JPS62255187A - Thermal transfer sheet for forming color picture - Google Patents
Thermal transfer sheet for forming color pictureInfo
- Publication number
- JPS62255187A JPS62255187A JP61097972A JP9797286A JPS62255187A JP S62255187 A JPS62255187 A JP S62255187A JP 61097972 A JP61097972 A JP 61097972A JP 9797286 A JP9797286 A JP 9797286A JP S62255187 A JPS62255187 A JP S62255187A
- Authority
- JP
- Japan
- Prior art keywords
- dye
- thermal transfer
- transfer sheet
- color
- yellow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000012546 transfer Methods 0.000 title claims abstract description 61
- 239000000975 dye Substances 0.000 claims abstract description 43
- 239000000203 mixture Substances 0.000 claims abstract description 14
- GBAJQXFGDKEDBM-UHFFFAOYSA-N 1-(methylamino)-4-(3-methylanilino)anthracene-9,10-dione Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(NC)=CC=C1NC1=CC=CC(C)=C1 GBAJQXFGDKEDBM-UHFFFAOYSA-N 0.000 claims abstract description 5
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001043 yellow dye Substances 0.000 claims abstract description 4
- GTZCVFVGUGFEME-UHFFFAOYSA-N aconitic acid Chemical compound OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000003086 colorant Substances 0.000 claims description 16
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 abstract description 10
- 238000007645 offset printing Methods 0.000 abstract description 10
- 239000002270 dispersing agent Substances 0.000 abstract description 4
- MHXFWEJMQVIWDH-UHFFFAOYSA-N 1-amino-4-hydroxy-2-phenoxyanthracene-9,10-dione Chemical compound C1=C(O)C=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C1OC1=CC=CC=C1 MHXFWEJMQVIWDH-UHFFFAOYSA-N 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 31
- 239000000976 ink Substances 0.000 description 24
- 239000000463 material Substances 0.000 description 23
- 238000007639 printing Methods 0.000 description 23
- 229920005989 resin Polymers 0.000 description 13
- 239000011347 resin Substances 0.000 description 13
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000000123 paper Substances 0.000 description 7
- -1 polypropylene Polymers 0.000 description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 230000000181 anti-adherent effect Effects 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- MTZWHHIREPJPTG-UHFFFAOYSA-N phorone Chemical compound CC(C)=CC(=O)C=C(C)C MTZWHHIREPJPTG-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000012461 cellulose resin Substances 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- NZTGGRGGJFCKGG-UHFFFAOYSA-N 1,4-diamino-2,3-diphenoxyanthracene-9,10-dione Chemical compound C=1C=CC=CC=1OC1=C(N)C=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C1OC1=CC=CC=C1 NZTGGRGGJFCKGG-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 229920001747 Cellulose diacetate Polymers 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 244000111306 Torreya nucifera Species 0.000 description 1
- 235000006732 Torreya nucifera Nutrition 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 235000005811 Viola adunca Nutrition 0.000 description 1
- 240000009038 Viola odorata Species 0.000 description 1
- 235000013487 Viola odorata Nutrition 0.000 description 1
- 235000002254 Viola papilionacea Nutrition 0.000 description 1
- 244000172533 Viola sororia Species 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- GVKCHTBDSMQENH-UHFFFAOYSA-L phloxine B Chemical compound [Na+].[Na+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 GVKCHTBDSMQENH-UHFFFAOYSA-L 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/3858—Mixtures of dyes, at least one being a dye classifiable in one of groups B41M5/385 - B41M5/39
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/34—Multicolour thermography
- B41M5/345—Multicolour thermography by thermal transfer of dyes or pigments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/3852—Anthraquinone or naphthoquinone dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/3854—Dyes containing one or more acyclic carbon-to-carbon double bonds, e.g., di- or tri-cyanovinyl, methine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/388—Azo dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/39—Dyes containing one or more carbon-to-nitrogen double bonds, e.g. azomethine
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はカラー画像形成用熱転写シートに関し、更に詳
しくは従来商業的に広く使用されている各種カラー印刷
の校正刷に有用であるカラー画像形成用熱転写シートに
関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a thermal transfer sheet for color image formation, and more particularly to a color image formation sheet useful for proof printing of various color printings conventionally widely used commercially. The present invention relates to a thermal transfer sheet for use.
（従来の技術）
従来、オフセット印刷、グラビア印刷等によって多量の
カラー印刷が行われており、このようなカラー印刷に際
しては、原稿をそのまま、あるいは他の原稿、文字、記
号等を組合せて色分解し、シアン、マゼンタ、イエロー
の三原色の版を作成し、更に必要に応じてブラックの版
を加え、夫々の印刷インキによって原稿の色相、模様等
を再現するものである。(Prior art) Conventionally, a large amount of color printing has been performed using offset printing, gravure printing, etc. When printing in color, the original is used as it is, or it is color separated by combining other originals, characters, symbols, etc. Then, plates for the three primary colors of cyan, magenta, and yellow are created, and a black plate is added as necessary to reproduce the hue, pattern, etc. of the original using each printing ink.
大量の印刷を行うためには、大量印刷に先立って原稿と
印刷物との色調、レイアウト、文字、記号等が正確に一
致しているか否かを予め確認する必要があり、このため
に従来は校正刷という工程が行われている。このような
校正刷によって原稿と印刷物との色調、レイアウト、そ
の他の異同の確認を行うものであるが、原稿と印刷物と
が最初から完成に一致することは殆どなく、異なる点に
ついてその都度印刷版の修正を行い、このような■程を
数回繰返すことで、原稿と印刷物の十分な一致が為され
ている。また、原稿自体が不十分な場合にも同様な操作
を繰返すことによって、注文主の要望に応えている。In order to print in large quantities, it is necessary to check in advance whether the color tone, layout, characters, symbols, etc. of the original and printed matter exactly match before printing in large quantities. A process called printing is being carried out. These proofs are used to check the color tone, layout, and other differences between the manuscript and the printed matter, but the manuscript and the printed matter are rarely exactly the same from the beginning, and the printed version is checked each time for differences. By making the following corrections and repeating this step several times, the manuscript and printed matter are sufficiently consistent. Additionally, even if the manuscript itself is insufficient, similar operations are repeated to meet the requests of the orderer.
（発明が解決しようとしている問題点）以上の如き校正
刷の工程は、大量印刷を行う時には必須の工程であるが
、この工程は版の修正等非常に煩雑であり、校正刷の工
程の省略あるいは筒素化が強く要望されている。しかし
ながら現在のところ、これらの要望に十分応える手段は
見い出されていない。(Problem to be solved by the invention) The proof printing process as described above is an essential process when performing mass printing, but this process is very complicated, such as plate correction, and the proof printing process can be omitted. Alternatively, there is a strong demand for cylindrical elements. However, at present, no means have been found that satisfactorily meet these demands.
本発明者は、上記の如き従来技術の問題点を解決し、」
二連の要望に応えるべく鋭意研究の結果、従来公知の熱
転写技術を利用することによって、上記要望に応えるこ
とができることを知見して本発明を完成した。The present inventor solved the problems of the prior art as described above,
As a result of intensive research to meet these two demands, the present invention was completed based on the finding that the above demands could be met by utilizing conventionally known thermal transfer technology.
（問題点を解決するための手段）
すなわち、本発明は、シアン、マゼンタおよびイエロー
の夫々の色相の染料を含む夫々の染料担持層を有する少
なくとも３種の熱転写シートからなるカラー画像形成用
熱転写シートにおいて、」−記シアン染料が、Ｃ．Ｉ．
ソルベントブルー６３および下記式（Ｉ）で表わされる
染料の混合物であり、上記マゼンタ染料が、Ｃ．Ｉ．デ
ィスバーズレッド６０およびＣ．Ｉ．ディスパーズウ゛
アイオレット２６の混合物であり、且つイエロー染料が
、下記式（ｎ ）で表わされる染料であることを特徴と
するカラー画像形成用熱転写シートである。(Means for Solving the Problems) That is, the present invention provides a thermal transfer sheet for color image formation comprising at least three types of thermal transfer sheets each having a dye-carrying layer containing a dye of each hue of cyan, magenta, and yellow. In the cyan dye labeled C. I.
It is a mixture of Solvent Blue 63 and a dye represented by the following formula (I), and the magenta dye is a mixture of C.I. I. Disbird's Red 60 and C.I. I. This is a thermal transfer sheet for forming a color image, which is a mixture of Disperse Eyelet 26, and the yellow dye is a dye represented by the following formula (n).
星
４Ｈ９
次に本発明を更に詳細に説明すると、本発明の主たる特
徴は、従来無数に知られている熱転写シート用染料から
、従来の印刷インキ、特番乙 オフセット印刷インキの
三原色、すなわち、シアン、マゼンタおよびイエローの
印刷インキの色調に最も近い染料を選択して、夫々の色
調の熱転写シートを用意した点にある。Star 4H9 Next, to explain the present invention in more detail, the main feature of the present invention is that from the countless known dyes for thermal transfer sheets, the three primary colors of conventional printing ink and offset printing ink, namely cyan, The key point is that the dyes closest to the magenta and yellow printing ink tones were selected, and thermal transfer sheets of the respective tones were prepared.
従来のオフセット印刷インキの三原色の色は、殆どが顔
料から構成されており、一方、熱転写シートに使用する
色材はすべて昇華性（あるいは熱移行性）染料であるこ
とから、両者は互いにその発色機構が異なり、オフセッ
ト印刷インキの三原色に一致する熱移行性染料の選択は
殆ど不可能であった。Most of the three primary colors of conventional offset printing inks are composed of pigments, but on the other hand, the coloring materials used in thermal transfer sheets are all sublimable (or heat transferable) dyes; The mechanism is different, and it has been almost impossible to select a heat-transferable dye that matches the three primary colors of the offset printing ink.
本発明者は、印刷インキの三原色に殆ど一致する染料の
選択について更に研究を続けたところ、イエロー以外に
ついては、１種のみの染料では印刷インキの三原色は再
現不能であるが、シアンおよびマゼンタについては、特
定の２種の染料を組合せることによって、印刷インキの
三原色が再現可能であることを知見したものである。The present inventor further researched the selection of dyes that almost matched the three primary colors of printing ink, and found that for colors other than yellow, it was impossible to reproduce the three primary colors of printing ink with only one type of dye, but for cyan and magenta. discovered that the three primary colors of printing ink can be reproduced by combining two specific dyes.
すなわち、本発明においてはシアン染料として、Ｃ．Ｉ
．ソルベントブルー６３と前記（Ｉ）で表わされる染料
（いずれも分散剤等を包含しうる、以下同様）を組合せ
、好ましくはその混合比を前者１重量部あたり後者２．
０〜８．０重量部の範囲の混合物とすることによって、
オフセット印刷インキのシアンインキに相当する色調を
再現することができる。この混合比の範囲を外れると本
発明の目的達成が十分でなくなる。That is, in the present invention, C.I. I
．． Solvent Blue 63 and the dye represented by (I) above (both may contain a dispersant, etc., the same applies hereinafter) are combined, preferably at a mixing ratio of 1 part by weight of the former to 2.0 parts by weight of the latter.
By making the mixture in the range of 0 to 8.0 parts by weight,
It is possible to reproduce the color tone equivalent to cyan ink of offset printing ink. If the mixing ratio falls outside of this range, the object of the present invention will not be fully achieved.
また、マゼンタ染料としては、Ｃ．Ｉ．ディスバーズレ
ッド６０とＣ．Ｉ．ディスパーズウ゛アイオレット２６
とを好ましくはその混合比を前者１重量部あたり後者０
．３〜１．０重量部の範囲の混合物とすることによって
、オフセット印刷インキのマゼンタインキに相当する色
調を再現することができる。Moreover, as a magenta dye, C. I. Disbirds Red 60 and C. I. Disperse Eye Iolette 26
Preferably, the mixing ratio is 1 part by weight of the former to 0 part by weight of the latter.
．． By using a mixture in the range of 3 to 1.0 parts by weight, a color tone corresponding to magenta ink of offset printing ink can be reproduced.
この混合比の範囲を外れると本発明の目的達成が１−分
でなくなる。If the mixing ratio is outside this range, the object of the present invention cannot be achieved within 1 minute.
更にイエロー染料として、前記式（ＩＩ ）で表わされ
る染料を使用することによってオフセラｉ・印刷インキ
のイエロー色に相当する色調を再現することができる。Further, by using the dye represented by the formula (II) as the yellow dye, it is possible to reproduce a color tone corresponding to the yellow color of Offsera i printing ink.
尚、以上のＣ．Ｉ．ソルベントブルー６３はＫａｙａｓ
ｅｔＢｌｕｅ ７１４ （日本化薬製）、前記式（Ｉ
） で表わされる染料は、Ｆｏｒｏｎ Ｂｒ１ｌｌｉａ
ｎｔ Ｂｌｕｅ Ｓ−Ｒ（サンド製） 、 Ｃ．Ｉ．デ
ィスバーズレッド２８は、 １．５ＲｅｄＧ（三井東圧
化学製） 、 Ｃ．Ｉ．ディスパーズウ゛アイオレット
は、Ｍａｃｒｏｌｅｘ Ｒｅｄ Ｖｉｏｌｅｔ Ｒ（バ
イエル製）、前記式（ＩＩ ）で表わされる染料は、Ｆ
ｏｒｏｎ Ｂｒ１ｌｌｉａｎｔ Ｙｅｌｌｏｖ ５−Ｂ
ＧＬ （サンド製）等として市場から入手できるもの
である。In addition, the above C. I. Solvent Blue 63 is Kayas
etBlue 714 (manufactured by Nippon Kayaku), the above formula (I
) The dye represented by Foron Brllia
nt Blue S-R (manufactured by Sandoz), C. I. Disbirds Red 28 is 1.5RedG (manufactured by Mitsui Toatsu Chemical), C. I. Disperse violet is Macrolex Red Violet R (manufactured by Bayer), and the dye represented by formula (II) is F
oron Br1lliant Yellow 5-B
It is available on the market as GL (manufactured by Sandoz) and the like.
本発明は、以上の如き特定の染料の組合せを利用して、
夫々シアン、マゼンタおよびイエロー発色の三色の熱転
写シートを提供するものであるが、これらの三色の熱転
写シートは夫々別の熱転写シートでもよいし、また連続
した基材シート」−１ご任意の順序で二色の染料を含む
染料担持層を形成したものでもよく、更にこれらの態様
に従来公知の任意のブラック発色の熱転写シートを組合
せてもよいものである。The present invention utilizes a combination of specific dyes as described above,
Three-color thermal transfer sheets of cyan, magenta, and yellow are provided, respectively, but these three-color thermal transfer sheets may be separate thermal transfer sheets, or a continuous base sheet''-1 of your choice. A dye-carrying layer containing dyes of two colors may be formed in this order, and any conventionally known black-colored thermal transfer sheet may be combined with these embodiments.
上記の如き熱転写シートを使用することにより、従来の
オフセット印刷により大量のカラー印刷を行うに先立っ
て、原稿の色分解をカラースキャナーで行い、これにコ
ンピュタ−を搭載した熱転写記録装置を接続してカラー
印刷を行い、これを校正刷に代えることにより、印刷物
の色の修正、レイアウトの変更、記号、文字、他の原稿
の挿入等が、そのつど版を作成したり修正したりするこ
となく、コンピュタ−」二の処理により最終的に決定す
ることができる。By using a thermal transfer sheet like the one described above, before printing a large amount of color using conventional offset printing, the colors of the original can be separated using a color scanner, and a thermal transfer recording device equipped with a computer can be connected to this. By printing in color and using it as a proof, you can correct the colors of printed matter, change the layout, insert symbols, characters, other documents, etc. without having to create or modify a plate each time. The final decision can be made through computer processing.
本発明の熱転写シートは以−１−の如き特定の組合せの
三色の染料を使用することを特徴とし、それ以外の構成
は従来公知の熱転写シートの構成と同様でよい。The thermal transfer sheet of the present invention is characterized by using a specific combination of three colors of dyes as described in -1- below, and other than that, the structure may be the same as that of a conventionally known thermal transfer sheet.
前記の染料を含む本発明の熱転写シートの構成に使用す
る基材シートとしては、従来公知のある程度の耐熱性と
強度を有するものであればいずれのものでもよく、例え
ば、０．５〜５０ｇｍ、好ましくは３〜１０／１．ｍ程
度の厚さの紙、各種加工紙、ポリエステルフィルム、ポ
リスチレンフィルム、ポリプロピレンフィルム、ポリサ
ルホンフィルム、ポリカーボネートフィルム、ポリビニ
ルアルコールフィルム、セロファン等でア’ｌ、特に好
ましいものはポリエステルフィルムである。The base sheet used in the construction of the thermal transfer sheet of the present invention containing the above-mentioned dye may be any conventionally known material having a certain degree of heat resistance and strength, for example, 0.5 to 50 gm, Preferably 3 to 10/1. Examples include paper with a thickness of about 200 m, various processed papers, polyester films, polystyrene films, polypropylene films, polysulfone films, polycarbonate films, polyvinyl alcohol films, cellophane, etc., with polyester films being particularly preferred.
上記の如き基材シートの表面に設ける染料担持層は、前
記の染料を任意のバインダー樹脂で担持させた層である
。The dye-carrying layer provided on the surface of the base sheet as described above is a layer in which the dye is supported by any binder resin.
前記の染料な担持するだめのバインダー樹脂としては、
従来公知のものがいずれも使用でき、好ましいものを例
示すれば、エチルセルロース、ヒドロキシエチルセルロ
ース、エチルヒドロキシセルロース、ヒドロキシプロプ
ルセルロース、メチルセルロース、酢酸セルロース、酢
酪酸セルロース等のセルロース系樹脂、ポリビニルアル
コール、ポリ酢酸ビニル、ポリビニルブチラール、ポリ
ビニルピロリドン、ポリアクリルアミド等のビニル系樹
脂、ポリエステル等が、耐熱性。As the binder resin for supporting the dye,
Any conventionally known ones can be used, and preferred examples include cellulose resins such as ethyl cellulose, hydroxyethyl cellulose, ethyl hydroxy cellulose, hydroxypropyl cellulose, methyl cellulose, cellulose acetate, and cellulose acetate butyrate, polyvinyl alcohol, and polyacetic acid. Vinyl resins such as vinyl, polyvinyl butyral, polyvinyl pyrrolidone, and polyacrylamide, polyester, etc. are heat resistant.
染料の移行性等の点から好ましいものである。This is preferable from the viewpoint of dye migration.
本発明の熱転写シートの染料担持層は、基本的には上記
の材料から形成されるが、その他必要に応じて従来公知
と同様な各種の添加剤をも包含し得るものである。The dye-carrying layer of the thermal transfer sheet of the present invention is basically formed from the above-mentioned materials, but may also contain various conventionally known additives as required.
このような染料担持層は、好ましくは適当な溶剤中に前
記の夫々の組合せの染料、バインダー樹脂その他の任意
成分を加えて各成分を溶解または分散させて相持層形成
用塗液またはインキを調製し、これを上記の基材シー］
・上に塗布および乾燥させて形成する。Such a dye-carrying layer is preferably prepared by adding the above-mentioned combinations of dyes, binder resin, and other optional components to a suitable solvent and dissolving or dispersing each component to prepare a coating liquid or ink for forming a compatible layer. and add this to the above base material sheet]
- Form by coating and drying.
このようにして形成する担持層は、０．２〜５ 、０
ｇｍ、好ましくは０．４〜２．０＃Ｌｍ程度の厚さであ
り、また担持層中の前記の染料は、担持層の重量の５〜
７０重量％、好ましくは１０〜６０重量％の量で存在す
るのが好適である。The support layer formed in this way has a density of 0.2 to 5,0
gm, preferably about 0.4 to 2.0 #Lm, and the dye in the carrier layer has a thickness of about 5 to 2.0 #Lm of the weight of the carrier layer.
Suitably it is present in an amount of 70% by weight, preferably 10-60% by weight.
上記の如き本発明の熱転写シートは、そのままで熱転写
用として十分に有用であるが、更にその染料担持層表面
に粘着防止層、すなわち離型層を設けてもよく、このよ
うな層を設けることにより、熱転写時における熱転写シ
ートと被転写材の粘着を防止し、更に高い熱転写温度を
使用し、一層優れた濃度の画像を形成することができる
。The thermal transfer sheet of the present invention as described above is fully useful for thermal transfer as it is, but it is also possible to provide an anti-adhesive layer, that is, a release layer, on the surface of the dye-carrying layer. This prevents adhesion between the thermal transfer sheet and the transfer material during thermal transfer, allows use of a higher thermal transfer temperature, and forms images with even better density.
この離型層としては、単に粘着防止性の無機粉末を付着
させたのみでも相当の効果を示し、更に、例えば、シリ
コーンポリマー、アクリルポリマー、フッ素化ポリマー
の如き離型性に優れた樹脂から０．０１〜５ｐＬｍ、好
ましくは０．０５〜２ｇｍの離型層を設けることによっ
て形成することができる。As this mold release layer, even if an inorganic powder with anti-adhesive properties is simply attached, it has a considerable effect. It can be formed by providing a release layer of 0.01 to 5 pLm, preferably 0.05 to 2 gm.
尚、］二記の如き無機粉体あるいは離型性ポリマーは染
料担持層中に包含させても十分な効果を奏するものであ
る。Incidentally, the inorganic powders or release polymers described in [2] can exhibit sufficient effects even if they are included in the dye-carrying layer.
更に、このような熱転写シートの裏面に、サーマルヘッ
ドの熱による悪影響を防止するために耐熱層を設けても
よい。Furthermore, a heat-resistant layer may be provided on the back surface of such a thermal transfer sheet in order to prevent adverse effects caused by the heat of the thermal head.
以上の如き熱転写シートを用いて、画像を形成するため
に使用する被転写材は、その記録面が前記の染料に対し
て染料受容性を有するものであればいかなるものでもよ
く、また染料受容性を有しない紙、金属、ガラス、合成
樹脂等である場合には、その少なくとも一方の表面に染
料受容層を形成すればよい。The transfer material used to form an image using the thermal transfer sheet as described above may be any material as long as its recording surface has dye receptivity to the above-mentioned dyes. If the material is paper, metal, glass, synthetic resin, etc., which does not have a dye, a dye-receiving layer may be formed on at least one surface thereof.
染料受容層を形成しなくてもよい被転写材としては、例
えば、ポリエチレン、ポリプロピレン等のポリオレフィ
ン系樹脂、ポリ塩化ビニル、ポリ塩化ビニリデン等のハ
ロゲン化ポリマー、ポリビニルアルコール、ポリ酢酸ビ
ニル、ポリアクリルエステル等のビニルポリマー、ポリ
エチレンテレフタレート、ポリブチレンテレフタレート
等のポリエステル系樹脂、ポリスチレン系樹脂、ポリア
ミド系樹脂、エチレンやプロピレン等のオレフィンと他
のビニルモノマーとの共重合体系樹脂、アイオノマー、
セルロースジアセテート、セルローストリアセテート等
のセルロース系樹脂、ポリカーボネート、ポリスルホン
、ポリイミド等からなる繊維、織布、フィルム、シート
、成形物等が挙げられる。Examples of transfer materials that do not require the formation of a dye-receiving layer include polyolefin resins such as polyethylene and polypropylene, halogenated polymers such as polyvinyl chloride and polyvinylidene chloride, polyvinyl alcohol, polyvinyl acetate, and polyacrylic ester. vinyl polymers such as polyethylene terephthalate, polyester resins such as polybutylene terephthalate, polystyrene resins, polyamide resins, copolymer resins of olefins such as ethylene and propylene with other vinyl monomers, ionomers,
Examples include fibers, woven fabrics, films, sheets, and molded products made of cellulose resins such as cellulose diacetate and cellulose triacetate, polycarbonate, polysulfone, and polyimide.
特に好ましいものはポリエステルからなるシートまたは
フィルムあるいはポリエステル層を設けた加工紙である
。また、紙、金属、ガラスその他の非染着性の被転写材
であっても、その記録面に１−記の如き染着性の樹脂の
溶液または分散液を塗布および乾燥させるが、あるいは
それらの樹脂フィルムをラミネートすることにより、被
転写材とすることができる。Particularly preferred are sheets or films made of polyester or processed paper provided with a polyester layer. In addition, even if the transfer material is non-dyeable such as paper, metal, glass, etc., a solution or dispersion of a dyeable resin as described in 1-1 is applied and dried on the recording surface, or By laminating the resin film, it can be used as a transfer material.
更に、上記の染着性のある被転写材であっても、その表
面に更に染着性の良い樹脂から、上記の紙の場合の如く
して染料受容層を形成してもよい。Furthermore, even if the transfer material has the dyeability described above, a dye-receiving layer may be formed on the surface thereof from a resin having better dyeability, as in the case of the paper described above.
このようにして形成する染料受容層は、単独または複数
の材料から形成でき、また、所期の目的を妨げない範囲
で更に各種の添加剤を包含してもよいのは当然である。The dye-receiving layer thus formed can be formed from a single material or a plurality of materials, and it goes without saying that it may further contain various additives as long as the intended purpose is not hindered.
このような染料受容層は任意の厚さでよいが。Such a dye-receiving layer may be of any thickness.
一般的には５〜５０＃Ｌｍの厚さである。また、このよ
うな染料受容層は連続被覆であるのが好ましいが、樹脂
エマルジョンや樹脂分散液を使用して、不連続の被覆と
して形成してもよい。Generally, the thickness is 5 to 50 #Lm. Although such a dye-receiving layer is preferably a continuous coating, it may also be formed as a discontinuous coating using a resin emulsion or resin dispersion.
このような被転写材は基本的には上記の如くで、そのま
までも十分に使用できるものであるが、上記被転写材ま
たはその染料受容層中に、粘着防止用の無機粉末を包含
させることができ、このようにすれば熱転写時の温度を
より高めても熱転写シートと被転写材との粘着を防止し
て、更にすぐれた熱転写を行うことができる。特に好ま
しいのは、微粉末のシリカである。Such a transfer material is basically as described above and can be used as is, but it is possible to incorporate an inorganic powder for anti-adhesion into the transfer material or its dye-receiving layer. In this way, even if the temperature during thermal transfer is increased, adhesion between the thermal transfer sheet and the material to be transferred can be prevented, and even better thermal transfer can be performed. Particularly preferred is finely powdered silica.
また、上記のシリカの如き無機粉末に代えて、または併
用して、離型性の良好な前述の如き樹脂を添加してもよ
い。特に好ましい離型性ポリマーは、シリコーン化合物
の硬化物、例えば、エポキシ変性シリコーンオイルと７
ミノ変性シリコーンオイルからなる硬化物が挙げられる
。このような離型剤は、染料受容層の重量の約０．５〜
３０重量％を占める割合が良い。Furthermore, in place of or in combination with the inorganic powder such as silica, the above-mentioned resin having good mold releasability may be added. Particularly preferred release polymers include cured products of silicone compounds, such as epoxy-modified silicone oil and
Examples include cured products made of mino-modified silicone oil. Such a release agent may be used in an amount of about 0.5 to about 0.5 to about 0.5 of the weight of the dye receiving layer.
A ratio of 30% by weight is good.
また使用する被転写材は、その染料受容層の表面に、」
−記の如き無機粉体を付着させて粘着防止効果を高めて
もよいし、また、前述の如き離型性に優れた離型剤から
なる層を設けてもよい。In addition, the transfer material used has "
- An inorganic powder as described above may be attached to enhance the anti-adhesive effect, or a layer made of a mold release agent having excellent mold release properties as described above may be provided.
このような離型層は約０．０１〜５）ｉｎの厚さで十分
な効果を発揮して、熱転写シートの染料受容層との粘着
を防止しつつ、一層染料受容性を向］二させることがで
きる。Such a release layer exhibits a sufficient effect at a thickness of about 0.01 to 5) inches to further improve dye receptivity while preventing adhesion to the dye receptive layer of the thermal transfer sheet. be able to.
上記の如き本発明の熱転写シートおよび上記の如き被記
録材を使用して熱転写を行う際に使用する熱エネルギー
の伺与手段は、従来公知の付与手段がいずれも使用でき
、例えば、サーマルプリンター（例えば、東芝■製、サ
ーマルプリンターＴＮ−５４００）等の記録装置によっ
て、記録時間をコントロールすることにより、５〜ｌ
００ ｍ Ｊ／ｍｍ’程度の熱エネルギーを伺４するこ
とによって、所期の目的を十分に達成することができる
。Any conventionally known means for imparting thermal energy can be used as the means for imparting thermal energy used when performing thermal transfer using the thermal transfer sheet of the present invention as described above and the recording material as described above, such as a thermal printer ( For example, by controlling the recording time using a recording device such as a thermal printer TN-5400 manufactured by Toshiba ■,
By applying a thermal energy of about 00 m J/mm', the intended purpose can be fully achieved.
（作用・効果）
上記の如き本発明の熱転写シートを使用することにより
、各種印刷方式、特にオフセット印刷方式により大量の
カラー印刷を実施するのに先立って、原稿の色分解をカ
ラースキャナーで行い、これにコンピュタ−を搭載した
熱転写記録装置を接続し、カラー印刷を行い、これを校
正刷に代えることにより、印刷物の色の修正、レイアウ
トの変更、記号、文字、他の原稿の挿入等が、そのつど
版を作成したり修正したりすることなく、コンピュタ−
上の処理により最終的に決定することができる。従って
、このように決定された状態で最終の版を作成すること
により、従来技術における如き煩雑な校正刷工程は大幅
に簡素化される。(Operations/Effects) By using the thermal transfer sheet of the present invention as described above, before carrying out a large amount of color printing using various printing methods, especially offset printing methods, the original can be color separated using a color scanner. By connecting this to a thermal transfer recording device equipped with a computer and printing in color, this can be used as a proof print, allowing you to correct the color of printed matter, change the layout, insert symbols, characters, other documents, etc. computer without the need to create or modify versions each time.
It can be finally determined by the above processing. Therefore, by creating the final plate in the state determined in this manner, the complicated proof printing process as in the prior art is greatly simplified.
次に実施例を挙げて前記を更に具体的に説明する。尚、
文中、部または％とあるのは特に断りの無い限り重量基
準である。Next, the above will be explained in more detail with reference to Examples. still,
In the text, parts or percentages are by weight unless otherwise specified.
実施例１
下記組成の３種の染料担持層形成用インキ組成物を調製
した。尚、シアンおよびイエロのインキ組成物は、成分
を溶解後にろ過して不溶分を除去した。これらを夫々背
面に耐熱処理を施した９ｔｉ−ｍ厚のポリエチレンテレ
フタレートフィルムに、乾燥塗布量が夫々１．０ｇ／ｒ
ｒｆになるように塗布および乾燥して本発明のシアン、
マゼンタおよびイエローの三色の夫々の熱転写シートを
得た。Example 1 Three kinds of ink compositions for forming a dye-carrying layer having the following compositions were prepared. In the cyan and yellow ink compositions, the components were dissolved and then filtered to remove insoluble matter. A dry coating amount of 1.0 g/r was applied to a 9ti-m thick polyethylene terephthalate film with heat-resistant treatment on the back side of each film.
The cyan of the present invention is coated and dried to achieve rf,
Three-color thermal transfer sheets, magenta and yellow, were obtained.
２ヱヱＬ
Ｋａｙａｓｅｔ Ｂｌｕｅ７１４
１．００部Ｆｏｒｏｎ Ｂｒ１ｌｌｉａｎｔ ＢＩｕｅ
Ｓ−Ｒ４，８０部（分散剤含有）
ポリブチラール樹脂 ４．６０部メチル
エチルケトン ４４．８０部トルエン
４４．８０部ヱ旦ヱＵ
ＭＳ Ｒｅｄ Ｇ ２．
８部１部Ｍａｃｒｏｌｅｘ Ｒｅｄ Ｖｉｏｌｅｔ
Ｒ１，５８部ポリブチラール樹脂 ４．
３２部メチルエチルケトン ４３．３４部
トルエン ４２．９２部シク
ロへキサノン ５．０部工王旦二氾
Ｆｏｒｏｎ Ｂｒ１ｌｌｉａｎｔ Ｙｅｌｌｏｗ Ｓ−
６ＧＬ ｆｌ、００部（分散剤含有）
ポリブチラール樹脂 ４．５２部メチル
エチルケトン ４３．９９部トルエン
４０．９９部シクロヘキサノン
４．５０部次に、基材シートとして
合成紙（玉子油化製。2ヱヱL Kayaset Blue714
1.00 copies Foron Br1lliant BIue
S-R 4.80 parts (contains dispersant) Polybutyral resin 4.60 parts Methyl ethyl ketone 44.80 parts Toluene
44.80 copies Edan EU MS Red G 2.
Part 8 Part 1 Macrolex Red Violet
R1,58 parts polybutyral resin 4.
32 parts Methyl ethyl ketone 43.34 parts Toluene 42.92 parts Cyclohexanone 5.0 parts Foron Br1lliant Yellow S-
6GL fl, 00 parts (contains dispersant) Polybutyral resin 4.52 parts Methyl ethyl ketone 43.99 parts Toluene
40.99 parts cyclohexanone 4.50 parts Next, synthetic paper (manufactured by Tamago Yuka) was used as a base sheet.
ユボＦＰＧ＃１５０）を用い、この一方の面に下記の組
成の塗工液を乾燥時４．５ｇ／ｒｒ？になる割合で塗布
し、１００℃で３０分間乾燥して被転写材を得た。Using Yubo FPG #150), apply a coating liquid with the following composition to one side of the coating at a dry rate of 4.5 g/rr? The transfer material was coated at a ratio of 100° C. and dried at 100° C. for 30 minutes to obtain a transfer material.
ポリエステル樹脂
（Ｖｙｌｏｎ２００、束祥紡製） １１
．５部塩化ビニル−酢酸ビニル共重合体（ＶＹＨＨ１Ｕ
ＣＣ製）５．０部
アミノ変性シリコーンオイル
（ＫＦ−３９３、信越化学工業酸）１．２部エポキシ変
性シリ−コーンオイル
（Ｘ−２２−３４３、信越化学工業製）１．２部メチル
エチルケトン／トルエン／シクロヘキサノン（重量比４
：４：２ ） １０２部前記の本発
明の三色の熱転写シートと上記の被転写材とを、夫々の
染料担持層と染料受容面とを対向させて重ね合せ、熱転
写シートの裏面からヘッド印加電圧ｉｏｖ、印字時間４
、０ｒｓｓｅｃ 、の条件でサーマルヘッドで記録を
行い、三色の画像を得た。これらの三色の画像の演色性
をオフセット印刷インキ（Ｇセットインキ、諸星インキ
製）の標準色による校正印刷画像と対比したところ、良
好な一致が認められた。Polyester resin (Vylon200, manufactured by Sokushobo) 11
．． 5 parts vinyl chloride-vinyl acetate copolymer (VYHH1U
CC) 5.0 parts Amino-modified silicone oil (KF-393, Shin-Etsu Chemical Acid) 1.2 parts Epoxy-modified silicone oil (X-22-343, Shin-Etsu Chemical) 1.2 parts Methyl ethyl ketone/toluene /cyclohexanone (weight ratio 4
:4:2) 102 parts The three-color thermal transfer sheet of the present invention and the transfer material described above were placed one on top of the other with their respective dye-carrying layers and dye-receiving surfaces facing each other, and a head was applied from the back side of the thermal transfer sheet. Voltage iov, printing time 4
Recording was performed with a thermal head under the conditions of , 0 rssec, and a three-color image was obtained. When the color rendering properties of these three-color images were compared with a proof print image using standard colors of offset printing ink (G Set Ink, manufactured by Moroboshi Ink), good agreement was found.
実施例２
実施例１において、三色の染料担持層形成用インキを、
一枚の連続シート（実施例１と回し基材）に一定の面積
で、シアン、マゼンタ、イエローの順で塗布および乾燥
させた以外は実施例１と同様にして三色が連続シート」
−に順々に並んだ本発明の連続シート状のカラー画像形
成用熱転写シートを得た。Example 2 In Example 1, three colors of dye-carrying layer forming inks were used.
A continuous sheet with three colors in the same manner as in Example 1, except that cyan, magenta, and yellow were applied and dried in that order in a fixed area on one continuous sheet (Example 1 and the rotating base material).''
A continuous sheet-shaped thermal transfer sheet for color image formation of the present invention was obtained, in which the color images were arranged in sequence.
この熱転写シートを使用してシアン、マゼンタ、イエロ
ーの順で実施例１と同様にして連続的に熱転写を行いカ
ラー画像を形成した。一方、比較のために、標準オフセ
ットインキ（Ｇセットインキ、諸星インキ製）を使用し
、校正刷機により、同一の原稿からカラー画像を形成し
、上記のカラー画像と比較したところ、肉眼では判別不
能であり、これら二種のカラー画像の演色性は第１図の
如くであった。Using this thermal transfer sheet, thermal transfer was performed successively in the order of cyan, magenta, and yellow in the same manner as in Example 1 to form a color image. On the other hand, for comparison, a color image was formed from the same document using a proofing machine using standard offset ink (G set ink, manufactured by Moroboshi Ink), and when compared with the color image above, it was impossible to distinguish with the naked eye. The color rendering properties of these two types of color images were as shown in FIG.
第１図は、実施例２で得た本発明によるカラー画像（Ａ
）と標準オフセットインキによるカラー画像（Ｂ）の夫
々を反射濃度計（マクベスＲＤ−９１８）を用いて、青
紫、緑、赤のフィルターで濃度を測定し、この値をＧＡ
ＴＦの方式に基すいて作成したカラーサークルである。
手続補正書印発）
昭和６１年 ６月 ９日FIG. 1 shows a color image (A
) and the standard offset ink color image (B) using a reflection densitometer (Macbeth RD-918), measure the density with blue-violet, green, and red filters, and calculate these values as GA.
This is a color circle created based on the TF method. Procedural amendments stamped) June 9, 1986
Claims (3)
染料を含む夫々の染料担持層を有する少なくとも３種の
熱転写シートからなるカラー画像形成用熱転写シートに
おいて、 上記シアン染料が、Ｃ．Ｉ．ソルベントブルー６３およ
び下記式（ I ）で表わされる染料の混合物であり、上
記マゼンタ染料が、Ｃ．Ｉ．ディスパーズレッド６０お
よびＣ．Ｉ．ディスパーズヴァイオレット２６の混合物
であり、且つイエロー染料が、下記式（II）で表わされ
る染料であることを特徴とするカラー画像形成用熱転写
シート。 ▲数式、化学式、表等があります▼（ I ） ▲数式、化学式、表等があります▼（II）(1) A thermal transfer sheet for color image formation comprising at least three types of thermal transfer sheets each having a dye-carrying layer containing a dye of each hue of cyan, magenta, and yellow, wherein the cyan dye is C.I. I. It is a mixture of Solvent Blue 63 and a dye represented by the following formula (I), and the magenta dye is a mixture of C.I. I. Dispersed Red 60 and C.I. I. A thermal transfer sheet for color image formation, which is a mixture of Disperse Violet 26, and wherein the yellow dye is a dye represented by the following formula (II). ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(II)
色の染料担持層が任意の順序で形成されている特許請求
の範囲第（１）項に記載のカラー画像形成用熱転写シー
ト。(2) Thermal transfer sheet for color image formation according to claim (1), wherein the base sheet is one sheet, and dye-supporting layers of three colors are formed on the surface of the base sheet in any order. .
らなる特許請求の範囲第（１）項に記載のカラー画像形
成用熱転写シート。(3) The thermal transfer sheet for color image formation according to claim (1), further comprising a thermal transfer sheet having a black dye-supporting layer.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61097972A JP2506614B2 (en) | 1986-04-30 | 1986-04-30 | Thermal transfer sheet for color image formation |
| EP87902757A EP0270677B1 (en) | 1986-04-30 | 1987-04-30 | Thermal transfer sheet for forming color image |
| DE8787902757T DE3777345D1 (en) | 1986-04-30 | 1987-04-30 | THERMAL TRANSFER LAYER FOR GENERATING COLORED IMAGES. |
| PCT/JP1987/000269 WO1987006533A1 (en) | 1986-04-30 | 1987-04-30 | Thermal transfer sheet for forming color image |
| US07/143,947 US4923846A (en) | 1986-04-30 | 1987-04-30 | Heat transfer sheet for color image formation |
| JP5117600A JP2601439B2 (en) | 1986-04-30 | 1993-04-22 | Thermal transfer sheet for color image formation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61097972A JP2506614B2 (en) | 1986-04-30 | 1986-04-30 | Thermal transfer sheet for color image formation |
Related Child Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5117602A Division JP2631806B2 (en) | 1993-04-22 | 1993-04-22 | Thermal transfer sheet for color image formation |
| JP5117600A Division JP2601439B2 (en) | 1986-04-30 | 1993-04-22 | Thermal transfer sheet for color image formation |
| JP5117601A Division JPH06127157A (en) | 1993-04-22 | 1993-04-22 | Thermal transfer sheet for forming color image |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62255187A true JPS62255187A (en) | 1987-11-06 |
| JP2506614B2 JP2506614B2 (en) | 1996-06-12 |
Family
ID=14206585
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61097972A Expired - Fee Related JP2506614B2 (en) | 1986-04-30 | 1986-04-30 | Thermal transfer sheet for color image formation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2506614B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63288781A (en) * | 1987-05-21 | 1988-11-25 | Dainippon Printing Co Ltd | Thermal transfer sheet for forming color image |
| JPH0248993A (en) * | 1988-05-06 | 1990-02-19 | Eastman Kodak Co | Alkyl or aryl-amino-pyridinyl or pyridinyl-azo yellow-dy dative element for dye heat transfer |
| JPH0284393A (en) * | 1988-09-21 | 1990-03-26 | Hitachi Ltd | Thermal transfer sheet, production thereof and thermal transfer method |
| JPH04195048A (en) * | 1990-11-28 | 1992-07-15 | Fuji Photo Film Co Ltd | Recording material |
| JPH04195047A (en) * | 1990-11-28 | 1992-07-15 | Fuji Photo Film Co Ltd | Recording material |
| JPH06135163A (en) * | 1986-04-30 | 1994-05-17 | Dainippon Printing Co Ltd | Thermal transfer sheet for forming color image |
| US5741754A (en) * | 1994-03-18 | 1998-04-21 | Dai Nippon Printing Co., Ltd. | Method for forming image on object and thermal transfer sheet and thermal transfer image-receiving sheet for use in said method |
| WO2018056395A1 (en) * | 2016-09-23 | 2018-03-29 | 大日本印刷株式会社 | Heat transfer sheet, method for producing print object, and game machine |
-
1986
- 1986-04-30 JP JP61097972A patent/JP2506614B2/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06135163A (en) * | 1986-04-30 | 1994-05-17 | Dainippon Printing Co Ltd | Thermal transfer sheet for forming color image |
| JPS63288781A (en) * | 1987-05-21 | 1988-11-25 | Dainippon Printing Co Ltd | Thermal transfer sheet for forming color image |
| JPH053985B2 (en) * | 1988-05-06 | 1993-01-19 | Eastman Kodak Co | |
| JPH0248993A (en) * | 1988-05-06 | 1990-02-19 | Eastman Kodak Co | Alkyl or aryl-amino-pyridinyl or pyridinyl-azo yellow-dy dative element for dye heat transfer |
| JPH0284393A (en) * | 1988-09-21 | 1990-03-26 | Hitachi Ltd | Thermal transfer sheet, production thereof and thermal transfer method |
| JPH04195048A (en) * | 1990-11-28 | 1992-07-15 | Fuji Photo Film Co Ltd | Recording material |
| JPH04195047A (en) * | 1990-11-28 | 1992-07-15 | Fuji Photo Film Co Ltd | Recording material |
| US5741754A (en) * | 1994-03-18 | 1998-04-21 | Dai Nippon Printing Co., Ltd. | Method for forming image on object and thermal transfer sheet and thermal transfer image-receiving sheet for use in said method |
| US6040269A (en) * | 1994-03-18 | 2000-03-21 | Dai Nippon Printing Co., Ltd. | Method for forming image on object and thermal transfer sheet and thermal transfer image-receiving sheet for use in said method |
| WO2018056395A1 (en) * | 2016-09-23 | 2018-03-29 | 大日本印刷株式会社 | Heat transfer sheet, method for producing print object, and game machine |
| JP6443597B2 (en) * | 2016-09-23 | 2018-12-26 | 大日本印刷株式会社 | Thermal transfer sheet, method for producing printed matter, and game machine |
| JPWO2018056395A1 (en) * | 2016-09-23 | 2019-03-14 | 大日本印刷株式会社 | Thermal transfer sheet, method for producing printed matter, and game machine |
| CN109562631A (en) * | 2016-09-23 | 2019-04-02 | 大日本印刷株式会社 | Hot transfer piece, the manufacturing method of photographic printed material and game machine |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2506614B2 (en) | 1996-06-12 |
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