JPS62199633A - Filler for composite material - Google Patents
Filler for composite materialInfo
- Publication number
- JPS62199633A JPS62199633A JP4030186A JP4030186A JPS62199633A JP S62199633 A JPS62199633 A JP S62199633A JP 4030186 A JP4030186 A JP 4030186A JP 4030186 A JP4030186 A JP 4030186A JP S62199633 A JPS62199633 A JP S62199633A
- Authority
- JP
- Japan
- Prior art keywords
- filler
- composite material
- acid
- resin
- metallic soap
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000945 filler Substances 0.000 title claims abstract description 32
- 239000002131 composite material Substances 0.000 title claims abstract description 13
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- 239000000344 soap Substances 0.000 claims abstract description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000010949 copper Substances 0.000 claims abstract description 9
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 7
- 239000010954 inorganic particle Substances 0.000 claims abstract description 7
- 238000004381 surface treatment Methods 0.000 claims abstract description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 229910052718 tin Inorganic materials 0.000 claims abstract description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 4
- 239000010941 cobalt Substances 0.000 claims abstract description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011256 inorganic filler Substances 0.000 claims abstract description 4
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 4
- 239000011133 lead Substances 0.000 claims abstract description 4
- 239000011135 tin Substances 0.000 claims abstract description 4
- 239000010936 titanium Substances 0.000 claims abstract description 4
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 4
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 4
- 239000011701 zinc Substances 0.000 claims abstract description 4
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000839 emulsion Substances 0.000 abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000377 silicon dioxide Substances 0.000 abstract description 3
- 238000012856 packing Methods 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- -1 pallite Substances 0.000 description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000012774 insulation material Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 241000779819 Syncarpia glomulifera Species 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910000464 lead oxide Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000001739 pinus spp. Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229940036248 turpentine Drugs 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- JXSRRBVHLUJJFC-UHFFFAOYSA-N 7-amino-2-methylsulfanyl-[1,2,4]triazolo[1,5-a]pyrimidine-6-carbonitrile Chemical compound N1=CC(C#N)=C(N)N2N=C(SC)N=C21 JXSRRBVHLUJJFC-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229910001323 Li2O2 Inorganic materials 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- ZCGHEBMEQXMRQL-UHFFFAOYSA-N benzyl 2-carbamoylpyrrolidine-1-carboxylate Chemical compound NC(=O)C1CCCN1C(=O)OCC1=CC=CC=C1 ZCGHEBMEQXMRQL-UHFFFAOYSA-N 0.000 description 1
- GONOPSZTUGRENK-UHFFFAOYSA-N benzyl(trichloro)silane Chemical compound Cl[Si](Cl)(Cl)CC1=CC=CC=C1 GONOPSZTUGRENK-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- QAEKNCDIHIGLFI-UHFFFAOYSA-L cobalt(2+);2-ethylhexanoate Chemical compound [Co+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O QAEKNCDIHIGLFI-UHFFFAOYSA-L 0.000 description 1
- AMFIJXSMYBKJQV-UHFFFAOYSA-L cobalt(2+);octadecanoate Chemical compound [Co+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AMFIJXSMYBKJQV-UHFFFAOYSA-L 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010920 waste tyre Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 101150050492 ytfJ gene Proteins 0.000 description 1
Abstract
Description
【発明の詳細な説明】
挟倣分粁
本発明は、樹脂との混合により得られる柔軟性９機械強
度、加工性に優れたシート状あるいは塗料状複合材を製
造するためのフィラーに関するものであり、遮音材、ｎ
ｇ Ｓｔ ｋｋ ｙｔｆＪタコ午蕗士子 ｒｌ
ｂｍＨｌ＆ａｅｔＦＬ ａｌｌ？Ｒ＆、ＬＩＭ＋
Ｌなど多方面の複合材料製造に適用するフィラーである
６従米挟権
カーボンブラック、グラファイト、セラミックス、酸化
鉄、鉄、銅、銀、パライト、鉛、酸化鉛等の無機質粒子
フィラーとして各種樹脂に混合した遮音材、吸音材。[Detailed Description of the Invention] The present invention relates to a filler for producing a sheet-like or paint-like composite material with excellent flexibility, mechanical strength, and workability, which can be obtained by mixing with a resin. , sound insulation material, n
g St kk ytfJ takogobushiko rl
bmHl&aetFL all? R&, LIM+
Mixed with various resins as inorganic particle filler such as carbon black, graphite, ceramics, iron oxide, iron, copper, silver, pallite, lead, lead oxide, etc., which is a filler that is applied to the production of composite materials in various fields such as L. Sound insulation and sound absorbing materials.
導電性シート、塗料が多種知られている。シート状に加
工し、自動車やビルや壁面に敷設したり、鋼板や不織布
と張り合わせた遮音材としての用途には１面密度が大で
、しかも柔軟性と機械的強度を有し、かつ成型加工性が
良いことが要求される。しかし樹脂に対し無機質粒子は
概して親和性に乏しく、大量の充填を行うと何れかの性
能が低下する。導電性樹脂組成物においても、カーボン
ブラック等を多量充填するのが望ましいのであるが、得
られるシートや塗膜の機械強度が低下し易い。また成形
加工時にフィラーが浮きあがる現象が見られる。塗料に
おいては、振動や衝撃による亀裂の発生やフィラーの脱
離があってはならない。Many types of conductive sheets and paints are known. It has a high surface density, has flexibility and mechanical strength, and is suitable for use as a sound insulating material by processing it into sheets and laying them on cars, buildings, and walls, or laminating them with steel plates or nonwoven fabrics, and which also has flexibility and mechanical strength. Good sexuality is required. However, inorganic particles generally have poor affinity for resins, and if a large amount is filled, some of the properties will deteriorate. Although it is desirable to fill a conductive resin composition with a large amount of carbon black, etc., the mechanical strength of the resulting sheet or coating film tends to decrease. In addition, a phenomenon in which the filler lifts up during the molding process is observed. Paints must not develop cracks or detach from fillers due to vibration or impact.
可撓性を有するシートや遮音被膜は、曲面に密着敷設が
可能のみならず、共鳴作用なく振動吸収と遮音作用を発
揮する。Flexible sheets and sound insulation coatings can not only be placed closely on curved surfaces, but also exhibit vibration absorption and sound insulation effects without resonance effects.
本発明が解決しようとする問題点
本発明者は、柔軟性に優れた複合材を、加工性良く製造
する研究を重ねたところ、フィラーを予め金属石鹸で表
面処理を施すことにより樹脂とフィラー接着力が著しく
向上し、柔軟性を維持しつつ充填可能量を高めることが
可能で、しかも機械強度が大きく、上記の全ての目的に
全く適合する事の知見を得て本発明の完成に至った。Problems to be Solved by the Invention The inventor of the present invention has repeatedly conducted research into manufacturing composite materials with excellent flexibility and good workability, and found that by surface-treating the filler with metal soap in advance, the resin and the filler adhere to each other. The present invention was completed based on the knowledge that the force is significantly improved, the amount of fillable material can be increased while maintaining flexibility, and the mechanical strength is high, which completely satisfies all of the above objectives. .
光呪例孤戊
本発明は、樹脂即ちバインダーに充填して複合材を製造
するに使用する無機質フィラーにおいて、鉄、スズ、コ
バルト、鉛、ジルコニウム、銅、亜鉛、ニッケル、チタ
ニウムの何れかを含有する金属石鹸の少なくとも１種若
しくは２種以上で表面処理したことを特徴とする複合材
用フィラーである。以下により詳しく内容を説明する。The present invention provides an inorganic filler that is used to manufacture a composite material by filling it into a resin, that is, a binder, containing any one of iron, tin, cobalt, lead, zirconium, copper, zinc, nickel, and titanium. This filler for composite materials is characterized by being surface-treated with at least one or two or more types of metal soaps. The details will be explained in more detail below.
本発明のフィラーは無機質粒子であり、樹脂あるいはア
スファルトに充填使用される。目的に適する種類が選ば
れる。例えば面密度の向上、導電性の付与あるいは顔料
や増量剤として酸化鉄、鉄、パライト、鉛、酸化鉛等の
球状、繊維状粒子、カーボンブラック、グラファイト。The filler of the present invention is an inorganic particle, and is used to fill resin or asphalt. The type suitable for the purpose is selected. For example, spherical or fibrous particles such as iron oxide, iron, pallite, lead, lead oxide, carbon black, graphite, etc. to improve areal density, impart electrical conductivity, or as a pigment or filler.
銅、銀、ニッケル等の粒子、チタニア、シリカ、アルミ
ナ等各種に適用される。よって対象とするフィラーは特
に制限されるものでは無い。遮音材のごとく、密度のフ
ィラーを大量に充填する場合、得ちれる遮音材の機械強
度が低下したり、プレートアウト現象を起こしたりフィ
ラーの分散が不均一になりがちであるが、本発明はこれ
ら現象の防止に有効である。Applicable to various particles such as copper, silver, nickel, etc., titania, silica, alumina, etc. Therefore, the target filler is not particularly limited. When filling a large amount of dense filler, such as in a sound insulation material, the mechanical strength of the resulting sound insulation material tends to decrease, a plate-out phenomenon occurs, and the filler is unevenly distributed. It is effective in preventing these phenomena.
本発明のフィラーは、金属石鹸で表面処理されたもので
ある。使用される金属石鹸としては、鉄、スズ、コバル
ト、鉛、ジルコニウム、銅、亜鉛、ニッケル、チタニウ
ムの何れかを含有する有機酸塩である。有機酸として炭
素２〜２０の脂肪酸、不飽和脂肪酸、ナフテン酸であり
、具体的には酢酸、プロピオン酸、オクチル酸、デカン
酸、ウンデカン酸、ドデカン酸、ヘキサン酸、２−エチ
ルヘキサン酸、ヘキサデカン酸、リノール酸、オレイン
酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチ
ン酸、ステアリン酸、トール油脂肪酸、ダイマー酸が例
示される。したがってこれら酸の前記金属塩が金属石鹸
として使用される。The filler of the present invention is surface-treated with metal soap. The metal soap used is an organic acid salt containing any of iron, tin, cobalt, lead, zirconium, copper, zinc, nickel, and titanium. Organic acids include fatty acids with 2 to 20 carbon atoms, unsaturated fatty acids, and naphthenic acids, specifically acetic acid, propionic acid, octylic acid, decanoic acid, undecanoic acid, dodecanoic acid, hexanoic acid, 2-ethylhexanoic acid, and hexadecane. Examples include linoleic acid, oleic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, tall oil fatty acid, and dimer acid. The metal salts of these acids are therefore used as metal soaps.
前記金属石鹸を無機質粒子の表面に金属分として約１０
〜５０００ｗｔ、ｐｐｍ好ましくは５０ないし１１００
０ｐｐ担持したものである。表面処理は、金属石鹸の溶
液又はエマルジョン液をフィラーに散布又は浸漬し。The metal soap is added to the surface of the inorganic particles with a metal content of about 10
~5000wt, ppm preferably 50 to 1100
0pp was supported. Surface treatment involves spraying or dipping the filler in a metal soap solution or emulsion.
乾燥すれば良い。溶剤として石油エキストラクト芳香族
系溶媒、ミネラルターペン、酢酸エステル、アミルアル
コール、ブチルアルコール等が好適である。特に水エマ
ルジョンの場合では、界面活性剤、特にノニオン系のも
のを少量添加した液が好適である。Just dry it. Suitable solvents include petroleum extract aromatic solvents, mineral turpentine, acetic acid esters, amyl alcohol, butyl alcohol, and the like. Particularly in the case of a water emulsion, a liquid containing a small amount of a surfactant, especially a nonionic one, is suitable.
前記の金属石鹸で表面処理された無機質粒子は、樹脂（
バインダー）に配合して使用される。即ちバインダーと
しては目的に応じ軟質塩化ビニル樹脂、塩化ビニル−酢
酸ビニル共重合体、エチレン−酢酸ビニル共重合体、ポ
リエステル樹脂、塩素化ポリエチレン樹脂、ポリプロピ
レン、ポリエチレン、スチレン−ブタジェンゴム、ブチ
ルゴム、アクリルニトリルゴム、シリコンゴム、フェノ
ール樹脂あるいは酢酸ビニールやエポキシ樹脂等の塗料
用接着性樹脂が使用される。廃ケーブル被覆材や農芸用
使用済みの塩化ビニールシート、廃タイヤは好ましいバ
インダーの１種である。また樹脂やゴム入りの石油アス
ファルトを使用することも出来る。The inorganic particles surface-treated with the metal soap described above are coated with resin (
binder). That is, depending on the purpose, the binder may include soft vinyl chloride resin, vinyl chloride-vinyl acetate copolymer, ethylene-vinyl acetate copolymer, polyester resin, chlorinated polyethylene resin, polypropylene, polyethylene, styrene-butadiene rubber, butyl rubber, acrylonitrile rubber. , silicone rubber, phenolic resin, or adhesive resin for paint such as vinyl acetate or epoxy resin. Waste cable sheathing material, used agricultural and agricultural vinyl chloride sheets, and waste tires are preferred binders. It is also possible to use petroleum asphalt containing resin or rubber.
これらバインダーに対し上記の表面処理されたフィラー
は極めて親和性が良く、一定量のバインダーに対し多量
のフィラーを充填しても柔軟性と良好な耐屈曲性を維持
できる。目的に応じ、バインダー１００重量部当たりフ
ィラー５０〜１０００重量部の割合で混合される。The above-mentioned surface-treated filler has a very good affinity with these binders, and even if a large amount of filler is filled with a certain amount of binder, flexibility and good bending resistance can be maintained. Depending on the purpose, the filler is mixed at a ratio of 50 to 1000 parts by weight per 100 parts by weight of the binder.
以下実施例に基づき説明する。The following will be explained based on examples.
実施例 １
塩化ビニール樹脂１００重量部、可塑剤としてＤＯＰ６
０重量部、錫系安定剤５重量部の割合のコンパウンド１
６４重量部に、以下の前処理したフィラーを５００゜７
００及び８００重量部混合し、混練した。・８インチ×
２０インチの２本ロールで１．０ｍ厚さのシートを製造
した。加工性および製品の性能の評価結果を第１表に示
す・
フィラー
ＦｅＯとＦｅ、Ｏ，合計７７ｗｔ％、シリカ２１ｗｔ％
。Example 1 100 parts by weight of vinyl chloride resin, DOP6 as plasticizer
Compound 1 in the proportion of 0 parts by weight and 5 parts by weight of tin-based stabilizer
Add the following pretreated filler to 64 parts by weight at 500°7
00 and 800 parts by weight were mixed and kneaded.・8 inches
A 1.0 m thick sheet was produced using two 20 inch rolls. The evaluation results of workability and product performance are shown in Table 1.Fillers FeO, Fe, O, total 77wt%, silica 21wt%
.
アルミナ１．１ｗｔ％、水分０＝５ｗｔ％の組成の銅製
錬工程で発生の鉄精鉱スラグ
２不二二例直外環
２−エチルヘキサン酸コバルト石鹸のミネラルターペン
液（Ｇｏ分；１０ｗｔ％）を、フィラー１００重量部当
たりＧ。Iron concentrate slag generated in the copper smelting process with a composition of alumina 1.1 wt% and moisture 0 = 5 wt% Mineral turpentine liquid of cobalt 2-ethylhexanoate soap (Go content: 10 wt%) , G per 100 parts by weight of filler.
として０．１重量部の割合で均一に散布し、１２０℃で
乾燥した。（以下余白）
第１表 加工性及び製品の評価結果
性１）ＪＩＳ−Ｌｉ２Ｏ２ストリップ法理２）１８０度
に５０回折曲げで表面を観察第１表に示されているよう
に、金属石鹸で表面処理したフィラーを使用したシート
は、シート表面が光沢を持ち１機械強度も向上する。The mixture was uniformly dispersed at a ratio of 0.1 part by weight and dried at 120°C. (Leaving space below) Table 1 Processability and product evaluation results 1) JIS-Li2O2 strip method 2) Observing the surface by bending 50 times at 180 degrees As shown in Table 1, surface treatment with metal soap Sheets using this filler have a glossy surface and improved mechanical strength.
実施例２
実施例１で使用の塩化ビニール樹脂コンパウンド１６５
重量部に対しステアリン酸銅（Ｓｔｅｒ、Ｃｕと略す）
、ナフテン酸ジルコニウム（Ｎａｐｈ、Ｚｒと略す）及
びナフテン酸コバルト（Ｎａｐｈ、ＣＯ）で表面処理し
たフィラー７００重量部を加え、実施例１の方法で厚さ
１．０ＩＩ１１のシートを製造した。得られたーシート
の試験結果を第２表に示す。Example 2 Vinyl chloride resin compound 165 used in Example 1
Copper stearate (Ster, abbreviated as Cu) based on weight part
, 700 parts by weight of fillers surface-treated with zirconium naphthenate (Naph, abbreviated as Zr) and cobalt naphthenate (Naph, CO) were added, and a sheet having a thickness of 1.0II11 was produced by the method of Example 1. The test results of the obtained sheet are shown in Table 2.
第２表
比較例 実施例 実施例 実施例金属石鹸
処理せず ５ｔａｒ、Ｃｕ Ｎａｐｈ、Ｚｒ
Ｎａｐｈ、Ｃ。Table 2 Comparative Examples Examples Examples Examples Metal soaps Not treated 5tar, Cu Naph, Zr
Naph, C.
担持量 −２００２００２００
金属分（ｐｐｍ）
引張強度Ｋｇｆ １５．１ １７．５
１７．６ １７．２実施例３
ブチルゴム（分子量約３２００００） −４９，Ｏ
ｗｔ％低密度ポリエチレン −２７
，５νｔ％ポリイシブチレン（分子量約５８０００）
−１７，Ｏｗｔ％潤滑油エキストラクト油（ｖｉｓ１５
ｃｓｔ、３７．８℃）−５，８ｔｚｔ％フェニルナフチ
ルアミン −０，７ｗｔ％の組成の高
分子材料１００重量部に実施例１のフィラー粉を以下の
通り処理し、これを５００重量部混合、混練し厚さ１゜
０ｍｍのシートを製造した。Supported amount -200200200 Metal content (ppm) Tensile strength Kgf 15.1 17.5
17.6 17.2 Example 3 Butyl rubber (molecular weight approximately 320000) -49,O
wt% low density polyethylene -27
, 5νt% polyisobutylene (molecular weight approximately 58,000)
-17, Owt% lubricating oil extract oil (vis15
cst, 37.8°C) -5.8 tzt% phenylnaphthylamine 100 parts by weight of a polymeric material having a composition of -0.7 wt% was treated with the filler powder of Example 1 as follows, and 500 parts by weight of this was mixed and kneaded. A sheet with a thickness of 1°0 mm was produced.
表面処理 Ａ、ステアリン酸コバルト石鹸のキシレン溶
液（Ｃｏ８．０ｗｔ％液）を粉に散布し、１２０〜１４
０℃で乾燥した。Surface treatment A. Sprinkle a xylene solution of cobalt stearate soap (Co8.0wt% solution) on the powder,
It was dried at 0°C.
Ｂ、ノニオン系界面活性剤を添加した酢酸銅のエマルシ
ョン液（Ｃｕ４．５ｗｔ％）を粉に散布し、風乾後、１
２０℃で乾燥した第３表
比較例 実施例 実施例
表面処理 無し Ａ
Ｂ引張り強度タテＫｇｆ １９．５ ２１．
５ ２１．２引裂強度 タテにｇｆ １４．
０ １６．５ １５．９本発明（７）幼果
本発明のフィラーは、樹脂との接着力が極めて強く、フ
ィラーを多量に充填することが可能となり、面密度が大
きいにもかかわらず、得られるシートあるいは皮膜が柔
軟性を示し、機械強度が大きく又成形加工時に起るプレ
ートアウト現象も発生しない。B. A copper acetate emulsion liquid (Cu4.5wt%) added with a nonionic surfactant was sprinkled on the powder, and after air drying, 1
Table 3 Comparative example dried at 20°C Example Example surface treatment None A
B tensile strength vertical Kgf 19.5 21.
5 21.2 Tear strength Vertical gf 14.
0 16.5 15.9 The present invention (7) Young fruits The filler of the present invention has an extremely strong adhesive force with resin, making it possible to fill a large amount of filler, and despite having a large areal density, it is possible to obtain The resulting sheet or film exhibits flexibility, has high mechanical strength, and does not suffer from the plate-out phenomenon that occurs during molding.
Claims (2)
質フィラーにおいて、鉄、スズ、コバルト、鉛、ジルコ
ニウム、銅、亜鉛、ニッケル、チタニウムの何れかを含
有する金属石鹸の少なくとも１種若しくは２種以上で表
面処理したことを特徴とする複合材用フィラー。(1) In the inorganic filler used to manufacture a composite material by filling it into a resin, at least one metal soap containing iron, tin, cobalt, lead, zirconium, copper, zinc, nickel, or titanium, or A filler for composite materials characterized by surface treatment with two or more types.
〜５０００ｗｔ．ｐｐｍ担持させた特許請求の範囲第１
項記載の複合材用フィラー。(2) Metal soap on the surface of inorganic particles, 10% as a metal component
~5000wt. Claim 1 in which ppm is supported
Composite filler as described in section.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4030186A JPS62199633A (en) | 1986-02-27 | 1986-02-27 | Filler for composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4030186A JPS62199633A (en) | 1986-02-27 | 1986-02-27 | Filler for composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62199633A true JPS62199633A (en) | 1987-09-03 |
Family
ID=12576790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4030186A Pending JPS62199633A (en) | 1986-02-27 | 1986-02-27 | Filler for composite material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62199633A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6366247A (en) * | 1986-09-05 | 1988-03-24 | Toyo Tire & Rubber Co Ltd | Production of rubber composition |
| DE102011101880A1 (en) * | 2011-05-18 | 2012-11-22 | Süd-Chemie AG | Process for the preparation of separation media for the purification and / or isolation of enzymes and / or proteins |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4855227A (en) * | 1971-11-12 | 1973-08-03 | ||
| JPS4933942A (en) * | 1972-07-28 | 1974-03-28 | ||
| JPS53142455A (en) * | 1977-05-17 | 1978-12-12 | Iwao Hishida | Particulate inorganic material and molding resin composition using same |
| JPS54140559A (en) * | 1978-04-17 | 1979-10-31 | Philips Nv | Coding and decoding method of body |
| JPS6233888A (en) * | 1985-08-01 | 1987-02-13 | Nippon Mining Co Ltd | Flexible composite material |
-
1986
- 1986-02-27 JP JP4030186A patent/JPS62199633A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4855227A (en) * | 1971-11-12 | 1973-08-03 | ||
| JPS4933942A (en) * | 1972-07-28 | 1974-03-28 | ||
| JPS53142455A (en) * | 1977-05-17 | 1978-12-12 | Iwao Hishida | Particulate inorganic material and molding resin composition using same |
| JPS54140559A (en) * | 1978-04-17 | 1979-10-31 | Philips Nv | Coding and decoding method of body |
| JPS6233888A (en) * | 1985-08-01 | 1987-02-13 | Nippon Mining Co Ltd | Flexible composite material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6366247A (en) * | 1986-09-05 | 1988-03-24 | Toyo Tire & Rubber Co Ltd | Production of rubber composition |
| DE102011101880A1 (en) * | 2011-05-18 | 2012-11-22 | Süd-Chemie AG | Process for the preparation of separation media for the purification and / or isolation of enzymes and / or proteins |
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