JPS61152603A - Transpiring agent for expelling cockroach - Google Patents
Transpiring agent for expelling cockroachInfo
- Publication number
- JPS61152603A JPS61152603A JP27627984A JP27627984A JPS61152603A JP S61152603 A JPS61152603 A JP S61152603A JP 27627984 A JP27627984 A JP 27627984A JP 27627984 A JP27627984 A JP 27627984A JP S61152603 A JPS61152603 A JP S61152603A
- Authority
- JP
- Japan
- Prior art keywords
- cockroaches
- hydroprene
- agent
- parts
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241001674044 Blattodea Species 0.000 title claims abstract description 34
- FYQGBXGJFWXIPP-UHFFFAOYSA-N hydroprene Chemical compound CCOC(=O)C=C(C)C=CCC(C)CCCC(C)C FYQGBXGJFWXIPP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 230000005068 transpiration Effects 0.000 claims description 23
- 229930000073 hydroprene Natural products 0.000 abstract description 27
- 239000003795 chemical substances by application Substances 0.000 abstract description 25
- 239000002917 insecticide Substances 0.000 abstract description 13
- 230000001954 sterilising effect Effects 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 4
- 239000000417 fungicide Substances 0.000 abstract description 3
- 239000003381 stabilizer Substances 0.000 abstract description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000460 chlorine Substances 0.000 abstract description 2
- 229910052801 chlorine Inorganic materials 0.000 abstract description 2
- 238000002788 crimping Methods 0.000 abstract 1
- 210000003746 feather Anatomy 0.000 abstract 1
- 230000000855 fungicidal effect Effects 0.000 abstract 1
- 230000009036 growth inhibition Effects 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 125000005461 organic phosphorous group Chemical group 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 239000002728 pyrethroid Substances 0.000 abstract 1
- 238000004904 shortening Methods 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- -1 pulp Substances 0.000 description 10
- 239000005001 laminate film Substances 0.000 description 9
- 235000019645 odor Nutrition 0.000 description 7
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 6
- 238000011109 contamination Methods 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 2
- GPNYZBKIGXGYNU-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-5-ethyl-2-hydroxyphenyl)methyl]-4-ethylphenol Chemical compound CC(C)(C)C1=CC(CC)=CC(CC=2C(=C(C=C(CC)C=2)C(C)(C)C)O)=C1O GPNYZBKIGXGYNU-UHFFFAOYSA-N 0.000 description 2
- 241000238657 Blattella germanica Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 229940073665 octyldodecyl myristate Drugs 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 1
- SKHBJDDIGYYYMJ-UHFFFAOYSA-N 2,6-ditert-butyl-6-methylcyclohexa-1,3-dien-1-ol Chemical compound CC(C)(C)C1=C(O)C(C)(C(C)(C)C)CC=C1 SKHBJDDIGYYYMJ-UHFFFAOYSA-N 0.000 description 1
- VTIMKVIDORQQFA-UHFFFAOYSA-N 2-Ethylhexyl-4-hydroxybenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(O)C=C1 VTIMKVIDORQQFA-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 1
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 1
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- CONKBQPVFMXDOV-QHCPKHFHSA-N 6-[(5S)-5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-2-oxo-1,3-oxazolidin-3-yl]-3H-1,3-benzoxazol-2-one Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C[C@H]1CN(C(O1)=O)C1=CC2=C(NC(O2)=O)C=C1 CONKBQPVFMXDOV-QHCPKHFHSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YKDMBTQVKVEMSA-UHFFFAOYSA-N diethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCOC(=O)CCCCCCCCCCCCCCCCC YKDMBTQVKVEMSA-UHFFFAOYSA-N 0.000 description 1
- 229940111071 diethylene glycol distearate Drugs 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- BNKAXGCRDYRABM-UHFFFAOYSA-N ethenyl dihydrogen phosphate Chemical compound OP(O)(=O)OC=C BNKAXGCRDYRABM-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 230000009422 growth inhibiting effect Effects 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 230000036244 malformation Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- BPJZKLBPJBMLQG-KWRJMZDGSA-N propanoyl (z,12r)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OC(=O)CC BPJZKLBPJBMLQG-KWRJMZDGSA-N 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】 [産業上の利用分野] 本発明は、ゴキブリ駆除用蒸散剤に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a transpiration agent for exterminating cockroaches.
ざらに詳しくは、エチル(2E、4E)−3,7,11
−トリメチル−2,4−ドデカジエノエート(以下、ハ
イドロプレンという)を活性成分とし、必要に応じて殺
虫剤、殺菌剤、安定剤、溶剤、揮散調節剤、香料、色素
などを配合し、担体に担持させてなるゴキブリ駆除用蒸
散剤に関する。In more detail, ethyl (2E, 4E)-3,7,11
- Trimethyl-2,4-dodecadienoate (hereinafter referred to as hydroprene) is used as an active ingredient, and insecticides, fungicides, stabilizers, solvents, volatility regulators, fragrances, pigments, etc. are added as necessary, This invention relates to a cockroach exterminating transpiration agent supported on a carrier.
[従来の技術]
従来、ゴキブリ駆除剤として、11Nしたり、燻蒸した
りして用いる殺虫剤が広く利用されている。[Prior Art] Conventionally, insecticides that are used after 11N or fumigation have been widely used as cockroach exterminators.
[発明が解決しようとする問題点]
殺虫剤によるゴキブリの駆除は、即効的であるが残効性
が弱く、1回の処理で3か月以上の長期にわたりゴキブ
リの数を減らすことは難しく、必然的に殺虫剤の使用回
数が増加し、多大な労力と経済的負担を余儀無くされて
いる。[Problems to be solved by the invention] Although the extermination of cockroaches using insecticides has an immediate effect, the residual effect is weak, and it is difficult to reduce the number of cockroaches over a long period of three months or more with a single treatment. Inevitably, the number of times insecticides are used increases, necessitating great labor and economic burden.
しかしながら、殺虫剤の多用はゴキブリの抵抗性を増大
させる危険性があり、殺虫剤の使用回数はできるだけ少
ない方が望ましい。However, frequent use of insecticides risks increasing the resistance of cockroaches, so it is desirable to use insecticides as few times as possible.
また、殺虫剤には汚染や不快臭を伴うものが多く、使用
場所を著しく限定されるのが通常である。In addition, many insecticides are associated with pollution and unpleasant odors, and the places where they can be used are usually severely limited.
[問題卓を解決するための手段]
本発明者らは、これらの問題点を除去すべく種々の薬剤
について検討を重ねた結果、ゴキブリに対して生長阻害
効果、不妊化効果を有するハイドロブレンに着目するに
至った。[Means for solving the problem table] As a result of repeated studies on various drugs in order to eliminate these problems, the present inventors have discovered that hydrobrene, which has a growth inhibiting effect and a sterilizing effect on cockroaches, has been developed. I came to pay attention to it.
ハイドロブレンには殺虫剤のような即効性はないが、ハ
イドロプレンで処理したゴキブリの幼虫は、生長が抑制
され、成虫となっても羽が縮れて短かくなるなどの外観
を呈し、また脱皮に失敗して死亡するばあいもある。な
お、成虫の中で羽が縮れて通常の羽の半分以下となった
り、全く羽のないゴキブリは不妊化されており、正常な
ゴキブリと交合しても子供が生まれない。Although hydroprene does not have the same immediate effect as insecticides, cockroach larvae treated with hydroprene have their growth suppressed, and even when they become adults, their wings appear curly and short, and they molt. In some cases, failure may result in death. Additionally, adult cockroaches whose wings are curled to less than half their normal size, or who have no wings at all, are sterile and cannot produce children even if they mate with normal cockroaches.
またハイドロプレンは、塩素系、有機リン系および(ま
たは)ピレスロイド系などの従来の殺虫剤に抵抗性を有
するゴキブリに対しても有効である。Hydroprene is also effective against cockroaches that are resistant to conventional insecticides such as chlorine, organophosphate and/or pyrethroids.
ハイドロプレンを含有する剤型として乳剤、油剤、エア
ゾール剤などが知られているが、これらはいずれもゴキ
ブリに接触することにより効果を発揮するものであり、
ハイドロプレンを含有するゴキブリ駆除用蒸散剤は知ら
れていない。Emulsions, oils, aerosols, etc. are known as formulations containing hydroprene, but all of these are effective when they come into contact with cockroaches.
There are no known transpiration agents for killing cockroaches that contain hydroprene.
本発明者らは、ハイドロプレンを活性成分とする各種の
剤型を検討した結果、ハイドロプレンは蒸気圧が低いに
もかかわらず、ゴキブリに対して自然蒸散方式で充分効
果があることを見出し、本発明を完成するに至った。As a result of examining various formulations containing hydroprene as an active ingredient, the present inventors found that hydroprene is sufficiently effective against cockroaches by natural transpiration, despite its low vapor pressure. The present invention has now been completed.
すなわち本発明は、ハイドロプレンを担持させた担体を
至内の天井に吊り下げたり、食器棚や引き出しなどに入
れておくだけの簡単な使用方法で、汚染や不快臭がなく
、1回の設置で半年から1年間という長期間にわたりゴ
キブリの生長を阻害したり、不妊化によりゴキブリを駆
除することができるゴキブリ駆除用蒸散剤に関する。In other words, the present invention can be easily used by simply hanging the carrier carrying hydroprene on the ceiling of a room or placing it in a cupboard or drawer, and there is no contamination or unpleasant odor, and it can be installed only once. The present invention relates to a transpiration agent for exterminating cockroaches that can inhibit the growth of cockroaches or exterminate cockroaches by sterilizing them over a long period of six months to one year.
[実施例]
本発明においてはハイドロプレンが担体に担持せしめら
れてゴキブリ駆除用蒸散剤が製造される。[Example] In the present invention, a transpiration agent for exterminating cockroaches is produced by supporting hydroprene on a carrier.
本発明に用いる担体としては、たとえば紙類、グラスウ
ール、パルプ、石綿、合成繊維、天然繊維などの繊維類
、塩化ビニル、ポリエチレン、ポリエチレン発泡体、ポ
リプロピレン、ウレタンなどの合成樹脂類、天然ゴム、
シリコーンゴム、パイトンゴム、ネオブレンゴムなどの
ゴム類、木粉、活性炭などの有機粉末や粒状物、シリカ
ゲル、アルミナ、ケイソウ土、パーライト、バーミキュ
ライト、ゼオライト、クレー、酸性白土、粉末ケイ酸(
商品名:アエロジル)などの無機粉末や粒状物J多孔質
無機焼結体、多孔質セラミックなどそのもの、あるいは
それらから成形されたりしたものなどがあげられ、それ
らを単独または併用することができる。前記の毬のを用
いて担体を形成するばあいには、必要に応じてデンプン
、メチルセルロース、カルボキシメチルセルロースナト
リウム(C)fc−Na)、ヒドロキシプロピルセルロ
ースなどのバインダーを加えて任意の形に成形してもよ
い。Examples of carriers used in the present invention include paper, glass wool, pulp, asbestos, fibers such as synthetic fibers and natural fibers, synthetic resins such as vinyl chloride, polyethylene, polyethylene foam, polypropylene, and urethane, natural rubber,
Rubbers such as silicone rubber, pyton rubber, neorene rubber, organic powders and granules such as wood flour and activated carbon, silica gel, alumina, diatomaceous earth, perlite, vermiculite, zeolite, clay, acid clay, powdered silicic acid (
Examples include inorganic powders such as (trade name: Aerosil), granular materials J porous inorganic sintered bodies, porous ceramics, etc., or products molded from them, and these can be used alone or in combination. When forming a carrier using the above-mentioned cones, a binder such as starch, methylcellulose, sodium carboxymethylcellulose (C)fc-Na), or hydroxypropylcellulose may be added as necessary and molded into any shape. It's okay.
前記担体にハイドロプレンを担持させる方法としては、
たとえばハイドロプレンをそのままあるいは溶剤で希釈
したものを担体と混合して吸着させたり、担体にふりか
けて吸着あるいは含浸させて担持させてもよく、ハイド
ロプレンやその希釈液に担体を浸漬して含浸させて担持
させでもよく、ハイドロプレンの存在下で担体を成形し
て担持させたりしてもよい。As a method for supporting hydroprene on the carrier,
For example, hydroprene as it is or diluted with a solvent may be adsorbed by mixing with a carrier, or may be supported by being adsorbed or impregnated by being sprinkled on the carrier, or by immersing the carrier in hydroprene or its diluted solution and impregnating it. Alternatively, the carrier may be formed and supported in the presence of hydroprene.
担体に担持ざぜるハイドロプレンの量は、担体の種類に
より異なるため一概には決定できないが、担体100部
(重量部、以下同様)に対して、好ましくは0.1〜5
0部、ざらに好ましくはO,S〜30部である。The amount of hydroprene supported on the carrier cannot be determined unconditionally because it varies depending on the type of carrier, but it is preferably 0.1 to 5 parts by weight per 100 parts (parts by weight, same hereinafter) of the carrier.
0 parts, preferably O,S to 30 parts.
担体にハイドロプレンを担持させるに際しては、活性成
分としてのハイドロプレンに、(R3)−(E)−1−
エチニル−2−メチル−2−ペンテニル−(IR)−シ
ス、トランスークリサンテマート(以下、エムペンスリ
ンという>、0.0−ジメチル−0−(2,2−ジクロ
ロ)ビニルホスフェート(以下、DDVPという)など
の蒸散性の高い殺虫剤、叶クロロートキシレノール、α
−ブロモシンナミックアルデヒドなどの蒸散性の高い殺
菌剤、安定剤である2、6−ジーt−ブチル−叶クレゾ
ール、2.2′−メチレンビス(4−エチル−6−t−
ブチルフェノール) 、4.4’−ブチリデンビス(3
−メチル−6−t−ブチルフェノール)、2.2−メチ
レンビス(4−メチル−6−t−ブチルフェノール)な
どの酸化防止剤、含浸を容易ならしめるための溶剤であ
るミリスチン酸イソプロピル、パルミチン酸イソプロピ
ル、ラウリル酸ヘキシル、脂肪酸エステル、ケロシン、
パラフィン系の有機溶剤などや、揮散調節剤であるミリ
スチン酸オクチルドデシル、オレイン酸オクチルドデシ
ル、ステアリン酸ブチル、オレイン酸ブチル、バルミチ
ン酸ブチル、ジエチレングリコールジステアレート、フ
マル酸ジブチル、マレイン酸ジブチル、グリセリンモノ
オレート、2−エチルへキシル−p−ヒドロキシベンゾ
エート、アセチルリシノール酸メチル、ジー2−エチル
へキシルセバケート、エポキシ化ダイズ油、フタル酸系
可塑剤、エポキシ系可塑剤、ポリエステル系可塑剤など
の可塑剤、ざらに香料、色素なども必要に応じて併用し
てもよい。When supporting hydroprene on a carrier, (R3)-(E)-1-
ethynyl-2-methyl-2-pentenyl-(IR)-cis, trans-chrysanthemate (hereinafter referred to as empensuline), 0.0-dimethyl-0-(2,2-dichloro)vinyl phosphate (hereinafter referred to as DDVP) ), highly transpiring insecticides such as Kanochlorotoxylenol, α
- Highly transpirable fungicides such as bromocinnamic aldehyde, stabilizers such as 2,6-di-t-butyl-cresol, 2,2'-methylenebis(4-ethyl-6-t-
butylphenol), 4,4'-butylidene bis(3
-methyl-6-t-butylphenol), antioxidants such as 2,2-methylenebis(4-methyl-6-t-butylphenol), isopropyl myristate, isopropyl palmitate, which are solvents to facilitate impregnation, hexyl laurate, fatty acid ester, kerosene,
Paraffin-based organic solvents, octyldodecyl myristate, octyldodecyl oleate, butyl stearate, butyl oleate, butyl balmitate, diethylene glycol distearate, dibutyl fumarate, dibutyl maleate, monoglycerin, etc. Plasticizers such as oleate, 2-ethylhexyl-p-hydroxybenzoate, methyl acetyl ricinoleate, di-2-ethylhexyl sebacate, epoxidized soybean oil, phthalate plasticizers, epoxy plasticizers, polyester plasticizers, If necessary, fragrances, pigments, etc. may also be used in combination.
このようにして製造された本発明のゴキブリ駆除用蒸散
剤は、使用に際してハイドロプレンが1TrL3当りo
、ia、g以上、好まL<G;t 1.OqQ上使用す
るのがよい。The cockroach extermination transpiration agent of the present invention produced in this way has a hydroprene content of o per TrL3 when used.
, ia, g or more, preferably L<G; t 1. It is better to use it on OqQ.
本発明においてはハイドロプレンを担体に担持させて蒸
散剤にすることによって、簡単な使用方法によって汚染
や不快臭がなく、長期間効力を維持しうるゴキブリ駆除
用蒸散剤かえられ ゛る。In the present invention, by supporting hydroprene on a carrier and making it into a transpiration agent, a transpiration agent for exterminating cockroaches that is easy to use, free from contamination and unpleasant odor, and maintains its effectiveness for a long period of time can be obtained.
つぎに本発明のゴキブリ駆除用蒸散剤を実施例にもとづ
き説明する。Next, the cockroach exterminating transpiration agent of the present invention will be explained based on Examples.
実施例1
ハイドロプレン10部、2.6−ジーt−ブチル−p−
クレゾール1部、ケロシン89部の混合物1gを75X
150x 0.3mの紙に含浸させ、アルミラミネー
トフィルムで密封して蒸散剤をえた。Example 1 10 parts of hydroprene, 2,6-di-t-butyl-p-
75X 1 g of a mixture of 1 part cresol and 89 parts kerosene
A 150 x 0.3 m paper was impregnated and sealed with an aluminum laminate film to obtain a transpiration agent.
実施例2
ハイドロプレン2部、2,2−メチレンビス(4−エチ
ル−6−t−ブチルフェノール)0.2部、ミリスチン
酸オクチルドデシル97.1部、香料0.1部の混合物
2gを5〜9メツシユの粒状シリカゲルに吸着させ、6
X 9 cmの不織布製の袋に入れ、ざらにこの袋を
アルミラミネートフィルムで密封して蒸散剤をえた。Example 2 2 g of a mixture of 2 parts of hydroprene, 0.2 parts of 2,2-methylenebis(4-ethyl-6-t-butylphenol), 97.1 parts of octyldodecyl myristate, and 0.1 part of fragrance was added to 5 to 9 Adsorbed onto mesh granular silica gel, 6
The mixture was placed in a nonwoven fabric bag measuring 9 cm x 9 cm, and the bag was sealed with an aluminum laminated film to obtain a transpiration agent.
実施例3
ハイドロプレン5部、2,6−ジーt−ブチル−p−ク
レゾール0.5部、ミリスチン酸イソプロピル50部、
ステアリン酸ブチル44部、香料0.5部からなる混合
物1gを50X80X 2an、密度0.0299 /
ctx ’の発泡ポリエチレン板に含浸させ、アルミ
ラミネートフィルムで密封して蒸散剤をえた。Example 3 5 parts of hydroprene, 0.5 parts of 2,6-di-t-butyl-p-cresol, 50 parts of isopropyl myristate,
1 g of a mixture consisting of 44 parts of butyl stearate and 0.5 parts of fragrance was prepared at 50 x 80 x 2 an, density 0.0299/
A transpiration agent was obtained by impregnating a foamed polyethylene board of CTX' and sealing it with an aluminum laminate film.
実施例4
ハイドロプレン5部、2,6−ジーt−ブチル−p−ク
レゾール0.5部、ミリスチン酸イソプロピル93.5
部、色素1部からなる混合物100qを35x22X
3711111のパルプ製マットに含浸させ、アルミラ
ミネートフィルムで密封して蒸散剤をえた。Example 4 5 parts of hydroprene, 0.5 part of 2,6-di-t-butyl-p-cresol, 93.5 parts of isopropyl myristate
35 x 22 x 100q of a mixture consisting of
A transpiration agent was obtained by impregnating a pulp mat of No. 3711111 and sealing it with an aluminum laminate film.
実施例5
ハイドロプレン1部、4,4−ブチリデンビス(3−メ
チル−6−t−ブチルフェノール)0.3部、木粉40
部、パーライト53.3部、色素0.1部、香料0.3
部、CHC−Ha 5部に水を加えて混練し、常法に
より径約1.2#1I11の顆粒を調製した。Example 5 1 part of hydroprene, 0.3 part of 4,4-butylidenebis(3-methyl-6-t-butylphenol), 40 parts of wood flour
part, perlite 53.3 parts, pigment 0.1 part, fragrance 0.3 parts
and 5 parts of CHC-Ha, water was added and kneaded to prepare granules having a diameter of about 1.2#1I11 by a conventional method.
この顆粒10gを5 x 5 cutの不織布製の袋に
入れ、ざらにアルミラミネートフィルムで密封して蒸散
剤をえた。10 g of the granules were placed in a 5 x 5 cut nonwoven fabric bag and sealed with an aluminum laminated film to obtain a transpiration agent.
実施例6
ハイドロプレン10部、DOVP 5部、2,6−ジ
ーt−ブチル−p−クレゾール1部、ミリスチン酸イソ
プロピル84部からなる混合物11001r1を30X
30X O,3mmの紙に含浸させ、アルミラミネート
フィルムで密封して蒸散剤をえた。Example 6 A mixture 11001r1 consisting of 10 parts of hydroprene, 5 parts of DOVP, 1 part of 2,6-di-t-butyl-p-cresol, and 84 parts of isopropyl myristate was heated at 30X
A transpiration agent was obtained by impregnating a 3mm paper with 30X O and sealing it with an aluminum laminate film.
実施例7
ハイドロプレン5部、エムペンスリン10部、2.2°
−メチレンビス(4−メチル−6−t−ブチルフェノー
ル)0.5部、ミリスチン酸イソプロピル84.5部か
らなる混合物200rIPgを50X40X5All。Example 7 5 parts of hydroprene, 10 parts of Empensuline, 2.2°
- 200 rIPg of a mixture consisting of 0.5 part of methylenebis(4-methyl-6-t-butylphenol) and 84.5 parts of isopropyl myristate in 50 x 40 x 5 All.
密度0.021g/CI&の発泡ポリエチレン板に含浸
させ、アルミラミネートフィルムで密封して蒸散剤をえ
た。A foamed polyethylene plate with a density of 0.021 g/CI& was impregnated with the mixture and sealed with an aluminum laminate film to obtain a transpiration agent.
実施例8および比較例1
実施例1でえられた蒸散剤をアルミラミネ−トフィルム
より取り出し、8畳間(3,6X 3.6x2.7m>
の天井に5枚吊り下げた。つぎに4〜5令のチャバネゴ
キブリの幼虫20匹を入れたポリカップ(φ12cmX
6cI11)を3個置き、それぞれ1日、2日および
4日間密閉したのち取り出して25℃の別の至に移し、
成虫になるまで継続して餌青し、脱皮の失敗などによる
死亡率と不妊化率とを求めた。不妊化率は、成虫となっ
たゴキブリの奇形スコアーを第1表にしたがって求め、
奇形スコアー3以上のものを不妊化虫とした。結果を第
2表に示す。Example 8 and Comparative Example 1 The transpiration agent obtained in Example 1 was taken out from an aluminum laminate film and placed in an 8-tatami space (3.6 x 3.6 x 2.7 m).
Five of them were hung from the ceiling. Next, a polycup (φ12cm
6cI11) was placed and sealed for 1 day, 2 days, and 4 days, respectively, and then taken out and transferred to another solstice at 25°C.
The insects were fed continuously until they became adults, and the mortality rate and sterilization rate due to failure to molt were determined. The sterilization rate is determined by calculating the deformity score of adult cockroaches according to Table 1.
Those with a malformation score of 3 or higher were considered sterile insects. The results are shown in Table 2.
また、汚染の有無を調べるため、底面にガラス板を置い
て4日間放置したのちのガラス板の汚染と不快臭の有無
をしらべた。その結果、汚染および不快臭ともに全く認
められなかった。In addition, to check for contamination, a glass plate was placed on the bottom of the container and after it was left for four days, the glass plate was checked for contamination and unpleasant odors. As a result, no contamination or unpleasant odor was observed.
比較のためにペルメトリン5%を含有する市販の着火式
燻煙剤(309筒)を同じ室で使用し、3時間後にガラ
ス板を取り出したところ、黄褐色に著しく汚染し、刺激
臭が感じられた。For comparison, a commercially available ignited smoke agent (309 cylinders) containing 5% permethrin was used in the same room, and when the glass plate was taken out after 3 hours, it was noticeably contaminated with a yellowish brown color and a pungent odor was felt. Ta.
[以下余白]
第2表
実施例9
実施例4でえられた蒸散剤をアルミラミネートフィルム
より取り出して、食器棚にある33X37X 10cI
Rの引き出しに入れた。つぎに4〜5令のチャバネゴキ
ブリの幼虫20匹を入れたポリカップを3個置き、それ
ぞれ8.16.24時間後に取り出して25℃の別の至
に移し、成虫になるまで継続して飼育し、脱皮の失敗な
どによる死亡率と不妊化率を求めた。不妊化率は実施例
8と同様にして調べた。結果を第3表に示す。[Margins below] Table 2 Example 9 The transpiration agent obtained in Example 4 was taken out from the aluminum laminate film and placed in a 33X37X 10cI container in a cupboard.
I put it in R's drawer. Next, 3 polycups containing 20 German cockroach larvae of 4 to 5 instars were placed, each was taken out after 8, 16, and 24 hours and transferred to another chamber at 25°C, where they were continuously reared until they became adults. The mortality rate and sterilization rate due to failure to molt were calculated. The sterilization rate was examined in the same manner as in Example 8. The results are shown in Table 3.
第3表
実施例10および比較例2
445X 356X 230mのプラスチックコンテナ
に餌、水、ろ紙シェルタ−を置き、チャバネゴキブリの
成虫50匹(雄:雌=1:1)、幼虫300匹゛を入れ
た。つぎに実施例6でえられた蒸散剤をアルミラミネー
トフィルムより取り出してゴキブリに接触しないように
吊り下げ、ガーゼで蓋をし、25℃の室で飼育し、1力
月、3力月、6力月および9力月後のゴキブリ数を調べ
た。結果を第4表に示す。Table 3 Example 10 and Comparative Example 2 Food, water, and a filter paper shelter were placed in a 445 x 356 x 230 m plastic container, and 50 adult German cockroaches (male:female = 1:1) and 300 larvae were placed therein. Next, the transpiration agent obtained in Example 6 was taken out from the aluminum laminate film, hung so as not to come into contact with the cockroaches, covered with gauze, and reared in a room at 25°C. The number of cockroaches was examined after the first month and after the 9th month. The results are shown in Table 4.
比較例のためにDDVP 5部、2.6−ジーt−ブ
チルーp−クレゾール1部、ミリスチン酸イソプロピル
94部からなる混合物100■を30X30X O,3
Mの紙に含浸させて製造した蒸散剤をアルミラミネート
フィルムで密封したものを、実施例6でえられた蒸散剤
のかわりに用いて、上記と同様にしてゴキブリ数を調べ
た。結果を第4表にあわせて示す。For a comparative example, 100 μ of a mixture consisting of 5 parts of DDVP, 1 part of 2,6-di-t-butyl-p-cresol, and 94 parts of isopropyl myristate was heated at 30×30× O,3
A transpiration agent produced by impregnating paper No. M and sealed with an aluminum laminate film was used in place of the evaporation agent obtained in Example 6, and the number of cockroaches was investigated in the same manner as above. The results are also shown in Table 4.
[発明の効果]
本発明のゴキブリ駆除用蒸散剤は天井に吊り下げたり、
食器棚なや引き出しなどに入れておくだけという簡単な
方法で使用することができ、汚染や不快臭がなく、1回
の設置で半年から1年間という長期にわたりゴキブリの
生長を阻害したり、不妊化によりゴキブリを駆除するこ
とができる。[Effect of the invention] The cockroach exterminating transpiration agent of the present invention can be hung on the ceiling,
It can be used simply by placing it in a cupboard or drawer, has no pollution or unpleasant odors, and can inhibit the growth of cockroaches for a long period of 6 months to 1 year with a single installation. Cockroaches can be exterminated by chlorination.
弓−ζ=朝゛Bow-ζ=morning
Claims (1)
−2,4−ドデカジエノエートを担体に担持させてなる
ゴキブリ駆除用蒸散剤。1 A transpiration agent for exterminating cockroaches comprising ethyl (2E, 4E)-3,7,11-trimethyl-2,4-dodecadienoate supported on a carrier.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27627984A JPS61152603A (en) | 1984-12-27 | 1984-12-27 | Transpiring agent for expelling cockroach |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27627984A JPS61152603A (en) | 1984-12-27 | 1984-12-27 | Transpiring agent for expelling cockroach |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61152603A true JPS61152603A (en) | 1986-07-11 |
JPH0561242B2 JPH0561242B2 (en) | 1993-09-06 |
Family
ID=17567228
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP27627984A Granted JPS61152603A (en) | 1984-12-27 | 1984-12-27 | Transpiring agent for expelling cockroach |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61152603A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61268602A (en) * | 1985-05-13 | 1986-11-28 | サンド・アクチエンゲゼルシヤフト | Novel composition and method for controlling cockroach |
EP0320917A2 (en) * | 1987-12-17 | 1989-06-21 | Hercules Incorporated | Method and composition for storage of plant material |
US5015475A (en) * | 1988-05-14 | 1991-05-14 | Degesch Gmbh | Method and means for preventing or delaying undesired phosphine levels |
JP2012067053A (en) * | 2010-09-27 | 2012-04-05 | Earth Chemical Co Ltd | Method for eliminating cockroaches |
US10730707B2 (en) | 2015-09-30 | 2020-08-04 | Walter Maschinenbau Gmbh | Conveying device for conveying a workpiece |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4844430A (en) * | 1971-02-01 | 1973-06-26 |
-
1984
- 1984-12-27 JP JP27627984A patent/JPS61152603A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4844430A (en) * | 1971-02-01 | 1973-06-26 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61268602A (en) * | 1985-05-13 | 1986-11-28 | サンド・アクチエンゲゼルシヤフト | Novel composition and method for controlling cockroach |
EP0320917A2 (en) * | 1987-12-17 | 1989-06-21 | Hercules Incorporated | Method and composition for storage of plant material |
US5015475A (en) * | 1988-05-14 | 1991-05-14 | Degesch Gmbh | Method and means for preventing or delaying undesired phosphine levels |
JP2012067053A (en) * | 2010-09-27 | 2012-04-05 | Earth Chemical Co Ltd | Method for eliminating cockroaches |
US10730707B2 (en) | 2015-09-30 | 2020-08-04 | Walter Maschinenbau Gmbh | Conveying device for conveying a workpiece |
Also Published As
Publication number | Publication date |
---|---|
JPH0561242B2 (en) | 1993-09-06 |
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