JPS6222872A - Printing ink - Google Patents
Printing inkInfo
- Publication number
- JPS6222872A JPS6222872A JP60162022A JP16202285A JPS6222872A JP S6222872 A JPS6222872 A JP S6222872A JP 60162022 A JP60162022 A JP 60162022A JP 16202285 A JP16202285 A JP 16202285A JP S6222872 A JPS6222872 A JP S6222872A
- Authority
- JP
- Japan
- Prior art keywords
- printing
- printing ink
- alcohol
- acid
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007639 printing Methods 0.000 title claims abstract description 152
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000002966 varnish Substances 0.000 claims abstract description 21
- 239000000976 ink Substances 0.000 claims description 100
- -1 alcohol ester Chemical class 0.000 claims description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000003086 colorant Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 150000005846 sugar alcohols Polymers 0.000 claims description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 abstract description 17
- 238000001035 drying Methods 0.000 abstract description 15
- 238000003860 storage Methods 0.000 abstract description 8
- 230000002028 premature Effects 0.000 abstract description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 abstract 2
- WGIMXKDCVCTHGW-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOCCO WGIMXKDCVCTHGW-UHFFFAOYSA-N 0.000 abstract 1
- IIOOMEJFHOOGOO-UHFFFAOYSA-N heptyl 2-hydroxyacetate Chemical compound CCCCCCCOC(=O)CO IIOOMEJFHOOGOO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 31
- 239000000463 material Substances 0.000 description 13
- 239000002904 solvent Substances 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000002250 absorbent Substances 0.000 description 6
- 230000002745 absorbent Effects 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- ULCZGKYHRYJXAU-UHFFFAOYSA-N heptacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCO ULCZGKYHRYJXAU-UHFFFAOYSA-N 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N pentadecanoic acid Chemical compound CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- HDQDUBPEBVXIBJ-VOTSOKGWSA-N (e)-hept-1-en-1-ol Chemical compound CCCCC\C=C\O HDQDUBPEBVXIBJ-VOTSOKGWSA-N 0.000 description 2
- JHEPBQHNVNUAFL-AATRIKPKSA-N (e)-hex-1-en-1-ol Chemical compound CCCC\C=C\O JHEPBQHNVNUAFL-AATRIKPKSA-N 0.000 description 2
- GWSURTDMLUFMJH-FOCLMDBBSA-N (e)-hexadec-1-en-1-ol Chemical compound CCCCCCCCCCCCCC\C=C\O GWSURTDMLUFMJH-FOCLMDBBSA-N 0.000 description 2
- LEAQUNCACNBDEV-ZHACJKMWSA-N (e)-undec-1-en-1-ol Chemical compound CCCCCCCCC\C=C\O LEAQUNCACNBDEV-ZHACJKMWSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- NJKOMDUNNDKEAI-UHFFFAOYSA-N beta-sitosterol Natural products CCC(CCC(C)C1CCC2(C)C3CC=C4CC(O)CCC4C3CCC12C)C(C)C NJKOMDUNNDKEAI-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- FIPPFBHCBUDBRR-UHFFFAOYSA-N henicosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCO FIPPFBHCBUDBRR-UHFFFAOYSA-N 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 2
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- ISYWECDDZWTKFF-UHFFFAOYSA-N nonadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCCC(O)=O ISYWECDDZWTKFF-UHFFFAOYSA-N 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- CNNRPFQICPFDPO-UHFFFAOYSA-N octacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCO CNNRPFQICPFDPO-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- IACKKVBKKNJZGN-UHFFFAOYSA-N pentacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCO IACKKVBKKNJZGN-UHFFFAOYSA-N 0.000 description 2
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 2
- 229960003656 ricinoleic acid Drugs 0.000 description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 2
- RGTIBVZDHOMOKC-UHFFFAOYSA-N stearolic acid Chemical compound CCCCCCCCC#CCCCCCCCC(O)=O RGTIBVZDHOMOKC-UHFFFAOYSA-N 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- TYWMIZZBOVGFOV-UHFFFAOYSA-N tetracosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCO TYWMIZZBOVGFOV-UHFFFAOYSA-N 0.000 description 2
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- FPLNRAYTBIFSFW-UHFFFAOYSA-N tricosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCO FPLNRAYTBIFSFW-UHFFFAOYSA-N 0.000 description 2
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- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
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- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 1
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- 239000004386 Erythritol Substances 0.000 description 1
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- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 235000021353 Lignoceric acid Nutrition 0.000 description 1
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021319 Palmitoleic acid Nutrition 0.000 description 1
- DYNKRGCMLGUEMN-YFKPBYRVSA-N Parasorbic acid Chemical compound C[C@H]1CC=CC(=O)O1 DYNKRGCMLGUEMN-YFKPBYRVSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NLDBCFRIELDMRO-UHFFFAOYSA-N Stigmasterin Natural products CCCC(CC)C=CC(C)C1CCC2C3CC=C4CC(O)CCC4(C)C3CCC12C NLDBCFRIELDMRO-UHFFFAOYSA-N 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 1
- HHORIIVYWGOMNE-UHFFFAOYSA-N aniline;prop-1-ene Chemical group CC=C.NC1=CC=CC=C1 HHORIIVYWGOMNE-UHFFFAOYSA-N 0.000 description 1
- BBEAQIROQSPTKN-UHFFFAOYSA-N antipyrene Natural products C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- MJVXAPPOFPTTCA-UHFFFAOYSA-N beta-Sistosterol Natural products CCC(CCC(C)C1CCC2C3CC=C4C(C)C(O)CCC4(C)C3CCC12C)C(C)C MJVXAPPOFPTTCA-UHFFFAOYSA-N 0.000 description 1
- LGJMUZUPVCAVPU-UHFFFAOYSA-N beta-Sitostanol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(CC)C(C)C)C1(C)CC2 LGJMUZUPVCAVPU-UHFFFAOYSA-N 0.000 description 1
- KTFZDGGBFILTSA-UHFFFAOYSA-N beta-Sitosterin Natural products CCC(CC)CCC(C)C1CCC2C1CCC3C2CC=C4CC(O)CCC34C KTFZDGGBFILTSA-UHFFFAOYSA-N 0.000 description 1
- OILXMJHPFNGGTO-ZAUYPBDWSA-N brassicasterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)/C=C/[C@H](C)C(C)C)[C@@]1(C)CC2 OILXMJHPFNGGTO-ZAUYPBDWSA-N 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- SGNBVLSWZMBQTH-PODYLUTMSA-N campesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](C)C(C)C)[C@@]1(C)CC2 SGNBVLSWZMBQTH-PODYLUTMSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- INSRQEMEVAMETL-UHFFFAOYSA-N decane-1,1-diol Chemical compound CCCCCCCCCC(O)O INSRQEMEVAMETL-UHFFFAOYSA-N 0.000 description 1
- 238000011981 development test Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- GTZOYNFRVVHLDZ-UHFFFAOYSA-N dodecane-1,1-diol Chemical compound CCCCCCCCCCCC(O)O GTZOYNFRVVHLDZ-UHFFFAOYSA-N 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- DNVPQKQSNYMLRS-APGDWVJJSA-N ergosterol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@@H](CC[C@@]3([C@@H]([C@H](C)/C=C/[C@H](C)C(C)C)CC[C@H]33)C)C3=CC=C21 DNVPQKQSNYMLRS-APGDWVJJSA-N 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010460 hemp oil Substances 0.000 description 1
- HOZOFMIVACKJMX-UHFFFAOYSA-N heptadecane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCC(O)O HOZOFMIVACKJMX-UHFFFAOYSA-N 0.000 description 1
- MHIBEGOZTWERHF-UHFFFAOYSA-N heptane-1,1-diol Chemical compound CCCCCCC(O)O MHIBEGOZTWERHF-UHFFFAOYSA-N 0.000 description 1
- SRYDOKOCKWANAE-UHFFFAOYSA-N hexadecane-1,1-diol Chemical compound CCCCCCCCCCCCCCCC(O)O SRYDOKOCKWANAE-UHFFFAOYSA-N 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- VLHZUYUOEGBBJB-UHFFFAOYSA-N hydroxy stearic acid Natural products OCCCCCCCCCCCCCCCCCC(O)=O VLHZUYUOEGBBJB-UHFFFAOYSA-N 0.000 description 1
- JNNNAJIAXISWGB-UHFFFAOYSA-N icosane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCCCCC(O)O JNNNAJIAXISWGB-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 238000007644 letterpress printing Methods 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- XGFDHKJUZCCPKQ-UHFFFAOYSA-N n-nonadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCCO XGFDHKJUZCCPKQ-UHFFFAOYSA-N 0.000 description 1
- SOUPDDNOZIKOBV-UHFFFAOYSA-N nonadecane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCCCC(O)O SOUPDDNOZIKOBV-UHFFFAOYSA-N 0.000 description 1
- FVXBCDWMKCEPCL-UHFFFAOYSA-N nonane-1,1-diol Chemical compound CCCCCCCCC(O)O FVXBCDWMKCEPCL-UHFFFAOYSA-N 0.000 description 1
- HOUDCAFABFEPLY-UHFFFAOYSA-N octadeca-9,11,13-trien-1-ol Chemical compound CCCCC=CC=CC=CCCCCCCCCO HOUDCAFABFEPLY-UHFFFAOYSA-N 0.000 description 1
- VJQGGZWPOMJLTP-UHFFFAOYSA-N octadecane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCCC(O)O VJQGGZWPOMJLTP-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- UGAGPNKCDRTDHP-UHFFFAOYSA-N omega-hydroxypalmitic acid Natural products OCCCCCCCCCCCCCCCC(O)=O UGAGPNKCDRTDHP-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- DYNKRGCMLGUEMN-UHFFFAOYSA-N parasorbic acid Natural products CC1CC=CC(=O)O1 DYNKRGCMLGUEMN-UHFFFAOYSA-N 0.000 description 1
- FDUBTTQMOFEVRB-UHFFFAOYSA-N pentadecane-1,1-diol Chemical compound CCCCCCCCCCCCCCC(O)O FDUBTTQMOFEVRB-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- KZJWDPNRJALLNS-VJSFXXLFSA-N sitosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](CC)C(C)C)[C@@]1(C)CC2 KZJWDPNRJALLNS-VJSFXXLFSA-N 0.000 description 1
- 229950005143 sitosterol Drugs 0.000 description 1
- NLQLSVXGSXCXFE-UHFFFAOYSA-N sitosterol Natural products CC=C(/CCC(C)C1CC2C3=CCC4C(C)C(O)CCC4(C)C3CCC2(C)C1)C(C)C NLQLSVXGSXCXFE-UHFFFAOYSA-N 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- HCXVJBMSMIARIN-PHZDYDNGSA-N stigmasterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)/C=C/[C@@H](CC)C(C)C)[C@@]1(C)CC2 HCXVJBMSMIARIN-PHZDYDNGSA-N 0.000 description 1
- BFDNMXAIBMJLBB-UHFFFAOYSA-N stigmasterol Natural products CCC(C=CC(C)C1CCCC2C3CC=C4CC(O)CCC4(C)C3CCC12C)C(C)C BFDNMXAIBMJLBB-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- CQTBQILMJBCTRS-UHFFFAOYSA-N tetradecane-1,1-diol Chemical compound CCCCCCCCCCCCCC(O)O CQTBQILMJBCTRS-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- ZUDWINGCBFUXNG-UHFFFAOYSA-N tridecane-1,1-diol Chemical compound CCCCCCCCCCCCC(O)O ZUDWINGCBFUXNG-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- GRXOWOKLKIZFNP-UHFFFAOYSA-N undecane-1,1-diol Chemical compound CCCCCCCCCCC(O)O GRXOWOKLKIZFNP-UHFFFAOYSA-N 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、印刷インキに関し、更に詳しく云えば、特に
紙等の吸収性被印刷材の印刷に適し、且つ優れた速乾性
と優れた印刷作業性を与える印刷インキに関する。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a printing ink, and more specifically, it is particularly suitable for printing on absorbent printing materials such as paper, and has excellent quick drying properties and excellent printing properties. Concerning printing ink that provides workability.
(従来の技術)
従来、各種の被印刷材に図柄を与えるために種々の印刷
インキが知られている。(Prior Art) Conventionally, various printing inks have been known for imparting designs to various printing materials.
例えば、プラスチックフィルム、金属、ガラス等の非吸
収性被印刷材の印刷に対しては、含有する溶剤の蒸発に
よって乾燥する溶剤蒸発型の印刷。For example, for printing on non-absorbent printing materials such as plastic films, metals, glass, etc., solvent evaporation printing, which dries by evaporation of the solvent it contains, is used.
インキが使用され、また紙を代表とする吸収性被印刷材
に対しては、含有する溶剤が吸収されて乾燥する印刷イ
ンキ、例えば、平版印刷インキ、凹版印刷インキ、凸版
印刷インキ、シルクスクリーン印刷インキ等が知られて
いる。Ink is used, and for absorbent printing materials such as paper, printing inks that dry by absorbing the solvent they contain, such as lithographic printing ink, intaglio printing ink, letterpress printing ink, silk screen printing Ink etc. are known.
(発明が解決しようとしている問題点)上述の如き各種
の印刷インキは、いずれもそれぞれの印刷形式に応じた
印刷版の表面に薄膜のインキを付与し、付与されたイン
キを被印刷材に転写し、溶剤の蒸発、溶剤の吸収、ワニ
スの酸化重合等によって乾燥させて印刷インキをセット
するものである。(Problem to be solved by the invention) The various printing inks mentioned above apply a thin film of ink to the surface of a printing plate according to each printing format, and transfer the applied ink to the printing material. Then, the printing ink is set by drying the varnish by evaporation of the solvent, absorption of the solvent, oxidative polymerization of the varnish, etc.
従って、これらの印刷インキは、転写後は速やかに乾燥
するのが好ましく、そのように工夫されているが、一方
では印刷インキの保存中あるいは印刷中は、これらの印
刷インキがなるべく乾燥しないことが要求される。これ
らの相反する要求を調整すべく、その乾燥性がコントロ
ールされている。Therefore, it is preferable for these printing inks to dry quickly after transfer, and measures are being taken to do so. However, on the other hand, it is desirable to prevent these printing inks from drying as much as possible during storage or printing. required. In order to adjust these conflicting demands, the drying properties are controlled.
しかしながら、従来の印刷操作は、なかには長時間連続
して行なわれるものもあるが、大部分は、時々中断され
る場合が多く1例えば、−日の作業が終了すると、その
後は翌朝の作業まで放置されることになる。このような
場合においては印刷インキは上述の如き適度の乾燥性が
付与されているため、中断時に印刷機の印刷版やブラン
ケットに付着している印刷インキ層がその中断中に機上
で乾燥することになる。However, while some conventional printing operations may be continuous for long periods of time, most are interrupted only from time to time1. will be done. In such cases, since the printing ink is given appropriate drying properties as mentioned above, the printing ink layer adhering to the printing plate or blanket of the printing press during the interruption will dry on the press during the interruption. It turns out.
このように機上で乾燥すると、そのままでは次回の印刷
開始時に満足できる印刷が行なえないために、印刷の中
断後は直ちに印刷インキを取除くか、あるいは印刷の開
始前に付着した印刷インキを取除くことが必要となる。If it dries on the machine in this way, you will not be able to print satisfactorily the next time you start printing, so either remove the printing ink immediately after printing is interrupted, or remove the adhering printing ink before printing starts. It is necessary to remove it.
このような作業は、例えば1〜2時間の時間が要求され
るため、その間は印刷ができず、またその作業に人員を
要するため、工業上非常に不経済な事態となっている。Such work requires, for example, 1 to 2 hours, during which time printing cannot be performed, and the work requires manpower, making it extremely uneconomical from an industrial standpoint.
従って、印刷インキの保存中、印刷前の準備段階あるい
は印刷中断時に印刷機上で乾燥せず、それにも係わらず
、印刷後の被印刷材上では十分な乾燥速度を有する印刷
インキが理想であり、且つそのような印刷インキが強く
要求されている。これらの要求は、相反する要求である
ため、従来は上記の如き特性を有する印刷インキは提供
し得なかった。Therefore, it would be ideal to have a printing ink that does not dry out on the printing press during storage, during preparation before printing, or during printing interruptions, but which nevertheless has a sufficient drying speed on the substrate after printing. , and there is a strong demand for such printing inks. Since these requirements are contradictory, it has not been possible to provide a printing ink having the above-mentioned characteristics in the past.
本発明者は上述の如き従来技術の欠点を解決し、上述の
業界の要望に応えるべく鋭意研究の結果、従来の印刷イ
ンキ、特に重合型の印刷インキに、特定の化合物を添加
するときは、保存中や印刷機上では非常に乾燥が遅く、
従って印刷操作を1例えば夜間中断したとしても、その
印刷機上では印刷インキが乾燥しないため、次の印刷開
始時に印刷機の機掃が不要で直ちに印刷が開始でき、そ
れにも係わらず被印刷材上では付与された印刷インキの
乾燥が十分に速いインキが得られることを知見して本発
明を完成した。The inventor of the present invention solved the above-mentioned drawbacks of the conventional technology and, as a result of intensive research in order to meet the above-mentioned demands of the industry, found that when adding a specific compound to a conventional printing ink, especially a polymeric printing ink, It dries very slowly during storage and on the printing press.
Therefore, even if a printing operation is interrupted at night, for example, the printing ink will not dry on the printing machine, so there is no need to clean the printing machine when the next printing starts, and printing can be started immediately. The present invention was completed based on the finding that an applied printing ink can be dried sufficiently quickly.
(問題点を解決するための手段)
すなわち2本発明は、着色剤およびワニスからなる印刷
インキに、炭素数6以上のアルコールを添加したことを
特徴とする印刷インキである。(Means for solving the problems) That is, the present invention is a printing ink characterized by adding an alcohol having 6 or more carbon atoms to a printing ink consisting of a colorant and a varnish.
次に本発明を更に詳細に説明すると、本発明者は、印刷
インキ、特に酸化重合型の印刷インキの添加剤について
従来から種々研究の結果、特定の化合物、すなわち炭素
数6以上のアルコールをこのような印刷インキに添加し
てみたところ、印刷インキの保存中や印刷機上では印刷
インキの酸化重合が十分に遅れ、一方、紙等の被印刷材
上では、転写された印刷インキが、従来公知の印刷イン
キと比較して著しく短時間で乾燥し、従って、前記の如
き従来技術の種々の問題点が容易に解決できることを知
見したものである。Next, to explain the present invention in more detail, the present inventor has conducted various studies on additives for printing inks, particularly oxidation-polymerized printing inks, and has discovered that a specific compound, that is, an alcohol having 6 or more carbon atoms, has been added to this additive. When added to printing ink such as It has been found that the printing ink dries in a significantly shorter time than known printing inks, and therefore the various problems of the prior art as described above can be easily solved.
本発明で使用する上記の如き作用をする炭素数6以上の
アルコールについて、更に具体的に説明すれば、本発明
において好ましいものは次の通りである。More specifically, the alcohols having 6 or more carbon atoms that function as described above and are used in the present invention are as follows.
(1)脂肪族アルコール
ヘキサノール、ヘプタツール、オクタツール、ノナノー
ル、デカノール、ウンデカノール、ドデカノール、トリ
デカノール、テトラデカノール。(1) Aliphatic alcohols hexanol, heptatool, octatool, nonanol, decanol, undecanol, dodecanol, tridecanol, tetradecanol.
ペンタデカノール、ヘキサデカメール、ヘプタデカノー
ル、オクタデカノール、ノナデカノール、エイコサノー
ル、ヘンエイコサノール、ドコサノール、トリコサノー
ル、テトラコサノール、ペンタコサノール、ヘキサコサ
ノール、ヘプタコサノール、オクタコサノール、ノナコ
サノール等の飽和脂肪族アルコール:
ヘキセノール、ヘプテノール、オクテノール、ウンデセ
ノール、テトラゾセノール、ベンタデセノール、ヘキサ
デセノール、ヘプタコサノール、オフタデセノール、ヘ
キセノール、ヘプテノール、ウンデセノール、トチセノ
ール、トチセノール、ヘキサデセノール、オレイルアル
コール、エーテルアルコール、リシルイルアルコール、
リシルイルアルコール、エレオステアリルアルコール、
リシルイルアルコール等の不飽和脂肪族アルコール:
コレステリン、カンペステリン、β−シトステリン、ス
チグマスステリン、ブラシカステリン、エルゴステリン
等の脂環族アルコール等が挙げられ、これらの中では特
に炭素a10〜40 のものが好ましい。Saturated fats such as pentadecanol, hexadecamer, heptadecanol, octadecanol, nonadecanol, eicosanol, heneicosanol, docosanol, tricosanol, tetracosanol, pentacosanol, hexacosanol, heptacosanol, octacosanol, nonacosanol Group alcohols: hexenol, heptenol, octenol, undecenol, tetrazocenol, bentadecenol, hexadecenol, heptacosanol, oftadecenol, hexenol, heptenol, undecenol, totisenol, totisenol, hexadecenol, oleyl alcohol, ether alcohol, lysyl alcohol,
lysylyl alcohol, eleostearyl alcohol,
Unsaturated aliphatic alcohols such as lysylyl alcohol: Examples include alicyclic alcohols such as cholesterin, campesterin, β-sitosterin, stigmasterin, brassicasterin, and ergosterin. Preferably.
(2)ヒドロキシカルボン酸と脂肪族アルコールとのエ
ステルアルコール
これらのエステルアルコールを形成するためのヒドロキ
シカルボン酸としては、グリコール酸、乳酸、とドロア
クリル酸、オキシ酪酸、オキシ吉草酸、オキシエナント
酸、オギシカプリル酸、オキシペラルゴン酸、オキシカ
プリン酸、オキシウンデカン酸、オギシトリデカン醜、
オキシミリスチン酸、オキシペンタデカン酸、オキシパ
ルミチン酸、オキシアラキン酸、オキシステアリン酸、
オキジノナデカン酸、オキシアラキン酸、オキシベヘン
酸、オキシテトラコサン酸、オキシヘキサコサン酸、オ
キシトリアコンタン酸、オキシテトラトリアコン酸、プ
ロペニルグリコール酸、パラソルビン酸、β−オキジヒ
ドロソルビン酸、アンプレットル酸、イソアンプレット
ル酸、リシノール酸、リシエライジン酸、オキシナ−ポ
ン酸、カモレン酸等が挙げられる。(2) Ester alcohols of hydroxycarboxylic acid and aliphatic alcohol Hydroxycarboxylic acids for forming these ester alcohols include glycolic acid, lactic acid, doroacrylic acid, oxybutyric acid, oxyvaleric acid, oxyenanthic acid, oxycaprylic acid, oxypelargonic acid, oxycapric acid, oxyundecanoic acid, oxytridecane ugly,
oxymyristic acid, oxypentadecanoic acid, oxypalmitic acid, oxyarachic acid, oxystearic acid,
Oxydinonadecanoic acid, oxyarachic acid, oxybehenic acid, oxytetracosanoic acid, oxyhexacosanoic acid, oxytriacontanoic acid, oxytetratriaconic acid, propenylglycolic acid, parasorbic acid, β-oxydihydrosorbic acid, ampletolic acid , isoampretolic acid, ricinoleic acid, ricieraidic acid, oxynaponic acid, and camoleneic acid.
またこれらのヒドロキシカルボン酸とエステルを形成す
るためのアルコールとしては、Ct〜C5の低級アルコ
ールまたは前記の如きC6以上の脂肪族アルコールが挙
げられる。このようなエステルアルコールとして特に好
ましいのは、総炭素数が6〜45のものである。Examples of alcohols for forming esters with these hydroxycarboxylic acids include Ct to C5 lower alcohols and C6 or higher aliphatic alcohols as described above. Especially preferred as such ester alcohols are those having a total carbon number of 6 to 45.
(3)多価アルコールと脂肪酸とのエステルアルコール
または上記の如き低級アルコールまたは06以上の脂肪
族アルコールとのエーテルアルコール
多価アルコールとしては、例えば、エチレングリコール
、プロピレングリコール、ブタンジオール、ベンタンジ
オール、ヘキサンジオール、ヘプタンジオール、オクタ
ンジオール、ノナンジオール、デカンジオール、ウンデ
カンジオール、ドデカンジオール、トリデカンジオール
、テトラデカンジオール、ペンタデカンジオール、ヘキ
サデカンジオール、ヘプタデカンジオール、オクタデカ
ンジオール、ノナデカンジオール、エイコサンジオール
、ジエチレングリコール、トリエチレングリコール、ポ
リエチレングリコール、ジプロピレングリコール、トリ
プロピレングリコール、ポリプロピレングリコール等の
2価アルコール;グリセリン、ブタントリオール、2−
メチルプロパントリオール、ヘキサントリオール等の3
価アルコールニジグリセリン、トリグリセリン等のポリ
グリセリン、エリトリット、D−1L−またはraC−
トリイット、ペンタエリトリット(ペンタエリスリトー
ル)、アトニット、D−1L−またはrac−アラビッ
ト(アラビトール)、キシリット、アリット、D−1L
−またはrac−タリット(タリトール)、D−、L−
またはraC−ソルビット(ソルビトール)、D−1L
−またはraC−マンニット(マンニトール)、ラクト
ース等の多価アルコール等が挙げられる。(3) Ester alcohol of polyhydric alcohol and fatty acid or ether alcohol of lower alcohol or aliphatic alcohol of 06 or more as mentioned above Polyhydric alcohols include, for example, ethylene glycol, propylene glycol, butanediol, bentanediol, hexane. Diol, heptanediol, octanediol, nonanediol, decanediol, undecanediol, dodecanediol, tridecanediol, tetradecanediol, pentadecanediol, hexadecanediol, heptadecanediol, octadecanediol, nonadecanediol, eicosanediol, diethylene glycol, Dihydric alcohols such as triethylene glycol, polyethylene glycol, dipropylene glycol, tripropylene glycol, polypropylene glycol; glycerin, butanetriol, 2-
3 such as methylpropanetriol, hexanetriol, etc.
Polyglycerin such as dihydric glycerin and triglycerin, erythritol, D-1L- or raC-
triit, pentaerythritol (pentaerythritol), atonite, D-1L- or rac-arabitol (arabitol), xylit, allit, D-1L
- or rac-talit (talitol), D-, L-
or raC-sorbitol, D-1L
- or raC-Mannitol, polyhydric alcohols such as lactose, and the like.
これらの多価アルコールとエーテルアルコールを形成す
るアルコールとしては前記の如き種々のアルコールが使
用される。As the alcohol for forming ether alcohol with these polyhydric alcohols, the various alcohols mentioned above are used.
またエステルアルコールを形成する脂肪酸としては、ギ
酸、酢酸、プロピオン酸、醋酸、吉草酸、カプロン酸、
エナントs、カプリル酸、ベラ。In addition, fatty acids that form ester alcohols include formic acid, acetic acid, propionic acid, acetic acid, valeric acid, caproic acid,
enant s, caprylic acid, vera.
ルゴン酸、カプリン酸、ウンデシル酸、ラウリン酸、ト
リデシル酸、ミリスチン酸、ペンタデシル酸、パルミチ
ン酸、ステアリン酸、ノナデカン酸、アラキン酸、ベヘ
ン酸、リグノセリン酸、セロチン酸、ヘプタコン酸、モ
ンタン酸、メリシン酸、ラフセル酸等の脂肪族飽和酸ニ
アクリル酸、クロトン酸、イソクロトン酸、カプリル(
711、ラウロレイン醜、ミリストレイン酸、パルミト
レイン酸、オレイン酸、エライジン酸、ソルビン酸、リ
ノール酸、リルン酸、ステアロール酸、エレオステアリ
ン酸、リシノール酸、アラキドン酸、タルパノドン酸、
アビエチン酸等の中〜高級不飽和脂肪酸、ヒマシ油、ア
マニ油、大豆油、サフラワー油、シナキリ油1日本キリ
油、ヒマワリ油、二)油、麻実油、トール油、ゴマ油、
コムギ胚芽油、トウモロコシ油、ナタネ油、コメヌカ油
、脱水ヒマシ油、綿実油、イカ油、魚油、鯨油等から得
られる混合不飽和脂肪酸等が挙げられる。rugonic acid, capric acid, undecylic acid, lauric acid, tridecylic acid, myristic acid, pentadecylic acid, palmitic acid, stearic acid, nonadecanoic acid, arachidic acid, behenic acid, lignoceric acid, cerotic acid, heptaconic acid, montanic acid, melisic acid , aliphatic saturated acids such as lafcelic acid, niacrylic acid, crotonic acid, isocrotonic acid, caprylic acid (
711, laurolein ugly, myristoleic acid, palmitoleic acid, oleic acid, elaidic acid, sorbic acid, linoleic acid, lylinic acid, stearolic acid, eleostearic acid, ricinoleic acid, arachidonic acid, tarpanodonic acid,
Medium to higher unsaturated fatty acids such as abietic acid, castor oil, linseed oil, soybean oil, safflower oil, sinakiri oil (1) Japanese tung oil, sunflower oil, (2) oil, hempseed oil, tall oil, sesame oil,
Examples include mixed unsaturated fatty acids obtained from wheat germ oil, corn oil, rapeseed oil, rice bran oil, dehydrated castor oil, cottonseed oil, squid oil, fish oil, whale oil, and the like.
これらのエーテルアルコールまたはエステルアルコール
のうちで特に好ましいものは総炭素数が6〜45のアル
コールである。Particularly preferred among these ether alcohols or ester alcohols are alcohols having a total carbon number of 6 to 45.
(4)アンモニア、有機アミン、アルコール、フェノー
ル等の単官能化合物を開始剤としたポリアルキレンオキ
サイド
例えば一方の末端がアンモニア、有機アミン、アルコー
ル、フェノールの残基であり、他方の末端が水酸基であ
るポリエチレンオキサイド、ポリプロピレンオキサイド
、ポリブチレンオキサイド等が挙げられる。(4) Polyalkylene oxide using a monofunctional compound such as ammonia, organic amine, alcohol, or phenol as an initiator.For example, one end is a residue of ammonia, organic amine, alcohol, or phenol, and the other end is a hydroxyl group. Examples include polyethylene oxide, polypropylene oxide, polybutylene oxide, and the like.
以上の例示は、本発明を説明するためのものであって、
上記以外の炭素数6以上のアルコールであっても、上記
と同様な機能を有するものは本発明に当然包含されるも
のである。The above examples are for explaining the present invention,
Even if it is an alcohol having 6 or more carbon atoms other than those mentioned above, those having the same functions as those mentioned above are naturally included in the present invention.
以上の如き従来公知の特定のアルコールは、いずれも本
発明において使用できるものであるが、本発明において
特に好適なものは、常温で不〜難揮発性であり、ワニス
中に可溶または安定に分散し得る化合物である。Any of the above-mentioned conventionally known specific alcohols can be used in the present invention, but those that are particularly suitable for the present invention are those that are non- to slightly volatile at room temperature and soluble or stable in varnish. It is a compound that can be dispersed.
これらの特定のアルコールが、常温で揮発性であったり
、あるいはワニス中に可溶性または分散性でないときは
、印刷機上での印刷インキの乾燥が十分には抑制されず
、また印刷後の印刷インキの乾燥速度が十分ではなくな
る。If these specific alcohols are volatile at room temperature or are not soluble or dispersible in the varnish, drying of the printing ink on the printing press may not be sufficiently suppressed, and the printing ink may not dry after printing. drying speed becomes insufficient.
本発明では、上記の如き特定のアルコールを、印刷イン
キ中に添加するときは、印刷インキの保存中あるいは印
刷機上では、印刷インキ中にこれら特定のアルコールが
均一に存在し、且つこれらの特定のアルコールは揮発性
でないために、印刷インキの重合、すなわち乾燥が遅れ
、従って前述の如き従来技術の問題点が解決されたもの
である。In the present invention, when the above-mentioned specific alcohols are added to printing ink, these specific alcohols are uniformly present in the printing ink during storage of the printing ink or on the printing machine, and these specific alcohols are added to the printing ink. Since the alcohol is not volatile, the polymerization and drying of the printing ink is delayed, thus solving the problems of the prior art as described above.
更に、本発明の印刷インキが被印刷材に付与されると、
特に被印刷材が紙の如き吸収性の被印刷材であるときは
、印刷インキ中のワニス中に溶解または安定に分散して
いる上記の特定のアルコールが、被印刷材中に速やかに
吸収されるため、被印刷材上に残った着色剤とワニスか
らなる成分は、従来の印刷インキと同等またはそれ以上
に速やかに乾燥することを知見し、本発明の目的が完全
に達成されたものである。Furthermore, when the printing ink of the present invention is applied to a printing material,
In particular, when the printing material is an absorbent printing material such as paper, the above-mentioned specific alcohol dissolved or stably dispersed in the varnish in the printing ink is quickly absorbed into the printing material. It has been found that the components consisting of the colorant and varnish remaining on the printing material dry as quickly as or faster than conventional printing inks, and the object of the present invention has been completely achieved. be.
従って、本発明の印刷インキは、特に紙の如き吸収性の
被印刷材の印刷、例えば平版印刷用のインキとして有用
である。Therefore, the printing ink of the present invention is particularly useful as an ink for printing on absorbent printing materials such as paper, for example for lithographic printing.
また、上記の如き特定のアルコールは、あまりに多量に
使用するのは経済的ではなく、また印刷後の乾燥を過度
に遅らせることがあり、また使用量が少なすぎるときは
、本発明の効果が十分に達成できない。In addition, it is not economical to use the specific alcohols mentioned above in too large a quantity, and the drying process after printing may be excessively delayed, and if the specific alcohols used are too small, the effects of the present invention may not be sufficient. cannot be achieved.
本発明者の詳細な研究によれば、本発明で使用する上記
の如き特定のアルコールは、印刷インキ100重量部中
で一般的には約 5〜70重量部を占める割合、より好
ましくは約 7〜40 重量部を占める割合であり、こ
のような使用割合において本発明の目的が十分に達成す
ることができる。According to the inventor's detailed research, the above-mentioned specific alcohol used in the present invention generally accounts for about 5 to 70 parts by weight, more preferably about 7 parts by weight, in 100 parts by weight of printing ink. This proportion accounts for ~40 parts by weight, and the purpose of the present invention can be fully achieved at such a proportion.
本発明の印刷インキの成分は、上記の如き特定の化合物
を添加する以外は、いずれも従来技術と同様でよい。The components of the printing ink of the present invention may be the same as those of the prior art, except for the addition of the above-mentioned specific compounds.
例えば、本発明の印刷インキを構成する着色剤は、従来
の印刷インキに使用されている顔料あるいは染料であっ
て、従来公知の顔料あるいは染料は本発明の印刷インキ
の着色剤としていずれもそのまま使用できるものである
。また、その使用量も従来公知の印刷インキと同様でよ
く1例えば、印刷インキ100重量部中で、例えば約1
0〜40重量部を占める割合が一般的である。For example, the colorant constituting the printing ink of the present invention is a pigment or dye that is used in conventional printing ink, and any conventionally known pigment or dye can be used as it is as the colorant in the printing ink of the present invention. It is possible. Further, the amount used may be the same as that of conventionally known printing inks. For example, in 100 parts by weight of printing ink, for example, about 1
The proportion is generally 0 to 40 parts by weight.
また、本発明の印刷インキを構成するワニスも、従来公
知の印刷インキ用ワニスはいずれも本発明においてその
まま使用できるものであり、その使用量も従来と同様に
、例えば印刷インキ100重量部中で約50〜80重量
部を占める割合が一般的である。Further, as for the varnish constituting the printing ink of the present invention, any conventionally known printing ink varnish can be used as is in the present invention, and the amount used is the same as before, for example, in 100 parts by weight of the printing ink. A proportion of about 50 to 80 parts by weight is common.
本発明の印刷インキのワニスとして好ましいものは、従
来の平版印刷インキ等に使用されている天然または合成
の酸化重合型樹脂、すなわちそれらの構造中に重合性二
重結合を有し、空気中の酸素によって型巻硬化して被膜
を構成するものである。これらの平版印刷インキ用のワ
ニスは、多数のものが公知であり1本発明においてはこ
れら公知のものがいずれも使用し得る。Preferable varnishes for the printing ink of the present invention are natural or synthetic oxidation-polymerizable resins used in conventional lithographic printing inks, that is, those having polymerizable double bonds in their structure and It forms a film by being mold-cured with oxygen. Many varnishes for these lithographic printing inks are known, and any of these varnishes can be used in the present invention.
本発明の印刷インキは上記の着色剤、ワニスおよび特定
のアルコールを主要な構成材料としており、その他イン
キ溶剤、ドライヤー、レベリング改良剤、増粘剤、皮張
り防止剤その他従来公知の添加剤は本発明の印刷インキ
においていずれも使用できる。The printing ink of the present invention has the above-mentioned colorant, varnish, and specific alcohol as its main constituent materials, and other conventionally known additives such as an ink solvent, a dryer, a leveling improver, a thickener, and an anti-skinning agent are also used. Either can be used in the printing ink of the invention.
例えば、インキ溶剤は、インキの粘度、稠度、フロー等
を修正をするために加えられるものであり、印刷インキ
用として従来使用されている各種の有機溶剤、例えば、
軽油、スピンドル油、各種インキソルベント、マシン油
等はいずれも使用し得るものであり、その使用量は、印
刷インキ100重量部中で約5〜80重量部を占める割
合が一般的である。For example, ink solvents are added to modify the viscosity, consistency, flow, etc. of ink, and various organic solvents conventionally used for printing inks, such as
Light oil, spindle oil, various ink solvents, machine oil, etc. can all be used, and the amount used is generally about 5 to 80 parts by weight per 100 parts by weight of printing ink.
ドライヤーとしては、コバルト、マンガン、セリウム、
ジルコニウム、鉛、鉄、亜鉛、銅、バナジウム、バリウ
ム、カルシウム等の多価金属のナフテン酸、オクチル酸
、樹脂酸、トール油等の油溶性カルボン酸の塩等であり
、これらのドライヤーは、印刷インキ100重量部中金
属として約0.005〜0.5重量%を占める割合で使
用するのが一般的である。As a dryer, cobalt, manganese, cerium,
These dryers are salts of polyvalent metals such as zirconium, lead, iron, zinc, copper, vanadium, barium, and calcium and oil-soluble carboxylic acids such as naphthenic acid, octylic acid, resin acid, and tall oil. Generally, the metal is used in an amount of about 0.005 to 0.5% by weight based on 100 parts by weight of the ink.
本発明の印刷インキは、前記の如き特定のアルコールを
印刷インキに添加する外は、その製造は従来公知の製造
方法、例えばロールによる混合練肉等がいずれも使用で
きる。The printing ink of the present invention can be manufactured by any conventionally known manufacturing method, such as mixing with a roll or the like, except for adding the above-mentioned specific alcohol to the printing ink.
(作用Φ効果)
以上の如き本発明のよれば、すでに述べた通り、印刷イ
ンキ中に特定のアルコールを適当な量で添加することに
よって、印刷インキの保存中あるいは印刷機上での印刷
インキの早すぎる乾燥を防止できるため、印刷操作を中
断し、かなりの時間が経過しても、印刷機上の印刷イン
キは実質的にそのままで未乾燥であるから、次の印刷開
始時に何らの機掃や特別の準備操作を要しないで直ちに
印刷を開始ができる。(Action Φ Effect) According to the present invention as described above, by adding an appropriate amount of a specific alcohol to the printing ink, the printing ink can be used during storage or on the printing press. Premature drying can be prevented, so even if a printing operation is interrupted and a considerable period of time has elapsed, the printing ink on the press remains virtually intact and undried, without any cleaning required when the next printing starts. Printing can be started immediately without any special preparatory operations.
従って、従来技術における印刷機の手数がかかり不経済
な機掃や印刷安定化までの不経済なならし運転等の種々
の問題点が解決された。それにも係わらず、特に吸収性
の被印刷材に印刷後の印刷インキの速やかな乾燥は何ら
阻害されないものである。Therefore, various problems of conventional printing presses, such as time-consuming and uneconomical cleaning and uneconomical running-in operation until printing is stabilized, have been solved. Nevertheless, this does not in any way hinder the rapid drying of the printing ink after printing, especially on absorbent printing materials.
次に実施例および比較例を挙げて本発明を更に具体的に
説明する。なお、文中、部とあるのは重量基準である。Next, the present invention will be explained in more detail with reference to Examples and Comparative Examples. Note that parts in the text are based on weight.
実施例1
酸化重合型ワニス250部とインステアリルアルコール
62.5部とを混合し、該混合物75.3部、ブリリア
ントカーミツ6820部、ナンテン酸マンガン0.8部
および165号ソルベント4.0部を配合し、三木ロー
ルで混合練肉し、タック値が10.2の本発明の印刷イ
ンキを得た。Example 1 250 parts of oxidative polymerization type varnish and 62.5 parts of instearyl alcohol were mixed, and 75.3 parts of the mixture, 6820 parts of brilliant carmite, 0.8 parts of manganese nanthenate, and 4.0 parts of No. 165 solvent were added. were mixed and kneaded using a Miki roll to obtain a printing ink of the present invention having a tack value of 10.2.
この印刷インキO,15mJlを4分割R1テスターで
アート紙に展色した。そのアート紙の展色面の光沢を測
定したところ67%であった。一方、上記印刷インキを
RIテスター上に一夜放置した後同様に展色したものの
光沢は29%であリ、印刷インキの優れた保存安定性を
示した。なお、アート紙上での印刷インキの乾燥時間は
4時間であった。15 mJl of this printing ink O was spread on art paper using a 4-division R1 tester. The gloss of the color surface of the art paper was measured and found to be 67%. On the other hand, when the printing ink was left on an RI tester overnight and then developed in the same manner, the gloss was only 29%, indicating the excellent storage stability of the printing ink. Note that the drying time of the printing ink on the art paper was 4 hours.
また、上記の印刷インキのテストを行った後・印刷機を
何ら洗浄することなく一夜放置し、翌朝再度印刷を試み
たところ、何らの支障もなくそのまま印刷が可flであ
った。In addition, after testing the above printing ink, the printing machine was left overnight without any cleaning, and printing was attempted again the next morning, and printing continued without any problems.
比較例1
実施例1で用いたインステアリルアルコールを添加する
前のワニス65.6部、ブリリアントカーミツ6820
部、ナフテン酸マンガン0.8部および165号ソルベ
ント14.6部を、三木ロールで混合練肉し、タック値
が9.9である比較用の印刷インキを得た。Comparative Example 1 65.6 parts of the varnish used in Example 1 before adding instearyl alcohol, Brilliant Carmite 6820
1, 0.8 parts of manganese naphthenate, and 14.6 parts of Solvent No. 165 were mixed and kneaded using a Miki roll to obtain a comparative printing ink having a tack value of 9.9.
このインキについて実施例1と同様にして展色試験を行
ったところ、光沢は73%であるに対し、RIテスター
上に一夜放置した場合の光沢は18%であり、印刷イン
キの保存安定性が不十分であることを宗した。また、ア
ート紙上での印刷インキの乾燥時間は4時間であった。When this ink was subjected to a color development test in the same manner as in Example 1, the gloss was 73%, but when left overnight on an RI tester, the gloss was 18%, indicating that the storage stability of the printing ink was He believed in being inadequate. The drying time of the printing ink on art paper was 4 hours.
また、印刷試験後−夜放置後の再印刷では、印刷版面の
インキが乾燥し不溶性の膜を生じ、印刷インキの転移不
良を生じ、そのままでは再印刷が不能であった。In addition, in reprinting after the printing test and after being left overnight, the ink on the printing plate surface dried to form an insoluble film, resulting in poor transfer of the printing ink, and reprinting was impossible as it was.
実施例2〜13
実施例1の特定のアルコールに代えて、下記第1表に示
す他の特定のアルコールを用い、他は実施例1と同様に
して印刷インキを調製し、同様にテストしたところ、下
記第1表の結果を得た。Examples 2 to 13 Printing inks were prepared in the same manner as in Example 1, except that other specific alcohols shown in Table 1 below were used in place of the specific alcohol in Example 1, and tested in the same manner. , the results shown in Table 1 below were obtained.
ト 1 −
2 デカノール 65294時間3 ロデカ
ノール 87314時間30分4 オレイルアル
コ 832E14時間30分−ル
5 グリコール酸へ 88344時間15分ブチル
エステル
6 ラウリン酸ジエ 8229 3時間45分チレ
ングリコー
ルエステル
7 カプリン酸プロ 83284時間ピレングリコ
−
ルエステル
8 ヒマシ油脂肪酸 60274時間45分9
大豆油脂脂肪酸 85324時間15分ジクリセライ
ド
10 ノニルフェノ−83304時間30分ルエチレ
ンオキ
サイド付加物
11 オクチルフェア 83304時間30分−ル
プロピレン
オギサイド付加
物
12 ラウリルアミン 80284時間15分エチ
レンオキサ
イド付加物
13 アニリンプロピ 60324時間45分し・
ンオキサイド
付加物
尚、上記実施例2〜13の印刷インキは、いずれも印刷
機上で一夜放置しても乾燥しなかった。To 1-2 Decanol 65294 hours 3 Rhodecanol 87314 hours 30 minutes 4 Oleyl alcohol 832E 14 hours 30 minutes - to glycolic acid 88344 hours 15 minutes Butyl ester 6 Lauric acid diene 8229 3 hours 45 minutes Thylene glycol ester 7 Capric acid pro 83284 hours Pyrene glycol ester 8 Castor oil fatty acid 60274 hours 45 minutes 9
Soybean fat and oil fatty acid 85324 hours 15 minutes Diglyceride 10 Nonylpheno-83304 hours 30 minutes - ethylene oxide adduct 11 Octylfair 83304 hours 30 minutes - propylene oxide adduct 12 Laurylamine 80284 hours 15 minutes Ethylene oxide adduct 13 Aniline propylene 60324 hours 45 minutes.
Incidentally, all of the printing inks of Examples 2 to 13 did not dry even when left on the printing press overnight.
これに対し、上記の如き特定のアルコールを添加しなか
った同様の印刷インキの場合には、印刷試験後−夜放置
後の再印刷では、印刷版面のインキが乾燥し不溶性の膜
を生じ、印刷インキの転移不良を生じ、そのままでは再
印刷が不能であった。On the other hand, in the case of a similar printing ink without the addition of specific alcohol as mentioned above, when reprinting after the printing test and after being left overnight, the ink on the printing plate dries and forms an insoluble film, causing the printing Poor ink transfer occurred, and reprinting was impossible as it was.
Claims (8)
数6以上のアルコールを添加したことを特徴とする印刷
インキ。(1) A printing ink characterized by adding an alcohol having 6 or more carbon atoms to a printing ink consisting of a colorant and a varnish.
である特許請求の範囲第(1)項に記載の印刷インキ。(2) The printing ink according to claim (1), wherein the alcohol is an aliphatic alcohol having 6 or more carbon atoms.
ルエステルである特許請求の範囲第(1)項に記載の印
刷インキ。(3) The printing ink according to claim (1), wherein the alcohol is an alcohol ester of hydroxycarboxylic acid.
テルアルコールまたはアルコールとのエーテルアルコー
ルである特許請求の範囲第(1)項に記載の印刷インキ
。(4) The printing ink according to claim (1), wherein the alcohol is an ester alcohol of a polyhydric alcohol and an organic acid or an ether alcohol of an alcohol.
アルキレンオキサイドである特許請求の範囲第(1)項
に記載の印刷インキ。(5) The printing ink according to claim (1), wherein the alcohol is a polyalkylene oxide using a monofunctional compound as an initiator.
求の範囲第(1)項に記載の印刷インキ。(6) The printing ink according to claim (1), wherein the alcohol is non- to slightly volatile at room temperature.
し得るものである特許請求の範囲第(1)項に記載の印
刷インキ。(7) The printing ink according to claim (1), wherein the alcohol is soluble or stably dispersible in the varnish.
〜70重量部の割合で存在する特許請求の範囲第(1)
項に記載の印刷インキ。(8) Alcohol is about 5 parts by weight in 100 parts by weight of printing ink.
Claim No. (1) present in a proportion of ~70 parts by weight
Printing inks listed in section.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60162022A JPS6222872A (en) | 1985-07-24 | 1985-07-24 | Printing ink |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60162022A JPS6222872A (en) | 1985-07-24 | 1985-07-24 | Printing ink |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6222872A true JPS6222872A (en) | 1987-01-31 |
JPH0556392B2 JPH0556392B2 (en) | 1993-08-19 |
Family
ID=15746574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60162022A Granted JPS6222872A (en) | 1985-07-24 | 1985-07-24 | Printing ink |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6222872A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5837046A (en) * | 1995-02-08 | 1998-11-17 | Xaar Technology Limited | Ink jet printer ink composition |
JP2009073953A (en) * | 2007-09-21 | 2009-04-09 | The Inctec Inc | Ink composition |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07314271A (en) * | 1994-05-31 | 1995-12-05 | Noritake Co Ltd | Clamping device for workpiece |
-
1985
- 1985-07-24 JP JP60162022A patent/JPS6222872A/en active Granted
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5837046A (en) * | 1995-02-08 | 1998-11-17 | Xaar Technology Limited | Ink jet printer ink composition |
JP2009073953A (en) * | 2007-09-21 | 2009-04-09 | The Inctec Inc | Ink composition |
Also Published As
Publication number | Publication date |
---|---|
JPH0556392B2 (en) | 1993-08-19 |
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