JPS6240368A - Continuous treatment installation for decreasing iron loss of grain oriented silicon steel sheet - Google Patents

Continuous treatment installation for decreasing iron loss of grain oriented silicon steel sheet

Info

Publication number
JPS6240368A
JPS6240368A JP60176819A JP17681985A JPS6240368A JP S6240368 A JPS6240368 A JP S6240368A JP 60176819 A JP60176819 A JP 60176819A JP 17681985 A JP17681985 A JP 17681985A JP S6240368 A JPS6240368 A JP S6240368A
Authority
JP
Japan
Prior art keywords
treatment
steel sheet
tank
silicon steel
oriented silicon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP60176819A
Other languages
Japanese (ja)
Other versions
JPH0248622B2 (en
Inventor
Masao Iguchi
征夫 井口
Ujihiro Nishiike
西池 氏裕
Yasuhiro Kobayashi
康宏 小林
Kazuhiro Suzuki
一弘 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP60176819A priority Critical patent/JPS6240368A/en
Publication of JPS6240368A publication Critical patent/JPS6240368A/en
Publication of JPH0248622B2 publication Critical patent/JPH0248622B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE:To efficiently form a tensile film and decrease iron loss by subjecting a grain oriented silicon steel sheet to polishing to a specular surface then to a cleaning treatment of sheet surfaces, preliminary heating treatment and ion bombardment treatment then subjecting the sheet to an ion plating treatment. CONSTITUTION:The grain oriented silicon steel sheet coil 1 subjected to the final pickling stage is passed through a treatment tank array 2 for electrolytic polishing and is polished to the specular surface by a pickling tank 3, a cleaning tank 4, electrolytic cells 5, 6, a cleaning tank 7 and a drying tank 8. The sheet surfaces are then cleaned by an ultrasonic cleaning installation 18 and is passed through preliminary evacuation vessels 11, 11', 11'' in which the pressures are regulated and segments to the degree of vacuum gradually higher toward a high vacuum treatment vessel 10 to assure the vacuum sealing of the vessel 10. The steel sheet surfaces are further preheated to about 200-500 deg.C or ion-bombarded with Ar ions, etc. in a preheating and/or ion bombardment treatment installation 19, by which the steel sheet surfaces are further cleaned. The steel sheet is passed through the vessel 10 and is subjected to the ion plating treatment by evaporating sources 15 and ionizing electrodes 16 disposed in two steps, upper and lower, by which the tensile thin film is formed on the steel sheet surface.

Description

【発明の詳細な説明】 (産業上の利用分野) 一方向性けい素鋼板は、一般に熱間圧延と冷間圧延を経
た冷延薄板の2次再結晶粒を、(100)〔001,1
方位、(すなわちゴス方位)に高度に集積させて所望の
磁気的性質を具備させ、主に変圧器その他の電気機器類
の鉄心に使用され、ここに磁束密度(B、O値で代表さ
れる)が高くしかも鉄損(W+715G値で代表される
)の低いことが要求されるが、これまでの研究努力によ
り当今は、板厚0.3+nmでB、、:1.90T以上
、W +qyso  : 1.05W/kg以下また、
板厚0.23mmではB、。: 1.89 T以上、W
 IT/So  : 0.901’l/kg以下のよう
な超低鉄損一方向性けい素鋼板も製造され得るようにな
った。
Detailed Description of the Invention (Field of Industrial Application) Unidirectional silicon steel sheets generally have secondary recrystallized grains of cold-rolled thin sheets that have undergone hot rolling and cold rolling.
It is highly concentrated in the direction (i.e., the Goss direction) to provide desired magnetic properties, and is mainly used in the iron cores of transformers and other electrical equipment. ) and low iron loss (represented by W + 715G value), but due to past research efforts, it is now possible to achieve B, .: 1.90 T or more, W + qyso: 1.05W/kg or less,
B for plate thickness 0.23mm. : 1.89 T or more, W
IT/So: Unidirectional silicon steel sheets with ultra-low core loss of 0.901'l/kg or less can now be manufactured.

しかるに省エネの見地で電力損失のより厳しい低減要求
は、とくに欧米にて鉄損の減少分を換価して変圧器価格
に上積みする、ロスエバリユエーション(鉄損評価)制
度にまで発展し、それも定着するに至っている。
However, from the perspective of energy conservation, demands for more stringent reductions in power loss have led to the development of loss evaluation systems, particularly in Europe and the United States, in which the reduction in iron loss is converted into cash and added to the transformer price. It has also become established.

このようにか酷な要請に応えるため発明者らは、一方向
性けい素鋼板の特性改善それも極限的な鉄損低減を1指
して研究活動を続けて来たが、方向性けい素鋼板の最終
焼鈍、つまり仕上焼鈍後の操作、とくに被膜処理につい
ての革新的な手法を試み、顕著な鉄損低減の成果を得、
引続く検討と研讃を加えて、以下に述べる一方向性けい
素鋼板の鉄損低減連続処理設備の適合を解明した。
In order to meet such severe demands, the inventors have continued their research activities with the aim of improving the properties of grain-oriented silicon steel sheets and also reducing iron loss to the utmost. We tried an innovative method for the final annealing, that is, the operation after the final annealing, especially the coating treatment, and achieved remarkable results in reducing iron loss.
Through subsequent studies and research, we have clarified the suitability of the continuous treatment equipment for reducing iron loss for unidirectional silicon steel sheets described below.

(従来の技術) 特開昭57−2252号、同57−53419号、同5
8−26405号及び同58−26405号各公報には
、仕上焼鈍後の一方向性けい素鋼板の表面に、圧延方向
とほぼ直角な向きにレーザ照射を施すことによって局部
的微小ひずみの導入による磁区細分化をもって、鉄損の
低減を図ることが開示されているが、この場合、いわゆ
るひずみ取り焼鈍を加えない使途では有効であっても、
該焼鈍が施されたときは折角導入された局部微小ひずみ
が加熱保持中に解放され、磁区幅が拡大してレーザ照射
による効果が喪失してしまう不利がある。
(Prior art) JP-A-57-2252, JP-A-57-53419, JP-A-5
No. 8-26405 and No. 58-26405 disclose that the surface of a unidirectional silicon steel sheet after finish annealing is irradiated with a laser in a direction substantially perpendicular to the rolling direction to introduce local minute strain. It has been disclosed that magnetic domain refining is used to reduce iron loss, but in this case, even if it is effective in applications where so-called strain relief annealing is not added,
When this annealing is performed, there is a disadvantage that the local minute strain that has been painstakingly introduced is released during heating and holding, the magnetic domain width expands, and the effect of laser irradiation is lost.

これに対して発明者らはさきに、上記のような高温処理
にも拘らず特性劣化を伴うことない超低鉄損一方向性け
い素鋼板の製造に成功した。
On the other hand, the inventors have previously succeeded in manufacturing an ultra-low iron loss unidirectional silicon steel sheet that does not suffer from characteristic deterioration despite the above-mentioned high-temperature treatment.

すなわち方向性けい素鋼板の常法に従う最終焼鈍工程を
経て鋼板の外面に生成した酸化物を除去した後、表裏両
面に研磨処理を施して鏡面状態にし、ついでイオンプレ
ーティングよりTi、 Zr、 V、 Nb。
That is, after removing the oxides generated on the outer surface of the steel plate through a final annealing process according to the conventional method for grain-oriented silicon steel sheets, both the front and back surfaces are polished to a mirror-like state, and then Ti, Zr, and V are coated by ion plating. , Nb.

Ta、 Cr、 Mo、 W、 Mn、 Co、 N 
i、 A β、B及びslの窒化物及び又は炭化物なら
びに A R,Ni、 Cu、 W、 Si及びZnの酸化物
のうちから選んだ少なくとも1種からなる極薄張力被膜
を形成させることである。
Ta, Cr, Mo, W, Mn, Co, N
i, A β, B, and sl nitrides and/or carbides, and AR, Ni, Cu, W, Si, and Zn oxides. .

(発明が解決しようとする問題点) 上記の成功を導いた実験的成果を基盤として1、工業的
規模における、その有利な適合を成就すべき、一方向性
けい素鋼板の鉄損低減連続処理設備を与えることがこの
発明の目的である。
(Problems to be solved by the invention) Based on the experimental results that led to the above-mentioned success, 1. Continuous iron loss reduction treatment of grain-oriented silicon steel sheets to achieve its advantageous suitability on an industrial scale. It is an object of this invention to provide a facility.

(問題点を解決するための手段) この発明は方向性けい素鋼板の常法に従う最終焼鈍工程
を経た鋼板の表裏両面の鏡面化処理に供する電解研磨用
処理槽列と、この電解研磨により鏡面化した鋼板の表裏
両面の連続的なイオンプレーティング処理に供する、2
組の蒸発源及びイオン化電極を有する高真空処理槽及び
この高真空処理槽の入側にて、上記鋼板を洗浄し、つい
で予熱する、超音波洗浄槽と予備加熱及び/又はイオン
ホンバード処理設備とをそなえることを特徴とする一方
向性けい素鋼板の鉄損低減連続処理設備である。
(Means for Solving the Problems) The present invention provides an array of electrolytic polishing baths for mirror-finishing both the front and back surfaces of a steel plate that has undergone a final annealing process according to a conventional method for grain-oriented silicon steel sheets, and a mirror-finishing treatment by this electrolytic polishing. 2. Subjecting both the front and back surfaces of the steel plate to continuous ion plating treatment.
A high vacuum treatment tank having a set of evaporation sources and ionization electrodes, and an ultrasonic cleaning tank and preheating and/or ion hombar treatment equipment for cleaning and then preheating the steel plate on the inlet side of the high vacuum treatment tank. This is a continuous processing facility for reducing iron loss for unidirectional silicon steel sheets, which is characterized by the following:

さて第1図に最終焼鈍を経た方向性けい素鋼板の表裏両
面上の酸化物を除去した後の鏡面研磨処理と、ひきつづ
くイオンプレーティング処理とを行う連続処理設備を模
式図をもって示す。
Now, FIG. 1 shows a schematic diagram of a continuous treatment facility that performs a mirror polishing treatment after removing oxides on both the front and back surfaces of a grain-oriented silicon steel sheet that has undergone final annealing, followed by an ion plating treatment.

図中1は外面上の酸化物を除去した後の方向性けい素鋼
板コイル、2は以下の各槽を含む電解研磨用処理槽列で
、3は酸洗槽、4は洗浄槽、5はNo、 1電解槽、6
はNo、 2電解槽、7は洗浄槽そして8は乾燥槽であ
り、9は電解研磨処理槽列2の入側と出側に設けたルー
パーである。
In the figure, 1 is a grain-oriented silicon steel sheet coil after removing oxides on the outer surface, 2 is an electrolytic polishing tank array including the following tanks, 3 is a pickling tank, 4 is a cleaning tank, and 5 is a cleaning tank. No. 1 electrolytic cell, 6
2 is an electrolytic tank, 7 is a cleaning tank, 8 is a drying tank, and 9 is a looper provided at the entrance and exit sides of the electropolishing tank row 2.

また10は高真空処理槽、11. ll’、 11’は
高真空処理槽10の入側に配列した予備排気槽列、12
は高真空排気系統、13はガス導入口、そして14゜1
4’、 14’は高真空処理槽10の出側に配列した予
備排気槽列であり、15は高真空処理槽10内で上下2
段に配設し、た蒸発源、16は各蒸発源15に対設した
イオン化電極をあられし、17は通板用ガイドロール群
を示す。さらに、18.19は、入側の予備排気槽列1
1.11’、11”を挟んで配列した超音波洗浄設備と
、予熱用イオンボンバード処理設備、そして20はイオ
ンプレーティング処理を経て巻取ったコイルを示し、な
お9′は高真空処理槽10の入側と出側に設けたルーバ
ーである。
Further, 10 is a high vacuum processing tank, 11. ll', 11' are preliminary exhaust tank rows arranged on the inlet side of the high vacuum processing tank 10;
is the high vacuum exhaust system, 13 is the gas inlet, and 14゜1
4' and 14' are preliminary evacuation tank rows arranged on the outlet side of the high vacuum processing tank 10, and 15 is a row of two upper and lower tanks in the high vacuum processing tank 10.
The evaporation sources 16 are arranged in stages, and the reference numeral 16 indicates an ionization electrode placed opposite to each evaporation source 15. The reference numeral 17 indicates a group of guide rolls for sheet passing. Furthermore, 18.19 is the pre-exhaust tank row 1 on the inlet side.
1.11', 11'' are arranged on both sides of the ultrasonic cleaning equipment, the ion bombardment treatment equipment for preheating, and 20 shows the coil wound up through the ion plating process, and 9' shows the high vacuum treatment tank 10. This is a louver installed on the entrance and exit sides.

なお図中21は、通板経路の要所に配置したシャーであ
る。
In addition, 21 in the figure is a shear arranged at important points on the sheet passing route.

第2図に超音波洗浄設備18の詳細を図解したように、
超音波槽(A)、(D)、リンス槽(B) 、([E)
、脱水槽(C)、蒸気槽(F)及び乾燥槽(G)の7つ
の槽よりなりこれによって鏡面化処理鋼板の表面をとく
にきれいに、浄化することにより板面との密着性改善に
役立てる。
As the details of the ultrasonic cleaning equipment 18 are illustrated in FIG.
Ultrasonic bath (A), (D), rinse bath (B), ([E)
It consists of seven tanks: a dehydration tank (C), a steam tank (F), and a drying tank (G), and these are used to particularly clean and purify the surface of the mirror-finished steel plate, thereby helping to improve its adhesion to the plate surface.

予熱用イオンボンバード処理設備20は、エレクトロン
ビームの如き予備加熱設備でもよいがそれに加えエレク
トロンビームによりArまたはH2イオンを鋼板表面上
にボンバードメントすることが有効である。
The preheating ion bombardment treatment equipment 20 may be a preheating equipment such as an electron beam, but in addition, it is effective to bombard Ar or H2 ions onto the surface of the steel plate using an electron beam.

(作  用) 鋼板表裏面に対する電解研磨処理およびそれにひきつづ
くイオンプレーティング処理は次の順序で行われる。
(Function) The electrolytic polishing treatment and the subsequent ion plating treatment on the front and back surfaces of the steel plate are performed in the following order.

最終焼鈍を経て巻取った一方向性けい素鋼板のコイル1
は電解研磨用処理槽列2の入側ルーパー9を通して、ま
ず酸洗槽3に導いて、鋼板の表面酸化物を除去し、次に
洗浄槽4に通して清浄化した後No、 1およびNo、
 2の電解槽5,6により電解研磨を施して鋼板表面を
鏡面状態に仕上げ、ついで、洗浄槽7で表面を洗浄し、
再び乾燥槽8を通して乾燥させる。
Coil 1 of unidirectional silicon steel plate wound after final annealing
No. 1 and No. 1 are passed through the inlet looper 9 of the electropolishing treatment tank row 2, first led to the pickling tank 3 to remove surface oxides on the steel plate, and then passed through the cleaning tank 4 for cleaning. ,
Electrolytic polishing is performed in the electrolytic baths 5 and 6 of No. 2 to finish the surface of the steel plate to a mirror finish, and then the surface is cleaned in the cleaning bath 7.
It is dried by passing it through the drying tank 8 again.

次に鋼板は電解研磨用処理槽列2の出側のルーパー9、
さらに高真空処理槽10の入側ルーパー9′を通し高真
空処理槽10へ導入するがこのとき、超音波洗浄設備1
8により板面を清浄にしてから高真空処理槽10の入側
でこの処理槽10に向けて漸次に高真空度に調圧区分し
た予備排気槽11.11’及び11〃を通して高真空処
理槽10の真空封止を確保する。ついで予備加熱及び/
又はイオンボンバード処理設備20において鋼板表面を
200〜500℃に予備加熱するか又はさらにAr又は
H2イオンボンバードにより鋼板表面をさらに清浄化し
てから、高真空処理槽10の内部で通板ガイドロール群
17により形成される迂曲した通板経路に沿って連続的
に通板して、該槽内で上、下2段に配設した蒸発源15
、イオン化電極16に沿う通板移動中に、イオンプレー
ティング処理を施す。
Next, the steel plate is placed in the looper 9 on the exit side of the electrolytic polishing treatment tank row 2.
Furthermore, the ultrasonic cleaning equipment 1 is introduced into the high vacuum processing tank 10 through the inlet looper 9' of the high vacuum processing tank 10.
After cleaning the plate surface by step 8, the high vacuum processing tank 10 is passed through preliminary exhaust tanks 11, 11' and 11, which are gradually pressure-regulated to a high degree of vacuum toward the processing tank 10 on the inlet side of the high vacuum processing tank 10. Ensure 10 vacuum seals. Then preheating and/or
Alternatively, the surface of the steel plate is preheated to 200 to 500°C in the ion bombardment treatment equipment 20, or the surface of the steel plate is further cleaned by Ar or H2 ion bombardment, and then the plate passing guide roll group 17 is heated inside the high vacuum treatment tank 10. The evaporation sources 15 are arranged in two stages, upper and lower, in the tank by continuously passing the plates along the curved passage path formed by the
, the ion plating process is performed while the plate is moving along the ionization electrode 16.

イオンプレーティング処理は蒸発源15中で溶酸金属の
蒸発を生じさせつつガス導入口13から微量のガスを導
入しこのガス雰囲気中でイオン化電極16を通してはじ
めに掲げた窒化物及び/又は炭化物並び酸化物からなる
張力薄膜の鋼板表面への被着を連続的に行う。
In the ion plating process, a trace amount of gas is introduced from the gas inlet 13 while evaporating the molten metal in the evaporation source 15, and in this gas atmosphere, the nitrides and/or carbides and oxidation mentioned above are passed through the ionization electrode 16. A tensile thin film made of a material is continuously applied to the surface of a steel plate.

この場合第1図から明らかなように鋼板表裏両面に対し
て薄膜コーティング処理を行い得る。
In this case, as is clear from FIG. 1, thin film coating can be applied to both the front and back surfaces of the steel plate.

蒸発源15として役立たせるための金属の溶解には図示
を略したが、電子ビーム、ホーローカンード、電極加熱
装置など従来公知のいずれの装置を用いてもよく、また
短時間に有効に被膜形成させるため通板中の鋼板面直下
に磁界をかけてイオンを加速させるマグネトロン装置を
使用しても良い。
Although not shown in the figure, any conventionally known device such as an electron beam, a hollow cand, or an electrode heating device may be used to melt the metal to serve as the evaporation source 15, and in order to effectively form a film in a short time. A magnetron device may be used that accelerates ions by applying a magnetic field just below the surface of the steel sheet being passed.

上記のようにして通板中の連続的なイオンプレーティン
グ処理を施した鋼板は高真空処理槽10の出側でやはり
この処理槽に近い程高真空度に調圧区分した予備排気槽
列14,14’及び14’を経由する差動排気システム
の採用により順次真空度を低くして大気中に導出し、ル
ーパー9′を通じてコイル18に巻取られる。
The steel sheet subjected to the continuous ion plating treatment during sheet passing as described above is placed on the exit side of the high vacuum treatment tank 10, and the pressure is regulated to be high nearer to this treatment tank in the pre-evacuation tank row 14. , 14' and 14' by employing a differential pumping system, the degree of vacuum is successively lowered and the air is drawn out into the atmosphere, and then wound into a coil 18 through a looper 9'.

(発明の効果) 一方向性けい素鋼板の鏡面研摩処理後に、超音波洗浄、
予備加熱及び/又はイオンボンバードメントを含めたイ
オンプレーティング処理が単一ラインで連続的に、とく
に鏡面研磨処理とその後の入念な洗浄に引続くイオンプ
レーティング処理が、表面の鏡面化の良好な表面性状で
劣化を来す前に、いち早く行なわれ得るので鋼板表面の
張力被膜が効果的に被着形成され、その密着性が際立っ
てすぐれることも相まって鉄損を効果的に低下させるこ
とができる。
(Effect of the invention) After mirror polishing of the unidirectional silicon steel plate, ultrasonic cleaning,
The ion plating process, including preheating and/or ion bombardment, can be performed continuously in a single line, especially the ion plating process followed by the mirror polishing process and subsequent careful cleaning, to achieve a good mirror finish on the surface. Since this process can be carried out quickly before the surface quality deteriorates, a tension film can be effectively formed on the surface of the steel sheet, and the adhesion of the film is extremely good, which together with the fact that iron loss can be effectively reduced. can.

なおこの装置は低炭素冷延鋼板や、ステンレス鋼板など
の一般鋼板についての鏡面研磨処理・セラミックコーテ
ィング処理の連続ラインにも利用可能である。
This equipment can also be used in a continuous line for mirror polishing and ceramic coating of general steel sheets such as low-carbon cold-rolled steel sheets and stainless steel sheets.

(実施例) 一方向性けい素鋼板(0,23mm厚)の仕上焼鈍機酸
洗により鋼板表面上の酸化物を除去して巻取ったコイル
(約8トン〉を第1図に示した連続処理設備に通しライ
ンスピード4Qm /minにて鋼板の表裏両面に0.
8μm厚のTiN張力被膜を形成させた。製品の磁気特
性は次のようであった。
(Example) A coil (approximately 8 tons) of a unidirectional silicon steel plate (0.23 mm thick) that was wound up after removing oxides on the surface of the steel plate by pickling in a finish annealing machine is shown in Figure 1. 0.0.
An 8 μm thick TiN tension coating was formed. The magnetic properties of the product were as follows.

B+o=1.92T  、 W+7/So =0.66
W/kg
B+o=1.92T, W+7/So=0.66
W/kg

【図面の簡単な説明】[Brief explanation of drawings]

第1図はこの発明による一方向性けい素鋼板の鉄損低減
連続処理設備の模式図、 第2図は超音波洗浄槽の詳細図である。 2・・・電解研磨用処理槽列
FIG. 1 is a schematic diagram of a continuous treatment facility for iron loss reduction of unidirectional silicon steel sheets according to the present invention, and FIG. 2 is a detailed diagram of an ultrasonic cleaning tank. 2... Processing tank row for electrolytic polishing

Claims (1)

【特許請求の範囲】 1、方向性けい素鋼板の常法に従う最終焼鈍工程を経た
鋼板の表裏両面の鏡面化処理に供する電解研磨用処理槽
列と、 この電解研磨により鏡面化した鋼板の表裏両面の連続的
なイオンプレーティング処理に供する、2組の蒸発源及
びイオン化電極を有する高真空処理槽及び この高真空処理槽の入側にて、上記鋼板を洗浄し、つい
で予熱する、超音波洗浄槽と予備加熱及び/又はイオン
ボンバード処理設備と をそなえることを特徴とする一方向性けい素鋼板の鉄損
低減連続処理設備。
[Scope of Claims] 1. An array of electrolytic polishing baths for mirror-finishing both the front and back surfaces of a steel plate that has undergone a final annealing process according to a conventional method for grain-oriented silicon steel sheets, and a front and back surface of the steel plate that has been mirror-finished by this electropolishing. A high vacuum treatment tank with two sets of evaporation sources and ionization electrodes is used for continuous ion plating treatment on both sides, and an ultrasonic wave is used at the entrance side of the high vacuum treatment tank to clean and then preheat the steel plate. A continuous treatment facility for reducing iron loss for unidirectional silicon steel sheets, characterized by being equipped with a cleaning tank and preheating and/or ion bombardment treatment facilities.
JP60176819A 1985-08-13 1985-08-13 Continuous treatment installation for decreasing iron loss of grain oriented silicon steel sheet Granted JPS6240368A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60176819A JPS6240368A (en) 1985-08-13 1985-08-13 Continuous treatment installation for decreasing iron loss of grain oriented silicon steel sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60176819A JPS6240368A (en) 1985-08-13 1985-08-13 Continuous treatment installation for decreasing iron loss of grain oriented silicon steel sheet

Publications (2)

Publication Number Publication Date
JPS6240368A true JPS6240368A (en) 1987-02-21
JPH0248622B2 JPH0248622B2 (en) 1990-10-25

Family

ID=16020397

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60176819A Granted JPS6240368A (en) 1985-08-13 1985-08-13 Continuous treatment installation for decreasing iron loss of grain oriented silicon steel sheet

Country Status (1)

Country Link
JP (1) JPS6240368A (en)

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JPH08144041A (en) * 1994-11-17 1996-06-04 Toppan Printing Co Ltd Winding-type vacuum deposition device
JPH0967664A (en) * 1995-08-28 1997-03-11 Ishikawajima Harima Heavy Ind Co Ltd Preheating method for steel sheet in continuous vacuum vapor deposition device and device therefor
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JPH08144041A (en) * 1994-11-17 1996-06-04 Toppan Printing Co Ltd Winding-type vacuum deposition device
JPH0967664A (en) * 1995-08-28 1997-03-11 Ishikawajima Harima Heavy Ind Co Ltd Preheating method for steel sheet in continuous vacuum vapor deposition device and device therefor
US7736749B2 (en) 2000-03-31 2010-06-15 Hitachi Chemichal Co., Ltd. Thermosetting resin composition, resin film, metallic foil provided with an insulation material, insulation film provided with a metallic foil on each side, metal-clad laminate, multi-layered metal-clad laminate, and multi-layered printed wiring board
JP2007092985A (en) * 2005-08-30 2007-04-12 Nissan Motor Co Ltd Piston ring structural body
WO2019188976A1 (en) 2018-03-30 2019-10-03 Jfeスチール株式会社 Method for producing grain-oriented electrical steel sheet and continuous film-forming device
WO2019188683A1 (en) 2018-03-30 2019-10-03 Jfeスチール株式会社 Surface treatment facility
WO2019188410A1 (en) 2018-03-30 2019-10-03 Jfeスチール株式会社 Equipment for manufacturing grain-oriented electromagnetic steel sheet
WO2019189122A1 (en) 2018-03-30 2019-10-03 Jfeスチール株式会社 Target exchanging device and surface treatment facility
JPWO2019188976A1 (en) * 2018-03-30 2020-04-30 Jfeスチール株式会社 Method for producing grain-oriented electrical steel sheet and continuous film forming apparatus
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KR20200118870A (en) 2018-03-30 2020-10-16 제이에프이 스틸 가부시키가이샤 Target exchange device and surface treatment facility
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