JPS62280272A - Coating material for use to impart suede-like finish to surface of object - Google Patents

Coating material for use to impart suede-like finish to surface of object

Info

Publication number
JPS62280272A
JPS62280272A JP12342686A JP12342686A JPS62280272A JP S62280272 A JPS62280272 A JP S62280272A JP 12342686 A JP12342686 A JP 12342686A JP 12342686 A JP12342686 A JP 12342686A JP S62280272 A JPS62280272 A JP S62280272A
Authority
JP
Japan
Prior art keywords
suede
coating material
fibers
give
product according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12342686A
Other languages
Japanese (ja)
Inventor
Michiaki Ijuin
伊集院 通明
Masao Suzuki
鈴木 將雄
Hiromi Shimozawa
下沢 博巳
Kaoru Taniguchi
薫 谷口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TOKUSHU SHIKIRIYOU KOGYO KK
Tatsuta Chemical Co Ltd
Original Assignee
TOKUSHU SHIKIRIYOU KOGYO KK
Tatsuta Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TOKUSHU SHIKIRIYOU KOGYO KK, Tatsuta Chemical Co Ltd filed Critical TOKUSHU SHIKIRIYOU KOGYO KK
Priority to JP12342686A priority Critical patent/JPS62280272A/en
Publication of JPS62280272A publication Critical patent/JPS62280272A/en
Pending legal-status Critical Current

Links

Landscapes

  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Paints Or Removers (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)

Abstract

PURPOSE:To provide the title coating material having excellent appearance, feeding and glare protection, by incorporating a fiber in a synthetic resin substrate. CONSTITUTION:Not more than 300pts.wt. fiber having a length of not longer than 3mm and a diameter of not larger than 300d (e.g., nylon), a color pigment, an extender pigment, a stabilizer, a plasticizer, a filler, etc., are blended with an org. solvent soln. of 100pts.wt. at least one synthetic resin substrate selected from the group consisting of acrylic, vinyl chloride, urethane, polyester and polyamide resins.

Description

【発明の詳細な説明】 3、発明の詳細な説明 産業上の利用分野 本発明は、コーティング材料、殊に物の表面をスェード
調にし、すぐれた外観、風合い(手触り等)を持ち、か
つ防眩性の良いものにする為のコーティング材料に関す
る。
Detailed Description of the Invention 3. Detailed Description of the Invention Industrial Application Field The present invention relates to a coating material, especially a coating material that has a suede-like surface, has an excellent appearance and feel (touch, etc.), and has an excellent resistance. Concerning coating materials to provide good glare.

従来の技術 例えば合成樹脂シートの表面をスェード調にするには、
エンボス法に依ったり、短い繊維を静゛1を植毛したり
、織布若しくは不縄lσを合成樹脂で固め毛羽立てたり
、発泡体をスライスして毛羽立てたり、或いは細かいビ
ーズを合成樹脂の表面に塗布したりしていた。
Conventional techniques For example, to make the surface of a synthetic resin sheet suede-like,
By embossing, by flocking short fibers, by hardening and fluffing woven or non-woven fabric with synthetic resin, by slicing foam and fluffing it, or by attaching fine beads to the surface of synthetic resin. It was also applied to

又1合成樹脂の表面を防眩性にするには、上記のほかに
、合成樹脂液にシリカ、炭酸マグ茅シュウム、タルク等
の無機質微粉末又はワックス類が混入されている艶消し
塗料も用いられていた。
In addition to the above, in order to make the surface of synthetic resin anti-glare, a matte paint in which fine inorganic powder such as silica, magnanium carbonate, talc, or wax is mixed into the synthetic resin liquid is also used. It was getting worse.

発り1が解決しようとする問題点 しかしエンボス法によりスェード調にした合成樹脂シー
トや発泡体をスライスして毛羽立てた合成樹脂シートは
、その後成形(例えば真空成形。
Problems that Origin 1 attempts to solve However, synthetic resin sheets that have been made into a suede-like appearance by the embossing method or synthetic resin sheets that have been sliced and fluffed from foam are then molded (e.g., vacuum formed).

圧空成形″J)は出来るが、外観も手触りもあまり良く
ない。
Pressure molding (J) is possible, but the appearance and feel are not very good.

織布若しくは不Jlt!布を用いたものも外観、L触り
は良いが成形には向かない。
Woven fabric or non-woven fabric! Those using cloth also have a good appearance and feel, but are not suitable for molding.

又、細かいビーズを合成樹脂の表面に接着したものや、
誠維を静電気を用いて整列させ接着剤を用いて合成樹脂
表面に固定したものは、接着剤が成形時の熱に耐えられ
ず、ヒビわれしたり、また、成形するとビーズや思雄の
配夕呵にムラが出来たりする。その為、専ら成形後の製
品への使用に限られている。
Also, fine beads glued to the surface of synthetic resin,
When the Sei fibers are aligned using static electricity and fixed to the synthetic resin surface using adhesive, the adhesive cannot withstand the heat during molding and may crack, or when molded, the beads and the fibers may be arranged. There may be unevenness in the evening. Therefore, its use is limited to products after molding.

さらに、艶消し塗料は防眩性がそれほど優れているとも
いえず、スクラッチも入りやすく、しかも成形時の加熱
延伸で艶変化があるため、成形前に塗布することは出来
なかった。
Furthermore, matte paints cannot be said to have very good anti-glare properties, are prone to scratches, and change in gloss due to heating and stretching during molding, so they could not be applied before molding.

本発明は、成形前でも成形後でも表向を防眩性が優れ外
観も丁触りも良いスェード調にすることができるコーテ
ィング材料を提供することを目的としている。
An object of the present invention is to provide a coating material that can give a suede-like surface with excellent anti-glare properties and a good appearance and feel both before and after molding.

問題点を解決する為のL段 本発明のコーティング材料には、繊維が混入されており
、これをスェード調にすべき表面に塗り乾燥後、場合に
より毛羽立てを行うものである。
L stage to solve the problem The coating material of the present invention contains fibers, which are applied to the surface to be suede-like, dried, and then fluffed if necessary.

本発明のコーティング材料は、例えばアクリル樹脂、塩
化ビニル樹脂、ウレタン樹脂、ポリエステル樹脂、ポリ
アミド樹脂、或いはこれらの混合物を基材とするが、種
類や性状は塗布すべき而の材質や、後に成形される場合
には成形時の伸度等も考慮して決められる。これ以外の
合成樹脂又は合成樹脂以外のもの(例えば天然樹脂)を
基材としたものや、これらとL記樹脂等とを組合わせた
ものでも良い。
The coating material of the present invention is based on, for example, acrylic resin, vinyl chloride resin, urethane resin, polyester resin, polyamide resin, or a mixture thereof, but the type and properties may vary depending on the material to be coated or the material to be molded later. In the case of molding, the elongation during molding is also taken into consideration. It is also possible to use other synthetic resins or materials other than synthetic resins (for example, natural resins) as a base material, or combinations of these and L resins.

コーティング材料には、必要に応じて有色顔料を入れ塗
料のかたちにしたり、シリカの如き艶消し助剤や1体質
顔料、安定剤、可塑剤、充Iri〜1等の補助剤を入れ
てもよい。
If necessary, the coating material may contain colored pigments to form a paint, or may contain auxiliary agents such as matting aids such as silica, unibody pigments, stabilizers, plasticizers, and fillers. .

基材は水または有機溶剤及び助剤など、それぞれの基材
に適切な溶剤、助剤で溶解されていることもできる。
The substrates can also be dissolved in water or with solvents and auxiliaries appropriate for the respective substrates, such as organic solvents and auxiliaries.

混入される18 mの長さ及び太さは、出来上がりのス
ェード調の外観及びト触り及び塗布方法にょり異なるが
、一般には長さ3ffi国以下、好ましくはlll11
以下、太さは300デニール以下、好ましくは10デニ
ール以下である。
The length and thickness of the 18 m mixed in will vary depending on the finished suede-like appearance and feel and application method, but generally the length is 3ffi or less, preferably lll11.
Hereinafter, the thickness is 300 deniers or less, preferably 10 deniers or less.

例えば、リバースロールコータ−法で塗布する場合 太さ 1.0〜10.0  デニール 長さ 0.5〜2  ■ が好ましい。For example, when applying with reverse roll coater method Thickness 1.0-10.0 denier Length 0.5-2 ■ is preferred.

FR雄の址は基材 100屯量部に対して 300重着
部以r、好ましくは基材100重着部に対して25〜1
001六部が良い。
The weight of FR male is 300 parts or more per 100 parts of base material, preferably 25 to 1 part per 100 parts of base material.
0016 parts is good.

繊維の材質は1例えばナイロン、ビニロン、ポリエステ
ル等の合成繊維であることができるが、これ以外の合し
&繊維或いは合成樹脂以外のものでも良い、mmは必要
に応じて着色しても良い。
The material of the fibers can be synthetic fibers such as nylon, vinylon, polyester, etc., but it may also be other combinations and fibers or materials other than synthetic resins.The fibers may be colored if necessary.

塗布する表面は、成形前のシート状の合成樹脂でも、成
形後の合成樹脂でも、或いは合成樹脂以外の木、金属、
ガラス、磁器等何んでも良く、又その形状も問わない。
The surface to be coated may be sheet-like synthetic resin before molding, synthetic resin after molding, or wood, metal, or other material other than synthetic resin.
It can be made of glass, porcelain, etc., and its shape does not matter.

塗布は、場合により塗布すべき表面を予め処理してから
、コーチづング材料をそのまま、溶剤などに溶解されて
いない場合には1水または有機溶剤及び助剤など、それ
ぞれの基材に適切な溶剤。
Application may be carried out by pre-treating the surface to be coated, and then using the coating material as is or, if not dissolved in a solvent, in a suitable solution for each substrate, such as 1 water or an organic solvent and an auxiliary agent. solvent.

助剤で溶解したり、希釈して刷毛、或いはリバースロー
ルコータ−を用いて若しくはその他の’Ix Ax方法
で行うことが出来る。
It can be applied by dissolving or diluting with an auxiliary agent and using a brush or reverse roll coater, or by other 'Ix Ax methods.

塗7σ礒は、塗布する個所及び表[nlの材質等で異な
るが、例えば、溶剤で溶解する前の状態でlモ方メート
ル当り数十g7″7全数百g、好ましくは、20〜to
o lであることができる。必要により、プラ・イマー
等を塗ってからコーティング材料ヲ塗っても良い。
The amount of coating 7σ varies depending on the area to be applied and the material of the material, but for example, before dissolving with a solvent, the amount is several tens of grams per meter, preferably several hundred grams.
It can be o l. If necessary, the coating material may be applied after applying a primer or primer.

乾燥方法は、自然乾燥でも、加熱乾燥でも如何なる方法
でも良い、乾爆後、ざらに毛羽tてを施すと、外観、風
合いがさらに良くなる。
The drying method may be natural drying or heat drying, or any other method.If the material is fluffed after dry blasting, the appearance and texture will be even better.

毛朋党ては、針AJ、サントペーパー等、塗布された表
面の形状及び犬ぎさに応じて適宜の方法を用いうる。
An appropriate method can be used depending on the shape and hardness of the coated surface, such as needle AJ or sandpaper.

実施例 I PVC(VYHH)11    l OOMEK(メチ
hzチhケトン)        150トルエン  
       150 DOP(ジすクナルプタレート)lO 顔料 (Δ−4シブラック)            
    5安定剤(Cd−Ba )        3
ビニロン短繊維?)25 1〉ユニオンカーバイト 社’JJ   塩化ヒニル樹
脂71 :jQデニール、  1.0 m箇溶解条件 オートクレーブ中で70°C4時間加温し溶解、分散さ
せた。
Example I PVC (VYHH) 11 l OOMEK (methyhzthihketone) 150 toluene
150 DOP (dicunal ptalate) lO pigment (Δ-4 siblack)
5 Stabilizer (Cd-Ba) 3
Vinylon staple fiber? )25 1>Union Carbide Co.'JJ Hinyl Chloride Resin 71: jQ denier, 1.0 m dissolution conditions Dissolved and dispersed by heating at 70°C for 4 hours in an autoclave.

」1記のコーティング材料を、厚さl 11mの軟質P
vCシートに、リバースロールローターで塗布した。1
30℃で3分間加熱して乾燥した結果、スェード調のシ
ートが得られた。このシートを1通常のごとく成形した
が、ヒビわれたり、ムラになったりすることもなく、外
観、−ト触りとも良(lrであった。また、このソート
をサントペーパーでt朋党てしたら、外観、風合いとも
さらに良好なスェード調のソートが得られた。
”The coating material described in item 1 was coated with a soft P coated with a thickness of
It was applied to the vC sheet using a reverse roll rotor. 1
As a result of heating and drying at 30° C. for 3 minutes, a suede-like sheet was obtained. This sheet was molded as usual, but there were no cracks or unevenness, and the appearance and feel were good. A suede-like sorting with even better appearance and texture was obtained.

実施例 2 アクリル樹脂11      100 MEK           150 トルエン         150 シリカ          10 顔料 (カーボンブラック)            
    5ビニロン短繊維2)25 1)MMA−EA共重合体、分子は 8万(70:30
) 712.0デニール、  1.011n溶解条件 オートクレーブ中で80℃ 6時間加温し溶解、分散さ
せた。
Example 2 Acrylic resin 11 100 MEK 150 Toluene 150 Silica 10 Pigment (carbon black)
5 Vinylon staple fiber 2) 25 1) MMA-EA copolymer, molecule is 80,000 (70:30)
) 712.0 denier, 1.011n dissolution conditions: Dissolved and dispersed by heating in an autoclave at 80°C for 6 hours.

L記のコーティング材料を、厚さ1II11の軟質PV
Cシートに、す/゛・−スロールローターで塗11した
。130°Cで3分間加熱して乾燥した結果、スェード
調のソートが得られた。このシートを5通常のこと〈成
形したが、ヒビわれたり、ムラになったりすることもな
く、外観、手触りとも良好であった。また、このシート
をサンドペーパーテ且朋党てしたら、外観、風合いとも
さらに良好なスェード調のシートが得られた。
The coating material listed in L is coated with soft PV having a thickness of 1II11.
Coating was carried out on C sheet using a S/゛・-throttle rotor. As a result of drying by heating at 130°C for 3 minutes, a suede-like sort was obtained. This sheet was molded in the usual way, but it did not crack or become uneven, and had a good appearance and feel. Furthermore, when this sheet was sandpapered, a suede-like sheet with even better appearance and texture was obtained.

従来品 PVC(VYHH)       60アクリル樹脂(
MMA−EA)  40MEK           
 150トルエン          150 シリカ           30 顔料 (h−5シブラツク)            
      5溶解条件 オートクレーブ中で80℃ 6時間加温し溶解、分散さ
せた。
Conventional product PVC (VYHH) 60 Acrylic resin (
MMA-EA) 40MEK
150 Toluene 150 Silica 30 Pigment (h-5 Shibrak)
5. Dissolution Conditions The mixture was heated in an autoclave at 80° C. for 6 hours to dissolve and disperse.

上−記のコーディング材料を、厚さl mmの軟質Pv
Cシートに、リバースロールローターで塗!■1した。
The above-mentioned coating material is coated with a soft Pv having a thickness of l mm.
Paint on C sheet with a reverse roll rotor! ■I did 1.

130℃で3分間加熱して乾燥した。It was dried by heating at 130° C. for 3 minutes.

実施例1.2のものと、従来品との防眩性を反射率で比
較測定し、次の結果を得た。
The anti-glare properties of Example 1.2 and the conventional product were compared and measured in terms of reflectance, and the following results were obtained.

daxメ−q−角度   実施例    従来品(投光
)(受光)l   2 70    80      0.3    Q、4 
      4.5Go     80      0
.1   0.2       3.550    [
100,00,02,040i30      0.0
   0.0       0.530     [1
00,00,00,220600,00,00,0 測定)Ill  Glass Meter TCニー1
080  (東京主色製)発明の効果 本発明のコーティング材料は、成形萌のシート状の合成
樹脂でも、成形後の合成樹脂でも、或いは合成樹脂以外
の木、全屈、ガラス、磁器笠何んでもその表面をスェー
ド調にするのに用いることができ、出来たスェード調表
面は、防眩性、外観、手触りがきわめて良好で、成形し
てもヒビわれたり、ムラになったりすることもないきわ
めて優れたものである。
dax me-q-angle Example Conventional product (light emission) (light reception) l 2 70 80 0.3 Q, 4
4.5 Go 80 0
.. 1 0.2 3.550 [
100,00,02,040i30 0.0
0.0 0.530 [1
00,00,00,220600,00,00,0 Measurement) Ill Glass Meter TC knee 1
080 (Manufactured by Tokyo Shushoku) Effects of the Invention The coating material of the present invention can be applied to sheet-shaped synthetic resin in molded form, synthetic resin after molding, or wood, full-length, glass, porcelain shade, etc. other than synthetic resin. However, it can be used to create a suede-like surface, and the resulting suede-like surface has excellent anti-glare properties, appearance, and feel, and does not crack or become uneven even when molded. It is extremely excellent.

Claims (14)

【特許請求の範囲】[Claims] (1)繊維を混入してなる、物の表面をスエード調にす
る為に用いられるコーティング材料
(1) Coating material mixed with fibers and used to make the surface of objects look like suede
(2)基材が合成樹脂である、特許請求の範囲第1項記
載の物の表面をスエード調にする為に用いられるコーテ
ィング材料。
(2) A coating material used to give a suede-like surface to a product according to claim 1, wherein the base material is a synthetic resin.
(3)基材が、アクリル樹脂、塩化ビニル樹脂、ウレタ
ン樹脂、ポリエステル樹脂、ポリアミド樹脂、或いはこ
れらの混合物である、特許請求の範囲第2項記載の物の
表面をスエード調にする為に用いられるコーティング材
料。
(3) Used to give a suede-like surface to the product according to claim 2, wherein the base material is acrylic resin, vinyl chloride resin, urethane resin, polyester resin, polyamide resin, or a mixture thereof. coating material.
(4)基材が合成樹脂以外のものである、特許請求の範
囲第1項記載の物の表面をスエード調にする為に用いら
れるコーティング材料。
(4) A coating material used to give a suede-like surface to a product according to claim 1, wherein the base material is other than a synthetic resin.
(5)基材が合成樹脂以外のものと、アクリル樹脂、塩
化ビニル樹脂、ウレタン樹脂、ポリエステル樹脂、ポリ
アミド樹脂、或いはこれらの混合物とを組合わせもので
ある、特許請求の範囲第1項記載の物の表面をスエード
調にする為に用いられるコーティング材料。
(5) The base material according to claim 1, wherein the base material is a combination of a material other than a synthetic resin and an acrylic resin, a vinyl chloride resin, a urethane resin, a polyester resin, a polyamide resin, or a mixture thereof. A coating material used to make the surface of objects look like suede.
(6)繊維が短繊維である、特許請求の範囲第1項記載
の物の表面をスエード調にする為に用いられるコーティ
ング材料。
(6) A coating material used to give a suede-like surface to a product according to claim 1, wherein the fibers are short fibers.
(7)繊維が合成繊維である、特許請求の範囲第1又は
6項記載の物の表面をスエード調にする為に用いられる
コーティング材料。
(7) A coating material used to give a suede-like surface to a product according to claim 1 or 6, wherein the fibers are synthetic fibers.
(8)繊維が合成繊維以外の繊維である、特許請求の範
囲第1又は6項記載の物の表面をスエード調にする為に
用いられるコーティング材料。
(8) A coating material used to give a suede-like surface to a product according to claim 1 or 6, wherein the fibers are fibers other than synthetic fibers.
(9)繊維が長さ3mm以下、太さは300デニール以
下である、特許請求の範囲第1又は6〜8項のいずれか
一つに記載の物の表面をスエード調にする為に用いられ
るコーティング材料。
(9) Used to give a suede-like surface to the product according to any one of claims 1 or 6 to 8, wherein the fibers have a length of 3 mm or less and a thickness of 300 denier or less. coating material.
(10)繊維が長さ1mm以下、太さは10デニール以
下である、特許請求の範囲第9項記載の物の表面をスエ
ード調にする為に用いられるコーティング材料。
(10) A coating material used to give a suede-like surface to a product according to claim 9, wherein the fibers have a length of 1 mm or less and a thickness of 10 denier or less.
(11)繊維の量が基材100重量部に対して300重
量部以下である、特許請求の範囲第1項記載の物の表面
をスエード調にする為に用いられるコーティング材料。
(11) A coating material used to give a suede-like surface to a product according to claim 1, wherein the amount of fiber is 300 parts by weight or less based on 100 parts by weight of the base material.
(12)繊維の量が基材100重量部に対して25〜1
00重量部である、特許請求の範囲第1項記載の物の表
面をスエード調にする為に用いられるコーティング材料
(12) The amount of fiber is 25 to 1 per 100 parts by weight of the base material.
00 parts by weight of a coating material used for making the surface of the article according to claim 1 suede-like.
(13)繊維の他に顔料、安定剤、可塑剤、充填剤等の
補助剤を混入してなる、特許請求の範囲第1項記載の物
の表面をスエード調にする為に用いられるコーティング
材料。
(13) A coating material used to make the surface of the article described in claim 1 suede-like, which is made by mixing auxiliary agents such as pigments, stabilizers, plasticizers, and fillers in addition to fibers. .
(14)基材が水または有機溶剤及び助剤で溶解されて
いる、特許請求の範囲第1項記載の物の表面をスエード
調にする為に用いられるコーティング材料。
(14) A coating material used to give a suede-like surface to a product according to claim 1, wherein the base material is dissolved in water or an organic solvent and an auxiliary agent.
JP12342686A 1986-05-30 1986-05-30 Coating material for use to impart suede-like finish to surface of object Pending JPS62280272A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12342686A JPS62280272A (en) 1986-05-30 1986-05-30 Coating material for use to impart suede-like finish to surface of object

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12342686A JPS62280272A (en) 1986-05-30 1986-05-30 Coating material for use to impart suede-like finish to surface of object

Publications (1)

Publication Number Publication Date
JPS62280272A true JPS62280272A (en) 1987-12-05

Family

ID=14860267

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12342686A Pending JPS62280272A (en) 1986-05-30 1986-05-30 Coating material for use to impart suede-like finish to surface of object

Country Status (1)

Country Link
JP (1) JPS62280272A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3928423A1 (en) * 1988-11-15 1990-05-17 Mikasa Paint Kk COATING MATERIAL FOR MEDIATING THE RECEPTION OF SUEDE AND PROCESS FOR APPLYING THE COATING MATERIAL
DE4019990A1 (en) * 1990-01-31 1991-08-01 Mikasa Paint Co Coating giving feel of doe-skin - contg. short fibres, small beads, solvent and carrier bonding fibres and beads to surface
JPH0392791U (en) * 1990-01-10 1991-09-20

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3928423A1 (en) * 1988-11-15 1990-05-17 Mikasa Paint Kk COATING MATERIAL FOR MEDIATING THE RECEPTION OF SUEDE AND PROCESS FOR APPLYING THE COATING MATERIAL
JPH02133472A (en) * 1988-11-15 1990-05-22 Mikasa Paint Kk Suede-like coating material and application thereof
JPH0392791U (en) * 1990-01-10 1991-09-20
DE4019990A1 (en) * 1990-01-31 1991-08-01 Mikasa Paint Co Coating giving feel of doe-skin - contg. short fibres, small beads, solvent and carrier bonding fibres and beads to surface
JPH03227377A (en) * 1990-01-31 1991-10-08 Mikasa Paint Kk Paint having suede-like feeling

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