JPS6217616B2 - - Google Patents

Info

Publication number: JPS6217616B2
Authority: JP; Japan
Prior art keywords: beads; propane; weight; dibromophenyl; bis
Prior art date: 1980-06-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP8588580A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5712048A (en

Inventor

Kazuyoshi Umeda

Fumiaki Nakamoto

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Teijin Ltd

Original Assignee

Teijin Chemicals Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-06-26

Filing date

1980-06-26

Publication date

1987-04-18

1980-06-26 Application filed by Teijin Chemicals Ltd filed Critical Teijin Chemicals Ltd

1980-06-26 Priority to JP8588580A priority Critical patent/JPS5712048A/ja

1982-01-21 Publication of JPS5712048A publication Critical patent/JPS5712048A/ja

1987-04-18 Publication of JPS6217616B2 publication Critical patent/JPS6217616B2/ja

Status Granted legal-status Critical Current

Links

PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 52
239000003063 flame retardant Substances 0.000 claims description 30
239000012508 resin bead Substances 0.000 claims description 27
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 24
239000012188 paraffin wax Substances 0.000 claims description 18
239000007788 liquid Substances 0.000 claims description 17
229920001890 Novodur Polymers 0.000 claims description 16
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 16
PWXTUWQHMIFLKL-UHFFFAOYSA-N 1,3-dibromo-5-[2-(3,5-dibromo-4-prop-2-enoxyphenyl)propan-2-yl]-2-prop-2-enoxybenzene Chemical compound C=1C(Br)=C(OCC=C)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(OCC=C)C(Br)=C1 PWXTUWQHMIFLKL-UHFFFAOYSA-N 0.000 claims description 15
150000003014 phosphoric acid esters Chemical class 0.000 claims description 12
239000000203 mixture Substances 0.000 claims description 9
239000001294 propane Substances 0.000 claims description 8
239000004088 foaming agent Substances 0.000 claims description 6
239000011324 bead Substances 0.000 description 27
238000000034 method Methods 0.000 description 26
229920005989 resin Polymers 0.000 description 14
239000011347 resin Substances 0.000 description 14
238000005187 foaming Methods 0.000 description 11
239000004604 Blowing Agent Substances 0.000 description 10
239000006260 foam Substances 0.000 description 10
238000005470 impregnation Methods 0.000 description 8
229910019142 PO4 Inorganic materials 0.000 description 6
YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 6
239000010452 phosphate Substances 0.000 description 6
238000001125 extrusion Methods 0.000 description 5
239000000178 monomer Substances 0.000 description 5
238000006116 polymerization reaction Methods 0.000 description 5
230000000694 effects Effects 0.000 description 4
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
-1 phosphate ester Chemical class 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
239000004793 Polystyrene Substances 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
238000002156 mixing Methods 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
230000000704 physical effect Effects 0.000 description 3
229920002223 polystyrene Polymers 0.000 description 3
GPTLIJNIIGNCIG-UHFFFAOYSA-N 1,2-dibromo-3-propylbenzene Chemical compound CCCC1=CC=CC(Br)=C1Br GPTLIJNIIGNCIG-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
239000001273 butane Substances 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
230000006866 deterioration Effects 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000012774 insulation material Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
AUTSLLHNWAZVLE-UHFFFAOYSA-N 1,1,2,2,3-pentabromo-3-chlorocyclohexane Chemical compound ClC1(Br)CCCC(Br)(Br)C1(Br)Br AUTSLLHNWAZVLE-UHFFFAOYSA-N 0.000 description 1
XQKQZOLAVMIQHZ-UHFFFAOYSA-N 1,1-dibromo-3-(3,3-dibromopropoxy)propane Chemical compound BrC(Br)CCOCCC(Br)Br XQKQZOLAVMIQHZ-UHFFFAOYSA-N 0.000 description 1
PHOBHMJNDXZVSI-UHFFFAOYSA-N 1,2,3,4-tetrabromo-2-chlorobutane Chemical compound BrCC(Br)(Cl)C(Br)CBr PHOBHMJNDXZVSI-UHFFFAOYSA-N 0.000 description 1
YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
239000004338 Dichlorodifluoromethane Substances 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
YYQRGCZGSFRBAM-UHFFFAOYSA-N Triclofos Chemical compound OP(O)(=O)OCC(Cl)(Cl)Cl YYQRGCZGSFRBAM-UHFFFAOYSA-N 0.000 description 1
PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000004566 building material Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 description 1
PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000000975 dye Substances 0.000 description 1
238000004134 energy conservation Methods 0.000 description 1
229920006248 expandable polystyrene Polymers 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000010097 foam moulding Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920006327 polystyrene foam Polymers 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000010558 suspension polymerization method Methods 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
229960001147 triclofos Drugs 0.000 description 1
DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
XHTMGDWCCPGGET-UHFFFAOYSA-N tris(3,3-dichloropropyl) phosphate Chemical compound ClC(Cl)CCOP(=O)(OCCC(Cl)Cl)OCCC(Cl)Cl XHTMGDWCCPGGET-UHFFFAOYSA-N 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

JP8588580A 1980-06-26 1980-06-26 Flame-retardant, expandable styrene resin bead composition Granted JPS5712048A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP8588580A JPS5712048A (en)	1980-06-26	1980-06-26	Flame-retardant, expandable styrene resin bead composition

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP8588580A JPS5712048A (en)	1980-06-26	1980-06-26	Flame-retardant, expandable styrene resin bead composition

Publications (2)

Publication Number	Publication Date
JPS5712048A JPS5712048A (en)	1982-01-21
JPS6217616B2 true JPS6217616B2 (es)	1987-04-18

Family

ID=13871357

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP8588580A Granted JPS5712048A (en)	1980-06-26	1980-06-26	Flame-retardant, expandable styrene resin bead composition

Country Status (1)

Country	Link
JP (1)	JPS5712048A (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2339258A1 (en)	1998-08-28	2000-03-09	The Dow Chemical Company	Fire resistant styrene polymer foams with reduced brominated fire retardant

1980
- 1980-06-26 JP JP8588580A patent/JPS5712048A/ja active Granted

Also Published As

Publication number	Publication date
JPS5712048A (en)	1982-01-21

Publication	Publication Date	Title
KR100492199B1 (ko)	2005-06-02	흑연 입자를 함유하는 발포성 스티렌 중합체의 제조 방법
JP2009536687A (ja)	2009-10-15	断熱特性に優れた発泡性ポリスチレン粒子の２段階製造方法
US4035315A (en)	1977-07-12	Fire-resistant styrene polymer foams
JP2002531659A (ja)	2002-09-24	難燃剤ポリスチレン発泡体
US5171757A (en)	1992-12-15	Fire resistant vinylaromatic foams
CA2471317A1 (en)	2003-09-04	Polymethacrylimide plastic foam materials with reduced inflammability in addition to a method for the production thereof
KR910008773B1 (ko)	1991-10-21	발포성 비닐리덴 클로라이드 조성물 및 그의 발포체
US5043218A (en)	1991-08-27	Flame resistant, expandable styrene polymers and foams, and flame retardants
US3361687A (en)	1968-01-02	Self-extinguishing finely divided expandable plastics compositions
JP4007738B2 (ja)	2007-11-14	発泡性熱可塑性共重合体粒子
US5837740A (en)	1998-11-17	Expandable ABS resin beads and process for producing the same
CA1214600A (en)	1986-11-25	Expandable thermoplastic resin particles and process for preparing the same
JPS6217616B2 (es)	1987-04-18
KR100884817B1 (ko)	2009-02-20	발포성 폴리스티렌 입자의 2단계 제조방법
US3554934A (en)	1971-01-12	Treatment of foam plastics to render them fire-resistant
JPH04211441A (ja)	1992-08-03	高い加熱歪み耐性を有する発泡シート
JPH0461896B2 (es)	1992-10-02
JP3580317B2 (ja)	2004-10-20	空隙を有する難燃性発泡スチレン系樹脂成形体の製造方法
KR100659450B1 (ko)	2006-12-19	고강도 착색성 발포 스티렌 수지, 그의 제조방법, 및 이를이용한 발포 성형품
EP0616619B1 (en)	1998-07-01	Fire resistant alkenylaromatic foams
JPS5858372B2 (ja)	1983-12-24	発泡可能な自消性熱可塑性樹脂粒子の製造方法
JPH0567654B2 (es)	1993-09-27
WO2004094517A1 (en)	2004-11-04	Flame retarded styrenic polymer foams
WO1995033790A1 (en)	1995-12-14	Coating composition for expandable beads
US4389495A (en)	1983-06-21	Foamable polymeric styrene particles