンモニウム塩および／または本
発明の第３の必須成分（化合物）を含む19種の
毛髪化粧料を調整し、それらの毛髪に対する性能
（光沢およびなめらかさ）を試験した。その結果
を表１に示す。なお、配合量は重量％である（他
の試験例でも同様）。
TECHNICAL FIELD The present invention relates to hair cosmetics that have excellent effects in imparting luster and smoothness to hair. Normally, hair is covered with animal and vegetable oils such as hair creams and hair oils, as well as sebum secreted from the hair itself, but when hair is washed with soap or synthetic detergents, these oils and fats are removed more than necessary. Put it away. As a result, the hair after washing loses its smoothness, feels dry and stiff, and becomes difficult to comb, making it more likely to cause split ends and split ends. In order to eliminate such inconveniences, various hair cosmetics have been developed and used as hair treatment agents after hair washing. These hair cosmetics contain quaternary compounds such as dialkyldimethylammonium chloride and alkyltrimethylammonium chloride.
The main active ingredient is grade ammonium salt. There are two types of ammonium salts: those that are poorly soluble in water and those that are easily soluble in water.Therefore, correspondingly, there are two types of hair cosmetics: ``rinse type'' and ``non-rinse type.'' However, each type of use is different. In order to prevent hair from squeaking and tangling after washing, etc., and to improve the finish when dry, the above ammonium salt must be adsorbed to the hair. However, conventional hair cosmetics have problems in the releasability and adsorption of the ammonium salt, regardless of the form of use, and are not fully satisfactory. In particular, the gloss and smoothness of the hair were still insufficient. In addition, various fiber treatment agents such as fiber softeners have been known, but although fibers, especially animal fibers, have a chemical structure similar to that of hair, their physical structure is completely different from that of hair. For,
Application of such fiber treatment agents to hair is difficult. The present invention has been made under the above circumstances, and the present invention is a hair cosmetic that exhibits the performance of imparting excellent luster and smoothness to hair when applied to both rinsing type and non-rinsing type. The purpose is to provide fees. That is, the hair cosmetic of the present invention contains 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (), 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (), 0.1 to 5.0% by weight of a compound represented by the following general formula ()
Contains as an essential component, and ()/()
The weight ratio of is 1/3 to 3/1. General formula (): (In the formula, R 1 and R 2 are alkyl groups having 16 to 18 carbon atoms, R 3 and R 4 are alkyl groups having 1 to 3 carbon atoms or hydroxyalkyl groups, and X is a halogen atom or an alkyl group having 1 carbon number. or 2 alkyl sulfate group.) General formula (): (In the formula, R 5 and R 6 are alkyl groups with 20 to 22 carbon atoms, R 7 and R 8 are alkyl groups with 1 to 3 carbon atoms or hydroxyalkyl groups, and X is a halogen atom or an alkyl group with 1 carbon number. or 2 alkyl sulfate group.) General formula (): (Polyoxyethylene glyceryl monopyroglutamate monoisostearate) Hereinafter, the hair cosmetic of the present invention will be explained in more detail. The first essential component of the hair cosmetic of the present invention is a di-C 16-18 alkyl group quaternary ammonium salt represented by the following general formula (). General formula (): (In the formula, R 1 and R 2 are alkyl groups having 16 to 18 carbon atoms, R 3 and R 4 are alkyl groups having 1 to 3 carbon atoms or hydroxyalkyl groups, and X is a halogen atom or an alkyl group having 1 carbon number. (or 2 alkyl sulfate group)) The amount of the first essential component is 0.1 to 3.0% by weight, preferably 0.1 to 3.0% by weight based on the total hair cosmetic.
It is 2.0% by weight. If it is less than 0.1% by weight, the effect of the present invention will not be exhibited, and if it exceeds 3.0% by weight, the hair will become sticky and the combability will be poor. The following substances are representative examples of the first essential component. Dipalmityl dimethylammonium chloride, distearyl dimethylammonium chloride, di-hydrogenated tallow alkyl dimethylammonium chloride, di-hydrogenated tallow alkyl dimethylammonium bromide, di-hydrogenated tallow alkyl diethylammonium methyl sulfate. The second essential component of the hair cosmetic of the present invention is a di-C 20-22 alkyl quaternary ammonium salt represented by the following general formula (). General formula (): (In the formula, R 5 and R 6 are alkyl groups with 20 to 22 carbon atoms, R 7 and R 8 are alkyl groups with 1 to 3 carbon atoms or hydroxyalkyl groups, and X is a halogen atom or an alkyl group with 1 carbon number. (or 2 alkyl sulfate group)) The amount of the second essential component is 0.1 to 3.0% by weight, preferably 0.1 to 3.0% by weight, based on the total hair cosmetic.
It is 2.0% by weight. If it is less than 0.1% by weight, the effect of the present invention will not be exhibited, and if it exceeds 3.0% by weight, the hair will become sticky, which is not preferable. Representative examples of the second essential component include the following substances. Dieicosyl dimethylammonium chloride, diheneicosyl dimethylammonium chloride, didocosyl dimethylammonium chloride, didocosyl dimethylammonium bromide, didocosyl diethylammonium chloride, didocosyl dimethylammonium methylsulfate, docosyl eicosyl dimethylammonium chloride. These substances are obtained by known production methods using rapeseed oil as a raw material. Specifically, fatty acids produced using rapeseed oil as a raw material are distilled and purified, then reacted with ammonia under a dehydration catalyst to synthesize nitriles, and this nitrile is reduced under a hydrogenation catalyst to form dialkyl secondary amines. It is obtained by quaternizing the product by adding methyl chloride and a caustic soda solution thereto. In the hair cosmetics of the present invention, the weight ratio ()/() of the quaternary ammonium salt of the above-mentioned general formula () to the quaternary ammonium salt of the general formula () is
must be in the range of 1/3 to 3/1. Particularly preferably, ()/()=1/2.5 to 2.5/1.
If ()/() exceeds 3/1, the "moisture feeling" of the hair will decrease, which is not preferable. If it is less than 1/3, the “smoothness” and “moisture” of the hair will be reduced.
This is not preferable because both decrease. In the hair cosmetic of the present invention, in addition to the above-mentioned first and second essential ingredients, a compound represented by the following general formula () (polyexyethylene glyceryl monopyroglutamate monoisostearate) is added as a third essential ingredient. Added as an essential ingredient. General formula (): The amount of the third essential ingredient is 0.1 to 5.0% by weight, preferably 0.1 to 3.0% by weight based on the entire hair cosmetic.
It is. If it is less than 0.1% by weight, the luster and smoothness of the hair, which are the effects of the present invention, cannot be achieved, and if it exceeds 5.0% by weight, it becomes undesirably sticky. Further, the third essential component has a+b+c in the general formula () of 20 to 25, and if it is outside this range, the effects of the present invention cannot be obtained. In the hair cosmetic of the present invention, other optional ingredients can be incorporated within a range that does not affect the effects of the present invention. Such optional ingredients include the following substances. liquid paraffin, vaseline, solid paraffin,
Hydrocarbons such as squalane and olefin oligomers; esters such as isopropyl myristate, isopropyl palmitate, stearyl stearate, octyldodecyl myristate, octyldodecyl oleate and 2-ethylhexane triglyceride; Higher alcohols; emulsifiers such as glyceryl monostearate, sorbitan monopalmitate, polyoxyethylene cetyl ether, polyoxyethylene stearate and polyoxyethylene sorbitan monolaurate; methyl cellulose, hydroxyethyl sululose, hydroxypropyl cellulose and cationization Cellulose derivatives such as cellulose; thickeners such as natural polymers; humectants such as ethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin and sorbitol; and other small amounts of ingredients such as solvents, disinfectants, and fragrances. be. The hair cosmetic composition of the present invention can be used in various applications such as a hair rinse, a spray-type or dispenser-type hair conditioner, and a hair lotion. Next, Examples and Comparative Examples of the present invention will be shown to explain the effects of the present invention more specifically. Before explaining each example, the test method will be explained. Smoothness: Apply 0.5g of the sample directly to a shampooed hair bundle (5g, 20cm) and spread it evenly by hand.
After drying in an atmosphere of 25°C and 65% RH and leaving it for a day and night, 20 panelists sensory-evaluated the "smoothness" of the hair strands. The evaluation criteria is a 5-level evaluation based on the evaluation obtained with a sample (Comparative Example 1) consisting of 1.0% by weight stearyltrimethylammonium chloride, 3% by weight cetyl alcohol, 10% by weight propylene glycol, and water (balance). It is. ◎: Good 〇: Slightly good △: Equal ×: Slightly inferior ××: Inferior gloss Apply 0.5g of the sample directly to a shampooed hair bundle (5g, 20cm) and spread it evenly by hand.
After drying in an atmosphere of 25°C and 65% RH, the gloss of the hair strands after being left overnight was visually evaluated by 20 panelists. The evaluation criteria for gloss was a sample consisting of 1.0% by weight stearyltrimethylammonium chloride, 3% by weight cetyl alcohol, 10% by weight propylene glycol, and water (balance) (Comparative Example 1)
This is a 5-level evaluation based on the evaluation obtained by. ◎: Good 〇: Slightly good △: Equal ×: Slightly inferior ××: Inferior Test example 1 19 types of hair cosmetics containing various quaternary ammonium salts and/or the third essential ingredient (compound) of the present invention were prepared and tested for their performance on hair (shininess and smoothness). The results are shown in Table 1. In addition, the blending amount is weight % (the same applies to other test examples).
【表】【table】
【表】
表１から明らかなように、ジ−Ｃ16-18アルキル
第４級アンモニウム塩、ジ−Ｃ20-22アルキル第４
級アンモニウム塩および化合物（）の組合せ
（実施例１）以外の配合物（比較例１〜18）は、
光沢およびなめらかさが不充分であることがわか
る。
試験例 ２
ジ−Ｃ16-18アルキル第４級アンモニウム塩とジ
−Ｃ20-22アルキル第４級アンモニウム塩との重量
比を変えた７種の毛髪化粧料を調整し、それらの
毛髪に対する性能について試験した。その結果を
以下の表２に示す。[Table] As is clear from Table 1, di-C 16-18 alkyl quaternary ammonium salt, di-C 20-22 alkyl quaternary ammonium salt,
The formulations (Comparative Examples 1 to 18) other than the combination of class ammonium salt and compound () (Example 1) are:
It can be seen that the gloss and smoothness are insufficient. Test Example 2 Seven types of hair cosmetics with different weight ratios of di-C 16-18 alkyl quaternary ammonium salt and di-C 20-22 alkyl quaternary ammonium salt were prepared, and their performance on hair was evaluated. was tested. The results are shown in Table 2 below.
【表】
表２から明らかなように、ジ−Ｃ16-18アルキル
第４級アンモニウム塩とジ−Ｃ20-22アルキル第４
級アンモニウム塩との重量比が1/3ないし3/1のと
きにいずれも優れた光沢およびなめらかさの性能
を示すことがわかる。
試験例 ３
ジ−Ｃ16-18アルキル第４級アンモニウム塩、ジ
−Ｃ20-22アルキル第４級アンモニウム塩および第
３の必須成分の種類および量を変えた10種の毛髪
化粧料を調整し、それらの毛髪に対する性能につ
いて試験した。その結果を以下の表３に示す。[Table] As is clear from Table 2, di-C 16-18 alkyl quaternary ammonium salt and di-C 20-22 alkyl quaternary ammonium salt
It can be seen that when the weight ratio with the grade ammonium salt is 1/3 to 3/1, both exhibit excellent gloss and smoothness performance. Test Example 3 Ten types of hair cosmetics were prepared in which the type and amount of di-C 16-18 alkyl quaternary ammonium salt, di-C 20-22 alkyl quaternary ammonium salt, and the third essential ingredient were changed. , tested for their performance on hair. The results are shown in Table 3 below.
【表】【table】
【表】
表３から明らかなように、本発明の各必須成分
の量および種類を本発明の範囲内で変化させた毛
髪化粧料はいずれも優れた性能を示すことがわか
る。
試験例 ４
下記の表４に示す配合組成の２種のヘアーリン
ス組成物を製造し、その性能を評価した。性能評
価は、40℃のヘアーリンス組成物の２％希釈液
200mlに毛束（8.5ｇ、20cm）を５秒間浸漬し、40
℃の温水200mlで30秒間づつ２回すすいで乾燥し
た後のものについて行なつた。[Table] As is clear from Table 3, all the hair cosmetics in which the amounts and types of each essential ingredient of the present invention are varied within the range of the present invention exhibit excellent performance. Test Example 4 Two types of hair rinse compositions having the formulations shown in Table 4 below were manufactured and their performance was evaluated. Performance evaluation was performed using a 2% diluted solution of hair rinse composition at 40°C.
Soak a bundle of hair (8.5g, 20cm) in 200ml for 5 seconds,
The samples were rinsed twice with 200 ml of warm water at ℃ for 30 seconds each time and dried.
【表】【table】
【表】
表４から明らかなように、本発明のヘアーリン
ス組成物は、従来のものよりも優れた光沢および
なめらかさの性能を有していることがわかる。
試験例 ５
下記の表５に示す配合、組成のヘアークリーム
組成物を製造し、その性能を評価した。[Table] As is clear from Table 4, the hair rinse composition of the present invention has better gloss and smoothness performance than conventional ones. Test Example 5 A hair cream composition having the formulation and composition shown in Table 5 below was manufactured and its performance was evaluated.
【表】【table】
【表】
本発明のヘアークリーム組成物は、従来のヘア
ークリームにない優れた光沢およびなめらかさの
性能を有していた。[Table] The hair cream composition of the present invention had excellent gloss and smoothness performance not found in conventional hair creams.
Claims (1)
ニウム塩0.1ないし３重量％と、下記一般式
（）で表わされる第４級アンモニウム塩0.1ない
し３重量％と、下記一般式（）で表わされる化
合物0.1ないし5.0重量％とを必須成分として含有
し、かつ（）／（）の重量比は1/3ないし3/1
であることを特徴とする毛髪化粧料。 一般式（）： （式中、R1およびR2は炭素数16〜18のアルキ
ル基、R3およびR4は炭素数１〜３のアルキル基
又はヒドロキシアルキル基、Ｘはハロゲン原子又
はアルキル基の炭素数が１又は２のアルキル硫酸
基を示す。） 一般式（）： （式中、R5およびR6は炭素数20〜22のアルキ
ル基、R7およびR8は炭素数１〜３のアルキル基
又はヒドロキシアルキル基、Ｘはハロゲン原子又
はアルキル基の炭素数が１又は２のアルキル硫酸
基を示す。） 一般式（）： （ポリオキシエチレングリセリールモノピログ
ルタメートモノイソステアレート）[Scope of Claims] 1 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (); 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (); and 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (); Contains 0.1 to 5.0% by weight of the compound represented by () as an essential component, and the weight ratio of ()/() is 1/3 to 3/1.
A hair cosmetic characterized by: General formula (): (In the formula, R 1 and R 2 are alkyl groups having 16 to 18 carbon atoms, R 3 and R 4 are alkyl groups having 1 to 3 carbon atoms or hydroxyalkyl groups, and X is a halogen atom or an alkyl group having 1 carbon number. or 2 alkyl sulfate group.) General formula (): (In the formula, R 5 and R 6 are alkyl groups with 20 to 22 carbon atoms, R 7 and R 8 are alkyl groups with 1 to 3 carbon atoms or hydroxyalkyl groups, and X is a halogen atom or an alkyl group with 1 carbon number. or 2 alkyl sulfate group.) General formula (): (Polyoxyethylene glyceryl monopyroglutamate monoisostearate)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12671480A JPS5750827A (en) | 1980-09-12 | 1980-09-12 | Hair cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12671480A JPS5750827A (en) | 1980-09-12 | 1980-09-12 | Hair cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5750827A JPS5750827A (en) | 1982-03-25 |
| JPS628092B2 true JPS628092B2 (en) | 1987-02-20 |
Family
ID=14942038
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12671480A Granted JPS5750827A (en) | 1980-09-12 | 1980-09-12 | Hair cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5750827A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0613450B2 (en) * | 1990-05-31 | 1994-02-23 | サンスター株式会社 | Cosmetics for hair |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4831900A (en) * | 1971-02-12 | 1973-04-26 | ||
| US4144326A (en) * | 1975-05-19 | 1979-03-13 | American Cyanamid Company | Oil free, water-soluble, clear creme rinse for hair |
| JPS55108811A (en) * | 1979-02-10 | 1980-08-21 | Lion Corp | Hair-treating composition |
-
1980
- 1980-09-12 JP JP12671480A patent/JPS5750827A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4831900A (en) * | 1971-02-12 | 1973-04-26 | ||
| US4144326A (en) * | 1975-05-19 | 1979-03-13 | American Cyanamid Company | Oil free, water-soluble, clear creme rinse for hair |
| JPS55108811A (en) * | 1979-02-10 | 1980-08-21 | Lion Corp | Hair-treating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5750827A (en) | 1982-03-25 |
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