JPS6114252B2 - - Google Patents
Info
- Publication number
- JPS6114252B2 JPS6114252B2 JP12438681A JP12438681A JPS6114252B2 JP S6114252 B2 JPS6114252 B2 JP S6114252B2 JP 12438681 A JP12438681 A JP 12438681A JP 12438681 A JP12438681 A JP 12438681A JP S6114252 B2 JPS6114252 B2 JP S6114252B2
- Authority
- JP
- Japan
- Prior art keywords
- foil
- thread
- silver
- gold
- short fibrous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011888 foil Substances 0.000 claims description 36
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 17
- 229910052737 gold Inorganic materials 0.000 claims description 14
- 239000010931 gold Substances 0.000 claims description 14
- 244000062175 Fittonia argyroneura Species 0.000 claims description 13
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 13
- 241000218202 Coptis Species 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 238000005520 cutting process Methods 0.000 claims description 7
- 230000001788 irregular Effects 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000010409 thin film Substances 0.000 claims description 4
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000007747 plating Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 238000007739 conversion coating Methods 0.000 claims 1
- 239000010408 film Substances 0.000 description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 10
- 229910052709 silver Inorganic materials 0.000 description 9
- 239000004332 silver Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000002932 luster Substances 0.000 description 6
- -1 Polyethylene terephthalate Polymers 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 238000009960 carding Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 210000000077 angora Anatomy 0.000 description 1
- 210000000085 cashmere Anatomy 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002343 gold Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Description
【発明の詳細な説明】
本発明は、平箔糸を短繊維状箔糸として用いた
金銀糸に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a gold and silver thread using a flat foil thread as a short fibrous foil thread.
一般に、金銀糸としては、平箔糸と撚り糸が知
られる。前者は箔シートを一定幅に裁断したもの
であり、後者は前記平箔糸を芯糸に巻きつけるか
又は前記平箔糸に細い糸を絡ませて形成したもの
である。これらはいずれも箔シートの性状をその
まま利用するものであり、規則正しい金属光沢を
有し、外観及び風合に剛直性があり、単独では妙
味のある製品とは云い難く、また他の繊維との組
合わせになる織成及び編成においても、その方法
及び用途に限度があつた。 Generally, flat foil threads and twisted threads are known as gold and silver threads. The former is formed by cutting a foil sheet to a certain width, and the latter is formed by winding the flat foil thread around a core thread or by entwining the flat foil thread with a thin thread. All of these utilize the properties of the foil sheet as they are, and have a regular metallic luster and rigidity in appearance and texture.It is difficult to say that they are attractive products on their own, and they do not work well with other fibers. There are also limits to the methods and uses of weaving and knitting that can be combined.
そこで、本発明は平箔糸を用いながら、従来の
金銀糸とは風合、外観及び物性が著しく異なり、
用途の広い金銀糸を提供する。 Therefore, although the present invention uses flat foil thread, it has a significantly different texture, appearance, and physical properties from conventional gold and silver thread.
Providing versatile gold and silver thread.
本発明の金銀糸は、短繊維状箔糸と天然及び合
成繊維から選ばれる少なくとも一種の繊維を混紡
してなるものである。 The gold and silver thread of the present invention is made by blending short fibrous foil thread and at least one type of fiber selected from natural and synthetic fibers.
本発明における短繊維状箔糸原料としては通常
の平箔糸がいずれも使用できる。これらは一般に
長繊維としてのみ使用されたものであるが、本発
明ではこれを短繊維状にして利用するものであ
り、普通糸との混紡に当り、短繊維状片の最適形
状及び構造についても種々検討した。 As the short fibrous foil yarn raw material in the present invention, any ordinary flat foil yarn can be used. These are generally used only as long fibers, but in the present invention they are used in the form of short fibers, and when blended with ordinary yarn, the optimum shape and structure of the short fiber pieces was also investigated. Various considerations were made.
本発明における平箔糸原料としては、一般的な
金銀糸素材となる箔シート、及び虹彩シート、例
えばフイルム又は紙などの基材に、金銀箔の貼
着、真空蒸着、スパツタリングなどによつて金属
層を設けたもの、特公昭56−41712号公報、特開
昭56−118916号公報、実開昭57−113935号公報及
び特願昭56−81650号明細書などに記載のものな
どがいずれも使用できる。 The flat foil thread raw materials used in the present invention include foil sheets and iris sheets, which are common gold and silver thread materials, such as metal sheets that are coated onto base materials such as film or paper by pasting gold and silver foil, vacuum deposition, sputtering, etc. Those with a layer, such as those described in Japanese Patent Publication No. 56-41712, Japanese Unexamined Patent Application Publication No. 118916-1980, Japanese Utility Model Application No. 113935-1983, and the specification of Japanese Patent Application No. 81650-1980, etc. Can be used.
短繊維状片の形状及び構造は、目的とする混紡
糸の用途及び組合わせられる繊維の種類によつて
種々異なり、特に限定されないが、通常衣料用と
して使用されることが多く、非常に細い繊維と混
紡される必要があるため、
１ 非常に柔軟で輝度の高い光沢を有する、
２ この光沢が紡績段階や製織、整染処理工程で
変質しない、
３ 人間の皮膚を害さず、また汗等によつて変質
しない、
４ 天然繊維等とも同化し、機械的に均質な混紡
が可能な細片である。 The shape and structure of the short fibrous pieces vary depending on the intended use of the blended yarn and the type of fibers to be combined, and are not particularly limited. Because it needs to be blended with 1) It is extremely flexible and has a high luster, 2) This luster does not change during the spinning, weaving, and dyeing processes, and 3) It does not harm human skin and is resistant to sweat, etc. 4. It is a fine piece that is assimilated with natural fibers and can be mechanically homogeneously blended.
などの条件を具備するのが好ましい。It is preferable to satisfy the following conditions.
そのためには、厚さ0.005〜0.012mmの、幅0.05
〜0.10mm好ましくは厚さ0.007〜0.01mm、幅0.05〜
0.07mmというような従来になく薄い箔シートを極
細に裁断して得た平箔糸を20〜50mm程度の長さに
切つて製造するのがよく、またその構造も金属層
を特願昭56−81650号明細書記載の如きクロメー
ト処理による化成皮膜やニツケルメツキによるニ
ツケル薄膜の形成、あるいは合成樹脂フイルムの
積層などで保護し、化学的に安定であり、機械的
強度のあるものとするのがよい。 For that, thickness 0.005~0.012mm, width 0.05
~0.10mm preferably thickness 0.007~0.01mm, width 0.05~
It is best manufactured by cutting an unprecedentedly thin foil sheet of 0.07 mm into ultra-fine pieces, then cutting the flat foil thread into lengths of about 20 to 50 mm, and its structure is based on a patent application made in 1983, with a metal layer. - It is preferable to protect it by forming a chemical conversion film by chromate treatment as described in the specification of No. 81650, forming a nickel thin film by nickel plating, or laminating a synthetic resin film to make it chemically stable and mechanically strong. .
箔シートの平箔糸への裁断は常法の如くマイク
ロスリツターによつてもよいが、この方法は剛直
性のある箔シートにしか適用し難く、厚さ0.015
〜0.03mm、幅0.25〜0.3mm程度の平箔糸の製造が限
度であり、前述の如き細片を得るのには適さな
い。従つて、本発明に適した薄く柔軟な箔シート
の裁断は、ギロチン式裁断によるのが好ましく、
この方法では凹凸表面を有する下敷、例えば波型
表面を有する紙や板の上に箔シートを置いて裁断
することによつて異型断面を有する短繊維状平箔
糸を得ることもできる。 The foil sheet may be cut into flat foil threads using a micro slitter as in the conventional method, but this method is difficult to apply only to rigid foil sheets, and is difficult to cut into flat foil threads with a thickness of 0.015 mm.
The production limit is limited to flat foil threads with a width of 0.03 mm and a width of 0.25 to 0.3 mm, and is not suitable for obtaining the above-mentioned strips. Therefore, the thin and flexible foil sheet suitable for the present invention is preferably cut by guillotine cutting.
In this method, a short fibrous flat foil yarn having an irregular cross section can also be obtained by placing a foil sheet on an underlay having an uneven surface, such as paper or a board having a corrugated surface, and cutting the foil sheet.
異型断面を有する短繊維状平箔糸の使用は、混
紡糸における金属光沢の露顕効果、光輝度を高め
ることとなる。 The use of a short fibrous flat foil yarn having an irregular cross section increases the metallic luster exposure effect and brightness in the blended yarn.
本発明における箔糸と他の繊維の混合割合は特
に限定されないが、箔糸が混紡糸中約50％以下、
30〜20％程度を占めるのが好ましい。 The mixing ratio of foil yarn and other fibers in the present invention is not particularly limited;
It is preferable that it accounts for about 30 to 20%.
次に本発明の実施例を示す。 Next, examples of the present invention will be shown.
実施例 （１）
フイルムAgを蒸着し、得られた蒸着フイルム
をCr（PO3）2を主成分とするクロム酸塩処理液に
浸漬して、電解処理し、処理面を別フイルムに接
着剤で貼着、転写し、Ag面を露出させ、該Ag面
を上記処理液に浸漬して再び電解処理し、処理面
に接着剤でフイルムを貼着した箔シート（厚さ約
0.01mm）を準備し、幅0.06mmの糸条に裁断し、更
に長さ30mm程度に切断して短繊維状片を作成し
た。Example (1) Film Ag was vapor-deposited, the obtained vapor-deposited film was immersed in a chromate treatment solution containing Cr(PO 3 ) 2 as the main component, electrolytically treated, and the treated surface was attached to another film with an adhesive. The Ag surface was exposed, the Ag surface was immersed in the above treatment solution and electrolytically treated again, and a foil sheet (thickness approx.
0.01 mm) was prepared, cut into threads with a width of 0.06 mm, and further cut into lengths of about 30 mm to create short fibrous pieces.
この短繊維状片を下記Ａ浴に60秒間浸漬し、水
洗乾燥した。 This short fibrous piece was immersed in Bath A below for 60 seconds, washed with water and dried.
Ａ浴
H3PO4（75％） 19ｇ/
CrO3 14ｇ/
HF（55％） 5.1ｇ/
Cr（NO3）3・9H2O 1.7ｇ/
Co（NO3）2・6H2O 1.8ｇ/
PH 1.7
短繊維状片は全く変色の認められない純銀色を
有するものであり、耐汗性及び耐硫黄性に非常に
優れたものであつた。 Bath A H 3 PO 4 (75%) 19g/ CrO 3 14g/ HF (55%) 5.1g/ Cr (NO 3 ) 3・9H 2 O 1.7g/ Co (NO 3 ) 2・6H 2 O 1.8g/ PH 1.7 The short fibrous pieces had a pure silver color with no discoloration, and had excellent sweat resistance and sulfur resistance.
この短繊維状片15重量部を、アンゴラ毛55重量
部とカシミヤ毛30重量部を常法に従つて紡糸する
際のカーデイング工程の初期に投入し、混合紡糸
した。短繊維状片は非常に細く、また側面に金属
が露出しているため、静電気を生ずることもない
ので、容易に均一な混紡ができ、風合のよい強度
ある金銀糸が得られた、この金銀糸を用いて編ん
だセーターは柔軟な感触で、上品な銀光沢の散在
する意匠効果に優れた気心地のよいセーターであ
つた。 15 parts by weight of these short fibrous pieces were added at the beginning of the carding process when 55 parts by weight of angora wool and 30 parts by weight of cashmere wool were spun according to a conventional method, and the mixture was spun. Since the short fibrous pieces are very thin and the metal is exposed on the sides, they do not generate static electricity, so they can be easily blended uniformly and a strong gold and silver thread with a good texture can be obtained. The sweater knitted with gold and silver thread had a soft feel and was a comfortable sweater with an excellent design effect, with elegant silver luster scattered throughout.
実施例 （２）
ポリエチレンテレフタレートフイルム＃25
（25／1000mm）に常法の活性化処理の後、直接硝
酸銀還元法による銀鏡反応を適用し、その片面に
銀面を形成し、得られた銀シートを純水で洗浄
し、乾燥した後、下記の組成からなるPH12、液
温30℃の浴中で、0.2A／ｄm2、15秒間浸漬処理
した。Example (2) Polyethylene terephthalate film #25
(25/1000mm) after a conventional activation treatment, a silver mirror reaction using a direct silver nitrate reduction method was applied to form a silver surface on one side, and the resulting silver sheet was washed with pure water and dried. The sample was immersed for 15 seconds at 0.2 A/dm 2 in a PH12 bath having the following composition and a liquid temperature of 30°C.
塩化ニツケル 30ｇ/
次亜リン酸ナトリウム 10ｇ/
クエン酸ナトリウム 65ｇ/
塩化アンモニウム 50ｇ/
水酸化ナトリウム 若干
銀シートの銀面上に極薄膜のニツケル被膜が形成
された。このニツケル被膜面を接着剤層（保護膜
としても働く）を介して、ポリエチレンテレフタ
レートフイルム（厚さ４μ）に貼着し、必要に応
じて熱処理後、先のポリエチレンテレフタレート
フイルム＃25を剥離し、露出した銀面に上記浴を
用いて前記同様の処理をして、ニツケル被膜を形
成し、更に接着剤を用いてポリエチレンテレフタ
レートフイルム（４μ）を貼着した。Nickel chloride 30g/ Sodium hypophosphite 10g/ Sodium citrate 65g/ Ammonium chloride 50g/ Sodium hydroxide An extremely thin nickel film was slightly formed on the silver surface of the silver sheet. This nickel coating surface is attached to a polyethylene terephthalate film (thickness 4 μm) via an adhesive layer (which also acts as a protective film), and after heat treatment if necessary, the polyethylene terephthalate film #25 is peeled off. The exposed silver surface was treated in the same manner as described above using the above bath to form a nickel film, and a polyethylene terephthalate film (4μ) was further adhered using an adhesive.
このようにして得たフイルム（４μ）／接着
剤／ニツケル薄膜／銀／ニツケル薄膜／接着剤／
フイルム（４μ）からなるシートを、波形の下敷
シート上でギロチン式裁断して、異型断面を有す
る短繊維状平箔糸を得た。 Film thus obtained (4μ)/Adhesive/Nickel thin film/Silver/Nickel thin film/Adhesive/
A sheet of film (4 μm) was cut by guillotine on a corrugated underlay sheet to obtain a short fibrous flat foil yarn having an irregular cross section.
この短繊維状平箔糸を、７〜８cmに裁断した絹
糸を用いた通常の紡糸法のカーデイング工程初期
に、絹糸75重量％に対して平箔糸15重量％となる
ように投入し、混合紡糸したところ、非常に金属
光沢に優れた柔軟な金銀糸が得られた。この金銀
糸を用いて織成した布帛は、通常の絹布同様、ス
カーフ及びブラウスなどとして品質よく着用でき
るものであつた。 This short fibrous flat foil yarn is added and mixed at the beginning of the carding process of a normal spinning method using silk yarn cut into 7 to 8 cm pieces so that the flat foil yarn is 15% by weight relative to 75% by weight of the silk yarn. When spun, a flexible gold and silver thread with excellent metallic luster was obtained. Fabrics woven using this gold and silver thread were of good quality and could be worn as scarves, blouses, etc., just like ordinary silk fabrics.
Claims (1)
0.012mm、幅0.05〜0.10mm、長さ20〜50mmの短繊維
状箔糸と天然及び合成繊維から選ばれる少なくと
も１種の繊維を混紡してなるものであつて、上記
短繊維状箔糸の金属層がクロメート処理による化
成皮膜又はニツケルメツキによるニツケル薄膜で
保護されていることを特徴とする金銀糸。 ２ 上記平箔糸が凹凸表面を有する下敷上で箔シ
ートをギロチン式裁断して得たものであることを
特徴とする特許請求の範囲第１項記載の金銀糸。 ３ 上記短繊維状箔糸が異形断面を有することを
特徴とする特許請求の範囲第１項又は第２項記載
の金銀糸。[Claims] 1. Obtained by cutting flat foil thread, thickness 0.005~
It is made by blending short fibrous foil yarn of 0.012 mm, width 0.05 to 0.10 mm, and length 20 to 50 mm with at least one type of fiber selected from natural and synthetic fibers, and the above short fibrous foil yarn is A gold and silver thread characterized in that the metal layer is protected with a chemical conversion coating formed by chromate treatment or a nickel thin film formed by nickel plating. 2. The gold and silver thread according to claim 1, wherein the flat foil thread is obtained by cutting a foil sheet using a guillotine on an underlayment having an uneven surface. 3. The gold and silver thread according to claim 1 or 2, wherein the short fibrous foil thread has an irregular cross section.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12438681A JPS5831134A (en) | 1981-08-07 | 1981-08-07 | Tinsel yarn blended spun yarn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12438681A JPS5831134A (en) | 1981-08-07 | 1981-08-07 | Tinsel yarn blended spun yarn |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5831134A JPS5831134A (en) | 1983-02-23 |
| JPS6114252B2 true JPS6114252B2 (en) | 1986-04-17 |
Family
ID=14884118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12438681A Granted JPS5831134A (en) | 1981-08-07 | 1981-08-07 | Tinsel yarn blended spun yarn |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5831134A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0386246U (en) * | 1989-12-21 | 1991-08-30 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2542294Y2 (en) * | 1993-04-21 | 1997-07-23 | 東北リコー株式会社 | Paper feed unit of printer |
-
1981
- 1981-08-07 JP JP12438681A patent/JPS5831134A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0386246U (en) * | 1989-12-21 | 1991-08-30 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5831134A (en) | 1983-02-23 |
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