JPS6237186A - Printing by ink jet printer and ink therefor - Google Patents
Printing by ink jet printer and ink thereforInfo
- Publication number
- JPS6237186A JPS6237186A JP60177403A JP17740385A JPS6237186A JP S6237186 A JPS6237186 A JP S6237186A JP 60177403 A JP60177403 A JP 60177403A JP 17740385 A JP17740385 A JP 17740385A JP S6237186 A JPS6237186 A JP S6237186A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- printing
- foaming agent
- foams
- transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004088 foaming agent Substances 0.000 claims abstract description 20
- 239000006260 foam Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 abstract description 5
- 239000007788 liquid Substances 0.000 abstract description 5
- 238000001035 drying Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 238000011282 treatment Methods 0.000 abstract description 3
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000001788 irregular Effects 0.000 abstract 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- 239000000049 pigment Substances 0.000 description 8
- 238000005187 foaming Methods 0.000 description 6
- 239000003086 colorant Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- MWRWFPQBGSZWNV-UHFFFAOYSA-N Dinitrosopentamethylenetetramine Chemical compound C1N2CN(N=O)CN1CN(N=O)C2 MWRWFPQBGSZWNV-UHFFFAOYSA-N 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- -1 nitrile compounds Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 125000005147 toluenesulfonyl group Chemical group C=1(C(=CC=CC1)S(=O)(=O)*)C 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0081—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0023—Digital printing methods characterised by the inks used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0064—Digital printing on surfaces other than ordinary paper on plastics, horn, rubber, or other organic polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0082—Digital printing on bodies of particular shapes
- B41M5/0088—Digital printing on bodies of particular shapes by ink-jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/16—Braille printing
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Electromagnetism (AREA)
- Thermal Sciences (AREA)
- Duplication Or Marking (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、インクジェットプリンタによる印刷方法及び
該印刷方法に用いられるインクに関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a printing method using an inkjet printer and an ink used in the printing method.
［従来の技術］
従来、インクジェットプリンタによる印刷で白色を得る
には、インク中に白色の顔料を含有させたインクを使用
した。これは、白色の着色剤としては顔料しか存在しな
いためである。[Prior Art] Conventionally, to obtain a white color by printing with an inkjet printer, an ink containing a white pigment has been used. This is because pigment is the only white coloring agent present.
［発明が解決しようとする問題点］
しかるに、この顔料は微細粒子でおるので、インクジェ
ットプリンタにおいて下記の問題点を有していた。[Problems to be Solved by the Invention] However, since this pigment is made up of fine particles, it has had the following problems in inkjet printers.
まず第一に、インクジェットプリンタにおけるインク噴
射ノズルの径は６０〜２００μφであり、粒子である顔
料が通過する際に目づまりを発生させる危険のあること
及び顔料によるインク粒の不均一噴射を生じやすい等の
ため、白色インクによる安定したインクジェットプリン
タ印刷が困難であった。First of all, the diameter of the ink jet nozzle in an inkjet printer is 60 to 200 μΦ, and there is a risk of clogging when pigment particles pass through, and the pigment tends to cause uneven jetting of ink droplets. Therefore, it has been difficult to perform stable printing with an inkjet printer using white ink.
第二に、インクがストックタンクの中におるとき粒子で
ある顔料が沈殿してインクの成分の不均一を来たし、顔
料の分散状態による粘度の変化がノズルより噴射される
インク粒の不均一を生じ印刷品質を悪くした。Second, when the ink is in the stock tank, the pigment particles precipitate, causing non-uniformity of the ink components, and changes in viscosity due to the dispersion state of the pigment cause non-uniformity of the ink particles ejected from the nozzle. This resulted in poor print quality.
これらは総て白色を得る着色剤が顔料のみしか存在しな
いために生じるものであり、インクジェットプリンタに
よる白色印刷の実用化を困ｌｉｔなものとしていた。All of these are caused by the fact that the only coloring agent that produces white color is pigment, making it difficult to put white printing using an inkjet printer into practical use.
本発明の目的は従来技術の欠点を解消し、インクジェッ
トプリンタにおいて目づまりによる不安定作業をなくし
、良好な白色印刷を得るインクジェットプリンタによる
印刷方法及びそのインクを提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a printing method using an inkjet printer that eliminates the drawbacks of the prior art, eliminates unstable work due to clogging in an inkjet printer, and provides good white printing, and an ink for the same.
［問題点を解決するための手段］
本発明の要旨はインフジエラ１〜プリンタ用インクとし
てインク内に発泡剤を含有させたものを用いたことにあ
る。即ち、第一の発明は、インクに適応し、且つ紫外線
又は熱により発泡する発泡剤を含有させたインクを用い
て、所定の印刷対象物に対してジェットプリントし、そ
の複核発泡剤を発泡させることを特徴とするインクジェ
ットプリンタによる印刷方法であり、特に電線・ケーブ
ルの印刷方法として有効でおる。[Means for Solving the Problems] The gist of the present invention is to use Infusiera 1 to printer ink containing a foaming agent in the ink. That is, the first invention uses jet printing on a predetermined printing object using an ink that is compatible with the ink and contains a foaming agent that foams when exposed to ultraviolet rays or heat, and foams the polynuclear foaming agent. This is a printing method using an inkjet printer that is characterized by the following, and is particularly effective as a printing method for electric wires and cables.
第二の発明のインクは、第一の発明を実施する為の物で
あって、インクの溶媒に適応し、且つ紫外線又は熱によ
り発泡する発泡剤を含有させたことを特徴とするインク
ジェットプリンタ用インクでおる。The ink of the second invention is for carrying out the first invention, and is suitable for the ink solvent and contains a foaming agent that foams when exposed to ultraviolet rays or heat. Cover with ink.
本発明に使用する溶媒に適応し且つ紫外線又は熱による
発泡剤としては、溶剤に水を用いた場合には、例えば重
炭酸ナトリウム、重炭酸アンモニウム、溶剤にメチルエ
チルケトン（ＭＥＫ）を用いた場合には、例えばアゾ化
合物（例えばアゾジカルポニアミド、アゾビスイソブチ
ロニトリル）、ニトリル化合物（例えばジニトロソペン
タメチレンテトラミン）、スルホニルヒドラジド化合物
、トルエンスルホニルヒドラジド、溶剤に石油系のもの
を用いた場合には、例えばベンゼンスホニルヒドラジド
、等がそれぞれ使われる。Foaming agents that are compatible with the solvent used in the present invention and are caused by ultraviolet rays or heat include, for example, sodium bicarbonate or ammonium bicarbonate when water is used as the solvent, and methyl ethyl ketone (MEK) when used as the solvent. For example, azo compounds (e.g. azodicarponiamide, azobisisobutyronitrile), nitrile compounds (e.g. dinitrosopentamethylenetetramine), sulfonyl hydrazide compounds, toluenesulfonyl hydrazide, when petroleum-based solvents are used. , for example, benzenesphonyl hydrazide, etc., respectively.
［作 用］
第１図、第２図は本発明の詳細な説明する図である。ま
ず白色印刷を得る場合、インクのバインダーとして使用
される高分子材料を、溶剤で溶解し透明インクを製作し
、この中に溶剤に適応した液体状の発泡剤を加え混合す
る。この発泡剤は印刷後の熱及び紫外線等の後処理によ
り発泡するタイプのものを選定する。[Function] FIGS. 1 and 2 are diagrams explaining the present invention in detail. First, to obtain white printing, a polymeric material used as an ink binder is dissolved in a solvent to produce a transparent ink, and a liquid foaming agent compatible with the solvent is added and mixed. This foaming agent is selected from a type that foams when subjected to post-treatments such as heat and ultraviolet rays after printing.
この状態で得られるインクは透明の液体でおり、前）ホ
した顔料等の如き粒子は存在しない。このためインクジ
ェットプリンタを使用し印刷しても、通常のインク例え
ば黒色の染料インクと同様の印刷が可能であり、前述し
た諸問題は一切発生しない。第２図はインクジェットプ
リンタで印刷した直後発泡前の断面図である。印字面（
１）上に透明インク（液）（２ａ）に発泡剤（３）を含
んだ状態を示す。The ink obtained in this state is a transparent liquid, and there are no particles such as the pigments mentioned above. Therefore, even if an inkjet printer is used for printing, it is possible to print in the same manner as with normal ink, such as black dye ink, and the above-mentioned problems do not occur at all. FIG. 2 is a sectional view immediately after printing with an inkjet printer and before foaming. Print surface (
1) The state in which the transparent ink (liquid) (2a) contains the foaming agent (3) is shown.
次に印刷後に後処理として、使用した発泡剤に対応した
紫外線又は熱等を加え、インクを発泡させ乾燥させる。Next, as a post-processing after printing, ultraviolet rays or heat corresponding to the foaming agent used is applied to foam and dry the ink.
これによって第１図に示す如く発泡気泡（４）は透明イ
ンク（乾燥後＞（２ｂ）のバインダーをふくらませ、イ
ンクは発泡気泡（４）の乱反射で透明より白色に変化し
、白色の印刷が得られることになる。As a result, as shown in Figure 1, the foamed bubbles (4) swell the transparent ink (after drying) (2b) binder, and the ink changes from transparent to white due to diffuse reflection from the foamed bubbles (4), resulting in white printing. It will be done.
特に、電線・ケーブルのプラスチック又はゴム等の押出
直後に印刷を行えば、被覆材の熱により自動的に後処理
なくして白色印刷が得られる。In particular, if printing is performed immediately after extrusion of plastic or rubber for electric wires and cables, white printing can be automatically obtained without post-processing due to the heat of the covering material.
本発明の応用としては、着色剤としての染料を含んだイ
ンクに発泡剤を加え印刷することも可能であり、この際
は明度の高い色相例えば黄色等も鮮明に印刷することが
出来る。As an application of the present invention, it is also possible to print by adding a foaming agent to an ink containing a dye as a coloring agent, and in this case, it is possible to print vivid hues such as yellow.
又、発泡することにより第１図に示す様に印字の容積が
膨張するので、これにより印刷面が盛り上がり凸状の印
刷を１ｑることが出来る。これによって視覚的により判
別しやすい印刷が出来る。Moreover, as the foaming causes the volume of the print to expand as shown in FIG. 1, the print surface swells, making it possible to print in a convex shape by 1q. This allows for printing that is easier to visually distinguish.
［実施例］
透明インクの材料として、
バインダー・・・ビニール樹脂 １００部溶
剤・・・メチルエチルケトン ９００部をタンクの中
で混合し、透明インクを作った。[Example] As a material for transparent ink, binder... 100 parts of vinyl resin was dissolved.
Agent: 900 parts of methyl ethyl ketone were mixed in a tank to prepare a transparent ink.
該透明インクの中に発泡剤としてアゾジカルポニアミド
を５部加え、よく混合して、インクジェットプリンタ用
インクを完成した。Five parts of azodicarponiamide as a foaming agent was added to the transparent ink and mixed well to complete an inkjet printer ink.
このインクを使用して、電線・ケーブルのプラスチック
押出直後に、インクジェットプリンタにより、印字した
ところ、明瞭なる白色印字を得ることが出来た。When this ink was used to print with an inkjet printer immediately after plastic extrusion of electric wires and cables, clear white print could be obtained.
［発明の効果］
以上説明した様にインクジェットプリンタ用インク中に
発泡剤を混合することにより、従来困難とされた目づま
りによる不安定作業もなく、良好な白色の印字が可能と
なった。又発泡気泡の乱反射により印刷面の色相の９３
９を防止することが出来るため、従来困難であった黒色
面への白色印字ばかりでなく、染料系の色相でおる黄、
赤色等も鮮明に印字可能となった。[Effects of the Invention] As explained above, by mixing a foaming agent into the ink for an inkjet printer, it is possible to print in a good white color without unstable operation due to clogging, which was previously considered difficult. In addition, due to the diffused reflection of foamed bubbles, the hue of the printed surface changes to 93%.
9, it is possible to prevent not only white printing on black surfaces, which was previously difficult, but also yellow printing with dye-based hues,
It is now possible to print colors such as red clearly.
又発泡によるインク自身の膨張により凸状の印字となり
視覚による確認ばかりでなく触覚による確認も可能とな
った。従って、特に電線・ケーブルの印刷には適した印
刷方法である。In addition, the ink itself expands due to foaming, resulting in convex prints that can be confirmed not only visually but also by touch. Therefore, this printing method is particularly suitable for printing electric wires and cables.
第１図は本発明の印刷方法を用いた発泡乾燥後の状態を
説明する原理図であり、第２図は本発明の印刷直後（発
泡前）の状態を説明する原理図である。
１・・・印字面、
２ａ・・・透明インク（液）、
２ｂ・・・透明インク（乾燥後）、
３・・・発泡剤、
４・・・発泡気泡。FIG. 1 is a principle diagram illustrating the state after foaming and drying using the printing method of the present invention, and FIG. 2 is a principle diagram illustrating the state immediately after printing (before foaming) according to the present invention. 1... Printed surface, 2a... Transparent ink (liquid), 2b... Transparent ink (after drying), 3... Foaming agent, 4... Foaming bubbles.
Claims (3)
る発泡剤を含有させたインクを用いて、所定の印刷対象
物に対してジェットプリントし、その後該発泡剤を発泡
させることを特徴とするインクジェットプリンタによる
印刷方法。(1) Jet printing is performed on a predetermined printing object using an ink that is compatible with the ink and contains a foaming agent that foams when exposed to ultraviolet rays or heat, and then the foaming agent is foamed. How to print using an inkjet printer.
囲第（１）項のインクジェットプリンタによる印刷方法
。(2) A printing method using an inkjet printer according to claim (1), wherein the object to be printed is an electric wire or cable.
発泡する発泡剤を含有させたことを特徴とするインクジ
ェットプリンタ用インク。(3) An ink for an inkjet printer characterized by containing a foaming agent that is compatible with the solvent of the ink and foams when exposed to ultraviolet light or heat.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60177403A JPS6237186A (en) | 1985-08-12 | 1985-08-12 | Printing by ink jet printer and ink therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60177403A JPS6237186A (en) | 1985-08-12 | 1985-08-12 | Printing by ink jet printer and ink therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6237186A true JPS6237186A (en) | 1987-02-18 |
| JPH0434952B2 JPH0434952B2 (en) | 1992-06-09 |
Family
ID=16030320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60177403A Granted JPS6237186A (en) | 1985-08-12 | 1985-08-12 | Printing by ink jet printer and ink therefor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6237186A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2713985A1 (en) * | 1993-12-16 | 1995-06-23 | Roland Man Druckmasch | Device comprising a form of erasable printing for typography, especially for flexographic printing. |
| US7812259B2 (en) | 2008-10-24 | 2010-10-12 | Southwire Company | Metal-clad cable with foraminous coded label |
| JP2012020405A (en) * | 2010-07-12 | 2012-02-02 | Hitachi Industrial Equipment Systems Co Ltd | Inkjet recording device and method of controlling the same |
| US9950826B1 (en) | 2009-01-30 | 2018-04-24 | Encore Wire Corporation | Method for applying labels to cable or conduit |
| US10035618B1 (en) | 2009-01-30 | 2018-07-31 | Encore Wire Corporation | System and apparatus for applying labels to cable or conduit |
| US10046879B1 (en) | 2007-06-04 | 2018-08-14 | Encore Wire Corporation | Method and apparatus for applying labels to cable |
| JP2018168203A (en) * | 2017-03-29 | 2018-11-01 | 日本新聞インキ株式会社 | Aqueous foam ink for inkjet and production method of the same |
| US11031157B1 (en) | 2013-08-23 | 2021-06-08 | Southwire Company, Llc | System and method of printing indicia onto armored cable |
| US11319104B1 (en) | 2009-01-30 | 2022-05-03 | Encore Wire Corporation | System and apparatus for applying labels to cable or conduit |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5793194A (en) * | 1980-12-03 | 1982-06-10 | Seiko Epson Corp | Simultaneous copy printing machine |
-
1985
- 1985-08-12 JP JP60177403A patent/JPS6237186A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5793194A (en) * | 1980-12-03 | 1982-06-10 | Seiko Epson Corp | Simultaneous copy printing machine |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2713985A1 (en) * | 1993-12-16 | 1995-06-23 | Roland Man Druckmasch | Device comprising a form of erasable printing for typography, especially for flexographic printing. |
| US11498715B1 (en) | 2007-06-04 | 2022-11-15 | Encore Wire Corporation | Method and apparatus for applying labels to cable |
| US11827409B1 (en) | 2007-06-04 | 2023-11-28 | Encore Wire Corporation | Method and apparatus for applying labels to cable |
| US10759558B1 (en) | 2007-06-04 | 2020-09-01 | Encore Wire Corporation | Method and apparatus for applying labels to cable |
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Also Published As
| Publication number | Publication date |
|---|---|
| JPH0434952B2 (en) | 1992-06-09 |
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