JPS621362B2 - - Google Patents
Info
- Publication number
- JPS621362B2 JPS621362B2 JP55094563A JP9456380A JPS621362B2 JP S621362 B2 JPS621362 B2 JP S621362B2 JP 55094563 A JP55094563 A JP 55094563A JP 9456380 A JP9456380 A JP 9456380A JP S621362 B2 JPS621362 B2 JP S621362B2
- Authority
- JP
- Japan
- Prior art keywords
- test
- composition
- humus
- activated carbon
- bacteria
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 28
- 239000003864 humus Substances 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- 230000001954 sterilising effect Effects 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 4
- 235000013311 vegetables Nutrition 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 52
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 36
- 241000894006 Bacteria Species 0.000 description 23
- 238000012360 testing method Methods 0.000 description 22
- 239000007789 gas Substances 0.000 description 21
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 18
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 18
- 229910021529 ammonia Inorganic materials 0.000 description 17
- 239000000047 product Substances 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- 238000001179 sorption measurement Methods 0.000 description 15
- 239000000523 sample Substances 0.000 description 14
- 238000004458 analytical method Methods 0.000 description 13
- 235000001014 amino acid Nutrition 0.000 description 12
- 150000001413 amino acids Chemical class 0.000 description 12
- 239000002609 medium Substances 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 239000002781 deodorant agent Substances 0.000 description 9
- 239000012153 distilled water Substances 0.000 description 9
- HYYBABOKPJLUIN-UHFFFAOYSA-N mefenamic acid Chemical compound CC1=CC=CC(NC=2C(=CC=CC=2)C(O)=O)=C1C HYYBABOKPJLUIN-UHFFFAOYSA-N 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 238000010998 test method Methods 0.000 description 9
- 230000001877 deodorizing effect Effects 0.000 description 8
- 238000010790 dilution Methods 0.000 description 8
- 239000012895 dilution Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 8
- 230000014759 maintenance of location Effects 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 239000002689 soil Substances 0.000 description 8
- 241000588724 Escherichia coli Species 0.000 description 7
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 241000191967 Staphylococcus aureus Species 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- 150000007524 organic acids Chemical class 0.000 description 6
- 239000012085 test solution Substances 0.000 description 6
- 241000206761 Bacillariophyta Species 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 230000001580 bacterial effect Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 235000019645 odor Nutrition 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 235000000346 sugar Nutrition 0.000 description 5
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000003463 adsorbent Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 4
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 238000000855 fermentation Methods 0.000 description 4
- 230000004151 fermentation Effects 0.000 description 4
- 239000004310 lactic acid Substances 0.000 description 4
- 235000014655 lactic acid Nutrition 0.000 description 4
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 238000004451 qualitative analysis Methods 0.000 description 4
- 238000004445 quantitative analysis Methods 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 229920001817 Agar Polymers 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 3
- 239000008272 agar Substances 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000012258 culturing Methods 0.000 description 3
- 238000000921 elemental analysis Methods 0.000 description 3
- 210000003608 fece Anatomy 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000000691 measurement method Methods 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 235000019750 Crude protein Nutrition 0.000 description 2
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 2
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 description 2
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 229940088710 antibiotic agent Drugs 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 2
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003797 essential amino acid Substances 0.000 description 2
- 235000020776 essential amino acid Nutrition 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000002538 fungal effect Effects 0.000 description 2
- 229930182830 galactose Natural products 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 244000144972 livestock Species 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000002504 physiological saline solution Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000006150 trypticase soy agar Substances 0.000 description 2
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 238000007696 Kjeldahl method Methods 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- 239000005949 Malathion Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229930182555 Penicillin Natural products 0.000 description 1
- JGSARLDLIJGVTE-MBNYWOFBSA-N Penicillin G Chemical compound N([C@H]1[C@H]2SC([C@@H](N2C1=O)C(O)=O)(C)C)C(=O)CC1=CC=CC=C1 JGSARLDLIJGVTE-MBNYWOFBSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000000944 Soxhlet extraction Methods 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 229930003270 Vitamin B Natural products 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- -1 citric acid Chemical compound 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000019784 crude fat Nutrition 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 239000002384 drinking water standard Substances 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- DFBKLUNHFCTMDC-GKRDHZSOSA-N endrin Chemical compound C([C@@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@@H]2[C@H]2[C@@H]1O2 DFBKLUNHFCTMDC-GKRDHZSOSA-N 0.000 description 1
- 235000021121 fermented vegetables Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 235000021190 leftovers Nutrition 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000000504 luminescence detection Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229960000453 malathion Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- HOVAGTYPODGVJG-ZFYZTMLRSA-N methyl alpha-D-glucopyranoside Chemical compound CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HOVAGTYPODGVJG-ZFYZTMLRSA-N 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 229940049954 penicillin Drugs 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 239000001965 potato dextrose agar Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
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Landscapes
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Description
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The present invention has properties such as deodorizing, sterilizing, and gas adsorption properties obtained by forcibly oxidizing and drying a fermented vegetable material, that is, humus mud, or low-level peat that has been deposited in water such as the seabed and lake bottom for many years. The present invention relates to a composition containing relatively abundant various amino acids and various metals. Here, deodorizing, sterilization, gas adsorption, etc. refer to the above-mentioned properties that are effective as food deterioration prevention agents, water quality deterioration prevention agents, fermentation accelerators, food consistency retaining agents, etc. In the specification, the three properties listed at the beginning, deodorizing, sterilization, and gas adsorption, are listed as representative agents for the sake of simplicity, but this agent also includes other properties and covers these properties as well. It is. Deodorizing, sterilizing, and
The side effects of gas adsorbents and the like have been a problem, and there is an increasing demand for natural substitutes or processed products thereof, but there are currently no suitable substitutes. The applicants had previously applied for a patent in Japanese Patent Application No. 102222/1983 for a method for extracting fermented soil materials with water, but the bactericidal power of the resulting aqueous solution was still not satisfactory, so they decided to use processed natural products. We have continued our research with the aim of obtaining compositions with even stronger bactericidal, deodorizing, and gas adsorption properties.
As a result, we have completed the invention regarding the composition of the present invention. Therefore, an object of the present invention is to effectively bring out the strong deodorizing, sterilizing, and gas adsorbing properties inherent in naturally occurring raw materials, and to provide a composition having such properties. The above object is achieved by the following composition of the present invention. Namely, (1) a gas adsorbent deodorizing/sterilizing composition obtained by forcibly oxidizing vegetable humus mud and drying it at a temperature of 80° C. or lower until the moisture content is 60% or less; (2) The composition according to item (1) above, obtained by finely pulverizing the composition obtained by drying the above to form a powder with a water content of about 30%. (3) A composition obtained by immersing the composition obtained by drying the above in warm water for 30 minutes or more to obtain an extract having a pH of 6.5 or less, and then filtering off the dust residue. (4) The composition according to item (3) above, wherein the filtration is performed in two stages: industrial filtration and micropore filtration that does not allow substances of 0.8Ό or larger to pass through. The raw material for the composition of the present invention is so-called humic mud, which is a clay-like form of fermented plant matter that has been deposited in water such as seabeds and lake bottoms over a long period of time. Fermented products cannot be used as raw materials for the composition of the present invention. The composition of the present invention usually uses diatoms and plants that are fermented in water and deposited in the form of mud as raw materials. The above raw materials are drained and transported to the factory for use, but in such conditions they usually contain more than 70% water. The raw materials brought into the factory are first subjected to a crushing process, where they are brought into sufficient contact with air and forcibly oxidized. Since the raw materials include some unfermented materials, it is necessary to subject them to the above-mentioned oxidation process for at least 30 minutes or more. After oxidation, dry the product at a temperature below 80°C to reduce the moisture content to below 60% by weight. The above-mentioned forced oxidation and drying are important processing methods for obtaining the composition of the present invention, and only by this method can a fermented composition whose performance is stabilized at a constant value be obtained. The obtained dried product is finely pulverized into a fine powder with a water content of approximately 30%, which can be used as a deodorizer and fermentation accelerator. It is also possible to form granules from a dried product or from a fine powder once produced. Add 5 to 10% (by weight) of the dried or finely ground product to warm water and immerse and stir for 30 minutes or more to obtain an extract having a pH of 6.5 or less (preferably 2.0 to 4.0). Next, impurities are filtered using an industrial filter to obtain a liquid deodorant. This thing has a light brown color. Filtered with an industrial filter, further filtered with 0.8Ό or
By passing the solution through a filter that does not allow anything larger than 0.45 Όm to pass through, such as a micropore filter, a solution that is extremely effective as a disinfectant, food deterioration preventive agent, and water quality deterioration preventive agent can be obtained. The powder deodorant obtained by the above method is a fine powder with an apparent specific gravity of 0.53 and a moisture content of 30±3%, and is useful for deodorizing human excrement, preventing scum, promoting fermentation, preventing rot, household waste, fish odor, and livestock production. It is used to prevent foul odors and deodorize sewage and manholes. For human feces, the total amount of human feces
The standard usage amount is 1/600, and it may increase or decrease depending on the odor generation situation. Powdered deodorants are reported to contain vitamins B6 and B12 . This product can be stored for a long time as long as it does not get wet. Granular deodorant has an apparent specific gravity of 0.9 to 0.94 and a moisture content of 10 to 30.
% To remove foul-smelling gases generated in the atmosphere or industrially, it is convenient to use the gas by directly feeding it through the packed bed of a packed column and exhausting it, or by circulating it. . To remove malodorous gases contained in water or aqueous solutions, or to suppress harmful gases generated by the decay of organic matter deposited at the bottom of oceans, rivers, lakes, ponds, etc., use granular deodorizers in an appropriate net. Use it by putting it in a container such as a bag, or by scattering or burying it as is. Liquid deodorant is a light brown liquid with a specific gravity of
1.001-1.002, PH3.0-3.6. It is used to deodorize fish and livestock industry, deodorize human feces, deodorize household leftovers and containers in refrigerators, deodorize rancid odors of pickles, and deodorize containers. To do so, spray the undiluted solution or diluted solution in the form of a mist. use. This product has also passed the drinking water standard test. According to the test results, neither tannin (0.01%) nor propyl gallate (0.005g/Kg) was detected in the obtained solution. , does not contain mercury, and does not detect arsenic, lead, copper, antimony, etc. Zinc content 0.1ppm or less, tin content
It has been tested to pass the soft drink standard test at 1.0ppm or less. This product contains large amounts of 17 essential amino acids including aspartic acid, vitamin B, organic acids such as citric acid, and mineral components such as iron and calcium ions. Detailed various test results will be described in Examples. The composition of the present invention will be further explained with reference to the following examples. Example 1 Approximately 300 g of drained raw material was obtained by draining 1,820 g of humus mud, a vegetable fermentation product with 95% water content that is thought to have been deposited in water for hundreds of years or more, and this was crushed while being crushed in an open container. Approximately 215 g of oxidized product was obtained by blowing air with a blower. This was dried with hot air at about 75°C to obtain 130 g of a dry product with a moisture content of about 30%.
This was finely pulverized to obtain a powder deodorant. Also, by extracting the same powder deodorant with 2000ml of warm water at 50â, approximately 2000ml of pH3.0 solution was obtained, which was filtered with an industrial filter to obtain approximately
1700ml of solution was obtained. The residue at that time is approximately
It was 300g. Example 2 Regarding the case where a granular product is made from the finely pulverized product obtained by the above method and used as a deodorizer in a refrigerator or other relatively humid atmosphere. A comparative test was conducted on activated carbon-based adsorbents. The outline of the experiment, experimental method, filling amount, experimental equipment, experimental procedure, measurement method, results and discussion are shown below. Hereinafter, this deodorizer will be referred to as humus guardran. Overview of the experiment Two types of odor components were used: ammonia and hydrogen sulfide. A glass column was filled with the same volume of coconut shell activated carbon as a control substance, and humid ammonia gas or hydrogen sulfide gas was added from the bottom for 30 minutes.
A large excess amount of air was supplied at a flow rate of ~50 cm/sec. Thereafter, only moisture-rich air was aerated until the above components no longer flowed out. Take out humus guardlan and activated carbon from the glass column and add them to the above 2
The adsorption amount of the component was measured and the adsorption retention amount was calculated. Experimental method 1 Generation and amount of ammonia and hydrogen sulfide gas These two components were generated using the following chemicals. (1) Ammonia gas 10%NH 4 Cl + 50% NaOH
âNH 3 âïŒNaClïŒH 2 O (2) Hydrogen sulfide gas 50%Na 2 S9H 2 OïŒ18NH 2 SO 4
âH 2 SâïŒNa 2 SO 4 +H 2 O (3) Amount of gas generated Referring to literature values for adsorption and retention of ammonia and hydrogen sulfide on activated carbon, 30% of that value
Double doses were generated continuously for 16 hours. 2 Packing amount of humus guardlan and activated carbon A glass column (diameter 1.55 cm) was packed at a height of 15 cm. The filling volume was 28.4 cm 3 . The activated carbon is Coconut Shell Activated Carbon, Shirasagi C 6 /10, manufactured by Takeda Pharmaceutical Co., Ltd., and has a particle size of 2 to 6 mm. 3 Experimental apparatus The experimental apparatus is shown in Figure 1. In the figure, 1 is a glass column with a diameter of 1.55 cm, 2 is a packed humus gardan or coconut shell activated carbon, and has a height of 15 cm. 3 is a separating funnel 4 is a gas generation container 5 is 10% NH 4 Cl or 50% Na 2 S9H 2 O 6 is a scour bin 7 is an air pump Four sets of the above devices were made and numbered No. 1 to No. 4. No. 1 For ammonia: Humus gardan ã 2 ã : Activated carbon ã 3 For hydrogen sulfide: Humus gardan ã 4 ã : Activated carbon 4 Experimental procedure 10% NH 4 Cl or 50% Na 2 S, 9H 2 Pour the required amount of O into the bottom of the gas generation container of the experimental apparatus, and
% NaOH or 18NH 2 SO 4 was added dropwise from a separatory funnel little by little. Air passed through an air washing bottle was sent to the bottom of the gas generation container to stir and mix the reaction solution and to aerate the mixture. Over a period of 16 hours, ammonia and hydrogen sulfide were continuously generated in large excess amounts relative to the estimated amount of adsorption and retention, and the two types of adsorbent materials were brought into contact with air. Thereafter, the reaction liquid in the gas generation container was removed, water was added, and only moisture-rich air was vented. Aeration was continued until no ammonia or hydrogen sulfide was detected at the outlet of the glass column. Humus gardane and activated carbon were taken out from the glass column and the amount of adsorption of ammonia and hydrogen sulfide was measured. 5 Measurement method For moisture, ammonia and hydrogen sulfide
Measurements were conducted in accordance with JIS K0102 factory wastewater test method. (1) Ammonia Titration method after alkaline distillation (2) Hydrogen sulfide Titration method after acidic distillation (3) 105â drying method Results and discussion Moisture, ammonia, and hydrogen sulfide for unused and adsorbed humus gardan and activated carbon The measurement results are shown below.
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äžèšæ瞟ãè¡šâïŒã«ç€ºãã[Table] Based on the above experimental results (1) The moisture content of unused Hyumas Guardan is 33%.
However, even when air with a high moisture content was brought into contact with the air, the moisture content did not increase. (2) On the other hand, the moisture content of activated carbon increased to 26% (compared to 3.7% for unused products). (3) When looking at unused products, activated carbon contains almost no ammonia and hydrogen sulfide, but humus gardan had higher values than the former, at 133 mg/Kg of ammonia and 21 mg/Kg of hydrogen sulfide. (4) Comparing the amount of adsorption and retention per unit weight of dry matter between humus gardan and activated carbon, it is found that humus gardan has more ammonia than activated carbon.
The value was 9 times higher for hydrogen sulfide. (5) In this way, humus gardane was clearly superior to activated carbon in its ability to adsorb and retain ammonia and hydrogen sulfide in a humid atmosphere. This experiment was conducted in a moisture-rich atmosphere, but under these conditions, the amount of adsorption and retention of activated carbon was significantly reduced. For reference, the amount of adsorption and retention of activated carbon in a dry atmosphere is shown below. Ammonia 0.2% Hydrogen sulfide 15% The amount of ammonia adsorbed and retained by humus gardan is 10% of the above value of activated carbon even in a moisture-rich atmosphere.
Although it was twice as high, this is thought to be due to the excellent properties of humus guard run. As described above, humus gardan, which has a higher adsorption and retention capacity than activated carbon in a moisture-rich atmosphere, can be used in a wider range of applications than activated carbon. Example 3 This example shows the results of the following component analysis experiment conducted on the finely ground powder deodorant produced by the method of Example 1. This powdered deodorant is called hyumascalmy. Outline of content analysis of âHyumascalmyâ 1 General property test PH, moisture, crude protein, crude fat, crude fiber, ash, acidity, phosphorus, potassium, COD (potassium dichromate method) 2 Hygiene test bacteria Inspection (general bacteria count, mold count, yeast count, coliform bacteria count) Toxic metals (mercury, cadmium, lead, arsenic, hexavalent chromium) Cyanide, PCB, pesticides (organic phosphorus, organic chlorine), phthalate 3 Special analysis elemental analysis (CNH), total organic carbon, luminescence spectrometry (qualitative analysis of metals), carboxylic acid composition analysis, saccharide composition analysis, amino acid composition analysis, antibiotics (penicillin), quantitative analysis of metals 4 Escherichia coli, yellow grapes Growth inhibition test 1 for cocci and Pseudomonas aeruginosa General property test 1.1 Test method PH: JIS Z8802 (glass electrode method) Moisture:
105â drying method Crude protein: Kjeldahl method
Crude lipid: Soxhlet extraction method Crude fiber: Henneberg-Staumann method Ash: Electric furnace ashing method (550â) Acidity: Neutralization titration method Phosphorus: Molybdenum blue method COD: JIS K0102.15 (potassium dichromate method) 1.2 Test Results The above results are shown in Table-1.
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åæçµæããŸãšããŠè¡šâïŒã«ç€ºãã[Table] As is clear from Table 1, Hyumascalmy is characterized by its strong acidity and high mineral content. Also, the water content of 33.3% may seem high on the surface, but since the measurement method was carried out using a 105°C drying method, it is possible that some of the volatile components in the sample were also measured as water content. 2 Hygiene test 2.1 Test method Mercury: Environment Agency Notification No. 64 (atomic absorption method) Cadmium: JIS K0102.40.2 (atomic absorption method)
Lead: JIS K0102.39.2 (atomic absorption method) Arsenic:
JIS K0102.48.2 (Atomic absorption method) Hexavalent chromium: JIS K0102.51.2 (Atomic absorption method) Cyan: JIS K0102.29.2 (Atomic absorption method) PCB:
JIS K0093 (Gas chroma method) Pesticides: Hygiene test method Phthalate esters: Chemical substance investigation method (published by the Environment Agency) Antibiotics: Paper desk method 2.2 Test results The analysis results are summarized in Table 2.
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ã«ç€ºããã[Table] Considering the hygienic content from the analysis results, it satisfies the standards of the Soil Contamination Prevention Act and the Food Sanitation Act.
No standard values have been established for phthalate esters at present. (Reference material) Laws and regulations (example) Regarding pesticide residues in the United States. Ingredient specifications BHC 0.2ppm or less Aldrin Not detected Deirdrin Not detected Endrin Not detected Parathion Not detected Malathion 0.1ppm or less Cadmium 1.0ppm or less 3 Qualitative analysis of metal components by emission spectrometry and quantitative analysis by atomic absorption spectrometry 3.1 Test method Qualitative by emission spectrometer Test: Sample 1 was mixed with graphite powder at a weight ratio of 2, and the mixture was subjected to an emission spectrometer to qualitatively characterize the metal based on the relative intensity of the absorption spectrum. Quantitative test by atomic absorption method: Sodium,
potassium, calcium, magnesium, iron,
Aluminum, manganese, chromium, etc. were wet decomposed with nitric acid and then analyzed using atomic absorption spectrometry. In addition, phosphorus was determined using the molybdenum blue method after wet decomposition. Silicon was quantified by spectrophotometry after alkali melt decomposition. 3.2 Test results Table 3 shows the qualitative analysis results using the luminescence spectrometer.
Table 4 also shows the results of quantitative analysis of the main components.
It was shown to.
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Silver, copper, vanadium, barium, lead, manganese, chromium, cobalt, strontium, etc. were in groups with (+) and small numbers.
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ã§ãã€ãã[Table] Based on the results of luminescence spectroscopy, quantitative analysis of 10 types of metals was conducted. The main metals were silicon at 9.2%, aluminum at 1.9%, iron at 1.7%, and sodium at 1.09%. 4 Organic acid composition analysis 4.1 Test method Free organic acid: Take 500 mg of sample and add 5 ml of water.
After adjusting the volume to a constant volume, centrifuge (3000 rpm x 20
After filtering the supernatant, it was measured using a carboxylic acid analyzer. Organic acid of hydrolyzate: Take 10g of sample and 1N-
Dissolve in approximately 40 ml of HCl and heat under reflux for 3 hours.
Hydrolysis was performed. After that, perform centrifugation (3000 rpm x 20 minutes) and filter the supernatant.
The filtrate was diluted to 40 ml and measured using a carboxylic acid analyzer. 4.2 Test results Table 5 shows the organic acids detected. A small amount of lactic acid was detected in the free state. In addition, three types of acetic acid, formic acid, and lactic acid were detected in the hydrolyzate: acetic acid 0.078%, formic acid 0.036%, and lactic acid 0.007%.
It was %.
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žã®å«æéãè¡šâïŒã«ç€ºãã[Table] 5 Amino acid composition analysis 5.2 Test method Free amino acids: Add 200 ml of distilled water to 10 g of sample, stir, filter through filter paper No. 2, concentrate the filtrate under reduced pressure, desalt, and dry again under reduced pressure. The volume was made constant with lithium buffer at pH 2.2 and analyzed using an amino acid analyzer. Total amino acids: Hydrolyze the sample with 6N hydrochloric acid at 110â for 24 hours, then dry under reduced pressure to obtain 2.2
The solution was made to a constant volume with Lithium Buffer and analyzed using an amino acid analyzer. 5.3 Test results The content of each amino acid is shown in Table 6.
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åçš®ã®å«æéãè¡šâïŒã«ç€ºãã[Table] Although the amount of free amino acids was extremely small, a considerable amount of total amino acids was extracted. 6 Sugar composition analysis 6.1 Test method Free sugar: 10 g of sample was dissolved in 40 ml of water, shaken for about 30 minutes, centrifuged, and the supernatant liquid was dried using a rotary evaporator. Sugar of hydrolyzate: Take 10g of sample and 1N-
Hydrolysis was carried out by dissolving in 40 ml of HCl and heating under reflux. Thereafter, centrifugation was performed, and the supernatant liquid was concentrated using a rotary evaporator and dried by bubbling with N2 . Add 4 ml of pyridine (containing hydroxylamine hydrochloride and α-methyl glucoside) to the sample treated as above and heat it at 75°C for 30 minutes.
4 ml of acetic anhydride was added and left overnight. The test solution prepared in this manner was measured using a gas chromatograph. 6.2 Test results The contents of each type are shown in Table 7.
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The cells were cultured at 30°C for 2 to 3 days, and the number of heat-resistant spores was measured. 2.2 Results Table 9 shows the results.
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æããã§ããã[Table] It was difficult to do so.
** All are mold spores.
Because the medium used to measure the number of bacteria is rich in nutrients, it was not possible to prevent the growth of mold, which is overwhelmingly present in the samples, and it was not possible to accurately measure the number of surviving bacteria. Based on the shape and color, nothing that could be assumed to be bacterial could be found. The desoxycholate medium used to measure coliform bacteria is a medium with good selective growth properties, and its measured values are highly reliable, but since the number of coliform bacteria is less than 10/g, it is estimated from this value. This suggests that the values for general bacteria would also be significantly lower. All of the heat-resistant spores measured as colonies were mold colonies, but the number was less than 1/2000 of that before heat treatment. This indicates that the sample before heat treatment had more fungal hyphae and fewer spores. In other words, this may indicate that those that exist in the form of hyphae will die if heated, but those that exist in the form of spores are heat resistant. If Hyumascalmy is a so-called humus soil, the presence of about 4 million molds per gram should not be a particular problem. Summary 1 The main components of Hyumascalmy are inorganic (40
%) and PH2.98 acidity (citric acid amount conversion value) 4.08%
It is an acidic substance. 2 As for inorganic substances, 19 types of metals were detected by emission analysis, including 9.2% silicon, 1.9% aluminum, and 1.7% iron.
%, sodium 1.09%, etc. are the main ingredients. 3. Hazardous substances such as residual pesticides and heavy metals meet the standard values of the Soil Contamination Prevention Act and the Food Sanitation Act. 4 Organic acids include acetic acid 0.078%, formic acid 0.036%, and lactic acid.
Three components were detected at 0.007%. 5. Among the constituent amino acids, 16 components including essential amino acids were detected, and the total amount of amino acids was 7841 ppm (0.78%). 6 The constituent sugars are galactose, arabinose, glucose, xylose, mannose, rhamnose, etc., and the total amount is 1.35%. 7 Constituent elements are C = 14.0%, H = 2.3%, N = 0.8
%. Example 4 This example shows the results of a microbial test on the solution obtained by further subjecting the pH 2.8 solution that was filtered using an industrial filter in Example 1 to micropore filtration that does not allow substances of 0.8Ό or larger to pass through. shows. Hereinafter, the above solution will be referred to as Humerous Rubin 1000. 1 Bacterial species used Escherichia coli IFO12734 Staphylococcus aureus
FDA209P) Pseuclomonas aeruginosa
IFO12689) were used as indicator bacteria. 2. Method for preparing Hyumascalmy extract 10 g of sample was weighed, 90 ml of purified water was added, mixed well, and extracted at 50° C. for 30 minutes with stirring.
The mixture was centrifuged at 8,000 rpm (10,000ÃG) for 15 minutes to remove precipitates, and sterilized by filtration using the above-mentioned bacterial filter to remove bacteria and mold. This filtrate was used as a humus errabine 1000 extract. 3. Dilution of Hummus erravin 1000 The pH of Hummus erravin 1000 is extremely low (around 2.8), so it is assumed that all indicator bacteria cannot tolerate low PH. Dilutions were made with sterile distilled water. That is, the above Hummus Errabine 1000 is mixed with sterile distilled water.
The test solutions were diluted 10 times, 100 times, 300 times, and 500 times. 4 Pre-culture of indicator bacteria and measurement of the number of viable bacteria in the test solution The indicator bacteria shown in 1) were incubated in ordinary broth (liquid) medium for 20 hours at 37â for Escherichia coli and Staphylococcus aureus, and at 30â for Pseudomonas aeruginosa. It was cultured and used. To inoculate the test solution, add 0.1 ml of a 100 to 500 times diluted culture solution to 10
This was done by pouring it into ml of test solution. The test solution inoculated with bacteria was kept in a furan vessel at 35â for 24 hours.
After leaving it for a while, the number of surviving bacteria was examined. To measure the number of viable bacteria, use a plain agar plate at 37°C (for E. coli and Staphylococcus aureus) or at 30°C.
It was calculated from the number of colonies formed by culturing at 1 to 2 days at â (Pseudomonas aeruginosa). Results Escherichia coli and Staphylococcus aureus were diluted 10 to 500 times with distilled water using Humus Errabine 1000, which was prepared by heating a 10% humus carmy suspension at 50â for 30 minutes, as a stock solution. The results of the antibacterial test against Pseudomonas aeruginosa and Pseudomonas aeruginosa are summarized in Table 2. Proliferation inhibitory effect when diluted with distilled water The pH of Hummus Errabine 1000 is 2.8,
When diluted 10 to 500 times with distilled water, the pH gradually increased toward neutrality as the dilution ratio increased. In a 10-fold dilution of the original solution, all E. coli bacteria died after 24 hours at 35°C, but in a 100- to 500-fold dilution, a very small number survived. Staphylococcus aureus is
It was completely destroyed up to 300 times dilution, but 10/ml survived at 500 times dilution. It had a bactericidal effect on Pseudomonas aeruginosa even when diluted 500 times. In other words, it is clear that as long as Hummus Errabine 1000 is diluted with distilled water, it has an effect of inhibiting the growth of the three types of bacteria mentioned above, although there are differences in degree.
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液ã§ãå¹æããã€ãã[Table] Distilled water Hummus Errabin 1000 was effective in inhibiting the growth of E. coli, Staphylococcus aureus, Pseudomonas aeruginosa, etc. even when diluted 500 times.
第ïŒå³ã¯å®æœäŸïŒã®å®éšè£ 眮ã瀺ãã FIG. 1 shows the experimental apparatus of Example 2.
Claims (1)
空æ°ãšå åæ¥è§Šãããããã®åæã®åããããšé
æ°ãå°ãå ±30å以äžç¶ããé žåã®çµã€ããã®ãçŽ
80âãçŽ75âã®ç±é¢šã§æ°ŽåçŽ60ïŒ ãçŽ30ïŒ ä»¥äžã®
也ç¥ç©ãšãåŸãããã¬ã¹åžçæ§ã»æ®ºèçµæç©ã ïŒ äžèšä¹Ÿç¥ããŠåŸãããçµæç©ãæŽã«åŸ®ç²ç ã
ãŠæ°Žå30ïŒ ååŸã®ç²æ«ãšããå Žåã®ç¹èš±è«æ±ã®ç¯
å²ïŒã®çµæç©ã ïŒ äžèšä¹Ÿç¥ããŠåŸãããçµæç©ãæž©æ°Žäžã§30å
é以äžæµžæŒ¬ããPH6.5以äžã®æœåºæ¶²ãšããåŸãŽã
æ®æž£ãå»ããŠåŸãããçµæç©ã ïŒ äžèšéãå·¥æ¥çéãš0.8M以äžã®ç©è³ªã
éããªããã¯ãããŒã¢éãšïŒæ®µã«è¡ãããå Žå
ã®ç¹èš±è«æ±ã®ç¯å²ïŒã®çµæç©ã[Claims] 1. Vegetable humus mud raw material is subjected to a crushing process, and the raw material is changed and aerated for at least 30 minutes to bring it into sufficient contact with air, and the oxidized material is crushed into approximately
A gas-adsorbing and sterilizing composition that can be dried with hot air at 80°C to about 75°C and has a moisture content of about 60% to about 30% or more. 2. The composition according to claim 1, wherein the composition obtained by drying the above is further finely pulverized into a powder having a water content of about 30%. 3. A composition obtained by immersing the composition obtained by drying the above in warm water for 30 minutes or more to obtain an extract having a pH of 6.5 or less, and then removing dust residue. 4. The composition according to claim 3, wherein the filtration is carried out in two stages: industrial filtration and micropore filtration which does not allow substances of 0.8M or more to pass through.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9456380A JPS5721474A (en) | 1980-07-12 | 1980-07-12 | Novel gas-adsorbable, deodorizing, bactericidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9456380A JPS5721474A (en) | 1980-07-12 | 1980-07-12 | Novel gas-adsorbable, deodorizing, bactericidal composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5721474A JPS5721474A (en) | 1982-02-04 |
| JPS621362B2 true JPS621362B2 (en) | 1987-01-13 |
Family
ID=14113779
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9456380A Granted JPS5721474A (en) | 1980-07-12 | 1980-07-12 | Novel gas-adsorbable, deodorizing, bactericidal composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5721474A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5391121A (en) * | 1977-01-22 | 1978-08-10 | Tokyo Shiyokubutsu Kagaku Kenk | Sterilizing agent and use thereof |
-
1980
- 1980-07-12 JP JP9456380A patent/JPS5721474A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5391121A (en) * | 1977-01-22 | 1978-08-10 | Tokyo Shiyokubutsu Kagaku Kenk | Sterilizing agent and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5721474A (en) | 1982-02-04 |
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