JPS62227794A - Indelible article - Google Patents
Indelible articleInfo
- Publication number
- JPS62227794A JPS62227794A JP61071287A JP7128786A JPS62227794A JP S62227794 A JPS62227794 A JP S62227794A JP 61071287 A JP61071287 A JP 61071287A JP 7128786 A JP7128786 A JP 7128786A JP S62227794 A JPS62227794 A JP S62227794A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- photochromic material
- printed
- irradiation
- immediately
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 13
- 238000000862 absorption spectrum Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000003973 paint Substances 0.000 description 5
- 238000012795 verification Methods 0.000 description 5
- 230000002265 prevention Effects 0.000 description 4
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000004893 oxazines Chemical class 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Credit Cards Or The Like (AREA)
- Holders For Sensitive Materials And Originals (AREA)
- Exposure Or Original Feeding In Electrophotography (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔発明の目的〕
（産業上の利用分野）
本発明は可視光線もしくは紫外線によって発色もしくは
変色し、加熱するか放置することによって再びものと色
に戻る材料を含有する放置防止物に関する。Detailed Description of the Invention [Objective of the Invention] (Industrial Application Field) The present invention relates to a material that develops or changes color when exposed to visible light or ultraviolet rays, and returns to its original color when heated or left. Regarding prevention.
（従来の技術）
従来、キャッシュカード、パスポート、印鑑証明書カー
ド、各種免許証、身分証明書、証券等には照゛ 合や
改■防止のために様々な機能が施されている。(Prior Art) Conventionally, cash cards, passports, seal certificate cards, various driver's licenses, identification cards, securities, etc. have been equipped with various functions for verification and prevention of tampering.
例えば通常の条件下で肉眼を以てしては視認し得ないよ
うにし、特定の操作によってのみ視認できる機能のある
螢光物質、液晶、導電性物質、磁性物質を施すことによ
って照合や改■防止機能が付与されている。これらの方
法は２例えば、肉眼での通常の条件下で視認防止効果が
不十分であったり、使用中の剥離、損傷や放置が容易で
あったり、照合の操作が容易に出来なかったりして、従
来の方法では照合や改■防止機能は必ずしも満足なもの
でない。For example, by applying a fluorescent material, liquid crystal, conductive material, or magnetic material that cannot be seen with the naked eye under normal conditions and can only be seen by specific operations, verification and tampering prevention functions can be applied. has been granted. For example, these methods may not be sufficiently effective in preventing visual recognition under normal conditions when viewed with the naked eye, may be easily peeled off, damaged or left unattended during use, or may not be easy to perform verification operations. However, in the conventional methods, the collation and tamper prevention functions are not necessarily satisfactory.
また、メタメリズムを利用した隠しインキ、偽造防止用
印刷物なども知られている（特公昭４６−２５２８８号
、特開昭５４−１２７７０９号公報）。Hidden ink using metamerism, printed materials for preventing counterfeiting, and the like are also known (Japanese Patent Publication No. 46-25288, Japanese Patent Application Laid-open No. 127709-1982).
このメタメリズムは、可視光線の領域においてはほぼ同
様の色調を有する２種以上の色素であって、赤外線の領
域では反射率を異にするそれぞれのインキを組合せるこ
とにより、肉眼での通常の条件下では視認し得ず、赤外
線の領域のみの光線を透過するフィルターを通して始め
て視認することができる手段である。しかしながら、メ
タメリズムは有用な手段と期待されながらも、メタメリ
ズムを示す色素が少ない。This metamerism is created by combining two or more types of pigments that have almost the same color tone in the visible light range, but with different reflectance in the infrared range, under normal conditions with the naked eye. This means that it cannot be seen from below, and can only be seen through a filter that transmits only light in the infrared region. However, although metamerism is expected to be a useful tool, there are few pigments that exhibit metamerism.
本発明者は、各種証明用カードの照合や放置防止。The inventor of the present invention aims to verify various identification cards and prevent them from being left unattended.
紙幣、証券の改東防止等について鋭意検討した結果、従
来よりも優れた照合や装置防止機能を有する改東防止物
を見い出した。As a result of intensive research into ways to prevent banknotes and securities from changing their dates, we have discovered a device that prevents them from changing their dates.
本発明は、基材に、フォトクロミック材料を含有するイ
ンキで文字、地紋、彩紋等の模様状に印刷または筆記し
てなる改■防止物である。The present invention is an anti-tampering product which is formed by printing or writing on a base material a pattern such as letters, a ground pattern, a colored pattern, etc. using an ink containing a photochromic material.
すなわちフォトクロミック材料を含有するインキを用い
た改■防止物である。That is, it is a tamper-proof product using ink containing a photochromic material.
本発明によると、フォトクロミック材料を用いて塗料、
印刷インキおよび着色樹脂組成物等を製造し、各種カー
ド、証券等にほどこすことによって、照合や改東を防止
することができる。According to the present invention, paint using photochromic material,
By producing printing ink, colored resin compositions, etc., and applying them to various cards, securities, etc., verification and East change can be prevented.
本発明に係わるフォトクロミック材料とはある波長の光
（主にＵＶ）を吸収して着色体に変わり、この着色体が
別の波数の光を吸収するか、あるいは熱処理によりもと
にもどる可逆的変化を示す化合物で、スピロピラン類、
ポリマー化したスピロピラン類、オキサジン系、スピラ
ン類、フルギド類、チオエン類などがある。The photochromic material related to the present invention is a reversible change that absorbs light of a certain wavelength (mainly UV) and changes into a colored body, and that this colored body absorbs light of a different wave number or returns to its original state by heat treatment. Compounds that show spiropyrans,
These include polymerized spiropyrans, oxazines, spiranes, fulgides, and thioenes.
本発明のフォトクロミック材料は通常樹脂中に分散させ
た状態１例えば印刷インキ、塗料等で使用される。The photochromic material of the present invention is usually used in the form of a dispersion in a resin, such as in printing inks, paints, etc.
本インキは、各種カード、証券等に使用して照合や偽造
防止能力を有する印刷物、筆記物を得ることができる。This ink can be used for various cards, securities, etc. to obtain printed materials and written materials that have verification and anti-counterfeiting abilities.
なお、基材としては紙、プラスチックフィルム。The base material is paper or plastic film.
プラスチック成形物などである。Plastic molded products, etc.
本発明によれば前記のフォトクロミンク材料を印刷イン
キや塗料等に使用する樹脂に３本ロール、アトライター
、サンドミルやボールミル中で分散して印刷インキや塗
料とし、目的物に印刷したり、塗布したり、筆記したり
することによって目的を達成する。なお２本発明に係わ
るインキには紫外線吸収剤およびまたは酸化防止剤を併
用することができる。According to the present invention, the photochromink material is dispersed in a resin used for printing ink, paint, etc. in a three-roll, attritor, sand mill, or ball mill to form a printing ink or paint, and the material is printed on a target object. Achieve a goal by painting or writing. Note that the ink according to the present invention may contain an ultraviolet absorber and/or an antioxidant.
このようにして得られた印刷物等は通常の条件下での肉
眼による視認では単なる印刷物等として認知できるにす
ぎないが、従来から知られている紫外線や可視光線を照
射すると、特定の印刷物等であることが認知できる。Printed materials obtained in this way can be recognized as mere printed materials when visually inspected with the naked eye under normal conditions, but when irradiated with conventionally known ultraviolet rays or visible light, certain printed materials, etc. I can recognize something.
その後必要とあらば別の波長の光を照射するか。After that, if necessary, light of a different wavelength can be irradiated.
加熱処理することによって１着色体が消色する。この操
作は繰り返して行うことができる。フォトクロミンク材
料を選択することによって着色体の色相をかえることが
できる。スピロピラン類を用いる場合には、紫、オレン
ジ、青、緑色が一般的である。One colored body is decolored by heat treatment. This operation can be repeated. By selecting a photochromic material, the hue of the colored body can be changed. When spiropyrans are used, purple, orange, blue, and green are commonly used.
従って、証明用カードや証券等に本発明のフォトクロミ
ンク材料を通用することにより、簡単な検知手段で、容
易に認知照合できる結果、改■等を防止することもでき
る。Therefore, by using the photochromic material of the present invention in identification cards, securities, etc., it is possible to easily recognize and verify the information using a simple detection means, and as a result, it is possible to prevent tampering.
以下実施例によって、詳細に説明する。This will be explained in detail below using examples.
実施例１
１．３．３−）ジメチル−６−二トロスビロビラン２ｇ
をポリエステル樹脂溶液（東洋紡績■製バイロン２００
のメチルイソブチルケトン２０％溶液）５０ｇとペイン
トコンディショナーによって充分混練してグラビアイン
キを作った。このインキを２０μｍの厚みのポリエステ
ルフィルムにグラビア印刷校正機によって印刷し、乾燥
し、透明な印刷物を得た。塗膜の厚さは５μｍであった
。Example 1 1.3.3-) 2 g of dimethyl-6-nitros bilobyran
Polyester resin solution (Byron 200 manufactured by Toyobo Co., Ltd.)
A gravure ink was prepared by thoroughly kneading 50 g of a 20% solution of methyl isobutyl ketone with a paint conditioner. This ink was printed on a 20 μm thick polyester film using a gravure proofing machine and dried to obtain a transparent printed matter. The thickness of the coating film was 5 μm.
このフィルムに紫外光線（波長＞ ３１０ ｎｍ）を５
秒間照射した直後に分光々変針（ＵＶ−３６５島津製作
所′！Ａ）を用いて吸光スペクトルを測定した。また、
このフィルムを８０℃のオーブン中に５分間入れ直後に
吸光スペクトルを測定した。これらの結果を第１図に示
した。図中Ａは未照射フィルム、Ｂは紫外光線照射直後
、Ｃは加熱直後およびＤはこの操作を１００回くりかえ
した直後の吸収スペクトルを表わす。図面から明らかな
ようにＢには５５０〜６００ｎｍにかけて強い吸収が認
められ、ＣとＤはほぼＡに一致している。このことから
本実施例に示したようなインキを用いて印刷した商券な
どを紫外線照射装置を用いることによって無色から発色
させて識別し、加熱することによってもとの無色の状態
にもどすことができる。無色の状態は肉眼では識別でき
ないので改東防止などに有効である。This film was exposed to ultraviolet light (wavelength > 310 nm) for 5
Immediately after the second irradiation, the absorption spectrum was measured using a spectroscopic variable needle (UV-365 Shimadzu '!A). Also,
The absorption spectrum was measured immediately after placing this film in an oven at 80° C. for 5 minutes. These results are shown in FIG. In the figure, A represents the unirradiated film, B represents the absorption spectrum immediately after irradiation with ultraviolet light, C represents the absorption spectrum immediately after heating, and D represents the absorption spectrum immediately after this operation was repeated 100 times. As is clear from the drawing, strong absorption is observed in B from 550 to 600 nm, and C and D almost match A. From this, it is possible to distinguish a commercial card printed using the ink shown in this example by changing it from colorless to colored by using an ultraviolet irradiation device, and returning it to its original colorless state by heating it. can. Since the colorless state cannot be identified with the naked eye, it is effective in preventing eastern changes.
実施例１と同様にしてフォトクロミンク材料をかえてイ
ンキを作りポリエステルフィルムに印刷して印刷物を作
った。紫外線照射前、照射後、加熱処理後の各々の色相
は次のようであり、実施例１と同様な紫外線照射識別、
加熱処理を行うことによって商品などのかくし印刷とし
て改東防止などに有効であることが明らかとなった。In the same manner as in Example 1, ink was prepared by changing the photochromic material and printed on a polyester film to produce printed matter. The hues before UV irradiation, after irradiation, and after heat treatment are as follows, and the same UV irradiation identification as in Example 1,
It has become clear that heat treatment can be used as a covert print on products to prevent eastern changes.
第１図は分光々変針を用いて吸光スペクトルを測定した
グラフであり、横軸に波長、縦軸に吸光度を示す。曲線
Ａは紫外線未照射、Ｂは紫外線を５秒照射直後、ＣはＢ
をさらに８０℃に５分間加熱直後。
Ｄはこの操作を１０回繰り返した直後の各々のフィルム
の吸収スペクトルを示す。FIG. 1 is a graph obtained by measuring an absorption spectrum using a spectrometer, in which the horizontal axis shows wavelength and the vertical axis shows absorbance. Curve A is without UV irradiation, B is immediately after 5 seconds of UV irradiation, and C is B
Immediately after further heating to 80°C for 5 minutes. D shows the absorption spectrum of each film immediately after repeating this operation 10 times.
Claims (1)
文字、地紋、彩紋等の模様状に印刷または筆記してなる
ことを特徴とする改■防止物。 ２、フォトクロミック材料がスピロピラン系化合物であ
る特許請求の範囲第１項記載の改■防止物。[Scope of Claims] 1. A tamper-proof product characterized by having patterns such as letters, background patterns, and colored patterns printed or written on a base material using ink containing a photochromic material. 2. The anti-tampering product according to claim 1, wherein the photochromic material is a spiropyran compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61071287A JPS62227794A (en) | 1986-03-31 | 1986-03-31 | Indelible article |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61071287A JPS62227794A (en) | 1986-03-31 | 1986-03-31 | Indelible article |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62227794A true JPS62227794A (en) | 1987-10-06 |
Family
ID=13456329
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61071287A Pending JPS62227794A (en) | 1986-03-31 | 1986-03-31 | Indelible article |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62227794A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01154799A (en) * | 1987-12-11 | 1989-06-16 | Kokando Co Ltd | Optical conversion recording card |
| JPH01223181A (en) * | 1988-01-12 | 1989-09-06 | Sicpa Holding Sa | Photochromic printing ink and its production |
| JPH01262194A (en) * | 1988-04-14 | 1989-10-19 | Toppan Printing Co Ltd | Photochromism card and gate passing system using the card |
| JPH01283193A (en) * | 1988-05-11 | 1989-11-14 | Toppan Printing Co Ltd | Card and identification thereof |
| JPH03126673U (en) * | 1990-04-03 | 1991-12-20 | ||
| US5344191A (en) * | 1992-12-09 | 1994-09-06 | Wallace Computer Services, Inc. | Hidden entry system and use thereof |
| JPH06301827A (en) * | 1993-04-16 | 1994-10-28 | Toray Ind Inc | Discrimination mark display body, commodity with the same, and discrimination mark reading method |
| US5427415A (en) * | 1992-12-09 | 1995-06-27 | Wallace Computer Services, Inc. | Heat sensitive system and use thereof |
| US5431452A (en) * | 1993-08-23 | 1995-07-11 | Wallace Computer Services, Inc. | Hidden entry system and image-developing device therefor |
| US5618063A (en) * | 1992-12-09 | 1997-04-08 | Wallace Computer Services, Inc. | Multicolor heat-sensitive verification and highlighting system |
| US5807625A (en) * | 1988-01-12 | 1998-09-15 | Sicpa Holding S.A. | Security document with reversibly photochromic printing inks |
| JP2012078872A (en) * | 2003-07-01 | 2012-04-19 | Transitions Optical Inc | Polarizing photochromic device and method for manufacturing the same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5297740A (en) * | 1976-02-12 | 1977-08-16 | Kyodo Printing Co Ltd | Format and printed matter difficultly capable of duplication |
| JPS5297741A (en) * | 1976-02-12 | 1977-08-16 | Kyodo Printing Co Ltd | Checking method using copying machine |
-
1986
- 1986-03-31 JP JP61071287A patent/JPS62227794A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5297740A (en) * | 1976-02-12 | 1977-08-16 | Kyodo Printing Co Ltd | Format and printed matter difficultly capable of duplication |
| JPS5297741A (en) * | 1976-02-12 | 1977-08-16 | Kyodo Printing Co Ltd | Checking method using copying machine |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01154799A (en) * | 1987-12-11 | 1989-06-16 | Kokando Co Ltd | Optical conversion recording card |
| JPH01223181A (en) * | 1988-01-12 | 1989-09-06 | Sicpa Holding Sa | Photochromic printing ink and its production |
| US5807625A (en) * | 1988-01-12 | 1998-09-15 | Sicpa Holding S.A. | Security document with reversibly photochromic printing inks |
| JPH01262194A (en) * | 1988-04-14 | 1989-10-19 | Toppan Printing Co Ltd | Photochromism card and gate passing system using the card |
| JPH01283193A (en) * | 1988-05-11 | 1989-11-14 | Toppan Printing Co Ltd | Card and identification thereof |
| JPH03126673U (en) * | 1990-04-03 | 1991-12-20 | ||
| US5618063A (en) * | 1992-12-09 | 1997-04-08 | Wallace Computer Services, Inc. | Multicolor heat-sensitive verification and highlighting system |
| US5427415A (en) * | 1992-12-09 | 1995-06-27 | Wallace Computer Services, Inc. | Heat sensitive system and use thereof |
| US5644352A (en) * | 1992-12-09 | 1997-07-01 | Wallace Computer Services, Inc. | Multicolor heat-sensitive verification and highlighting system |
| US5344191A (en) * | 1992-12-09 | 1994-09-06 | Wallace Computer Services, Inc. | Hidden entry system and use thereof |
| JPH06301827A (en) * | 1993-04-16 | 1994-10-28 | Toray Ind Inc | Discrimination mark display body, commodity with the same, and discrimination mark reading method |
| US5431452A (en) * | 1993-08-23 | 1995-07-11 | Wallace Computer Services, Inc. | Hidden entry system and image-developing device therefor |
| JP2012078872A (en) * | 2003-07-01 | 2012-04-19 | Transitions Optical Inc | Polarizing photochromic device and method for manufacturing the same |
| JP2014016626A (en) * | 2003-07-01 | 2014-01-30 | Transitions Optical Inc | Polarizing photochromic device and method of manufacturing the same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69721855T2 (en) | pigment compositions | |
| DE602004013360T2 (en) | SAFETY DOCUMENT, METHOD FOR PRODUCING A SECURITY DOCUMENT AND USE OF A SECURITY ELEMENT | |
| KR102325796B1 (en) | Optically variable magnetic security threads and stripes | |
| US5289547A (en) | Authenticating method | |
| EP1274585B2 (en) | Method for producing laser-writable data carriers and data carrier produced according to this method | |
| RU2641864C2 (en) | Optically variable security threads and strips | |
| DE3741179A1 (en) | DOCUMENT WITH FALSE-PROOF SURFACE RELIEF AND METHOD FOR PRODUCING THE SAME | |
| CN105980162B (en) | Safety line and bar | |
| DE69802696T2 (en) | COMPOSITE FILM STRUCTURE | |
| WO2003032243A1 (en) | Valuable document and security mark using a marking substance | |
| EP1156934A1 (en) | Value document | |
| DE102016201709A1 (en) | Value or security product, process for producing an intermediate product and verification process | |
| JPS62227794A (en) | Indelible article | |
| EP2734383A1 (en) | Microcapsule and use thereof, security element having microcapsules and data carrier equipped therewith | |
| DE69029888T2 (en) | Writing media | |
| JPH03154187A (en) | Record identifiable by near infrared rays | |
| EP3012784B1 (en) | Selective optical data carrier | |
| EP3047429B1 (en) | Manipulation-safe valuable or security product and method for verifying the authenticity of the manipulation-safe valuable or security product | |
| RU2634772C1 (en) | Optically variable security threads and strips | |
| JP2589701B2 (en) | Thermal transfer material | |
| KR100603103B1 (en) | Specific security thread and security papers using the same | |
| EP3046777B1 (en) | Method for producing a security feature of a value or security product | |
| JP2634050B2 (en) | Thermal transfer material | |
| EP3838994A1 (en) | An ink recipe composition for printing a multi-color image in a security element on a substrate, which element is visible both in the wavelength range of visible light (vis) and in the wavelength range of ultraviolet light (uv), a method of preparation of a system with such security element on a substrate and a system to be used as a security or identification feature of the object marked with such system | |
| JPH0410973A (en) | Recorded matter for identification |