JPS62171871A - Taking-up of pitch group carbon fiber - Google Patents

Taking-up of pitch group carbon fiber

Info

Publication number
JPS62171871A
JPS62171871A JP61012716A JP1271686A JPS62171871A JP S62171871 A JPS62171871 A JP S62171871A JP 61012716 A JP61012716 A JP 61012716A JP 1271686 A JP1271686 A JP 1271686A JP S62171871 A JPS62171871 A JP S62171871A
Authority
JP
Japan
Prior art keywords
bobbin
angle
winding
fiber
pitch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61012716A
Other languages
Japanese (ja)
Inventor
Takahisa Fukao
深尾 隆久
Eisaku Karikura
栄作 柿倉
Morimi Takagi
高木 司美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP61012716A priority Critical patent/JPS62171871A/en
Publication of JPS62171871A publication Critical patent/JPS62171871A/en
Pending legal-status Critical Current

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  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Winding Of Webs (AREA)
  • Filamentary Materials, Packages, And Safety Devices Therefor (AREA)
  • Inorganic Fibers (AREA)

Abstract

PURPOSE:To permit the rewinding from a product bobbin free from the thread cut, fluffing, etc. by taking up the pitch group carbon fiber having an elongation modulus of 400ton/mm<2> or more onto a taper end bobbin at an edge angle and a taper end angle of each specific value. CONSTITUTION:When the pitch group carbon fiber 3 having an elongation modulus of 40ton/mm<2> or more and an elongation of 1% or less is taken up onto a bobbin 4, taking-up operation onto a tapered end bobbin is carried out with an edge angle 1 of 0.1-25 deg. and a tapered angle 2 of 10-70 deg.. In concrete, taking-up is carried out in one layer with a prescribed edge angle so that the fibers are not superposed from one edge of the bobbin 4 to the other edge, and then turn-over operation is carried out, and the fiber bundle is taken up in one layer. The edge angle is changed by varying the traverse speed. In other words, generation of thread cut, etc. on rewinding is prevented by sufficiently preventing the state where the fiber bundle taken up onto the upper layer side is dropped into the fiber layer on the lower layer side.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はピッチ系炭素繊維の巻〔0方法に関するもので
1Lよ〕詳しくは高弾性率のピッチ系炭素繊維の製品ボ
ビンとしての巻き取シ方法に関するものである。
Detailed Description of the Invention (Field of Industrial Application) The present invention relates to winding of pitch-based carbon fiber [0 method, 1L] Specifically, the present invention relates to a winding system of pitch-based carbon fiber with a high modulus of elasticity as a product bobbin. It is about the method.

(従来の技術) 炭素繊維は高性能複合材料のフィラー繊維として近年注
目されている。
(Prior Art) Carbon fiber has recently attracted attention as a filler fiber for high-performance composite materials.

一般に炭素繊維の製造法としては、炭素質ピッチ、ポリ
アクリロニトリル、セルローズ、ポリビニルアルコール
等を原料とし、これらの原料を湿式あるいは乾式溶融紡
糸し、得られる有機重合体繊維を不融化処理もしくは耐
炎化処理し、次いで炭化焼成処理、必要に応じて黒鉛化
処理することによシ製造される。
Generally, carbon fiber is produced by using carbon pitch, polyacrylonitrile, cellulose, polyvinyl alcohol, etc. as raw materials, wet- or dry-melt spinning these raw materials, and treating the resulting organic polymer fibers to be infusible or flame-resistant. Then, it is manufactured by carbonization firing treatment and, if necessary, graphitization treatment.

そして、これらの炭素繊維を最終的に製品ボビンとする
場合、他の合成繊維や天然繊維等と同様にボビンに連続
長繊維束をボビンの巻き取シ厚み方向に重な9合うよう
に多層状態に巻き取シ、最終製品とするのが一般的に行
なわれる。
When these carbon fibers are finally made into product bobbins, like other synthetic fibers and natural fibers, continuous long fiber bundles are wound onto the bobbin in a multi-layered state so that they overlap in the thickness direction. It is generally rolled up and made into a final product.

しかしながら、ボビン等に対し、繊維束を多層状態で巻
き取る場合、巻き取シ張力のため、上層側に巻き取られ
る繊維束が下層側の繊維層に陥没する状況がしばしば発
生する。そしてこの状況は生産性を向上させるために巻
き取ジ速度ケ早めるとよ)張力が増すためよシ一層発生
し易く、又より長い繊維長を得るために巻き取シ厚みを
大きくするほど繊維層はよシ大きな張力を受けることと
なシ、上層側の繊維束が陥没し易くなる。そしてかかる
状況が発生した巻き取シ状態のボビンから繊維束を巻き
戻す場合、上7#側繊維束が下層側繊維層に陥没した個
所において、繊維束に対し、異常に大きな張力が加わる
ことによシ、ボビン離れが不良となったシ、糸切れ、ケ
バ立ち等の損傷を生じ、安定的に巻き戻し操作を行なう
ことが出来なかったシ、巻き戻した繊維の品質低下した
シする問題があった。
However, when winding a fiber bundle in a multi-layered state onto a bobbin or the like, a situation often occurs in which the fiber bundle wound on the upper layer side collapses into the lower fiber layer due to the winding tension. This situation is more likely to occur due to the increase in tension (if the winding speed is increased to improve productivity), and as the winding thickness is increased to obtain a longer fiber length, the fiber layer Otherwise, the fiber bundles on the upper layer side will easily collapse if subjected to large tension. When rewinding a fiber bundle from a bobbin in the winding state where such a situation has occurred, an abnormally large tension will be applied to the fiber bundle at the location where the upper 7# side fiber bundle collapses into the lower side fiber layer. However, problems such as failure to separate the bobbin, thread breakage, fuzzing, etc., making it impossible to rewind stably, and deterioration of the quality of the unwound fibers may occur. there were.

かかる問題は合成繊維や天然繊維などのように、繊維自
体が強靭である場合にはほとんど支障とはならない。
This problem hardly poses a problem when the fiber itself is strong, such as synthetic fiber or natural fiber.

そこで、従来においても多層巻き取シ時に上層側の繊維
束が、下層側の繊維層に陥没するのを防止するため、ボ
ビン上で繊維束をトラバースし、上層側繊維束が下層繊
維束に対して交互に交叉するようにして巻き取ることや
、これに加えて定速フィード機構とダンサ−ローラーと
の組合せ等によシ張力を漸減させながら巻きとることが
行なわれている。
Therefore, conventionally, in order to prevent the upper fiber bundle from collapsing into the lower fiber layer during multilayer winding, the fiber bundle is traversed on the bobbin, and the upper fiber bundle is moved against the lower fiber bundle. In addition to this, winding is carried out in such a way that the tension is gradually reduced by a combination of a constant speed feed mechanism and a dancer roller.

(発明が解決しようとする問題点) しかしながら、かかる巻き取シ方法を高弾性率を有する
ピッチ糸炭素繊維に適用すると、ポリアクリロニトリル
等を原料にした炭素繊維とは異なシ、綾角の大きな製品
ボビンから巻き戻しする際に、高弾性率ピッチ系炭素繊
維特有の曲げに対する弱さのためにボビン上の繊維束の
屈曲角度に耐え得ず、繊維が切れた)、折れたシする問
題があった。
(Problems to be Solved by the Invention) However, when this winding method is applied to pitch yarn carbon fibers having a high elastic modulus, products with large wind angles differ from carbon fibers made from polyacrylonitrile or the like. When unwinding from the bobbin, due to the unique bending weakness of high modulus pitch carbon fibers, the fiber bundle on the bobbin cannot withstand the bending angle, resulting in fiber breakage). Ta.

(問題点を解決するための手段) そこで、本発明者等は上記問題点を解決するべく鋭意検
討を行なった結果、高弾性率のピッチ系炭素繊維とボビ
ンに巻き取るに際し、特定角度の綾角で、かつ特定角度
のテーパ角でテーバエンド巻きに巻き取ることにより上
記問題点が解消できることを見い出し本発明に到達した
(Means for Solving the Problems) Therefore, as a result of intensive studies to solve the above problems, the inventors of the present invention found that when winding pitch-based carbon fibers with a high modulus of elasticity onto a bobbin, the twill twill at a specific angle. The present inventors have discovered that the above-mentioned problems can be solved by winding the material in a tapered end manner at a specific taper angle.

すなわち、本発明の目的は高弾性率のピッチ系炭素繊維
束を製品ボビンから糸切れ、ケバ立ち等が発生すること
なく巻き戻しでき5また巻き戻し時の糸くずれが々く、
更には製品ボビンとしての見栄えのよいピッチ系炭素繊
維の巻き取シ方法を提供するものである。そしてその目
的は引張)弾性率がe Oton /−以上のピッチ系
炭素繊維をボビンに巻き取るに際し、綾角を0、/〜コ
j0  とし、かつテーパ角10〜70°でテーパーエ
ンド巻きに巻き取ることによシ容易に達成される。
That is, an object of the present invention is to be able to unwind a pitch-based carbon fiber bundle with a high elastic modulus from a product bobbin without causing yarn breakage or fuzzing, etc.5, and to prevent yarn breakage during unwinding.
Furthermore, the present invention provides a method for winding pitch-based carbon fibers that look good as product bobbins. The purpose of this is to wind pitch-based carbon fiber with a tensile modulus of elasticity of e Oton /- or more onto a bobbin, with a winding angle of 0, / ~ coj0, and a tapered end winding with a taper angle of 10 to 70°. This is easily achieved by taking.

以下、本発明の詳細な説明するに、本発明に用いられる
ピッチ系炭素繊維は下記の様にして製造される。
Hereinafter, the present invention will be described in detail. The pitch-based carbon fiber used in the present invention is manufactured as follows.

すなわち、周知の方法に従って紡糸ピッチとしてコール
タールピッチ、石炭液化物等の石炭系ピッチ、各種の石
油系ピッチ及び合成樹脂や天然樹脂を乾留すること罠よ
って得られる高分子i成ピッチ等が用いられ、溶融状態
の紡糸ピッチを紡糸口金から気相中に紡出し、集束して
ピッチ繊維束が得られる。
That is, coal tar pitch, coal-based pitch such as liquefied coal, various petroleum-based pitches, and polymeric i-formed pitch obtained by carbonizing synthetic resins or natural resins are used as spinning pitches according to well-known methods. The molten spinning pitch is spun out from a spinneret into a gas phase and bundled to obtain a pitch fiber bundle.

次いで得られたピッチ繊維束は酸素、オゾン。The resulting pitch fiber bundle is then exposed to oxygen and ozone.

空気、窒素酸化物、ハロゲン、亜硫酸ガス等の酸化性雰
囲気下、730〜ダ00℃の温度にs分〜70時間不融
化処理することによって不融化繊維束が得られる。得ら
れた不融化繊維束−は不活性雰囲気回申、SOO〜/1
00℃で炭化処理、更に8袂に応じて−000〜−ざ0
0℃で黒鉛化処理されて目的のピッチ系炭素繊維が製造
される。
An infusible fiber bundle is obtained by infusible treatment at a temperature of 730 to 00° C. for s minutes to 70 hours in an oxidizing atmosphere such as air, nitrogen oxide, halogen, sulfur dioxide gas, etc. The obtained infusible fiber bundle was placed in an inert atmosphere, SOO~/1
Carbonization treatment at 00°C, then -000 to -za0 depending on the 8 layers.
The target pitch-based carbon fiber is produced by graphitization treatment at 0°C.

特に本発明におりては、上記方法によシ得られたピッチ
糸炭素繊維のうち、引張シ弾性率がxi o ton/
−以上の高弾性率のピッチ系炭素繊維を対象にするもの
でア)、更に伸度が7%以下のピッチ系炭素繊維を対象
とするものでおる。
In particular, in the present invention, the pitch yarn carbon fiber obtained by the above method has a tensile modulus of xio ton/
- This method targets pitch-based carbon fibers with a high elastic modulus of 7% or higher, and (a) also targets pitch-based carbon fibers with an elongation of 7% or less.

なお、本発明のピッチ系炭素繊維とは炭化処理されて得
られた炭素繊維及び更に黒鉛化処理された黒鉛繊維を含
むものとする。
Note that the pitch-based carbon fibers of the present invention include carbon fibers obtained by carbonization treatment and graphite fibers further graphitized.

本発明においては、かかる高弾性率のピッチ系炭素繊維
をボビンに巻き取るに際し、綾角を0.7〜二S0  
としテーパ角10〜70°でテーパーエンド巻きに巻き
取シを行なう。具体的にはボビンの一端から他端に向っ
て各繊維束同士が重な)合わな因ようにして所定の綾角
で一層で巻き取った後、折シ返しを行ない同様にして繊
維束を一層で巻き取る。
In the present invention, when winding such high modulus pitch carbon fiber onto a bobbin, the helix angle is set to 0.7 to 2S0.
Winding is performed at a taper end winding with a taper angle of 10 to 70°. Specifically, each fiber bundle is wound from one end of the bobbin to the other end in a single layer at a predetermined winding angle so that the fiber bundles overlap each other, and then the fiber bundles are folded back and folded in the same manner. Roll up in one layer.

重ね巻きする際、同一方向の下糸との交差角が0070
以上となるように綾角を選択することが好ましい。これ
によ)巻き取られる繊維束が、その直下の下糸と平行に
重な夛あうことを防止することができる。綾角の変更は
トラバース速度を変更することによシ行なうことができ
る。
When overlapping, the intersection angle with the bobbin thread in the same direction is 0070
It is preferable to select the winding angle so as to satisfy the above. This can prevent the fiber bundle being wound up from stacking up parallel to the bobbin thread directly below it. Changing the wind angle can be done by changing the traverse speed.

トラバース速度はステッピングモーターとギア・の組合
せ等によ多口動的に容易に行なうことができる。
The traverse speed can be easily controlled dynamically using a combination of a stepping motor and gears.

その際下層側の繊維束の少し内側からテーパ角が上記範
囲内となるように折)返しを行なう。
At this time, the fiber bundle on the lower layer side is folded slightly from the inside so that the taper angle is within the above range.

かかる操作をくシ返し行なうことによシ連続長繊維状の
繊維束を所定のテーパ角を有するテーパーエンド巻きに
多層巻き取りを行なうものである。
By repeating this operation, the continuous long fiber bundle is wound in multiple layers into a tapered end winding having a predetermined taper angle.

ここで綾角とはボビンの半径方向に対する巻き取り繊維
束の有する角度(第1図の/に相当)を意味し、テーパ
角とはボビンの軸方向に対する巻き取シ繊維來の有する
角度(第1図の−に相当)を意味するものである。
Here, the wind angle means the angle that the winding fiber bundle has with respect to the radial direction of the bobbin (corresponding to / in Fig. 1), and the taper angle means the angle that the winding fiber bundle has with respect to the axial direction of the bobbin (corresponding to / in Fig. 1). (equivalent to - in Figure 1).

綾角としては0./〜二SO1好ましくは3〜/!0と
なるように行なうのがより0綾角を上記範囲よシ大きく
すると、折多返しの際繊維束に対し曲シ角度がつきすぎ
て糸切れ等を生じたシ、解舒時の横ずれによシ糸束を損
傷したシするので好ましくない。tた小さいと、繊維束
が重な)やすく巻き戻しの際にクバ、糸切れ等を生じ好
ましくない。
0. /~2SO1 preferably 3~/! It is better to do it so that the wind angle is 0. If the wind angle is set to be larger than the above range, the bending angle will be too high for the fiber bundle during folding, resulting in yarn breakage, etc., and lateral slippage during unwinding. This is not preferable because it may damage the weft thread bundle. If the diameter is too small, the fiber bundles tend to overlap, resulting in curling, thread breakage, etc. during unwinding, which is undesirable.

また、テーパ角としては10〜りOO,好ましくは/S
〜300となるようにテーパーエンド巻きとする。テー
パ角を上記範囲よシ大きくすると、巻き崩れが生じやす
く好ましくない。また、上記範囲よ)小さくすると巻き
取シ量が少なくなり製品ボビンとして好ましくない。
In addition, the taper angle is 10 to 000, preferably /S
Taper end winding is performed so that the thickness is ~300. If the taper angle is made larger than the above range, the winding tends to collapse, which is not preferable. Moreover, if it is smaller than the above range, the amount of winding will decrease, which is not preferable as a product bobbin.

ボビンの大きさとしては繊維束の巻き取シ量や巻き取り
速度などにより適宜選択決定されるが、通常ボビンの直
径が7oN、tool、長さが100〜3!rOvas
程度のもので、紙管状のものを用いるのが便利である。
The size of the bobbin is appropriately selected depending on the winding amount and winding speed of the fiber bundle, but the diameter of the bobbin is usually 7 oN, the tool, and the length are 100 to 3 mm. rOvas
It is convenient to use something in the shape of a paper tube.

ボビンへの巻き取りピッチは、ボビン径と綾角の大きさ
によって一義的に定まる。例えばボビン径が3インチ(
り6.−藺)であるとき、綾角をlOoとすると繊維束
の芯・思量の距離はλ、lI−となる。
The winding pitch onto the bobbin is uniquely determined by the bobbin diameter and the winding angle. For example, the bobbin diameter is 3 inches (
6. - 藺), when the wind angle is lOo, the distance between the core and the fiber bundle is λ, lI-.

更に繊維束の糸幅は単繊維の太さ、集束数等により変わ
シ1例えば10μ単糸で集束本数/ 000本の場合は
o、a −o、s園、同じく集束本数booo本の場合
はコ、S〜3IIl+l+となる。従って、同一方向の
直下の糸束と重なシあわないように、すなわちピッチが
糸幅よシ大きくなるように前記綾角を0./〜jj’の
範囲から適宜に調整することが重要である。
Furthermore, the yarn width of the fiber bundle varies depending on the thickness of the single fibers, the number of bundles, etc. 1. For example, if the number of bundles is 10 μ single yarn / 000, it is o, a - o, s, and similarly, if the number of bundles is boo, ko, S~3IIl+l+. Therefore, the helix angle should be set to 0.0 to avoid overlapping with the yarn bundle immediately below in the same direction, that is, so that the pitch is larger than the yarn width. It is important to make appropriate adjustments from the range of / to jj'.

特に繊維束を高張力でボビンに巻き取る場合には、同一
方向の直下の下糸との交差角力10.10以以上外るよ
うに綾角を変更するのが好ましい。
In particular, when winding a fiber bundle onto a bobbin with high tension, it is preferable to change the helix angle so that the cross angle force with the lower thread directly below in the same direction is 10.10 or more.

同一方向の直下の下糸の綾角よ)も0110以上綾角を
大きくしたシ、小さくした)することによって、上層側
に巻き取られる繊維束75に下層(11の繊維層に陥没
する状況を充分防止することカニできる。
By increasing or decreasing the winding angle of the bobbin thread directly under the same direction by 0110 or more, the situation where the fiber bundle 75 wound on the upper layer side collapses into the lower layer (fiber layer 11) is prevented. It is enough to prevent crabs.

各層毎の綾角の変更の度合は0.70以上、好ましくは
O,コル80程度とするのがよい。
The degree of change in the helix angle for each layer is preferably 0.70 or more, preferably about 80.

(効 果) 以上のように本発明によれば、連続長繊維状のピッチ系
炭素繊維を製品ボビンとして形成する際に特定角度の綾
角とテーノく角とでテーノ(−エンド巻きにすることに
より低張力下でも得られる製品ボビンの見栄えがよく、
また、巻き戻し時に糸切れ等を発生せず、巻き崩れのな
い、極めて良好な製品ボビンを得ること25!できる。
(Effects) As described above, according to the present invention, when forming pitch-based carbon fibers in the form of continuous long fibers into a product bobbin, it is possible to perform teno (-end winding) with a wind angle and a wind angle of a specific angle. This allows the product bobbin to look good even under low tension.
Also, to obtain an extremely good product bobbin that does not cause thread breakage or the like during unwinding and does not have loose winding.25! can.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は製品ボビンの巻き形状を示したものである。 /:綾角     、2:テーパ角 、?: ピッチ系炭素繊維 り :ボビン出鳳人 三菱
化成工業株式会社
FIG. 1 shows the winding shape of the product bobbin. /: Aya angle, 2: Taper angle, ? : Pitch-based carbon fiber Ri : Bobbin maker Mitsubishi Chemical Industries, Ltd.

Claims (3)

【特許請求の範囲】[Claims] (1)引張り弾性率が40ton/mm^2以上のピッ
チ系炭素繊維をボビンに巻き取るに際し、綾角を0.1
〜25°とし、かつテーパ角10〜70°でテーパーエ
ンド巻きに巻き取ることを特徴とするピッチ系炭素繊維
の巻き取り方法。
(1) When winding pitch-based carbon fiber with a tensile modulus of 40 ton/mm^2 or more onto a bobbin, the helix angle should be set to 0.1.
A method for winding pitch-based carbon fiber, characterized by winding it in a tapered end winding with a taper angle of ~25° and a taper angle of 10-70°.
(2)ピッチ系炭素繊維の伸度が1%以下であることを
特徴とする特許請求の範囲第1項記載の方法。
(2) The method according to claim 1, wherein the elongation of the pitch-based carbon fiber is 1% or less.
(3)重ね巻きする際、同一方向の下糸との交差角が0
.1°以上となるように綾角を選択することを特徴とす
る特許請求の範囲第1項記載の方法。
(3) When overlapping, the crossing angle with the bobbin thread in the same direction is 0.
.. A method according to claim 1, characterized in that the helix angle is selected to be 1° or more.
JP61012716A 1986-01-23 1986-01-23 Taking-up of pitch group carbon fiber Pending JPS62171871A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61012716A JPS62171871A (en) 1986-01-23 1986-01-23 Taking-up of pitch group carbon fiber

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Application Number Priority Date Filing Date Title
JP61012716A JPS62171871A (en) 1986-01-23 1986-01-23 Taking-up of pitch group carbon fiber

Publications (1)

Publication Number Publication Date
JPS62171871A true JPS62171871A (en) 1987-07-28

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JP61012716A Pending JPS62171871A (en) 1986-01-23 1986-01-23 Taking-up of pitch group carbon fiber

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998024721A1 (en) * 1996-12-05 1998-06-11 Toray Industries, Inc. Carbon fiber package and carbon fiber package body
JP2015030555A (en) * 2013-07-31 2015-02-16 三菱瓦斯化学株式会社 Wound article
WO2020050156A1 (en) * 2018-09-03 2020-03-12 三菱瓦斯化学株式会社 Wound body and wound body manufacturing method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58212563A (en) * 1982-06-02 1983-12-10 Toray Ind Inc Package of graphite thread and method of manufacture
JPS6151464A (en) * 1984-08-14 1986-03-13 Teijin Ltd Cheese package of temporary twist crimped yarn

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58212563A (en) * 1982-06-02 1983-12-10 Toray Ind Inc Package of graphite thread and method of manufacture
JPS6151464A (en) * 1984-08-14 1986-03-13 Teijin Ltd Cheese package of temporary twist crimped yarn

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998024721A1 (en) * 1996-12-05 1998-06-11 Toray Industries, Inc. Carbon fiber package and carbon fiber package body
JP2015030555A (en) * 2013-07-31 2015-02-16 三菱瓦斯化学株式会社 Wound article
WO2020050156A1 (en) * 2018-09-03 2020-03-12 三菱瓦斯化学株式会社 Wound body and wound body manufacturing method
JP2020037456A (en) * 2018-09-03 2020-03-12 国立大学法人岐阜大学 Winding body, and manufacturing method of winding body
CN112638799A (en) * 2018-09-03 2021-04-09 三菱瓦斯化学株式会社 Wound body and method for manufacturing wound body
US11834294B2 (en) 2018-09-03 2023-12-05 Mitsubishi Gas Chemical Company, Inc. Wound body and method for manufacturing wound body

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