JPS6210565B2 - - Google Patents

Info

Publication number: JPS6210565B2
Authority: JP; Japan
Prior art keywords: monomer; graft copolymer; graft; rubber; polymerization
Prior art date: 1981-10-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP15964881A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5861112A (ja

Inventor

Hiromi Takao

Mikio Hirai

Masaru Yamada

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sumitomo Chemical Co Ltd

Original Assignee

Sumitomo Chemical Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-10-06

Filing date

1981-10-06

Publication date

1987-03-06

1981-10-06 Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd

1981-10-06 Priority to JP15964881A priority Critical patent/JPS5861112A/ja

1983-04-12 Publication of JPS5861112A publication Critical patent/JPS5861112A/ja

1987-03-06 Publication of JPS6210565B2 publication Critical patent/JPS6210565B2/ja

Status Granted legal-status Critical Current

Links

229920001971 elastomer Polymers 0.000 claims description 41
239000000178 monomer Substances 0.000 claims description 34
229920000578 graft copolymer Polymers 0.000 claims description 31
239000005060 rubber Substances 0.000 claims description 25
239000002270 dispersing agent Substances 0.000 claims description 13
238000000034 method Methods 0.000 claims description 13
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
239000007900 aqueous suspension Substances 0.000 claims description 6
239000004721 Polyphenylene oxide Substances 0.000 claims description 5
229920000570 polyether Polymers 0.000 claims description 5
229920001577 copolymer Polymers 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
150000001875 compounds Chemical class 0.000 claims description 3
229920001897 terpolymer Polymers 0.000 claims description 3
150000001993 dienes Chemical class 0.000 claims description 2
229920000642 polymer Polymers 0.000 description 17
239000006227 byproduct Substances 0.000 description 13
238000006116 polymerization reaction Methods 0.000 description 12
239000002245 particle Substances 0.000 description 11
238000006243 chemical reaction Methods 0.000 description 10
238000005470 impregnation Methods 0.000 description 7
239000000203 mixture Substances 0.000 description 7
229920005989 resin Polymers 0.000 description 7
239000011347 resin Substances 0.000 description 7
239000000047 product Substances 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
-1 ether compound Chemical class 0.000 description 4
238000003756 stirring Methods 0.000 description 4
239000000725 suspension Substances 0.000 description 4
239000002202 Polyethylene glycol Substances 0.000 description 3
229920001893 acrylonitrile styrene Polymers 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
229920001223 polyethylene glycol Polymers 0.000 description 3
239000002685 polymerization catalyst Substances 0.000 description 3
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 3
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 2
239000004372 Polyvinyl alcohol Substances 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000000605 extraction Methods 0.000 description 2
239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
229910052740 iodine Inorganic materials 0.000 description 2
239000011630 iodine Substances 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
229920002451 polyvinyl alcohol Polymers 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
238000010557 suspension polymerization reaction Methods 0.000 description 2
OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 2
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
239000004609 Impact Modifier Substances 0.000 description 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
101100208721 Mus musculus Usp5 gene Proteins 0.000 description 1
229920002025 Pluronic® F 88 Polymers 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001253 acrylic acids Chemical class 0.000 description 1
229920000800 acrylic rubber Polymers 0.000 description 1
239000000654 additive Substances 0.000 description 1
229920013820 alkyl cellulose Polymers 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229920006026 co-polymeric resin Polymers 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
HQPMKSGTIOYHJT-UHFFFAOYSA-N ethane-1,2-diol;propane-1,2-diol Chemical compound OCCO.CC(O)CO HQPMKSGTIOYHJT-UHFFFAOYSA-N 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
239000005038 ethylene vinyl acetate Substances 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
238000005187 foaming Methods 0.000 description 1
238000010559 graft polymerization reaction Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
125000005641 methacryl group Chemical group 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
239000011259 mixed solution Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001993 poloxamer 188 Polymers 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
238000004904 shortening Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
229920006027 ternary co-polymer Polymers 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Landscapes

Polymerisation Methods In General (AREA)
Graft Or Block Polymers (AREA)

JP15964881A 1981-10-06 1981-10-06 改良されたグラフト共重合体の製造方法 Granted JPS5861112A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP15964881A JPS5861112A (ja)	1981-10-06	1981-10-06	改良されたグラフト共重合体の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP15964881A JPS5861112A (ja)	1981-10-06	1981-10-06	改良されたグラフト共重合体の製造方法

Publications (2)

Publication Number	Publication Date
JPS5861112A JPS5861112A (ja)	1983-04-12
JPS6210565B2 true JPS6210565B2 (es)	1987-03-06

Family

ID=15698297

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP15964881A Granted JPS5861112A (ja)	1981-10-06	1981-10-06	改良されたグラフト共重合体の製造方法

Country Status (1)

Country	Link
JP (1)	JPS5861112A (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6114460A (en) *	1997-05-15	2000-09-05	Sumitomo Chemical Company, Limited	Method for producing graft copolymer rubber and polypropylene-based resin composition

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH08302099A (ja) *	1995-04-27	1996-11-19	Sumitomo Chem Co Ltd	ポリプロピレン組成物

1981
- 1981-10-06 JP JP15964881A patent/JPS5861112A/ja active Granted

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6114460A (en) *	1997-05-15	2000-09-05	Sumitomo Chemical Company, Limited	Method for producing graft copolymer rubber and polypropylene-based resin composition

Also Published As

Publication number	Publication date
JPS5861112A (ja)	1983-04-12

Publication	Publication Date	Title
US5168109A (en)	1992-12-01	Process for preparing low inherent viscosity-high glass transition agents as an overpolymer on polyvinyl chloride resins
US4798869A (en)	1989-01-17	Process for the production of thermoplastic compositions and compositions produced thereby
US3676528A (en)	1972-07-11	Preparation of polymeric compositions of high impact resistance
EP0208382B1 (en)	1991-09-18	Rubber-reinforced styrenic polymer resins having improved flow and gloss characteristics
JPH0714987B2 (ja)	1995-02-22	エラストマー含有塩化ビニルグラフト共重合体の製造方法
JPH0617429B2 (ja)	1994-03-09	粒子状ブラフトポリマーの合成法
JPS5940845B2 (ja)	1984-10-03	小粒度スパインを使用する重合方法
US2442588A (en)	1948-06-01	Copolymer of acrylate ester, acrylonitrile, and a diene-1, 3
US3551523A (en)	1970-12-29	Polymerization process for preparing high impact polymers
JPS6210565B2 (es)	1987-03-06
US4746705A (en)	1988-05-24	Vinyl chloride polymer composition containing (meth)acrylate-alpha methyl styrene copolymer
JPS61207411A (ja)	1986-09-13	塩化ビニル系樹脂の製造法
JPH04216808A (ja)	1992-08-06	重合可能なモノマーとオレフィン／一酸化炭素コポリマーとのグラフトコポリマー
EP0061134B1 (en)	1986-08-06	Improved polyvinyl chloride and preparation thereof
US3719731A (en)	1973-03-06	High-impact moulding compositions and process for preparing same
JPS63245414A (ja)	1988-10-12	グラフト重合体の製造法
KR20030056031A (ko)	2003-07-04	내후성과 내충격성이 향상된 열가소성 수지 조성물 및 그제조방법
EP0177956B1 (en)	1989-04-19	Low molecular weight vinyl halide/vinyl ester copolymers by aqueous polymerization
JPH02265908A (ja)	1990-10-30	共役ジエン系共重合体の製造方法
US2663701A (en)	1953-12-22	Process for polymerizing certain unsaturated compounds in an aqueous system
JP3402016B2 (ja)	2003-04-28	塩化ビニル系重合体の製造方法
JPH0224842B2 (es)	1990-05-30
EP0177974B1 (en)	1990-09-12	A method for the preparation of a polyvinyl chloride resin
JPH0225923B2 (es)	1990-06-06
US4342845A (en)	1982-08-03	Vinyl halide-polyolefin polymer and copolymers and method of making

JPS6210565B2 - - Google Patents

Info

Links

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=15698297

Family Applications (1)

Country Status (1)

Cited By (1)

Families Citing this family (1)

Cited By (1)

Also Published As

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