JPS62184116A - Polyester monofilament fiber for screen gauze - Google Patents

Polyester monofilament fiber for screen gauze

Info

Publication number
JPS62184116A
JPS62184116A JP2400786A JP2400786A JPS62184116A JP S62184116 A JPS62184116 A JP S62184116A JP 2400786 A JP2400786 A JP 2400786A JP 2400786 A JP2400786 A JP 2400786A JP S62184116 A JPS62184116 A JP S62184116A
Authority
JP
Japan
Prior art keywords
screen gauze
strength
elongation
heat treatment
tension
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2400786A
Other languages
Japanese (ja)
Inventor
Shuichi Oshima
修一 大島
Etsuro Hosoi
細井 悦朗
Koichi Sato
晃一 佐藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP2400786A priority Critical patent/JPS62184116A/en
Publication of JPS62184116A publication Critical patent/JPS62184116A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N1/00Printing plates or foils; Materials therefor
    • B41N1/24Stencils; Stencil materials; Carriers therefor
    • B41N1/247Meshes, gauzes, woven or similar screen materials; Preparation thereof, e.g. by plasma treatment

Landscapes

  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Textile Engineering (AREA)
  • Printing Plates And Materials Therefor (AREA)
  • Artificial Filaments (AREA)

Abstract

PURPOSE:To provide the titled fiber having a stress corresponding to a specific elongation in stress-strain curve, a strength at break and a shrinkage in dry-heat treatment falling within respective specific ranges and giving a woven fabric having excellent quality while suppressing the generation of white powder and falling-off of scum during weaving process. CONSTITUTION:The objective fiber can be produced by melt-spinning a polyester and properly combining the drawing condition and method, etc., to attain a stress of 1.5-3.2g/d corresponding to the elongation of 10% in a stress-strain curve of the fiber, a strength at break of >=4.0g/d and a shrinkage of <=12% by dry-heat treatment at 200 deg.C for 15min.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、スクリーン紗用ポリエステルモノフィラメン
ト糸に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a polyester monofilament yarn for screen gauze.

[従来の技術] ポリエステルモノフィラメント糸は寸法安定性、弾性回
復性など、他の繊維素材がイイしていない数多くの優れ
た特性を持っているため従来からスクリーン紗素材とし
て幅広く使用されている。また、近年のエレクトロニク
スの進歩、印刷物の高級化に伴い、スクリーン紗は益々
高メツシュ織物化が要求されている。
[Prior Art] Polyester monofilament yarn has been widely used as a screen gauze material because it has many excellent properties that other fiber materials do not have, such as dimensional stability and elastic recovery. In addition, with the recent progress in electronics and the increasing quality of printed materials, screen gauze is increasingly required to be woven with a high mesh.

しかしながら、ポリエステルモノフィラメント糸はヤン
グ率が高いという点ではスクリーン紗性能として有用で
あるが、反面¥IJ織性においてマイナスの特性を有し
ている。
However, although polyester monofilament yarn has a high Young's modulus and is useful as a screen gauze, on the other hand, it has negative characteristics in terms of IJ weavability.

つまり、ポリエステルモノフィラメント糸は製織工程で
白粉、スカムが脱落し、筬の目詰りによる経糸切れ、経
筋むら、あるいは白粉スカムの織込みによるスクリーン
紗の品位の低下などの問題点があった。
In other words, polyester monofilament yarn has problems such as white powder and scum falling off during the weaving process, warp breakage due to clogging of the reed, warp unevenness, and deterioration of the quality of the screen gauze due to the weaving of white powder scum.

従来問題になっていた前記白粉、スカム発生の抑制に関
しくは、特開昭!1s−16948号公報あるいは特m
1昭58−169540号公報などで提案されているよ
うに種々検討が試みられている。
For information on suppressing the generation of white powder and scum, which has been a problem in the past, please refer to JP-A-Sho! 1s-16948 publication or special
Various studies have been attempted, as proposed in 1982-169540.

[発明が解決しようとする問題点] 通常、スクリーン紗用途も含む一般のポリエステル糸の
製織性(白粉、スカムの脱落も含む)を改善するため、
原糸の伸長に対Jる張力の比を低くする、つまり張力・
細工(曲線をわがぼる方法が常套手段として採用されて
いる。
[Problems to be Solved by the Invention] Generally, in order to improve the weavability (including shedding of white powder and scum) of general polyester yarns, including those used for screen gauze,
Lower the ratio of the tension to the elongation of the yarn, that is, lower the tension
Craftsmanship (the method of making curved lines is commonly used).

しかしながら、この手法はスクリーン紗用途には適用で
きない。なぜならば、単純に張力・伸長曲線をねかぜた
だけでは、スクリーン紗の張力・伸長曲線もねてしまい
、ポリエステルスクリーン紗の特徴の1つである寸法安
定性を欠くためである。
However, this method cannot be applied to screen gauze applications. This is because if the tension/elongation curve of the screen gauze is simply changed, the tension/elongation curve of the screen gauze will also be changed, resulting in a lack of dimensional stability, which is one of the characteristics of polyester screen gauze.

スクリーン紗の製織はオープニングエリア(経糸と緯糸
で構成される空隙)の正確さ、均一性を要求されること
から、衣料用などの一般的な織物の製織よりはるかに高
い張力の条件下で製織される。、また、織密度も100
本/インチか&j 500本、7インチと高いため、経
糸はm機上の綜絖、筬などで繰返し強い擦過を受ける。
Screen gauze weaving requires precision and uniformity in the opening area (the voids made up of warp and weft yarns), so it is woven under conditions of much higher tension than the weaving of general textiles such as clothing. be done. , and the weave density is also 100
Since the warp yarns are high (500 yarns/inch, 7 inches), the warp yarns are repeatedly subjected to strong abrasion by the heddles, reeds, etc. on the machine.

そのため、経糸の糸表面が破壊し、削り取られ、あらか
じめ糸表面に付着されている仕上げ油剤と混り合い、一
般的に白粉、スカムと呼ばれるガム状物質が生成される
。この白粉、スカムが綜絖、改」二に蓄積すると開口不
良を起し、経糸切れが発生ずる。また筬の目詰まりによ
る経筋欠点および白粉、スカムが織込まれることによる
品位の低下など、重大な問題を引起すことになる。この
ため、綜絖、筬は白粉、スカムを取除くため頻繁に洗浄
が必要になってくる。
As a result, the thread surfaces of the warp threads are destroyed, scraped off, and mixed with the finishing oil that has been previously attached to the thread surfaces, producing a gummy substance generally called white powder or scum. When this white powder and scum accumulates on the healds and scum, it causes poor shedding and warp thread breakage. In addition, serious problems such as warp defects due to clogging of the reed and deterioration of quality due to white powder and scum being woven will occur. For this reason, the healds and reeds need to be washed frequently to remove white powder and scum.

製織時の白粉、スカムを抑制するという面からみれば、
原糸の張力・伸長曲線でスクリーン紗の製織夕^糸張力
に相当する付近、つまり、伸びが10%の時の強度を低
くすれば低いほど白粉、スカムの発生の抑制に著しい効
果が見られるが、仕上熱処理加工後のスクリーン紗は、
従来糸使いのものと比較して、張力・伸長曲線がかなり
ねたものとなり、また、オープニングエリアの正確性、
均一性など品位ち低Fする傾向になり、実用上も問題が
残る。
From the perspective of suppressing white powder and scum during weaving,
The lower the strength is when the tension/elongation curve of the raw yarn corresponds to the thread tension during weaving screen gauze, that is, when the elongation is 10%, the more remarkable the effect is seen in suppressing the generation of white powder and scum. However, the screen gauze after finishing heat treatment is
Compared to conventional thread-based products, the tension and elongation curves are considerably smoother, and the accuracy of the opening area and
There is a tendency for quality such as uniformity to be low, and problems remain in practical use.

そこで、本発明者らは、仕上熱処理加工されたスクリー
ン紗を解析した結果、仕上熱処理加工されたスクリーン
紗の張力・伸長曲線、および品位は、原糸が保持してい
る乾熱処理による収縮率と重大、かつ密接な関係がある
ことを見出し、さらに検討したところ、原糸が保持して
いる乾熱処理による収縮率が低ければ低い程、仕上熱処
理加工されたスクリーン紗の張力・伸長曲線は立ち、オ
ープニングエリアの正確性、均一性などの品位−す向上
するという知見を得たのである。
Therefore, as a result of analyzing screen gauze subjected to finish heat treatment, the present inventors found that the tension/elongation curve and quality of screen gauze subjected to finish heat treatment are related to the shrinkage rate due to dry heat treatment maintained by the raw yarn. We found that there is a significant and close relationship, and upon further investigation, we found that the lower the shrinkage rate of the raw yarn due to dry heat treatment, the higher the tension/elongation curve of screen gauze that has been subjected to finishing heat treatment. They found that the accuracy and uniformity of the opening area can be improved significantly.

本発明の目的は、実質的に製織工程で発生する白粉、ス
カムを抑制し、効率よく、オープニングエリアの正確性
、均一性などの品位、品質の19れl、ニスクリーン紗
を得ることのできるポリ」ステルモノフィラメント糸を
提供するものである。
The object of the present invention is to substantially suppress the white powder and scum generated in the weaving process, and to efficiently obtain 19-degree, high-quality Nisqueen gauze, including accuracy and uniformity of the opening area. Poly” stell monofilament yarn.

[問題点を解決するための手段] 本発明の目的は、張力・伸長曲線において、伸びが10
%の時の強度を1.5〜3.2 g/dの範囲とし、破
1gi強度−が4,0 (1/d以上で、かつ200℃
15分屹然処理における収縮率を12%以下とするスク
リーン紗用ポリエステルモノフィラメント糸によって達
成することができる。
[Means for Solving the Problems] The object of the present invention is to achieve an elongation of 10 in the tension/elongation curve.
% strength is in the range of 1.5 to 3.2 g/d, and the breaking 1gi strength is 4.0 (1/d or more and at 200℃
This can be achieved by using polyester monofilament yarn for screen gauze, which has a shrinkage rate of 12% or less in a 15-minute treatment.

以下、本発明について詳細に説明する。The present invention will be explained in detail below.

本発明においては、製織時の白粉、スカムの発生を抑制
するという面からみれば、原糸のモノフィラメント糸の
張力・伸長曲線で、伸びが10%の時の強度を低くすれ
ば低いほど白粉、スカムの発生の抑制に著しい効果が見
られるが、反面、仕上熱処理加工後のスクリーン紗の破
断強度も低くなるため、モノフィラメント糸は張力・伸
長曲線において、伸びが10%の時の強度を1.5〜3
.2 g/dの範囲とし、破断強度を4.0 g/d以
上にすることが必要である。
In the present invention, from the viewpoint of suppressing the generation of white powder and scum during weaving, the lower the strength at 10% elongation in the tension/elongation curve of the monofilament yarn of the raw yarn, the lower the white powder. Although a remarkable effect is seen in suppressing the generation of scum, on the other hand, the breaking strength of the screen gauze after finishing heat treatment is also lowered, so the monofilament yarn has a strength of 1.0% at an elongation of 10% in the tension/elongation curve. 5-3
.. 2 g/d, and the breaking strength must be 4.0 g/d or more.

つまり、モノフィラメント糸の伸びが1096の時の強
度が1.5 g/d未満、または破断強度が4、Og/
d未満になると、仕上熱処理加工後のスクリーン紗の破
断強度が低すぎて、実用上問題である。逆に、伸びが1
0%の時の強度が3.2g/dを越えると、白粉、スカ
ムの発生の抑制効果が小さくなる。
In other words, when the elongation of the monofilament yarn is 1096, the strength is less than 1.5 g/d, or the breaking strength is 4, Og/d.
If it is less than d, the breaking strength of the screen gauze after finishing heat treatment is too low, which is a practical problem. On the other hand, the elongation is 1
If the strength at 0% exceeds 3.2 g/d, the effect of suppressing the generation of white powder and scum will be reduced.

また、モノフィラメント糸の乾熱処理における収縮率は
、ポリエステルモノフィラメン1〜糸の、200℃15
分の乾熱処理にお(〕る収縮率を12%以下とする必要
がある。前記収縮率が12%を越えると、オープニング
の正確性が欠けるという欠点がある。
In addition, the shrinkage rate in dry heat treatment of monofilament yarn is 200℃ 15 for polyester monofilament 1 to yarn.
It is necessary to keep the shrinkage rate during the dry heat treatment () to 12% or less. If the shrinkage rate exceeds 12%, there is a drawback that opening accuracy is lacking.

なお、モノフィラメント糸の乾熱処理における収縮率は
前記したように低い程、スクリーン紗性能どして良い結
果が19られるが、ポリエステルモノフィラメント糸の
延伸工程における作業性、収率などを考慮した場合、2
00℃15分乾熱処理における収縮率を1%以上とする
ことか好ましい。
As mentioned above, the lower the shrinkage rate in the dry heat treatment of monofilament yarn, the better the screen gauze performance.
It is preferable that the shrinkage rate in dry heat treatment at 00° C. for 15 minutes is 1% or more.

本発明の原料として用いるポリエステルは、テレフタル
酸、エチレングリコールからなるポリエチレンテレフタ
レートを主たる対象とするが、シュウ酸、セバシン酸、
フタル酸、ポリエチレンオキサイド、ポリプロピレンオ
キナイド、m−フェノールスルホン酸ナトリウムなどの
第3成分を1〜15モル%共重合したものであってもよ
く、また艶消し効果や製糸性改善効果などを目的に、通
常よく使われる酸化チタンを0.1〜5%含有したもの
であっても有効である。
The polyester used as a raw material in the present invention is mainly polyethylene terephthalate consisting of terephthalic acid and ethylene glycol, but oxalic acid, sebacic acid,
It may be a copolymer of 1 to 15 mol% of a third component such as phthalic acid, polyethylene oxide, polypropylene oquinide, sodium m-phenolsulfonate, etc., and may also be used for the purpose of matting effect or improving thread-spinning property. , even those containing 0.1 to 5% of commonly used titanium oxide are effective.

さらにポリエステルマルチフィラメント糸は通常の方法
で溶融紡糸し、延伸したマルチフィラメントを分繊して
モノフィラメントを1rする方法、またはモノフィラメ
ントとして溶融紡糸し延伸して得る方法、またはマルチ
フィラメントとして紡糸し、分繊しC延伸しモノフィラ
メントを得る方法、さらには一工程で延伸糸を1qる方
法などいずれの方法であってもよい。なお、本発明のモ
ノフィラメントの所望の各物性値を1′、lるためには
、延伸条件、方法を適宜組合せることによって1!ノる
ことができる。
Furthermore, the polyester multifilament yarn can be obtained by melt-spinning in a conventional manner and dividing the drawn multifilament into monofilaments, or by melt-spinning and drawing the monofilament, or by spinning it as a multifilament and dividing it into monofilaments. Any method may be used, such as a method of obtaining a monofilament by C drawing, or a method of producing 1 q of drawn yarn in one step. In order to reduce the desired physical properties of the monofilament of the present invention by 1', l, by appropriately combining the stretching conditions and methods. I can do it.

また、前記したマルチフィラメントとは複数のモノフィ
ラメントが集束している糸条を言うが、本発明では一般
に構成本数が2〜20本程度が好ましい。ざらにモノフ
ィラメント延伸後、またはマルチフィラメント延伸分繊
後のモノフィラメントの繊度は5〜406程度のものが
好ましい。
Furthermore, the above-mentioned multifilament refers to a yarn in which a plurality of monofilaments are bundled together, and in the present invention, it is generally preferable that the number of the monofilaments is about 2 to 20. The fineness of the monofilament after rough monofilament drawing or multifilament drawing and splitting is preferably about 5 to 406.

なお、本発明で規定する伸びが10%の時の強度、破断
強度および収縮率の測定方法は次のとおりである。
The method for measuring the strength, breaking strength, and shrinkage rate when the elongation defined in the present invention is 10% is as follows.

(伸びが10%の時の強度) 試料を温1夏20℃、相対湿度65%の雰囲気において
、インストロン万能引張り試験により、鍼灸20cm、
速度20Cm/分で引張り測定し、第1図に示すように
、伸びが鍼灸に対し10%の時の張力Tを、引張り前の
デニールで除して求める。
(Strength when elongation is 10%) In an atmosphere of temperature 20°C and relative humidity 65%, the sample was subjected to an Instron universal tensile test to measure acupuncture 20cm, moxibustion 20cm,
Tensile measurement is carried out at a speed of 20 cm/min, and as shown in FIG. 1, the tension T when the elongation is 10% of that of acupuncture is divided by the denier before tension.

(破断強度) 伸びが10%の時の強度を測定するのと同一条件下で測
定し、試料が破断した時の強力を引張り前のデニールで
除して求める。
(Breaking strength) Measure under the same conditions as when measuring the strength when the elongation is 10%, and calculate the strength when the sample breaks by dividing it by the denier before tension.

(収縮率) 200℃にコントロールした熱風循環型恒温層で、無緊
張下で15分熱処理しIζ際の原試良に対する処理後の
鍼灸により次式で算出する。
(Shrinkage rate) Calculated by the following formula using acupuncture after treatment of the original sample after heat treatment for 15 minutes without tension in a hot air circulation constant temperature layer controlled at 200°C.

収縮率=・((原試艮−処理後の鍼灸)÷原鍼灸x 1
00) [実施例] 以下、本発明を実施例でさらに詳述する。
Shrinkage rate = ((Original trial - acupuncture after treatment) ÷ original acupuncture x 1
00) [Examples] The present invention will be explained in more detail below using Examples.

実施例 1 25℃オルソクロロフェノール溶液から求めた極限粘度
0.65を有するポリエチレンテレフタレートを、紡糸
温度290℃で2孔を有する紡糸口金を用いて溶融紡糸
し、(t i油剤を付与後、巻取速度1240 m/分
で分繊し巻き取った。
Example 1 Polyethylene terephthalate having an intrinsic viscosity of 0.65 determined from an orthochlorophenol solution at 25°C was melt-spun using a spinneret with two holes at a spinning temperature of 290°C. The fibers were separated and wound up at a take-up speed of 1240 m/min.

得られたモノフィラメント未延伸糸を表面渇痕を60〜
240℃にコントロール可能なホットロールを3個有す
る多段延伸機で、m度、延伸倍率および倍率配分を変え
、第1表に示す物性を有する繊115〜16デニールの
モノフィラメント糸を得た。次いで、該モノフィラメン
ト糸をスルザー#IB!で、経、緯225本/インチの
織密度からなるスクリーン紗を製織し、仕上熱処理を行
なった。得られた結果を第1表に示す。
The obtained monofilament undrawn yarn has a surface scar of 60~
A monofilament yarn of 115 to 16 denier having the physical properties shown in Table 1 was obtained using a multistage drawing machine having three hot rolls that could be controlled at 240° C. by changing the degree of m, the drawing ratio, and the ratio distribution. The monofilament yarn was then coated with Sulzer #IB! A screen gauze having a weave density of 225 threads/inch in both warp and weft was woven and subjected to finishing heat treatment. The results obtained are shown in Table 1.

第1表の実験NO1,5,6および11は比較例である
Experiments Nos. 1, 5, 6 and 11 in Table 1 are comparative examples.

第1表において、本発明で規定する緒特性を満たしてい
る実験No2〜4および7〜10は、筬の洗浄周期が長
く、またスクリーン紗強力が高い上、オープニング正確
性も良好であった。
In Table 1, in Experiments Nos. 2 to 4 and 7 to 10, which satisfied the wire characteristics specified in the present invention, the reed cleaning cycle was long, the screen gauze strength was high, and the opening accuracy was also good.

実験NO4は筬の洗浄周期がやや短く、実験No 7は
スクリーン紗強力がやや低目であったが、実用上問題は
なかった。
In Experiment No. 4, the reed cleaning cycle was a little short, and in Experiment No. 7, the strength of the screen gauze was a little low, but there were no practical problems.

しかし、本発明で規定する緒特性を満たさない実験NO
Iは、スクリーン紗強力が低目であり、オープニング正
確性もやや欠けていた。実験No5は膏の洗浄周期が短
かった。実験N06はスクリーン紗強力が低目であった
。実験No11はオープニング正確性が欠けていた。
However, experiment NO.
In I, the strength of the screen gauze was low, and the opening accuracy was also somewhat lacking. In Experiment No. 5, the plaster cleaning cycle was short. In Experiment No. 6, the strength of the screen gauze was low. Experiment No. 11 lacked opening accuracy.

[発明の効果] 本発明は上記の構成を採用することにより、ポリエステ
ルモノフィラメント糸のスクリーン紗製織工程での白粉
、スカム脱落を抑&Qし、スクリーン紗強力、オープニ
ング正確性など品質の優れたスクリーン紗が効率良く得
られた。
[Effects of the Invention] By adopting the above configuration, the present invention suppresses white powder and scum shedding during the screen gauze weaving process of polyester monofilament yarn, and produces screen gauze with excellent quality such as screen gauze strength and opening accuracy. was obtained efficiently.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、本発明における[伸びが10%の時の強度」
の測定方法を説明するためのグラフである。
Figure 1 shows [strength at 10% elongation] in the present invention.
It is a graph for explaining the measurement method.

Claims (1)

【特許請求の範囲】[Claims] 張力・伸長曲線において、伸びが10%の時の強度を1
.5〜3.2g/dの範囲とし、破断強度が4.0g/
d以上で、かつ200℃ 15分乾熱処理における収縮
率を12%以下とすることを特徴とするスクリーン紗用
ポリエステルモノフィラメント糸。
In the tension/elongation curve, the strength when elongation is 10% is 1
.. The range is 5 to 3.2 g/d, and the breaking strength is 4.0 g/d.
A polyester monofilament yarn for screen gauze, characterized in that it has a shrinkage rate of 12% or less when subjected to dry heat treatment at 200° C. for 15 minutes.
JP2400786A 1986-02-07 1986-02-07 Polyester monofilament fiber for screen gauze Pending JPS62184116A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2400786A JPS62184116A (en) 1986-02-07 1986-02-07 Polyester monofilament fiber for screen gauze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2400786A JPS62184116A (en) 1986-02-07 1986-02-07 Polyester monofilament fiber for screen gauze

Publications (1)

Publication Number Publication Date
JPS62184116A true JPS62184116A (en) 1987-08-12

Family

ID=12126497

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2400786A Pending JPS62184116A (en) 1986-02-07 1986-02-07 Polyester monofilament fiber for screen gauze

Country Status (1)

Country Link
JP (1) JPS62184116A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02127513A (en) * 1988-11-01 1990-05-16 Teijin Ltd Polyester monofilament for screen gauze
JPH02277818A (en) * 1989-04-14 1990-11-14 Toray Ind Inc Polyester monofilament for screen gauze
JP2008248870A (en) * 2007-03-30 2008-10-16 Honda Motor Co Ltd Engine valve gear

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02127513A (en) * 1988-11-01 1990-05-16 Teijin Ltd Polyester monofilament for screen gauze
JPH02277818A (en) * 1989-04-14 1990-11-14 Toray Ind Inc Polyester monofilament for screen gauze
JP2008248870A (en) * 2007-03-30 2008-10-16 Honda Motor Co Ltd Engine valve gear

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