JPS61175601A - Light selectively absorptive synthetic resin plate - Google Patents
Light selectively absorptive synthetic resin plateInfo
- Publication number
- JPS61175601A JPS61175601A JP1527385A JP1527385A JPS61175601A JP S61175601 A JPS61175601 A JP S61175601A JP 1527385 A JP1527385 A JP 1527385A JP 1527385 A JP1527385 A JP 1527385A JP S61175601 A JPS61175601 A JP S61175601A
- Authority
- JP
- Japan
- Prior art keywords
- synthetic resin
- neodymium
- resin
- absorbing
- transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 24
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 24
- 229910052779 Neodymium Inorganic materials 0.000 claims abstract description 19
- -1 neodymium carboxylate Chemical class 0.000 claims abstract description 10
- 230000000694 effects Effects 0.000 abstract description 11
- 229920005989 resin Polymers 0.000 abstract description 11
- 239000011347 resin Substances 0.000 abstract description 11
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 abstract description 9
- 230000007423 decrease Effects 0.000 abstract description 4
- 229920000728 polyester Polymers 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 2
- 230000005540 biological transmission Effects 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 150000002798 neodymium compounds Chemical class 0.000 description 5
- 230000003595 spectral effect Effects 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- ARWCRSVRKCNEDI-UHFFFAOYSA-K neodymium(3+);octanoate Chemical compound [Nd+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O ARWCRSVRKCNEDI-UHFFFAOYSA-K 0.000 description 2
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 238000000045 pyrolysis gas chromatography Methods 0.000 description 1
- 238000002215 pyrolysis infrared spectroscopy Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Landscapes
- Optical Filters (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
り凹
本発明はオフィースφオートメイション機器等のカラー
ブラウン管の表示面に被覆し、又は表示面前面に設置し
、或いはこれら機器の作業者の保エヘメガネとし・て使
用される合成樹脂板に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention can be used to coat the display surface of a color cathode ray tube in office φ automation equipment, etc., or to be installed in front of the display surface, or to be used as safety glasses for workers of these equipment. This invention relates to a synthetic resin board.
” l fl ベ
オフィース・オートメイション機器等のカラーブラウン
管の表示面上の画像は1gk光体から発せられる赤、&
1.青色の光を合成して得られる。近年、これらのa器
が造速に普及しこれに伴いより昨明な画像が求められて
いる。然し、通常使用される蛍光体では発光スペクトラ
ムにおけるメインピークの割合が高く色純度が悪く忠実
な色再現がなされない、たとえば、赤、緑、青色の発光
体に夫々希土類系のY2O3:Eu 或いはGdz
O2S: Tb、硫化物系のZnS : AHが用いら
れた時、発光のメインピークが夫々82Qnm、 55
0nm、 450nmであるのに対し、サブピークが赤
色の場合560〜@00nm及び1330nm付近に生
じ、緑色の場合480〜490nm、 580〜590
nm、 1125nm付近に生じる。これらのサブピー
クの影響に因り画面の輝度が落ち。” l fl The image on the display screen of a color cathode ray tube such as Beofice automation equipment is the red light emitted from the 1gk light body, &
1. Obtained by synthesizing blue light. In recent years, these type-A devices have become increasingly popular, and as a result, there is a demand for clearer images. However, commonly used phosphors have a high proportion of the main peak in the emission spectrum and have poor color purity, making it difficult to reproduce faithful colors. For example, rare earth Y2O3:Eu or Gdz are used as red, green, and blue light emitters, respectively.
When O2S: Tb and sulfide-based ZnS: AH are used, the main peaks of luminescence are 82Qnm and 55, respectively.
0nm and 450nm, whereas sub-peaks occur around 560~@00nm and 1330nm for red color, and 480~490nm and 580~590nm for green color.
nm, occurring around 1125 nm. The brightness of the screen decreases due to the influence of these sub-peaks.
色の純度が落ちるという問題がある。There is a problem that the purity of the color decreases.
従来、他のサブピークを吸収し鮮唄な画像を(する為に
ブラウン管パネルにネオジウム元素を分散させる方法が
行われているが、この方法ではパネルの研摩される部分
や表示面として使用されない部分にまでネオジウムが分
散されることになり、製品コストの点で問題がある。ま
た、他の方法としてサブピークに相当する波長を吸収す
るネオジウム化合物を合成樹脂に分散させ、この樹脂を
表示面に被覆、又は表示面前面に設置する方法が知られ
ている。然しネオジウム化合物として無機化合物を選択
すると吸収特性がそれほど顕著では無くサブピークを選
択吸収する効果が少ない、又。Conventionally, a method has been used to disperse neodymium in the cathode ray tube panel in order to absorb other subpeaks and produce a clear image. This results in the neodymium being dispersed up to 500 nm, which poses a problem in terms of product cost.Another method is to disperse a neodymium compound that absorbs the wavelength corresponding to the subpeak into a synthetic resin, and coat the display surface with this resin. Alternatively, a method is known in which the neodymium compound is installed in front of the display screen.However, if an inorganic compound is selected as the neodymium compound, the absorption characteristics are not so pronounced and the effect of selectively absorbing subpeaks is small.
ネオジウム化合物として有機化合物を選択し、この微粒
子を合成樹脂に分散させた場合も同様にサブピークを吸
収する効果が少ない、しかも樹脂の透明度が低下する問
題がある。Even when an organic compound is selected as the neodymium compound and the fine particles are dispersed in a synthetic resin, there is a similar problem in that the effect of absorbing subpeaks is small and the transparency of the resin is reduced.
&監立亘旦
本発明者等は植種検討の結果、可視部において透明な合
成樹脂にカルボン酸ネオジウムを成る割合に配合にする
とこの樹脂は紫外線(波長400nm ”未満)を吸収
し、更に500〜530nm及び570〜600nmの
波長帯を選択的に吸収する特性を有し、しかも他の可視
部の波長に対しては良好な透明性を示すため、サブピー
クの影響を著しく低減しカラーブラウン管表示面上の画
像を鮮明にする効果の有ることの知見を得た。本発明は
上記知見に基づくものであり、本発明によれは、可視部
において透明な合成樹脂にカルボン酸ネオジウムをネオ
ジウムとして 0.25〜5.00重量%配合したこと
を特徴とする光選択吸収性合成樹脂板が提供される。As a result of seed planting studies, the inventors of the present invention have found that when neodymium carboxylate is blended with a transparent synthetic resin in the visible region, this resin absorbs ultraviolet rays (wavelengths less than 400 nm), and It has the property of selectively absorbing wavelength bands of ~530nm and 570~600nm, and also exhibits good transparency for other wavelengths in the visible region, significantly reducing the effects of subpeaks and improving the color cathode ray tube display surface. The present invention is based on the above knowledge, and according to the present invention, neodymium carboxylate is added to a transparent synthetic resin in the visible region as neodymium. A light-selective absorptive synthetic resin board is provided, characterized in that it contains 25 to 5.00% by weight.
本発明において、可視部において透明な合成樹脂とは、
可視光線及び紫外線の波長を透過する性質の合成樹脂を
言い1例えばポリエステル、ポリスチレン、メタクリル
樹脂、ポリカーボネイト。In the present invention, the synthetic resin that is transparent in the visible part is
Synthetic resins that transmit visible and ultraviolet wavelengths include polyester, polystyrene, methacrylic resin, and polycarbonate.
ポリメチルペンテン、塩化ビニール等が挙げられる。勿
論上記樹脂に限定されない。Examples include polymethylpentene and vinyl chloride. Of course, it is not limited to the above resins.
又、本発明で用いられるカルボン酸ネオジウムはカルボ
ン酸の種類については限定されず、例えば、オクタン酸
、ナフテン酸、ステアリン酸等が挙げられる。これらの
カルボン酸ネオジウムの合成樹脂への添加量はネオジウ
ムとして 0.25〜5゜00重量2が好ましい、 5
.00重量2を越えると樹脂が白濁し、また0、25重
重量上り少ないとサブピークを吸収する効果が少なく板
の厚さを非現実的な厚さとしなければ充分な吸収効果が
得られず、実用に酎えない。Further, the type of carboxylic acid used in the neodymium carboxylate used in the present invention is not limited, and examples thereof include octanoic acid, naphthenic acid, and stearic acid. The amount of these neodymium carboxylates added to the synthetic resin is preferably 0.25 to 5.00% by weight2 as neodymium.
.. If the weight exceeds 0.00 weight 2, the resin will become cloudy, and if the weight exceeds 0.25 weight, it will not be effective in absorbing sub-peaks, and unless the thickness of the plate is unrealistic, sufficient absorption effect will not be obtained, making it difficult for practical use. I can't drink alcohol.
え見立羞】
本発明の合成樹脂は、紫外線を吸収する効果がある他、
後述の実施例及び比較例に示されるように他のネオジウ
ム化合物を添加するものに比べ、500〜530nm及
び570〜1300nmの波長の光を選択吸収する効果
が大きい、この為、赤、緑、青色のサブピークを吸収し
画像鮮明にする効果が優れている。これはカルボン酸ネ
オジウムが合成樹脂に対して相溶性があるため、他のネ
オジウムの無機化合物や有機化合物を添加した場合に比
べ選択吸収性が格段に優れるからであると考えられる。The synthetic resin of the present invention has the effect of absorbing ultraviolet rays, as well as
As shown in the Examples and Comparative Examples below, compared to those added with other neodymium compounds, it has a greater effect of selectively absorbing light with wavelengths of 500 to 530 nm and 570 to 1300 nm. It has an excellent effect of absorbing sub-peaks and making images clearer. This is thought to be because neodymium carboxylate is compatible with the synthetic resin, and therefore has much better selective absorption than when other inorganic or organic compounds of neodymium are added.
更に、本発明の合成樹脂板は他のネオジウム有機化合物
を分散したものとは異なり樹脂の透明度が低下すること
もない。Further, the synthetic resin plate of the present invention does not have a decrease in resin transparency, unlike those in which other neodymium organic compounds are dispersed.
L1町 次に本発明の実施例及び比較例を示す。L1 town Next, Examples and Comparative Examples of the present invention will be shown.
実施例1〜4及び比較例1〜2
オクタン酸ネオジウムを次表に示す植種の割合でポリエ
チレンフマレートに均一に混合し、0.31の厚さの板
に成形し得られたポリエステル樹脂板の波長520mm
、580nmにおける分光透過率を測定した。結果を次
表に示す、この結果から明らかなように本発明の樹脂は
分光透過率が著しく小さくこの波長帯の光を選択的に吸
収することが判る。Examples 1 to 4 and Comparative Examples 1 to 2 A polyester resin board obtained by uniformly mixing neodymium octoate with polyethylene fumarate at the inoculum ratio shown in the following table and molding it into a board with a thickness of 0.31. wavelength of 520mm
, the spectral transmittance at 580 nm was measured. The results are shown in the following table. As is clear from the results, the resin of the present invention has an extremely low spectral transmittance and selectively absorbs light in this wavelength range.
尚、実施例1〜4で得られたポリエステル樹脂板につい
て熱分解ガスクロマトグラフィー、赤外線分光分析によ
る含有有機化合物の分析を行ったところ夫々のポリエス
テル樹脂板にはオクタン酸ネオジウムが所定着合まれて
いることが確認された。Incidentally, when the polyester resin plates obtained in Examples 1 to 4 were analyzed for organic compounds contained therein by pyrolysis gas chromatography and infrared spectroscopy, it was found that neodymium octoate was incorporated into each polyester resin plate in a predetermined amount. It was confirmed that there is.
(注)表中O印は透明度が良好、 X印は白濁していることを示す。(Note) The O mark in the table indicates good transparency. The X mark indicates cloudiness.
実施例5
ナフテン酸ネオジウムをネオジウムとして4.01重量
駕配合したポリスチレンを押出機により 1.4mmの
厚さの板に成形し、可視部の分光透過率を測定した。こ
の結果を図に示す。図から明らかなように本実施例の樹
脂は500〜530nm及び570〜600nmの波長
帯において極めて顕著な吸収特性を示している。Example 5 Polystyrene containing 4.01 weight percent neodymium naphthenate was molded into a 1.4 mm thick plate using an extruder, and the spectral transmittance in the visible region was measured. The results are shown in the figure. As is clear from the figure, the resin of this example exhibits extremely remarkable absorption characteristics in the wavelength bands of 500 to 530 nm and 570 to 600 nm.
比較例3
平均粒径4終履の酸化ネオジウムをネオジウムとして4
.12重1に%分散させたポリスチレンを実施例5と同
様に板に成形し可視部の分光透過率を測定した。結果を
図に示す0図に示されるように実施例5に比べ吸収特性
はそれほど顕著ではないことが判る。Comparative Example 3 Neodymium oxide with an average particle size of 4 was used as neodymium 4
.. Polystyrene dispersed in 12 parts by 1 part was molded into a plate in the same manner as in Example 5, and the spectral transmittance in the visible region was measured. As shown in Figure 0, which shows the results, it can be seen that the absorption characteristics are not so remarkable compared to Example 5.
図は本発明の実施例5と比較例3に係る合成樹脂板の分
光透過率の測定結果を示すグラフである。
特許出願人 三菱金属株式会社
第一エンジニアリング株式会社The figure is a graph showing the measurement results of the spectral transmittance of synthetic resin plates according to Example 5 of the present invention and Comparative Example 3. Patent applicant Mitsubishi Metals Corporation Dai-ichi Engineering Co., Ltd.
Claims (1)
をネオジウムとして0.25〜5.00重量%配合した
ことを特徴とする光選択吸収性合成樹脂板。1. A light-selective absorptive synthetic resin board, characterized in that 0.25 to 5.00% by weight of neodymium carboxylate is blended with a synthetic resin that is transparent in the visible region.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1527385A JPS61175601A (en) | 1985-01-31 | 1985-01-31 | Light selectively absorptive synthetic resin plate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1527385A JPS61175601A (en) | 1985-01-31 | 1985-01-31 | Light selectively absorptive synthetic resin plate |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS61175601A true JPS61175601A (en) | 1986-08-07 |
Family
ID=11884251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1527385A Pending JPS61175601A (en) | 1985-01-31 | 1985-01-31 | Light selectively absorptive synthetic resin plate |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61175601A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999051680A1 (en) * | 1998-03-31 | 1999-10-14 | Seiko Instruments Inc. | Composition exhibiting reversible color change and exterior parts for clock using the same |
WO2000023829A1 (en) * | 1998-10-20 | 2000-04-27 | Fuji Photo Film Co., Ltd. | Optical filter |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5158444A (en) * | 1974-11-19 | 1976-05-21 | Matsushita Electric Works Ltd | PURASUCHITSU KUSUSOSEIBUTSU |
JPS559801A (en) * | 1977-12-27 | 1980-01-24 | Manami Matsuoka | Plastic plate for exposure |
JPS5915910A (en) * | 1982-07-20 | 1984-01-27 | Yoshimi Matsuoka | Manufacture of antidazzling plastic filter |
-
1985
- 1985-01-31 JP JP1527385A patent/JPS61175601A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5158444A (en) * | 1974-11-19 | 1976-05-21 | Matsushita Electric Works Ltd | PURASUCHITSU KUSUSOSEIBUTSU |
JPS559801A (en) * | 1977-12-27 | 1980-01-24 | Manami Matsuoka | Plastic plate for exposure |
JPS5915910A (en) * | 1982-07-20 | 1984-01-27 | Yoshimi Matsuoka | Manufacture of antidazzling plastic filter |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999051680A1 (en) * | 1998-03-31 | 1999-10-14 | Seiko Instruments Inc. | Composition exhibiting reversible color change and exterior parts for clock using the same |
JPH11344580A (en) * | 1998-03-31 | 1999-12-14 | Seiko Instruments Inc | Reversible discoloring composition and clock enclosing part using this |
US6569919B1 (en) * | 1998-03-31 | 2003-05-27 | Seiko Instruments Inc. | Composition exhibiting reversible color change and exterior parts for clock using the same |
WO2000023829A1 (en) * | 1998-10-20 | 2000-04-27 | Fuji Photo Film Co., Ltd. | Optical filter |
US6532120B1 (en) * | 1998-10-20 | 2003-03-11 | Fuji Photo Film Co., Ltd. | Optical filter |
CN1295523C (en) * | 1998-10-20 | 2007-01-17 | 富士胶片株式会社 | Optical filter |
KR100684343B1 (en) * | 1998-10-20 | 2007-02-20 | 후지필름 홀딩스 가부시끼가이샤 | Optical filter |
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