JPS62263293A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPS62263293A JPS62263293A JP61106667A JP10666786A JPS62263293A JP S62263293 A JPS62263293 A JP S62263293A JP 61106667 A JP61106667 A JP 61106667A JP 10666786 A JP10666786 A JP 10666786A JP S62263293 A JPS62263293 A JP S62263293A
- Authority
- JP
- Japan
- Prior art keywords
- lactate
- ethoxylate
- phenol
- lactic acid
- ethylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 33
- 239000003599 detergent Substances 0.000 title description 23
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 83
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 56
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 39
- 238000004140 cleaning Methods 0.000 claims description 32
- 239000004310 lactic acid Substances 0.000 claims description 28
- 235000014655 lactic acid Nutrition 0.000 claims description 28
- 239000003054 catalyst Substances 0.000 claims description 27
- -1 alkali metal salt Chemical class 0.000 claims description 20
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims description 19
- 229940001447 lactate Drugs 0.000 claims description 19
- 239000004480 active ingredient Substances 0.000 claims description 16
- 239000003513 alkali Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical group C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- PHZLMBHDXVLRIX-UHFFFAOYSA-M potassium lactate Chemical group [K+].CC(O)C([O-])=O PHZLMBHDXVLRIX-UHFFFAOYSA-M 0.000 claims description 3
- 239000001521 potassium lactate Substances 0.000 claims description 3
- 235000011085 potassium lactate Nutrition 0.000 claims description 3
- 229960001304 potassium lactate Drugs 0.000 claims description 3
- 239000001540 sodium lactate Substances 0.000 claims description 3
- 235000011088 sodium lactate Nutrition 0.000 claims description 3
- 229940005581 sodium lactate Drugs 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical group CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 claims 1
- JYCQQPHGFMYQCF-UHFFFAOYSA-N 4-tert-Octylphenol monoethoxylate Chemical group CC(C)(C)CC(C)(C)C1=CC=C(OCCO)C=C1 JYCQQPHGFMYQCF-UHFFFAOYSA-N 0.000 claims 1
- 229920000847 nonoxynol Polymers 0.000 claims 1
- 229920002113 octoxynol Polymers 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 20
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 18
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 16
- 150000002989 phenols Chemical class 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 239000012459 cleaning agent Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 235000002639 sodium chloride Nutrition 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 229910015900 BF3 Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003752 hydrotrope Substances 0.000 description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical class C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- LMEWRZSPCQHBOB-UHFFFAOYSA-M silver;2-hydroxypropanoate Chemical compound [Ag+].CC(O)C([O-])=O LMEWRZSPCQHBOB-UHFFFAOYSA-M 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- YNVZDODIHZTHOZ-UHFFFAOYSA-K 2-hydroxypropanoate;iron(3+) Chemical compound [Fe+3].CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O YNVZDODIHZTHOZ-UHFFFAOYSA-K 0.000 description 1
- KSNGEYQWLMRSIR-UHFFFAOYSA-L 2-hydroxypropanoate;manganese(2+) Chemical compound [Mn+2].CC(O)C([O-])=O.CC(O)C([O-])=O KSNGEYQWLMRSIR-UHFFFAOYSA-L 0.000 description 1
- MIPSDSUWRUZGAB-UHFFFAOYSA-N 2-methyl-3,4-dioctylphenol Chemical compound CCCCCCCCC1=CC=C(O)C(C)=C1CCCCCCCC MIPSDSUWRUZGAB-UHFFFAOYSA-N 0.000 description 1
- CBQDTCDOVVBGMN-UHFFFAOYSA-N 2-methyl-3-octylphenol Chemical compound CCCCCCCCC1=CC=CC(O)=C1C CBQDTCDOVVBGMN-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-M 2-methylbenzenesulfonate Chemical compound CC1=CC=CC=C1S([O-])(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HORNXRXVQWOLPJ-UHFFFAOYSA-N 3-chlorophenol Chemical compound OC1=CC=CC(Cl)=C1 HORNXRXVQWOLPJ-UHFFFAOYSA-N 0.000 description 1
- QEVPNCHYTKOQMP-UHFFFAOYSA-N 3-octylphenol Chemical compound CCCCCCCCC1=CC=CC(O)=C1 QEVPNCHYTKOQMP-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- IZVFFXVYBHFIHY-SKCNUYALSA-N 5alpha-cholest-7-en-3beta-ol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@@H](CC[C@@]3([C@@H]([C@H](C)CCCC(C)C)CC[C@H]33)C)C3=CC[C@H]21 IZVFFXVYBHFIHY-SKCNUYALSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004251 Ammonium lactate Substances 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical class OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical class CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- CANRESZKMUPMAE-UHFFFAOYSA-L Zinc lactate Chemical compound [Zn+2].CC(O)C([O-])=O.CC(O)C([O-])=O CANRESZKMUPMAE-UHFFFAOYSA-L 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229940059265 ammonium lactate Drugs 0.000 description 1
- 235000019286 ammonium lactate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- RZOBLYBZQXQGFY-HSHFZTNMSA-N azanium;(2r)-2-hydroxypropanoate Chemical compound [NH4+].C[C@@H](O)C([O-])=O RZOBLYBZQXQGFY-HSHFZTNMSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- HLKMEIITONDPGG-UHFFFAOYSA-L barium(2+);2-hydroxypropanoate Chemical compound [Ba+2].CC(O)C([O-])=O.CC(O)C([O-])=O HLKMEIITONDPGG-UHFFFAOYSA-L 0.000 description 1
- 125000005501 benzalkonium group Chemical class 0.000 description 1
- 229950011260 betanaphthol Drugs 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- XHRPOTDGOASDJS-UHFFFAOYSA-N cholesterol n-octadecanoate Natural products C12CCC3(C)C(C(C)CCCC(C)C)CCC3C2CC=C2C1(C)CCC(OC(=O)CCCCCCCCCCCCCCCCC)C2 XHRPOTDGOASDJS-UHFFFAOYSA-N 0.000 description 1
- XHRPOTDGOASDJS-XNTGVSEISA-N cholesteryl stearate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCCCCCCCCCCCC)C1 XHRPOTDGOASDJS-XNTGVSEISA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000003893 lactate salts Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- GKQWYZBANWAFMQ-UHFFFAOYSA-M lithium;2-hydroxypropanoate Chemical compound [Li+].CC(O)C([O-])=O GKQWYZBANWAFMQ-UHFFFAOYSA-M 0.000 description 1
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- OVGXLJDWSLQDRT-UHFFFAOYSA-L magnesium lactate Chemical compound [Mg+2].CC(O)C([O-])=O.CC(O)C([O-])=O OVGXLJDWSLQDRT-UHFFFAOYSA-L 0.000 description 1
- 239000000626 magnesium lactate Substances 0.000 description 1
- 235000015229 magnesium lactate Nutrition 0.000 description 1
- 229960004658 magnesium lactate Drugs 0.000 description 1
- 229940100630 metacresol Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 239000004306 orthophenyl phenol Substances 0.000 description 1
- 229940090668 parachlorophenol Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229940117972 triolein Drugs 0.000 description 1
- VXYADVIJALMOEQ-UHFFFAOYSA-K tris(lactato)aluminium Chemical compound CC(O)C(=O)O[Al](OC(=O)C(C)O)OC(=O)C(C)O VXYADVIJALMOEQ-UHFFFAOYSA-K 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- 239000011576 zinc lactate Substances 0.000 description 1
- 235000000193 zinc lactate Nutrition 0.000 description 1
- 229940050168 zinc lactate Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は低臭気性でしかも経時変化による看臭が極めて
少ない洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a cleaning composition that has low odor and exhibits very little odor over time.
さらに詳しくは改良されたフェノール類とエチレンオキ
シドとを反応させて得られるフェノール類エトキシレー
トに特定の中和剤を添加して得られる経時変化が極めて
少ない安定化したフェノール類エトキシレートを洗浄剤
組成物の基材として使用することに関するものである。More specifically, a detergent composition is prepared by adding a specific neutralizing agent to a phenol ethoxylate obtained by reacting an improved phenol with ethylene oxide. It relates to use as a base material for.
フェノール類エトキシレートは洗浄剤組成物の主要洗浄
活性成分として広い分野で使用される。Phenolic ethoxylates are used in a wide range of fields as the main cleaning active ingredient in cleaning compositions.
たとえば繊維、金属、皮革、自動車、住居用等の各種洗
浄剤に使用することができる。For example, it can be used in various cleaning agents for textiles, metals, leather, automobiles, homes, etc.
これらの洗浄剤にはその用途に応じて種々の香料が添加
されるのが一般的である。しかし主要洗浄活性成分であ
るフェノール類エトキシレートの臭気に問題がある場合
１、香料の本来の作用効果が発揮できないことがある。Generally, various fragrances are added to these cleaning agents depending on their use. However, if there is a problem with the odor of phenol ethoxylates, which are the main cleaning active ingredients, the fragrance may not be able to exert its original effects.
本発明は乳酸および／または乳酸塩を含有するフェノー
ル類エトキシレートを洗浄剤原料として使用することに
より低臭気性でしかも経時変化による着臭が極めて少な
い高品質の洗浄剤を提供するものである。The present invention uses phenolic ethoxylate containing lactic acid and/or lactate as a cleaning agent raw material to provide a high-quality cleaning agent that is low in odor and exhibits extremely little odor over time.
（従来の技術）
洗浄剤原料として、洗浄力、易無隣化性、耐硬水性、相
溶性、易溶解性、低温安定性（耐寒性）泡切れ、すすぎ
性という面で特にフェノール類エトキシレートが使用さ
れている。一般にフェノール類のエトキシ化物は、水酸
化ナトリウム、水酸化カリウム、ナトリウムアルコキシ
ド等のアルカリ触媒または三フフ化ホウ素、三フッ化ホ
ウ素−諸体、五塩化アンチモン、四塩化スズ等の酸性触
媒の存在下、フェノール類にエチレンオキシドを付加し
て製造される。(Prior art) Phenol ethoxylates are particularly useful as raw materials for detergents in terms of detergency, ease of adhesion, hard water resistance, compatibility, easy solubility, low temperature stability (cold resistance), foam removal, and rinsability. is used. Generally, ethoxylated phenols are prepared in the presence of an alkaline catalyst such as sodium hydroxide, potassium hydroxide, or sodium alkoxide, or an acidic catalyst such as boron trifluoride, boron trifluoride, antimony pentachloride, or tin tetrachloride. , produced by adding ethylene oxide to phenols.
このような方法で得られたフェノール類エトキシレート
は未反応のフェノール類を含む外に、触媒、アルデヒド
類、遊離酸類、エステル類、過酸化物類およびその他の
悪臭あるいは着色の原因となるような不純物を微量含有
している。このアルデヒド類、遊離酸類、エステル類、
過酸化物等の不純物はアルカリ水溶液による洗浄、ケン
化、蒸留により、又アルカリ触媒は通常、硫酸、リン酸
等の鉱酸あるいは酢酸等を添加して中和処理して精製さ
れる。このようにして得られたフェノール類エトキシレ
ー トはこの他にも悪臭および着色の原因となる不純物
があって、経時変化と共に悪臭を発生する問題がある。Phenol ethoxylates obtained by this method contain not only unreacted phenols but also catalysts, aldehydes, free acids, esters, peroxides, and other substances that may cause odor or color. Contains trace amounts of impurities. These aldehydes, free acids, esters,
Impurities such as peroxides are purified by washing with an aqueous alkaline solution, saponification, and distillation, and alkaline catalysts are usually neutralized by adding mineral acids such as sulfuric acid and phosphoric acid, or acetic acid. Phenol ethoxylates obtained in this manner contain other impurities that cause bad odor and coloration, and there is a problem in that they generate bad odor as they change over time.
また、経時変化したフェノール類エトキシレートに三酸
化硫黄、り０ルスルホン酸等の硫酸化剤で硫酸化した場
合には生成した硫酸化物の色相が著しく悪化するという
問題がある。以上のように従来技術で得られたフェノー
ル類エトキシレートを用いて洗浄剤の製品にした場合、
製品の臭気、製品の品質および劣化の原因となる問題が
あり好ましくない。Furthermore, when phenol ethoxylates that have changed over time are sulfated with a sulfating agent such as sulfur trioxide or sulfonic acid, there is a problem in that the hue of the sulfates produced is significantly deteriorated. As described above, when phenolic ethoxylates obtained by conventional techniques are used to make detergent products,
It is undesirable because it causes problems such as product odor, product quality, and deterioration.
特にフェノール類とエチレンオキシドとを反応させてフ
ェノール類エトキシレートを製造する際に使用される水
酸化ナトリウム、水酸化カリウム、ナトリウムアルコキ
シド等のアルカリ触媒は通常、硫酸、リン酸等の鉱酸あ
るいは酢酸のごとき中和剤を添加して中和処理して精製
されるが、この従来の中和剤を使用したフェノール類エ
トキシレートを洗浄剤原料として使用した場合には配合
時点ですでに臭気があると共に、経時変化により臭気が
発生するため臭気の少ない洗浄剤を製造する上で大きな
問題であった。In particular, alkaline catalysts such as sodium hydroxide, potassium hydroxide, and sodium alkoxide used when producing phenol ethoxylates by reacting phenols with ethylene oxide are usually mixed with mineral acids such as sulfuric acid, phosphoric acid, or acetic acid. However, when phenol ethoxylates containing conventional neutralizing agents are used as raw materials for detergents, they already have an odor and This was a big problem in producing a cleaning agent with little odor because it generates odor due to changes over time.
（発明が解決しようとする問題点）
本発明の目的は、フェノール類とエチレンオキシドとを
反応させて得られたフェノール類エトキシレートを用い
て洗浄剤の洗浄活性成分としたときに、洗浄剤配合時点
での臭気が少なく、なおかつ経時変化による着臭も極め
て少ない洗浄剤を提供することにある。(Problems to be Solved by the Invention) It is an object of the present invention to provide a solution that can be used at the time of formulation of a detergent when a phenol ethoxylate obtained by reacting phenols with ethylene oxide is used as a cleaning active ingredient of a detergent. To provide a cleaning agent which has little odor and also has very little odor due to change over time.
（問題点を解決するための手段）
本発明はフェノール類エトキシレートを洗浄活性成分と
して含有する洗浄剤組成物において、乳酸および／また
は乳酸塩を含有するフェノール類エトキシレートがフェ
ノール類とエチレンオキシドとをアルカリ触媒の存在下
に反応させて得られる未中和のフェノール類エトキシレ
ートに乳酸および／または乳酸塩を添加して得られるフ
ェノール類エトキシレートであるか、フェノール類と工
チレンオキシドとをアルカリ触媒の存在下に反応させて
得られる未中和のフェノール類エトキシレートの触媒を
中和した状態または口過によって触媒を除去したフェノ
ール類エトキシレートに乳酸および／または乳酸塩を添
加して得られるフェノール類エトキシレ−（を含有する
洗浄剤組成物に関するものである。(Means for Solving the Problems) The present invention provides a cleaning composition containing phenolic ethoxylates as a cleaning active ingredient, in which the phenolic ethoxylates containing lactic acid and/or lactate combine phenols and ethylene oxide. Phenol ethoxylate is obtained by adding lactic acid and/or lactate to unneutralized phenol ethoxylate obtained by reacting in the presence of an alkali catalyst, or phenol and engineered ethylene oxide are reacted in the presence of an alkali catalyst. Phenol obtained by adding lactic acid and/or lactate to phenol ethoxylate in which the catalyst has been neutralized or from which the catalyst has been removed by mouth filtration. The present invention relates to a cleaning composition containing ethoxylates.
本発明で使用する乳酸は醗酵法および合成法いずれの方
法で製造されたものでもよく、また乳酸の純度は特に限
定するものでないが通常市販されている工業用、醸造用
、食品添加用のいずれにも使用できる。The lactic acid used in the present invention may be produced by either a fermentation method or a synthetic method, and the purity of the lactic acid is not particularly limited. It can also be used for
本発明で使用する乳酸塩は乳酸ナトリウム、乳酸カリウ
ム、乳酸リチウム等の乳酸のアルカリ金属塩、乳酸カル
シウム、乳酸マグネシウム、乳酸バリウム等の乳酸のア
ルカリ土類金属塩、乳酸アルミニウム、乳酸亜鉛、乳酸
銀、乳酸銀、乳酸鉄、乳酸マンガン、乳酸アンモニウム
等があり、特に乳酸ナトリウム、乳酸カリウムが好まし
い。The lactate salts used in the present invention include alkali metal salts of lactic acid such as sodium lactate, potassium lactate, and lithium lactate, alkaline earth metal salts of lactic acid such as calcium lactate, magnesium lactate, and barium lactate, aluminum lactate, zinc lactate, and silver lactate. , silver lactate, iron lactate, manganese lactate, ammonium lactate, etc., and sodium lactate and potassium lactate are particularly preferred.
本発明で使用する乳酸および／または乳酸塩の添加量は
フェノール類エトキシレート１００重量部に対して５〜
０．００１ｆｆｌｆｆｉ部、好ましくは１〜０．０５重
量部である。添加に際し、水溶液のｐＨは４〜９好まし
くは、５〜７の範囲にすることが好ましい。The amount of lactic acid and/or lactate used in the present invention is 5 to 5 parts by weight per 100 parts by weight of phenolic ethoxylate.
0.001fflffi part, preferably 1 to 0.05 part by weight. Upon addition, the pH of the aqueous solution is preferably in the range of 4 to 9, preferably 5 to 7.
本発明の乳酸および／または乳酸塩の添加方法はフェノ
ール類とエチレンオキシドとを水酸化ナトリウム、水酸
化カリウムおよびナトリウムアルコキシド等のアルカリ
触媒の存在下に反応させて得られる未中和のフェノール
類エトキシレートに乳酸を添加する方法、あるいは口過
等の公知の方法によって触媒を除去したフェノール類エ
トキシレートに乳酸を添加する方法がある。乳酸および
／または乳酸塩の添加はフェノール類エトキシレートに
乳酸および／または乳酸塩をそのまま、または溶液にし
て添加し３０分程度撹拌し、完全に溶解させるのが好ま
しい。The method of adding lactic acid and/or lactate of the present invention is an unneutralized phenol ethoxylate obtained by reacting phenols and ethylene oxide in the presence of an alkali catalyst such as sodium hydroxide, potassium hydroxide, and sodium alkoxide. There is a method of adding lactic acid to the phenol ethoxylate, or a method of adding lactic acid to the phenol ethoxylate from which the catalyst has been removed by a known method such as filtration. When adding lactic acid and/or lactate, it is preferable to add lactic acid and/or lactate to phenol ethoxylate as is or as a solution and stir for about 30 minutes to completely dissolve.
本発明で用いられるフェノール類エトキシレートは前記
フェノール類に水酸化ナトリウム、水酸化カリウムおよ
びナトリウムアルコキシド等のアルカリ触媒、または三
フッ化ホウ素、三フフ化ホウ素−錯体、五塩化アンチモ
ン、四塩化スズ等の酸性触媒の存在下エチレンオキシド
を付加反応して得られたものが挙げられる。The phenolic ethoxylates used in the present invention include the above phenols and an alkali catalyst such as sodium hydroxide, potassium hydroxide, and sodium alkoxide, or boron trifluoride, boron trifluoride-complex, antimony pentachloride, tin tetrachloride, etc. Examples include those obtained by addition reaction of ethylene oxide in the presence of an acidic catalyst.
本発明のフェノール類とエチレンオキシドとを反応させ
て得られるフェノール類エトキシレートの反応温度は、
５０〜２００”Ｃ１特に１２０〜１８０℃の温度範囲が
好ましい。The reaction temperature of the phenol ethoxylate obtained by reacting the phenols and ethylene oxide of the present invention is:
A temperature range of 50 to 200"C1, particularly 120 to 180"C, is preferred.
本発明のフェノール類とエチレンオキシドとを反応させ
て得られるフェノール類エトキシレートの反応圧力は、
Ｏ〜３０ Ｋｇ ／ ｔ：ｄ Ｇ 、特に０．５〜２０
Ｋｇ ／ ｃｔｄ Ｇの圧力範囲が好ましい。The reaction pressure of the phenol ethoxylate obtained by reacting the phenols and ethylene oxide of the present invention is:
O~30 Kg/t:dG, especially 0.5~20
A pressure range of Kg/ctd G is preferred.
フェノール類に対しエチレンオキシドの付加はフェノー
ル１モルに対しエチレンオキシドが０゜１〜１００モル
、好ましくは１〜５０モルの範囲である。The addition of ethylene oxide to phenol is in the range of 0.1 to 100 mol, preferably 1 to 50 mol, per 1 mol of phenol.
フェノール類としは、フェノール、ビスフェノール、オ
ルトクレゾール、メタクレゾール、バラクレゾール、２
．４−ジアルキルフェノール、２゜５−ジアルキルフェ
ノール、２，６−ジアルキルフェノール、ノニルフェノ
ール、オクチルフェノール、オルソクロロフェノール、
メタクロロフェノール、パラクロロフェノール、バラメ
トキシフェノール、バラアミノフェノール、オルソフェ
ニールフェノール、ｔ−ブチル−バラクレゾール、ヒド
ロキノン、カテコール、レゾルシン、ピロガロール、１
−ナフトール、２−ナフトール、４−クロｏ−２−二ト
ロフエノール、バラ−ｔ−ブチルフェノール、オルソア
ミノフェノール、ドデシルフェノール、オクチルクレゾ
ール、ジオクチルクレゾール、ジノニルフェノール、２
．５−ジクロロフェノール等がある。Phenols include phenol, bisphenol, orthocresol, metacresol, valacresol, 2
．． 4-dialkylphenol, 2゜5-dialkylphenol, 2,6-dialkylphenol, nonylphenol, octylphenol, orthochlorophenol,
Metachlorophenol, parachlorophenol, paramethoxyphenol, paraaminophenol, orthophenylphenol, t-butyl-valacresol, hydroquinone, catechol, resorcinol, pyrogallol, 1
- Naphthol, 2-naphthol, 4-chloro-o-2-nitrophenol, rose-t-butylphenol, orthoaminophenol, dodecylphenol, octylcresol, dioctylcresol, dinonylphenol, 2
．． Examples include 5-dichlorophenol.
本発明のフェノール類エトキシレートを洗浄活性成分と
して含有する洗浄剤組成物において、乳酸および／また
は乳酸塩を含有するフェノール類エトキシレートの他に
種々の用途に応じて配合される種々の添加剤たとえば活
性剤、ハイドロトロープ剤、起泡剤、泡安定剤、制泡剤
、増粘剤、低粘剤、ビルダー、再汚染防止剤、漂白剤、
香料、蛍光増白剤、香料、染料増白剤等を配合組み合せ
ることにより極めて良好なるパーホーマンスを有する洗
浄剤組成物が１！？られることがわかり本発明を完成し
たものである。In the cleaning composition containing the phenolic ethoxylate of the present invention as a cleaning active ingredient, in addition to the phenolic ethoxylate containing lactic acid and/or lactate, various additives may be added depending on various uses, such as Activators, hydrotropes, foaming agents, foam stabilizers, antifoaming agents, thickeners, thinners, builders, anti-resoiling agents, bleaching agents,
By combining fragrances, optical brighteners, perfumes, dye brighteners, etc., we have created a cleaning composition that has extremely good performance! ? As a result, the present invention has been completed.
本発明のフェノール類エトキシレ−１・を洗浄活性成分
として含有する洗浄剤組成物において、乳酸および／ま
たは乳酸塩を含有するフェノール類エトキシレートの洗
浄剤組成物の含有割合は１〜９ Ｑ ｔｆ＞量％が好ま
しい。In the cleaning composition containing phenol ethoxylate-1 as a cleaning active ingredient of the present invention, the content ratio of the phenol ethoxylate containing lactic acid and/or lactate is 1 to 9 Q tf> Amount % is preferred.
本発明の液体洗剤組成物の用途による特徴たとえば起泡
、制泡、洗浄の相乗効果の効果的な活性剤としてアルキ
ルベンゼンスルホン１％ｌ ｆ’、ｉ類、アルキルエー
テルカルボン酸塩、脂肪酸石鹸類、α−オレフィンスル
ホン酸塩類、高級アルコール硫酸エステル塩類、アルキ
ルエーテル硫酸塩類、脂肪酸アルキロールアマイドの硫
酸エステル塩類、アルキルニーデルリン酸エステル塩、
アルキルリン酸エステル塩類、Ｎ−アシルメチルタウリ
ン、Ｎ−アシルアミノ酸塩類、アシル化ペプチド類、ア
ルキルアルカノールアマイド類、脂肪族アミン塩類、脂
肪族４級アンモニウム塩類、ベンザルコニウム塩類、イ
ミダゾリニウム塩類、カルボキシベタイン型、アミノカ
ルボン酸塩類、イミダゾリニウムベタイン類、アルキル
アミンオキサイド類、ポリオキシエチレンアルキルアミ
ン類、脂肪酸アルカノールアミド類等の１種または二種
以上の混合物を０〜３０重ω％添加がするのが好ましい
。Characteristics of the liquid detergent composition of the present invention according to its use, such as alkylbenzenesulfone 1% l f', group I, alkyl ether carboxylates, fatty acid soaps, as effective activators for foaming, antifoaming, and cleaning synergistic effects α-olefin sulfonates, higher alcohol sulfate ester salts, alkyl ether sulfates, fatty acid alkylolamide sulfate ester salts, alkyl needle phosphate ester salts,
Alkyl phosphate ester salts, N-acylmethyl taurine, N-acyl amino acid salts, acylated peptides, alkyl alkanolamides, aliphatic amine salts, aliphatic quaternary ammonium salts, benzalkonium salts, imidazolinium salts, One or a mixture of two or more of carboxybetaine types, aminocarboxylic acid salts, imidazolinium betaines, alkylamine oxides, polyoxyethylene alkylamines, fatty acid alkanolamides, etc. can be added in an amount of 0 to 30 wt ω%. It is preferable to do so.
また、液体洗浄剤の可溶化剤（ハイドロトロープ）とし
ては、低級アルコール類、エチレングリコール類、プロ
ピレングリコール類、グリセリン、セルソルブ類、エタ
ノールアミン類、トルエンスルボン酸塩、キシレンスル
へホン酸塩、尿素から選ばれた一種または二種以上の混
合物を０〜１０損量％用いることができる。In addition, solubilizing agents (hydrotropes) for liquid cleaning agents include lower alcohols, ethylene glycols, propylene glycols, glycerin, cellosolves, ethanolamines, toluene sulfonate, xylene sulfonate, urea One or a mixture of two or more selected from can be used in an amount of 0 to 10% loss.
粘度調整剤としては、無機塩類たとえば塩化ナトリウム
、塩化カリウム、塩化マグネシウム、硫酸ナトリウム、
炭酸ナトリウム、ビロリン酸カリウムから選ばれた一種
または二種以上の混合物をＯ〜５唄橙％用いることがで
きる。As the viscosity modifier, inorganic salts such as sodium chloride, potassium chloride, magnesium chloride, sodium sulfate,
One or a mixture of two or more selected from sodium carbonate and potassium birophosphate can be used in an amount of 0 to 5%.
そして残部は水であるが特に脱イオン水または蒸留水が
好ましい。The remainder is water, with deionized water or distilled water being particularly preferred.
なお、腐敗を防止するために防腐剤、殺菌剤等を添加し
てもよい。さらにビルダー、再汚染防止剤、漂白剤、蛍
光剤、着色料、香料、酸化防止剤等の添加剤も使用でき
る。Note that preservatives, bactericides, etc. may be added to prevent spoilage. Furthermore, additives such as builders, anti-restaining agents, bleaching agents, fluorescent agents, colorants, fragrances, and antioxidants can also be used.
（作 用）
フェノール類とエヂレンオキシドとを反応させて得られ
たフェノール類エトキシレートに乳酸および／または乳
酸塩を含有させ、得られたフェノール類エトキシレート
を洗浄剤の基材としたとき、臭気の経時変化が極めて少
なくなる作用を発揮することがわかった。(Function) When phenol ethoxylate obtained by reacting phenol and edylene oxide contains lactic acid and/or lactate, and the obtained phenol ethoxylate is used as a base material for a cleaning agent, odor is reduced. It has been found that it exhibits an effect that significantly reduces changes over time.
（実 施 例）
以下、実施例をあげて、本発明の実施の態様を具体的に
例示して説明する。本発明はこれからの実施例に限定さ
れるものではない。(Example) Hereinafter, embodiments of the present invention will be specifically illustrated and explained by giving examples. The invention is not limited to the following embodiments.
実施例で行なった各試験方法は以下の通りである。The test methods used in the examples are as follows.
（１） 臭気
試料０．１ｄに活性炭処理を行なった無臭蒸留水１００
ａｅを加え温度５０℃にて標準品との一対比較法で判定
した。臭気の判定は次の通りとした。(1) 100% odorless distilled water treated with activated carbon on 0.1d odor sample
Ae was added to the sample at a temperature of 50°C, and the test was determined by a paired comparison method with a standard product. The odor was judged as follows.
５ ： 標準品と同様
４ ： 標準品よりかすかに臭気あり３ ： 標準
品よりやや臭気あり
２ ： 標準品より明らかに臭気あり１ ： 標準
品より非常に臭気が強い標準品
（Ａ） 実施例１〜３および比較例１〜３に対して、
経時変化していない実施例１の洗浄剤を標準品とした。5: Same as the standard product 4: Slightly more odor than the standard product 3: Slightly more odor than the standard product 2: Noticeably more odor than the standard product 1: Standard product with a much stronger odor than the standard product (A) Example 1 ~3 and Comparative Examples 1 to 3,
The cleaning agent of Example 1, which had not changed over time, was used as a standard product.
■洗浄力試験
（Ａ 法）
規定の濃度にした洗浄剤水溶液１１にＩＯＸＩＯｃｍの
人工汚染布６５％ポリエステル３５％綿ブロード布３枚
を入れ、ターボトメ−ター（回転数：１１００ｒｐ＞に
て洗浄した。■Cleaning Power Test (Method A) Three pieces of IOXIOcm artificially contaminated cloth (65% polyester, 35% cotton broadcloth) were placed in detergent aqueous solution 11 at a specified concentration and washed in a turbotometer (rotation speed: 1100 rpm).
（１）洗浄条件
洗浄剛製 度 ： ０．０６７ｗｔ％使用水
： 水道水
水温 ＝ ２５℃
洗浄時間 ： ５分間
すすぎ ： 水道水にて５分間
人工汚染布の汚垢組成
Ａ 有機質 （重量％）
ミリスチン酸 １６．７オレイン
酸 １６．７トリステアリン
１６．７トリオレイン
１６．７コレステロール
８．８ステアリン酸コレステロール
２．２パラフインロウ（ｍ、ｐ、５０〜５２℃）１１
．１スクワレン １１．１Ｂ
無機質
粘土 （関東ローム ２５０メツシ１通過）Ｃカーボン
カーボンブラック （２５０メツシュ通過）有機質４９
．７５重敞％、無機質４９．７５重分％、カーボン０．
５重量％を混合して汚垢とし、反射率が４５％±２％に
なるように精製白布を汚染した。(1) Cleaning conditions Cleaning strength: 0.067wt% water used
: Tap water temperature = 25℃ Washing time : Rinse for 5 minutes : Rinse with tap water for 5 minutes Stain composition of artificially contaminated cloth A Organic matter (wt%) Myristic acid 16.7 Oleic acid 16.7 Tristearin 16.7 Triolein
16.7 cholesterol
8.8 Cholesterol stearate
2.2 Paraffin wax (m, p, 50-52℃) 11
．． 1 Squalene 11.1B
Inorganic clay (Kanto loam 250 mesh 1 pass) C carbon carbon black (250 mesh passed) Organic matter 49
．． 75% by weight, inorganic 49.75% by weight, carbon 0.
5% by weight was mixed to form a stain, and purified white cloth was contaminated so that the reflectance was 45%±2%.
（３） 人工汚染布の洗浄率の算
出洗浄前の原布および洗浄前後人工汚染布の５３０ｍμ
における反射率を反射率
計（平沼産業製５ＰＲ−３型）にて測定し、次式によっ
て洗浄率（％）を算出した。(3) Calculation of cleaning rate of artificially contaminated cloth 530 mμ of original cloth before washing and artificially contaminated cloth before and after washing
The reflectance was measured using a reflectance meter (Model 5PR-3 manufactured by Hiranuma Sangyo), and the cleaning rate (%) was calculated using the following formula.
洗浄率（％’） ＝１００Ｘ 実施例 １ 温度計、圧力計、撹拌機を備えた容ｆｆ１ｌｏｏ。Cleaning rate (%’) = 100X Example 1 Capacity ff1loo equipped with thermometer, pressure gauge and stirrer.
ｍ１ステンレス製反応器にノニルフェノール（分子ｆｆ
１２２１’）２００ｇ、触媒として水酸化ナトリウム０
．６ｇ、エチレンオキシド４００Ｑを仕込み、温度１５
０℃、圧力６．０幻／ｉＧで反応させた。、得られたノ
ニルフェノールのエチレンオキシド平均１０モル付加物
に５０重量％乳酸水溶液２．７０を添加し、よく撹拌し
た。得られたノニルフェノールのエチレンオキシド平均
１０．０モル付加物（試料−１）を主要洗浄活性成分と
して含有する第１表の洗浄剤組成物を１４製し、臭気、
洗浄力の試験を行なった。結果は第１表に示す通りであ
った。Nonylphenol (molecule ff
1221') 200g, 0 sodium hydroxide as catalyst
．． 6g, prepare ethylene oxide 400Q, temperature 15
The reaction was carried out at 0°C and a pressure of 6.0 phantom/iG. 2.70% of a 50% by weight aqueous lactic acid solution was added to the obtained adduct of nonylphenol with 10 moles of ethylene oxide on average, and the mixture was thoroughly stirred. Fourteen cleaning compositions shown in Table 1 containing the obtained nonylphenol adduct with ethylene oxide (Sample-1) of 10.0 moles on average as the main cleaning active ingredient were prepared,
A detergency test was conducted. The results were as shown in Table 1.
比較例 １
温度計、圧力計、撹拌機を備えた容量１０００ｍ１ステ
ンレス製反応器にノニルフェノール（分子ｆｆ１２２１
）２００Ｇ、触媒として水酸化ナトリウム０．６ｑ１エ
チレンオキシド４００Ｑを仕込み、温度１５０℃、圧力
６．０Ｋｇ／ｃｉＧで反応させた。得られたノニルフェ
ノールのエチレンオキシド平均１０モル付加物に酢酸０
．９ｇを添加し、よく撹拌した。得られたノニルフェノ
ールのエチレンオキシド平均１０．０モル付加物（比較
試料−１）を主要洗浄活性成分として含有する第１表の
洗浄剤組成物を調製し、臭気、洗浄力の試験を行なった
。結果は第１表に示す通りであった。Comparative Example 1 Nonylphenol (molecules ff1221
) 200G, 0.6ql of sodium hydroxide and 400Q of ethylene oxide as a catalyst were charged, and the reaction was carried out at a temperature of 150°C and a pressure of 6.0Kg/ciG. Acetic acid 0 was added to the obtained nonylphenol adduct with ethylene oxide on average of 10 moles.
．． 9 g was added and stirred thoroughly. The detergent compositions shown in Table 1 containing the obtained nonylphenol adduct with ethylene oxide (Comparative Sample-1) with an average of 10.0 moles as a main detergent active ingredient were prepared and tested for odor and detergency. The results were as shown in Table 1.
実施例 ２
温度計、圧力計、撹拌機を備えた容ｆｆ１１０００ｍ１
ステンレス製反応器にノニルフェノール（分子ｆｆ１２
２１ ）１４３ｑ、触媒として水酸化カリウム０．６０
．エチレンオキシド４５７ｇを仕込み、温度１５０℃、
圧力６．０に９／ｃｉＧで反応さけた。Example 2 Capacity ff 11000ml equipped with thermometer, pressure gauge and stirrer
Nonylphenol (molecule ff12) was added to a stainless steel reactor.
21) 143q, potassium hydroxide 0.60 as a catalyst
．． 457g of ethylene oxide was charged, the temperature was 150℃,
The reaction was carried out at a pressure of 6.0 and 9/ciG.
得られたノニルフェノールのエチレンオキシド平均１６
．０モル付加物に５０重量％乳酸水溶液１゜９０を添加
し、よく撹拌した。The average ethylene oxide content of the obtained nonylphenol was 16
．． 1°90 of a 50% by weight aqueous lactic acid solution was added to the 0 mol adduct and stirred well.
得られたノニルフェノールのエチレンオキシド平均１６
．０モル付加物水溶液（試料−２）を主要洗浄活性成分
として含有する第１表の洗浄剤組成物をＷＡ製し、臭気
、洗浄力の試験を行なった。結果は第１表に示す通りで
あった。The average ethylene oxide content of the obtained nonylphenol was 16
．． The detergent compositions shown in Table 1 containing a 0 molar adduct aqueous solution (Sample-2) as the main detergent active ingredient were manufactured by WA and tested for odor and detergency. The results were as shown in Table 1.
比較例 ２
温度計、圧力計、撹拌機を備えた容ｆｆ１１０００ｍｊ
！ステンレス製反不反応器ニルフェノール（分子ｆｆ１
２２１ ＞１４３０、触媒として水酸化カリウム０．６
Ｑ、エチレンオキシド４５７Ｑを仕込み、温度１５０℃
、圧力６．０Ｋｇ／ｃｄＧで反応させた。Comparative Example 2 Capacity ff11000mj equipped with thermometer, pressure gauge, and stirrer
! Stainless steel anti-non-reactor Nylphenol (molecule ff1
221 >1430, potassium hydroxide 0.6 as catalyst
Q. Prepare ethylene oxide 457Q, temperature 150℃
, the reaction was carried out at a pressure of 6.0 Kg/cdG.
得られたノニルフェノールのエチレンオキシド平均１６
．０モル付加物に５０重ａ％硫酸水溶液１゜０ｇを添加
添加し、よく撹伴した。得られたノニルフェノールのエ
チレンオキシド平均１６．０モル付加物水溶液（比較試
料−２）を主要洗浄活性成分として含有する第１表の洗
浄剤組成物を調製し、臭気、洗浄力の試験を行なった。The average ethylene oxide content of the obtained nonylphenol was 16
．． 1.0 g of a 50 wt% aqueous sulfuric acid solution was added to the 0 mole adduct and stirred thoroughly. The detergent compositions shown in Table 1 containing the resulting aqueous solution of the ethylene oxide adduct of nonylphenol (Comparative Sample-2) as the main detergent active ingredient were prepared and tested for odor and detergency.
結果は第１表に示す通りであった。The results were as shown in Table 1.
実施例 ３
温度計、圧力計、撹拌機を備えた容量１０００ｍ１ステ
ンレス製反応器にオクチルフェノール（分子１１２０６
）１９１ｇ、触媒として水酸化ナトリウム０．６Ｑ、エ
チレンオキシド４０９ｑを仕込み、温度１５０℃、圧力
６．０Ｋｇ／ｄＧで反応させた。得られたオクチルフェ
ノールのエチレンオキシド平均１０モル付加物に５０重
量％乳酸水溶液２．７ｇを添加し、よく撹伴した。得ら
れたオクチルフェノールのエチレンオキシド平均１０．
０モル付加物（試料−３）を主要洗浄活性成分として含
有する第１表の洗浄剤組成物を調製し、臭気、洗浄力の
試験を行なった。結果は第１表に示す通りであった。Example 3 Octylphenol (molecules 11206
), 0.6Q of sodium hydroxide and 409q of ethylene oxide as catalysts were charged, and the reaction was carried out at a temperature of 150°C and a pressure of 6.0Kg/dG. 2.7 g of a 50% by weight aqueous lactic acid solution was added to the obtained adduct of octylphenol with an average of 10 moles of ethylene oxide, and the mixture was thoroughly stirred. The average ethylene oxide content of the obtained octylphenol was 10.
The detergent compositions shown in Table 1 containing the 0 mole adduct (Sample-3) as the main detergent active ingredient were prepared and tested for odor and detergency. The results were as shown in Table 1.
比較例 ３
温度計、圧力計、撹拌機を備えた容量１０００ｍ！ステ
ンレス製反応器にオクチルフェノール（分子ｆｆ１２０
６＞１９１０、触媒として水酸化ナトリウム０．６Ｑ、
エチレンオキシド４０９Ｑを仕込み、温度１５０℃、圧
力６．ＯＫ！Ｊ／ｃｄＧで反応させた。得られたオクチ
ルフェノールのエチレンオキシド平均１０モル付加物に
８５重重量リン酸水溶液０．９０を添加し、よく撹伴し
た。得られたオクチルフェノールのエチレンオキシド平
均１０．０モル付加物（比較試料−３）を主要洗浄活性
成分として含有する第１表の洗浄剤組成物を調製し、臭
気、洗浄力の試験を行なった。結果は第１表に示す通り
であった。Comparative Example 3 Capacity 1000m equipped with thermometer, pressure gauge, and stirrer! Octylphenol (molecular ff120) in a stainless steel reactor
6>1910, sodium hydroxide 0.6Q as a catalyst,
Charge ethylene oxide 409Q, temperature 150°C, pressure 6. OK! The reaction was performed with J/cdG. To the obtained adduct of octylphenol with 10 moles of ethylene oxide on average, 0.90 of an 85% weight aqueous phosphoric acid solution was added and stirred well. The detergent compositions shown in Table 1 containing the obtained octylphenol adduct with ethylene oxide (Comparative Sample-3) with an average of 10.0 moles as a main detergent active ingredient were prepared and tested for odor and detergency. The results were as shown in Table 1.
実施例 ４
温度計、圧力計、撹拌機を備えた容量１０１００Ｏステ
ンレス製反応鼎にノニルフェノール（分子ｆｆ１２２１
）２００Ｇ、触媒として水酸化ナトリウム０．６ａ、エ
チレンオキシド４００ｑを仕込み、温度１５０℃、圧力
６．０に９／ｃｉＧで反応させた。得られたノニルフェ
ノールのエチレンオキシド平均１０モル付加物にキョワ
ード・６００ＢＬＩＰＳ（協和化学工業社製 合成吸着
剤）７．５０を添加し８０℃で３０分間撹拌した後ケイ
ソウ土でプレコートした口過器に移し触媒を吸着したキ
ョワード８６００ＢｔＪＰＳを除去した。ついで口過し
たエチレンオキシド付加物に５０＜ｆｆｉ％乳酸水溶液
３．５０を添加し、よく撹伴した。得られたノニルフェ
ノールのエチレンオキシド平均１０．０モル付加物（試
料−４）を主要洗浄活性成分として含有する第１表の洗
浄剤組成物を調製し、臭気および洗浄力の試験を行なっ
た。結果は第１表に示す通りであった。Example 4 Nonylphenol (molecules ff 1221
)200G, 0.6a of sodium hydroxide as a catalyst, and 400q of ethylene oxide were charged, and the reaction was carried out at a temperature of 150°C and a pressure of 6.0 at a rate of 9/ciG. To the resulting adduct of nonylphenol with an average of 10 moles of ethylene oxide, 7.50% of Kyoward 600BLIPS (synthetic adsorbent manufactured by Kyowa Chemical Industry Co., Ltd.) was added, stirred at 80°C for 30 minutes, and then transferred to a filter pre-coated with diatomaceous earth to absorb the catalyst. Kyoward 8600BtJPS adsorbed was removed. Then, 3.50% of a 50<ffi% lactic acid aqueous solution was added to the sipped ethylene oxide adduct and stirred well. The detergent compositions shown in Table 1 containing the obtained nonylphenol adduct with ethylene oxide (Sample-4) with an average of 10.0 moles as a main detergent active ingredient were prepared and tested for odor and detergency. The results were as shown in Table 1.
比較例 ４
温度計、圧力計、撹拌機を備えた容量１０００ｍｊＩス
テンレス製反応器にノニルフェノール（分子ｆｆ１２２
１ ）２００Ｑ１触媒として水酸化ナトリウム０．６ｇ
、エチレンオキシド４００ｇを仕込み、Ｗｍ１５０℃、
圧力６．０に９／ｄＧで反応させた。得られたノニルフ
ェノールのエチレンオキシド平均１０モル付加物にキヨ
ワード・６００Ｂｕｐｓ ＜協和化学工業社製 合成吸
着剤）７．５９を添加し８０℃で３０分間撹拌した後ケ
イソウ土でプレコートした口過器に移し触媒を吸着した
キヨワード０６００ＢＵＰＳを除去した。得られたノニ
ルフェノールのエチレンオキシド平均１０゜０モル付加
物（比較試料−４）を主要洗浄活性成分として含有する
第１表の洗浄剤組成物を調製し、臭気および洗浄力の試
験を行なった。結果は第１表に示す通りであった。Comparative Example 4 Nonylphenol (molecules ff 122
1) 0.6g of sodium hydroxide as 200Q1 catalyst
, charged 400g of ethylene oxide, Wm 150℃,
The reaction was performed at a pressure of 6.0 and 9/dG. To the resulting adduct of nonylphenol with an average of 10 moles of ethylene oxide, Kyoward 600Bups (synthetic adsorbent manufactured by Kyowa Chemical Industry Co., Ltd.) 7.59 was added, stirred at 80°C for 30 minutes, and then transferred to a filter pre-coated with diatomaceous earth to remove the catalyst. The Kyoward 0600BUPS adsorbed was removed. The detergent compositions shown in Table 1 containing the obtained nonylphenol adduct with ethylene oxide (Comparative Sample-4) with an average of 10.0 mol as a main detergent active ingredient were prepared and tested for odor and detergency. The results were as shown in Table 1.
（発明の効果）
フェノール類とエチレンオキシドとを反応させて得られ
たフェノール類エトキシレートに乳酸および／または乳
酸塩を含有させて得られたフェノール類エトキシレート
は、臭気の経時変化が極めて少なくなる効果を発揮する
ことがわかった。さらに得られたフェノール類エトキシ
レートは界面活性剤として広い分野で使用できるもので
ある。(Effect of the invention) The phenol ethoxylate obtained by reacting phenol and ethylene oxide with lactic acid and/or lactate has the effect of extremely reducing odor change over time. It was found that Furthermore, the obtained phenolic ethoxylate can be used as a surfactant in a wide range of fields.
Claims (8)
て含有する洗浄剤組成物において、該洗浄活性成分が乳
酸および／または乳酸塩を含有するフェノール類エトキ
シレートであることを特徴とする洗浄剤組成物。(1) A cleaning composition containing phenolic ethoxylate as a cleaning active ingredient, wherein the cleaning active ingredient is a phenolic ethoxylate containing lactic acid and/or lactate.
類エトキシレートがフェノール類とエチレンオキシドと
をアルカリ触媒の存在下に反応させて得られる未中和の
フェノール類エトキシレートに乳酸を中和剤として添加
して得られたものである特許請求の範囲第１項記載の洗
浄剤組成物。(2) Phenol ethoxylate containing lactic acid and/or lactate is obtained by reacting phenol and ethylene oxide in the presence of an alkali catalyst.Lactic acid is added as a neutralizing agent to unneutralized phenol ethoxylate. The cleaning composition according to claim 1, which is obtained by:
類エトキシレートがフェノール類とエチレンオキシドと
をアルカリ触媒の存在下に反応させて得られる未中和の
フェノール類エトキシレートの触媒を中和した状態また
はロ過によって触媒を除去したフェノール類エトキシレ
ートに乳酸および／または乳酸塩を添加して得られたも
のである特許請求の範囲第１項記載の洗浄剤組成物。(3) A state in which phenol ethoxylate containing lactic acid and/or lactate has neutralized the catalyst of unneutralized phenol ethoxylate obtained by reacting phenol and ethylene oxide in the presence of an alkali catalyst, or The cleaning composition according to claim 1, which is obtained by adding lactic acid and/or lactate to phenolic ethoxylate from which the catalyst has been removed by filtration.
エトキシレートである特許請求の範囲第１項記載の洗浄
剤組成物。(4) The cleaning composition according to claim 1, wherein the phenol ethoxylate is nonylphenol ethoxylate.
ルエトキシレートである特許請求の範囲第１項記載の洗
浄剤組成物。(5) The cleaning composition according to claim 1, wherein the phenol ethoxylate is octylphenol ethoxylate.
範囲第１項記載の洗浄剤組成物。(6) The cleaning composition according to claim 1, wherein the lactate is an alkali metal salt of lactic acid.
１項記載の洗浄剤組成物。(7) The cleaning composition according to claim 1, wherein the lactate is sodium lactate.
項記載の洗浄剤組成物。(8) Claim 1 in which the lactate is potassium lactate
The cleaning composition described in .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61106667A JPH0684509B2 (en) | 1986-05-12 | 1986-05-12 | Cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61106667A JPH0684509B2 (en) | 1986-05-12 | 1986-05-12 | Cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62263293A true JPS62263293A (en) | 1987-11-16 |
| JPH0684509B2 JPH0684509B2 (en) | 1994-10-26 |
Family
ID=14439428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61106667A Expired - Lifetime JPH0684509B2 (en) | 1986-05-12 | 1986-05-12 | Cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0684509B2 (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2244375A1 (en) * | 1972-09-09 | 1974-03-14 | Licentia Gmbh | PROCEDURE FOR SWITCHING OFF THE AUTOMATIC CONTROL OF AN AMPLIFIER IN TRANSMISSION SYSTEMS |
| CA1086178A (en) * | 1977-04-04 | 1980-09-23 | Christian R. Barrat | Liquid detergent composition |
| JPS5667497A (en) * | 1979-11-07 | 1981-06-06 | Tokyo Tatsuno Kk | Vendor |
| JPS56112931A (en) * | 1980-02-12 | 1981-09-05 | Sanyo Chem Ind Ltd | Polyol composition |
| JPS57177100A (en) * | 1981-04-24 | 1982-10-30 | Kao Corp | Detergent composition for cattle shed |
| JPS58198532A (en) * | 1982-05-17 | 1983-11-18 | Asahi Denka Kogyo Kk | Curable composition |
| US4533759A (en) * | 1982-04-09 | 1985-08-06 | National Distillers And Chemical Corporation | Process for the production of fragrance quality ethylene glycol monoaryl ethers |
-
1986
- 1986-05-12 JP JP61106667A patent/JPH0684509B2/en not_active Expired - Lifetime
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2244375A1 (en) * | 1972-09-09 | 1974-03-14 | Licentia Gmbh | PROCEDURE FOR SWITCHING OFF THE AUTOMATIC CONTROL OF AN AMPLIFIER IN TRANSMISSION SYSTEMS |
| CA1086178A (en) * | 1977-04-04 | 1980-09-23 | Christian R. Barrat | Liquid detergent composition |
| JPS5667497A (en) * | 1979-11-07 | 1981-06-06 | Tokyo Tatsuno Kk | Vendor |
| JPS56112931A (en) * | 1980-02-12 | 1981-09-05 | Sanyo Chem Ind Ltd | Polyol composition |
| JPS57177100A (en) * | 1981-04-24 | 1982-10-30 | Kao Corp | Detergent composition for cattle shed |
| US4533759A (en) * | 1982-04-09 | 1985-08-06 | National Distillers And Chemical Corporation | Process for the production of fragrance quality ethylene glycol monoaryl ethers |
| JPS58198532A (en) * | 1982-05-17 | 1983-11-18 | Asahi Denka Kogyo Kk | Curable composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0684509B2 (en) | 1994-10-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1170952A (en) | Mixed ethoxylated alcohol/ethoxy sulfate surfactants and synthetic detergents incorporating the same | |
| JPH064878B2 (en) | Liquid laundry detergent composition containing no ethanol | |
| DE2412839C3 (en) | ||
| JPS6225196A (en) | Uniform thick liquid detergent composition containing three-component detergent system | |
| US5117032A (en) | Process for making glycerol ether sulfates | |
| US3798168A (en) | Detergent composition | |
| US4737314A (en) | Stabilized alkylene oxide adduct containing lactic acid or a lactate | |
| NO140678B (en) | FOAMY DISHWASHER MIXTURE. | |
| US3623988A (en) | Use of polyether-substituted chlorohydrins as a low-foam, caustic stable cleaning agent | |
| JPS6187657A (en) | Preparation of alpha-sulfo-fatty acid ester salt | |
| JPS62263293A (en) | Detergent composition | |
| JP3172754B2 (en) | High bulk density granular detergent composition | |
| AU598489B2 (en) | Detergent composition of improved oily soil removing capability | |
| JPH05222396A (en) | Concentrated liquid detergent composition | |
| JPS6339993A (en) | Liquid detergent composition | |
| JPH0253417B2 (en) | ||
| JPS6341597A (en) | Detergent composition | |
| JPH027694B2 (en) | ||
| JPH0144758B2 (en) | ||
| JP3628449B2 (en) | Surfactant | |
| JPS61280467A (en) | Aqueous solution of alpha-sulfofatty acid ester salt having high concentration | |
| JPH066719B2 (en) | Liquid detergent composition | |
| JPH0253418B2 (en) | ||
| JPH0393900A (en) | Liquid surface active composition | |
| JPH0726114B2 (en) | Liquid detergent composition |