JPS62292881A - Backfill grout for cavity - Google Patents
Backfill grout for cavityInfo
- Publication number
- JPS62292881A JPS62292881A JP13611486A JP13611486A JPS62292881A JP S62292881 A JPS62292881 A JP S62292881A JP 13611486 A JP13611486 A JP 13611486A JP 13611486 A JP13611486 A JP 13611486A JP S62292881 A JPS62292881 A JP S62292881A
- Authority
- JP
- Japan
- Prior art keywords
- component
- resin
- injection material
- modified
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011440 grout Substances 0.000 title abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 52
- 239000011347 resin Substances 0.000 claims abstract description 52
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- NEBBLNDVSSWJLL-UHFFFAOYSA-N 2,3-bis(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(OC(=O)C(C)=C)COC(=O)C(C)=C NEBBLNDVSSWJLL-UHFFFAOYSA-N 0.000 claims abstract description 4
- UKMBKKFLJMFCSA-UHFFFAOYSA-N [3-hydroxy-2-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)OC(=O)C(C)=C UKMBKKFLJMFCSA-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 57
- 239000007924 injection Substances 0.000 claims description 55
- 238000002347 injection Methods 0.000 claims description 55
- 239000003822 epoxy resin Substances 0.000 abstract description 10
- 229920000647 polyepoxide Polymers 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 9
- 229920002803 thermoplastic polyurethane Polymers 0.000 abstract description 9
- 229920006337 unsaturated polyester resin Polymers 0.000 abstract description 8
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000945 filler Substances 0.000 abstract description 5
- 238000004132 cross linking Methods 0.000 abstract 2
- 239000004567 concrete Substances 0.000 description 18
- 230000000704 physical effect Effects 0.000 description 18
- 229920005862 polyol Polymers 0.000 description 15
- 150000003077 polyols Chemical class 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 11
- 229920000768 polyamine Polymers 0.000 description 11
- 229920001228 polyisocyanate Polymers 0.000 description 11
- 239000005056 polyisocyanate Substances 0.000 description 11
- 239000004570 mortar (masonry) Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 7
- 230000005484 gravity Effects 0.000 description 7
- 125000001931 aliphatic group Chemical group 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000006260 foam Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000010426 asphalt Substances 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 229920006305 unsaturated polyester Polymers 0.000 description 4
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 239000000539 dimer Substances 0.000 description 3
- 239000010451 perlite Substances 0.000 description 3
- 235000019362 perlite Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DDKMFQGAZVMXQV-UHFFFAOYSA-N (3-chloro-2-hydroxypropyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(O)CCl DDKMFQGAZVMXQV-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N Methyl ethyl ketone Natural products CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 229910001562 pearlite Inorganic materials 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- QRIMLDXJAPZHJE-UHFFFAOYSA-N 2,3-dihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(O)CO QRIMLDXJAPZHJE-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 241000975357 Salangichthys microdon Species 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- -1 ether ketone Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 229920000582 polyisocyanurate Polymers 0.000 description 1
- 239000011495 polyisocyanurate Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Sealing Material Composition (AREA)
Abstract
Description
【発明の詳細な説明】
３発明の詳細な説明
産業上の利用分野
本発明は新規な空洞裏込注入材に関するものである。さ
らに詳しくいえば、本発明は、トンネルの補修工事にお
いて、トンネル覆工コンクリートの背面などの空洞部光
てん用として好適な、比重が比較的小さく、かつゲルタ
イムが長い上に、硬化物の圧縮強度が高いなど、優れた
特徴を有する新規な空洞裏込注入材に関するものである
。DETAILED DESCRIPTION OF THE INVENTION 3. DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a novel cavity backfilling injection material. More specifically, the present invention has a relatively low specific gravity, a long gel time, and a high compressive strength of the cured product, which is suitable for use as a light source in cavities such as the back of tunnel lining concrete in tunnel repair work. The present invention relates to a novel cavity backfilling material that has excellent characteristics such as high
従来の技術
従来、トンネル覆工コンクリートの打設方法として、一
般に逆巻工法によるコンクリートパイプの引抜方法が採
用されているが、このような方法により該覆工コンクリ
ートを打設する場合、いかに入念に施工してもアーチ上
部と地山との間に空洞が発生するのを免れず、特に、支
保工に縫地や掛矢板を施工した場合にはかなりの空洞が
発生する。このような空洞が発生すると、覆工コンクリ
ートに加わる主働比圧が不均一となり、かつ地山の受働
土圧を有効に利用することができなくなるため、覆工コ
ンクリートにとっては空洞の発生は好ましくない現象で
ある。したがって、これまでモルタルなどを用いて、該
空洞を充てんする方法がとられてきた。Conventional technology Conventionally, as a method for placing tunnel lining concrete, the method of pulling out concrete pipes using the reverse winding method has generally been adopted. No matter how much construction is done, cavities inevitably occur between the upper part of the arch and the ground, and especially when sewn fabric or hanging sheets are installed on the shoring, a considerable amount of cavities occur. When such cavities occur, the active specific pressure applied to the lining concrete becomes uneven, and the passive earth pressure of the ground cannot be used effectively, so the occurrence of cavities is preferable for the lining concrete. This is a phenomenon that does not exist. Therefore, a method of filling the cavity using mortar or the like has been used so far.
ところで、最近になって、老朽劣化の進んだトンネルの
調査により、このようなトンネルにおいては、覆工コン
クリート巻厚が数口も不足して覆工コンクリートの背面
などがかなり空洞化し、これによって該コンクリートが
変圧を受け、覆工コンクリートのはく離やはく落が生じ
ているものもあることが分かった。By the way, a recent survey of tunnels that had deteriorated over time revealed that in such tunnels, the thickness of the concrete lining was several inches short, and the back surface of the concrete lining became quite hollow. It was found that the concrete was subjected to deformation, causing the concrete lining to peel or fall off in some cases.
このような老朽劣化の進んだトンネルにおいて、該空洞
にモルタルなどを充てんして補修する場合、モルタルは
比重が大きいので、注入材の自重のみで覆エコンクＪ−
トが落下するおそれがあり、保安対策上極めて危険であ
る上に、たとえモルタルを充てんしても、覆工コンクリ
ートの巻厚不足に対して、一体の強度は確保できない、
などの問題がある。さらに、電気運転区間の鉄道在来線
トンネルにおいては、モルタルで補修すると、覆工コン
クリートのクラック部分からモルタルの濁水が洩れ、架
線に垂れてショートし列車運転障害事故をひき起こすお
それもある。When repairing a tunnel that has deteriorated over time by filling the cavity with mortar, etc., the mortar has a high specific gravity, so it is necessary to cover the cavity with only the weight of the injection material.
This is extremely dangerous from a security standpoint, as there is a risk that the concrete may fall, and even if it is filled with mortar, it will not be able to ensure the strength of the concrete against the insufficient thickness of the concrete lining.
There are other problems. Furthermore, when conventional railway tunnels in electric operation sections are repaired with mortar, turbid water from the mortar leaks from cracks in the concrete lining and drips onto the overhead wires, causing a short circuit and potentially causing train operation problems.
このような問題を解決するための空洞裏込注入材と、し
ては、（１）水を使用しない注入材、（２）流動性のあ
る注入材、（６）コンクリートとの接着性が極めてよく
、一体化する注入材、（４）比重の小さい注入材、（５
）硬化物の圧縮強度が１８０ｋｇ／ｃＭ２ 以上の注
入材、（６）硬化反応時間が長い注入材、（７）注入施
工性のよい注入材などの条件を満たすものが挙げられる
が、従来のセメント°モルタル系注入材では、これらの
条件すべてを満足することができない。Cavity backfilling materials to solve these problems include: (1) a material that does not use water, (2) a fluid material, and (6) an extremely adhesive material with concrete. (4) Injection materials with low specific gravity, (5)
) Injection materials with a compressive strength of 180 kg/cm2 or more after hardening, (6) Injection materials with a long curing reaction time, and (7) Injection materials with good injection workability. °Mortar-based injection materials cannot satisfy all of these conditions.
最近、トンネルの裏込注入工事として、ポリウレタン発
泡グラウトを用いた施工が注目されている。しかしなが
ら、この注入材は、前記の条件をある程度満たしつるも
のの、すべての条件を十分に満たしうるものとはいえな
い。Recently, construction using polyurethane foam grout has been attracting attention for tunnel backfilling work. However, although this injection material satisfies the above conditions to some extent, it cannot be said to fully satisfy all of the conditions.
発明が解決しようとする問題点
本発明はこのような事情のもとで、トンネルの補修工事
において、トンネル覆エコンクＪ−トの背面などの空洞
部充てん用として好適な、前記条件をすべて満たしうる
新規な空洞裏込注入材の提供を目的としてなされたもの
である。Problems to be Solved by the Invention Under these circumstances, the present invention satisfies all of the above conditions, making it suitable for filling cavities such as the back of tunnel covering concrete J-types in tunnel repair work. This was done with the aim of providing a new cavity backfilling injection material.
問題点を解決するための手段
本発明者らは、前記目的を達成するために鋭意研究を重
ねた結果、硬化性樹脂、−架橋性多官能単量体、硬化剤
及び特定の軽量光てん剤を所定の割合で含有して成るも
のが、その目的に適合しうろことを見出し、この知見に
基づいて本発明を完成するに至った。Means for Solving the Problems As a result of extensive research to achieve the above object, the present inventors have developed a curable resin, a crosslinkable polyfunctional monomer, a curing agent, and a specific lightweight photonic agent. It was discovered that a scale containing a predetermined proportion of the following is suitable for the purpose, and based on this knowledge, the present invention was completed.
すなわち、本発明は、（Ａ）硬化性樹脂、（Ｂ）架橋性
多官能単量体、（Ｃ）硬化剤及び（Ｄ）シラスバルーン
又はシラスパーライト若しくはその両方を含有し、該（
Ｂ）成分の含有量が（Ａ）成分１００重量部に対して５
〜１５０重量部であり、かつ該（Ｄ）成分の含有量が注
入材全量に対して１０〜４０重ｆｆｉ％であることを特
徴とする空洞裏込注入材を提供するものである。That is, the present invention contains (A) a curable resin, (B) a crosslinkable polyfunctional monomer, (C) a curing agent, and (D) a shirasu balloon or a shirasu pearlite, or both;
The content of component B) is 5 parts by weight per 100 parts by weight of component (A).
to 150 parts by weight, and the content of the component (D) is 10 to 40% by weight based on the total amount of the injection material.
本発明注入材において（Ａ）成分として用いられる硬化
性樹脂としては、例えば不飽和ポリエステル樹脂や不飽
和ポリエステル変性樹脂などの不飽和ポリエステル系樹
脂、エポキシ樹脂、アスファルト変性エポキシ樹脂、ゴ
ム変性エポキシ樹脂などのエポキシ系樹脂、ウレタン樹
脂用ポリオール樹脂、ウレタンプレポリマー、ウレタン
変性ｔＭ脂、エポキンウレタン樹脂などのウレタン系樹
脂、さらにはアクリル変性樹脂、シリコン変性樹脂、尿
素変性樹脂、ゴム変性樹脂、フェノール変性樹脂、アル
キド変性樹脂、キシレン変性樹脂、メラミン変性樹脂、
フラン変性樹脂、アニリン変性樹脂、ＡＢＳ樹脂などが
挙げられる。これらの硬化性樹脂の中で、特に不飽和ポ
リエステル系樹脂、エポキシ系樹脂及びウレタン系樹脂
が好適である。Examples of the curable resin used as component (A) in the injection material of the present invention include unsaturated polyester resins such as unsaturated polyester resins and unsaturated polyester-modified resins, epoxy resins, asphalt-modified epoxy resins, rubber-modified epoxy resins, etc. Urethane resins such as epoxy resins, polyol resins for urethane resins, urethane prepolymers, urethane-modified tM resins, and epoxy urethane resins, as well as acrylic-modified resins, silicone-modified resins, urea-modified resins, rubber-modified resins, and phenol-modified resins. resin, alkyd modified resin, xylene modified resin, melamine modified resin,
Examples include furan-modified resin, aniline-modified resin, and ABS resin. Among these curable resins, unsaturated polyester resins, epoxy resins, and urethane resins are particularly suitable.
本発明注入材においては、（Ｂ）成分として架橋性多官
能単量体が用いられる。この単量体としては、分子中に
官能基として、例えばビニル性二重結合を２個以上有す
るもの、あるいはビニル性二重結合を少なくとも１個含
有し、他にヒドロキシル基やエポキン基を有するものな
どが挙げられる。In the injection material of the present invention, a crosslinkable polyfunctional monomer is used as the component (B). This monomer is one that has two or more vinyl double bonds as a functional group in the molecule, or one that contains at least one vinyl double bond and also has a hydroxyl group or an epoquine group. Examples include.
この−架橋°性多官能単量体の具体例としては、グリセ
ロールトリメタクリレート、
？８・
ｆ’ｉ２１．；＝１．；−１，；ＩＪＩＪ−シ１１２ク
リセロールジメタクリレート、
ＣＨ３
■
Ｈ２Ｃ＝ ｃ−ｃｏｏ−ｃｑ２
ＣＨ３ＣＨ−ＯＨ
ｌ
Ｈ２Ｃ＝Ｃ−Ｃｏｏ−ＣＨ２
２−ヒドロキシ−３−クロロプロピルメタクリレート、
ＯＨ３
Ｈ２Ｃ＝Ｃ−Ｃ００ＣＨ２−ＣＨ−ＣＨ２Ｃ１！ＯＨ
２，３−エポキンープロビルメタクリレートＨ３
Ｈ２Ｃ＝Ｃ−Ｃ００ＣＨ２−ＣＨ−ＣＨ２及びこれらの
混合物などを好ましく挙げることができる。Specific examples of this crosslinkable polyfunctional monomer include glycerol trimethacrylate, ? 8. f'i21. ;=1. ;-1, ;IJIJ-C112 Clycerol dimethacrylate, CH3 ■ H2C= c-coo-cq2 CH3CH-OH l H2C=C-Coo-CH2 2-Hydroxy-3-chloropropyl methacrylate, OH3 H2C=C-C00CH2 -CH-CH2C1! Preferred examples include OH 2,3-epoquine-probyl methacrylate H3 H2C=C-C00CH2-CH-CH2 and mixtures thereof.
該−架橋性多官能単量体は、前記硬化性樹脂を架橋して
硬化物の機械的強度、特に圧縮強度を高め、かつ反応性
希釈剤として得られる注入材の粘度及びゲルタイムを適
切に調節する作用を有している。このような作用を有す
る代表的な架橋性多官能単量体としては、ブレンマーＣ
Ｐ（日本油脂（株）製、商品名〕が市販されている。こ
のものは、グリセロールトリメタクリレート２５〜４０
重量係、グリセロールジメタクリレート３０〜４５重量
％、２−ヒドロキシ−３−クロロプロピルメタクリレー
ト１０〜２５重量％、２．３−エボキシグロピルメタク
９レート３〜１０重量係、その他５〜１０重量係から成
る混合物で、粘度２０〜６０センチポイズ（２５°Ｃ）
の暗赤色液体である。The crosslinkable polyfunctional monomer crosslinks the curable resin to increase the mechanical strength, especially compressive strength, of the cured product, and serves as a reactive diluent to appropriately adjust the viscosity and gel time of the resulting injection material. It has the effect of A typical crosslinkable polyfunctional monomer having such an effect is Blemmer C.
P (manufactured by NOF Corporation, trade name) is commercially available. This product contains glycerol trimethacrylate 25-40
Weight: 30-45% by weight of glycerol dimethacrylate, 10-25% by weight of 2-hydroxy-3-chloropropyl methacrylate, 3-10% by weight of 2.3-epoxyglopyl methacrylate, 5-10% by weight of others. with a viscosity of 20 to 60 centipoise (25°C)
It is a dark red liquid.
本発明注入材において、前記架橋性多官能単量体の配合
量は、硬化性樹脂１００重量部に対し、５〜１５０重量
部の範囲で選ばれる。この量が５重量部未満では硬化物
の圧縮強度が向上しない上に、ゲルタイムが短く、また
１５０重量部を超えると硬化物の圧縮強度が低下する。In the injection material of the present invention, the blending amount of the crosslinkable polyfunctional monomer is selected within the range of 5 to 150 parts by weight based on 100 parts by weight of the curable resin. If this amount is less than 5 parts by weight, the compressive strength of the cured product will not improve and the gel time will be short, and if it exceeds 150 parts by weight, the compressive strength of the cured product will decrease.
該架橋性多官能単量体の好ましい配合量は、使用する硬
化性樹脂の種類によって左右され、例えば硬化性樹脂と
して不飽和ポリエステル系樹脂を用いる場合は３０〜１
２０重量部、エポキシ系樹脂の場合は５〜５０重量部、
ウレタン系樹脂の場合は１５〜８０重量部の範囲で選ば
れる。The preferred blending amount of the crosslinkable polyfunctional monomer depends on the type of curable resin used, and for example, when an unsaturated polyester resin is used as the curable resin, the amount is 30 to 1
20 parts by weight, 5 to 50 parts by weight in the case of epoxy resin,
In the case of urethane resin, the amount is selected within the range of 15 to 80 parts by weight.
本発明注入材において、（Ｃ）成分として用いられる硬
化剤としては、例えば変性脂肪族ポリアミン、変性芳香
族ポリアミン、変性ポリアミドアミン、ポリチオール、
脂環式の酸又はその無水物、第三級アミン、ポリサルフ
ァイド、メチルエチルケトンパーオキシド、クロロへキ
サンパーオキサイド、過酸化ベンゾイル、ナフテン酸コ
バルト、ジメチルアニリン、ポリオール、ポリイソシア
ナート化合物などが挙げられる。In the injection material of the present invention, examples of the curing agent used as component (C) include modified aliphatic polyamine, modified aromatic polyamine, modified polyamide amine, polythiol,
Examples include alicyclic acids or their anhydrides, tertiary amines, polysulfides, methyl ethyl ketone peroxide, chlorohexane peroxide, benzoyl peroxide, cobalt naphthenate, dimethylaniline, polyols, polyisocyanate compounds, and the like.
これらの硬化剤は前記（Ａ）成分の硬化性樹脂の種類に
よって適宜選ばれる。該硬化性樹脂と硬化剤との組合せ
の例としては、流動性、接着性、圧縮強度、耐水性など
に優れた硬化物を与える点で、不飽和ポリエステル系樹
脂と過酸化物との組合せ、エポキシ系樹脂と変性ポリア
ミドポリアミンや変性脂肪族ポリアミンとの組合せ、ポ
リオール樹脂とポリイソシアナート化合物との組合せな
どが好ましく挙げられる。These curing agents are appropriately selected depending on the type of curable resin of component (A). Examples of combinations of the curable resin and curing agent include combinations of unsaturated polyester resins and peroxides, which provide cured products with excellent fluidity, adhesion, compressive strength, water resistance, etc.; Preferred examples include a combination of an epoxy resin and a modified polyamide polyamine or a modified aliphatic polyamine, and a combination of a polyol resin and a polyisocyanate compound.
不飽和ポリエステル系樹脂と過酸化物との組合せでは、
圧縮強度などの機械的物性や接着性などに優れた硬化物
を与えるが、通常１０〜３０分と短い時間で硬化する。In combination with unsaturated polyester resin and peroxide,
It provides a cured product with excellent mechanical properties such as compressive strength and adhesion, but it usually cures in a short time of 10 to 30 minutes.
空洞へ樹脂を注入する際、施工にかなりの時間を要する
ので、このように短時間で硬化する場合、樹脂注入中に
ゲル化して注入施工が困難となる。When injecting resin into a cavity, it takes a considerable amount of time to perform the process, so if the resin hardens in such a short time, the resin will gel during injection, making the injection process difficult.
しかし、本発明においては、前記のように（Ｂ）成分の
架橋性多官能単量体を配合することにより、該硬化時間
を調節することができ、例えば硬化時間が３時間以上、
配合によっては１０時間以上の注入材を調製することが
できる。However, in the present invention, by blending the crosslinkable polyfunctional monomer of component (B) as described above, the curing time can be adjusted, for example, the curing time is 3 hours or more,
Depending on the formulation, injection materials can be prepared for 10 hours or more.
前記硬化剤の配合割合は、硬化性樹脂との組合せにより
異なり、−概に限定することができず、例えば不飽和ポ
リエステル系樹脂と過酸化物との組合せでは、過酸化物
は、不飽和ポリエステル系樹脂１００重量部に対し、通
常１〜５重量部の範囲で用いられ、エポキシ系樹脂と変
性ポリアミドポリアミンや変性脂肪族ポリアミンとの組
合せでは、変性ポリアミドポリアミンや変性脂肪族ポリ
アミンは、エポキシ系樹脂１００重量部に対し、通常２
０〜１００重量部の範囲で用いられる。また、ポリオー
ル樹脂とポリイソシアナート化合物との組合せでは、ポ
リイソシアナート化合物は、ポリオール樹脂１００重量
部に対し、１００〜３００重量部の範囲で用いられる。The blending ratio of the curing agent varies depending on the combination with the curable resin, and cannot be generally limited. For example, in a combination of an unsaturated polyester resin and a peroxide, the peroxide is It is usually used in the range of 1 to 5 parts by weight per 100 parts by weight of the resin. Usually 2 parts per 100 parts by weight
It is used in a range of 0 to 100 parts by weight. Further, in the combination of a polyol resin and a polyisocyanate compound, the polyisocyanate compound is used in an amount of 100 to 300 parts by weight based on 100 parts by weight of the polyol resin.
本発明注入剤においては、（Ｄ）成分の軽量充てん剤と
して、シラスバルーン又はパーライト若しくはその両方
が用いられる。これらの軽量充てん剤は、硬化物の圧縮
強度を高め、かつ注入材の比重を調節するために用いら
れ、その配合量は、注入材全量に対して１０〜４０重量
％の範囲で選ばれる。この量が１０重量％未満では硬化
物の圧縮強度を高める効果がなく、また４０重量％を超
えると、硬化物の接着性が低下するとともに、注入材の
粘度が高くなりすぎて、取り扱い性が悪くなる。In the injection preparation of the present invention, Shirasu balloons, pearlite, or both are used as the lightweight filler of component (D). These lightweight fillers are used to increase the compressive strength of the cured product and to adjust the specific gravity of the injection material, and their blending amount is selected within the range of 10 to 40% by weight based on the total amount of the injection material. If this amount is less than 10% by weight, it will not have the effect of increasing the compressive strength of the cured product, and if it exceeds 40% by weight, the adhesiveness of the cured product will decrease and the viscosity of the injection material will become too high, making it difficult to handle. Deteriorate.
本発明注入材には、所望に応じ、他の充てん剤、例えば
金属酸化物、金属水酸化物、金属塩、カーボン、金属粉
、沈降性炭酸カルシウム、ベントナイト、重質炭酸カル
シウム、含水ケイ酸、無水ケイ酸、ケイ酸アルミニウム
、タルク、カオリン、酸化マグネシウム、ケイ砂、砕石
などを、本発明の目的を損わない範囲で配合することが
できる。The injection material of the present invention may optionally contain other fillers such as metal oxides, metal hydroxides, metal salts, carbon, metal powders, precipitated calcium carbonate, bentonite, heavy calcium carbonate, hydrated silicic acid, Anhydrous silicic acid, aluminum silicate, talc, kaolin, magnesium oxide, silica sand, crushed stone, and the like can be blended within the range that does not impair the object of the present invention.
本発明においては、硬化性樹脂の種類、架橋性多官能単
量体の配合量、硬化剤の種類と配合量、軽量充てん剤の
配合量などを適切に選択することにより、比重０．８〜
１，０、ゲルタイム１〜５時間、硬化物の圧縮強度５０
０〜９００に９／α２などの優れた物性を有する空洞裏
込注入材を調製することができる。In the present invention, by appropriately selecting the type of curable resin, the amount of the crosslinkable polyfunctional monomer, the type and amount of the curing agent, the amount of the lightweight filler, etc.
1.0, gel time 1-5 hours, compressive strength of cured product 50
A cavity backfilling injection material having excellent physical properties such as 9/α2 of 0 to 900 can be prepared.
発明の効果
本発明の空洞裏込注入材は、長時間のポットライフを有
し、空洞に該注入材を配管を通じて長時間にわたり圧送
する場合でも、途中で硬化して配管を詰まらせることが
ない。また、老朽劣化が進行して、トンネル覆工コンク
リートの巻厚が数αという極端に不足した場所に用いて
も、モルタル。Effects of the Invention The cavity backfilling injection material of the present invention has a long pot life, and even when the injection material is pumped into the cavity through piping for a long time, it will not harden midway and clog the piping. . Mortar can also be used in places where the tunnel lining concrete has an extremely insufficient thickness of several α due to aging and deterioration.
セメント系注入材に比べて比重がかなり小さいので、注
入材の自重で劣化した覆工コンクリートを落下させたり
、破壊させたりするおそれがなく、安全対策上において
も優れた注入材である。さらに、従来のモルタル系注入
材のように、水を使用しないために、漏水して架線をシ
ョートさせ、列車運転障害事故をもたらすことがないと
いう利点も有している。Since the specific gravity is considerably lower than that of cement-based injection materials, there is no risk of the degraded lining concrete falling or being destroyed by the weight of the injection material, making it an excellent injection material in terms of safety measures. Furthermore, unlike conventional mortar-based injection materials, it does not use water, so it has the advantage that it does not leak water and cause short-circuits in overhead wires, causing train operation problems.
また、該注入材は、通常硬化前は緑色を呈しており、硬
化が進行するに伴い赤色を経て無色に変色する。したが
って、その色調により硬化程度をある程度把握すること
ができるという利点もある。Further, the injection material is usually green in color before curing, and as the curing progresses, the color changes to red and then colorless. Therefore, there is an advantage that the degree of curing can be determined to some extent by the color tone.
実施例 次に実施例により本発明をさらに詳細に説明する。Example Next, the present invention will be explained in more detail with reference to Examples.
なお、使用した各成分の種類は次のとおりであるＯ
不飽和ポリエステル（オルソ系） ＰＨ−１１５Ｍ（犬
日本インキ製）
ビスフェノールＡ系エポキシ樹脂 エピコート８２８（
シェル化学袋）
アスファルトエポキシ樹脂 Ｌ−７Ｑ７（特公昭５２−
１９８５２号公報実施例）ポリオール樹脂 デスモヘン
１１００
（日本ポリウレタン製）
ポリイソシアナート化合物 コロネートＬ（日本ポリウ
レタン製）
ダイマー酸アミドポリアミン Ｑ−６５２（三井エポキ
ン製）
メテルエテルケトンパーオキンド パーメックＮ（日本
油脂製）
グリセロールメタクリレート混合物 ブレンマー〇Ｐ（
日本油脂製）
変性脂肪族ポリアミン ＥＨ−２２０
（加電化工業製）
実施例１
不飽和ポリエステル（オルソ系）樹脂５２９及びプレン
マー〇Ｐ ２３９を５０°Ｃで加熱混合し、この温度で
３０分かきまぜたのち、冷却し、シラスバルー７２５．
９を混入した。これにメチルエチルケトンパーオキシド
１１を均一になるよう配合し、かきまぜて、注入材を調
製した。この注入材を空洞か所へ注入し２５°Ｃで１０
日間かけて硬化させたところ、完全に空洞か所がコンク
リートと一体になり埋った。この硬化後の物性を別表に
示す。The types of each component used are as follows: O Unsaturated polyester (ortho type) PH-115M (manufactured by Inu Nippon Ink) Bisphenol A-based epoxy resin Epicoat 828 (
Shell chemical bag) Asphalt epoxy resin L-7Q7 (Special Publication 52-
No. 19852 publication example) Polyol resin Desmohen 1100 (manufactured by Nippon Polyurethane) Polyisocyanate compound Coronate L (manufactured by Nippon Polyurethane) Dimer acid amide polyamine Q-652 (manufactured by Mitsui Epokin) Mether ether ketone perokind Permec N (manufactured by Nippon Oil & Fats) ) Glycerol methacrylate mixture Bremmer〇P (
(manufactured by NOF) Modified aliphatic polyamine EH-220 (manufactured by Kadenka Kogyo) Example 1 Unsaturated polyester (ortho) resin 529 and Premer〇P 239 were heated and mixed at 50°C, and stirred at this temperature for 30 minutes. After that, it is cooled and whitebait 725.
9 was mixed. Methyl ethyl ketone peroxide 11 was mixed uniformly with this and stirred to prepare an injection material. Inject this injection material into the cavity and heat it at 25°C for 10 minutes.
After allowing it to harden for several days, the hollow areas were completely filled in with the concrete. The physical properties after curing are shown in the attached table.
実施例２
不飽和ポリエステル（オルソ系）樹脂３８．９及びプレ
ンマーＧＰ ３７ Ｊを５０°Ｃで加熱混合し、この温
度で３０分かきまぜるのち、冷却しバーライ）２５．９
を混入した。これにメチルエチルケトンパーオキシド１
１を均一になるように配合し、かきまぜて注入材を調製
した。この注入材を空洞か所に注入し、実施例１と同様
にして硬化させた。Example 2 Unsaturated polyester (ortho-based) resin 38.9 and Premer GP 37 J were heated and mixed at 50°C, stirred at this temperature for 30 minutes, and then cooled to give a mixture of 25.9
was mixed in. Add 1 methyl ethyl ketone peroxide to this
1 was mixed uniformly and stirred to prepare an injection material. This injection material was injected into the cavity and cured in the same manner as in Example 1.
硬化物の物性を別表に示す。The physical properties of the cured product are shown in the attached table.
実施例３
ビスフェノールＡ系エポキシ樹脂ろＯｇ及びプレンマー
〇Ｐ ３ ｇを１２０°Ｃで加熱混合し、さらにこの温
度で３０分間かきまぜたのち冷却し、シラスバルーン１
８９を混入した。これにダイマー酸アミドポリアミン２
０．９を均一に配合して、注入材を調製し、実施例１と
同様にして硬化させた。Example 3 Bisphenol A-based epoxy resin filter Og and Premer 〇P 3 g were heated and mixed at 120°C, stirred at this temperature for 30 minutes, cooled, and made into Shirasu Balloon 1.
89 was mixed. Dimer acid amide polyamine 2
0.9 was uniformly blended to prepare an injection material, and cured in the same manner as in Example 1.
硬化物の物性を別表に示す。The physical properties of the cured product are shown in the attached table.
実施例４
ビスフェノールＡ系エポキシ樹脂２３．９及びプレンマ
ー〇Ｐ １０ ｇを１２０°Ｃで加熱混合し、さらにこ
の温度で３０分間かきまぜたのち冷却し、バーライ）１
８Ｊを混入した。これとダイマー酸アミドポリアミン２
０Ｊを均一に配合して注入材を調製し、実施例１と同様
にして硬化させた。硬化物の物性を別表に示す。Example 4 23.9 g of bisphenol A-based epoxy resin and 10 g of Premer 〇P were heated and mixed at 120°C, further stirred at this temperature for 30 minutes, and then cooled to produce Barley) 1
8J was mixed. This and dimer acid amide polyamine 2
An injection material was prepared by uniformly blending 0J and cured in the same manner as in Example 1. The physical properties of the cured product are shown in the attached table.
実施例５
アスファルトエポキン樹脂３０ｇ及びプレンマーＧＰ３
９を、１２０’Ｃｆ加熱混合し、さらに、この温度で３
０分間かきまぜて均一に混合したのち冷却し、シラスバ
ルーン１８ｇを混入した。これに変性脂肪族ポリアミン
１３．９を均一に配合して注入材を調製し、実施例１と
同様にして硬化させた。Example 5 30g of asphalt Epoquine resin and Premar GP3
9 was heated and mixed at 120'Cf, and further 3 was heated at this temperature.
After stirring for 0 minutes to mix uniformly, the mixture was cooled and 18 g of Shirasu balloons were mixed therein. Modified aliphatic polyamine 13.9 was uniformly blended with this to prepare an injection material, and cured in the same manner as in Example 1.
硬化物の物性を別表に示す。The physical properties of the cured product are shown in the attached table.
実施例６
アスフアルトエボキン樹脂２３９及びプレンマーＧＰ１
０．９を１２０°Ｃで加熱混合し、さらにこの温度で５
０分間かきまぜたのち冷却し、パーライト１８ｇを混入
した。これに変性脂肪族ポリアミン１３！ｉを均一に配
合して、注入材を調製し、実施例１と同様にして硬化さ
せた。硬化物の物性を別表に示す。Example 6 Asphalt Evoquin Resin 239 and Premar GP1
0.9 was heated and mixed at 120°C, and further 5 was added at this temperature.
After stirring for 0 minutes, the mixture was cooled and 18 g of perlite was mixed therein. This is modified aliphatic polyamine 13! i was uniformly blended to prepare an injection material, and cured in the same manner as in Example 1. The physical properties of the cured product are shown in the attached table.
比較例１
ウレタン樹脂用ポリオール３２．５’及びプレンマーＧ
Ｐ８．９を８０°Ｃで加熱混合し、さらにこの温度で３
０分間かきまぜたのち冷却し、これにポリイソシアナー
ト化合物６２ｇ、水２．５Ｉを均一に配合して、注入材
を調製し、注入して、発泡しながら反応開始した。実施
例１と同様にして硬化させた。硬化物の物性を別表に示
す。Comparative Example 1 Polyol 32.5' for urethane resin and Premer G
P8.9 was heated and mixed at 80°C, and further heated at this temperature for 3
After stirring for 0 minutes, the mixture was cooled, and 62 g of a polyisocyanate compound and 2.5 I of water were uniformly blended thereto to prepare an injection material, which was injected and the reaction started while foaming. It was cured in the same manner as in Example 1. The physical properties of the cured product are shown in the attached table.
比較例２
ウレタン樹脂用ポリオール２４９及びプレンマーＣＰ１
６ｇを８０’Ｃで加熱混合し、さらにこの温度で６０分
間かきまぜたのち冷却し、これにボリイソンアナート化
合物６２ｙ１水２，５．９を均一に配合して注入材を調
製し、注入して発泡しながら反応開始した。実施例１と
同様にして硬化させた。Comparative Example 2 Polyol 249 for urethane resin and Premer CP1
6g was heated and mixed at 80'C, further stirred at this temperature for 60 minutes, then cooled, and an injection material was prepared by uniformly blending 62y1 of water with 2.5.9% of the borysonanate compound, and the mixture was injected. The reaction started with foaming. It was cured in the same manner as in Example 1.
硬化物の物性を別表に示す。The physical properties of the cured product are shown in the attached table.
比較例３
不飽和ポリエステル（オルソ系）樹脂７５７に、シラス
バルーン２５ｐを混入し、これにメチルエチルケトンパ
ーオキシド１ｇを均一に混合して、注入材を調製し、実
施例１と同様にして硬化させた。硬化物の物性を別表に
示す。Comparative Example 3 25p of Shirasu balloon was mixed into unsaturated polyester (ortho-based) resin 757, and 1g of methyl ethyl ketone peroxide was mixed uniformly therein to prepare an injection material, and cured in the same manner as in Example 1. . The physical properties of the cured product are shown in the attached table.
比較例４
アスファルトエポキン樹脂３３夕にパーライト１８．９
を混入し、これに変性脂肪族ポリアミン１３ｇを均一に
混合して注入材を調製し、実施例１と同様にして硬化さ
せた。硬化物の物［生を別表に示す。Comparative Example 4 Asphalt Epoquin resin 33 and perlite 18.9
and 13 g of modified aliphatic polyamine were uniformly mixed therein to prepare an injection material, and cured in the same manner as in Example 1. Cured products (raw ones are shown in the attached table).
比較例５
ウレタン樹脂用ポリオール４０．９にポリイソシアナー
ト化合物６２ｇ、水２．５夕を均一に混合して注入材を
調製し注入して、発泡しながら反応開始した（約８倍発
泡＊）。実施例１と同様にして硬化させた。硬化物の物
性を別表に示す。Comparative Example 5 An injection material was prepared by uniformly mixing 40.9 g of a polyol for urethane resin, 62 g of a polyisocyanate compound, and 2.5 g of water, and the mixture was injected, and the reaction was started while foaming (about 8 times foaming*). . It was cured in the same manner as in Example 1. The physical properties of the cured product are shown in the attached table.
比較例６
モルタル注入材用セメント２７ｇ、川砂５３ｇを混合し
、これに水２０Ｊを入れ、さらにかきまぜて調製し、エ
アーと共に注入し、実施例１と同様にして硬化させた。Comparative Example 6 27 g of cement for mortar pouring material and 53 g of river sand were mixed, 20 J of water was added thereto, and the mixture was further stirred, injected with air, and cured in the same manner as in Example 1.
硬化物の物性を別表に示す。The physical properties of the cured product are shown in the attached table.
比較例フ
ミルク注入材用セメン）７０，９、水３（Ｊ９を混合し
、ミルク状にして注入し、実施例１と同様にして硬化さ
せた。硬化物の物性を別表に示す。Comparative Example Cement (Cement for Milk Injection Material) 70.9, water (J9) was mixed, the mixture was made into milk and injected, and cured in the same manner as in Example 1. The physical properties of the cured product are shown in the attached table.
手続補正書
昭和６２年６月１７日
１、事件の表示
昭和６１年特許願第１３６１１４号
２、発明の名称
愛知県名古屋市天白区天白町大字へ事
字裏山１２４番地の６
藤 １） 昌 利
４、代理人
東京都港区新橋２丁目２番２号川志満・邦信ビル８階（
７１８２）弁理士 阿 形 明不−１９
・５、補正命令の日付 自 発
６、補正により増加する発明の数 ０
７、補正の対象 明細書の発明の詳細な説明の欄８
、補正の内容
（１） 明細書第１２ページ第１１行の「比重。、ト
１．０」を「比重０．３−１．ＯＪｉ、：訂正Ｌ！ｔ。Procedural amendment dated June 17, 1988 1. Indication of case Patent Application No. 136114 of 1988 2. Name of invention 124-6 Fuji Urayama, Tenpaku-cho, Tenpaku-ku, Nagoya-shi, Aichi Prefecture 1) Masatoshi 4. Agent: 8th floor, Kawashima Kuninobu Building, 2-2-2 Shinbashi, Minato-ku, Tokyo (
7182) Patent Attorney Akira Agata-19
・5. Date of amendment order 6. Number of inventions increased by amendment 0. 7. Subject of amendment Detailed explanation of the invention in the specification column 8
, Details of the correction (1) In the 11th line of page 12 of the specification, "specific gravity., t 1.0" was changed to "specific gravity 0.3-1.OJi,: correction L!
（２）同第１２ページ第１２行の１圧縮強度５００〜９
００ｋｇ／ｃｍ”Ｊを「圧縮強度１ｊＯ−９００ｋｇ／
ｃｍ２ｊに訂正します。(2) 1 compressive strength 500 to 9 on page 12, line 12
00kg/cm”J to “compressive strength 1jO-900kg/
I will correct it to cm2j.
（３）同第１４ページ第１６行の次に改行して以下の各
成分種類を加入します。(3) Add the following ingredient types on a new line after line 16 on page 14.
［変性硬質ポリオール樹脂２Ｐ−ｉ２１０Ｋ（無気泡型
）（犬日本インキ化学製）
変性硬質ポリオール樹脂ＲＲ−６０２０（独立気泡型約
１倍）
（加電化工業製）
変性硬質プレボ１）マー樹脂ＴＰ−１！３０（独立気泡
湿潤面型）
（大日本インキ化学製）
ポリイソシアナート化合物 ５Ｐ−２９６（大日本イン
キ化学製）
ポリイソシアナート化合物 ＲＮ−１３００（加電化工
業製）」
（４）同第１５ページ第６行及び第１６行の「別表」を
「第１表」に訂正します。[Modified hard polyol resin 2P-i210K (non-cell type) (manufactured by Inu Nippon Ink Chemical Co., Ltd.) Modified hard polyol resin RR-6020 (closed cell type, about 1x) (manufactured by Kadenka Kogyo Co., Ltd.) Modified hard prevo 1) mer resin TP- 1!30 (closed cell wet surface type) (manufactured by Dainippon Ink Chemical) Polyisocyanate compound 5P-296 (manufactured by Dainippon Ink Chemical) Polyisocyanate compound RN-1300 (manufactured by Kadenka Kogyo)" (4) Same No. "Appended Table" in lines 6 and 16 of page 15 will be corrected to "Table 1."
（５）同第１６ページ第４行、１２行及び最下行の「別
表」を「第１表」に訂正します。(5) "Appended Table" on the 4th line, 12th line and the bottom line of the same page 16 will be corrected to "Table 1".
（６）同第１７ページ第８行及び下から５行目の「別表
」を「第１表」に訂正します。(6) “Appended Table” in the 8th line and 5th line from the bottom of the same page 17 will be corrected to “Table 1.”
（７）同第１８ページ第４行、第１０行及び第１５行の
「別表」を「第１表」にそれぞれ訂正します。(7) "Appended Table" in lines 4, 10, and 15 of page 18 will be corrected to "Table 1."
（８）同第１９ページ第２行、第７行及び第１１行の「
別表」を「第１表」にそれぞれ訂正します。(8) On page 19, lines 2, 7, and 11, “
"Appended Table" will be corrected to "Table 1."
（９）同第２０ページの表に「第１表」の表示を加入し
ます。(9) Add "Table 1" to the table on page 20.
（１０）同第２１ページ第１行「特許出願人・・・」の
前に以下の実施例、比較例及び第２表を加入します。(10) The following Examples, Comparative Examples, and Table 2 are added in the first line of page 21, before "Patent applicant...".
「実施例７
ウレタンフオーム樹脂用変性硬質ポリオール（無気泡型
）ＲＰ−１２１０Ｋ ４０９及びブレンマーＧＰ１０ｇ
を８０°Ｃで加熱混合し、さらにこの温度で３０分かき
まぜたのち冷却し、ンラスバルーン１５９を混入した。"Example 7 Modified hard polyol for urethane foam resin (non-cell type) RP-1210K 409 and Blenmar GP10g
The mixture was heated and mixed at 80° C., further stirred at this temperature for 30 minutes, cooled, and Nurasu Balloon 159 was mixed therein.
これにポリイソ・／アナート化合物５Ｐ−２９６５０９
を入れ、さらにかきまぜて注入材を調製し、実施例１と
同様にして硬化させた。硬化物の物性を第２表に示す。To this, polyiso/anate compound 5P-296509
was added and further stirred to prepare an injection material, which was cured in the same manner as in Example 1. Table 2 shows the physical properties of the cured product.
実施例８
ウレタンフオーム樹脂用変性硬質ポリオールＲＲ−６０
２０（独立気泡型約１倍）４０ｇ及びブレンマーＧＰ１
０９を８０°Ｃで加熱混合し、さらにこの温度で３０分
間かきまぜたのち冷却し、パーライト２０９を混入した
。これにポリイソノアナート化合物ＲＮ−１３００５０
９を入れさらにかきまぜ、注入材を調製し、実施例１と
同様にして硬化させた。Example 8 Modified hard polyol RR-60 for urethane foam resin
20 (closed cell type approx. 1x) 40g and Bremmer GP1
09 was heated and mixed at 80°C, and after further stirring at this temperature for 30 minutes, it was cooled and Perlite 209 was mixed. To this, polyisonoanato compound RN-130050
9 was added and further stirred to prepare an injection material, which was cured in the same manner as in Example 1.
硬化物の物性を第２表に示す。Table 2 shows the physical properties of the cured product.
実施例９
ウレタンフ丁−ム樹脂用変性硬質プレポリマーＴＰ−Ｉ
ＮＯ（独立気泡湿潤面型）９０９及びブレンマーＧＰ１
０９を常温でよくかきまぜて、その中にンラスバルーン
１０９混入して、注入材を調製し、湿潤面の箇所に実施
例１と同様にして硬化させた。Example 9 Modified rigid prepolymer TP-I for urethane film resin
NO (closed cell wet surface type) 909 and Bremmer GP1
09 was well stirred at room temperature, and the non-rath balloon 109 was mixed therein to prepare an injection material, which was cured on the wet surface in the same manner as in Example 1.
硬化物の物性を第２表に示す。Table 2 shows the physical properties of the cured product.
比較例８
ウレタンフオーム樹脂用変性硬質ポリオールＲＦ’−１
２１０Ｋ（無気泡型）５０ｇ及びポリイソシアナート化
合物ＳＰ−２９６５０９を混入し、よくかきまぜ注入材
を調製し、実施例１と同様にして硬化させた。Comparative Example 8 Modified hard polyol RF'-1 for urethane foam resin
50 g of 210K (non-bubble type) and polyisocyanate compound SP-296509 were mixed and stirred well to prepare an injection material, and cured in the same manner as in Example 1.
硬化物の物性を第２表に示す。Table 2 shows the physical properties of the cured product.
比較例９
ウレタンフオーム樹脂用変性硬質ポリオール■−６０２
０（独立気泡型約１倍）５０ｇ及びポリイソシアナート
化合物ＲＮ−１３００５０ｇを入れかきまぜ注入材を調
製した。実施例１と同様にして硬化させた。硬化物の物
性を第２表に示す。Comparative Example 9 Modified hard polyol for urethane foam resin ■-602
An injection material was prepared by adding 50 g of 0 (closed cell type approximately 1 times) and 50 g of polyisocyanate compound RN-13000 and stirring. It was cured in the same manner as in Example 1. Table 2 shows the physical properties of the cured product.
゛比較例１０
ウレタンフオーム樹脂用変性硬質プレポリマーＴＰ−Ｉ
ＮＱ（独立気泡湿潤面型）１００ｇを注入材として、湿
潤面の箇所に実施例１と同様にして硬化させた。Comparative Example 10 Modified rigid prepolymer TP-I for urethane foam resin
Using 100 g of NQ (closed cell wet surface type) as an injection material, it was cured on the wet surface in the same manner as in Example 1.
Claims (1)
Ｃ）硬化剤及び（Ｄ）シラスバルーン又はシラスパーラ
イト若しくはその両方を含有し、該（Ｂ）成分の含有量
が（Ａ）成分１００重量部に対して５〜１５０重量部で
あり、かつ該（Ｄ）成分の含有量が注入材全量に対して
１０〜４０重量％であることを特徴とする空洞裏込注入
材。 ２ （Ｂ）成分がグリセロールトリメタクリレート及び
グリセロールジメタクリレートを主成分として含有して
成る混合物である特許請求の範囲第１項記載の注入材。[Claims] 1 (A) curable resin, (B) crosslinkable polyfunctional monomer, (
C) contains a curing agent and (D) a shirasu balloon or shirasperlite, or both, the content of the component (B) is 5 to 150 parts by weight based on 100 parts by weight of the component (A), and the ( D) A cavity backfilling injection material characterized in that the content of the component is 10 to 40% by weight based on the total amount of the injection material. 2. The injection material according to claim 1, wherein component (B) is a mixture containing glycerol trimethacrylate and glycerol dimethacrylate as main components.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13611486A JPS62292881A (en) | 1986-06-13 | 1986-06-13 | Backfill grout for cavity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13611486A JPS62292881A (en) | 1986-06-13 | 1986-06-13 | Backfill grout for cavity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62292881A true JPS62292881A (en) | 1987-12-19 |
| JPH0223588B2 JPH0223588B2 (en) | 1990-05-24 |
Family
ID=15167623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13611486A Granted JPS62292881A (en) | 1986-06-13 | 1986-06-13 | Backfill grout for cavity |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62292881A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109485803A (en) * | 2018-10-31 | 2019-03-19 | 中科院广州化灌工程有限公司 | A kind of aqueous acrylamide hydrochlorate-epoxy resin composite grouting material and the preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5534196A (en) * | 1974-04-01 | 1980-03-10 | Ppg Industries Inc | Electrostatic atomizing painting device |
-
1986
- 1986-06-13 JP JP13611486A patent/JPS62292881A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5534196A (en) * | 1974-04-01 | 1980-03-10 | Ppg Industries Inc | Electrostatic atomizing painting device |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109485803A (en) * | 2018-10-31 | 2019-03-19 | 中科院广州化灌工程有限公司 | A kind of aqueous acrylamide hydrochlorate-epoxy resin composite grouting material and the preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0223588B2 (en) | 1990-05-24 |
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